PVAc/OMMT纳米复合材料的制备与表征
摘要
聚乙酸乙烯酯(PVAc)是由乙酸乙烯酯(VAc)通过乳液聚合而得的无定形聚合物,属于热塑性树脂,其线型大分子链可以插入进有机蒙脱土(OMMT)晶片层间,从而得到剥离型PVAc/OMMT纳米复合材料。为此,在实验室常规条件下,采用不同工艺通过乳液聚合法制备PVAc/OMMT纳米复合材料,并采用X-射线衍射(XRD)、傅里叶变换红外光谱(FTIR)、动态力学分析(DMA)和热重-差热(TG-DTA)法对其进行表征,同时根据Agrawal积分方程解析其玻璃化转变、冷结晶和热动力学。
研究内容为：
(1) PVAc的制备与表征。
(2) OMMT的制备与表征。
(3) PVAc/OMMT的制备与表征。
研究结果为：
(1)在实验室常规条件下,采用不同工艺通过乳液聚合法制备PVAc/OMMT纳米复合材料是切实可行的。
(2) PVAc线型大分子链能在OMMT层间形成,OMMT被剥离成片层结构或片状的纳米粒子,呈无序状态分散在PVAc基体聚合物中,从而得到剥离型PVAc/OMMT纳米复合材料。
(3) OMMT与PVAc之间是物理作用,由于基体聚合物PVAc相似甚至相同,采用不同工艺合成的PVAc/OMMT的分子结构基本一致；PVAc与PVAc/OMMT的玻璃化转变动力学虽有不同,其冷结晶动力学和热动力学却基本一致。
Polyvinyl acetate (PVAc) is an amorphous polymer prepared by emulsion polymerization from vinyl acetate (VAc). It is a thermoplastic resin. Its linear macromolecular chain can intercalate into the layers of organic montmorillionite (OMMT). The exfoliated nano composite of PVAc/OMMT can be obtained. Therefore, PVAc/OMMT was prepared by emulsion polymerization with different processes under normal condition in laboratory, and characterized by X-ray diffraction (XRD), fourier transform infrared spectroscopy (FTIR), dynamic mechanical analysis (DMA), thermo gravimetry and differential thermal analysis (TG-DTA). Moreover, the glass transition, cold crystal and pyrolysis kinetics were found by Agrawal integral equation.
The main content were as follows:
(1) Preparation and characterization of PVAc.
(2) Preparation and characterization of OMMT.
(3) Preparation and characterization of PVAc/OMMT.
The main results were as follows:
(1) Under normal condition, the exfoliated nano composite of PVAc/OMMT could be prepared by emulsion polymerization with different processes in laboratory.
(2) The linear macromolecular chain of PVAc could be formed in the layers of OMMT. OMMT could be exfoliated into nano particles of layers or sheets, and then dispersed in the matrix of PVAc with random state. The exfoliated nano composite of PVAc/OMMT could be obtained.
(3) OMMT and PVAc were bonded by physical interaction. Because the matrix of PVAc was the same or nearly the same, the molecular structure of PVAc/OMMT synthesized by different processes was nearly the same, too. The glass transition kinetics of PVAc and PVAc/OMMT were found that different, but nearly the same of that of cold crystal and pyrolysis kinetics.
研究内容为：
(1) PVAc的制备与表征。
(2) OMMT的制备与表征。
(3) PVAc/OMMT的制备与表征。
研究结果为：
(1)在实验室常规条件下,采用不同工艺通过乳液聚合法制备PVAc/OMMT纳米复合材料是切实可行的。
(2) PVAc线型大分子链能在OMMT层间形成,OMMT被剥离成片层结构或片状的纳米粒子,呈无序状态分散在PVAc基体聚合物中,从而得到剥离型PVAc/OMMT纳米复合材料。
(3) OMMT与PVAc之间是物理作用,由于基体聚合物PVAc相似甚至相同,采用不同工艺合成的PVAc/OMMT的分子结构基本一致；PVAc与PVAc/OMMT的玻璃化转变动力学虽有不同,其冷结晶动力学和热动力学却基本一致。
Polyvinyl acetate (PVAc) is an amorphous polymer prepared by emulsion polymerization from vinyl acetate (VAc). It is a thermoplastic resin. Its linear macromolecular chain can intercalate into the layers of organic montmorillionite (OMMT). The exfoliated nano composite of PVAc/OMMT can be obtained. Therefore, PVAc/OMMT was prepared by emulsion polymerization with different processes under normal condition in laboratory, and characterized by X-ray diffraction (XRD), fourier transform infrared spectroscopy (FTIR), dynamic mechanical analysis (DMA), thermo gravimetry and differential thermal analysis (TG-DTA). Moreover, the glass transition, cold crystal and pyrolysis kinetics were found by Agrawal integral equation.
The main content were as follows:
(1) Preparation and characterization of PVAc.
(2) Preparation and characterization of OMMT.
(3) Preparation and characterization of PVAc/OMMT.
The main results were as follows:
(1) Under normal condition, the exfoliated nano composite of PVAc/OMMT could be prepared by emulsion polymerization with different processes in laboratory.
(2) The linear macromolecular chain of PVAc could be formed in the layers of OMMT. OMMT could be exfoliated into nano particles of layers or sheets, and then dispersed in the matrix of PVAc with random state. The exfoliated nano composite of PVAc/OMMT could be obtained.
(3) OMMT and PVAc were bonded by physical interaction. Because the matrix of PVAc was the same or nearly the same, the molecular structure of PVAc/OMMT synthesized by different processes was nearly the same, too. The glass transition kinetics of PVAc and PVAc/OMMT were found that different, but nearly the same of that of cold crystal and pyrolysis kinetics.
引文
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