非均相催化过硫酸盐氧化技术研究进展
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摘要
活化过硫酸盐氧化技术因其自由基持续时间长、pH适用范围广、前体氧化剂稳定等优势,在高级氧化技术的开发和应用中备受关注。本文综述了有效活化过硫酸盐的非均相催化材料(金属氧化物、金属基复合材料、碳材料、天然矿物等),探讨了非均相催化剂的不同催化机制及其催化活性、稳定性、可重复利用性等,并在此基础上提出了非均相催化与其他技术(紫外光辐射、超声、热、微波等)联用以提高其处理效率及范围的发展方向。
Activated persulfate oxidation technology has attracted much attention in the development and application of advanced oxidation technologies,attributing to its advantages of long duration of free radicals,wide application range of pH and good stability of precursor oxidant. In this paper,the heterogeneous catalytic materials(metal oxides,metal matrix composites,carbon materials,natural mineral materials,etc.)for effectively activating persulfate are reviewed.The catalytic mechanism,catalytic activity,stability and reproducibility of the heterogeneous catalysts are discussed.On this basis,the development direction to improve the processing efficiency and processing range by combining heterogeneous catalytic technology with other technologies(with ultraviolet radiation,ultrasound,heat,microwave,etc.)is proposed.
Activated persulfate oxidation technology has attracted much attention in the development and application of advanced oxidation technologies,attributing to its advantages of long duration of free radicals,wide application range of pH and good stability of precursor oxidant. In this paper,the heterogeneous catalytic materials(metal oxides,metal matrix composites,carbon materials,natural mineral materials,etc.)for effectively activating persulfate are reviewed.The catalytic mechanism,catalytic activity,stability and reproducibility of the heterogeneous catalysts are discussed.On this basis,the development direction to improve the processing efficiency and processing range by combining heterogeneous catalytic technology with other technologies(with ultraviolet radiation,ultrasound,heat,microwave,etc.)is proposed.
引文
[1]李社锋,王文坦,邵雁,等.活化过硫酸盐高级氧化技术的研究进展及工程应用[J].环境工程,2016,34(9):171-174.
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[3]高耀文,张晖.高级氧化技术再生吸附剂的研究进展[J].化工环保,2016,36(4):357-363.
[4]范聪剑,刘石军,刘哲,等.过硫酸盐技术去除水中有机污染物的研究进展[J].环境科学与技术,2015,38(S1):136-141.
[5]MIKLOS D B,REMY C,JEKEL M,et al.Evaluation of advanced oxidation processes for water and wastewater treatment:a critical review[J].Water Res,2018,139:118-131.
[6]MATZEK L W,CARTER K E.Sustained persulfate activation using solid iron:kinetics and application to ciprofloxacin degradation[J].Chem Eng J,2017,307:650-660.
[7]CHOI J B,CUI M C,LEE Y H,et al.Hydrodynamic cavitation and activated persulfate oxidation for degradation of bisphenol A:kinetics and mechanism[J].Chem Eng J,2018,338:323-332.
[8]LI Y,LIU L D,LIU L,et al.Efficient oxidation of phenol by persulfate using manganite as a catalyst[J].JMol Catal A,2016,411:264-271.
[9]CHENG X,GUO H G,ZHANG Y L,et al.Non-photochemical production of singlet oxygen via activation of persulfate by carbon nanotubes[J].Water Res,2017,113:80-88.
[10]YAN J C,GAO W G,DONG M G,et al.Degradation of trichloroethylene by activated persulfate using a reduced graphene oxide supported magnetite nanoparticle[J].Chem Eng J,2016,295:309-316.
[11]YAN J C,CHEN Y,QIAN L B,et al.Heterogeneously catalyzed persulfate with a CuMgFe layered double hydroxide for the degradation of ethylbenzene[J].J Hazard Mater,2017,338:372-380.
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[14]ZHANG T,CHEN Y,WANG Y R,et al.Efficient peroxydisulfate activation process not relying on sulfate radical generation for water pollutant degradation[J].Environ Sci Technol,2014,48(10):5868-5875.
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[28]唐海,李洋,汤同欢,等.CuO/UV/过硫酸盐体系深度降解印染废水[J].中国给水排水,2016,32(19):89-94.
[29]杜江坤.新型硫、锰改性铁基材料的制备及其去除水体污染物的研究[D].武汉:中国地质大学,2016.
[30]ZHANG Y C,ZHANG Q,HONG J M.Sulfate radical degradation of acetaminophen by novel iron-copper bimetallic oxidation catalyzed by persulfate:mechanism and degradation pathways[J].Appl Surf Sci,2017,422:443-451.
[31]WANG J J,WANG C,TONG S P.A novel composite Fe-N/O catalyst for the effective enhancement of oxidative capacity of persulfate at ambient temperature[J].Catal Commun,2018,103:105-109.
[32]史宸菲,薛瑞杰,李雨濛,等.不同活性炭活化过硫酸盐的效能及机理的规律研究[J].环境科学学报,2018,38(4):1501-1508.
[33]WANG Z H,SUN L Y,LOU X Y,et al.Chemical instability of graphene oxide following exposure to highly reactive radicals in advanced oxidation processes[J].J Colloid Interface Sci,2017,507:51-58.
[34]DUAN X G,SU C,ZHOU L,et al.Surface controlled generation of reactive radicals from persulfate by carbocatalysis on nanodiamonds[J].Appl Catal B.2016,194:7-15.
[35]LUO J,PENG F,WANG H J,et al.Enhancing the catalytic activity of carbon nanotubes by nitrogen doping in the selective liquid phase oxidation of benzyl alcohol[J].Catal Commun,2013,39:44-49.
[36]OUYANG D,YAN J C,QIAN L B,et al.Degradation of 1,4-dioxane by biochar supported nano magnetite particles activating persulfate[J].Chemosphere,2017,184:609-617.
[37]赵莹,任月明,张慧玉,等.GO/CoFe2O4催化过硫酸盐降解邻苯二甲酸二丁酯效能[J].哈尔滨工业大学学报,2017,49(8):31-36.
[38]JIANG X,GUO Y H,ZHANG L B,et al.Catalytic degradation of tetracycline hydrochloride by persulfate activated with nano Fe0 immobilized mesoporous carbon[J].Chem Eng J,2018,341:392-401.
[39]黄晓东.负载铁、锰活性炭催化过硫酸盐降解染料[J].化学工程与装备,2015(10):12-15.
[40]许志至.过硫酸盐高级氧化-BAF深度处理难降解有机废水的试验研究[D].镇江:江苏大学,2017.
[41]HAN J S,CHUNG D Y,HA D G,et al.Nitrogen and boron co-doped hollow carbon catalyst for the oxygen reduction reaction[J].Carbon,2016,105:1-7.
[42]DUAN X G,O’DONNELL K,SUN H Q,et al.Sulfur and nitrogen Co-doped graphene for metal-free catalytic oxidation reactions[J].Small,2015,11(25):3036-3044.
[43]FURIMSKY E.Carbon materials for catalysis[J].JAm Chem Soc,2009,131(28):9856-9857.
[44]LIU N,ZHANG L Y,XUE Y,et al.Nitrogen-doped carbon material as a catalyst for the degradation of Direct Red 23 based on persulfate oxidation[J].Sep Purif Technol,2017,184:213-219.
[45]于小龙.氮掺杂碳纳米孔材料催化过硫酸盐氧化直接红23染料废水[D].长春:吉林大学,2017.
[46]WANG X R,LI X L,ZHANG L,et al.N-doping of graphene through electrothermal reactions with ammonia[J].Science,2009,324(5928):768-771.
[47]Guo Y P,Zeng Z Q,Li Y L,et al.In-situ sulfur-doped carbon as a metal-free catalyst for persulfate activated oxidation of aqueous organics[J].Catal Today,2018,307:12-19.
[48]TIAN W J,ZHANG H Y,DUAN X G,et al.Nitrogen-and sulfur-codoped hierarchically porous carbon for adsorptive and oxidative removal of pharmaceutical contaminants[J].ACS Appl Mater Interface,2016,8(11):7184-7193.
[49]CHENG X,GUO H G,ZHANG Y L,et al.Oxidation of 2,4-dichlorophenol by non-radical mechanism using persulfate activated by Fe/S modified carbon nanotubes[J].J Colloid Interface Sci,2016,469:277-286.
v50]MATZEK L W,CARTER K E.Activated persulfate for organic chemical degradation:a review[J].Chemosphere,2016,151:178-188.
[51]TEEL A L,AHMAD M,WATTS R J.Persulfate activation by naturally occurring trace minerals[J].JHazard Mater,2011,196:153-159.
[52]高焕方,龙飞,曹园城,等.新型过硫酸盐活化技术降解有机污染物的研究进展[J].环境工程学报,2015,9(12):5659-5664.
[53]王思齐.过硫酸盐高级氧化法处理含酚废水的实验研究[D].包头:内蒙古科技大学,2017.
[54]KERMANI M,MOHAMMADI F,KAKAVANDIB,et al.Simultaneous catalytic degradation of 2,4-Dand MCPA herbicides using sulfate radical-based heterogeneous oxidation over persulfate activated by natural hematite(α-Fe2O3/PS)[J].J Phys Chem Solids,2018,117:49-59.
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[2]刘占孟,徐礼春,赵杰峰,等.新型高级氧化技术处理垃圾渗滤液的研究进展[J].水处理技术,2018,44(1):7-12,25.
[3]高耀文,张晖.高级氧化技术再生吸附剂的研究进展[J].化工环保,2016,36(4):357-363.
[4]范聪剑,刘石军,刘哲,等.过硫酸盐技术去除水中有机污染物的研究进展[J].环境科学与技术,2015,38(S1):136-141.
[5]MIKLOS D B,REMY C,JEKEL M,et al.Evaluation of advanced oxidation processes for water and wastewater treatment:a critical review[J].Water Res,2018,139:118-131.
[6]MATZEK L W,CARTER K E.Sustained persulfate activation using solid iron:kinetics and application to ciprofloxacin degradation[J].Chem Eng J,2017,307:650-660.
[7]CHOI J B,CUI M C,LEE Y H,et al.Hydrodynamic cavitation and activated persulfate oxidation for degradation of bisphenol A:kinetics and mechanism[J].Chem Eng J,2018,338:323-332.
[8]LI Y,LIU L D,LIU L,et al.Efficient oxidation of phenol by persulfate using manganite as a catalyst[J].JMol Catal A,2016,411:264-271.
[9]CHENG X,GUO H G,ZHANG Y L,et al.Non-photochemical production of singlet oxygen via activation of persulfate by carbon nanotubes[J].Water Res,2017,113:80-88.
[10]YAN J C,GAO W G,DONG M G,et al.Degradation of trichloroethylene by activated persulfate using a reduced graphene oxide supported magnetite nanoparticle[J].Chem Eng J,2016,295:309-316.
[11]YAN J C,CHEN Y,QIAN L B,et al.Heterogeneously catalyzed persulfate with a CuMgFe layered double hydroxide for the degradation of ethylbenzene[J].J Hazard Mater,2017,338:372-380.
[12]XIAO R Y,LUO Z H,WEI Z S,et al.Activation of peroxymonosulfate/persulfate by nanomaterials for sulfate radical-based advanced oxidation technologies[J].Curr Opin Chem Eng,2018,19:51-58.
[13]DU X D,ZHANG Y Q,HUSSAIN I,et al.Insight into reactive oxygen species in persulfate activation with copper oxide:activated persulfate and trace radicals[J].Chem Eng J,2017,313:1023-1032.
[14]ZHANG T,CHEN Y,WANG Y R,et al.Efficient peroxydisulfate activation process not relying on sulfate radical generation for water pollutant degradation[J].Environ Sci Technol,2014,48(10):5868-5875.
[15]GUO Y P,ZENG Z Q,ZHU Y C,et al.Catalytic oxidation of aqueous organic contaminants by persulfate activated with sulfur-doped hierarchically porous carbon derived from thiophene[J].Appl Catal B,2018,220:635-644.
[16]WU Y,GUO J,HAN Y J,et al.Insights into the mechanism of persulfate activated by rice straw biochar for the degradation of aniline[J].Chemosphere,2018,200:373-379.
[17]DUAN X G,SUN H Q,TADE M,et al.Metal-free activation of persulfate by cubic mesoporous carbons for catalytic oxidation via radical and nonradical processes[J].Catal Today,2018,307:140-146.
[18]张炳烛,张钊,王昆亭,等.过硫酸盐非均相催化剂进展[J].应用化工,2018,47(1):176-180.
[19]TAN C Q,GAO N Y,DENG Y,et al.Radical induced degradation of acetaminophen with Fe3O4 magnetic nanoparticles as heterogeneous activator of peroxymonosulfate[J].J Hazard Mater,2014,276:452-460.
[20]ANIPSITAKIS G P,DIONYSIOU D D,GONZA-LEZ M A.Cobalt-mediated activation of peroxymonosulfate and sulfate radical attack on phenolic compounds:implications of chloride ions[J].Environ Sci Technol,2006,40(3):1000-1007.
[21]CHEN X Y,CHEN J W,QIAO X L,et al.Performance of nano-Co3O4/peroxymonosulfate system:kinetics and mechanism study using Acid Orange 7as a model compound[J].Appl Catal B,2008,80(1/2):116-121.
[22]YAO Y J,XU C,QIN J C,et al.Synthesis of magnetic cobalt nanoparticles anchored on graphene nanosheets and catalytic decomposition of OrangeⅡ[J].Ind Eng Chem Res,2013,52(49):17341-17350.
[23]REN Y M,LIN L Q,Ma J,et al.Sulfate radicals induced from peroxymonosulfate by magnetic ferrospinel MFe2O4(M=Co,Cu,Mn,and Zn)as heterogeneous catalysts in the water[J].Appl Catal B,2015,165:572-578.
[24]SAPUTRA E,MUHAMMAD S,SUN H Q,et al.Shape-controlled activation of peroxymonosulfate by single crystalα-Mn2O3 for catalytic phenol degradation in aqueous solution[J].Appl Catal B,2014,154/155:246-251.
[25]杜红梅.不同晶态MnO2协同过硫酸盐降解有机污染物的机理研究[D].南昌:南昌航空大学,2017.
[26]SAPUTRA E,MUHAMMAD S,SUN H Q,et al.Different crystallographic one-dimensional MnO2 nanomaterials and their superior performance in catalytic phenol degradation[J].Environ Sci Technol,2013,47(11):5882-5887.
[27]WANG Y X,INDRAWIRAWAN S,DUAN X G,et al.New insights into heterogeneous generation and evolution processes of sulfate radicals for phenol degradation over one-dimensionalα-MnO2 nanostructures[J].Chem Eng J,2015,266:12-20.
[28]唐海,李洋,汤同欢,等.CuO/UV/过硫酸盐体系深度降解印染废水[J].中国给水排水,2016,32(19):89-94.
[29]杜江坤.新型硫、锰改性铁基材料的制备及其去除水体污染物的研究[D].武汉:中国地质大学,2016.
[30]ZHANG Y C,ZHANG Q,HONG J M.Sulfate radical degradation of acetaminophen by novel iron-copper bimetallic oxidation catalyzed by persulfate:mechanism and degradation pathways[J].Appl Surf Sci,2017,422:443-451.
[31]WANG J J,WANG C,TONG S P.A novel composite Fe-N/O catalyst for the effective enhancement of oxidative capacity of persulfate at ambient temperature[J].Catal Commun,2018,103:105-109.
[32]史宸菲,薛瑞杰,李雨濛,等.不同活性炭活化过硫酸盐的效能及机理的规律研究[J].环境科学学报,2018,38(4):1501-1508.
[33]WANG Z H,SUN L Y,LOU X Y,et al.Chemical instability of graphene oxide following exposure to highly reactive radicals in advanced oxidation processes[J].J Colloid Interface Sci,2017,507:51-58.
[34]DUAN X G,SU C,ZHOU L,et al.Surface controlled generation of reactive radicals from persulfate by carbocatalysis on nanodiamonds[J].Appl Catal B.2016,194:7-15.
[35]LUO J,PENG F,WANG H J,et al.Enhancing the catalytic activity of carbon nanotubes by nitrogen doping in the selective liquid phase oxidation of benzyl alcohol[J].Catal Commun,2013,39:44-49.
[36]OUYANG D,YAN J C,QIAN L B,et al.Degradation of 1,4-dioxane by biochar supported nano magnetite particles activating persulfate[J].Chemosphere,2017,184:609-617.
[37]赵莹,任月明,张慧玉,等.GO/CoFe2O4催化过硫酸盐降解邻苯二甲酸二丁酯效能[J].哈尔滨工业大学学报,2017,49(8):31-36.
[38]JIANG X,GUO Y H,ZHANG L B,et al.Catalytic degradation of tetracycline hydrochloride by persulfate activated with nano Fe0 immobilized mesoporous carbon[J].Chem Eng J,2018,341:392-401.
[39]黄晓东.负载铁、锰活性炭催化过硫酸盐降解染料[J].化学工程与装备,2015(10):12-15.
[40]许志至.过硫酸盐高级氧化-BAF深度处理难降解有机废水的试验研究[D].镇江:江苏大学,2017.
[41]HAN J S,CHUNG D Y,HA D G,et al.Nitrogen and boron co-doped hollow carbon catalyst for the oxygen reduction reaction[J].Carbon,2016,105:1-7.
[42]DUAN X G,O’DONNELL K,SUN H Q,et al.Sulfur and nitrogen Co-doped graphene for metal-free catalytic oxidation reactions[J].Small,2015,11(25):3036-3044.
[43]FURIMSKY E.Carbon materials for catalysis[J].JAm Chem Soc,2009,131(28):9856-9857.
[44]LIU N,ZHANG L Y,XUE Y,et al.Nitrogen-doped carbon material as a catalyst for the degradation of Direct Red 23 based on persulfate oxidation[J].Sep Purif Technol,2017,184:213-219.
[45]于小龙.氮掺杂碳纳米孔材料催化过硫酸盐氧化直接红23染料废水[D].长春:吉林大学,2017.
[46]WANG X R,LI X L,ZHANG L,et al.N-doping of graphene through electrothermal reactions with ammonia[J].Science,2009,324(5928):768-771.
[47]Guo Y P,Zeng Z Q,Li Y L,et al.In-situ sulfur-doped carbon as a metal-free catalyst for persulfate activated oxidation of aqueous organics[J].Catal Today,2018,307:12-19.
[48]TIAN W J,ZHANG H Y,DUAN X G,et al.Nitrogen-and sulfur-codoped hierarchically porous carbon for adsorptive and oxidative removal of pharmaceutical contaminants[J].ACS Appl Mater Interface,2016,8(11):7184-7193.
[49]CHENG X,GUO H G,ZHANG Y L,et al.Oxidation of 2,4-dichlorophenol by non-radical mechanism using persulfate activated by Fe/S modified carbon nanotubes[J].J Colloid Interface Sci,2016,469:277-286.
v50]MATZEK L W,CARTER K E.Activated persulfate for organic chemical degradation:a review[J].Chemosphere,2016,151:178-188.
[51]TEEL A L,AHMAD M,WATTS R J.Persulfate activation by naturally occurring trace minerals[J].JHazard Mater,2011,196:153-159.
[52]高焕方,龙飞,曹园城,等.新型过硫酸盐活化技术降解有机污染物的研究进展[J].环境工程学报,2015,9(12):5659-5664.
[53]王思齐.过硫酸盐高级氧化法处理含酚废水的实验研究[D].包头:内蒙古科技大学,2017.
[54]KERMANI M,MOHAMMADI F,KAKAVANDIB,et al.Simultaneous catalytic degradation of 2,4-Dand MCPA herbicides using sulfate radical-based heterogeneous oxidation over persulfate activated by natural hematite(α-Fe2O3/PS)[J].J Phys Chem Solids,2018,117:49-59.
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