用户名: 密码: 验证码:
纳米硫化物的制备方法及其优缺点
详细信息    本馆镜像全文|  推荐本文 |  |   获取CNKI官网全文
摘要
综述了近年来纳米的制备技术及其材料的研究与应用进展,硫化镉纳米材料具有许多特异的性质,其合成方法研究近年来受到人们的青睐。硫化镉纳米材料的制备方法有固相法、液相法和气相法,对这些方法进行了综述,并展望了硫化镉纳米材料合成技术的发展前景。认为纳米高分子材料具有含量可控、稳定性好、表面可修饰、光学性能好等优点,在光、电、传感、催化等领域有良好的发展前景,有待于深入研究。
     硫化锌是一种重要的宽带隙半导体材料,因其特殊的光电性质已引起制备领域的关注。纳米硫化锌具有许多特异的光电性能,对其制备方法的研究越来越引起人们的重视。详细介绍了制备纳米硫化锌颗粒的固相法、液相法、气相法等不同方法并比较了它们的优缺点,结合纳米硫化锌材料的实际应用选用不同的制备方法,必将进一步推动纳米硫化锌的开发研究。
The latest technologies of prepration for nanomaterial CdS and application to the materials were summarized. The synthesis of CdS nanomaterials with unique properties has attracted much greater attention in recent years. The nanomaterials of CdS are synthesized by different methods, such as solid, liquid and gas phase reactions. These synthesis methods are reviewed in this paper. It is predicted that nanomaterials method of CdS will become a tendency in future. It′s believed that nano CdS-polymer fluorescent materials can be used in the fields of light, electricity, sensor and photocatalyst due to their performances such as the controlled content, stability, modifiable surface and excellent optical capability and so on, The materials should be studied futher to be realized their applied potential.
     Zinc sulfide, an important wide band-gap semiconductor, has attracted much attention owing to its wide applications. The preparation of ZnS nanoparticles with unique electrical and optical properties has attracted much greater attention in recent years. The nanoparticles of ZnS are prepared by different methods, such as solid, liquid and gas phase reactions. Every preparation method has its own advantages and disadvantages, and all are reviewed in this thesis. The right method can be selected depending on the applications of ZnS nanoparticles in practice, which, on the other hand, will promote the research on ZnS nanoparticles preparation.
引文
[1]张立德,牟季美. 纳米材料和纳米结构[M] 北京:科学出版社,2002.21-24.
    [2]刘吉平,廖莉玲. 无机纳米材料[M] 北京:科学出版社,2003.15-16.
    [3]黄德欢. 纳米技术与应用[M] 上海:中国纺织大学出版社,2001.54-57.
    [4]张志琨,崔化林. 纳米技术与纳米材料[M] 北京:国防工业出版社, 2000.78-83
    [5]Eychmuller A . Structure and Photophysics of Semiconductor Nanocrystals, J Phy chem B, 2000,104:6514-6528
    [6]Zangling,LiuChunyuan,ZhaoJincai,et al. Synthesisof semiconductor namoparticles in reverse micelles and microheterogenous electron-tranfer from pyrene to these particles[J] Photographic Science and Photochemistry,1996,14(4): 331-340.
    [7]Pileni M P,Motte L,Billoudet F,et al. Nanosized silver sulfide particles: Characterization self-organization into 2D and 3D superlattices [J]. Materials Lett,1997,31:255-260
    [8]李守田,赵家龙,邹炳锁,等. 微乳状液中 CdS 超微粒制备与光学性质研究[J]. 半导体学报,1993,14(3):143-147.
    [9]LinSongli,ShiMeijiang,ZhuLiangdu,et al. Studies of nanoparticulate cadmium sulfide in amphiphilic polymaleic acid octadecanol ester Langmuir-Blodgett films[J]. Supramolecular Science,1998,5: 475-478.
    [10]HerroN,WangY,Eddy M M,et al. Structure and optical-properties of CdS supercluster in Zeolite Hosts [J]. J Am.Chem.Soc.,1989,111:530-540.
    [11]ZhengMaojun,ZhangLide,ZhangXinyi,et al. Fabrication-andoptical absorption of ordered indium oxide nanowire arrays embedded in alumina membranes [J]. Chemical Physics Lett.2001,334: 298-302.
    [12]徐大鹏,徐正. CdS 纳米管有序阵列的制备和表征[J]. 无机化学学报,2002,18(9):871-873.
    [13]Facci P,Erokhin V,Nicolini C. Formation and characterization of an ultrathin semiconductor polycrystal layer for transducer applications [J]. Biosensors and Bioelectronics,1997,12(7):607-611.
    [14]Yang X M,Wang G M,Lu Z H. Characterization of CdS nanoparticles formed and aggregated instearicacid Langmuir 2Blodgett films by atomic force microscopy[J]. Supramocular Science,1998,5:549-552.
    [15]PanZhiyu,PengXiaogang,LiTijin,et al. Controlled growth of thesize~quantized CdS at the interface of thestearic acid Langmuir lodgettfilms [J]. Appl.SurfaceScience,1997,108:439-447.
    [16]MoriguchiI,NiiH,HanaiK,et al. Synthesis of size confined metal sulfides in Langmuir-Blodgett films[J].Colloids and Surfaces A,1995,103:173-181.
    [17]平贵臣,杜滨阳,王丽颖,等. CdS 纳米微粒有序组装体系的制备与结构研究[J]. 光散射学报,2000,12(2):66-70.
    [18]倪永红,葛学武,刘华蓉,等. 硫化银纳米晶的 C 射线制备[J]. 高等化学学报,2002,23(2):176-178.
    [19]牛今书,刘艳丽,徐甲强. 室温固相合成纳米 ZnS 及其气敏性能研究[J]. 无机材料学报,2002,17(4):817-821.
    [20]李文戈,戴洁,卞国庆,等. 合成 CdS 纳米材料的新方法[J]. 化学世界,2002,(1):13-15.
    [21]娄向东,贾晓华,王晓兵. 纳米材料 CdS 的制备及气敏性研究[J]. 传感器技术,2005,24(8):22-24.
    [22]曹洁明,房宝青,刘劲松,等. 微波固相反应制备 CdS 纳米粒子[J]. 无机化学学报,2005,21(1):105-108.
    [23]张俊松,马娟,周益明,等. 低温固相反应法合成水分散性 CdS 纳米晶[J] 无机化学学报,2005,21(2):295-297.
    [24]唐文华,蒋天智,文正康,等.纳米硫化镉的低温固相合成[J]. 黔东南民族师范高等专科学校学报 2005,23(6):14-15.
    [25]刘辉,李文友,尹洪宗,等.CdS 纳米粒子制备的影响因素及 CdS 纳米粒子的酚藏红花体系的光谱特性[J]. 化学学报,2005,63(4):301-306.
    [26]苏凌浩,张校刚. 脲酶诱发均匀沉淀法室温制备纳米[J]. 功能材料与器件学报,2005,11(3):273-276.
    [27]俞英,周震涛. 核壳纳米晶二硒化镉/硫化镉的合成及荧光法测定溶菌酶[J]. 分析化学,2005,33(5):650-652.
    [28]张言波,邵华峰,钱雪峰,等.单分散球形硫化镉粒子的制备及其形貌控制[J].无机材料学报,2005,20(3):575-579.
    [29]彭小雷,桑文斌,等. CdS 纳米微晶在 PAN 膜中的形成与特性 稀有金属,1999,23(5):321
    [30]Yang Jianjun,Jin Zhensheng,et al. Chemical Researches,1998,9(1):17
    [31]钟淮真,李国强,何晓云,等. 有机溶剂热生长技术制备及其与聚苯胺复合膜的光学性质[J]. 发光学报,2004,25(5):585-590.
    [32]高宁,郭范,郑伟威,等. 六方柱与六角片状 CdS 晶体的水热法生长[J]. 人工晶体学报,2005,34(4):633-636.
    [33]Ming chen,Lijia Pan,Jieming Cao, etal. Synthesis of CdS nanoplates by PAA-assisted hydrothermal approach[J]. Materials Letter 2006,60:3842-3845.
    [34]聂秋林,袁求理,徐铸德. 单齿络合剂辅助水热合成 CdS 纳米棒[J]. 无机材料学报,2004,19(6):1411-1414.
    [35]孙景志,曹健,李寒莹,等. CdS 纳米棒/酞箐氧钛复合光导体的光电导性能[J]. 高等学校化学学报,2005,26(9):1722-1725.
    [36]杜娟,李越湘,彭绍琴,等. 用水热、溶剂热方法制备纳米 CdS 粒子及其光催化性能[J].功能材料,2005,36(10):1603-1606.
    [37]聂秋林,袁求理,徐铸得,等. 水热合成 CdS 纳米晶体的形貌控制研究[J]. 物理化学学报,2003,19(12):1138-1142.
    [38]a.Qi L,Ma J,Cheng H,et al,Reverse Micelle Based Formation of BaCO3 Nanowires, J.Phys.Chem,B,1997,101:3460-3463.b.Hopwood J D,Mann S, Synthesis of Barium Sulfate Nanoparticles and Nanofilaments in Reverse Micelles and Microemulsions,.Chem.Mater,1997,9:1819-1828.
    [39]张鹏,高濂,等. 水热微乳液法合成硫化镉纳米棒晶[J]. 无机材料学报,2003,18(4):772-776.
    [40]臧金鑫,赵高凌,韩高荣,等.CdS 纳米粒子的水热微乳法制备[J]. 无机化学学报,2006,22(5):917-920.
    [41]容敏智,章明秋,梁海春,等. 原位表面修饰纳米 CdS 粒子的表面结构和光学性能[J]. 材料研究学报,2004,18(4):343-350.
    [42]张颖,房喻,林书玉,等. 纳米结构型 PMAA/CdS 复合微球的微凝胶模板法制备研究[J]. 物理化学学报,2004,20(专刊):897-901.
    [43]陈锋,朱依萍,马宏燎,等. TiO2-CdS-MCM-41 复合纳米材料的合成和表征[J]. 物理化学学报,2004,20(11):1292-1296.
    [44]李平,刘梅川,张成林,等. 聚乙烯吡咯烷酮/硫化镉量子点修饰电极的制备及其对血红蛋白的测定研究[J]. 化学学报,2005,63(12):1075-1080.
    [45]张俊松,马娟,曹志坚,等. 8-羟基喹啉修饰玻璃基质中 CdS 纳米粒子的制备及性质[J].南京师范大学学报,2005,28(2):64-66.
    [46]张宇,张俊祥,等.用硫脲分子表面修饰的 CdS 纳米粒子的合成和表征 无机化学学报,1999.15(5):595
    [47]崔玉民,范少华. Cd/CdS 光催化降解甲基橙的研究[J]. 功能材料,2005,36(6):859-861.
    [48]廖学红,杨水彬,陈年友,等. CdS 纳米粒子的合成方法[J].材料与结构,2003,9:44-46.
    [49]王峰. 辐射法制备具有核壳结构的 CdS/PSt 纳米复合微球[J]. 安徽建筑工业学院学报(自然科学版),2005,13(5):81-83.
    [50]a. Martin C R. nanomaterials - a membrane-based synthetic approach, Science,1994,266:1961 b. Kyotani T,Tsai L,Tomita A. Formation of platinum nanorods and nanoparticles in uniform carbon nanotubes prepared by a template carbonization method,Chem Commun,1997,(7):701 c.endler J H,Meldrum F C. The Colloid Chemical Approach to Nanostructured Materials, Adv Mater 1995,(7):607
    [51]Geoffrey A Ozin. Nanochemistry: Synthesis in diminishing dimensions, Adv Mater,1992,4(10):612
    [52]翟庆洲,蔡建岩,于淼,等. 沸石 Y 用于组装纳米 CdS[J]. 稀有金属材料与工程,2006,35(1):146-149.
    [53]王强,赵军钗,蒋世春,等. 模板法室温合成 CdS 纳米棒[J]. 应用化学,2006,23(1):7-11.
    [54]潘志宇,等. 气——液界面 Q-态 CdS 的生长仪器仪表学报,1996,17(1):150
    [55]孙聆东,徐波,等. 聚合物为模板制备 CdS,ZnS 及其掺杂纳米材料 中国科学(B 辑),2001.31(2):146
    [56]于广友,范希武,等.在 SiO2 分子筛内 CdS 纳米晶的内延生长及特性研究 发光学报,1997,18(2):182
    [57]程光伟,陈邦林,等.凝胶网格法制备 CdS 超细颗粒 华东师范大学学报(自然科学版),1999,(4):57
    [58]刘春霞,严文,范新会,等. 用热蒸发法制备 CdS 纳米带[J]. 材料科学与工程学报,2005,23(1):102-104.
    [59]于灵敏,范新会,刘春霞,等. 外加电场对硫化镉晶须生长的影响研究[J]. 材料科学与工程学报,2004,22(3):414-416.
    [60]Liema N Q,Quann V X, Thanha D X, et al. Temperature dependence of biexciton luminescence in cubic ZnS single crystals[J].Solid State Communications,2001,117:255-259
    [61]匡汉茂,邓兆祥,李春辉,等.CdS/MS(M=Ag,Pb,Cu,Zn)半导体纳米复合结构的制备[J] 无机化学学报,2002,18(2):133.
    [62]Sun X L,Hong C Y. Preparing nano-ZnS by solid state reaction at room temperature Chin Chem Lett[J],2001,12(2):187.
    [63]Tsuzuki T,Ding J,Mechanochemical synthesis of ultrafine zinc sulfide particles, Mccormick P G.PhysicaB[J],1997,239:378.
    [64]马国峰,邵忠宝,姜涛,等. 室温固相合成纳米硫化锌及其性能研究[J]. 有色金属,2004,20(6):34-37.
    [65]Hirai T,Sato H,Komasaw I. Mechanism of formation of Cds and Zns ultrafine particles in reverse micelles,Ind Eng Chem Res[J],1994,33(12):3262.
    [66]成国祥,沈锋,姚康德,等.反相胶束微反应器特性与 ZnS 纳米微粒制备 功能材料[J],1998,29(2):183.
    [67]刘红华. 反胶束法制备纳米硫化锌微粒及其润滑性能[J]. 润滑与密封,2006,8:122-123.
    [68]曾贵玉,聂福德,尹莉莎,等. 硫化锌纳米粒子的乳液合成 化学研究与应用[J],2001,13(4):442.
    [69]Ma J,Huang X,ChengH,et al. Preparation of nanosized ZnS particles in water/oil emulsions by microwave heating ,J Mater Sci[J],1996,15:1247.
    [70]黄宵滨,马季铭,程虎民,等. 乳状液法制备 ZnS 纳米粒子 应用化学[J],1997,14(1):117.
    [71]Qian Y T,Su Y,Chen Q W,et al. Hydrothermal preparation and characterization of nanocrystalline powder of sphalerite[J]. Mater Res Bull,1995,30(5):601-605.
    [72]郭广生,刘颖荣,王志华,等. 单分散 ZnS 颗粒制备参数的研究[J]. 北京化工大学学报,2000,27(2):56-58.
    [73]Li J P,Xu Y,Wu D,et al . Hydrothemal synthesis of novel sandwich-like structure ZnS/octylamine hybrid nanosheets[J]. SolidState Communicationn,2004,130(9):619-622.
    [74]Huang F,Zhang H Z,Banfield J F. The role of oriented attachment crystal growth in hydrothermal coarsening of nanocrystalline ZnS[J]. J Phy Chem B,2003,107(38):10470-10475.
    [75]李兰英,郭峰,古国华,等. 水热法制备军分散的硫化锌纳米晶聚集体[J]. 青岛科技大学学报,2005,26(3):211-214.
    [76]杨富国,朱琼霞,方 正. 快速均匀沉淀法制备纳米微粒 ZnS 中南工业大学学报[J]. 2001,32(3):270.
    [77]王鹏飞,奚军,刘华,等. 利用热处理方法制备纳米硫化锌晶体[J]. 技术进步,2003,3:21-22.
    [78]王大文,刘延秋,徐广智,等. 纳米尺寸 ZnS 胶体颗粒结构状态的 STM 研究 科学通报[J].1994,36(16):1489.
    [79]Thomas B,Abdulkhadar M,Elasticproperties of consolidated nano-particles of ZnS and CdS. Solid State Communi cations [J]. 1995,94 (3):205-210
    [80]Xu J F,JI W,Lin J Y,et al. Preparation of ZnS nanoparticles by ultrasonic radiation method, Appl Phys A[J]. 1998,66:639.
    [81]Xu J F,JI W.J Characterization of ZnS nanoparticles prepared by new route, Mater SciLett[J]. 1999,18:115.
    [82]Antony A,Murali K V,Manoj R,et al. [J]. The effect of the pH value on the growth and properties of chemical-bath-deposited ZnS thin films .Materials Chemistryand Physics,2005,90:106-110.
    [83]Makhova LV,Konovalov I,Szargan R,et al. [J].Physica Status Solidi(c),2005,2(3):1206-1211.
    [84]Zhai R,Wang S B,Xu H Y,et al. Rapid formation of CdS, ZnS thin films by microwave-assisted chemical bath deposition [J]. Materials Letters,2005,59:1497-1501.
    [85]Zhang Y N,Raman N,Bailey J K,et al. A new Sol-Gel route for the preparatlon of nanometer-scale semiconductor particles:that exhibit quantum optical behavior, J Phys Chem[J].1992,96(23):9098.
    [86]Yang Y,Hang J M,Liu S Y,et al. Preparation, characterization and electroluminescence of ZnS nanocrystals in a polymer matrix, J Mater Chem[J]. 1997,7(1):131.
    [87]Guiton T A,Czekaj C L,Pantano C G. Organometallic sol/gel chemistry of metal sulfides,J Non-Cryst Solids [J]. 1990,121(1-3):7.
    [88]Haggata S W,LI X C,David J,et al. Synthesis and characterization of II–VI semiconductor nanoparticulates by the reaction of a metal alkyl polymer adduct with hydrogen sulfide, J Mater Chem[J],1996,6(11):1771.
    [89]Maity R,Chattopadhyay K K.[J]. Synthesis and optical characterization of ZnS and ZnS : Mn nanocrystalline thin films by chemical route, Nanotechnology,2004,15:812-816.
    [90]Wang X D,Gao P X,Li J,et al. Rectangular Porous ZnO-ZnS Nanocables and ZnS Nanotubes, [J].Advanced Materials,2002,14(23):1732-1735.

© 2004-2018 中国地质图书馆版权所有 京ICP备05064691号 京公网安备11010802017129号

地址:北京市海淀区学院路29号 邮编:100083

电话:办公室:(+86 10)66554848;文献借阅、咨询服务、科技查新:66554700