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大茶园铀矿床成矿物质来源:C-O和Sr-Nd同位素证据
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  • 英文篇名:Ore-forming material sources of the Dachayuan uranium deposit,Zhejiang Province: Evidence from C-O and Sr-Nd isotopes
  • 作者:田建吉 ; 张国全 ; 商朋强 ; 齐有强
  • 英文作者:TIAN JianJi;ZHANG GuoQuan;SHANG PengQiang;QI YouQiang;Key Laboratory of Uranium Resource Exploration and Evaluation Technology,Beijing Research Institute of Uranium Geology CNNC;State Key Laboratory of Ore Deposit Geochemistry,Institute of Geochemistry,Chinese Academy of Sciences;Zhejiang Geology Exploration Bureau for Non-ferrous Metals;General Institute of Chemical Geology Survey,Bureau of Mining and Geology of China Chemical Industry;
  • 关键词:C-O和Sr-Nd同位素 ; 成矿物质来源 ; 大茶园(661)铀矿床 ; 赣杭铀成矿带
  • 英文关键词:C-O and Sr-Nd isotopes;;Ore-forming material sources;;Dachayuan(No.661) uranium deposit;;Gan-Hang uranium metallogenic belt
  • 中文刊名:岩石学报
  • 英文刊名:Acta Petrologica Sinica
  • 机构:核工业北京地质研究院中核集团铀资源勘查与评价技术重点实验室;中国科学院地球化学研究所矿床地球化学国家重点实验室;浙江省有色金属地质勘查局;中化地质矿山总局化工地质调查总院;
  • 出版日期:2019-09-15
  • 出版单位:岩石学报
  • 年:2019
  • 期:09
  • 基金:国家重点基础研究发展规划项目(2007CB411408);; 国家自然科学基金项目(40634020);; 中核集团集中研发项目(LTD1603)联合资助
  • 语种:中文;
  • 页:195-207
  • 页数:13
  • CN:11-1922/P
  • ISSN:1000-0569
  • 分类号:P619.14;P597
摘要
赣杭铀成矿带是我国最大的火山岩型铀成矿带,大茶园(661)铀矿床是该成矿带东段最重要的火山岩型铀矿床,矿体赋存于晚中生代磨石山群九里坪组流纹岩中。为探讨该铀矿床成矿物质来源,对采自大茶园铀矿床中的脉石矿物开展了系统的C-O和Sr-Nd同位素研究。结果表明,成矿流体中矿化剂∑CO_2主要来源于地幔,部分来自于基底大理岩或沉积碳酸盐岩碳;成矿期后方解石碳同位素组成靠近基底大理岩或沉积碳酸盐岩组成,可能主要为壳源碳酸盐岩的贡献;成矿期流体中∑CO_2以HCO_3~-为主,CO_2去气作用为方解石沉淀形成的主要机制。成矿期不同阶段方解石与萤石的Sr、Nd同位素组成没有明显差别且变化较小,显示矿床中脉石矿物的同源性。通过与基底陈蔡群变质岩和盖层火山岩的Sr、Nd同位素组成对比发现,成矿期萤石与盖层火山岩具有类似的Sr同位素组成,表明大茶园铀矿床成矿物质以壳源为主,主要来自于赋矿火山岩,而Nd同位素进一步表明成矿物质可能来源于赋矿的流纹岩。岩石圈伸展控制着富CO_2热液的形成,富CO_2热液在上升过程中萃取壳源(尤其是富铀火山岩)中成矿物质,并在有利的成矿部位通过CO_2去气作用导致铀沉淀成矿。
        Gan-Hang uranium metallogenic belt is the largest volcanic-type uranium metallogenic belt in China. The Dachayuan( No. 661) uranium deposit,one of the most important uranium deposits in the Dazhou uranium orefield,is located in the eastern part of Gan-Hang uranium metallogenic belt,with the orebodies existent in the Late Mesozoic rhyolite of Jiuliping Formation,Moshishan Group. In order to define the source of metallogenic matter at the Dachayuan uranium deposit,C,O,Sr and Nd isotopic compositions of hydrothermal minerals( including fluorite,calcite) associated with uranium mineralization were systematically analyzed in this paper. The results show that the mineralizer ∑CO2 in the ore-forming fluid was mainly derived from the mantle,and partly from the marble of Chencai Group or the sedimentary carbonate; the post-mineralization calcites have the similar carbon isotopic compositions with the marble of Chencai Group or the sedimentary carbonate,indicating the main contribution of crust-derived carbonate rock. A quantitative mode simulated for the formation of calcites shows that the mineralizer ∑CO_2 in metallogenic fluid mainly occurs in the form of HCO_3~-,and the degasification of CO_2 is the main precipitation mechanism of calcite. The Sr and Nd isotopic compositions of gangue minerals in different stages are similar and fall in a narrow range,indicating a uniform and homogenous origin of Sr and Nd isotopes. In comparison with that of metamorphite from Chencai Group and volcanic rocks from Moshishan Group,the compositions of Sr and Nd isotopes indicate that the metallogenic matter of the Dachayuan uranium deposit may be mainly derived from crust,and the Nd isotopic composition further shows that the ore material might come from the rhyolite of the Jiuliping Formation. The CO_2-rich fluid that formed by the lithospheric extension,can leach the ore-forming matters from crust-derived rocks( especially the uranium-rich volcanics) during the rising process,and finally uranium precipitated in the favorable position through the degasification of CO_2.
引文
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