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天然气水合物开采方法的研究综述
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  • 英文篇名:A comprehensive review in natural gas hydrate recovery methods
  • 作者:张旭辉 ; 鲁晓兵 ; 李鹏
  • 英文作者:ZHANG XuHui;LU XiaoBing;LI Peng;Institute of Mechanics, Chinese Academy of Sciences;School of Engineering Science, University of Chinese Academy of Sciences;
  • 关键词:水合物 ; 开采方法 ; 试生产 ; 固态流化 ; 机械-热联合
  • 英文关键词:gas hydrate;;exploitation;;trial production;;solid fluidization;;mechanical-thermal recovery
  • 中文刊名:中国科学:物理学 力学 天文学
  • 英文刊名:Scientia Sinica(Physica,Mechanica & Astronomica)
  • 机构:中国科学院力学研究所;中国科学院大学工程科学学院;
  • 出版日期:2018-11-07 14:12
  • 出版单位:中国科学:物理学 力学 天文学
  • 年:2019
  • 期:03
  • 基金:国家自然科学基金(编号:51239010,51639008,11272314,11102209);; 中国地质调查局项目(编号:DD20160217-1-1-1);; 中石油-中科院高端战略联盟研究计划(编号:2015A-4813);; 中国科学院青年创新促进会(编号:2017027)资助项目
  • 语种:中文;
  • 页:38-59
  • 页数:22
  • CN:11-5848/N
  • ISSN:1674-7275
  • 分类号:TE37;P744.4
摘要
天然气水合物(简称水合物)是天然气(主要成分甲烷)和水在高压和低温条件下形成的类冰固体化合物.我国将水合物开采研究归入战略发展规划.本文首先介绍水合物地层成藏和分类以及适合大规模商业化开采的地区;然后系统地总结了当前提出的水合物开采方法和适用条件,重点介绍了机械-热联合开采水合物方法的工艺流程和基本科学原理;阐述了水合物开采涉及的热传导、相变、渗流和应力变化4个效应,说明了水合物开采过程中各个物理量演化的特征,作为水合物开采与相关监测的理论基础;最后分析了国内外现场试验性开采的研究进展,并指出了未来水合物开采的研究方向.
        Natural gas hydrate is an ice-like compound composed of mainly methane molecules and water molecules under proper high pressure and low temperature, and is being studied as a strategic energy resource. This paper first introduces the research advance of reservoir formation and classification of hydrate formation, and then systematically summarizes the current methods and their applicable conditions for hydrate exploitation. A new concept i.e. mechanical-thermal hydrate recovery method is presented based on the geological-mechanical characteristics in China and the technological process and scientific principles were introduced and overiewed. Hydrate mining mainly involves four effects of heat conduction,phase change, seepage and stress change. Through the analysis of the four characteristic time, the problem is decoupled and the characteristics of the evolution of the physical quantities in the process of hydrate mining can be determined,which can provide theoretical guidance for the practical exploitation of hydrates. Finally, the research progress of field trial production is analyzed and the future research direction of hydrate mining is pointed out.
引文
1 Englezos P.Clathrate hydrates.Ind Eng Chem Res,1993,32:1251-1274
    2 Sloan E D.Clathrate Hydrates of Natural Gases.New York:Marcel Dekker,1998.18-28
    3 Koh C A.Towards a fundamental understanding of natural gas hydrates.Chem Soc Rev,2002,31:157-167
    4 Chen G J,Sun C Y,Ma Q L.Science and Technology of Gas Hydrates(in Chinese).Beijing:Chemical Industry Press,2007[陈光进,孙长宇,马庆兰.气体水合物科学与技术.北京:化学工业出版社,2007]
    5 Ginsburg G D,Soloviev VA.Methane migration within the submarine gas-hydrate stability zone under deep-water conditions.Mar Geol,1997,137:49-57
    6 Martin J B,Kastner M,Henry P,et al.Chemical and isotopic evidence for sources of fluids in a mud volcano field seaward of the Barbados accretionary wedge.J Geophys Res,1996,101:20325-20345
    7 Yao B C.Preliminary exploration of gas hydrate in the northern margin of the South China Sea(in Chinese).Marin Geol Quat Geol,1998,18:11-18[姚伯初.南海北部陆缘天然气水合物初探.海洋地质与第四纪地质,1998,18:11-18]
    8 Zhu Y H,Wu B H,Lu Z Q.The prospecting for gas hydrate offshore China(in Chinese).Miner Depos,2001,2:174-180[祝有海,吴必豪,卢振权.中国近海天然气水合物找矿前景.矿床地质,2001,2:174-180]
    9 Wu N Y,Yang S X,Wang H B,et al.Gas-bearing fluid influx sub-system for gas hydrate geological system in Shenhu Area,Northern South China Sea(in Chinese).Chin J Geophys,2009,52:1641-1650[吴能友,杨胜雄,王宏斌,等.南海北部陆坡神狐海域天然气水合物成藏的流体运移体系.地球物理学报,2009,52:1641-1650]
    10 Chen D F,Su Z,Feng D,et al.Formation and its controlling factors of gas hydrate reservoir in marine gas vent system(in Chinese).J Trop Oceanogr,2005,24:38-46[陈多福,苏正,冯东,等.海底天然气渗漏系统水合物成藏过程及控制因素.热带海洋学报,2005,24:38-46]
    11 Kvenvolden K A,Lorenson T D.The global occurrence of natural gas hydrate.Geophys Monogr,2001,124:3-18
    12 Trehu A M,Bohrmann G,Rack F R,et al.Proc.ODP,Initial reports 204,Ocean Drilling Program,Texas A&M Un.,College Station TX 77845-9547,USA,2003
    13 Jin C S,Wang J Y,Zhang G X.Factors affecting natural gas hydrate stability zone in the South China Sea(in Chinese).Miner Depos,2005,24:388-397[金春爽,汪集旸,张光学.南海天然气水合物稳定带的影响因素.矿床地质,2005,24:388-397]
    14 Gong J M,Wang H X,Chen J W,et al.Distribution model for gas hydrate in sediments(in Chinese).Mar Geol Lett,2004,20:6-8[龚建明,王红霞,陈建文等.天然气水合物在沉积地层中的分布模式.海洋地质动态,2004,20:6-8]
    15 Wu N Y,Zhang H Q,Su X,et a1.High concentrations of hydrate in disseminated forms found in very fine-grained sediments of Shenhu area,South China Sea.Terra Nostra,2007,l2:236-237
    16 Zhu Y H,Zhang Y Q,Wen H J,et al.Gas hydrates in the Qilian Mountain permafrost and their basic characteristics(in Chinese).Acta Geosci Sin,2010,31:7-16[祝有海,张永勤,文怀军,等.祁连山冻土区天然气水合物及其基本特征.地球学报,2010,31:7-16]
    17 Zhang H T,Zhu Y H.Survey and research on gas hydrate in permafrost region of China(in Chinese).Geol Bull China,2011,30:1809-1815[张洪涛,祝有海.中国冻土区天然气水合物调查研究.地质通报,2011,30:1809-1815]
    18 Boswell R,Collett T S.The gas hydrates resource pyramid.Fire in the ice,Methane hydrate newsletter,US Department of Energy,Office of Fossil Energy,National Energy Technology Laboratory,2006,Fall Issue,5-7
    19 White M D,Wurstner S K,McGrail B P.Numerical studies of methane production from Class 1 gas hydrate accumulations enhanced with carbon dioxide injection.Mar PetGeol,2011,28:546-560
    20 Moridis G J.Numerical studies of gas production from methane hydrates.SPE J,2003,32:359-370
    21 Moridis G J,Sloan E D.Gas production potential of disperse low-saturation hydrate accumulations in oceanic sediments.Energy Convers Manage,2007,48:1834-1849
    22 Kayen R E,Lee H J.Pleistocene slope instability of gas hydrate-laden sediment on the Beaufort sea margin.Mar Geotech,1991,10:125-141
    23 Milkov A V.Worldwide distribution of submarine mud volcanoes and associated gas hydrates.Mar Geol,2000,167:29-42
    24 Makogon Y F.Hydrate of Natural Gas.Oklahoma:PennWell Publishing Co.,1981
    25 Moridis G J,Reagan M T.Strategies for gas production from oceanic Class 3 hydrate accumulations.In:Proceedings of the Offshore Technology Conference.Houston,2007
    26 Moridis G J,Reagan M T.Gas production from Class 2 hydrate accumulations in the permafrost.In:Proceedings of SPE Annual Technical Conference and Exhibition.Anaheim,2007
    27 Stevens J C,Howard J J,Baldwin B A.Experimental hydrate formation and gas production scenarios based on CO2sequestration.In:Proceedings of the 6th International Conference on Gas Hydrates.Vancouver,2008
    28 Moridis G J,Reagan M T,Boyle K,et al.Evaluation of a deposit at the PBU L-106 Site,North Slope,Alaska,for a potential long term test of gas production from hydrates.In:Proceedings of the SPE Western Regional Meeting.Anaheim,2010
    29 Handa Y P,Stupin D Y.Thermodynamic properties and dissociation characteristics of methane and propane hydrates in 70-.ANG.-radius silica gel pores.J Phys Chem,1992,96:8599-8603
    30 Waite W F,Winters W J,Mason D H.Methane hydrate formation in partially water-saturated Ottawa sand.Am Miner,2004,89:1202-1207
    31 Kneafsey T J,Tomutsa L,Moridis G J,et al.Methane hydrate formation and dissociation in a partially saturated core-scale sand sample.J Pet Sci Eng,2007,56:108-126
    32 Marcelle-De Silva J,Dawe R.Towards commercial gas production from hydrate deposits.Energies,2011,4:215-238
    33 Tang G L,Feng Z P,Li X S,et al.A new production method for offshore seep gas hydrate reservoir(in Chinese).Energ Eng,2006,1:15-18[唐良广,冯自平,李小森,等.海洋渗漏型天然气水合物开采的新模式.能源工程,2006,1:15-18]
    34 Xu H L,Lin L C,Wu W R,et al.Cutter-suction exploitation mode of marine gas hydrate(in Chinese).Acta Sci Nat Univ Sunyatseni,2011,50:48-52[徐海良,林良程,吴万荣,等.海底天然气水合物绞吸式开采方法研究.中山大学学报(自然科学版),2011,50:48-52]
    35 Matsukuma Y,Miwa M,Inoue G,et al.Study of recovery system of methane hydrate using gas lift method.In:Proceedings of the 6th International Conference on Gas Hydrates.Vancouver,2008
    36 Ji C,Ahmadi G,Smith D H.Constant rate natural gas production from a well in a hydrate reservoir.Energy Convers Manage,2003,44:2403-2423
    37 Bai Y H,Ye C M,Li Q P,et al.Advances in exploitation models of gas hydrate and their prospects(in Chinese).China Offshore Oil Gas,2009,21:251-256[白玉湖,叶长明,李清平,等.天然气水合物开采模型研究进展与展望.中国海上油气,2009,21:251-256]
    38 McGuire P L.Recovery of gas form hydrate deposits using conventional technology.In:SPE Unconventional Gas Recovery Symposium.Pittsburgh,1982.373-379
    39 Yousif M H,Abass H H,Selim M S,et al.Experimental and theoretical investigation of methane-gas-hydrate dissociation in porous media.SPEReservoir Eng,1991,6:69-76
    40 Kim H C,Bishnoi P R,Heidemann R A,et al.Kinetics of methane hydrate decomposition.Chem Eng Sci,1987,42:1645-1653
    41 Sun X,Nanchary N,Mohanty K K.1-D modeling of hydrate depressurization in porous media.Transp Porous Media,2005,58:315-338
    42 Moridis G J,Collett T S,Dallimore S R,et al.Numerical studies of gas production from several CH4hydrate zones at the Mallik site,Mackenzie Delta,Canada.J Pet Sci Eng,2004,43:219-238
    43 Hong H,Pooladi-Darvish M,Bishnoi P R.Analytical modelling of gas production from hydrates in porous media.J Can Pet Tech,2003,42:45-56
    44 Sung W,Kang H.Experimental investigation of production behaviors of methane hydrate saturated in porous rock.Energy Sources,2003,25:845-856
    45 Lee J,Park S,Sung W.An experimental study on the productivity of dissociated gas from gas hydrate by depressurization scheme.Energy Convers Manage,2010,51:2510-2515
    46 Sun J Y,Ye Y G,Liu C L,et al.Experimental research of gas hydrate dissociation in sediments by depressurization method(in Chinese).Geoscience,2010,24:614-621[孙建业,业渝光,刘昌岭,等.沉积物中天然气水合物减压分解实验.现代地质,2010,24:614-621]
    47 Li S X,Chen Y M,Wang X H,et al.Experimental study on synthesis and depressurization of natural gas hydrate in sand filling model(in Chinese).Oil-Gasfield Surf Eng,2009,28:1-3[李淑霞,陈月明,王晓红,等.填砂模型中天然气水合物合成及降压分解实验研究.油气田地面工程,2009,28:1-3]
    48 Nazridoust K,Ahmadi G.Computational modeling of methane hydrate dissociation in a sandstone core.Chem Eng Sci,2007,62:6155-6177
    49 Corey A T.The interrelation between gas and oil relative permeability.Produc Month,1954,19:38-41
    50 Chen Y M,Liu Y P,Zhang X J,et al.Numerical simulation of natural gas hydrate production by depressurization in salt-water system(in Chinese).J Chin Univ Petrol,2009,33:80-84[陈月明,刘亚平,张新军,等.盐水体系中天然气水合物降压开采数值模拟.中国石油大学学报,2009,33:80-84]
    51 Cheng Y F,Shen H C,Zhao Y Z,et al.Numerical simulation with finite element method on natural gas hydrate decomposition by depressurization in porous media(in Chinese).J China Univ Petrol,2009,33:85-89[程远方,沈海超,赵益忠,等.多孔介质中天然气水合物降压分解有限元模拟.中国石油大学学报,2009,33:85-89]
    52 Bai Y H,Li Q P.Simulation of gas production from hydrate reservoir by the combination of warm water flooding and depressurization(in Chinese).Sci China Tech Sci,2011,41:262-268[白玉湖,李清平.注温水-降压法联合开采天然气水合物藏模拟.中国科学:技术科学,2011,41:262-268]
    53 Kimoto S,Oka F,Fushita T,et al.A chemo-thermo-mechanically coupled numerical simulation of the subsurface ground deformations due to methane hydrate dissociation.Comput Geotech,2007,34:216-228
    54 Rutqvist J,Moridis G J.Development of a numerical simulator for analyzing the geomechanical performance of hydrate-bearing sediments.In:The 42nd US Rock Mechanics Symposium and 2nd US-Canada Rock Mechanics Symposium.San Francisco,2008
    55 Shen H C,Cheng Y F,Hu X Q.Numerical simulation of near wellbore reservoir stability during gas hydrate production by depressurization(in Chinese).Petol Drilling Tech,2012,40:76-81[沈海超,程远方,胡晓庆.天然气水合物降压开采近井储层稳定性数值模拟.石油钻探技术,2012,40:76-81]
    56 Konno Y,Masuda Y,Akamine K,et al.Sustainable gas production from methane hydrate reservoirs by the cyclic depressurization method.Energy Convers Manage,2016,108:439-445
    57 Si N,An L,Deng H,et al.Discussion on natural gas hydrate production technologies(in Chinese).China Petrol Expl,2016,21:52-61[思娜,安雷,邓辉,等.天然气水合物开采技术研究进展及思考.中国石油勘探,2016,21:52-61]
    58 Kamath V A.A perspective on gas production from hydrate.In:The JNOC’s Methnae hydrate International Symposium.Chiba City:Japan National Oil Corporation,1998.87-92
    59 Wan L H,Li X S,Li G.An experimental study on dissociation behavior of methane hydrate under hot brine stimulation(in Chinese).Mod Chem Ind,2008,28:47-50[万丽华,李小森,李刚.热盐水分解甲烷水合物实验研究.现代化工,2008,28:47-50]
    60 Song Y C,Ruan X K,Liang H F,et al.Research advance in thermal recovery of natural gas hydrate(in Chinese).Chin J Proc Eng,2009,9:1035-1040[宋永臣,阮徐可,梁海峰,等.天然气水合物热开采技术研究进展.过程工程学报,2009,9:1035-1040]
    61 Holder G D,Angel P F,Godbole S P.Simulation of gas production from a reservoir containing both gas hydrates and free natural gas.In:Proceedings of 57th Society of Petroleum Engineers Technology Conference.New Orleans:International Society of Petroleum Engineers,1982.1-6
    62 Selim M S,Sloan E D.Heat and mass transfer during the dissociation of hydrates in porous media.AIChE J,1989,35:1049-1052
    63 Ullerich J W,Selim M S,Sloan E D.Theory and measurement of hydrate dissociation.AIChE J,1987,33:747-752
    64 Selim M S,Sloan E D.Modeling of the dissociation of an in-situ hydrate.In:Proceedings of the 1985 California Regional Meeting.Bakersfield:Society of Petroleum Engineers,1985.75-79
    65 Li G,Tang L G,Huang C,et al.Thermodynamic evaluation of hot brine stimulation for natural gas hydrate dissociation(in Chinese).CIESC J,2006,57:2033-2038[李刚,唐良广,黄冲,等.热盐水开采天然气水合物的热力学评价.化工学报,2006,57:2033-2038]
    66 Zhang X H,Lu X B,Li Q P,et al.Heat transfer analysis in hydrate deposits with phase transformation(in Chinese).Sci China-Phys Mech Astron,2010,40:1028-1034[张旭辉,鲁晓兵,李清平,等.水合物沉积层中考虑相变的热传导分析.中国科学:物理学力学天文学,2010,40:1028-1034]
    67 Roadifer R D,Godbole S P,Kamath V A.Thermal model for establishing guidelines for drilling in presence of hydrates.In:Proceedings of the1987 California Regional Meeting.Bakersfield:Society of Petroleum Engineers,1987.8-10
    68 Durgut I,Parlaktuna M.A numerica1 method for the gas production process in gas hydrate reservoirs.In:Proceedings of the Second International Conference on Natural Gas Hydrates.Toulouse:Tapir Academic Press,1996.549-556
    69 Swinkels W J A M,Drenth R J J.Thermal reservoir simulation model of production from naturally occurring gas hydrate accumulations.SPEReserv Eval Eng,2000,3:559-566
    70 Uchida T,Takeya S,Chuvilin E M,et al.Decomposition of methane hydrates in sand,sandstone,clays,and glass beads.J Geophys Res,2004,109:B05206
    71 Moridis G J,Apps J,Pruess K.EOSHYDR:A TOUGH2 module for CH4-hydrate release and flow in the subsurface.Berkeley:Lawrence Berkeley National Laboratory,LBNL-42386,1998
    72 Moridis G J,Collet T S,Dallimore S R.Numerical studies of gas production from several CH4,hydrate zones at the Mallik site.Berkeley:Lawrence Berkeley National Laboratory,LBNL-50257,2002
    73 Tang L G,Xiao R,Li G.Experimental investigation of production behavior of gas hydrate under thermal stimulation(in Chinese).Chin J Proc Eng,2006,6:548-553[唐良广,肖睿,李刚.热力法开采天然气水合物的模拟实验研究.过程工程学报,2006,6:548-553]
    74 Ebinuma T.Method for dumping and disposing of carbon dioxide gas and apparatus therefor.US Patent,US 5261490 A,1993
    75 Ohgaki K,Takano K,Sangawa H,et al.Methane exploitation by carbon dioxide from gas hydrates.Phase equilibria for CO2-CH4mixed hydrate system.J Chem Eng Jpn/JCEJ,1996,29:478-483
    76 Anderson R,Llamedo M,Tohidi B,et al.Experimental measurement of methane and carbon dioxide clathrate hydrate equilibria in mesoporous silica.J Phys Chem B,2003,107:3507-3514
    77 Akihiro H.Phase equilibrium and comparison of formation speeds of CH4and CO2hydrate below the ice point.In:Roceedings of The Fifth International Conference on Gas Hydrates.Norway,2005
    78 Li Z Z,Guo X Q,Chen G J,et al.Experimental and kinetic studies on methane replacement from methane hydrate formed in SDS system by using pressurized CO2(in Chinese).CIESC J,2007,58:l197-1202[李遵照,郭绪强,陈光进,等.CO2置换CH4水合物中CH4的实验和动力学.化工学报,2007,58:l197-1202]
    79 Ota M,Morohashi K,Abe Y,et al.Replacement of CH4in the hydrate by use of liquid CO2.Energy Convers Manage,2005,46:1680-1691
    80 McGrail B P,Zhu T,Hunter R B,et al.A new method for enhanced production of gas hydrate with CO2.In:AAPG Hedberg Conference.Vancouver,2004
    81 Ota M,Saito T,Aida T,et al.Macro and microscopic CH4-CO2replacement in CH4hydrate under pressurized CO2.AIChE J,2007,53:2715-2721
    82 Uchida T,Takeya S,Ebinuma T,et al.Replacing methane with CO2in clathrate hydrate:Observations using raman spectroscopy.In:Proceeding of 5th International Confference on Greenhouse Gas Control Technologies.Collingwood:CSIRO Publishing,2001.523-527
    83 Zhou X T,Fan S S,Liang D Q.Advancement in research on replacement of CH4from hydrate with CO2(in Chinese).Chem Ind Eng Prog,2006,25:524-527[周锡堂,樊栓狮,梁德青.CO2置换开采天然气水合物研究进展.化工进展,2006,25:524-527]
    84 Baldwin B A,Stevens J,Howard J J,et al.Using magnetic resonance imaging to monitor CH4hydrate formation and spontaneous conversion of CH4hydrate to CO2hydrate in porous media.Magn Reson Imag,2009,27:720-726
    85 Jung J W,Santamarina J C.CH4-CO2replacement in hydrate-bearing sediments:A pore-scale study.Geochem Geophys Geosyst,2010,11:Q0AA13
    86 Zhou L S,Guo P,Du J F,et al.Research progressed in phase equilibria research on replacement of CH4from hydrate with CO2(in Chinese).Chem Ind Eng Prog,2013,32:2543-2548[周琳淞,郭平,杜建芬,等.CO2置换CH4水合物的相平衡研究进展.化工进展,2013,32:2543-2548]
    87 Qi Y X,Zhang H.MD simulation of CO2-CH4mixed hydrate on crystal structure and stability.Adv Mater Res,2011,181-182:310-315
    88 Dholabhai P D,Bishnoi P R.Hydrate equilibrium conditions in aqueous electrolyte solutions:Mixtures of methane and carbon dioxide.J Chem Eng Data,1994,39:191-194
    89 Wang S H,Song H B,Yan W.The change of external conditions effects on the phase equilibrium curve of gas hydrate and the thickness of hydrate stability zone(in Chinese).Prog Geophys,2005,20:761-765[王淑红,宋海斌,颜文.外界条件变化对天然气水合物相平衡曲线及稳定带厚度的影响.地球物理学进展,2005,20:761-765]
    90 Servio P,Lagers F,Peters C,et al.Gas hydrate phase equilibrium in the system methane-carbon dioxide-neohexane and water.Fluid Phase Equilib,1999,158-160:795-800
    91 Yu H J,Wang S L,Jiang G S,et al.Experimental study of the impact of compound additives on CO2hydrate formation conditions(in Chinese).JChangzhou Univ(Nat Sci Ed),2011,23:55-59[余汇军,王树立,江光世,等.表面活性剂对CO2水合物生成影响的实验研究.常州大学学报:自然科学版,2011,23:55-59]
    92 Zeng Z Y,Li X S.Hydrate formation phase equilibrium model in the porous media based on PC-SAFT equation of state(in Chinese).Chem JChin Univ,2011,32:908-914[曾志勇,李小森.基于PC-SAFT方程研究多孔介质中水合物相平衡的预测模型.高等学校化学学报,2011,32:908-914]
    93 Smith D H,Seshadri K,Wilder J W.Assessing the thermodynamic feasibility of the conversion of methane hydrate into carbon dioxide hydrate in porous media.Energy Environ Res,2001,1:101-117
    94 He Y Y.Formation of methane and carbon dioxide hydrates in bulk and in porous media.Munich:Technische Universiteit Delft,2012
    95 Luo S S,Liu H J,Sun Y.Advancement on natural gas production from hydrate in deep-sea sediments with CO2(in Chinese).China Resour Compr Utiliz,2008,26:19-23[罗莎莎,刘宏菊,孙也.CO2开采海底天然气水合物的研究进展.中国资源综合利用,2008,26:19-23]
    96 Yang G,Qi Y X,Zhang H,et al.Advances in experimental research on replacement of CH4from hydrate with CO2(in Chinese).Cryog Superconduct,2010,38:70-75[杨光,祁影霞,张华,等.CO2置换CH4水合物实验研究进展.低温与超导,2010,38:70-75]
    97 Yan K F,Li X S,Chen Z Y,et al.Research on replacement exploitation of natural gas hydrate with carbon dioxide(in Chinese).Mod Chem Ind,2012,32:42-49[颜克凤,李小森,陈朝阳,等.二氧化碳置换开采天然气水合物研究.现代化工,2012,32:42-49]
    98 Wang Y,Li X S.Research progress of natural gas hydrate production technology(in Chinese).J Circ Syst,2013,1:69-79[王屹,李小森.天然气水合物开采技术研究进展.新能源进展,2013,1:69-79]
    99 Collett T S,Boswell R,Lee M W,et al.Evaluation of long-term gas-hydrate-production testing locations on the alaska north slope.SPEReservoir Evaluation Eng,2012,15:243-264
    100 He T.Synthesis and evaluation of gas hydrate kinetic inhibitors(in Chinese).Dissertation for Master Degree.Chengdu:Southwest Petroleum University,2017[何腾.天然气水合物动力学抑制剂的合成与评价.硕士学位论文.成都:西南石油大学,2017]
    101 Qin H B.Research on the mechansim of gas hydrate kinetic inhibitors and the development of high efficient kinetic inhibitors(in Chinese).Dissertation for Doctoral Degree.Beijing:China University of Petroleum(Beijing),2016[秦慧博.水合物动力学抑制剂机理研究及高效水合物动力学抑制剂开发.博士学位论文.北京:中国石油大学(北京),2016]
    102 Wu D J,Hu Y F,Yang J T.Progress in study of new inhibitor for natural gas hydrate(in Chinese).Nat Gas Ind,2000,20:95-98[吴德娟,胡玉峰,杨继涛.天然气水合物新型抑制剂的研究进展.天然气工业,2000,20:95-98]
    103 Tang C P,Dai X X,Liang D Q,et al.Equilibrium conditions for methane hydrate in the presence of low-dosage hydrate inhibitors aqueous solutions(in Chinese).J Circ Syst,2018,6:42-46[唐翠萍,戴兴学,梁德青,等.低剂量抑制剂Inhibex501存在下的甲烷水合物相平衡研究.新能源进展,2018,6:42-46]
    104 He Y,Tang C P,Liang D Q.The study on gas hydrate inhibition of PVP in drilling fluid(in Chinese).J Circ Syst,2016,4:127-131[何勇,唐翠萍,梁德青.聚乙烯吡咯烷酮对钻井液水合物抑制性能的影响研究.新能源进展,2016,4:127-131]
    105 Zhang Q,Shen X D,Liang D Q,et al.Synthesis and application of modified natural gas hydrate kinetic inhibitors based on PVP(in Chinese).Petrochem Tech,2016,45:1506-1512[张倩,申小冬,梁德青,等.基于PVP改性的水合物抑制剂的合成与应用.石油化工,2016,45:1506-1512]
    106 Xu W X,Li Q J,Chen G J.Progress in study of natural gas hydrate inhibitor(in Chinese).Chem Ind Eng Prog,2006,25:1289-1300[许维秀,李其京,陈光进.天然气水合物抑制剂研究进展.化工进展,2006,25:1289-1300]
    107 Sun C Y,Chen G J,Guo T M.Study of hydrate inhibition in multiphase pipelines(in Chinese).Nat Gas Ind,2003,23:105-108[孙长宇,陈光进,郭天民.多相混输管线中的水合物抑制研究现状.天然气工业,2003,23:105-108]
    108 Ma Q L,Chen G J,Guo T M.Study on the hydrate formation conditions from system containing polar inhibitor(in Chinese).J Chem Eng Chin Univ,2000,14:7-11[马庆兰,陈光进,郭天民.含极性抑制剂体系中水合物生成条件的研究.高校化学工程学报,2000,14:7-11]
    109 Tang C P,Fan S S.Progress on low dosage hydrate inhibitors for natural gas(in Chinese).Chem Eng Oil Gas,2004,33:157-159[唐翠萍,樊栓狮.天然气水合物新型抑制剂的研究进展.石油与天然气化工,2004,33:157-159]
    110 Makogon T Y,Sloan E D.Mechanism of kinetic inhibition.In:Proceedings of the 4th Confer on Natural Gas Hydrate.Yokohama,2002
    111 Huang A Y.Inhibition of gas hydrate in oil and gas transportation(in Chinese).Dissertation for Master Degree.Qingdao:China University of Petroleum(East China),2011[黄安源.油气运输过程中水合物的抑制.硕士学位论文.青岛:中国石油大学(华东),2011]
    112 Hu J,Wang Y H,Lang X M,et al.Synthesis and application of a novel combined kinetic hydrate inhibitor.Sci China Tech Sci,2011,54:3289-3295
    113 Xu Y J,Yang X X,Ding J,et al.Study on anti-agglomerates of gas hydrate(in Chinese).Nat Gas Ind,2004,24:135-138[徐勇军,杨晓西,丁静,等.气体水合物防聚剂研究.天然气工业,2004,24:135-138]
    114 Xu Y J,Yang X X,Ding J,et al.Compound hydrate anti-agglomerates(in Chinese).CIESC J,2004,55:1358-1364[徐勇军,杨晓西,丁静,等.复合型水合物防聚剂.化工学报,2004,55:1358-1364]
    115 Koh C A,Westacott R E,Zhang W,et al.Mechanisms of gas hydrate formation and inhibition.Fluid Phase Equilib,2002,194-197:143-151
    116 Monfort J P,Jussaume L,El Hafaia T,et al.Kinetics of gas hydrates formation and tests of efficiency of kinetic inhibitors:Experimental and theoretical approaches.Ann New York Acad Sci,2000,912:753-765
    117 Fu Y R.Research status of combustible ice and the bottleneck of its commercial exploitation(in Chinese).Oil Drill Product Tech,2018,1:1-16[付亚荣.可燃冰研究现状及商业化开采瓶颈.石油钻采工艺,2018,1:1-16]
    118 Sasaki K,Ono S,Sugai Y,et al.Gas production from methane hydrate sediment layer by thermal stimulation with hot water injection.In:Offshore Technology Conference(OTC).Houston,2010
    119 Li G,Li X S.Numerical simulation for gas production from hydrate accumulated in Shenhu Area,South China Sea,using huff and puff method(in Chinese).CIESC J,2011,62:458-468[李刚,李小森.单井热吞吐开采南海神狐海域天然气水合物数值模拟.化工学报,2011,62:458-468]
    120 Sasaki K,Yamakawa T,Sugai Y.Integrated thermal gas production from methane hydrate formation.In:SPE/EAGE European Unconventional Resources Conference and Exhibition.Vienna,2014
    121 Takeshi K.Numerical simulation of gas hydrate bearing sediments for enhanced recovery using partial oxidation method.In:International Ocean and Polar Engineering Conference,2015
    122 Minagawa H.Depressurization and electrical heating of hydrate sediment for gas production.In:Eleventh Ocean Mining and Gas Hydrates Symposium.Kona:International Society of Offshore and Polar Engineers,2015.82-88
    123 Gupta A,Aggarwa1 A.Gas hydrates extraction by swapping-depressurization method.In:Proceedings of the Annual Offshore Thchnology Conference.Kuala,2014.1299-1304
    124 Khlebnikov V N,Gushchin P A,Antonov S V,et al.Simultaneous injection of thermodynamic inhibitors and CO2to exploit natural gas hydrate:An experimental study.Nat Gas Ind,2017,37:40-46
    125 Dou B,Jiang G S,Qin M J,et al.Hydraulic mining technology used for exploitation of marine gas hydrates(in Chinese).Geol Prospec,2009,45:427-430[窦斌,蒋国盛,秦明举,等.水力输送法开采海底浅层天然气水合物技术研究.地质与勘探,2009,45:427-430]
    126 Sun J Y,Ye Y G,Liu C L,et al.Research progress on new method of gas hydrate mining(in Chinese).Marin Geol Lett,2008,24:24-31[孙建业,业渝光,刘昌岭,等.天然气水合物新开采方法研究进展.海洋地质动态,2008,24:24-31]
    127 Zhou S W,Chen W,Li Q P.The green solid fluidization development principle of natural gas hydrate stored in shallow layers of deep water(in Chinese).China Offshore Oil Gas,2014,26:1-7[周守为,陈伟,李清平.深水浅层天然气水合物固态流化绿色开采技术.中国海上油气,2014,26:1-7]
    128 Zhou S W,Zhao J Z,Li Q P,et al.Optimal design of the engineering parameters for the first global trial production of marine natural gas hydrates through solid fluidization(in Chinese).Nat Gas Ind,2017,37:1-14[周守为,赵金洲,李清平,等.全球首次海洋天然气水合物固态流化试采工程参数优化设计.天然气工业,2017,37:1-14]
    129 Zhao J Z,Zhou S W,Zhang L H,et al.The first global physical simulation experimental systems for the exploitation of marine natural gas hydrates through solid fluidization(in Chinese).Nat Gas Ind,2017,37:15-22[赵金洲,周守为,张烈辉,等.世界首个海洋天然气水合物固态流化开采大型物理模拟实验系统.天然气工业,2017,37:15-22]
    130 Liu L L.Research on the evolution of phase transition front during gas hydrate dissociation(in Chinese).Dissertation for Doctoral Degree.Beijing:University of Chinese Academy of Sciences,2013[刘乐乐.水合物沉积物中水合物分解相变阵面演化研究.博士学位论文.北京:中国科学院大学,2013]
    131 Zhang X H,Lu X B,Liu L L.Advances in natural gas hydrate recovery methods(in Chinese).Prog Geophys,2014,29:858-869[张旭辉,鲁晓兵,刘乐乐.天然气水合物开采方法研究进展.地球物理学进展,2014,29:858-869]
    132 Li P,Zhang X H,Lu X B,et al.Study on gas hydrate dissociation in small bodies of hydrate-bearing sediments under water-heating condition.In:Proceedings of the Twenty-sixth International Ocean and Polar Engineering Conference.Rhodes,2016.20-24
    133 Zhang X H,Lu X B.A new exploitation method for gas hydrate in shallow stratum:Mechanical-thermal method(in Chinese).Chin J Theor Appl Mech,2016,48:1238-1246[张旭辉,鲁晓兵.一种新的海洋浅层水合物开采法-机械-热联合开采法.力学学报,2016,48:1238-1246]
    134 Zhang X H.Research on the softening and damage of hydrate deposit due to the themal decompositon of hydrates(in Chinese).Dissertation for Doctoral Degree.Beijing:Institute of Mechanics,Chinese Academy of Sciences,2010[张旭辉.水合物沉积层因水合物热分解引起的软化和破坏研究.博士学位论文.北京:中国科学院力学研究所,2010]
    135 Lu X B,Lu L,Zhang X H,et al.Theoretical analysis of gas hydrate dissociation in sediment.In:Zhang L,Goncalves da Silva B,Zhao C,eds.Proceedings of GeoShanghai 2018 International Conference:Rock Mechanics and Rock Engineering.GSIC 2018.Singapore:Springer,2018.109-116
    136 Makogon Y F,Holditch S A,Makogon T Y.Russian field illustrates gas-hydrate production.Oil Gas J,2005,103:43-47
    137 Grover T,Moridis G J,Holditch S A.Analysis of reservoir performance of Messoyakha gas hydrate Field.In:SPE Annual Technical Conference and Exhibition.Denver,2008
    138 Shao M J,Zhang W,Wu X S,et al.Natural gas hydrate exploitation at Messoyakha gas field(in Chinese).Land Resour Inf,2016,12:17-19[邵明娟,张炜,吴西顺,等.麦索亚哈气田天然气水合物开发.国土资源情报,2016,12:17-19]
    139 Kurihara M,Funatsu K,Ouchi H,et al.Analyses of production tests and MDT tests conducted in Mallik and Alaska methane hydrate reservoirs:What can we learn from these well tests?In:Proceedings of the 6th International Conference on Gas Hydrates.Vancouver,2008
    140 Numasawa M,Yamamoto K,Yasuda M,et al.Objectives and operation overview of the 2007 JOGMEC/NRCAN/AURORA Mallik 2L-38 gas hydrate production test.In:Proceedings of the 6th International Conference on Gas Hydrates.Vancouver,2008
    141 Fujii K,Yasuda M,Cho B,et al.Development of a monitoring system for the JOGMEC/NRCAN/AURORA Mallik gas hydrate production test program.In:Proceedings of the 6th International Conference on Gas Hydrates.Vancouver,2008
    142 Fujii T,Takayama T,Nakamizu M,et al.Wire-line logging analysis of the 2007 JOGMEC/NRCAN/AURORA Mallik gas hydrate production test well.In:Proceedings of the 6th International Conference on Gas Hydrates.Vancouver,2008
    143 ConocoPhillips.ConocoPhillips gas hydrate production test.Oil&Natural Gas Technology,Progress report first half 2012,Office of Fossil Energy.Anchorage,2012
    144 ConocoPhillips.ConocoPhillips gas hydrate production test.Oil&Natural Gas Technology,Progress report second half 2011,Office of Fossil Energy,Anchorage,2012
    145 Collett T S,Lewis R E,Winters W J,et al.Downhole well log and core montages from the mount elbert gas hydrate stratigraphic test well,Alaska North Slope.Mar Petgeol,2011,28:561-577
    146 Rose K,Boswell R,Collett T.Mount elbert gas hydrate stratigraphic test well,Alaska North Slope:Coring operations,core sedimentology,and lithostratigraphy.Mar PetGeol,2011,28:311-331
    147 Schultheiss P,Holland M,Roberts J,et al.PCATS:Pressure core analysis and transfer system.In:Proceedings of the 7th International Conference on Gas Hydrates.Edinburgh,2011
    148 Zhang W,Bai F L,Shao M J,et al.Progress of offshore natural gas hydrate production tests in Japan and implications(in Chinese).Marin Geol Quat Geol,2017,37:27-33[张炜,白凤龙,邵明娟,等.日本海域天然气水合物试采进展及其对我国的启示.海洋地质与第四纪地质,2017,37:27-33]
    149 Wu N Y,Huang L,Hu G W,et al.Geological controlling factors and scientific challenges for offshore gas hydrate exploitation(in Chinese).Marin Geol Quat Geol,2017,37:1-11[吴能友,黄丽,胡高伟,等.海域天然气水合物开采的地质控制因素和科学挑战.海洋地质与第四纪地质,2017,37:1-11]
    150 Zhou S W,Chen W,Li Q P,et al.Research on the solid fluidization well testing and production for shallow non-diagenetic natural gas hydrate in deep water area(in Chinese).China Offshore Oil Gas,2017,29:1-8[周守为,陈伟,李清平,等.深水浅层非成岩天然气水合物固态流化试采技术研究及进展.中国海上油气,2017,29:1-8]

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