渤海海域深层潜山油气地球化学特征及油气来源
|
摘要
渤海湾盆地渤海海域渤中19-6深层潜山构造带周缘发育多个富烃深次洼,油气聚集条件复杂,对其油气的有机地球化学特征及主要来源认识尚不明确。为此,利用饱和烃及轻烃色谱、色谱—质谱、天然气组分及碳同位素组分检测等地球化学测试技术对该潜山构造带的原油、天然气与其周缘富烃深次洼烃源岩的地球化学特征进行对比分析,运用油—源生物标志化合物分析技术,系统研究了渤中19-6潜山构造带油气的来源与特征。结果表明:(1)渤中19-6深层潜山构造带周缘凹陷主要发育古近系东营组二段下亚段、东营组三段、沙河街组一段及沙河街组三段上亚段等4套烃源岩,其中东三段和沙三上亚段烃源岩为其主力烃源灶,有机质丰度较高,为偏腐泥混合型有机质类型,已进入生烃高峰期;(2)深层太古界潜山及上覆古近系孔店组天然气为典型的油型气,具有不同成熟度天然气混合特征,成藏过程具有多阶段性;(3)浅层与深层油气来源都具有3套烃源岩混源输入的特征,但仍存在着差异性,其中浅层油气来源以东三段烃源岩的输入为主,并且可能存在着东二下亚段烃源岩的输入,而深层油气来源则以沙三上亚段烃源岩的输入为主。结论认为,该区油气源条件复杂,油气源主要以周缘富烃深次洼内沙三上亚段烃源岩为主,其深层凝析气藏表现出多期次油型气输入的特征。
Many hydrocarbon-rich deep subsags are developed in the periphery of the BZ19-6 deep buried-hill structural belt in the Bohai Sea area,Bohai Bay Basin,and their hydrocarbon accumulation conditions are complicated.So far,the organic geochemical characteristics and main sources of their oil and gas have not been figured out.In this paper,the geochemical characteristics of crude oil and natural gas in this belt and those of the source rocks of hydrocarbon-rich deep subsags around the buried-hill structure belt were analyzed by means of geochemical testing technologies,such as saturated hydrocarbon and light hydrocarbon chromatography,chromatography–mass spectrometry,detection of natural gas components and carbon isotope components.Then,the sources and characteristics of oil and gas in the BZ19-6 deep buried-hill structural belt were studied systematically by using the oil-source biomarker analysis technology.And the following research results were obtained.First,in the peripheral sags of this belt are mainly developed four sets of source rocks,i.e.,the lower submember of the second Member of Paleogene Dongying Fm(E_2d_2~1),the third Member of Dongying Fm(E_2d_3),the first Member of Shahejie Fm(E_2s_1)and the upper submember of the third Member of Shahejie Fm(E_2s_3~2).Among them,E_2d_3 and E_2s_3~2 are the principal hydrocarbon source kitchens.Their organic abundance is relatively high and their organic matter is of sapropel-prone mixed type.And now they are in the peak stage of hydrocarbon generation.Second,natural gas in the Archean deep buried hill and its overlying Paleogene Kongdian Fm(E_1k)is typical oiltype gas.It presents the mixed characteristics of natural gas with different maturities and multiple stages of hydrocarbon accumulation process.Third,the source of oil and gas in shallow layers is different from that in deep layers,though they both present the mixed source input characteristics of three sets of source rocks.The oil and gas in shallow layers is mainly derived from E_2d_3 source rocks and possibly from E_2d_2~1 source rocks,while the oil and gas in deep layers is mainly derived from E_2s_3~2 source rocks.In conclusion,the hydrocarbon source conditions in this area are complex,the hydrocarbon source is mainly contributed by the E_2s_3~2 source rocks in the hydrocarbon-rich deep subsags in the periphery of this belt,and the deep condensate gas reservoirs are characterized by multi-stage oil-type gas input.
Many hydrocarbon-rich deep subsags are developed in the periphery of the BZ19-6 deep buried-hill structural belt in the Bohai Sea area,Bohai Bay Basin,and their hydrocarbon accumulation conditions are complicated.So far,the organic geochemical characteristics and main sources of their oil and gas have not been figured out.In this paper,the geochemical characteristics of crude oil and natural gas in this belt and those of the source rocks of hydrocarbon-rich deep subsags around the buried-hill structure belt were analyzed by means of geochemical testing technologies,such as saturated hydrocarbon and light hydrocarbon chromatography,chromatography–mass spectrometry,detection of natural gas components and carbon isotope components.Then,the sources and characteristics of oil and gas in the BZ19-6 deep buried-hill structural belt were studied systematically by using the oil-source biomarker analysis technology.And the following research results were obtained.First,in the peripheral sags of this belt are mainly developed four sets of source rocks,i.e.,the lower submember of the second Member of Paleogene Dongying Fm(E_2d_2~1),the third Member of Dongying Fm(E_2d_3),the first Member of Shahejie Fm(E_2s_1)and the upper submember of the third Member of Shahejie Fm(E_2s_3~2).Among them,E_2d_3 and E_2s_3~2 are the principal hydrocarbon source kitchens.Their organic abundance is relatively high and their organic matter is of sapropel-prone mixed type.And now they are in the peak stage of hydrocarbon generation.Second,natural gas in the Archean deep buried hill and its overlying Paleogene Kongdian Fm(E_1k)is typical oiltype gas.It presents the mixed characteristics of natural gas with different maturities and multiple stages of hydrocarbon accumulation process.Third,the source of oil and gas in shallow layers is different from that in deep layers,though they both present the mixed source input characteristics of three sets of source rocks.The oil and gas in shallow layers is mainly derived from E_2d_3 source rocks and possibly from E_2d_2~1 source rocks,while the oil and gas in deep layers is mainly derived from E_2s_3~2 source rocks.In conclusion,the hydrocarbon source conditions in this area are complex,the hydrocarbon source is mainly contributed by the E_2s_3~2 source rocks in the hydrocarbon-rich deep subsags in the periphery of this belt,and the deep condensate gas reservoirs are characterized by multi-stage oil-type gas input.
引文
[1]陈昭年.石油与天然气地质学[M].北京:地质出版社,2013.Chen Zhaonian.Oil and gas geology[M].Beijing:Geological Publishing House,2013.
[2]高长海,查明,赵贤正,金凤鸣.渤海湾盆地冀中坳陷深层古潜山油气成藏模式及其主控因素[J].天然气工业,2017,37(4):52-59.Gao Changhai,Zha Ming,Zhao Xianzheng&Jin Fengming.Hydrocarbon accumulation models and their main controlling factors in the deep buried hills of the Jizhong Depression,Bohai Bay Basin[J].Natural Gas Industry,2017,37(4):52-59.
[3]Jin Qiang,Zhao Xianzheng,Jin Fengming,Ma Peng,Wang Quan&Wang Jing.Generation and accumulation of hydrocarbons in a deep"buried hill"structure in the Baxian Depression,Bohai Bay Basin,Eastern China[J].Journal of Petroleum Geology,2014,37(4):391-404.
[4]孟卫工,陈振岩,李湃,郭彦民,高先志,回雪峰,等.潜山油气藏勘探理论与实践--以辽河坳陷为例[J].石油勘探与开发,2009,36(2):136-143.Meng Weigong,Chen Zhenyan,Li Pai,Guo Yanmin,Gao Xianzhi,Hui Xuefeng,et al.Exploration theories and practices of buried-hill reservoirs:A case from Liaohe Depressions[J].Petroleum Exploration and Development,2009,36(2):136-143.
[5]蒋有录,叶涛,张善文,刘华.渤海湾盆地潜山油气富集特征与主控因素[J].中国石油大学学报(自然科学版),2015,39(3):20-29.Jiang Youlu,Ye Tao,Zhang Shanwen&Liu Hua.Enrichment characteristics and main controlling factors of hydrocarbon in buried hill of Bohai Bay Basin[J].Journal of China University of Petroleum(Edition of Natural Science),2015,39(3):20-29.
[6]薛永安,李慧勇.渤海海域深层太古界变质岩潜山大型凝析气田的发现及其地质意义[J].中国海上油气,2018,30(3):1-9.Xue Yong'an,Li Huiyong.Large condensate gas field in deep Archean metamorphic buried hill in Bohai Sea:Discovery and geological significance[J].China Offshore Oil and Gas,2018,30(3):1-9.
[7]李德生.渤海湾含油气盆地的地质和构造特征[J].石油学报,1980,1(1):6-20.Li Desheng.Geology and structural characteristics of Bohai Bay,China[J].Acta Petrolei Sinica,1980,1(1):6-20.
[8]周心怀,张如才,李慧勇,王保全,郭永华.渤海湾盆地渤中凹陷深埋古潜山天然气成藏主控因素探讨[J].中国石油大学学报(自然科学版),2017,41(1):42-50.Zhou Xinhuai,Zhang Rucai,Li Huiyong,Wang Baoquan&Guo Yonghua.Major controls on natural gas accumulations in deep-buried hills in Bozhong Depression,Bohai Bay Basin[J].Journal of China University of Petroleum(Edition of Natural Science),2017,41(1):42-45.
[9]Tian Jinqiang,Hao Fang,Zhou Xinhuai&Zou Huayao.Distribution,controlling factors,and oil-source correlation of biodegraded oils in the Bohai offshore area,Bohai Bay Basin,China[J].AAPG Bulletin,2017,101(3):361-385.
[10]胡见义,黄第藩.中国陆相石油地质理论基础[M].北京:石油工业出版社,1991.Hu Jianyi&Huang Difan.The bases of nonmarine petroleum geology in China[M].Beijing:Petroleum Industry Press,1991.
[11]崔景伟,王铁冠,李美俊,耿峰,唐友军,胡健.塔西南地区原油轻烃特征及成因类型[J].天然气地球科学,2015,26(7):1354-1364.Cui Jingwei,Wang Tieguan,Li Meijun,Geng Feng,Tang Youjun&Hu Jian.Light hydrocarbon characteristics and oil family classification of crude oils,Southwest Tarim Basin,Northwest China[J].Natural Gas Geoscience,2015,26(7):1354-1364.
[12]Cui Jingwei,Wang Tieguan,Li Meijun,Ou Guangxi,Geng Feng&Hu Jian.Oil filling history of the Bashituo Oilfield in the Markit Slope,SW Tarim Basin,China[J].Petroleum Science,2013,10(1):58-64.
[13]Cui Jingwei,Wang Tieguan,Wang Chunjiang&Li Meijun.Quantitative assessment and significance of gas washing of oil in Block 9 of the Tahe Oilfield,Tarim Basin,NW China[J].Chinese Journal of Geochemistry,2012,31(2):165-173.
[14]翟俪娜,倪云燕,吴朝东,高金亮.川中地区须家河组天然气地球化学特征[J].天然气地球科学,2017,28(4):539-549.Zhai Lina,Ni Yunyan,Wu Chaodong&Gao Jinliang.Geochemical characteristics of the natural gas from the Xujiahe Formation in the central Sichuan Basin,China[J].Natural Gas Geoscience,2017,28(4):539-549.
[15]Dai Jinxing,Xia Xinyu,Qin Shengfei&Zhao Jingzhou.Origins of partially reversed alkaneδ13C values for biogenic gases in China[J].Organic Geochemistry,2004,35(4):405-411.
[16]贺聪,吉利明,苏奥,吴远东,张明震.天然气组分碳同位素倒转成因分析及地质应用[J].特种油气藏,2016,23(4):14-19.He Cong,Ji Liming,Su Ao,Wu Yuandong&Zhang Mingzhen.Genesis analysis and geological application of gas component carbon isotope reversal[J].Special Oil&Gas Reservoirs,2016,23(4):14-19.
[17]Dai Jinxing,Song Yang,Dai Chunsen&Wang Darui.Geochemistry and accumulation of carbon dioxide gases in China[J].AAPG Bulletin,1996,80(10):1615-1626.
[18]戴金星,秦胜飞,陶士振,朱光有,米敬奎.中国天然气工业发展趋势和天然气地学理论重要进展[J].天然气地球科学,2005,16(2):127-142.Dai Jinxing,Qin Shengfei,Tao Shizhen,Zhu Guangyou&Mi Jingkui.Developing trends of natural gas industry and the significant progress on natural gas geological theories in China[J].Natural Gas Geoscience,2005,16(2):127-142.
[19]刘新社,蒋有录,侯云东,刘景东,文彩霞,朱荣伟,等.鄂尔多斯盆地靖西地区奥陶系中组合天然气成因与成藏主控因素[J].天然气工业,2016,36(4):16-26.Liu Xinshe,Jiang Youlu,Hou Yundong,Liu Jingdong,Wen Caixia,Zhu Rongwei,et al.Origins of natural gas and the main controlling factors of gas accumulation in the Middle Ordovician assemblages in the Jingxi area,Ordos Basin[J].Natural Gas Industry,2016,36(4):16-26.
[20]蒋飞,李忠诚,程日辉,刘宇,许中杰,王茂汀.王府断陷小城子气田火石岭组气藏天然气成藏模式及富集规律[J].天然气工业,2016,36(10):46-55.Jiang Fei,Li Zhongcheng,Cheng Rihui,Liu Yu,Xu Zhongjie&Wang Maoting.Natural gas accumulation models and enrichment patterns of the Huoshiling Fm reservoirs in the Xiaochengzi gas field,Wangfu fault depression,Songliao Basin[J].Natural Gas Industry,2016,36(10):46-55.
[21]郭潇潇,熊小峰,徐新德,甘军,梁刚.莺歌海盆地天然气类型划分与来源分析[J].特种油气藏,2017,24(5):54-58.Guo Xiaoxiao,Xiong Xiaofeng,Xu Xinde,Gan Jun&Liang Gang.Type classification and origin analysis of natural gas in the Yinggehai Basin[J].Special Oil&Gas Reservoirs,2017,24(5):54-58.
[22]Lorant F,Prinzhofer A,Behar F&Huc AY.Carbon isotopic and molecular constraints on the formation and the expulsion of thermogenic hydrocarbon gases[J].Chemical Geology,1998,147(3/4):249-264.
[23]Berner U&Faber E.Empirical carbon isotope/maturity relationships for gases from algal kerogens and terrigenous organic matter,based on dry,open-system pyrolysis[J].Organic Geochemistry,1996,24(10/11):947-955.
[24]Bernard BB,Brooks JM&Sackett WM.Light hydrocarbons in recent Texas continental shelf and slope sediments[J].Journal of Geophysical Research,1978,33(8):4053-4061.
[25]Stahl WJ&Garey BD.Source-rock identification by isotope analyses of natural gases from fields in the Val Verde and Delaware Basins,West Texas[J].Chemical Geology,1975,16(4):257-267.
[26]戴金星,戚厚发.我国煤成烃气的δ13C-Ro关系[J].科学通报,1989,34(9):690-692.Dai Jinxing&Qi Houfa,Relationship ofδ13C-Ro of coal-derived gas in China[J].Chinese Science Bulletin,1989,34(9):690-692.
[27]沈平,徐永昌,王先彬.气源岩和天然气地球化学特征及成气机理研究[M].兰州:甘肃科学技术出版社,1991.Shen Ping,Xu Yongchang&Wang Xianbin.Study on geochemical characteristics of gas source rock and natural gas and mechanism of genesis of gas[M].Lanzhou:Gansu Science and Technology Press,1991.
[28]Thompson KFM.Classification and thermal history of petroleum based on light hydrocarbons[J].Geochimica et Cosmochimica Acta,1983,47(2):303-316.
[29]Thompson KFM.Fractionated aromatic petroleum and the generation of gas-condensates[J].Organic Geochemistry,1987,11(6):573-590.
[30]王培荣,徐冠军,张大江,肖廷荣,任冬苓.烃源岩与原油中轻馏分烃的对比--以胜利油田东营、沾化凹陷为例[J].石油与天然气地质,2013,34(1):1-10.Wang Peirong,Xu Guanjun,Zhang Dajiang,Xiao Tingrong&Ren Dongling.Correlation of light hydrocarbons between source rock and crude:An example from Dongying and Zhanhua Depressions in Jiyang Subbasin,Bohai Bay Basin[J].Oil&Gas Geology,2013,34(1):1-10.
[31]王培荣,赵红,肖廷荣,朱翠山,徐冠军,张敏,等.采用气相色谱“反吹、微流控”技术分析原油C5-C13轻馏分及其地球化学意义初探[J].自然科学进展,2007,17(8):1144-1149.Wang Peirong,Zhao Hong,Xiao Tingrong,Zhu Cuishan,Xu Guanjun,Zhang Min,et al.Application of backflush and micro-flow techniques to the analysis of C5-C13 hydrocarbons in crude oils and its geochemical significance[J].Progress in Natural Science,2007,17(8):1144-1149.
[32]Peters KE,Walters CC&Moldowan JM.The biomarker guide:Interpreting molecular fossils in petroleum and ancient sediments(second edition)[M].New York:Prentice Hall,1992.
[33]Zhu Yangming,Weng Huanxin,Su Aiguo,Liang Digang&Peng Dehua.Geochemical characteristics of Tertiary saline lacustrine oils in the Western Qaidam Basin,Northwest China[J].Applied Geochemistry,2005,20(10):1875-1889.
[34]Chen Jianyu,Bi Yanpong,Zhang Jiguo&Li Shuafu.Oil-source correlation in the Fulin Basin,Shengli petroleum province,East China[J].Organic Geochemistry,1996,24(8/9):931-940.
[35]Hao Fang,Zhou Xinhuai,Zhu Yangming&Yang Yuanyuan.Mechanisms for oil depletion and enrichment on the Shijiutuo uplift,Bohai Bay Basin,China[J],AAPG Bulletin,2009,93(8):1015-1037.
[36]Huang Wenyen&Meinschein WG.Sterols as ecological indicators[J].Geochimica et Cosmochimica Acta,1979,43(5):739-745.
[37]昝灵,张枝焕,王顺华,邢辉,李文浩,刘炜楠,等.4-甲基甾烷在油源对比中的应用--以渤南洼陷北部陡坡带为例[J].沉积学报,2012,30(4):770-778.Zan Ling,Zhang Zhihuan,Wang Shunhua,Xing Hui,Li Wenhao,Liu Weinan,et al.Application of 4-methyl steranes in oil-source correlation:A case study from northern steep slope zone of Bonan Sag[J].Acta Sedimentologica Sinica,2012,30(4):770-778.
[38]王铁冠,钟宁宁,侯读杰,黄光辉,包建平,李贤庆,等.低熟油气形成机理与分布[M].北京:石油工业出版社,1995.Wang Tieguan,Zhong Ningning,Hou Dujie,Huang Guanghui,Bao Jianping,Li Xianqing,et al.Genetic mechanism and occurrence of immature hydrocarbon[M].Beijing:Petroleum Industry Press,1995.
[2]高长海,查明,赵贤正,金凤鸣.渤海湾盆地冀中坳陷深层古潜山油气成藏模式及其主控因素[J].天然气工业,2017,37(4):52-59.Gao Changhai,Zha Ming,Zhao Xianzheng&Jin Fengming.Hydrocarbon accumulation models and their main controlling factors in the deep buried hills of the Jizhong Depression,Bohai Bay Basin[J].Natural Gas Industry,2017,37(4):52-59.
[3]Jin Qiang,Zhao Xianzheng,Jin Fengming,Ma Peng,Wang Quan&Wang Jing.Generation and accumulation of hydrocarbons in a deep"buried hill"structure in the Baxian Depression,Bohai Bay Basin,Eastern China[J].Journal of Petroleum Geology,2014,37(4):391-404.
[4]孟卫工,陈振岩,李湃,郭彦民,高先志,回雪峰,等.潜山油气藏勘探理论与实践--以辽河坳陷为例[J].石油勘探与开发,2009,36(2):136-143.Meng Weigong,Chen Zhenyan,Li Pai,Guo Yanmin,Gao Xianzhi,Hui Xuefeng,et al.Exploration theories and practices of buried-hill reservoirs:A case from Liaohe Depressions[J].Petroleum Exploration and Development,2009,36(2):136-143.
[5]蒋有录,叶涛,张善文,刘华.渤海湾盆地潜山油气富集特征与主控因素[J].中国石油大学学报(自然科学版),2015,39(3):20-29.Jiang Youlu,Ye Tao,Zhang Shanwen&Liu Hua.Enrichment characteristics and main controlling factors of hydrocarbon in buried hill of Bohai Bay Basin[J].Journal of China University of Petroleum(Edition of Natural Science),2015,39(3):20-29.
[6]薛永安,李慧勇.渤海海域深层太古界变质岩潜山大型凝析气田的发现及其地质意义[J].中国海上油气,2018,30(3):1-9.Xue Yong'an,Li Huiyong.Large condensate gas field in deep Archean metamorphic buried hill in Bohai Sea:Discovery and geological significance[J].China Offshore Oil and Gas,2018,30(3):1-9.
[7]李德生.渤海湾含油气盆地的地质和构造特征[J].石油学报,1980,1(1):6-20.Li Desheng.Geology and structural characteristics of Bohai Bay,China[J].Acta Petrolei Sinica,1980,1(1):6-20.
[8]周心怀,张如才,李慧勇,王保全,郭永华.渤海湾盆地渤中凹陷深埋古潜山天然气成藏主控因素探讨[J].中国石油大学学报(自然科学版),2017,41(1):42-50.Zhou Xinhuai,Zhang Rucai,Li Huiyong,Wang Baoquan&Guo Yonghua.Major controls on natural gas accumulations in deep-buried hills in Bozhong Depression,Bohai Bay Basin[J].Journal of China University of Petroleum(Edition of Natural Science),2017,41(1):42-45.
[9]Tian Jinqiang,Hao Fang,Zhou Xinhuai&Zou Huayao.Distribution,controlling factors,and oil-source correlation of biodegraded oils in the Bohai offshore area,Bohai Bay Basin,China[J].AAPG Bulletin,2017,101(3):361-385.
[10]胡见义,黄第藩.中国陆相石油地质理论基础[M].北京:石油工业出版社,1991.Hu Jianyi&Huang Difan.The bases of nonmarine petroleum geology in China[M].Beijing:Petroleum Industry Press,1991.
[11]崔景伟,王铁冠,李美俊,耿峰,唐友军,胡健.塔西南地区原油轻烃特征及成因类型[J].天然气地球科学,2015,26(7):1354-1364.Cui Jingwei,Wang Tieguan,Li Meijun,Geng Feng,Tang Youjun&Hu Jian.Light hydrocarbon characteristics and oil family classification of crude oils,Southwest Tarim Basin,Northwest China[J].Natural Gas Geoscience,2015,26(7):1354-1364.
[12]Cui Jingwei,Wang Tieguan,Li Meijun,Ou Guangxi,Geng Feng&Hu Jian.Oil filling history of the Bashituo Oilfield in the Markit Slope,SW Tarim Basin,China[J].Petroleum Science,2013,10(1):58-64.
[13]Cui Jingwei,Wang Tieguan,Wang Chunjiang&Li Meijun.Quantitative assessment and significance of gas washing of oil in Block 9 of the Tahe Oilfield,Tarim Basin,NW China[J].Chinese Journal of Geochemistry,2012,31(2):165-173.
[14]翟俪娜,倪云燕,吴朝东,高金亮.川中地区须家河组天然气地球化学特征[J].天然气地球科学,2017,28(4):539-549.Zhai Lina,Ni Yunyan,Wu Chaodong&Gao Jinliang.Geochemical characteristics of the natural gas from the Xujiahe Formation in the central Sichuan Basin,China[J].Natural Gas Geoscience,2017,28(4):539-549.
[15]Dai Jinxing,Xia Xinyu,Qin Shengfei&Zhao Jingzhou.Origins of partially reversed alkaneδ13C values for biogenic gases in China[J].Organic Geochemistry,2004,35(4):405-411.
[16]贺聪,吉利明,苏奥,吴远东,张明震.天然气组分碳同位素倒转成因分析及地质应用[J].特种油气藏,2016,23(4):14-19.He Cong,Ji Liming,Su Ao,Wu Yuandong&Zhang Mingzhen.Genesis analysis and geological application of gas component carbon isotope reversal[J].Special Oil&Gas Reservoirs,2016,23(4):14-19.
[17]Dai Jinxing,Song Yang,Dai Chunsen&Wang Darui.Geochemistry and accumulation of carbon dioxide gases in China[J].AAPG Bulletin,1996,80(10):1615-1626.
[18]戴金星,秦胜飞,陶士振,朱光有,米敬奎.中国天然气工业发展趋势和天然气地学理论重要进展[J].天然气地球科学,2005,16(2):127-142.Dai Jinxing,Qin Shengfei,Tao Shizhen,Zhu Guangyou&Mi Jingkui.Developing trends of natural gas industry and the significant progress on natural gas geological theories in China[J].Natural Gas Geoscience,2005,16(2):127-142.
[19]刘新社,蒋有录,侯云东,刘景东,文彩霞,朱荣伟,等.鄂尔多斯盆地靖西地区奥陶系中组合天然气成因与成藏主控因素[J].天然气工业,2016,36(4):16-26.Liu Xinshe,Jiang Youlu,Hou Yundong,Liu Jingdong,Wen Caixia,Zhu Rongwei,et al.Origins of natural gas and the main controlling factors of gas accumulation in the Middle Ordovician assemblages in the Jingxi area,Ordos Basin[J].Natural Gas Industry,2016,36(4):16-26.
[20]蒋飞,李忠诚,程日辉,刘宇,许中杰,王茂汀.王府断陷小城子气田火石岭组气藏天然气成藏模式及富集规律[J].天然气工业,2016,36(10):46-55.Jiang Fei,Li Zhongcheng,Cheng Rihui,Liu Yu,Xu Zhongjie&Wang Maoting.Natural gas accumulation models and enrichment patterns of the Huoshiling Fm reservoirs in the Xiaochengzi gas field,Wangfu fault depression,Songliao Basin[J].Natural Gas Industry,2016,36(10):46-55.
[21]郭潇潇,熊小峰,徐新德,甘军,梁刚.莺歌海盆地天然气类型划分与来源分析[J].特种油气藏,2017,24(5):54-58.Guo Xiaoxiao,Xiong Xiaofeng,Xu Xinde,Gan Jun&Liang Gang.Type classification and origin analysis of natural gas in the Yinggehai Basin[J].Special Oil&Gas Reservoirs,2017,24(5):54-58.
[22]Lorant F,Prinzhofer A,Behar F&Huc AY.Carbon isotopic and molecular constraints on the formation and the expulsion of thermogenic hydrocarbon gases[J].Chemical Geology,1998,147(3/4):249-264.
[23]Berner U&Faber E.Empirical carbon isotope/maturity relationships for gases from algal kerogens and terrigenous organic matter,based on dry,open-system pyrolysis[J].Organic Geochemistry,1996,24(10/11):947-955.
[24]Bernard BB,Brooks JM&Sackett WM.Light hydrocarbons in recent Texas continental shelf and slope sediments[J].Journal of Geophysical Research,1978,33(8):4053-4061.
[25]Stahl WJ&Garey BD.Source-rock identification by isotope analyses of natural gases from fields in the Val Verde and Delaware Basins,West Texas[J].Chemical Geology,1975,16(4):257-267.
[26]戴金星,戚厚发.我国煤成烃气的δ13C-Ro关系[J].科学通报,1989,34(9):690-692.Dai Jinxing&Qi Houfa,Relationship ofδ13C-Ro of coal-derived gas in China[J].Chinese Science Bulletin,1989,34(9):690-692.
[27]沈平,徐永昌,王先彬.气源岩和天然气地球化学特征及成气机理研究[M].兰州:甘肃科学技术出版社,1991.Shen Ping,Xu Yongchang&Wang Xianbin.Study on geochemical characteristics of gas source rock and natural gas and mechanism of genesis of gas[M].Lanzhou:Gansu Science and Technology Press,1991.
[28]Thompson KFM.Classification and thermal history of petroleum based on light hydrocarbons[J].Geochimica et Cosmochimica Acta,1983,47(2):303-316.
[29]Thompson KFM.Fractionated aromatic petroleum and the generation of gas-condensates[J].Organic Geochemistry,1987,11(6):573-590.
[30]王培荣,徐冠军,张大江,肖廷荣,任冬苓.烃源岩与原油中轻馏分烃的对比--以胜利油田东营、沾化凹陷为例[J].石油与天然气地质,2013,34(1):1-10.Wang Peirong,Xu Guanjun,Zhang Dajiang,Xiao Tingrong&Ren Dongling.Correlation of light hydrocarbons between source rock and crude:An example from Dongying and Zhanhua Depressions in Jiyang Subbasin,Bohai Bay Basin[J].Oil&Gas Geology,2013,34(1):1-10.
[31]王培荣,赵红,肖廷荣,朱翠山,徐冠军,张敏,等.采用气相色谱“反吹、微流控”技术分析原油C5-C13轻馏分及其地球化学意义初探[J].自然科学进展,2007,17(8):1144-1149.Wang Peirong,Zhao Hong,Xiao Tingrong,Zhu Cuishan,Xu Guanjun,Zhang Min,et al.Application of backflush and micro-flow techniques to the analysis of C5-C13 hydrocarbons in crude oils and its geochemical significance[J].Progress in Natural Science,2007,17(8):1144-1149.
[32]Peters KE,Walters CC&Moldowan JM.The biomarker guide:Interpreting molecular fossils in petroleum and ancient sediments(second edition)[M].New York:Prentice Hall,1992.
[33]Zhu Yangming,Weng Huanxin,Su Aiguo,Liang Digang&Peng Dehua.Geochemical characteristics of Tertiary saline lacustrine oils in the Western Qaidam Basin,Northwest China[J].Applied Geochemistry,2005,20(10):1875-1889.
[34]Chen Jianyu,Bi Yanpong,Zhang Jiguo&Li Shuafu.Oil-source correlation in the Fulin Basin,Shengli petroleum province,East China[J].Organic Geochemistry,1996,24(8/9):931-940.
[35]Hao Fang,Zhou Xinhuai,Zhu Yangming&Yang Yuanyuan.Mechanisms for oil depletion and enrichment on the Shijiutuo uplift,Bohai Bay Basin,China[J],AAPG Bulletin,2009,93(8):1015-1037.
[36]Huang Wenyen&Meinschein WG.Sterols as ecological indicators[J].Geochimica et Cosmochimica Acta,1979,43(5):739-745.
[37]昝灵,张枝焕,王顺华,邢辉,李文浩,刘炜楠,等.4-甲基甾烷在油源对比中的应用--以渤南洼陷北部陡坡带为例[J].沉积学报,2012,30(4):770-778.Zan Ling,Zhang Zhihuan,Wang Shunhua,Xing Hui,Li Wenhao,Liu Weinan,et al.Application of 4-methyl steranes in oil-source correlation:A case study from northern steep slope zone of Bonan Sag[J].Acta Sedimentologica Sinica,2012,30(4):770-778.
[38]王铁冠,钟宁宁,侯读杰,黄光辉,包建平,李贤庆,等.低熟油气形成机理与分布[M].北京:石油工业出版社,1995.Wang Tieguan,Zhong Ningning,Hou Dujie,Huang Guanghui,Bao Jianping,Li Xianqing,et al.Genetic mechanism and occurrence of immature hydrocarbon[M].Beijing:Petroleum Industry Press,1995.
© 2004-2018 中国地质图书馆版权所有 京ICP备05064691号 京公网安备11010802017129号 地址：北京市海淀区学院路29号 邮编：100083 电话：办公室：(+86 10)66554848；文献借阅、咨询服务、科技查新：66554700 |