安妥岭斑岩钼矿的成因及其深部约束
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摘要
多个火山口近同时喷发成就了托云火山群,形成塌陷破火山口、火山颈以及锥状岩席等火山机构,出露熔岩流相、岩席相和火山颈相。托云玄武岩具有贫硅富碱的特点,属于碱性玄武岩系列,既有原生岩浆的产物,也存在进化岩浆的产物,岩浆上升过程中没有遭受到地壳物质的混染,部分熔融源区经历了富CO2地幔流体交代、金云母为部分熔融源区残余相、地幔源区的多期分离、深部流体储池间的相互作用以及部分熔融源区顶部(熔融柱顶部)区域内的结晶分异作用等复杂过程。锥状岩席相玄武岩样品的SHRIMP锆石U-Pb协和年龄为48.1±1.6Ma,熔岩相和火山颈相玄武岩单颗粒锆石年龄形成一个复杂的锆石年龄谱。地幔熔融柱模型反演获得,48.1Ma时托云盆地的岩石圈的厚度为84.3km,认为托云玄武岩为托云岩石圈拆沉作用的产物,也就是说由复杂地幔源区过程以及深部流体储池间的相互作用所造就的混合流体体系由岩石圈拆沉作用释放,沿深大断裂快速就位与地表浅部。
运用地幔熔融柱模型反演获得了华北北部和太行山造山带中、新生代岩石圈厚度的演化历程,发现华北克拉通岩石圈厚度演化存在时间空间的不均一,如太行山造山带的北部、中部和南部具有三种截然不同的岩石圈演化历程。在安妥岭矿区内发现了早白垩世具有原生岩浆性质的玄武岩,运用地幔熔融柱模型反演获得了安妥岭-南大岭-南口岩石圈厚度经历小规模减薄-增厚-拆沉-稳定的演化过程,成为建立安妥岭斑岩钼矿成矿模式的深部动力学背景。
安妥岭斑岩钼矿矿区内正断层发育,5组断层形成网格式的断裂构造系统,剪节理为主,产状变化大。矿区内具有复杂的火成岩组合,其中斑岩体主要为石英二长斑岩和花岗闪长斑岩,脉岩主要包括玄武质岩墙、辉绿岩、煌斑岩、闪长玢岩、花岗闪长斑岩、二长斑岩、正长斑岩、花岗斑岩和细晶岩。石英二长斑岩和花岗闪长斑岩的SHRIMP锆石U-Pb测年结果为141.3±1.5Ma和139.4±1.7Ma,安妥岭斑岩体形成中存在额外富钾流体的注入,具有比较一致的Rb和K正异常与Th、Nb、Ta、P和Ti负异常,稀土配分模式具有右倾平滑,安妥岭斑岩体具有埃达克岩的特征,斜长石斑晶的韵律性环带表明岩浆混合作用与基性岩浆的反复注入。安妥岭煌斑岩形成于早白垩世,均有一致明显的Nb、Ta槽和Ti负异常,具有右倾、平滑、轻稀土富集的稀土配分模式,安妥岭煌斑岩的岩墙状产出方式,且其内产出碳酸盐矿物和橄榄石捕掳晶,源区组成与部分熔融程度综合控制了安妥岭煌斑岩的成分变异。
安妥岭斑岩钼矿辉钼矿矿化地段主要就位于高-低电阻率的转换带内,其中规模较大的矿化层的形成于深部高-低电阻率转换带(双层结构的深部组成部分)密切相关。安妥岭斑岩钼矿体空间形态变化大,流体包裹体以富H2O和富CO2气液两相包裹体为主,成矿期流体包裹体进行了均一温度峰值介于220℃~260℃之间,成矿期包裹体均一温度高于成矿前包裹体均一温度表明成矿流体为额外注入的高温流体,成矿流体来源于下地壳-上地幔。
安妥岭岩石圈拆沉作用为深部流体大量释放的触发机制,多半斑状结构做为隐伏矿体预测的重要岩石学标志在安妥岭斑岩钼矿地质勘探中得到验证,安妥岭斑岩钼矿成为透岩浆流体成矿理论应用的典型实例,并以此建立了安妥岭斑岩钼矿的成矿模式。
Tuoyun volcanic group was formed while several volcanoes erupted nearly same time in Tuoyun basin in southwest Tianshan Mountain. These volcanoes can be divided into two types: central-eruption-type an d flood-basalt-type. A series of volcanic apparatus were formed including calderas,volcanic necks and cone sheets.The volcanic face of lava face, cone sheet face and volcanic neck face were found in Tuoyun basin. Tuyon volcanic rocks are classified as alkali basalts with low in silicon and high in alkali. The products of both primary magma and evolved magma were found in Tuoyun basin. Basaltic magma ascended rapidly because of hosting peridotite xenoliths, which means magma was not contaminated by crustal materials. Partial melting source of Tuoyun basaltic magma, whose one of residual minerals is phlogopite, has underwent complex process, such as metasomatism of mantle fluid enriched CO2, multi-stage separation of mantle partial melting source, interaction of deep fluid pools and fractional crystallization in upper area of partial melting mantle source (melting column). SHRIMP U-Pb age of sample from cone sheet is 48.1±1.6Ma, however, zircon ages of 3 basaltic rocks from lava face and volcanic neck face shape a complex age assemblage. According to depth inversion of partial melting source by using mantle melting column model, the lithosphere thickness under Tuoyun basin at 48.1Ma is 84.3km. Tuoyun basalts is products of Tuoyun lithosphere delamination, which means a mixed fluid system formed in the complex process of mantle partial melting source and interaction of deep fluid pools was triggered to discharge, and ascended rapidly along the lithospheric fault.
Lithosphere depth evolution of north part of north China Craton and Taihang Mountain orogen area in Mesozoic-Cenozoic was received by employing mantle melting column model. Lithosphere depth evolution in two areas in Mz-Cz is a heterogeneous process, for instance, there are three distinct types lithosphere depth history for north section, middle section and south section of Taihang Mountain orogen in Mz-Cz. Antuoling basalt occurred as basaltic dyke with 1.0~2.5m in depth, and was formed in early Cretaceous (122.31Ma) by K-Ar whole rock dating. Peridotite xenolith, assemblage of carbonate and megacrysts of anorthoclase, corundum and phlogopite were found in basalt. Antuoling basalt with 46.50-50.20% in SiO2 content has suffered slightly alternation of carbonatization, chloritization and serpentinization of olivine, and chloritization and carbonatization of clinopyroxene. The compositional points of Antuoling basalt in Zr/TiO2-Nb/Y diagram fall into alkaline basalt field. According to mantle melting column model, the melting column locates from 82.5km to 75.3km in depth, which means that the lithosphere depth under Antuoling was 75.5km when Antuoling basaltic magma erupted in 122.31Ma. So Antuoling basalt is production of lithosphere delamination of North Taihang Mountain in Mesozoic. Combined with composition and ages of Nandaling basalt and Nankou mafic dykes, the lithosphere depth evolution under Antuoling-Nandaling-Nankou was established, a process of a small size delamination, thickening, delamination and keeping stable. It becomes deep dynamic condition for constructing Antuoling Mo deposit model.
Normal faults extensively distribute in Antuoling Mo deposit, and they have formed a grid-shape faults system. Shear joint develops comprehensively with diverse occurrence. There is a complex igneous assemblage, and divided into two groups: porphyry body and dykes. Antuoling porphyry body is composed mainly of quartz-monzonite porphyry in central and granodiorite porphyry in outer. Dykes type are basalt, diabase, lamprophyre, diorite porphyrite, granodiorite porphyry, monzonite porphyry, syenite porphyry, granite porphyry and aplite. SHRIMP U-Pb age results for quartz-monzonite porphyry and granodiorite porphyry are 141.3±1.5Ma and 139.4±1.7Ma, respectively. Petrography and major elements features of Antuoling porphyry body has suggested that fluid enriched in potassium has been injected in the process of porphyritic igneous rock. They shows positive anomaly for Rb and K, negative anomaly for Th, Nb,Ta, P and Ti, smoothed REE pattern with enrichment of LREE and the depletion of HREE, and characterized by adakite. Oscillatory zonings of plagioclase phenocryst in diorite porphyrite has become the proof of magma mixing and mafic magma injection during the process of porphyritic rock formation. Lamprophyre occurred in Antuoling Mo deposit was intruded in early Cretaceous, and they shows negative anomaly for Nb, Ta and Ti, smoothed REE pattern with enrichment of LREE and the depletion of HREE. Antuoling lamprophyre occurred as dykes, and olivine xenocrysts and carbonate can be found in lamprophyre, has indicated lamprophyre magma ascended rapidly, and their geochemistry features is controlled by source composition and fraction of partial melting.
Favorable mineralized areas at Antuoling Mo deposit are mainly located in the transition belt of higher-lower resistivity anomaly, i.e., the alternation belt of outer granodiorite porphyry. Furthermore, the formation of more extensive mineralization is tightly related to transition belt of higher-lower resistivity in deeper. The 3D ore bodies shape built by Micromine in Antuoling Mo deposit is irregular and complex. Re-Os model ages of molybdenite are from 144.91±0.54 Ma to 146.11±0.71Ma. Fluid inclusions in Antuoling Mo deposit are composed mainly of H2O-rich and CO2-rich types, whose homogenization temperature peak is from 220℃to 260℃. In the process of mineralization, the high temperature fluids while mineralization progressed have been injected because the homogenization temperature of fluid inclusions in molybdenum quartz is higher than those located in quartz before mineralization. According to Pb isotope of molybdenite and pyrite, the mineralization fluids come from lower crust-upper mantle.
Huge deep fluid was discharged, which triggered by the process of Antuoling lithosphere delamination. Polyporphyritic texture is an important petrological indicator for finding concealed ore body, which has been proofed in the exploration process at Antuoling Mo deposit. Antuoling porphyritic molybdenum deposit is a successful example for metallogenic theory on the transmamagtic fluids, and metallogenic model was displaced.
运用地幔熔融柱模型反演获得了华北北部和太行山造山带中、新生代岩石圈厚度的演化历程,发现华北克拉通岩石圈厚度演化存在时间空间的不均一,如太行山造山带的北部、中部和南部具有三种截然不同的岩石圈演化历程。在安妥岭矿区内发现了早白垩世具有原生岩浆性质的玄武岩,运用地幔熔融柱模型反演获得了安妥岭-南大岭-南口岩石圈厚度经历小规模减薄-增厚-拆沉-稳定的演化过程,成为建立安妥岭斑岩钼矿成矿模式的深部动力学背景。
安妥岭斑岩钼矿矿区内正断层发育,5组断层形成网格式的断裂构造系统,剪节理为主,产状变化大。矿区内具有复杂的火成岩组合,其中斑岩体主要为石英二长斑岩和花岗闪长斑岩,脉岩主要包括玄武质岩墙、辉绿岩、煌斑岩、闪长玢岩、花岗闪长斑岩、二长斑岩、正长斑岩、花岗斑岩和细晶岩。石英二长斑岩和花岗闪长斑岩的SHRIMP锆石U-Pb测年结果为141.3±1.5Ma和139.4±1.7Ma,安妥岭斑岩体形成中存在额外富钾流体的注入,具有比较一致的Rb和K正异常与Th、Nb、Ta、P和Ti负异常,稀土配分模式具有右倾平滑,安妥岭斑岩体具有埃达克岩的特征,斜长石斑晶的韵律性环带表明岩浆混合作用与基性岩浆的反复注入。安妥岭煌斑岩形成于早白垩世,均有一致明显的Nb、Ta槽和Ti负异常,具有右倾、平滑、轻稀土富集的稀土配分模式,安妥岭煌斑岩的岩墙状产出方式,且其内产出碳酸盐矿物和橄榄石捕掳晶,源区组成与部分熔融程度综合控制了安妥岭煌斑岩的成分变异。
安妥岭斑岩钼矿辉钼矿矿化地段主要就位于高-低电阻率的转换带内,其中规模较大的矿化层的形成于深部高-低电阻率转换带(双层结构的深部组成部分)密切相关。安妥岭斑岩钼矿体空间形态变化大,流体包裹体以富H2O和富CO2气液两相包裹体为主,成矿期流体包裹体进行了均一温度峰值介于220℃~260℃之间,成矿期包裹体均一温度高于成矿前包裹体均一温度表明成矿流体为额外注入的高温流体,成矿流体来源于下地壳-上地幔。
安妥岭岩石圈拆沉作用为深部流体大量释放的触发机制,多半斑状结构做为隐伏矿体预测的重要岩石学标志在安妥岭斑岩钼矿地质勘探中得到验证,安妥岭斑岩钼矿成为透岩浆流体成矿理论应用的典型实例,并以此建立了安妥岭斑岩钼矿的成矿模式。
Tuoyun volcanic group was formed while several volcanoes erupted nearly same time in Tuoyun basin in southwest Tianshan Mountain. These volcanoes can be divided into two types: central-eruption-type an d flood-basalt-type. A series of volcanic apparatus were formed including calderas,volcanic necks and cone sheets.The volcanic face of lava face, cone sheet face and volcanic neck face were found in Tuoyun basin. Tuyon volcanic rocks are classified as alkali basalts with low in silicon and high in alkali. The products of both primary magma and evolved magma were found in Tuoyun basin. Basaltic magma ascended rapidly because of hosting peridotite xenoliths, which means magma was not contaminated by crustal materials. Partial melting source of Tuoyun basaltic magma, whose one of residual minerals is phlogopite, has underwent complex process, such as metasomatism of mantle fluid enriched CO2, multi-stage separation of mantle partial melting source, interaction of deep fluid pools and fractional crystallization in upper area of partial melting mantle source (melting column). SHRIMP U-Pb age of sample from cone sheet is 48.1±1.6Ma, however, zircon ages of 3 basaltic rocks from lava face and volcanic neck face shape a complex age assemblage. According to depth inversion of partial melting source by using mantle melting column model, the lithosphere thickness under Tuoyun basin at 48.1Ma is 84.3km. Tuoyun basalts is products of Tuoyun lithosphere delamination, which means a mixed fluid system formed in the complex process of mantle partial melting source and interaction of deep fluid pools was triggered to discharge, and ascended rapidly along the lithospheric fault.
Lithosphere depth evolution of north part of north China Craton and Taihang Mountain orogen area in Mesozoic-Cenozoic was received by employing mantle melting column model. Lithosphere depth evolution in two areas in Mz-Cz is a heterogeneous process, for instance, there are three distinct types lithosphere depth history for north section, middle section and south section of Taihang Mountain orogen in Mz-Cz. Antuoling basalt occurred as basaltic dyke with 1.0~2.5m in depth, and was formed in early Cretaceous (122.31Ma) by K-Ar whole rock dating. Peridotite xenolith, assemblage of carbonate and megacrysts of anorthoclase, corundum and phlogopite were found in basalt. Antuoling basalt with 46.50-50.20% in SiO2 content has suffered slightly alternation of carbonatization, chloritization and serpentinization of olivine, and chloritization and carbonatization of clinopyroxene. The compositional points of Antuoling basalt in Zr/TiO2-Nb/Y diagram fall into alkaline basalt field. According to mantle melting column model, the melting column locates from 82.5km to 75.3km in depth, which means that the lithosphere depth under Antuoling was 75.5km when Antuoling basaltic magma erupted in 122.31Ma. So Antuoling basalt is production of lithosphere delamination of North Taihang Mountain in Mesozoic. Combined with composition and ages of Nandaling basalt and Nankou mafic dykes, the lithosphere depth evolution under Antuoling-Nandaling-Nankou was established, a process of a small size delamination, thickening, delamination and keeping stable. It becomes deep dynamic condition for constructing Antuoling Mo deposit model.
Normal faults extensively distribute in Antuoling Mo deposit, and they have formed a grid-shape faults system. Shear joint develops comprehensively with diverse occurrence. There is a complex igneous assemblage, and divided into two groups: porphyry body and dykes. Antuoling porphyry body is composed mainly of quartz-monzonite porphyry in central and granodiorite porphyry in outer. Dykes type are basalt, diabase, lamprophyre, diorite porphyrite, granodiorite porphyry, monzonite porphyry, syenite porphyry, granite porphyry and aplite. SHRIMP U-Pb age results for quartz-monzonite porphyry and granodiorite porphyry are 141.3±1.5Ma and 139.4±1.7Ma, respectively. Petrography and major elements features of Antuoling porphyry body has suggested that fluid enriched in potassium has been injected in the process of porphyritic igneous rock. They shows positive anomaly for Rb and K, negative anomaly for Th, Nb,Ta, P and Ti, smoothed REE pattern with enrichment of LREE and the depletion of HREE, and characterized by adakite. Oscillatory zonings of plagioclase phenocryst in diorite porphyrite has become the proof of magma mixing and mafic magma injection during the process of porphyritic rock formation. Lamprophyre occurred in Antuoling Mo deposit was intruded in early Cretaceous, and they shows negative anomaly for Nb, Ta and Ti, smoothed REE pattern with enrichment of LREE and the depletion of HREE. Antuoling lamprophyre occurred as dykes, and olivine xenocrysts and carbonate can be found in lamprophyre, has indicated lamprophyre magma ascended rapidly, and their geochemistry features is controlled by source composition and fraction of partial melting.
Favorable mineralized areas at Antuoling Mo deposit are mainly located in the transition belt of higher-lower resistivity anomaly, i.e., the alternation belt of outer granodiorite porphyry. Furthermore, the formation of more extensive mineralization is tightly related to transition belt of higher-lower resistivity in deeper. The 3D ore bodies shape built by Micromine in Antuoling Mo deposit is irregular and complex. Re-Os model ages of molybdenite are from 144.91±0.54 Ma to 146.11±0.71Ma. Fluid inclusions in Antuoling Mo deposit are composed mainly of H2O-rich and CO2-rich types, whose homogenization temperature peak is from 220℃to 260℃. In the process of mineralization, the high temperature fluids while mineralization progressed have been injected because the homogenization temperature of fluid inclusions in molybdenum quartz is higher than those located in quartz before mineralization. According to Pb isotope of molybdenite and pyrite, the mineralization fluids come from lower crust-upper mantle.
Huge deep fluid was discharged, which triggered by the process of Antuoling lithosphere delamination. Polyporphyritic texture is an important petrological indicator for finding concealed ore body, which has been proofed in the exploration process at Antuoling Mo deposit. Antuoling porphyritic molybdenum deposit is a successful example for metallogenic theory on the transmamagtic fluids, and metallogenic model was displaced.
引文
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