东昆仑夏日哈木镁铁-超镁铁岩中的钛闪石-韭闪石对成矿过程的约束
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摘要
夏日哈木含铜镍矿镁铁-超镁铁岩位于东昆仑西段的昆北地体,主要由方辉橄榄岩、橄榄方辉岩、斜方辉石岩以及辉长岩组成,赋矿岩石类型包括橄榄方辉岩和斜方辉石岩,但含矿岩体形成的温度、压力和氧逸度条件仍不清楚。本文在含长橄榄方辉岩中发现填隙相的角闪石,电子探针分析结果显示其属于钛闪石和韭闪石。角闪石整体具有贫硅(SiO_2=40.97%～44.63%)、贫镁(MgO=14.46%～16.75%),富铝(Al_2O_3=12.56%～13.95%)、富钛(TiO_2=1.46%～5.52%)特征,显示岩浆成因特征。根据角闪石成分计算结果显示,角闪石结晶温度为980～1040℃,形成压力为700～840MPa,氧逸度范围为NNO-0.54～+1.36。角闪石核边成分反映其结晶时降温降压的过程。角闪石氧逸度具有先升高后降低的规律:核部具有低氧逸度特征,表明母岩浆有利于成矿物质的富集;早期氧逸度升高可能受到围岩金水口群大理岩同化混染作用影响;后期氧逸度降低可能与同源高镁拉斑玄武质岩浆注入有关,新的岩浆注入促进了硫化物的熔离成矿。
The Xiarihamu Ni-Cu mafic-ultramafic intrusion in North Kunlun Terrane,in the western part of the Eastern Kunlun Orogenic Belt,is mainly composed of harzburgite,Ol-orthopyroxenite,orthopyroxenite and gabbro.Ol-orthopyroxenite and orthopyroxenite are the main host rocks for the Ni-Cu ores.The temperature,pressure and oxygen fugacity conditions of mineral crystallization remain unclear.The interstitial amphiboles appear in the sample of Pl-bearing Ol-orthopyroxenite.Mineral chemistry data of the amphiboles by EMPA are characterized by low silica(SiO_2=40.97%～44.63%),low magnesium(MgO=14.46%～16.75%),high aluminum(Al_2O_3=12.56%～13.95%)and high tatimiun(TiO_2=1.46%～5.52%)contents,indicating a magmatic origin.Using the hornblende geothermobarometry,the calculation temperature of mineral crystallization is 980～1040℃,and the pressure is 700～840MPa.The oxygen fugacity of amphibole ranges from NNO-0.54 to NNO+1.36.The core-rim composition of amphibole suggests the process of magma cooling and depressurization during the mineral crystallization.The oxygen fugacity of amphibole increases at the initial stage and then decreases.The characteristics of low oxygen fugacity in amphibole core indicate that the primary magma is conducive to enrichment of ore-forming materials.The increase of magma oxygen fugacity may be affected by assimilation-contamination by the country rock marble.The decrease of oxygen fugacity may be related to the homologous magma injection of high-Mg basaltic magma,which is conductive to the sulfide segregation.
The Xiarihamu Ni-Cu mafic-ultramafic intrusion in North Kunlun Terrane,in the western part of the Eastern Kunlun Orogenic Belt,is mainly composed of harzburgite,Ol-orthopyroxenite,orthopyroxenite and gabbro.Ol-orthopyroxenite and orthopyroxenite are the main host rocks for the Ni-Cu ores.The temperature,pressure and oxygen fugacity conditions of mineral crystallization remain unclear.The interstitial amphiboles appear in the sample of Pl-bearing Ol-orthopyroxenite.Mineral chemistry data of the amphiboles by EMPA are characterized by low silica(SiO_2=40.97%～44.63%),low magnesium(MgO=14.46%～16.75%),high aluminum(Al_2O_3=12.56%～13.95%)and high tatimiun(TiO_2=1.46%～5.52%)contents,indicating a magmatic origin.Using the hornblende geothermobarometry,the calculation temperature of mineral crystallization is 980～1040℃,and the pressure is 700～840MPa.The oxygen fugacity of amphibole ranges from NNO-0.54 to NNO+1.36.The core-rim composition of amphibole suggests the process of magma cooling and depressurization during the mineral crystallization.The oxygen fugacity of amphibole increases at the initial stage and then decreases.The characteristics of low oxygen fugacity in amphibole core indicate that the primary magma is conducive to enrichment of ore-forming materials.The increase of magma oxygen fugacity may be affected by assimilation-contamination by the country rock marble.The decrease of oxygen fugacity may be related to the homologous magma injection of high-Mg basaltic magma,which is conductive to the sulfide segregation.
引文
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