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BiIO_4/Bi_2WO_6复合光催化剂及可见光催化活性研究
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  • 英文篇名:Study on BiIO_4/Bi_2WO_6 Composite Photocatalyst and Its Visible Light Catalytic Activity
  • 作者:张丽红
  • 英文作者:ZHANG Li-hong;Department of Biology Science and Chemistry,Fujian Normal University Minnan Science and Technology Institute;
  • 关键词:光催化 ; 钨酸铋 ; 碘酸铋
  • 英文关键词:photocatalysis;;bismuth tungstate;;bismuth iodate
  • 中文刊名:GZHA
  • 英文刊名:Guangzhou Chemical Industry
  • 机构:福建师范大学闽南科技学院生命科学与化学系;
  • 出版日期:2019-05-23
  • 出版单位:广州化工
  • 年:2019
  • 期:v.47
  • 基金:福建省教育厅科技项目(JAT170878)
  • 语种:中文;
  • 页:GZHA201910030
  • 页数:4
  • CN:10
  • ISSN:44-1228/TQ
  • 分类号:88-90+126
摘要
以Bi(NO_3)_3·5H_2O、Na_2W_4·2H_2O和I_2O_5为原料,使用水热法合成复合催化剂Bi IO_4/Bi_2WO_6。用甲基橙作为污染物并以250 W金卤灯模拟太阳光光源,研究复合催化剂的催化性能,结果表明复合催化剂较纯的钨酸铋和碘酸铋催化降解甲基橙的性能有所提高,可达93.66%。同时利用固体紫外-可见漫反射测试(UV-vis DRS)、X射线光电子能谱(XPS),对合成样品进行表征,研究所得Bi IO_4/Bi_2WO_6的结构和性能。
        With Bi(NO_3)_3·5H_2O、Na_2WO_4·2H_2O and I_2O_5as raw materials,the composite catalysts BiIO_4/Bi_2WO_6were synthesized by hydrothermal method.Photocatalytic activity of the composite catalyst was studied by using methyl orange as contaminants and simulating 250 W metal halide lamp as the sun light.The results showed that the catalytic properties of composite catalyst compound for degradation of methyl orange had increased to 93.66%compared with Bi_2WO_6and BiIO_4.Then the synthesized samples were characterized via UV-visible diffuse-reflectance spectrum(UV-vis DRS)and X-ray photoelectron spectroscopy(XPS).
引文
[1]EliFujishima A,Honda K. Electrochemical photocatalysis of water at a semiconduct or electrode[J]. Nature,1972,238:37-38.
    [2]Asahi R,Morikawa T,Ohwaki T,et al. Visible-light Photocatalysis in nitrogen-doped titanium oxides[J]. Science,2001,293(5528):269-271.
    [3]Liu S W,Song C F,Lv M K. A novel Ti O2/Zrx Ti1-xO2composite photocatalytic film[J]. Catalysis Communications,2003,4(7):343-346.
    [4]Tian Y,Hua G M,Xu W,et al. Bismuth tungstate nano microstructures:controllable morphologies, growth mechanism and photocatalytic properties[J]. Journal of Alloys and Compounds,2011,509:724-730.
    [5]姚三丽,陈建林,王仪春.水热合成纳米Bi2WO6粉末及其可见光催化活性[J].中国环境科学,2008,28(3):242-245.
    [6]曹振博,岳银超,胡章贵. BiIO4:一种新型红外非线性光学晶体[J].人工晶体学报,2011,4:858-861.
    [7]Huang H W,Wang S B,Tian N,et al. A one-step hydrothermal preparation strategy for layered BiIO4/Bi2WO6heterojunctions with enhanced visible light photocatalytic activities[J]. RSC Advances,2014,4(11):5561-5567.
    [8]Yang J,Pan X L,Bi K,et al. One-step hydrothermal route to synthesise BiIO4/Bi2O2(BO2OH)heterostructure with improved photocatalytic performance[J]. Micro&Nano Letters,2017,12(12):944-948.

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