流变学方法研究无水氯化铝原位催化增容聚丙烯/聚苯乙烯合金体系
|
摘要
聚丙烯(PP)和聚苯乙烯(PS)都是重要的通用热塑性塑料品种,原料来源丰富,合成工艺成熟,且性能互补性强,分子结构中都没有典型的其它元素如N、P、S等,有很好的环保潜质,在汽车、电器、包装及日用品工业等诸多领域应用广泛,若能通过界面增容实现PP、PS优势互补,集中两者优良性能于一体,将在各应用领域相对其它聚合物材料品种具有很强竞争力。
本文选用典型路易斯酸无水氯化铝(AlCl_3)作为催化剂,利用烷基化反应机理,对PP/PS合金直接进行原位催化反应增容,以流变学方法(包括静态流变和动态流变学方法)为主,详细探讨无水AlCl_3对PP/PS合金体系中PP和PS两组分的影响,并在此基础上进一步系统研究无水AlCl_3原位催化增容PP/PS合金的相结构演变及增容反应特征,然后对不同原位催化增容条件下获得增容合金材料的流变行为特征作了深入探讨。
结果表明,在熔融共混条件下,无水AlCl_3对PP和PS有一定催化降解作用,并可分别在PP和PS中形成C-O-C结构和PS-AlCl_3复合物结构,进而对其流变性能产生复杂影响。无水AlCl_3对PP/PS合金具有原位催化增容作用,产生的PP-g-PS接枝共聚物可在合金相界面处形成具有一定厚度的界面层,且增容作用和PP/AlCl_3和PS/AlCl_3组分的粘度比变化共同影响增容合金相结构的演变,由此产生相界面的大小及同时形成PP碳正离子浓度大小,共同对增容反应产生影响。据线性加和规则,PP/PS合金及增容合金的粘度或模量可分别归结为组分的贡献、几何相结构的贡献及界面粘结作用的贡献,由此可计算原位增容反应引起体系界面粘结作用的大小,所得结果与界面层厚度的演变规律一致。
在熔融共混条件下,研究无水AlCl_3对PP/PS/AlCl_3原位催化增容合金中PP、PS组分的影响,进而对增容体系相结构演变、增容反应特征、流变学特征展开研究,有助于深入理解其反应增容机理,阐释增容合金体系的结构与性能特征,进而合理优化PP/PS合金原位催化增容技术,推进相关高性能合金材料的研发。
Polypropylene (PP) and polystyrene (PS) are two of the most important thermoplastics because of their abundant resources and convenient industrial production. PP and PS have different merits which are complementary, and in their molecular chains the elements of N, P, and S are all invisible. So PP/PS blends can be widely used in mobiles, electronics, packaging fields, and so on, with precious environmental potentials. And furthermore, if the interfacial adhesion can be improved by compatibilization, the obtained PP/PS alloys would be much more competitive compared with other polymer materials.
In this paper, as a typical lewis acid, anhydrous aluminum (AlCl_3) was used as the catalyst to get PP/PS blends compatibilized by in-situ Fridel-Crafts alkylation. The effects on PP and PS components of AlCl_3 were investigated first, mainly by rheology, including steady rheology method and dynamic rheology method. Then the in-situ reactions in PP/PS alloys under different conditions were executed and studied in detail by selective Soxhlet solvent extraction. And at the same time, the evolutions of phase structures of PP/PS and the resulted PP/PS/AlCl_3 alloys were investigated by SEM(Scanning electric morphology) and SALS(Small angle laser scattering). The steady and dynamic rheological behaviors of in-situ compatibilized PP/PS alloys were obtained systematically.
The results showed that, under melt mixing conditions, PP or PS degradation would take place catalyzed by AlCl_3, but not very seriously with lower AlCl_3 content. And at the same time, C-O-C structure and PS-AlCl_3 complex would be formed in PP/AlCl_3 and PS/AlCl_3, respectively, resulted in complex rheological behaviors of systems. In-situ compatibilized reaction of Fridel-Craft alkylation in PP/PS/AlCl_3 alloys catalyzed by AlCl_3 may form PP-g-PS copolymer distributed in interfacial surfaces as interfacial layer with a certain depth. The effects of compatibilization and the ratio of viscosities of PP/AlCl_3 and PS/AlCl_3 determined the evolution of phase structures of PP/PS/AlCl_3, together. And the compatibilization reaction was influenced by the area of interfacial surfaces and the concentration of PP+ ion in the reactive system. According to log-linearly additivity method, storage modulus, loss modulus, complex modulus and complex viscosity of PP/PS alloys or compatibilized PP/PS/AlCl_3 alloys could be divided into three parts, including contribution of components, contribution of geometrical phase structure, and contribution of the interfacial adhesion of phases. Thus the contribution of PP or PS component and contribution of geometrical phase structure could be separated away and contribution of interfacial adhesion of in-situ compatibilization could be calculated out. The dependence of interfacial adhesion on compositions calculated from static rheology and dynamic rheology, especially, was the same to the dependence of PP-g-PS yield determined by soxhlet extracted method, and also was the same to the dependence of interfacial layer thickness d obtained by SALS.
Investigations on the influences of AlCl3 on PP and PS under melt mixing conditions and on the resulted phase structure evolutions, reactive characteristics, and rheological properties of PP/PS/AlCl3 alloys were helpful to understand the reactive mechanism, to explain the characteristic structure and property changes of alloys, and to prepare better PP/PS alloys with competitive potentials.
本文选用典型路易斯酸无水氯化铝(AlCl_3)作为催化剂,利用烷基化反应机理,对PP/PS合金直接进行原位催化反应增容,以流变学方法(包括静态流变和动态流变学方法)为主,详细探讨无水AlCl_3对PP/PS合金体系中PP和PS两组分的影响,并在此基础上进一步系统研究无水AlCl_3原位催化增容PP/PS合金的相结构演变及增容反应特征,然后对不同原位催化增容条件下获得增容合金材料的流变行为特征作了深入探讨。
结果表明,在熔融共混条件下,无水AlCl_3对PP和PS有一定催化降解作用,并可分别在PP和PS中形成C-O-C结构和PS-AlCl_3复合物结构,进而对其流变性能产生复杂影响。无水AlCl_3对PP/PS合金具有原位催化增容作用,产生的PP-g-PS接枝共聚物可在合金相界面处形成具有一定厚度的界面层,且增容作用和PP/AlCl_3和PS/AlCl_3组分的粘度比变化共同影响增容合金相结构的演变,由此产生相界面的大小及同时形成PP碳正离子浓度大小,共同对增容反应产生影响。据线性加和规则,PP/PS合金及增容合金的粘度或模量可分别归结为组分的贡献、几何相结构的贡献及界面粘结作用的贡献,由此可计算原位增容反应引起体系界面粘结作用的大小,所得结果与界面层厚度的演变规律一致。
在熔融共混条件下,研究无水AlCl_3对PP/PS/AlCl_3原位催化增容合金中PP、PS组分的影响,进而对增容体系相结构演变、增容反应特征、流变学特征展开研究,有助于深入理解其反应增容机理,阐释增容合金体系的结构与性能特征,进而合理优化PP/PS合金原位催化增容技术,推进相关高性能合金材料的研发。
Polypropylene (PP) and polystyrene (PS) are two of the most important thermoplastics because of their abundant resources and convenient industrial production. PP and PS have different merits which are complementary, and in their molecular chains the elements of N, P, and S are all invisible. So PP/PS blends can be widely used in mobiles, electronics, packaging fields, and so on, with precious environmental potentials. And furthermore, if the interfacial adhesion can be improved by compatibilization, the obtained PP/PS alloys would be much more competitive compared with other polymer materials.
In this paper, as a typical lewis acid, anhydrous aluminum (AlCl_3) was used as the catalyst to get PP/PS blends compatibilized by in-situ Fridel-Crafts alkylation. The effects on PP and PS components of AlCl_3 were investigated first, mainly by rheology, including steady rheology method and dynamic rheology method. Then the in-situ reactions in PP/PS alloys under different conditions were executed and studied in detail by selective Soxhlet solvent extraction. And at the same time, the evolutions of phase structures of PP/PS and the resulted PP/PS/AlCl_3 alloys were investigated by SEM(Scanning electric morphology) and SALS(Small angle laser scattering). The steady and dynamic rheological behaviors of in-situ compatibilized PP/PS alloys were obtained systematically.
The results showed that, under melt mixing conditions, PP or PS degradation would take place catalyzed by AlCl_3, but not very seriously with lower AlCl_3 content. And at the same time, C-O-C structure and PS-AlCl_3 complex would be formed in PP/AlCl_3 and PS/AlCl_3, respectively, resulted in complex rheological behaviors of systems. In-situ compatibilized reaction of Fridel-Craft alkylation in PP/PS/AlCl_3 alloys catalyzed by AlCl_3 may form PP-g-PS copolymer distributed in interfacial surfaces as interfacial layer with a certain depth. The effects of compatibilization and the ratio of viscosities of PP/AlCl_3 and PS/AlCl_3 determined the evolution of phase structures of PP/PS/AlCl_3, together. And the compatibilization reaction was influenced by the area of interfacial surfaces and the concentration of PP+ ion in the reactive system. According to log-linearly additivity method, storage modulus, loss modulus, complex modulus and complex viscosity of PP/PS alloys or compatibilized PP/PS/AlCl_3 alloys could be divided into three parts, including contribution of components, contribution of geometrical phase structure, and contribution of the interfacial adhesion of phases. Thus the contribution of PP or PS component and contribution of geometrical phase structure could be separated away and contribution of interfacial adhesion of in-situ compatibilization could be calculated out. The dependence of interfacial adhesion on compositions calculated from static rheology and dynamic rheology, especially, was the same to the dependence of PP-g-PS yield determined by soxhlet extracted method, and also was the same to the dependence of interfacial layer thickness d obtained by SALS.
Investigations on the influences of AlCl3 on PP and PS under melt mixing conditions and on the resulted phase structure evolutions, reactive characteristics, and rheological properties of PP/PS/AlCl3 alloys were helpful to understand the reactive mechanism, to explain the characteristic structure and property changes of alloys, and to prepare better PP/PS alloys with competitive potentials.
引文
[1] C. A. A. Thomas. Anhydrous Aluninum Chloride in Organic Chemistry[M]. Reinhold:New York, 1948
[2] G. A. Olah Ed. Friedel-Crafts and related-Reactions[M], New York: Interscience, 1964
[3] Y. J. Sun, W. E. Baker. Polyolefin/Polystyrene in situ compatibilization using Fridel-Crafts Alkylation[J], Journal of Applied Polymer Science, 1997, 65: 1385-1393
[4] F. D. Monica, S. E. Barbosa, N. J. Capiati. Polypropylene/Polystyrene Blends: In Situ Compatibilization by Friedel-Crafts Alkylation Reaction [J], Journal of Polymer Science, Part B, Polymer Physics, 2004, 42: 452-462
[5] 高瑛,殷敬华. 线性低密度聚乙烯和聚苯乙烯共混物的原位增容及其形态、结构和性能[J], 应用化学,2002,19(9):822-826
[6] B. D. Park, H. I. Lee, S. J. Ryoo, Y. S. Lee. Convenient Method for Preparing Polystyrene having β-Hydroxy Group: Its Application to the Synthesis of Polyethylene Glycol-Grafted Polystyrene Resin[J], Tetrahedron Letters, 1997, 38(4): 591-594
[7] H. Y. Yao, M. A. Mckinney, C. Dick, J. J. Liggat, C. E. Snape, C. A. Wilkie. Cross-linking of polystyrene by Friedel-Crafts chemistry: reaction of p-hydroxymethylbenzyl chloride with polystyrene[J]. Polymer degradation and stability, 2001, 72:399-405
[8] W. L. Carrick. Journal of Polymer Science, Part A, Polymer chemistry, 1970, 1(8):215
[9] W. M. Barentsen, D. Heikens. Mechanical properties of polystyrene/low density polyethylene blends [J]. Polymer, 1973, 14:579-583
[10] D. Heikens, N. Hoen, W. Barentsen, P. Piet, H. Laden. Mechanical properties and morphology of copolymer modified polymer blends [J]. Journal of Polymer Science, Polymer Symposic, 1977, 62:309-341
[11] M. F. Diaz, S. E. Barbosa, N. J. Capiati. Polyethylene-Polystyrene grafting reaction: effects of polyethylene molecular weight[J], Polymer, 2002,43:4851-4858
[12] 钱逸泰编著. 结晶化学[M],合肥:中国科学技术大学出版社,1988 年 8 月,P236
[13] 邵学俊,董平安,魏益海编著. 无机化学上册(第二版)[M],武汉:武汉大学出版社,2003 年 4 月第二版第二次印刷,P423-424
[14] A. L. N. Silva, M. C. G. Rocha, F. M. B. Coutinho. Study of rheological behavior of elastomer/polypropylene blends [J]. Polymer testing, 2002, 21: 289-293
[15] C. D. Han, K. U. Kim, N. Siskovic, C. R. Huang. An appraisal or rheological models as applied to polymer melt flow [J]. Rheologica Acta, 1975, 14(6): 533-549
[16] C. A. Hieber, H. H. Chiang. Shear-rate-dependence modeling of polymer melt viscosity[J]. Polymer engineering and science, 1992, 32(14): 931-938
[17] L. D. Orazio, C. Mancarella, E. Martuscelli, F. Polato. Polypropylene/ethylene-co-propylene blends: influence of molecular structure and composition of EPR on melt rheology, morphology and impact properties of injection-moulded samples [J]. Polymer, 1991, 32(7): 1186-1194
[18] 卢红斌,杨玉良. 支化聚合物的熔体流变特性[J]. 高分子通报,2002,1:16-23
[19] J. Roovers. Melt rheology of highly branched polymers [J]. Journal of non-crystalline solids, 1991, 131:793-798
[20] 梁瑞凤,许元泽. 碳酸钙填充聚丙烯熔体的流变性质[J]. 高分子材料科学与工程,1992,3:38-44
[21] N. R. Demarquette. Comparison between five experimental methods to evaluate interfacial tension between molten polymers [J]. Polymer engineering and science, 2003, 43(3): 670-682
[22] 江苏俊,贾向明,李光宪,陈大华. 多组分聚合物体系的动态流变行为与其相行为的关系[J]. 高分子通报,2004,1:57-64
[23] J. Wu. The interfacial properties and porous structures of polymer blends characterized by synchrotron small-angle X-ray scattering [J]. Polymer, 2003, 44(26): 8033-8040
[24] 郑强,杨碧波,吴刚,李立伟. 多组分高分子体系动态流变学研究[J]. 高等学校化学学报,20(9):1483-1490
[25] C. A. Hieber, H. H. Chiang. Some correlations involving the shear viscosity of polystyrene melts [J]. Rheologica Acta, 1989, 28(4): 321-323
[26] 钟世云,许乾慰,王公善. 聚合物降解与稳定化[M]. 北京:化学工业出版社,2002 年 12 月,P4
[27] Z. T. Wang, D. D. Jiang, M. A. McKinney, C. A. Wilkie. Cross-linking of polystyrene by Friedel-Crafts chemistry to improve thermal stability [J]. Polymer degradation and stability, 1999, 64:387-395
[28] B. Tamami, K. P. Boruieny. Chemoselective tetrahydropyranylation of alcohols and phenols using polystyrene supported aluminium chloride as a catalyst [J]. Tetrahedron Letters, 2004, 45: 715-718
[29] N. E. Villarreal, B.I. Kharisov, I.I. Ivanova, B.V. Romanovskii. Optimal conditions of toluene alkylation by ethanol using pentasile zeolite as catalyst [J]. Applied Catalysis A: General , 2002, 224: 161–166
[30] X. D. Bi, D. K. Wang, Z. Wu. Unusual polymerization activities of bulky aluminum alkyl complexes [J]. Journal of molecular catalysis A: Chemical, 2002, 179: 53-57
[31] T. Hirano, K. Higashi, M. Seno, T. Sato. Radical polymerization of di-n-butyl itaconate in the presence of lewis acids [J]. European polymer journal, 2003, 39: 1801-1808
[32] F. J. Chen, J. E. Stanat, H. Cheradame, G. Rissoan. Heterogeneous lewis acid-type catalysts[P]. US Patent: 5874380
[33] M. A. Beckett, G. C. Strickland. A convenient n.m.r. method for the measurement of lewis acidity at boron centres: correlation of reaction rates of lewis acid initiated epoxide polymerizations with lewis acidity [J]. Polymer, 1996, 37(20): 4629-4631
[34] Z. Funke, C. Schwinger, R. Adhikari, J. Kressler. Surface tension in polymer blends of isotactic poly(propylene) and atactic polystyrene [J]. Macromolecular Materials and Engineering, 2001, 286(12): 744-750
[35] N. R. Demarquette, M. R. Kamal. Interfacial tension in polymer melts. I: An improved pendant drop apparatus [J]. Polymer engineering and science, 2004, 34(24): 1823-1833
[36] J. M. Li, C. A. Wilkie. Improving the thermal stability of polystyrene by friedel-crafts chemistry [J]. Polymer degradation and stability, 1997, 57: 293-299
[37] D. C. Neckers, D. A.Kooistra, G. W. Green. Polymer-protected reagents Polystyrene-Aluminum Chloride [J]. Journal of American Chemistry Society, 1972, 94(26): 9284-9285
[38] E. C. Blossey, L. M. Turner, D. C. Neckers. Polymer-protected reagents. Ⅲ. Acetal formation with polymer-protected aluminum chloride. [J]. Journal of Organic Chemistry, 1975, 40: 959-960
[39] A. Saber, A. Smahi, A. Solhy, R. Nazih, B. Elaabar, M. Maizi, S. Sebti. Heterogeneous catalysis of Friedel-Crafts alkylation by the fluorapatite alone and doped with metal halides [J]. Journal of Molecular Catalysis A: Chemical, 2003, 202: 229–237
[40] 徐鸿升,李忠明,杨鸣波. 多组分聚合物的动态流变特性[J]. 高分子材料科学与工程,2004,20(6):24-28
[41] Y. J. Sun, R. J. G. Willemse, T. M. Liu and W. E. Baker. In situ compatibilization of Polyolefin and Polystyrene using Fridel-Crafts Alkylation through reactive extrusion[J]. Polymer,1998, 39(11): 2201-2208
[42] F. D. Monica, S. E. Barbosa, N. J. Capiati. Improvement of mechamical properties for PP/PS blends by in situ compatibilization [J]. Polymer, 2005, 46: 6096-6101
[43] P. Scholz, D. Froelich, R. Muller. Viscoelastic properties and morphology of two-phase polypropylene/polyamide6 blends in the melt: interpretation of results with an emulsion model [J]. Journal of Rheology, 1989, 33(3): 481-499
[44] B. Brahimi, A. Ait-Kadi, A. Ajji, R. Jerome, R. Fayt. Rheological properties of copolymer modified polyethylene/polystyrene blends [J]. Journal of Rheology, 1991, 35(6): 1069-1091
[45] D. Graebling, D. Froelich, R. Muller. Viscoelastic properties of polydimethylsiloxane-propylene blends in the melt: emulsion model [J]. Journal of Rheology, 1989, 33(8):1283-1291
[46] D. Graebling, R. Muller. Determination of interfacial tension of polymer melts by dynamic shear measurements [J]. Colloids and Surfaces. 1991, 55:89-103
[47] D. Graebling, R. Muller, J. F. Palierne. Macromolecules. Linear viscoelastic behavior of some incompatible polymer blends in the melt: interpretation of data with a model of emulsion of viscoelastic liquids [J]. Macromolecules, 1993, 26(2):320-329
[48] D. Graebling, A. Benkira, Y. Gallot, R. Muller. Dynamic viscoelastic behavior of polymer blends in the melt – experimental results for PDMS/POE-DO, PS/PMMA and PS/PEMA blends [J]. European Polymer Journal. 1994, 30(3):301-308
[49] H. Gramespacher, J. Meissner. Interfacial tension between polymer melts measured by shear oscillations of their blends [J]. Journal of Rheology, 1992, 36(6):1127-1141
[50] Y. Germain, B. Ernest, O. Genelot, L. Dhamani. Rheological and morphological analysis of compatibilized polypropylene/polyamide blends [J]. Journal of Rheology, 1994, 38(3):681-697
[51] W. Gleinser, H. Braun, C. Friedrich, H. J. Cantow. Correlation between rheology and morphology of compatibilized immiscible blends [J]. Polymer, 1994, 35(1):128-135
[52] M. Bousmina, P. Bataille, S. Sapieha, H. P. Schreiber. Comparing the effect of corona treatment and block copolymer addition on rheological properties of polystyrene/polyethylene blends [J]. Journal of Rheology, 1995, 39(3):499-517
[53] C. Lacroix, M. Aressy, P. J. Carreau. Linear viscoelastic behavior of molten polymer blends: A comparative study of the Palierne and Lee and Park models [J]. Rheologica Acta, 1997, 36:416-428
[54] C. Lacroix, M. Grmela, P. J. Carreau. Relations between rheology and morphology for immiscible molten blends of polypropylene and ethylene copolymers under shear flow [J]. Journal of Rheology, 1998, 42(1): 41-62
[55] P. H. P. Macaubas, N. R. Demarquette. Morphologies and interfacial tensions of immiscible polypropylene/polystyrene blends modified with triblock copolymers [J]. Polymer, 2001, 42: 2543-2554
[56] M. A. Villar, M. D. Failla, R. Quijada, R. S. Mauler, E. M. Vallés, G. B. Galland and L. M. Quinzani. Rheological characterization of molten ethylene–olefin copolymers synthesized with Et[Ind]2ZrCl2/MAO catalyst[J]. Polymer, 2001, 42(22):9269-9279
[57] J. K. Kim, H. W. Son. The rheological properties of polystyrene/poly(vinylmethylether) blend near the critical region and in the homogenous region[J]. Polymer, 1999, 40:6789-6801
[58] 姜苏俊,李光宪,贾向明,吴兆权,陆玉本. 聚合物共混体系相行为的动态流变学研究进展[J]. 高分子材料科学与工程,2003,19(6):27-31
[59] 郁锋,李树材. 聚合物体系相行为的流变学研究[J]. 中国塑料,2001,15(1):19-23
[60] 刘萌戈,周持兴. 化学反应中聚合物流变动力学的研究进展[J]. 高分子材料科学与工程,2005,21(4):42-45,50
[61] Q. Zheng, Y. X. Cao, M. Du. Dynamic rheological behavior of polypropylene filled with ultra-fine powdered rubber particles[J]. Chinese Journal of Polymer Science, 2004, 22(4): 363-367
[62] H. H. Ismail, M. Nasir. Morphological studies of uncompatibilized and compatibilized polystyrene/polypropylene blend [J]. Polymer testing, 2002, 21: 263-267
[63] H. H. Ismail, M. Nasir. The effect of various compatibilizers on mechanical properties of polystyrene/polypropylene blend [J]. Polymer testing, 2002, 21: 163-170
[64] G. Radonjic. Compatibilization effects of styrenic/rubber block copolymers in polypropylene/polystyrene blends [J]. Journal of Applied Polymer Science, 1999, 72: 291-307
[65] 汪多仁 编著. 现代高分子材料生产及应用手册[M],北京:中国石化出版社,2002,P25
[66] Z. Horak, J. kolarik, M. Sipek, V. Hynek, F. vecerka. Gas permeability and mechanical properties of polystyrene-polypropylene blends [J]. Journal of Applied Polymer Science, 1998, 69: 2615-2623
[67] L. Dorazio, R. Guarino, C. Mancarella, E. Martuscelli, G. Cecchin. Morphology, crystallization, and thermal behavior of isotactic polypropylene/polystyrene blends: effects of the addition of a graft copolymer of propylene with styrene [J]. Journal of Applied Polymer Science, 1999, 72: 1429-1442
[68] J. Schellenberg. Properties of the polyethylene/poly(2,6-dimethyl-1,4-phenylene ether)/polystyrene system in the presence of SEPS block copolymers [J]. Journal of Applied Polymer Science, 1997, 64(9): 1835-1842
[69] D. Hlavata, J. Hromadkova, I. Fortelny, V. Hasova, J. Pulda. Compatibilization efficiency of styrene-butadiene triblock copolymers in polystyrene-polypropylene blends with varying compositions [J]. Journal of Applied Polymer Science, 2004, 92: 2431-2441
[70] Z. Li, Y. Ke, Y. L. Hu. Study on a new kind of polypropylene-g-polystyrene: preparation and application [J]. Journal of Applied Polymer Science, 2004, 93: 314-322
[71] S. Raha, N. Kao, S. N. Bhattacharya. Effect of polypropylene on the rheolgy of co-continuous PP/SEBS blends [J]. Polymer engineering and Science, 2005, 1432-1444
[72] J. Kim, J. Kwak, D. Kim. Synthesis and characterization of polyethylene-g-polystyrene as the compatibilizer for polypropylene/polystyrene blends [J]. Polymers for advanced technologies, 2003, 14: 58-65
[73] S. J. Syed Mustafa, M. R. Nor Azlan, M. Y. Ahmad Fuad, Z. A. Mohd Ishak, U. S. Ishiaku. Polypropylene/polystyrene blends—prelininary studies for compatibilization by aromatic-grafted polypropylene [J]. Journal of Applied Polymer Science, 2001, 82: 428-434
[74] 赵义平,李树才,揣成智.反应性共混体系研究进展[J]. 中国塑料,2000,14(9):6-11
[75] 杨军忠. PP/PS/SEBS 三元共混物的研究[J]. 中国塑料,2000,14(11):32-37
[76] 高军,佘万能. 新型热塑性弹性体 SEBS[J]. 化工新型材料, 2004,32(4):21-24
[77] 杜仕国,高欣宝,宣兆龙. 高分子合金的反应性增容技术与应用[J]. 中国塑料,1999,13(7):7-11
[78] L. Assoun, S. C. Manning, R. B. Moore. Carboxylation of polypropylene by reactive extrusion with functionalised peroxides [J]. Polymer, 1998, 39(12): 2571-2577
[79] B. wong, W. E. Baker. Melt rheology of graft modified polypropylene [J]. Polymer, 38(11): 2781-2789
[80] 谢续明,李颖,张景春. 马来酸酐-苯乙烯熔融接枝聚丙烯的影响因素及其性能研究[J]. 高分子学报,2002,1:7-12
[81] W. H. Jo, C. D. Park. Preparation of functionalized polystyrene by reactive extrusion and its blend with polyamide6 [J]. Polymer, 1996, 37(9): 1709-1714
[82] F. C. Chang, Y. C. Hwu. Styrene maleic anhydride and styrene glycidyl methacrylate copolymers as in situ reactive compatibilizers of polystyrene/nylon6,6 blends [J]. Polymer Engineering and Science, 1991, 31(21): 1509-1519
[83] C. A. Orr, J. J. Cernohous, P. Guegan, A. Hirao, H. K. Jeon, C. W. Macosko. Homogeneous reactive coupling of terminally functional polymers [J]. Polymer, 2001, 42: 8171-8178
[84] H. M. Wilhelm, M. I. Felisberti. Reactive compatibilization of maleated polypropylene and maleated poly(styrene-b-butadiene-b-styrene) blends [J]. Journal of Applied Polymer Science, 2002, 86(2): 366-371
[85] J. Pionteck, P. Potschke, N. Proske, H. Y. Zhao, H. Malz. Morphology of reactivePP/PS blends with Hyperbranched Polymers [J]. Macromolecular Symposia, 2003, 198: 209-220
[86] S. Kim, J. K. Kim, C. E. Park. Effect of molecular architecture of in situ reactive compatibilizer on the morphology and interfacial activity of an immiscible polyolifin/polystyrene blend [J]. Polymer, 1997, 38(8): 1809-1815
[87] J. K. Kim, D. K. Yi, H. K. Jeon, C. E. Park. Effect of the functional group inhomogeneity of an in situ reactive compatibilizer on the morphology and rheological properties of immiscible polymer blends [J]. Polymer, 1999, 40: 2737-2743
[88] P. Potschke, H. Malz, J. Pionteck. Influence of interfacial reaction on morphology in modified PP/PS blends [J]. Macromolecular Symposia, 2000, 149: 231-246
[89] J. Pionteck, P. Potschke, U. Schulze, N. Proske, A. Kaya, H. Zhao, H. Malz. Influence of reactive compatibilization on the morphology of polypropylene/polystyrene blends [J]. Macromolecular Symposia, 2004, 214: 279-288
[90] L. Nie, R. Narayan, E. A. Grulke. Effect of intramolecular reaction on the branching process of grafting reaction between two reactive polymers [J]. Polymer, 1995, 36(7): 1469-1478
[91] T. J. Mulkern, N. C. B. Tan. Processing and characterization of reactive polystyrene/hyperbranched polyester blends [J]. Polymer, 2000, 41: 3193-3203
[92] M. F. Zhu, W. D. Yan, Y. Lu, Y. M. Chen, H-J. P. Adler, P. Potschke, J. Pionteck. Modification of PP by blending with PS and reactive polymers [J]. Macromolecular Symposia, 2001, 164: 369-376
[93] Y. Roiter, V. Samaryk, S. Varvarenko, N. Nosova, I. Tarnavchyk, J. Pionteck, P. Potschke, S. voronov. Peroxide-containing compatibilizer for polypropylene blends with other polymers [J]. Macromolecular Symposia, 2004, 210: 209-217
[94] S. voronov, V. Samaryk,Y. Roiter, J. Pionteck, P. Potschke, S. Minko, I. Tokarev, S. Varvarenko, N. Nosova. Compatibilization of polymer blends with high-molecular-weight peroxides [J]. Journal of Applied Polymer Science, 2005, 96: 232-242
[95] S. Keszei, S. Matko, G. Bertalan, P. Anna, G. Marosi, A. Toth. Progress in interface modifications: from compatibilization to adaptive and smart interphases [J]. European polymer journal, 2005, 41: 697-705
[96] C. Albano, J. Reyes, M. Ichazo, J. Gonzalez, M. Hernandez, M. Rodriguez. Mechanical, thermal and morphological behaviour of the polystyrene/polypropylene (80/20) blend, irradiated with γ–rays at low doses (0-70 kGy) [J]. Polymer degradation and stability, 2003, 80: 251-261
[97] J. Reyes, C. Albano, M. Claro, D. Moronta. Electron spin resonance studies on PS, PP and PS/PP blends under gamma irradiation [J]. Radiation physics and chemistry, 2003, 67: 453-457
[98] X. M. Xie, X. Zheng. Effect of addition of multifunctional monomers on one-step reactive extrusion of PP/PS blends [J]. Materials and design, 2001, 22: 11-14
[99] G. Dlubek, M. A. Alam. Studies of the positron lifetime and Doppler-broadened annihilation radiation of polypropylene-polystyrene alloys [J]. Polymer, 2002, 43: 4025-4031
[100] Z. Chang, J. A. Laverne. Hydrogen Production in gamma-Ray and Helium-Ion Radiolysis of Polyethylene, Polypropylene, Poly(methylmethacrylate), and Polystyrene [J]. Journal of polymer science, Part A, Polymer chemistry, 2000, 38: 1656-1661
[101] D. Li, Z. M. Liu, B. X. Han, L. P. Song, G. Y. Yang, T. Jiang. Preparation of nanometer dispersed polypropylene/polystyrene interpenetrating network using supercritical CO2 as a swelling agent [J]. Polymer, 2002, 43: 5363-5367
[102] S. B. Roscoe, C. G. Gong, J. M. J. Frechet, J. F. Walzer. Functionalized polystyrene as a versatile support for olefin polymerization catalysts [J]. Journal of polymer science, Part A, polymer chemistry, 2000, 38: 2979-2992
[103] Q. Zhang, H. Yang, Q. Fu. Kinetics-controlled compatibilization of immiscible polypropylene/polystyrene blends using nano-SiO2 particles [J]. Polymer, 2004, 45: 1913-1922
[104] S. S. Ray, S. Pouliot, M. Bousmina, L. A. Utracki. Role of organically modified layered silicate as an active interfacial modifier in immiscible polystyrene/polypropylene blends [J]. Polymer, 2004, 45: 8403-8413
[105] D. Y. Wang, C. A. Wilkie. In-situ reactive blending to prepare polystyrene-clay and polypropylene-clay nanocomposites [J]. Polymer degradation and stability, 2003, 80: 171-182
[106] M.F. Diaz, S.E. Barbosa, N.J. Capiati. Addition compatibilization of PP/PS blends by tailor-maid copolymers [J]. Polymer engineering and science, 2006,329-336
[107] G. Jannerfeldt, L. Boogh, J. -A. E. Manson. Influence of hyperbranched polymers on the interfacial tension of polypropylene/polyamide-6 blends [J]. Journal of Polymer Science, Part B, Polymer Physics, 1999, 37: 2069-2077
[108] G. Jannerfeldt, L. Boogh, J. -A. E. Manson. Tailored interfacial properties for immiscible polymers by hyperbranched polymers. Polymer, 2000, 41: 7627–7634
[109] G. Jannerfeldt, L. Boogh, J. A. E. Maanson. The morphology of hyperbranched polymer compatibilized polypropylene/polyamide 6 blends [J]. Polymer Engineering and Science, 2001, 41(2): 293-300
[110] P. Poetschke, H. Malz, J. Pionteck. Influence of interfacial reaction on morphology in modified PP/PS blends [J]. Macromolecular Symposia, 2000, 149: 231-236
[111] Y. Zhang, Y. P. Huang, K. C. Mai. Crystallization and dynamic mechanical properties of polypropylene/polystyrene blends modified with maleic anhydride and styrene [J]. Journal of Applied Polymer Science, 2005, 96(6): 2038 - 2045
[112] Y. Roiter, V. Samaryk, N. Nosova, S. Varvarenko, P. Potschke, S. Voronov. Radical processes for the creation of compatibilizing layers in polyolefinblends [J]. Macromolecular Symposia, 2001, 164: 377-387
[113] J. Pionteck, V. B. Sadhu, L. Jakisch, P. P?tschke, L. H?u?ler, A. Janke. Crosslinkable coupling agents: Synthesis and use for modification of interfaces in polymer blends [J]. Polymer, 2005, 46 (17): 6563-6574
[114] S. Varvarenko, F. Bohme, J. Pionteck, P. Potschke, V. Samaryk, Y. Roiter, S. Varvarenko, N. Nosova. Polymer peroxide compatibilizer for reactive blending of carbon-chain polymers, Theses of EuroPolymer Foundation Congress, Eindhoven, 2001, S.3 N.214
[115] 邰向阳,谢续明. PP/AS/DCP 反应共混中的 SEBS 添加效应[J].合成树脂与塑料, 1998, 15(1):35-37
[116] 邰向阳,谢续明. 聚丙烯共混物反应共混中的降解抑制[J].功能高分子学报, 1998, 11(2): 231-236
[117] 谢续明, 李颖, 张景春, 杨讯. 马来酸酐-苯乙烯熔融接枝聚丙烯的影响因素及其性能研究[J]. 高分子学报, 2002, 1: 7-12
[118] P. Cassagnau, T. Nietsch, M. Bert, A. Michel. Reactive blending by in situ polymerization of the dispersed phase [J]. Polymer, 1998, 40:131-138
[119] 王亚. 聚丙烯/聚苯乙烯(苯乙烯)原位合金的研究. 硕士学位论文,天津大学,导师:盛京,天津大学,2005 年 1 月
[120] 金慧. 聚丙烯/聚苯乙烯原位合金化的研究. 硕士学位论文,导师:盛京,天津大学,2006 年 1 月
[121] 李云岩. 多项聚合物相结构的形成与演变-PS/PP合金相结构及其演变特征.硕士学位论文,导师:盛京,天津大学,2005 年 1 月
[122] 张佩君,郑强,王旭. 催化合金研究进展[J]. 中国塑料,2003,17(5):7-11
[123] 张玉清,范志强,封麟先. 聚丙烯催化合金的相结构研究[J]. 高分子学报,2001,5:687-690
[124] S. S. Pesetskii, B. Jurkowski, O. A. Makarenko. Free radical grafting of itaconic acid and glycidyl methacrylate onto PP initiated by organic peroxides [J]. Journal of Applied Polymer Science, 2002, 86: 64-72
[125] J. A. Galloway, M. D. Montminy, C. W. Macosko. Image analysis for interfacial area and cocontinuity detection in polymer blends [J]. Polymer, 2002, 43: 4715–4722
[126] G. Khanarian. Rubber Toughened and Optically Transparent Blends of Cyclic Olefin Copolymers [J]. Polymer engineering and science, 2000, 40(12): 2590-2601
[127] V.B.Sadhu, J. Pionteck, P. P?tschke, L.Jakisch, A.Janke. Creation of Crosslinkable Interphases in Polymer Blends [J]. Macromolecular Symposia, 2004, 210: 165-174
[128] G. Pompe, P. P?tschke, J. Pionteck. Reactive melt blending of modified Polyamide and Polypropylene: Assessment of compatibilization by fractionated crystallization and blend morphology [J]. Journal of Applied Polymer Science, 2002, 86: 3445-3453
[129] R.T. Tol, G. Groeninckx, I. Vinckier, P. Moldenaers, J. Mewis. Phase morphology and stability of co-continuous (PPE/PS)/PA6 and PS/PA6 blends: effect of rheology and reactive compatibilization [J]. Polymer, 2004, 45: 2587–2601
[130] P. V. Puyvelde, S. Velankar, P. Moldenaers. Rheology and morphology of compatibilized polymer blends [J]. Current Opinion in Colloid and Interface Science, 2001, 6: 457-463
[131] J. L. Bolland. Kinetic Studies in the Chemistry of Rubber and Related Materials.I. The Thermal Oxidation of Ethyl Linoleate[J]. Proceedings of the Royal Society of London. Series A, Mathematical and Physical Sciences, 1946, 186(1005): 218-236
[132] 钟世云,许乾慰,王公善编著. 聚合物降解与稳定化[M]. 北京:化学工业出版社,2002 年 12 月,P25,P63
[133] 廖凯荣,卢泽俭,苏瑾. 聚磷酸铵型膨胀阻燃剂对聚丙烯的阻燃作用[J]. 高分子材料科学与工程,1999,15(2):59-61
[134] Q. Li, P. K. Jiang, P. Wei. Thermal Degradation Behavior of Poly(propylene) with a Novel Silicon-Containing Intumescent Flame Retardant[J]. Macromol. Mater. Eng. , 2005, 290: 912–919
[135] J. Guisandez, P. Tiemblo, J.M. Gomez-Elvira. Change of thermal and dynamic-mechanical behaviour of a metallocene isotactic polypropylene during low-temperature thermo-oxidation[J]. Polymer Degradation and Stability, 2005, 87: 543-553
[136] M. Elvira, P. Tiemblo, J.M. Gomez-Elvira. Changes in the crystalline phase during the thermo-oxidation of a metallocene isotactic polypropylene. A DSC study[J]. Polymer Degradation and Stability, 2004, 83: 509-518
[137] J.M. Gomez-Elvira, P. Tiemblo, M. Elvira, L. Matisova-Rychla, J. Rychly. Relaxations and thermal stability of low molecular weight predominantly isotactic metallocene and ZieglereNatta polypropylene[J]. Polymer Degradation and Stability, 2004, 85: 873-882
[138] N. Olivares, P. Tiemblo, J. M. Gomez-Elvira. Physicochemical processes along the early stages of the thermal degradation of isotactic polypropylene I. Evolution of the g relaxation under oxidative conditions[J]. Polymer Degradation and Stability, 1999, 65: 297-302
[139] R. Sciamanna, G. Arribas, C. Albano, E. Horie, B. Soto. Effect of different copolymers (hydrogenated and non-hydrogenated, with different molecular weights and different content of styrene) in the compatibilization of PS + PP (80+20) polyblend[J]. Mat. Res. Innovat., 2001, 4:311–321
[140] 谢晶曦,常俊标,王绪明编著[M]. 红外光谱在有机化学和药物化学中的应用[M]. 北京:科学出版社,2001年12月修订版,P46-52
[141] 谢晶曦,常俊标,王绪明编著[M]. 红外光谱在有机化学和药物化学中的应用[M]. 北京:科学出版社,2001年12月修订版,P97。
[142] S.H. Hsiao, C.H. Yu. Aromatic polyamides bearing ether and isopropylidene orhexafluoroisopropylidene links in the main chain[J]. Journal of Polymer Research, 1996, 3(4): 247-256
[143] 吴刚主编. 材料结构表征及应用[M]. 北京:化学工业出版社,2002年1月,P162
[144] H. Pehlivan, D. Balkose, S. Ulku, F. T?hm?nl?oglu. Effect of Zeolite Filler on the Thermal Degradation Kinetics of Polypropylene[J]. Journal of Applied Polymer Science, 2006,101:143–148
[145] M. L Arnal, A.J. Muller, B. Mendez. Synthesis and characterization of aPP/aPS graft copolymers[J]. Polymer Bulletin, 1996, 36: 687-694
[146] R. R. Wu, H. M. Kao, J. C. Chiang, E. M. Woo. Solid-state NMR studies on phase behavior and motional mobility in binary blends of polystyrene and poly(cyclohexyl methacrylate)[J]. Polymer, 2002, 43: 171-176
[147] E. Cloutet, Y. Gnanou, J.L. Fillaut, D. Astruc. C60 end-capped polystyrene stars[J]. Chemical Communications, 1996, 1565-1566
[148] 易大年,徐光漪编著. 核磁共振波谱在药物分析中的应用[M]. 上海:上海科学技术出版社,1985 年 10 月,P322
[149] 钟世云,许乾慰,王公善. 聚合物降解与稳定化[M]. 北京:化学工业出版社,2002 年 12 月,P78-P80
[150] 钟世云,许乾慰,王公善. 聚合物降解与稳定化[M]. 北京:化学工业出版社,2002 年 12 月,P4
[151] D.A. Anderson, E.S. Freeman. The kinetics of the thermal degradation of polystyrene and polyethylene[J]. J. Polym. Sci., 1961, 54: 253–260
[152] T. Faravelli, M. Pinciroli, F. Pisano, G. Bozzano, M. Dente, E. Ranzi. Thermal degradation of polystyrene[J]. Journal of Analytical and Applied Pyrolysis, 2001, 60: 103–121
[153] J. D. Peterson, S. Vyazovkin, C. A. Wight. Kinetics of the Thermal and Thermo-Oxidative Degradation of Polystyrene, Polyethylene and Poly(propylene)[J]. Macromol. Chem. Phys., 2001, 202(6): 775–784
[154] X. S. Zhu. Effects of acids on thermal and thermo-oxidative degradation of polystyrene[J]. Polymer degradation and stability, 1997, 57: 163-173
[155] X.S. Zhu, M. Elomaa, F. Sundholma, C. H. Lochmuller. Infrared and thermogravimetric studies of thermal degradation of polystyrene in the presence of ammonium sulfate[J]. Polymer Degradation and Stability, 1998, 62: 487-494
[156] S. Vyazovkin, I. Dranca, X.W. Fan, R. Advincula. Kinetics of the Thermal andThermo-Oxidative Degradation of a Polystyrene–Clay Nanocomposite[J]. Macromol. Rapid Commun. 2004, 25: 498–503
[157] 谢晶曦,常俊标,王绪明编著[M]. 红外光谱在有机化学和药物化学中的应用[M]. 北京:科学出版社,2001年12月修订版,P161-162
[158] 谢晶曦,常俊标,王绪明编著[M]. 红外光谱在有机化学和药物化学中的应用[M]. 北京:科学出版社,2001年12月修订版,P20。
[159] 韩蕴萍. 多相聚合物体系熔体动态过程中的相结构与行为━━高抗冲聚苯乙烯/顺丁橡胶共混过程中的结构与性能. 硕士学位论文,天津大学,导师:盛京,天津大学,2001 年 1 月
[160] S. Wu. Entanglement, friction, and free volume between dissimilar chains in compatible polymer blends[J]. J. Polym. Sci. B Polym. Phys. 1987, 25(12): 2511-2529
[161] J. H. Han, C. F. Chin, D. J. Li. Effect of flow geometry on the rheology of dispersed two-phase blends of polystyrene and poly(methacrylate)[J]. Polymer, 1995, 36(12): 2451-2462
[162] L. A. Utracki. On the viscosity-concentratin dependence of immiscible blends[J]. J. Rheo. 1991, 35(8): 1615-1637
[163] N. A. Frankel, A. Acrivos. The constitutive equation for a dilute emulsion[J]. J. Fluid Mech, 1970, 44: 65-78
[164] S. J. Choe, W. R. Schowalter. Rheological properties of nondilute suspensions of deformable paticles[J]. Phys. Fluids, 1975, 18: 420-427
[165] H. M. Lee, O. O. Park. Rheology and dynamics of immiscible polymer blends. J. Rheol. 1994, 38: 1405-1425
[166] 俞炜. 不相容聚合物共混体系分散相形态学的研究。博士学位论文,上海交通大学,导师:周持兴,上海交通大学,2000 年 10 月
[2] G. A. Olah Ed. Friedel-Crafts and related-Reactions[M], New York: Interscience, 1964
[3] Y. J. Sun, W. E. Baker. Polyolefin/Polystyrene in situ compatibilization using Fridel-Crafts Alkylation[J], Journal of Applied Polymer Science, 1997, 65: 1385-1393
[4] F. D. Monica, S. E. Barbosa, N. J. Capiati. Polypropylene/Polystyrene Blends: In Situ Compatibilization by Friedel-Crafts Alkylation Reaction [J], Journal of Polymer Science, Part B, Polymer Physics, 2004, 42: 452-462
[5] 高瑛,殷敬华. 线性低密度聚乙烯和聚苯乙烯共混物的原位增容及其形态、结构和性能[J], 应用化学,2002,19(9):822-826
[6] B. D. Park, H. I. Lee, S. J. Ryoo, Y. S. Lee. Convenient Method for Preparing Polystyrene having β-Hydroxy Group: Its Application to the Synthesis of Polyethylene Glycol-Grafted Polystyrene Resin[J], Tetrahedron Letters, 1997, 38(4): 591-594
[7] H. Y. Yao, M. A. Mckinney, C. Dick, J. J. Liggat, C. E. Snape, C. A. Wilkie. Cross-linking of polystyrene by Friedel-Crafts chemistry: reaction of p-hydroxymethylbenzyl chloride with polystyrene[J]. Polymer degradation and stability, 2001, 72:399-405
[8] W. L. Carrick. Journal of Polymer Science, Part A, Polymer chemistry, 1970, 1(8):215
[9] W. M. Barentsen, D. Heikens. Mechanical properties of polystyrene/low density polyethylene blends [J]. Polymer, 1973, 14:579-583
[10] D. Heikens, N. Hoen, W. Barentsen, P. Piet, H. Laden. Mechanical properties and morphology of copolymer modified polymer blends [J]. Journal of Polymer Science, Polymer Symposic, 1977, 62:309-341
[11] M. F. Diaz, S. E. Barbosa, N. J. Capiati. Polyethylene-Polystyrene grafting reaction: effects of polyethylene molecular weight[J], Polymer, 2002,43:4851-4858
[12] 钱逸泰编著. 结晶化学[M],合肥:中国科学技术大学出版社,1988 年 8 月,P236
[13] 邵学俊,董平安,魏益海编著. 无机化学上册(第二版)[M],武汉:武汉大学出版社,2003 年 4 月第二版第二次印刷,P423-424
[14] A. L. N. Silva, M. C. G. Rocha, F. M. B. Coutinho. Study of rheological behavior of elastomer/polypropylene blends [J]. Polymer testing, 2002, 21: 289-293
[15] C. D. Han, K. U. Kim, N. Siskovic, C. R. Huang. An appraisal or rheological models as applied to polymer melt flow [J]. Rheologica Acta, 1975, 14(6): 533-549
[16] C. A. Hieber, H. H. Chiang. Shear-rate-dependence modeling of polymer melt viscosity[J]. Polymer engineering and science, 1992, 32(14): 931-938
[17] L. D. Orazio, C. Mancarella, E. Martuscelli, F. Polato. Polypropylene/ethylene-co-propylene blends: influence of molecular structure and composition of EPR on melt rheology, morphology and impact properties of injection-moulded samples [J]. Polymer, 1991, 32(7): 1186-1194
[18] 卢红斌,杨玉良. 支化聚合物的熔体流变特性[J]. 高分子通报,2002,1:16-23
[19] J. Roovers. Melt rheology of highly branched polymers [J]. Journal of non-crystalline solids, 1991, 131:793-798
[20] 梁瑞凤,许元泽. 碳酸钙填充聚丙烯熔体的流变性质[J]. 高分子材料科学与工程,1992,3:38-44
[21] N. R. Demarquette. Comparison between five experimental methods to evaluate interfacial tension between molten polymers [J]. Polymer engineering and science, 2003, 43(3): 670-682
[22] 江苏俊,贾向明,李光宪,陈大华. 多组分聚合物体系的动态流变行为与其相行为的关系[J]. 高分子通报,2004,1:57-64
[23] J. Wu. The interfacial properties and porous structures of polymer blends characterized by synchrotron small-angle X-ray scattering [J]. Polymer, 2003, 44(26): 8033-8040
[24] 郑强,杨碧波,吴刚,李立伟. 多组分高分子体系动态流变学研究[J]. 高等学校化学学报,20(9):1483-1490
[25] C. A. Hieber, H. H. Chiang. Some correlations involving the shear viscosity of polystyrene melts [J]. Rheologica Acta, 1989, 28(4): 321-323
[26] 钟世云,许乾慰,王公善. 聚合物降解与稳定化[M]. 北京:化学工业出版社,2002 年 12 月,P4
[27] Z. T. Wang, D. D. Jiang, M. A. McKinney, C. A. Wilkie. Cross-linking of polystyrene by Friedel-Crafts chemistry to improve thermal stability [J]. Polymer degradation and stability, 1999, 64:387-395
[28] B. Tamami, K. P. Boruieny. Chemoselective tetrahydropyranylation of alcohols and phenols using polystyrene supported aluminium chloride as a catalyst [J]. Tetrahedron Letters, 2004, 45: 715-718
[29] N. E. Villarreal, B.I. Kharisov, I.I. Ivanova, B.V. Romanovskii. Optimal conditions of toluene alkylation by ethanol using pentasile zeolite as catalyst [J]. Applied Catalysis A: General , 2002, 224: 161–166
[30] X. D. Bi, D. K. Wang, Z. Wu. Unusual polymerization activities of bulky aluminum alkyl complexes [J]. Journal of molecular catalysis A: Chemical, 2002, 179: 53-57
[31] T. Hirano, K. Higashi, M. Seno, T. Sato. Radical polymerization of di-n-butyl itaconate in the presence of lewis acids [J]. European polymer journal, 2003, 39: 1801-1808
[32] F. J. Chen, J. E. Stanat, H. Cheradame, G. Rissoan. Heterogeneous lewis acid-type catalysts[P]. US Patent: 5874380
[33] M. A. Beckett, G. C. Strickland. A convenient n.m.r. method for the measurement of lewis acidity at boron centres: correlation of reaction rates of lewis acid initiated epoxide polymerizations with lewis acidity [J]. Polymer, 1996, 37(20): 4629-4631
[34] Z. Funke, C. Schwinger, R. Adhikari, J. Kressler. Surface tension in polymer blends of isotactic poly(propylene) and atactic polystyrene [J]. Macromolecular Materials and Engineering, 2001, 286(12): 744-750
[35] N. R. Demarquette, M. R. Kamal. Interfacial tension in polymer melts. I: An improved pendant drop apparatus [J]. Polymer engineering and science, 2004, 34(24): 1823-1833
[36] J. M. Li, C. A. Wilkie. Improving the thermal stability of polystyrene by friedel-crafts chemistry [J]. Polymer degradation and stability, 1997, 57: 293-299
[37] D. C. Neckers, D. A.Kooistra, G. W. Green. Polymer-protected reagents Polystyrene-Aluminum Chloride [J]. Journal of American Chemistry Society, 1972, 94(26): 9284-9285
[38] E. C. Blossey, L. M. Turner, D. C. Neckers. Polymer-protected reagents. Ⅲ. Acetal formation with polymer-protected aluminum chloride. [J]. Journal of Organic Chemistry, 1975, 40: 959-960
[39] A. Saber, A. Smahi, A. Solhy, R. Nazih, B. Elaabar, M. Maizi, S. Sebti. Heterogeneous catalysis of Friedel-Crafts alkylation by the fluorapatite alone and doped with metal halides [J]. Journal of Molecular Catalysis A: Chemical, 2003, 202: 229–237
[40] 徐鸿升,李忠明,杨鸣波. 多组分聚合物的动态流变特性[J]. 高分子材料科学与工程,2004,20(6):24-28
[41] Y. J. Sun, R. J. G. Willemse, T. M. Liu and W. E. Baker. In situ compatibilization of Polyolefin and Polystyrene using Fridel-Crafts Alkylation through reactive extrusion[J]. Polymer,1998, 39(11): 2201-2208
[42] F. D. Monica, S. E. Barbosa, N. J. Capiati. Improvement of mechamical properties for PP/PS blends by in situ compatibilization [J]. Polymer, 2005, 46: 6096-6101
[43] P. Scholz, D. Froelich, R. Muller. Viscoelastic properties and morphology of two-phase polypropylene/polyamide6 blends in the melt: interpretation of results with an emulsion model [J]. Journal of Rheology, 1989, 33(3): 481-499
[44] B. Brahimi, A. Ait-Kadi, A. Ajji, R. Jerome, R. Fayt. Rheological properties of copolymer modified polyethylene/polystyrene blends [J]. Journal of Rheology, 1991, 35(6): 1069-1091
[45] D. Graebling, D. Froelich, R. Muller. Viscoelastic properties of polydimethylsiloxane-propylene blends in the melt: emulsion model [J]. Journal of Rheology, 1989, 33(8):1283-1291
[46] D. Graebling, R. Muller. Determination of interfacial tension of polymer melts by dynamic shear measurements [J]. Colloids and Surfaces. 1991, 55:89-103
[47] D. Graebling, R. Muller, J. F. Palierne. Macromolecules. Linear viscoelastic behavior of some incompatible polymer blends in the melt: interpretation of data with a model of emulsion of viscoelastic liquids [J]. Macromolecules, 1993, 26(2):320-329
[48] D. Graebling, A. Benkira, Y. Gallot, R. Muller. Dynamic viscoelastic behavior of polymer blends in the melt – experimental results for PDMS/POE-DO, PS/PMMA and PS/PEMA blends [J]. European Polymer Journal. 1994, 30(3):301-308
[49] H. Gramespacher, J. Meissner. Interfacial tension between polymer melts measured by shear oscillations of their blends [J]. Journal of Rheology, 1992, 36(6):1127-1141
[50] Y. Germain, B. Ernest, O. Genelot, L. Dhamani. Rheological and morphological analysis of compatibilized polypropylene/polyamide blends [J]. Journal of Rheology, 1994, 38(3):681-697
[51] W. Gleinser, H. Braun, C. Friedrich, H. J. Cantow. Correlation between rheology and morphology of compatibilized immiscible blends [J]. Polymer, 1994, 35(1):128-135
[52] M. Bousmina, P. Bataille, S. Sapieha, H. P. Schreiber. Comparing the effect of corona treatment and block copolymer addition on rheological properties of polystyrene/polyethylene blends [J]. Journal of Rheology, 1995, 39(3):499-517
[53] C. Lacroix, M. Aressy, P. J. Carreau. Linear viscoelastic behavior of molten polymer blends: A comparative study of the Palierne and Lee and Park models [J]. Rheologica Acta, 1997, 36:416-428
[54] C. Lacroix, M. Grmela, P. J. Carreau. Relations between rheology and morphology for immiscible molten blends of polypropylene and ethylene copolymers under shear flow [J]. Journal of Rheology, 1998, 42(1): 41-62
[55] P. H. P. Macaubas, N. R. Demarquette. Morphologies and interfacial tensions of immiscible polypropylene/polystyrene blends modified with triblock copolymers [J]. Polymer, 2001, 42: 2543-2554
[56] M. A. Villar, M. D. Failla, R. Quijada, R. S. Mauler, E. M. Vallés, G. B. Galland and L. M. Quinzani. Rheological characterization of molten ethylene–olefin copolymers synthesized with Et[Ind]2ZrCl2/MAO catalyst[J]. Polymer, 2001, 42(22):9269-9279
[57] J. K. Kim, H. W. Son. The rheological properties of polystyrene/poly(vinylmethylether) blend near the critical region and in the homogenous region[J]. Polymer, 1999, 40:6789-6801
[58] 姜苏俊,李光宪,贾向明,吴兆权,陆玉本. 聚合物共混体系相行为的动态流变学研究进展[J]. 高分子材料科学与工程,2003,19(6):27-31
[59] 郁锋,李树材. 聚合物体系相行为的流变学研究[J]. 中国塑料,2001,15(1):19-23
[60] 刘萌戈,周持兴. 化学反应中聚合物流变动力学的研究进展[J]. 高分子材料科学与工程,2005,21(4):42-45,50
[61] Q. Zheng, Y. X. Cao, M. Du. Dynamic rheological behavior of polypropylene filled with ultra-fine powdered rubber particles[J]. Chinese Journal of Polymer Science, 2004, 22(4): 363-367
[62] H. H. Ismail, M. Nasir. Morphological studies of uncompatibilized and compatibilized polystyrene/polypropylene blend [J]. Polymer testing, 2002, 21: 263-267
[63] H. H. Ismail, M. Nasir. The effect of various compatibilizers on mechanical properties of polystyrene/polypropylene blend [J]. Polymer testing, 2002, 21: 163-170
[64] G. Radonjic. Compatibilization effects of styrenic/rubber block copolymers in polypropylene/polystyrene blends [J]. Journal of Applied Polymer Science, 1999, 72: 291-307
[65] 汪多仁 编著. 现代高分子材料生产及应用手册[M],北京:中国石化出版社,2002,P25
[66] Z. Horak, J. kolarik, M. Sipek, V. Hynek, F. vecerka. Gas permeability and mechanical properties of polystyrene-polypropylene blends [J]. Journal of Applied Polymer Science, 1998, 69: 2615-2623
[67] L. Dorazio, R. Guarino, C. Mancarella, E. Martuscelli, G. Cecchin. Morphology, crystallization, and thermal behavior of isotactic polypropylene/polystyrene blends: effects of the addition of a graft copolymer of propylene with styrene [J]. Journal of Applied Polymer Science, 1999, 72: 1429-1442
[68] J. Schellenberg. Properties of the polyethylene/poly(2,6-dimethyl-1,4-phenylene ether)/polystyrene system in the presence of SEPS block copolymers [J]. Journal of Applied Polymer Science, 1997, 64(9): 1835-1842
[69] D. Hlavata, J. Hromadkova, I. Fortelny, V. Hasova, J. Pulda. Compatibilization efficiency of styrene-butadiene triblock copolymers in polystyrene-polypropylene blends with varying compositions [J]. Journal of Applied Polymer Science, 2004, 92: 2431-2441
[70] Z. Li, Y. Ke, Y. L. Hu. Study on a new kind of polypropylene-g-polystyrene: preparation and application [J]. Journal of Applied Polymer Science, 2004, 93: 314-322
[71] S. Raha, N. Kao, S. N. Bhattacharya. Effect of polypropylene on the rheolgy of co-continuous PP/SEBS blends [J]. Polymer engineering and Science, 2005, 1432-1444
[72] J. Kim, J. Kwak, D. Kim. Synthesis and characterization of polyethylene-g-polystyrene as the compatibilizer for polypropylene/polystyrene blends [J]. Polymers for advanced technologies, 2003, 14: 58-65
[73] S. J. Syed Mustafa, M. R. Nor Azlan, M. Y. Ahmad Fuad, Z. A. Mohd Ishak, U. S. Ishiaku. Polypropylene/polystyrene blends—prelininary studies for compatibilization by aromatic-grafted polypropylene [J]. Journal of Applied Polymer Science, 2001, 82: 428-434
[74] 赵义平,李树才,揣成智.反应性共混体系研究进展[J]. 中国塑料,2000,14(9):6-11
[75] 杨军忠. PP/PS/SEBS 三元共混物的研究[J]. 中国塑料,2000,14(11):32-37
[76] 高军,佘万能. 新型热塑性弹性体 SEBS[J]. 化工新型材料, 2004,32(4):21-24
[77] 杜仕国,高欣宝,宣兆龙. 高分子合金的反应性增容技术与应用[J]. 中国塑料,1999,13(7):7-11
[78] L. Assoun, S. C. Manning, R. B. Moore. Carboxylation of polypropylene by reactive extrusion with functionalised peroxides [J]. Polymer, 1998, 39(12): 2571-2577
[79] B. wong, W. E. Baker. Melt rheology of graft modified polypropylene [J]. Polymer, 38(11): 2781-2789
[80] 谢续明,李颖,张景春. 马来酸酐-苯乙烯熔融接枝聚丙烯的影响因素及其性能研究[J]. 高分子学报,2002,1:7-12
[81] W. H. Jo, C. D. Park. Preparation of functionalized polystyrene by reactive extrusion and its blend with polyamide6 [J]. Polymer, 1996, 37(9): 1709-1714
[82] F. C. Chang, Y. C. Hwu. Styrene maleic anhydride and styrene glycidyl methacrylate copolymers as in situ reactive compatibilizers of polystyrene/nylon6,6 blends [J]. Polymer Engineering and Science, 1991, 31(21): 1509-1519
[83] C. A. Orr, J. J. Cernohous, P. Guegan, A. Hirao, H. K. Jeon, C. W. Macosko. Homogeneous reactive coupling of terminally functional polymers [J]. Polymer, 2001, 42: 8171-8178
[84] H. M. Wilhelm, M. I. Felisberti. Reactive compatibilization of maleated polypropylene and maleated poly(styrene-b-butadiene-b-styrene) blends [J]. Journal of Applied Polymer Science, 2002, 86(2): 366-371
[85] J. Pionteck, P. Potschke, N. Proske, H. Y. Zhao, H. Malz. Morphology of reactivePP/PS blends with Hyperbranched Polymers [J]. Macromolecular Symposia, 2003, 198: 209-220
[86] S. Kim, J. K. Kim, C. E. Park. Effect of molecular architecture of in situ reactive compatibilizer on the morphology and interfacial activity of an immiscible polyolifin/polystyrene blend [J]. Polymer, 1997, 38(8): 1809-1815
[87] J. K. Kim, D. K. Yi, H. K. Jeon, C. E. Park. Effect of the functional group inhomogeneity of an in situ reactive compatibilizer on the morphology and rheological properties of immiscible polymer blends [J]. Polymer, 1999, 40: 2737-2743
[88] P. Potschke, H. Malz, J. Pionteck. Influence of interfacial reaction on morphology in modified PP/PS blends [J]. Macromolecular Symposia, 2000, 149: 231-246
[89] J. Pionteck, P. Potschke, U. Schulze, N. Proske, A. Kaya, H. Zhao, H. Malz. Influence of reactive compatibilization on the morphology of polypropylene/polystyrene blends [J]. Macromolecular Symposia, 2004, 214: 279-288
[90] L. Nie, R. Narayan, E. A. Grulke. Effect of intramolecular reaction on the branching process of grafting reaction between two reactive polymers [J]. Polymer, 1995, 36(7): 1469-1478
[91] T. J. Mulkern, N. C. B. Tan. Processing and characterization of reactive polystyrene/hyperbranched polyester blends [J]. Polymer, 2000, 41: 3193-3203
[92] M. F. Zhu, W. D. Yan, Y. Lu, Y. M. Chen, H-J. P. Adler, P. Potschke, J. Pionteck. Modification of PP by blending with PS and reactive polymers [J]. Macromolecular Symposia, 2001, 164: 369-376
[93] Y. Roiter, V. Samaryk, S. Varvarenko, N. Nosova, I. Tarnavchyk, J. Pionteck, P. Potschke, S. voronov. Peroxide-containing compatibilizer for polypropylene blends with other polymers [J]. Macromolecular Symposia, 2004, 210: 209-217
[94] S. voronov, V. Samaryk,Y. Roiter, J. Pionteck, P. Potschke, S. Minko, I. Tokarev, S. Varvarenko, N. Nosova. Compatibilization of polymer blends with high-molecular-weight peroxides [J]. Journal of Applied Polymer Science, 2005, 96: 232-242
[95] S. Keszei, S. Matko, G. Bertalan, P. Anna, G. Marosi, A. Toth. Progress in interface modifications: from compatibilization to adaptive and smart interphases [J]. European polymer journal, 2005, 41: 697-705
[96] C. Albano, J. Reyes, M. Ichazo, J. Gonzalez, M. Hernandez, M. Rodriguez. Mechanical, thermal and morphological behaviour of the polystyrene/polypropylene (80/20) blend, irradiated with γ–rays at low doses (0-70 kGy) [J]. Polymer degradation and stability, 2003, 80: 251-261
[97] J. Reyes, C. Albano, M. Claro, D. Moronta. Electron spin resonance studies on PS, PP and PS/PP blends under gamma irradiation [J]. Radiation physics and chemistry, 2003, 67: 453-457
[98] X. M. Xie, X. Zheng. Effect of addition of multifunctional monomers on one-step reactive extrusion of PP/PS blends [J]. Materials and design, 2001, 22: 11-14
[99] G. Dlubek, M. A. Alam. Studies of the positron lifetime and Doppler-broadened annihilation radiation of polypropylene-polystyrene alloys [J]. Polymer, 2002, 43: 4025-4031
[100] Z. Chang, J. A. Laverne. Hydrogen Production in gamma-Ray and Helium-Ion Radiolysis of Polyethylene, Polypropylene, Poly(methylmethacrylate), and Polystyrene [J]. Journal of polymer science, Part A, Polymer chemistry, 2000, 38: 1656-1661
[101] D. Li, Z. M. Liu, B. X. Han, L. P. Song, G. Y. Yang, T. Jiang. Preparation of nanometer dispersed polypropylene/polystyrene interpenetrating network using supercritical CO2 as a swelling agent [J]. Polymer, 2002, 43: 5363-5367
[102] S. B. Roscoe, C. G. Gong, J. M. J. Frechet, J. F. Walzer. Functionalized polystyrene as a versatile support for olefin polymerization catalysts [J]. Journal of polymer science, Part A, polymer chemistry, 2000, 38: 2979-2992
[103] Q. Zhang, H. Yang, Q. Fu. Kinetics-controlled compatibilization of immiscible polypropylene/polystyrene blends using nano-SiO2 particles [J]. Polymer, 2004, 45: 1913-1922
[104] S. S. Ray, S. Pouliot, M. Bousmina, L. A. Utracki. Role of organically modified layered silicate as an active interfacial modifier in immiscible polystyrene/polypropylene blends [J]. Polymer, 2004, 45: 8403-8413
[105] D. Y. Wang, C. A. Wilkie. In-situ reactive blending to prepare polystyrene-clay and polypropylene-clay nanocomposites [J]. Polymer degradation and stability, 2003, 80: 171-182
[106] M.F. Diaz, S.E. Barbosa, N.J. Capiati. Addition compatibilization of PP/PS blends by tailor-maid copolymers [J]. Polymer engineering and science, 2006,329-336
[107] G. Jannerfeldt, L. Boogh, J. -A. E. Manson. Influence of hyperbranched polymers on the interfacial tension of polypropylene/polyamide-6 blends [J]. Journal of Polymer Science, Part B, Polymer Physics, 1999, 37: 2069-2077
[108] G. Jannerfeldt, L. Boogh, J. -A. E. Manson. Tailored interfacial properties for immiscible polymers by hyperbranched polymers. Polymer, 2000, 41: 7627–7634
[109] G. Jannerfeldt, L. Boogh, J. A. E. Maanson. The morphology of hyperbranched polymer compatibilized polypropylene/polyamide 6 blends [J]. Polymer Engineering and Science, 2001, 41(2): 293-300
[110] P. Poetschke, H. Malz, J. Pionteck. Influence of interfacial reaction on morphology in modified PP/PS blends [J]. Macromolecular Symposia, 2000, 149: 231-236
[111] Y. Zhang, Y. P. Huang, K. C. Mai. Crystallization and dynamic mechanical properties of polypropylene/polystyrene blends modified with maleic anhydride and styrene [J]. Journal of Applied Polymer Science, 2005, 96(6): 2038 - 2045
[112] Y. Roiter, V. Samaryk, N. Nosova, S. Varvarenko, P. Potschke, S. Voronov. Radical processes for the creation of compatibilizing layers in polyolefinblends [J]. Macromolecular Symposia, 2001, 164: 377-387
[113] J. Pionteck, V. B. Sadhu, L. Jakisch, P. P?tschke, L. H?u?ler, A. Janke. Crosslinkable coupling agents: Synthesis and use for modification of interfaces in polymer blends [J]. Polymer, 2005, 46 (17): 6563-6574
[114] S. Varvarenko, F. Bohme, J. Pionteck, P. Potschke, V. Samaryk, Y. Roiter, S. Varvarenko, N. Nosova. Polymer peroxide compatibilizer for reactive blending of carbon-chain polymers, Theses of EuroPolymer Foundation Congress, Eindhoven, 2001, S.3 N.214
[115] 邰向阳,谢续明. PP/AS/DCP 反应共混中的 SEBS 添加效应[J].合成树脂与塑料, 1998, 15(1):35-37
[116] 邰向阳,谢续明. 聚丙烯共混物反应共混中的降解抑制[J].功能高分子学报, 1998, 11(2): 231-236
[117] 谢续明, 李颖, 张景春, 杨讯. 马来酸酐-苯乙烯熔融接枝聚丙烯的影响因素及其性能研究[J]. 高分子学报, 2002, 1: 7-12
[118] P. Cassagnau, T. Nietsch, M. Bert, A. Michel. Reactive blending by in situ polymerization of the dispersed phase [J]. Polymer, 1998, 40:131-138
[119] 王亚. 聚丙烯/聚苯乙烯(苯乙烯)原位合金的研究. 硕士学位论文,天津大学,导师:盛京,天津大学,2005 年 1 月
[120] 金慧. 聚丙烯/聚苯乙烯原位合金化的研究. 硕士学位论文,导师:盛京,天津大学,2006 年 1 月
[121] 李云岩. 多项聚合物相结构的形成与演变-PS/PP合金相结构及其演变特征.硕士学位论文,导师:盛京,天津大学,2005 年 1 月
[122] 张佩君,郑强,王旭. 催化合金研究进展[J]. 中国塑料,2003,17(5):7-11
[123] 张玉清,范志强,封麟先. 聚丙烯催化合金的相结构研究[J]. 高分子学报,2001,5:687-690
[124] S. S. Pesetskii, B. Jurkowski, O. A. Makarenko. Free radical grafting of itaconic acid and glycidyl methacrylate onto PP initiated by organic peroxides [J]. Journal of Applied Polymer Science, 2002, 86: 64-72
[125] J. A. Galloway, M. D. Montminy, C. W. Macosko. Image analysis for interfacial area and cocontinuity detection in polymer blends [J]. Polymer, 2002, 43: 4715–4722
[126] G. Khanarian. Rubber Toughened and Optically Transparent Blends of Cyclic Olefin Copolymers [J]. Polymer engineering and science, 2000, 40(12): 2590-2601
[127] V.B.Sadhu, J. Pionteck, P. P?tschke, L.Jakisch, A.Janke. Creation of Crosslinkable Interphases in Polymer Blends [J]. Macromolecular Symposia, 2004, 210: 165-174
[128] G. Pompe, P. P?tschke, J. Pionteck. Reactive melt blending of modified Polyamide and Polypropylene: Assessment of compatibilization by fractionated crystallization and blend morphology [J]. Journal of Applied Polymer Science, 2002, 86: 3445-3453
[129] R.T. Tol, G. Groeninckx, I. Vinckier, P. Moldenaers, J. Mewis. Phase morphology and stability of co-continuous (PPE/PS)/PA6 and PS/PA6 blends: effect of rheology and reactive compatibilization [J]. Polymer, 2004, 45: 2587–2601
[130] P. V. Puyvelde, S. Velankar, P. Moldenaers. Rheology and morphology of compatibilized polymer blends [J]. Current Opinion in Colloid and Interface Science, 2001, 6: 457-463
[131] J. L. Bolland. Kinetic Studies in the Chemistry of Rubber and Related Materials.I. The Thermal Oxidation of Ethyl Linoleate[J]. Proceedings of the Royal Society of London. Series A, Mathematical and Physical Sciences, 1946, 186(1005): 218-236
[132] 钟世云,许乾慰,王公善编著. 聚合物降解与稳定化[M]. 北京:化学工业出版社,2002 年 12 月,P25,P63
[133] 廖凯荣,卢泽俭,苏瑾. 聚磷酸铵型膨胀阻燃剂对聚丙烯的阻燃作用[J]. 高分子材料科学与工程,1999,15(2):59-61
[134] Q. Li, P. K. Jiang, P. Wei. Thermal Degradation Behavior of Poly(propylene) with a Novel Silicon-Containing Intumescent Flame Retardant[J]. Macromol. Mater. Eng. , 2005, 290: 912–919
[135] J. Guisandez, P. Tiemblo, J.M. Gomez-Elvira. Change of thermal and dynamic-mechanical behaviour of a metallocene isotactic polypropylene during low-temperature thermo-oxidation[J]. Polymer Degradation and Stability, 2005, 87: 543-553
[136] M. Elvira, P. Tiemblo, J.M. Gomez-Elvira. Changes in the crystalline phase during the thermo-oxidation of a metallocene isotactic polypropylene. A DSC study[J]. Polymer Degradation and Stability, 2004, 83: 509-518
[137] J.M. Gomez-Elvira, P. Tiemblo, M. Elvira, L. Matisova-Rychla, J. Rychly. Relaxations and thermal stability of low molecular weight predominantly isotactic metallocene and ZieglereNatta polypropylene[J]. Polymer Degradation and Stability, 2004, 85: 873-882
[138] N. Olivares, P. Tiemblo, J. M. Gomez-Elvira. Physicochemical processes along the early stages of the thermal degradation of isotactic polypropylene I. Evolution of the g relaxation under oxidative conditions[J]. Polymer Degradation and Stability, 1999, 65: 297-302
[139] R. Sciamanna, G. Arribas, C. Albano, E. Horie, B. Soto. Effect of different copolymers (hydrogenated and non-hydrogenated, with different molecular weights and different content of styrene) in the compatibilization of PS + PP (80+20) polyblend[J]. Mat. Res. Innovat., 2001, 4:311–321
[140] 谢晶曦,常俊标,王绪明编著[M]. 红外光谱在有机化学和药物化学中的应用[M]. 北京:科学出版社,2001年12月修订版,P46-52
[141] 谢晶曦,常俊标,王绪明编著[M]. 红外光谱在有机化学和药物化学中的应用[M]. 北京:科学出版社,2001年12月修订版,P97。
[142] S.H. Hsiao, C.H. Yu. Aromatic polyamides bearing ether and isopropylidene orhexafluoroisopropylidene links in the main chain[J]. Journal of Polymer Research, 1996, 3(4): 247-256
[143] 吴刚主编. 材料结构表征及应用[M]. 北京:化学工业出版社,2002年1月,P162
[144] H. Pehlivan, D. Balkose, S. Ulku, F. T?hm?nl?oglu. Effect of Zeolite Filler on the Thermal Degradation Kinetics of Polypropylene[J]. Journal of Applied Polymer Science, 2006,101:143–148
[145] M. L Arnal, A.J. Muller, B. Mendez. Synthesis and characterization of aPP/aPS graft copolymers[J]. Polymer Bulletin, 1996, 36: 687-694
[146] R. R. Wu, H. M. Kao, J. C. Chiang, E. M. Woo. Solid-state NMR studies on phase behavior and motional mobility in binary blends of polystyrene and poly(cyclohexyl methacrylate)[J]. Polymer, 2002, 43: 171-176
[147] E. Cloutet, Y. Gnanou, J.L. Fillaut, D. Astruc. C60 end-capped polystyrene stars[J]. Chemical Communications, 1996, 1565-1566
[148] 易大年,徐光漪编著. 核磁共振波谱在药物分析中的应用[M]. 上海:上海科学技术出版社,1985 年 10 月,P322
[149] 钟世云,许乾慰,王公善. 聚合物降解与稳定化[M]. 北京:化学工业出版社,2002 年 12 月,P78-P80
[150] 钟世云,许乾慰,王公善. 聚合物降解与稳定化[M]. 北京:化学工业出版社,2002 年 12 月,P4
[151] D.A. Anderson, E.S. Freeman. The kinetics of the thermal degradation of polystyrene and polyethylene[J]. J. Polym. Sci., 1961, 54: 253–260
[152] T. Faravelli, M. Pinciroli, F. Pisano, G. Bozzano, M. Dente, E. Ranzi. Thermal degradation of polystyrene[J]. Journal of Analytical and Applied Pyrolysis, 2001, 60: 103–121
[153] J. D. Peterson, S. Vyazovkin, C. A. Wight. Kinetics of the Thermal and Thermo-Oxidative Degradation of Polystyrene, Polyethylene and Poly(propylene)[J]. Macromol. Chem. Phys., 2001, 202(6): 775–784
[154] X. S. Zhu. Effects of acids on thermal and thermo-oxidative degradation of polystyrene[J]. Polymer degradation and stability, 1997, 57: 163-173
[155] X.S. Zhu, M. Elomaa, F. Sundholma, C. H. Lochmuller. Infrared and thermogravimetric studies of thermal degradation of polystyrene in the presence of ammonium sulfate[J]. Polymer Degradation and Stability, 1998, 62: 487-494
[156] S. Vyazovkin, I. Dranca, X.W. Fan, R. Advincula. Kinetics of the Thermal andThermo-Oxidative Degradation of a Polystyrene–Clay Nanocomposite[J]. Macromol. Rapid Commun. 2004, 25: 498–503
[157] 谢晶曦,常俊标,王绪明编著[M]. 红外光谱在有机化学和药物化学中的应用[M]. 北京:科学出版社,2001年12月修订版,P161-162
[158] 谢晶曦,常俊标,王绪明编著[M]. 红外光谱在有机化学和药物化学中的应用[M]. 北京:科学出版社,2001年12月修订版,P20。
[159] 韩蕴萍. 多相聚合物体系熔体动态过程中的相结构与行为━━高抗冲聚苯乙烯/顺丁橡胶共混过程中的结构与性能. 硕士学位论文,天津大学,导师:盛京,天津大学,2001 年 1 月
[160] S. Wu. Entanglement, friction, and free volume between dissimilar chains in compatible polymer blends[J]. J. Polym. Sci. B Polym. Phys. 1987, 25(12): 2511-2529
[161] J. H. Han, C. F. Chin, D. J. Li. Effect of flow geometry on the rheology of dispersed two-phase blends of polystyrene and poly(methacrylate)[J]. Polymer, 1995, 36(12): 2451-2462
[162] L. A. Utracki. On the viscosity-concentratin dependence of immiscible blends[J]. J. Rheo. 1991, 35(8): 1615-1637
[163] N. A. Frankel, A. Acrivos. The constitutive equation for a dilute emulsion[J]. J. Fluid Mech, 1970, 44: 65-78
[164] S. J. Choe, W. R. Schowalter. Rheological properties of nondilute suspensions of deformable paticles[J]. Phys. Fluids, 1975, 18: 420-427
[165] H. M. Lee, O. O. Park. Rheology and dynamics of immiscible polymer blends. J. Rheol. 1994, 38: 1405-1425
[166] 俞炜. 不相容聚合物共混体系分散相形态学的研究。博士学位论文,上海交通大学,导师:周持兴,上海交通大学,2000 年 10 月
© 2004-2018 中国地质图书馆版权所有 京ICP备05064691号 京公网安备11010802017129号 地址：北京市海淀区学院路29号 邮编：100083 电话：办公室：(+86 10)66554848；文献借阅、咨询服务、科技查新：66554700 |