海泡石吸附混合污染物和气态污染物的研究进展
|
摘要
海泡石是一种具有吸附活性的天然硅酸盐黏土矿物,在水污染、土壤污染、大气污染治理中可作为一种高效吸附剂。本文论述了海泡石的吸附机理,介绍了海泡石吸附混合重金属离子、混合有机染料、重金属与有机物共存等混合污染物和CO2、CH2O、NH3、SO2等有毒有害气体的吸附效果,并展望了今后的研究方向:(1)目前的研究多是基于静态吸附试验,且试验所用废水均为实验室配制的模拟废水,今后应进行动态吸附试验,并以实际废水为研究对象;(2)海泡石经过改性后,可在一定程度上提高吸附容量,今后可继续优化改性剂和改性工艺,从而进一步提高吸附容量;(3)结合各类吸附剂之所长,将海泡石与其他有机、无机或生物材料复合,研制出吸附效果更佳的新型复合吸附剂。
Sepiolite,a natural silicate clay mineral with adsorption activity,is a kind of adsorbent with high efficiency in water pollution,soil pollution and air pollution control.The adsorption mechanism of sepiolite is reviewed,and the effects of sepiolite adsorption on mixed pollutants,such as mixed heavy metal ions,mixed organic dye,coexistence of heave metal and organic dye,and toxic and/or harmful gases,such as carbon dioxide,formaldehyde,ammonia,sulfur dioxide is introduced.The existing problems of sepiolite used as adsorbent for environmental protection are summarized,and the directions for future research direction are prospected.The current research is mainly based on static adsorption tests,and the wastewater used in experiments is simulated wastewater prepared by the laboratory.Dynamic adsorption tests should be carried out in the future,and the actual wastewater should be taken as the research object.After being modified,the adsorption capacity of sepiolite is improved to a certain extent.In the future,the modifier and modification process should be optimized,thus the adsorption capacity can be improved further.Combining with the advantages of all kinds of adsorbent,sepiolite should be combined with other organic,inorganic or biological materials to develop new composite adsorbents with better adsorption effect.
Sepiolite,a natural silicate clay mineral with adsorption activity,is a kind of adsorbent with high efficiency in water pollution,soil pollution and air pollution control.The adsorption mechanism of sepiolite is reviewed,and the effects of sepiolite adsorption on mixed pollutants,such as mixed heavy metal ions,mixed organic dye,coexistence of heave metal and organic dye,and toxic and/or harmful gases,such as carbon dioxide,formaldehyde,ammonia,sulfur dioxide is introduced.The existing problems of sepiolite used as adsorbent for environmental protection are summarized,and the directions for future research direction are prospected.The current research is mainly based on static adsorption tests,and the wastewater used in experiments is simulated wastewater prepared by the laboratory.Dynamic adsorption tests should be carried out in the future,and the actual wastewater should be taken as the research object.After being modified,the adsorption capacity of sepiolite is improved to a certain extent.In the future,the modifier and modification process should be optimized,thus the adsorption capacity can be improved further.Combining with the advantages of all kinds of adsorbent,sepiolite should be combined with other organic,inorganic or biological materials to develop new composite adsorbents with better adsorption effect.
引文
[1]蔡作乾,王琏,杨根.陶瓷材料词典[M].北京:化学工业出版社,2002.
[2]郑水林.非金属矿加工与应用[M].北京:化学工业出版社,2003.
[3] ALKAN M,ELIKAPA S,DEMIRBA爦,et al.Removal of reactive blue 221 and acid blue 62 anionic dyes from aqueous solutions by sepiolite[J].Dyes&Pigments,2005,65(3):251-259.
[4]张永辉.五水硫代硫酸钠/海泡石复合相变储热材料的制备与性能测试[D].西安:西北大学,2017.
[5] GONZLEZ-PRADAS E,SOCAS-VICIANA M,UREAAMATE M D,et al.Adsorption of chloridazon from aqueous solution on heat and acid treated sepiolites[J].Water Research,2005,39(9):1849-1857.
[6] KARA K,YUZER H,SABAH E,et al.Adsorption of cobalt from aqueous solutions onto sepiolite[J].Water Research,2003,37(1):224-232.
[7]李双双,戴友芝,于磊,等.铁改性海泡石除锑的影响因素研究[J].环境工程学报,2009,3(3):485-488.LI Shuangshuang,DAI Youzhi,YU Lei,et al.Study on affecting factors of removing antimony with iron modified sepiolite[J].Chinese Journal of Environmental Engineering,2009,3(3):485-488.
[8] ALKAN M,TEKIN G,NAMLI H.FTIR and zeta potential measurements of sepiolite treated with some organosilanes[J].Microporous&Mesoporous Materials,2005,84(1):75-83.
[9]丁德宝,汤庆国,王菲,等.偶联改性对海泡石粉体表面官能团结构及性能的影响[J].科学技术与工程,2017,17(20):17-22.DING Debao,TANG Qingguo,WANG Fei,et al.Effect of coupling modification on the surface functional group and properties of sepiolite powder[J].Science Technology and Engineering,2017,17(20):17-22.
[10]苏小丽,夏光华,廖润华.有机海泡石的制备及其结构性能的研究[J].陶瓷学报,2010,31(2):310-314.SU Xiaoli,XIA Guanghua,LIAO Runhua.Study on preparation and properties of organic sepiolite[J].Journal of Ceramics,2010,31(2):310-314.
[11]ZDEMIR O,INAR M,SABAH E,et al.Adsorption of anionic surfactants onto sepiolite[J].Journal of Hazardous Materials,2007,147(1-2):625-632.
[12]杨秀敏,乔艳云,李立欣,等.重金属Cu2+、Zn2+、Cd2+在海泡石中的吸附特征[J].黑龙江科技学院学报,2013,23(1):51-54.YANG Xiumin,QIAO Yanyun,LI Lixin,et al.Adsorption characteristic of Cu2+,Zn2+and Cd2+by sepiolite[J].Journal of Heilongjiang Institute of Science&Technology,2013,23(1):51-54.
[13]刘翔.改性海泡石对Cu2+和Zn2+混合溶液吸附效果研究[J].工业安全与环保,2015,41(11):29-32.LIU Xiang.The study on the adsorption effect of modified sepiolite on Cu2+and Zn2+mixed solution[J].Industrial Safety and Environmental Protection,2015,41(11):29-32.
[14]胡忠于,罗道成,易平贵,等.改性海泡石对电镀废水中Pb2+、Cu2+、Cd2+的吸附[J].材料保护,2002,35(5):45-46,53.HU Zhongyu,LUO Daocheng,YI Pinggui,et al.Adsorption of Pb2+,Cu2+,Cd2+in electroplating wastewater by modified meerschaum[J].Materials Protection,2002,35(5):45-46,53.
[15]金胜明,阳卫军,唐谟堂.海泡石表面改性及其应用试验研究[J].非金属矿,2001,24(4):23-24,49.JINShengming, YANGWeijun, TANGMotang.Experimental research on surface modification of sepiolite and its application[J].Non-Metallic Mines,2001,24(4):23-24,49.
[16]李琛,于俊洋.海泡石的改性及其在铅锌冶炼废水处理中的应用[J].科学技术与工程,2013,13(30):9153-9157.LI Chen,YU Junyang.Modification and application of sepiolite inlead and zinc smelter wastewater treatment[J].Science Technology and Engineering,2013,13(30):9153-9157.
[17]余铁萍,戴友芝,王未平,等.磁性海泡石吸附水中重金属离子的特性及机理[J].环境化学,2013,32(8):1566-1570.YU Tieping,DAI Youzhi,WANG Weiping,et al.Adsorption characteristic andmechanismofheavymetalsonto magnetically modified sepiolite[J].Environmental Chemistry,2013,32(8):1566-1570.
[18]林大松,刘尧,徐应明,等.海泡石对污染土壤镉、锌有效态的影响及其机制[J].北京大学学报:自然科学版,2010,46(3):346-350.LIN Dasong,LIU Yao,XU Yingming,et al.Effects of sepiolite on the immobilization of cadmium and zinc in soil[J].Acta Scientiarum Naturalium Universitatis Pekinensis,2010,46(3):346-350.
[19]方至萍,廖敏,张楠,等.施用海泡石对铅、镉在土壤-水稻系统中迁移与再分配的影响[J].环境科学,2017,38(7):3028-3035.FANG Zhiping,LIAO Min,ZHANG Nan,et al.Effect of sepiolite application on the migration and redistribution of Pb and Cd in soil rice system in soil with Pb and Cd combined contamination[J].Environmental Science,2017,38(7):3028-3035.
[20]孙约兵,王朋超,徐应明,等.海泡石对镉-铅复合污染钝化修复效应及其土壤环境质量影响研究[J].环境科学,2014,35(12):4720-4726.SUN Yuebing,WANG Pengchao,XU Yingming,et al.Immobilization remediation of Cd and Pb contaminated soil:remediation potential and soil environmental quality[J].Environmental Science,2014,35(12):4720-4726.
[21]吴玉俊,周航,朱维,等.碳酸钙和海泡石组配对水稻中Pb和Cd迁移转运的影响[J].环境工程学报,2015,9(8):4047-4054.WU Yujun,ZHOU Hang,ZHU Wei,et al.Effects of combined amendment(limestone+sepiolite)on translocation of Pb and Cd in rice[J].Chinese Journal of Environmental Engineering,2015,9(8):4047-4054.
[22]王林,徐应明,孙国红,等.海泡石和磷酸盐对镉铅污染稻田土壤的钝化修复效应与机理研究[J].生态环境学报,2012,21(2):314-320.WANG Lin,XU Yingming,SUN Guohong,et al.Effect and mechanism of immobilization of paddy soil contaminated by cadmium and lead using sepiolite and phosphate[J].Ecology and Environmental Sciences,2012,21(2):314-320.
[23]周歆,周航,曾敏,等.石灰石和海泡石组配对水稻糙米重金属积累的影响[J].土壤学报,2014,51(3):555-563.ZHOU Xin,ZHOU Hang,ZENG Min,et al.Effects of combined amendment(limestone+sepiolite)on heavy metal accumulation in brown rice[J].Acta Pedologica Sinica,2014,51(3):555-563.
[24]何文婷.有机改性海泡石对阴离子染料的吸附试验研究[D].长沙:湖南大学,2014.
[25]李广超.有机改性海泡石对单元与多元阳离子染料体系的吸附研究[D].长沙:湖南大学,2014.
[26]杜婷,戴友芝,王未平,等.磁性海泡石-好氧微生物耦合体系处理苯酚-铬复合废水影响因素研究[J].水处理技术,2012,38(8):92-95.DU Ting,DAI Youzhi,WANG Weiping,et al.Influencing factor on removing of composite wastewater composed by phenol and chromium in the coupling systems of magnetical sepiolite and aerobe[J].Technology of Water Treatment,2012,38(8):92-95.
[27]龚敏,余铁萍,李芬芳,等.TiO2/磁性海泡石光催化处理复合废水性能[J].水处理技术,2015,41(6):43-45,51.GONG Min,YU Tieping,LI Fenfang,et al.Performance of TiO2/magnetic-sepiolite inphotocatalytic treatmentof composite wastewater[J].Technology of Water Treatment,2015,41(6):43-45,51.
[28]龚敏.TiO2/磁性海泡石复合光催化剂制备及其处理Cu(Ⅱ)-EDTA废水[D].湘潭:湘潭大学,2015.
[29]庞湘.有机改性海泡石对阳离子染料与重金属的吸附试验研究[D].长沙:湖南大学,2014.
[30]张华丽,严春杰,周红,等.离子液体改性海泡石及其对二氧化碳的吸附[J].非金属矿,2014,37(2):75-78.ZHANG Huali,YAN Chunjie,ZHOU Hong,et al.Study on CO2adsorption of sepiolite modified by ionic-liquid[J].NonMetallic Mines,2014,37(2):75-78.
[31] IRANI M,FAN M,ISMAIL H,et al.Modified nanosepiolite as an inexpensive support of tetraethylenepentamine for CO2sorption[J].Nano Energy,2015,11:235-246.
[32] SHI J W,LI Y J,ZHANG Q,et al.CO2capture performance of a novel synthetic CaO/sepiolite sorbent at calcium looping conditions[J].Applied Energy,2017,203:412-421.
[33]郑承辉,欧阳静,侯凯,等.β-海泡石提纯与胺基改性及其用作CO2固体吸附剂的研究[J].矿冶工程,2017,37(3):129-132.ZHENG Chenghui,OUYANG Jing,HOU Kai,et al.Investigation on purified and amine-modifiedβ-sepiolite as solid sorbent for CO2[J].Mining and Metallurgical Engineering,2017,37(3):129-132.
[34] CHEN C,PARK D W,AHN W S.Surface modification of a low cost bentonite for post-combustion CO2 capture[J].Applied Surface Science,2013,283(11):699-704.
[35] TANG Z,HAN Z,YANG G,et al.Polyethylenimine loaded nanoporous carbon with ultra-large pore volume for CO2capture[J].Applied Surface Science,2013,277(28):47-52.
[36] LIU J L,LIN R B.Structural properties and reactivities of aminomodified silica fume solid sorbents for low-temperature CO2capture[J].Powder Technology,2013,241(3):188-195.
[37] GUI M M,YAN X Y,CHAI S P,et al.Multi-walled carbon nanotubes modified with(3-aminopropyl)triethoxysilane for effective carbon dioxide adsorption[J].International Journal of Greenhouse Gas Control,2013,14(2):65-73.
[38] NIU M,YANG H,ZHANG X,et al.Amine-impregnated mesoporous silica nanotube as an emerging nanocomposite for CO2capture[J].ACS Applied Materials&Interfaces,2016(8):17312-17320.
[39] ROTH E A,AGARWAL S,GUPTA R K.Nanoclay-based solid sorbents for CO2capture[J].Energy&Fuels,2013,27(8):4129-4136.
[40] BING X,WEI Y,WANG M,et al.Template-free synthesis of nitrogendoped hierarchical porous carbons for CO2adsorption and supercapacitor electrodes[J].Journal of Colloid and Interface Science,2016,488:207-217.
[41]张韬,贺洋.海泡石环境吸附材料制备研究[J].非金属矿,2016,39(4):46-47.ZHANG Tao,HE Yang.Environmental adsorbing material prepared by sepiolite[J].Non-Metallic Mines,2016,39(4):46-47.
[42]易文静,高小红.改性海泡石除甲醛净化剂的研制[J].科技创业月刊,2014,27(2):188-189.YI Wenjing,GAO Xiaohong.Preparation of modified sepiolite formaldehyde removal agent[J].Pioneering with Science&Technology Monthly,2014,27(2):188-189.
[43]周雪,程俊,李珍珍,等.CNTs/TiO2/海泡石多孔光催化复合材料的制备及性能[J].化工新型材料,2014,42(2):44-46.ZHOU Xue,CHENG Jun,LI Zhenzhen,et al.Study on preparation and photocatalytic activity of TiO2/CNTs/sepiolite composite[J].New Chemical Materials,2014,42(2):44-46.
[44]王青,程俊,周雪,等.稀土元素掺杂TiO2/海泡石复合材料的制备及其性能研究[J].化工新型材料,2016,44(5):112-114.WANG Qing,CHENG Jun,ZHOU Xue,et al.Study on preparation and photocatalytic activity of REE doping TiO2/sepiolite composite[J].New Chemical Materials,2016,44(5):112-114.
[45]张春霞,陈平,陈丽英.改性海泡石对NH3吸附特性的研究[J].河南化工,1994(6):9-10.ZHANG Chunxia,CHEN Ping,CHEN Liying.Study on adsorption characteristics of modified sepiolite on NH3[J].Henan Chemical Industry,1994(6):9-10.
[46]王继徽,关影莲,曾乐.海泡石吸附脱除低浓度SO2废气的研究[J].湖南大学学报,1994,21(3):112-116,128.WANG Jihui,GUAN Yinglian,ZENG Le.Study on desulfurization of waste gas with low concentration SO2 by sepiolote as adsorbent[J].Journal of Hunan University,1994,21(3):112-116,128.
[2]郑水林.非金属矿加工与应用[M].北京:化学工业出版社,2003.
[3] ALKAN M,ELIKAPA S,DEMIRBA爦,et al.Removal of reactive blue 221 and acid blue 62 anionic dyes from aqueous solutions by sepiolite[J].Dyes&Pigments,2005,65(3):251-259.
[4]张永辉.五水硫代硫酸钠/海泡石复合相变储热材料的制备与性能测试[D].西安:西北大学,2017.
[5] GONZLEZ-PRADAS E,SOCAS-VICIANA M,UREAAMATE M D,et al.Adsorption of chloridazon from aqueous solution on heat and acid treated sepiolites[J].Water Research,2005,39(9):1849-1857.
[6] KARA K,YUZER H,SABAH E,et al.Adsorption of cobalt from aqueous solutions onto sepiolite[J].Water Research,2003,37(1):224-232.
[7]李双双,戴友芝,于磊,等.铁改性海泡石除锑的影响因素研究[J].环境工程学报,2009,3(3):485-488.LI Shuangshuang,DAI Youzhi,YU Lei,et al.Study on affecting factors of removing antimony with iron modified sepiolite[J].Chinese Journal of Environmental Engineering,2009,3(3):485-488.
[8] ALKAN M,TEKIN G,NAMLI H.FTIR and zeta potential measurements of sepiolite treated with some organosilanes[J].Microporous&Mesoporous Materials,2005,84(1):75-83.
[9]丁德宝,汤庆国,王菲,等.偶联改性对海泡石粉体表面官能团结构及性能的影响[J].科学技术与工程,2017,17(20):17-22.DING Debao,TANG Qingguo,WANG Fei,et al.Effect of coupling modification on the surface functional group and properties of sepiolite powder[J].Science Technology and Engineering,2017,17(20):17-22.
[10]苏小丽,夏光华,廖润华.有机海泡石的制备及其结构性能的研究[J].陶瓷学报,2010,31(2):310-314.SU Xiaoli,XIA Guanghua,LIAO Runhua.Study on preparation and properties of organic sepiolite[J].Journal of Ceramics,2010,31(2):310-314.
[11]ZDEMIR O,INAR M,SABAH E,et al.Adsorption of anionic surfactants onto sepiolite[J].Journal of Hazardous Materials,2007,147(1-2):625-632.
[12]杨秀敏,乔艳云,李立欣,等.重金属Cu2+、Zn2+、Cd2+在海泡石中的吸附特征[J].黑龙江科技学院学报,2013,23(1):51-54.YANG Xiumin,QIAO Yanyun,LI Lixin,et al.Adsorption characteristic of Cu2+,Zn2+and Cd2+by sepiolite[J].Journal of Heilongjiang Institute of Science&Technology,2013,23(1):51-54.
[13]刘翔.改性海泡石对Cu2+和Zn2+混合溶液吸附效果研究[J].工业安全与环保,2015,41(11):29-32.LIU Xiang.The study on the adsorption effect of modified sepiolite on Cu2+and Zn2+mixed solution[J].Industrial Safety and Environmental Protection,2015,41(11):29-32.
[14]胡忠于,罗道成,易平贵,等.改性海泡石对电镀废水中Pb2+、Cu2+、Cd2+的吸附[J].材料保护,2002,35(5):45-46,53.HU Zhongyu,LUO Daocheng,YI Pinggui,et al.Adsorption of Pb2+,Cu2+,Cd2+in electroplating wastewater by modified meerschaum[J].Materials Protection,2002,35(5):45-46,53.
[15]金胜明,阳卫军,唐谟堂.海泡石表面改性及其应用试验研究[J].非金属矿,2001,24(4):23-24,49.JINShengming, YANGWeijun, TANGMotang.Experimental research on surface modification of sepiolite and its application[J].Non-Metallic Mines,2001,24(4):23-24,49.
[16]李琛,于俊洋.海泡石的改性及其在铅锌冶炼废水处理中的应用[J].科学技术与工程,2013,13(30):9153-9157.LI Chen,YU Junyang.Modification and application of sepiolite inlead and zinc smelter wastewater treatment[J].Science Technology and Engineering,2013,13(30):9153-9157.
[17]余铁萍,戴友芝,王未平,等.磁性海泡石吸附水中重金属离子的特性及机理[J].环境化学,2013,32(8):1566-1570.YU Tieping,DAI Youzhi,WANG Weiping,et al.Adsorption characteristic andmechanismofheavymetalsonto magnetically modified sepiolite[J].Environmental Chemistry,2013,32(8):1566-1570.
[18]林大松,刘尧,徐应明,等.海泡石对污染土壤镉、锌有效态的影响及其机制[J].北京大学学报:自然科学版,2010,46(3):346-350.LIN Dasong,LIU Yao,XU Yingming,et al.Effects of sepiolite on the immobilization of cadmium and zinc in soil[J].Acta Scientiarum Naturalium Universitatis Pekinensis,2010,46(3):346-350.
[19]方至萍,廖敏,张楠,等.施用海泡石对铅、镉在土壤-水稻系统中迁移与再分配的影响[J].环境科学,2017,38(7):3028-3035.FANG Zhiping,LIAO Min,ZHANG Nan,et al.Effect of sepiolite application on the migration and redistribution of Pb and Cd in soil rice system in soil with Pb and Cd combined contamination[J].Environmental Science,2017,38(7):3028-3035.
[20]孙约兵,王朋超,徐应明,等.海泡石对镉-铅复合污染钝化修复效应及其土壤环境质量影响研究[J].环境科学,2014,35(12):4720-4726.SUN Yuebing,WANG Pengchao,XU Yingming,et al.Immobilization remediation of Cd and Pb contaminated soil:remediation potential and soil environmental quality[J].Environmental Science,2014,35(12):4720-4726.
[21]吴玉俊,周航,朱维,等.碳酸钙和海泡石组配对水稻中Pb和Cd迁移转运的影响[J].环境工程学报,2015,9(8):4047-4054.WU Yujun,ZHOU Hang,ZHU Wei,et al.Effects of combined amendment(limestone+sepiolite)on translocation of Pb and Cd in rice[J].Chinese Journal of Environmental Engineering,2015,9(8):4047-4054.
[22]王林,徐应明,孙国红,等.海泡石和磷酸盐对镉铅污染稻田土壤的钝化修复效应与机理研究[J].生态环境学报,2012,21(2):314-320.WANG Lin,XU Yingming,SUN Guohong,et al.Effect and mechanism of immobilization of paddy soil contaminated by cadmium and lead using sepiolite and phosphate[J].Ecology and Environmental Sciences,2012,21(2):314-320.
[23]周歆,周航,曾敏,等.石灰石和海泡石组配对水稻糙米重金属积累的影响[J].土壤学报,2014,51(3):555-563.ZHOU Xin,ZHOU Hang,ZENG Min,et al.Effects of combined amendment(limestone+sepiolite)on heavy metal accumulation in brown rice[J].Acta Pedologica Sinica,2014,51(3):555-563.
[24]何文婷.有机改性海泡石对阴离子染料的吸附试验研究[D].长沙:湖南大学,2014.
[25]李广超.有机改性海泡石对单元与多元阳离子染料体系的吸附研究[D].长沙:湖南大学,2014.
[26]杜婷,戴友芝,王未平,等.磁性海泡石-好氧微生物耦合体系处理苯酚-铬复合废水影响因素研究[J].水处理技术,2012,38(8):92-95.DU Ting,DAI Youzhi,WANG Weiping,et al.Influencing factor on removing of composite wastewater composed by phenol and chromium in the coupling systems of magnetical sepiolite and aerobe[J].Technology of Water Treatment,2012,38(8):92-95.
[27]龚敏,余铁萍,李芬芳,等.TiO2/磁性海泡石光催化处理复合废水性能[J].水处理技术,2015,41(6):43-45,51.GONG Min,YU Tieping,LI Fenfang,et al.Performance of TiO2/magnetic-sepiolite inphotocatalytic treatmentof composite wastewater[J].Technology of Water Treatment,2015,41(6):43-45,51.
[28]龚敏.TiO2/磁性海泡石复合光催化剂制备及其处理Cu(Ⅱ)-EDTA废水[D].湘潭:湘潭大学,2015.
[29]庞湘.有机改性海泡石对阳离子染料与重金属的吸附试验研究[D].长沙:湖南大学,2014.
[30]张华丽,严春杰,周红,等.离子液体改性海泡石及其对二氧化碳的吸附[J].非金属矿,2014,37(2):75-78.ZHANG Huali,YAN Chunjie,ZHOU Hong,et al.Study on CO2adsorption of sepiolite modified by ionic-liquid[J].NonMetallic Mines,2014,37(2):75-78.
[31] IRANI M,FAN M,ISMAIL H,et al.Modified nanosepiolite as an inexpensive support of tetraethylenepentamine for CO2sorption[J].Nano Energy,2015,11:235-246.
[32] SHI J W,LI Y J,ZHANG Q,et al.CO2capture performance of a novel synthetic CaO/sepiolite sorbent at calcium looping conditions[J].Applied Energy,2017,203:412-421.
[33]郑承辉,欧阳静,侯凯,等.β-海泡石提纯与胺基改性及其用作CO2固体吸附剂的研究[J].矿冶工程,2017,37(3):129-132.ZHENG Chenghui,OUYANG Jing,HOU Kai,et al.Investigation on purified and amine-modifiedβ-sepiolite as solid sorbent for CO2[J].Mining and Metallurgical Engineering,2017,37(3):129-132.
[34] CHEN C,PARK D W,AHN W S.Surface modification of a low cost bentonite for post-combustion CO2 capture[J].Applied Surface Science,2013,283(11):699-704.
[35] TANG Z,HAN Z,YANG G,et al.Polyethylenimine loaded nanoporous carbon with ultra-large pore volume for CO2capture[J].Applied Surface Science,2013,277(28):47-52.
[36] LIU J L,LIN R B.Structural properties and reactivities of aminomodified silica fume solid sorbents for low-temperature CO2capture[J].Powder Technology,2013,241(3):188-195.
[37] GUI M M,YAN X Y,CHAI S P,et al.Multi-walled carbon nanotubes modified with(3-aminopropyl)triethoxysilane for effective carbon dioxide adsorption[J].International Journal of Greenhouse Gas Control,2013,14(2):65-73.
[38] NIU M,YANG H,ZHANG X,et al.Amine-impregnated mesoporous silica nanotube as an emerging nanocomposite for CO2capture[J].ACS Applied Materials&Interfaces,2016(8):17312-17320.
[39] ROTH E A,AGARWAL S,GUPTA R K.Nanoclay-based solid sorbents for CO2capture[J].Energy&Fuels,2013,27(8):4129-4136.
[40] BING X,WEI Y,WANG M,et al.Template-free synthesis of nitrogendoped hierarchical porous carbons for CO2adsorption and supercapacitor electrodes[J].Journal of Colloid and Interface Science,2016,488:207-217.
[41]张韬,贺洋.海泡石环境吸附材料制备研究[J].非金属矿,2016,39(4):46-47.ZHANG Tao,HE Yang.Environmental adsorbing material prepared by sepiolite[J].Non-Metallic Mines,2016,39(4):46-47.
[42]易文静,高小红.改性海泡石除甲醛净化剂的研制[J].科技创业月刊,2014,27(2):188-189.YI Wenjing,GAO Xiaohong.Preparation of modified sepiolite formaldehyde removal agent[J].Pioneering with Science&Technology Monthly,2014,27(2):188-189.
[43]周雪,程俊,李珍珍,等.CNTs/TiO2/海泡石多孔光催化复合材料的制备及性能[J].化工新型材料,2014,42(2):44-46.ZHOU Xue,CHENG Jun,LI Zhenzhen,et al.Study on preparation and photocatalytic activity of TiO2/CNTs/sepiolite composite[J].New Chemical Materials,2014,42(2):44-46.
[44]王青,程俊,周雪,等.稀土元素掺杂TiO2/海泡石复合材料的制备及其性能研究[J].化工新型材料,2016,44(5):112-114.WANG Qing,CHENG Jun,ZHOU Xue,et al.Study on preparation and photocatalytic activity of REE doping TiO2/sepiolite composite[J].New Chemical Materials,2016,44(5):112-114.
[45]张春霞,陈平,陈丽英.改性海泡石对NH3吸附特性的研究[J].河南化工,1994(6):9-10.ZHANG Chunxia,CHEN Ping,CHEN Liying.Study on adsorption characteristics of modified sepiolite on NH3[J].Henan Chemical Industry,1994(6):9-10.
[46]王继徽,关影莲,曾乐.海泡石吸附脱除低浓度SO2废气的研究[J].湖南大学学报,1994,21(3):112-116,128.WANG Jihui,GUAN Yinglian,ZENG Le.Study on desulfurization of waste gas with low concentration SO2 by sepiolote as adsorbent[J].Journal of Hunan University,1994,21(3):112-116,128.
© 2004-2018 中国地质图书馆版权所有 京ICP备05064691号 京公网安备11010802017129号 地址：北京市海淀区学院路29号 邮编：100083 电话：办公室：(+86 10)66554848；文献借阅、咨询服务、科技查新：66554700 |