低成本无机陶瓷膜制备研究进展
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摘要
无机陶瓷膜是MBR污水处理技术的关键,与有机膜相比,无机膜具有化学稳定性好,耐酸碱、耐有机溶剂,孔径分布窄,分离效率高且易控制,热稳定性强等优点。本文介绍了无机陶瓷膜制备过程的工艺流程且分析了成本构成要素,主要从陶瓷膜制备过程中原料成分、制备方法、影响降低成本的因素、烧结温度的控制过程等方面分析降低成本的方法,通过建立一套低成本的理论框架,实现陶瓷膜材料选择与工艺参数的共同优化,促进无机陶瓷膜技术的快速发展,并对后期研究无机陶瓷膜的发展方向进行了探讨与展望。
Inorganic ceramic membrane is the key to MBR wastewater treatment technology. Compared with organic membrane,inorganic membrane has good chemical stability,acid and alkali resistance,organic solvent resistance,narrow pore size distribution,high separation efficiency and easy control,and strong thermal stability. This paper introduces the process flow of the preparation process of inorganic ceramic membrane and analyzes the cost components. It mainly analyzes the method of reducing the cost from the aspects of raw material composition,preparation method,factors affecting cost reduction and control process of sintering temperature in the preparation process of ceramic membrane. Through the establishment of a low-cost theoretical framework,the ceramic membrane material selection and process parameters are optimized together,and the rapid development of inorganic ceramic membrane technology is promoted. The development direction of inorganic ceramic membranes is discussed and prospected.
Inorganic ceramic membrane is the key to MBR wastewater treatment technology. Compared with organic membrane,inorganic membrane has good chemical stability,acid and alkali resistance,organic solvent resistance,narrow pore size distribution,high separation efficiency and easy control,and strong thermal stability. This paper introduces the process flow of the preparation process of inorganic ceramic membrane and analyzes the cost components. It mainly analyzes the method of reducing the cost from the aspects of raw material composition,preparation method,factors affecting cost reduction and control process of sintering temperature in the preparation process of ceramic membrane. Through the establishment of a low-cost theoretical framework,the ceramic membrane material selection and process parameters are optimized together,and the rapid development of inorganic ceramic membrane technology is promoted. The development direction of inorganic ceramic membranes is discussed and prospected.
引文
[1]曹静杰,董新法,董应超,等.无机陶瓷膜分离技术应用研究进展[J].广州化工,2014,42(9):19-21.
[2]崔佳,王鹤立,龙佳.无机陶瓷膜在水处理中的研究进展[J].工业水处理,2011,31(2):13-16.
[3] Jie L,Si X,Wang N. In situ Repairing the Large Defects of Macroporous Ceramic membranes by Polyelectrolyte-coated Nanoparticles[J].Separation&Purification Technology,2017,183:318-326.
[4]孔凡军,马华兴,张栋,等.无机陶瓷膜在氯化钠生产中的应用[J].盐科学与化工. 2015,44(7):32-34.
[5]新型陶瓷分离膜制备科学基础和性能研究[D].合肥:中国科学技术大学,2006.
[6]付长翼,黄孝华,胡紫.陶瓷膜制备低成本化途径的研究进展[J].陶瓷研究,2017(s3).
[7]李友铃,邓志毅,柳寒等.无机陶瓷膜分离耦合高级氧化技术在水处理中的研究进展[J].膜科学与技术,2017,37(5):134-141.
[8] Lorente-Ayza M M,Sánchez E,Sanz V. Influence of starch content on the properties of low-cost microfiltration ceramic membranes[J]. Ceramics International,2015,41(10):S0272884215013826.
[9]秦建良,田蒙奎,陶文亮,等.利用煤矸石制备无机陶瓷膜支撑体[J].中国陶瓷,2015(6):59-63.
[10]同帜,高婷婷,高丹等.烧结制度对添加CuO-TiO2制备的Al2O3陶瓷膜支撑体性能的影响[J].膜科学与技术,2018(1):37-43.
[11] Liu S H,Guo L L,Wang Q P. Preparation of Aluminum Composite Ceramic Membrane by Inorganic Precursor Sol-Gel Method[J]. Applied Mechanics and Materials,2012,268-270:4.
[12] Chen X,Wei Z,Lin Yl. Preparation of high-fluxγ-alumina nanofiltration membranes by using a modified sol-gel method[J]. Microporous&Mesoporous Materials,2015,214:195-203.
[13]刘敏芳,任立琴,占启安,等.溶胶-凝胶法制备低温烧结无机陶瓷膜[J].中国陶瓷,2016(12):31-34.
[14]廉晓庆,隆万坤,徐菊花,等.液相先驱体转化结合溶胶凝胶法合成Zr C-SiC纳米复合粉体[J].硅酸盐通报,2018,37(1):195-199.
[15]溶胶—凝胶法在磷酸钙陶瓷制备中的应用研究[D].成都:西南交通大学,2009.
[16] Maria-Magdalena Lorente-Ayza,Maria-Jose Orts,Gozalbo A. Preparation of Chamottes as a Raw Material for Low-Cost Ceramic Membranes[J].International Journal of Applied Ceramic Technology,2016,13(6):1149-1158.
[17]杨桂忠,杨座国.低成本陶瓷膜制备技术研究进展[J].上海化工,2008(4):14-18.
[18] Li K. Preparation of Ceramic Membranes[M]. New Jersey:John Wibey&Sons,Ltd.,2007.
[19]张杰.利用废弃资源制备多孔陶瓷膜支撑体的研究[D].贵阳:贵州大学,2017.
[20]刘晶.低成本固废基无机陶瓷膜的反应制备与性能研究[D].广州:华南理工大学,2015.
[21]张学斌,任祥军,刘杏芹,等.几种非金属矿物基陶瓷分离膜的制备和表征[J].中国非金属矿工业导刊,2004(5):53-55+62。
[22]韩磊,王军凯,邓先功,等.硅酸钠添加量对多孔硅藻土陶瓷性能的影响[J].机械工程材料,2018,42(4):73-77.
[23]孙小娟,董旭娟,同帜,等. Al2O3陶瓷膜支撑体制备方案的优化探究[J].中国陶瓷,2018,54(7):19-24.
[24]同帜,王婕,崔双科,等. CuO烧结助剂对陶瓷管支撑体性能的影响[J].膜科学与技术,2014,34(4):67-70.
[25] Sarkar S. Process for Preparation of Low Cost Clay-Alumina Multichannel Ceramic Membrane for Liquid Filtration Application[J]. Transactions of the Indian Ceramic Society,2014,73(3):239-244.
[26]佚名.一种多孔高铝陶瓷材料的制备方法及其制得的产品:CN 102432328 B[P]. 2013.
[27]同帜,朱庆鹏,李大川,等.管式多孔α-Al2O3陶瓷膜支撑体的制备与性能表征[J].膜科学与技术,2013,33(2):10-15.
[28]张帅,李迎,黄文帅,等.羧甲基纤维素对氧化铝陶瓷支撑体性能的影响研究[J].粉末冶金技术,2016,34(3):205-208+221+227.
[29]李茂模,刘馨雨.大尺寸等静压真空电子陶瓷管的研制与探索[J].真空电子技术,2004(4):52-53.
[30]贺毅强,徐虎林,钱晨晨,等.机械合金化后注射成形制备Cu/Al2O3复合材料的显微组织与力学性能[J].材料工程,2019,47(03):154-161.
[31]王延庆,吉喆,崔永莉,等.基于快速原型的金属粉浆无压浇注成型与烧结[J].机械工程材料,2007(12):51-53+65.
[32] Liu K Q,Luo Z Y,Kang F. Shape and Distribution of Pores in SiC Ceramic Membrane Supports Formed by Extrusion Molding[J]. Key Engineering Materials,2016,680(453):99-102.
[33] Vinoth Kumar R,Kumar Ghoshal A,et al. Elaboration of novel tubular ceramic membrane from inexpensive raw materials by extrusion method and its performance in microfiltration of synthetic oily wastewater treatment[J]. Journal of Membrane Science,2015,490:92-102.
[34]鲍崇高,许飞.挤出成形法制备多孔SiC陶瓷工艺研究[J].稀有金属材料与工程,2011(s1):604-607.
[35]杨志华,余萍,肖定全,等.利用无机盐制备γ-Al2O3粉体与薄膜的工艺技术研究[J].功能材料,2004,35(4):474-476.
[36]同帜,行静,樊璐,等.以硝酸铝为前驱体制备Al2O3薄膜及其表征[J].膜科学与技术,2017,37(05):56-60+74.
[37]张建松,吴克宏,冉琳,等.动态膜支撑体及涂膜材料[J].化学工程师,2010,24(1):31-33+37.
[38] Lu L,Feng G G. The Study on Preparation Process Optimization of Ceramic Membrane Layer[J]. Applied Mechanics&Materials,2012,217-219:1230-1234.
[39] Jin Z,Fan Y,Xu N. Modified dip-coating method for preparation of pinhole-free ceramic membranes[J]. Journal of Membrane Science,2011,367(1):14-20.
[40] Mohammad,Mahdyarfar,Toraj,等.支撑炭膜制备过程中的缺陷形成与避免[J].新型炭材料,2013,28(5):369-377.
[41]宋成文,邱英华,王同华,等.成膜条件对聚丙烯腈炭膜性能的影响[J].化工新型材料,2007,35(11):45-46.
[42]施圣芳,谷景华,张跃.负载型Ti O2超滤膜的制备[J].功能材料,2015,46(10):10148-10152.
[43]陆亚伟,陈献富,闻娟娟,等.改进的颗粒溶胶工艺制备高性能Zr O2-Ti O2复合纳滤膜[J].化工学报,2015,66(9):3769-3775.
[44]杨桂忠,杨座国,刘妲妮,等.支撑体生坯浸涂溶胶(一步法)制备不对称结构陶瓷超滤膜的研究[J].中国陶瓷,2008,44(12):23-25.
[45]朱明燕.多孔氧化锆陶瓷膜涂膜液的制备及相关基础研究[D].武汉:中国地质大学,2005.
[46] Uhlhorn R J R,Keizer K,Burggraaf A J. Gas transport and separation with ceramic membranes. Part 1. Multilayer diffusion and capillary condensation(J). J Menbr. Sci. 2010,66; 29-269
[47]王佳悦,马明晶,同帜,等.溶胶-凝胶法制备Al2O3-Zr O2复合膜及其性能表征[J].功能材料,2018,49(5):5120-5125.
[48]郝艳霞,李健生,王连军.固态粒子烧结法制备YSZ超滤膜[J].中国陶瓷工业,2005(01):22-25.
[49]牛冬梅.阳极氧化法制备Ti O2纳米管阵列的研究[J].科技视界,2018(36):116-117.
[50]吴慰,张琼,苏轼,等.激光化学气相沉积法制备YBa2Cu3O7-δ超导薄膜[J].武汉工程大学学报,2018,40(5):514-523.
[51] Lange R S A D,Hekkink J H A,Keizer K. Formation and characterization of supported microporous ceramic membranes prepared by sol-gel modification techniques[J]. Journal of Membrane Science,2017,99(1):57-75.
[52] Li X,Wang Y,Pan J. The preparation and application of a low-cost multi-channel tubular inorganic-organic composite microfiltration membrane[J]. Separation&Purification Technology,2015,151:131-138.
[2]崔佳,王鹤立,龙佳.无机陶瓷膜在水处理中的研究进展[J].工业水处理,2011,31(2):13-16.
[3] Jie L,Si X,Wang N. In situ Repairing the Large Defects of Macroporous Ceramic membranes by Polyelectrolyte-coated Nanoparticles[J].Separation&Purification Technology,2017,183:318-326.
[4]孔凡军,马华兴,张栋,等.无机陶瓷膜在氯化钠生产中的应用[J].盐科学与化工. 2015,44(7):32-34.
[5]新型陶瓷分离膜制备科学基础和性能研究[D].合肥:中国科学技术大学,2006.
[6]付长翼,黄孝华,胡紫.陶瓷膜制备低成本化途径的研究进展[J].陶瓷研究,2017(s3).
[7]李友铃,邓志毅,柳寒等.无机陶瓷膜分离耦合高级氧化技术在水处理中的研究进展[J].膜科学与技术,2017,37(5):134-141.
[8] Lorente-Ayza M M,Sánchez E,Sanz V. Influence of starch content on the properties of low-cost microfiltration ceramic membranes[J]. Ceramics International,2015,41(10):S0272884215013826.
[9]秦建良,田蒙奎,陶文亮,等.利用煤矸石制备无机陶瓷膜支撑体[J].中国陶瓷,2015(6):59-63.
[10]同帜,高婷婷,高丹等.烧结制度对添加CuO-TiO2制备的Al2O3陶瓷膜支撑体性能的影响[J].膜科学与技术,2018(1):37-43.
[11] Liu S H,Guo L L,Wang Q P. Preparation of Aluminum Composite Ceramic Membrane by Inorganic Precursor Sol-Gel Method[J]. Applied Mechanics and Materials,2012,268-270:4.
[12] Chen X,Wei Z,Lin Yl. Preparation of high-fluxγ-alumina nanofiltration membranes by using a modified sol-gel method[J]. Microporous&Mesoporous Materials,2015,214:195-203.
[13]刘敏芳,任立琴,占启安,等.溶胶-凝胶法制备低温烧结无机陶瓷膜[J].中国陶瓷,2016(12):31-34.
[14]廉晓庆,隆万坤,徐菊花,等.液相先驱体转化结合溶胶凝胶法合成Zr C-SiC纳米复合粉体[J].硅酸盐通报,2018,37(1):195-199.
[15]溶胶—凝胶法在磷酸钙陶瓷制备中的应用研究[D].成都:西南交通大学,2009.
[16] Maria-Magdalena Lorente-Ayza,Maria-Jose Orts,Gozalbo A. Preparation of Chamottes as a Raw Material for Low-Cost Ceramic Membranes[J].International Journal of Applied Ceramic Technology,2016,13(6):1149-1158.
[17]杨桂忠,杨座国.低成本陶瓷膜制备技术研究进展[J].上海化工,2008(4):14-18.
[18] Li K. Preparation of Ceramic Membranes[M]. New Jersey:John Wibey&Sons,Ltd.,2007.
[19]张杰.利用废弃资源制备多孔陶瓷膜支撑体的研究[D].贵阳:贵州大学,2017.
[20]刘晶.低成本固废基无机陶瓷膜的反应制备与性能研究[D].广州:华南理工大学,2015.
[21]张学斌,任祥军,刘杏芹,等.几种非金属矿物基陶瓷分离膜的制备和表征[J].中国非金属矿工业导刊,2004(5):53-55+62。
[22]韩磊,王军凯,邓先功,等.硅酸钠添加量对多孔硅藻土陶瓷性能的影响[J].机械工程材料,2018,42(4):73-77.
[23]孙小娟,董旭娟,同帜,等. Al2O3陶瓷膜支撑体制备方案的优化探究[J].中国陶瓷,2018,54(7):19-24.
[24]同帜,王婕,崔双科,等. CuO烧结助剂对陶瓷管支撑体性能的影响[J].膜科学与技术,2014,34(4):67-70.
[25] Sarkar S. Process for Preparation of Low Cost Clay-Alumina Multichannel Ceramic Membrane for Liquid Filtration Application[J]. Transactions of the Indian Ceramic Society,2014,73(3):239-244.
[26]佚名.一种多孔高铝陶瓷材料的制备方法及其制得的产品:CN 102432328 B[P]. 2013.
[27]同帜,朱庆鹏,李大川,等.管式多孔α-Al2O3陶瓷膜支撑体的制备与性能表征[J].膜科学与技术,2013,33(2):10-15.
[28]张帅,李迎,黄文帅,等.羧甲基纤维素对氧化铝陶瓷支撑体性能的影响研究[J].粉末冶金技术,2016,34(3):205-208+221+227.
[29]李茂模,刘馨雨.大尺寸等静压真空电子陶瓷管的研制与探索[J].真空电子技术,2004(4):52-53.
[30]贺毅强,徐虎林,钱晨晨,等.机械合金化后注射成形制备Cu/Al2O3复合材料的显微组织与力学性能[J].材料工程,2019,47(03):154-161.
[31]王延庆,吉喆,崔永莉,等.基于快速原型的金属粉浆无压浇注成型与烧结[J].机械工程材料,2007(12):51-53+65.
[32] Liu K Q,Luo Z Y,Kang F. Shape and Distribution of Pores in SiC Ceramic Membrane Supports Formed by Extrusion Molding[J]. Key Engineering Materials,2016,680(453):99-102.
[33] Vinoth Kumar R,Kumar Ghoshal A,et al. Elaboration of novel tubular ceramic membrane from inexpensive raw materials by extrusion method and its performance in microfiltration of synthetic oily wastewater treatment[J]. Journal of Membrane Science,2015,490:92-102.
[34]鲍崇高,许飞.挤出成形法制备多孔SiC陶瓷工艺研究[J].稀有金属材料与工程,2011(s1):604-607.
[35]杨志华,余萍,肖定全,等.利用无机盐制备γ-Al2O3粉体与薄膜的工艺技术研究[J].功能材料,2004,35(4):474-476.
[36]同帜,行静,樊璐,等.以硝酸铝为前驱体制备Al2O3薄膜及其表征[J].膜科学与技术,2017,37(05):56-60+74.
[37]张建松,吴克宏,冉琳,等.动态膜支撑体及涂膜材料[J].化学工程师,2010,24(1):31-33+37.
[38] Lu L,Feng G G. The Study on Preparation Process Optimization of Ceramic Membrane Layer[J]. Applied Mechanics&Materials,2012,217-219:1230-1234.
[39] Jin Z,Fan Y,Xu N. Modified dip-coating method for preparation of pinhole-free ceramic membranes[J]. Journal of Membrane Science,2011,367(1):14-20.
[40] Mohammad,Mahdyarfar,Toraj,等.支撑炭膜制备过程中的缺陷形成与避免[J].新型炭材料,2013,28(5):369-377.
[41]宋成文,邱英华,王同华,等.成膜条件对聚丙烯腈炭膜性能的影响[J].化工新型材料,2007,35(11):45-46.
[42]施圣芳,谷景华,张跃.负载型Ti O2超滤膜的制备[J].功能材料,2015,46(10):10148-10152.
[43]陆亚伟,陈献富,闻娟娟,等.改进的颗粒溶胶工艺制备高性能Zr O2-Ti O2复合纳滤膜[J].化工学报,2015,66(9):3769-3775.
[44]杨桂忠,杨座国,刘妲妮,等.支撑体生坯浸涂溶胶(一步法)制备不对称结构陶瓷超滤膜的研究[J].中国陶瓷,2008,44(12):23-25.
[45]朱明燕.多孔氧化锆陶瓷膜涂膜液的制备及相关基础研究[D].武汉:中国地质大学,2005.
[46] Uhlhorn R J R,Keizer K,Burggraaf A J. Gas transport and separation with ceramic membranes. Part 1. Multilayer diffusion and capillary condensation(J). J Menbr. Sci. 2010,66; 29-269
[47]王佳悦,马明晶,同帜,等.溶胶-凝胶法制备Al2O3-Zr O2复合膜及其性能表征[J].功能材料,2018,49(5):5120-5125.
[48]郝艳霞,李健生,王连军.固态粒子烧结法制备YSZ超滤膜[J].中国陶瓷工业,2005(01):22-25.
[49]牛冬梅.阳极氧化法制备Ti O2纳米管阵列的研究[J].科技视界,2018(36):116-117.
[50]吴慰,张琼,苏轼,等.激光化学气相沉积法制备YBa2Cu3O7-δ超导薄膜[J].武汉工程大学学报,2018,40(5):514-523.
[51] Lange R S A D,Hekkink J H A,Keizer K. Formation and characterization of supported microporous ceramic membranes prepared by sol-gel modification techniques[J]. Journal of Membrane Science,2017,99(1):57-75.
[52] Li X,Wang Y,Pan J. The preparation and application of a low-cost multi-channel tubular inorganic-organic composite microfiltration membrane[J]. Separation&Purification Technology,2015,151:131-138.
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