山东菏泽定陶地区土壤元素地球化学特征
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摘要
对山东菏泽定陶地区进行土壤地球化学研究,利用AFS820原子荧光光度计和2100 DV电感耦合等离子体发射光谱仪,测定土壤元素的种类和含量。对区内土壤元素的含量特征进行分析,元素迁移转化规律研究及对元素的地球化学等级划分。结果表明:①研究区表层土壤中养份元素K和Ca均与植物的长势成正相关;②深层土壤元素(S、K、Fe、Ca、N、Mn、Cu、Mo等)与植物的长势相关性较小;③植物(山药)对土壤中V、Mn、Zn、Sr、Se、I、Ni元素需求较多;④Ca、N、Mn、Cu、Ni、Co、P、B、Sb、F元素的K值(深层土壤/表层土壤)较高。
The soil geochemistry was studied in Dingtao area of Heze,Shandong,and the species and content of soil elements were determined by AFS820 atomic fluorescence photometer and 2100DV inductively coupled plasma emission spectrometer. The content characteristics of soil elements in the area were analyzed,element migration and transformation were studied,and the geochemical classification of elements was conducted. The results showed that: ① the nutrient elements K and Ca in surface soil were positively correlated with plant growth in the studied area; ② deep soil elements (such as S,K,Fe,Ca,N,Mn,Cu,Mo,etc) have little correlation with plant growth; ③ plants (such as yam) need more V,Mn,Zn,Sr,Se,I and Ni in soil; ④K values (deep soil/surface soil) of Ca,N,Mn,Cu,Ni,Co,P,B,Sb and F were higher.
The soil geochemistry was studied in Dingtao area of Heze,Shandong,and the species and content of soil elements were determined by AFS820 atomic fluorescence photometer and 2100DV inductively coupled plasma emission spectrometer. The content characteristics of soil elements in the area were analyzed,element migration and transformation were studied,and the geochemical classification of elements was conducted. The results showed that: ① the nutrient elements K and Ca in surface soil were positively correlated with plant growth in the studied area; ② deep soil elements (such as S,K,Fe,Ca,N,Mn,Cu,Mo,etc) have little correlation with plant growth; ③ plants (such as yam) need more V,Mn,Zn,Sr,Se,I and Ni in soil; ④K values (deep soil/surface soil) of Ca,N,Mn,Cu,Ni,Co,P,B,Sb and F were higher.
引文
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[29]李晓晖，袁峰，白晓宇，等．典型矿区非正态分布土壤元素数据的正态变换方法对比研究[J]．地理与地理信息科学，2010,26(6):102-105.LI Xiao-hui,YUAN Feng,BAI Xiao-yu,et al.Comparison of normalization methods for non-normal distribution soil elements data in typical minning area[J].Geography and Geo-Information Science,2010,26(6):102-105．
[30]王文森．变异系数:一个衡量离散程度简单而有用的统计指标[J]．中国统计，2007(6):41-42.WANG Wen-sen.Coefficient of variation:a simple but useful statistical measure of dispersion[J].China Statistics,2007(6):41-42．
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[2]孙向阳．土壤学[M]．北京:中国林业出版社，2005:3-5.SUN Xiang-yang.Pedology[M].Beijing:China Forestry Press,2005:3-5．
[3]崔晓阳．土壤资源学[M]．北京:中国林业出版社，2007:15-23.CUI Xiao-yang.Soil resources science[M].Beijing:China Forestry Press,2007:15-23．
[4]熊毅．试论土壤生态系统[J]．土壤，1983,15(4):3-7.XIONG Yi.On soil ecosystem[J].Soil,1983,15(4):3-7．
[5]ZHAO Jun,NI Tian,LI Yong,et al.Responses of bacterial communities in arable soils in a rice-wheat cropping system to different fertilizer regimes and sampling times[J].Plos One,2014,9(1):1-10．
[6]Alexande M.Agriculture responsibility in establishing soil quality criteria[C]//Environmental improvement-agricultural challenge in the seventies.Washington DC:National Academy of Sciences,1971:66-71．
[7]Warkentin B P,Fletcher H F.Soi1 quality for intensive agriculture[C]//Proceedings of international seminar on Soil Environment and Fertility Management in Intensive Agriculture.Society of Science Soil and Manure,1977:594-598．
[8]Kelepertisis A,Alexakis D,Kita I.Environmental geochemistry of soils and waters of susaki area,korinthos,Greece[J].Environmental Geochemistry&Health,2001,23(2):117-135．
[9]Vinogradov A Q.土壤中稀有和扩散化学元素的地球化学[M]．周启琇，译．北京:中国科学院，1954:1-10.Vinogradov A Q.Geochemistry of rare and diffuse chemical elements in soil[M].ZHOU Qi-xiu,translated.Beijing:Chinese Academy of Sciences,1954:1-10．
[10]李家熙，吴功建，黄怀曾．生物地球化学环境研究的进展在生命科学上的应用[J]．中国地质，1996(10):24-26.LI Jia-xi,WU Gong-jian,HUANG Huai-zeng.Advances in biogeochemical environmental research and applications in life sciences[J].Geology of China,1996(10):24-26．
[11]何小平，江法源，邓泽周，等．密度和施肥方式对定向槽浅生栽培紫山药产量的影响[J]．中国农学通报，2016,32(1):39-42.HE Xiao-ping,JIANG Fa-yuan,DENG Ze-zhou,et al.Effects of different planting densities and fertilizer methods on yield of purple yam with the directionalnotch technology[J].Chinese Agricultural Science Bulletin,2016,32(1):39-42．
[12]张增奇，张成基，王世进，等．山东省地层侵入岩构造单元划分对比意见[J]．山东国土资源，2014,30(3):1-23.ZHANG Zeng-qi,ZHANG Cheng-ji,WANG Shi-jin,et al.View on classification and contrast of tectonic units in strata in Shandong Province[J].Shandong Land and Resources,2014,30(3):1-23．
[13]徐皓，刘水英．湿法消解-原子吸收光谱法测定紫山药中矿质元素[J]．食品科学，2015,36(16):192-196.XU Hao,LIU Shui-ying.Determination of mineral elements in Dioscorea alata L.tubers by atomic absorption spectrometry with wet digestion[J].Food Science,2015,36(16):192-196．
[14]黄通明．应用AFS-820双道原子荧光光度计测定饮用水中的铅[J]．海峡预防医学杂志，2004,10(6):37-38.HUANG Tong-ming.Lead in drinking water was determined by AFS-2820 double-channel atomic fluorescence photometer[J].Strait Journal of Preventive Medicine,2004,10(6):37-38．
[15]张薇，张卓勇，施燕支，等．火焰原子吸收光谱法测定山药中多种微量元素[J]．光谱学与光谱分析，2006,26(5):963-965.ZHANG Wei,ZHANG Zhuo-yong,SHI Yan-zhi,et al.Determination of nine trace elements in dioscorea opposita thumb by flame atomic absorption spectrophotom[J].Spectroscopy and Spectral Analysis,2006,26(5):963-965．
[16]王秀梅，马晓程．利用原子荧光法测定土壤中汞、砷元素样品前处理方法的研究[J]．石油化工应用．2005,24(3):34-35.WANG Xiu-mei,MA Xiao-cheng.Determination of mercury and arsenic in soil by atomic fluorescence spectrometry[J].Petrochemical Application,2005,24(3):34-35．
[17]李冰，杨红霞．电感耦合等离子体质谱技术最新进展[J]．分析试验室，2003,22(1):94-100.LI Bing,YANG Hong-xia.The latest development of inductively coupled plasma mass spectrometry[J].Analytical Laboratory,2003,22(1):94-100．
[18]刘兆云．土壤中黑炭的积累、分布特征及其稳定性的模拟研究:博士学位论文[D]．杭州:浙江大学，2013.LIU Zhao-yun.Accumulation and distribution of black carbon in soils and its simulated degradation:doctor's degree thesis[D].Hangzhou:Zhejiang University,2013．
[19]廖启林，华明，张为，等．人为活动对江苏土壤元素含量分布的影响[J]．地质学刊，2012,36(2):147-156.LIAO Qi-lin,HUA Ming,ZHANG Wei,et al.Influence of human activities on soil element distribution in Jiangsu[J].Geological Journals,2012,36(2):147-156．
[20]梁硕，李月芬，汤洁，等．吉林西部土壤铁形态分布及其与土壤性质的关系研究[J]．世界地质，2016,35(2):593-600.LIANG Shuo,LI Yue-fen,YANG Jie,et al.Study on form distribution of soil iron in western Jilin and its correlation with soil properties[J].Global Geology,2016,35(2):593-600．
[21]施宪，王冬艳，李月芬，等．吉林西部锰、钼元素土壤地球化学特征[J]．世界地质，2010,29(2):256-261.SHI Xian,WANG Dong-yan,LI Yue-fen,et al.Soil geochemical characteristics of elements Mn,Mo in western Jilin Province[J].Global Geology,2010,29(2):256-261．
[22]孟智磊．山东省典型地区土壤及农产品中硒等元素的地球化学特征:硕士学位论文[D]．北京:中国地质大学(北京)，2016.MENG Zhi-lei.Geochemical characteristics of selenium and other elements in soil and agricultural products in typical areas of Shandong Province:master's degree thesis[D].Beijing:China University of Geosciences(Beijing),2016．
[23]王常青，杨继峰，杨言辰，等．内蒙古沙锡拉特地区土壤地球化学特征及找矿方向[J]．世界地质，2018,37(3):826-837.WANG Chang-qing,YANG Ji-feng,YANG Yan-chen,et al.Soil geochemical characteristics and prospecting direction in Shaxilat,Inner Mongolia[J].Global Geology,2018,37(3):826-837．
[24]李荣兴，王冬艳，李文博．吉林中西部土壤Cu、Zn元素有效态转化效率及自然影响因素分析[J]．世界地质，2017,36(1):316-326.LI Rong-xing,WANG Dong-yan,LI Wen-bo.Available state transformation efficiency of soil copper and zinc in central-western Jilin and its natural impact factors[J].Global Geology,2017,36(1):316-326．
[25]马志抒，刘希瑶．土壤表层与深层元素含量比值系数研究[J]．地质与资源，2013,22(2):155-158.MA Zhi-shu,LIU Xi-yao.Research on the ratio of element contents in upper and deep soil layers[J].Geology and Resources,2013,22(2):155-158．
[26]庞绪贵，陶建玉，李建华，等．山东省小清河中下游地区土壤地球化学特征[J]．山东国土资源，2002,18(5):44-47.PANG Xu-gui,TAO Jian-yu,LI Jian-hua,et al.Geochemical characteristics of soils in middle and lower reach of Xiaoqinghe River in Shandong Province[J].Land and Resources in Shandong,2002,18(5):44-47．
[27]盛奇，李玲，付巧玲，等．灵宝苹果优质产区土壤元素含量特征研究[J]．安徽农业科学，2013,41(15):6684-6687.SHENG Qi,LI Ling,FU Qiao-ling,et al.Study on quality characteristics of soil element content in Lingbao apple production areas[J].Journal of Agricultural Sciences,2013,41(15):6684-6687．
[28]任林子．元素正态分布偏度，峰度检验法PC-1500应用程序[J]．黄金地质科技，1990(2):62-63.REN Lin-zi.Element normal distribution skewness,kurtosis test PC-1500 application[J].Gold Geological Technology,1990(2):62-63．
[29]李晓晖，袁峰，白晓宇，等．典型矿区非正态分布土壤元素数据的正态变换方法对比研究[J]．地理与地理信息科学，2010,26(6):102-105.LI Xiao-hui,YUAN Feng,BAI Xiao-yu,et al.Comparison of normalization methods for non-normal distribution soil elements data in typical minning area[J].Geography and Geo-Information Science,2010,26(6):102-105．
[30]王文森．变异系数:一个衡量离散程度简单而有用的统计指标[J]．中国统计，2007(6):41-42.WANG Wen-sen.Coefficient of variation:a simple but useful statistical measure of dispersion[J].China Statistics,2007(6):41-42．
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