离子型稀土矿环境风险评估及污染治理研究进展
|
摘要
离子型稀土是关系国家安全和发展的重要战略性和保护性资源,具有配分齐全、中重稀土元素含量高、放射性比度低、综合利用价值大、提取工艺简单等优点。离子型稀土开采先后经历了池浸、堆浸和原地浸矿工艺,目前大力推广原地浸矿。矿山开采活动对环境的影响、环境评价和污染防治一直是人们关注的问题,在分析和总结近二十年来离子型稀土资源环境问题领域的研究成果基础上,从开采过程中的主要环境问题、环境监测与评价方法、环境污染防治技术等方面进行了综述,提出了进一步提高稀土回收率以及有利于解决环境问题的思路和研究方向。
Ion adsorption type rare earths are important strategic and protective resources which have significant effections on the national security and economic development. They have the advantages of complete distribution, high content of middle heavy rare earth elements, low radioactivity ratio, high comprehensive utilization value and simple extraction process. Ion adsorption rare earths mining has experienced pool leaching, heap leaching and in-situ leaching processes. At present, in-situ leaching is commonly used. The problem of environmental impact and pollution prevention are matters of concern. On the basis of analyzing and summarizing the research results of ion adsorption rare earth resources and environment problems in recent twenty years, the main environmental problems in the process of mining, environmental monitoring and evaluation methods and control technology of environmental problem have been reviewed. At last, the ideas for further improvements of the rare earth recovery rate and the research directions for solving environmental problems have been put forward.
Ion adsorption type rare earths are important strategic and protective resources which have significant effections on the national security and economic development. They have the advantages of complete distribution, high content of middle heavy rare earth elements, low radioactivity ratio, high comprehensive utilization value and simple extraction process. Ion adsorption rare earths mining has experienced pool leaching, heap leaching and in-situ leaching processes. At present, in-situ leaching is commonly used. The problem of environmental impact and pollution prevention are matters of concern. On the basis of analyzing and summarizing the research results of ion adsorption rare earth resources and environment problems in recent twenty years, the main environmental problems in the process of mining, environmental monitoring and evaluation methods and control technology of environmental problem have been reviewed. At last, the ideas for further improvements of the rare earth recovery rate and the research directions for solving environmental problems have been put forward.
引文
[1] 李永绣,周新木,刘艳珠,李东平,李静,唐群.离子吸附型稀土高效提取和分离技术进展[J].中国稀土学报,2012,30(3):258-264.Li Y X,Zhou X M,Liu Y Z,Li D P,Li J,Tang Q.Development of high efficiency extraction and separation technologies of rare earths from ion-adsorbed type deposit [J].Journal of the Society of Chinese Rare Earths,2012,30(3):258-264.
[2] 池汝安,田君.风化壳淋积型稀土矿评述[J].中国稀土学报,2007,25(6):641-650.Chi R A,Tian J.Review of weathered crust rare earth ore [J].Journal of the Society of Chinese Rare Earths,2007,25(6):641-650.
[3] 郭钟群,金解放,赵奎,王晓军,陈国梁.离子吸附型稀土开采工艺与理论研究现状[J].稀土,2018,39(1):132-141.Guo Z Q,Jin J F,Zhao K,Wang X J,Chen G L.Status of leaching technology and theory of ion adsorption type rare earth ores [J].Chinese Rare Earths,2018,39(1):132-141.
[4] 饶振华,武立群,袁源明.离子型稀土发现、命名与提取工艺发明大解密[J].中国金属通报,2007,(29):8-15.Rao Z H,WU L Q,Yuan Y M.Ion type rare earth discovery,naming and extraction technology invention decryption [J].China Metal Bulletin,2007,(29):8-15.
[5] 罗仙平,钱有军,梁长利.从离子型稀土矿浸取液中提取稀土的技术现状与展望[J].有色金属科学与工程,2012,3 (5):50-53.Luo X P,Qian Y J,Liang C L.Research progress and developing trend of rare earth extraction from ionic rare earth leach solution [J].Nonferrous Metals Science and Engineering,2012,3 (5):50-53.
[6] 李永绣,张玲,周新木.南方离子型稀土的资源和环境保护性开采模式[J].稀土,2010,31(2):80-85.Li Y X,Zhang L,Zhou X M.Resource and environment protected exploitation model for ion-type rare earth deposit in southern of China [J].Chinese Rare Earths,2010,31(2):80-85.
[7] 郭钟群,金解放,秦艳华,王晓军,钟文,赵奎.南方离子型稀土一维水平入渗规律试验研究[J].有色金属科学与工程,2017,8(2):102-106.Guo Z Q,Jin J F,Qin Y H,Wang X J,Zhong W,Zhao K.Experimental research on one-dimensional horizontal infiltration rules of ion-adsorption rare earth[J].Nonferrous Metals Science and Engineering,2017,8(2):102-106.
[8] 李永绣.稀土开发的环境工程模式[J].中国金属通报,2010(1):38-39.Li Y X.Environment protected exploitation model for ion-type rare earth deposit [J].China Metal Bulletin,2010(1):38-39.
[9] 郭钟群,金解放,王观石,秦艳华,王晓军,赵奎.风化壳淋积型稀土矿浸取动力学基础理论研究[J].有色金属科学与工程,2017,8(5):102-108.Guo Z Q,Jin J F,Wang G S,Qin Y H,Wang X J,Zhao K.Basic theory of leaching kinetics on the weathered crust elution-deposited rare earth ores[J].Nonferrous Metals Science and Engineering,2017,8(5):102-108.
[10] 田君,唐学昆,尹敬群,罗仙平.风化壳淋积型稀土矿浸取过程中基础理论研究现状[J].有色金属科学与工程,2012,3(4):48-52.Tian J,Tang X K,Yin J Q,Luo X P.Present situation of fundamental theoretical research on leaching process of weathered crust elution-deposited rare earth ore[J].Nonferrous Metals Science and Engineering,2012,3(4):48-52.
[11] 郭伟,付瑞英,赵仁鑫,赵文静,郭江源,毕娜,张君.稀土开发导致的环境问题及土壤稀土污染治理措施初探[J].安全与环境学报,2014,14(5):245-251.Guo W,Fu R Y,Zhao R X,Zhao W J,Guo J Y,Bi N,Zhang J.Eco-environment contaminations caused by the rare earth mining and the related controlling measures [J].Journal of Safety and Environment,2014,14(5):245-251.
[12] 林河成.稀土生产中的“三废”治理及环境保护[J].稀土,1996,17 (6):54-58.Lin H C.Waste disposal and environment protection in rare earth production[J].Chinese Rare Earths,1996,17 (6):54-58.
[13] 高志强,周启星.稀土矿露天开采过程的污染及对资源和生态环境的影响[J].生态学杂志,2011,30 (12):2915-2922.Gao Z Q,Zhou Q X.Contamination from rare earth ore strip mining and ins impacts on resources and eco-environment[J].Chinese Journal of Ecology,2011,30 (12):2915-2922.
[14] 肖子捷,刘祖文,张念.离子型稀土采选工艺环境影响分析与控制技术[J].稀土,2014,35 (6):56-61.Xiao Z J,Liu Z W,Zhang N.Environmental impact analysis and control technology of ion rare earth mining in south of Jiangxi province [J].Chinese Rare Earths,2014,35 (6):56-61.
[15] 兰荣华.赣南离子型稀土矿环境问题及防治对策[J].求是,2004,(6):174-175.Lan R H.The environmental problems and prevention treatment of rare earth minerals in south Jiangxi province[J].QiuShi,2004,(6):174-175.
[16] 彭冬水.赣南稀土矿水土流失特点及防治技术[J].亚热带水土保持,2005,17(3):14-15.Peng D S.Characteristics of soil erosion and prevention and control of rare earth minerals in south Jiangxi[J].Subtropical Soil and Water Conservation,2005,17(3):14-15.
[17] 汤洵忠,李茂楠,杨殿.离子型稀土矿原地浸析采场滑坡及其对策[J].金属矿山,2000,(7):5-8.Tang X Z,Li M N,Yang D.Stope slide in in-situ leaching of ionic type rare earth ore and its countermeasures[J].Metal Mine,2000,(7):5-8.
[18] 黄紫彬,蔡昶,袁宪强,王强.浅析原地浸矿开采的离子型稀土矿山安全问题[J].稀土,2013,34(4):99-102.Huang Z B,Cai C,Yuan X Q,Wang Q.Analysis of safety problems of ion type rare earth mine during in-situ leaching [J].Chinese Rare Earths,2013,34(4):99-102.
[19] 雷国静,刘少峰,程三友.遥感在稀土矿区植被污染信息提取中的应用[J].江西有色金属,2006,20(2):1-5.Lei G J,Liu S F,Chen S Y,et al.Application of remote sensing data on extraction of contaminating vegetation on rare earth minerals area [J].Jiangxi Nonferrous Metals,2006,20(2):1-5.
[20] 王陶,刘衍宏,王平,刘少峰.多源多时相遥感分类技术在赣州稀土矿区环境变化检测中的应用[J].中国矿业,2009,18(11):88-91,109.Wang T,Liu Y H,Wang P,Liu S F.Application of multi-source and multi-temporal RS image classification method in REE mineral development and environment variation in the Ganzhou mineral district [J].China Mining Magazine,2009,18(11):88-91,109.
[21] 彭燕,何国金,张兆明,江威,欧阳志云,王桂周.赣南稀土矿开发区生态环境遥感动态监测与评估[J].生态学报,2016,36(6):1676-1685.Pen Y,He G J,Zhang Z M,Jiang W,Ouyang Z Y,Wang G Z.Eco-environmental dynamic monitoring and assessment of rare earth mining area in Southern Ganzhou using remote sensing[J].Acta Ecologica Sinica,2016,36(6):1676-1685.
[22] 代晶晶,王登红,陈郑辉,于扬.IKONOS遥感数据在离子吸附型稀土矿区环境污染调查中的应用研究—以赣南寻乌地区为例[J].地球学报,2013,34(3):354-360.Dai J J,Wang D H,Chen Z H,Yu Y.Environment contamination investigation of ion-absorbed rare earth ore districts based on ikonos remote sensing data:a case study of xunwu area in south Jiangxi [J].Acta Geoscientica Sinica,2013,34(3):354-360.
[23] 黄铁兰,吴海陆,黄华谷.基于多源多时相遥感数据的稀土开采状况与地质环境问题监测[J].华南地质与矿产,2014,30(2):169-175.Huang T L,Wu H L,Huang H G.Motoring of exploitation status and geological environment problem of rare earth elements ore mining base on multi-source and multi-temporal remote sensing data in northern Guangdong province[J].Geology and Mineral Resources of South China,2014,30(2):169-175.
[24] 李恒凯,吴立新,熊云飞,徐露.基于RUSLE模型的离子稀土矿区土壤侵蚀时空演变分析——以岭北矿区为例[J].稀土,2016,37(4):35-44.Li H K,Wu L X,Xiong Y F,Xu L.Spatiotemporal change of soil erosion in rare earth mining area based on RUSLE model:a case in lingbei mining area [J].Chinese Rare Earths,2016,37(4):35-44.
[25] 李恒凯,雷军,杨柳.基于Landsat影像的离子稀土矿区植被覆盖度提取及景观格局分析[J].农业工程学报,2016,32(10):267-276.Li H K,Lei J,Yang L,et al.Extraction of vegetation coverage and analysis of landscape pattern in rare earth mining area based on Landsat image [J].Transactions of the Chinese Society of Agricultural Engineering,2016,32(10):267-276.
[26] 李芹,李恒凯,杨柳,雷军.离子稀土开采扰动下的矿区荒漠化遥感监测分析——以岭北矿区为例[J].有色金属科学与工程,2017,8(3):114-120.Li Q,Li H K,Yang L,Lei J.Remote sensing monitoring of mining area desertification under disturbance of ionic rare earth mining:using Lingbei rare earth mining area as the case [J].Nonferrous Metals Science and Engineering,2017,8(3):114-120.
[27] 李恒凯,吴立新,刘小生.稀土矿区地表环境变化多时相遥感监测研究——以岭北矿区为例[J].中国矿业大学学报,2014,43(6):1087-1094.Li H K,Wu L X,Liu X S.Change detection of ground-surface environment in rare earth mining area based on multi-temporal remote sensing:a case in Lingbei rare earth mining area[J].Journal of China University of Mining & Technology,2014,43(6):1087-1094.
[28] 彭高辉,陈守余.模糊ISODATA聚类在矿山环境评价中的应用[J].安全与环境工程,2004,11(1):7-8.Peng G H,Chen S Y.The Application of fuzzy ISODATA clustering method to mine environment assessment[J].Safety and Environmental Engineering,2004,11(1):7-8.
[29] 王炳强,沈智慧,白喜庆.层次分析法(AHP)在矿山环境地质评价中的应用[J].中国煤田地质,2007,19(S2):57-59.Wang B Q,Shen Z H,Bai X Q,et al.Application of AHP in mine environmental geological evaluation[J].Coal Geology of China,2007,19(S2):57-59.
[30] 李东,周可法,孙卫东,王金林,于浩,刘慧.BP神经网络和SVM在矿山环境评价中的应用分析[J].干旱区地理,2015,38(1):128-134.Li D,Zhou K F,Sun W D,Wang J L,Yu H,Liu H.Application of BP neural network and SVM in mine environmental assessment[J].Arid Land Geography,2015,38(1):128-134.
[31] 陈奇,武强,徐佳成.专家系统在矿山环境治理中的应用研究[J].水文地质工程地质,2010,37(5):113-117.Chen Q,Wu Q,Xu J C.Application of the expert system to mine environment treatment[J].Hydrogeology & Engineering Geology,2010,37(5):113-117.
[32] 陈建平,范立民,李成,宁建民.基于模糊综合评判和 GIS 技术的矿山地质环境影响评价[J].中国煤炭地质,2014,26(2):43-48.Chen J P,Fan L M,Li C,Ning J M.Mine geological environment impact assessment based on fuzzy comprehensive evaluation and GIS technology [J].Coal Geology of China,2014,26(2):43-48.
[33] 吕铁硬,郝多虎,梅军军.赣南地区离子型稀土矿山地质环境问题评价方法探讨[J].河南科技,2013,(10):180-181.Lv T Y,Hao D H,Mei J J.Discussion on evaluation method of geological environment problems of ion type rare earth mines in South Jiangxi [J].Journal of Henan Science and Technology,2013,(10):180-181.
[34] 姚栋伟,程莉,汪洋,李天慈.基于BP神经网络和GIS的矿山地质环境评价方法[J].采矿技术,2016,16(3):56-58.Yao D W,Chen L,Wang Y,Li T C.Evaluation method of mine geological environment based on BP neural network and GIS[J].Mining Technology,2016,16(3):56-58.
[35] 王婷茹.基于MapGIS的岗下稀土矿山地质环境评价与分区[J].金属矿山,2016,(2):167-171.Wang T R.Evaluation and division of the geological environment of gangxia rare earth mine based on mapGIS [J].Metal Mine,2016,(2):167-171.
[36] 马伟,徐素宁,王润生,赵珍梅,文元亮.基于证据权法的赣南稀土矿山地质环境评价[J].地球学报,2015,36(1):103-110.Ma W,Xu S N,Wang R S,Zhao Z M,Wen Y L.Geo-environmental quality assessment of rare-earth mines in southern jiangxi province using weights-of-evidence modeling [J].Acta Geoscientica Sinica,2015,36(1):103-110.
[37] 何书,陈飞,江文才,薛国栋,袁子婷.稀土原地浸矿区地下水污染风险评价方法研究[J].有色金属科学与工程,2015,6(2):136-142.He S,Chen F,Jiang W C,Xue G D,Yuan Z T.Risk assessment of groundwater pollution in the in-situ leaching mining area of rare earth[J].Nonferrous Metals Science and Engineering,2015,6(2):136-142.
[38] 于扬,王登红,田兆雪,黄凡,赵芝,孙艳,李德先,何晗晗,邓茂春.稀土矿区环境调查SMAIMA方法体系、评价模型及其应用—以赣南离子吸附型稀土矿山为例[J].地球学报,2017,38(3):335-344.Yu Y,Wang D H,Tian Z X,Huang F,Zhao Z,Sun Y,Li D X,He H H,Deng M C.Establishment and application of SMAIMA working method system and environment evaluation model for rare earth elements mine:a case study of ion-absorption type ree mines in southern Jiangxi province [J].Acta Geoscientica Sinica,2017,38(3):335-344.
[39] 环境保护部,国家质量监督检验检疫总局.GB 26451-2011.稀土工业污染物排放标准[S].北京:中国环境科学出版社,2011.Ministry of Environment Protection of the People’s Republic of China,General Administration of Quality Supervision,Inspection and Quarantine of the People’s Republic of China.GB 26451-2011.Emission standard of pollutants for rare earths industry [S].Beijing:China Environmental Science Press,2011.
[40] 陈熙,蔡奇英,余祥单,刘以珍,葛刚,吴兰,王秀峰.赣南离子型稀土矿山土壤环境因子垂直分布—以龙南矿区为例[J].稀土,2015,36(1):23-28.Chen X,Cai Q Y,Yu X S,Liu Y Z,Ge G,Wu L,Wang X F.Vertical distributions of soil environmental factors in ion-type rare earth mining of southern Jiangxi:a case study in Longnan rare earth mining area [J].Chinese Rare Earths,2015,36(1):23-28.
[41] 刘斯文,黄园英,韩子金,刘晓端.离子型稀土矿山土壤生态修复研究与实践[J].环境工程,2015(11):160-165.Liu S W,Huang Y Y,Han Z J,Liu X R.Practices of the soil ecological remediation in ion-absorbed rare earth mine[J].Environmental Engineering,2015(11):160-165.
[42] 李永绣.离子型吸附型稀土资源与绿色提取[M].北京:化学工业出版社,2014:280.Li Y X.Ion adsorption rare earth resources and their green extraction [M].Beijing:Chemical Industry Press,2014:280.
[43] 陈振金,郑大增.稀土尾矿场土地复垦技术研究[J].上海环境科学,1998,17(9):28-31.Chen Z J,Zheng D Z.Study on land reclamation of rare earth trailing sites[J].Shanghai Environmental Sciences,1998,17(9):28-31.
[44] 李德荣,董闻达,廖汉民,利隆橙,李文煜,赖俊明.治理稀土尾砂中百喜草的生长和促苗措施的研究[J].江西农业大学学报,2001,23(1):93-95.Li D R,Dong W D,Liao H M,Li L C,Li W Y,Lai J M.A study on the growth and seedling improvement of bahia grass in the tail mineral slag of rare earth [J].Acta AgricuIturae Universitatis Jiangxiensis,2001,23(1):93-95.
[45] 曹学章,李小青,池明茹,张赶年,陈昌春.4种草用于南方稀土尾砂地种植的适宜性之比较[J].江西农业大学学报,2012,34(3):603-608.Cao X Z,Li X Q,Chi M R,Zhang G N,Chen C C.Comparison of planting suitability of four herbaceous plants on rare earth tailings in south China [J].Acta AgricuIturae Universitatis Jiangxiensis,2012,34(3):603-608.
[46] 蔡奇英,刘以珍,管毕财,吴兰,葛刚.南方离子型稀土矿的环境问题及生态重建途径[J].国土与自然资源研究,2013(5):52-54.Cai Q Y,Liu Y Z,Guan B C,Wu L,Ge G.Environmental issues and ecological restoration of ion-absorbed-type rare earth deposit in south China [J].Territory and natural resources study,2013(5):52-54.
[47] 罗才贵,罗仙平,苏佳,陈春飞,韩冬雪.离子型稀土矿山环境问题及其治理方法[J].金属矿山,2014,(6):91-96.Luo C G,Luo X P,Su J,Chen C F,Han D X.Environmental problems and treatment measures in ionic-type rare earth mine [J].Metal Mine,2014,(6):91-96.
[48] 魏娟萍,王海宁,晏江波.南方离子型稀土矿开采的环境损伤及防治[J].有色金属科学与工程,2016,7(1):125-132.Wei J P,Wang H N,Yan J B,et al.Environmental damages and control measures in exploiting ion-absorbed rare earth of south China [J].Nonferrous Metals Science and Engineering,2016,7(1):125-132.
[49] 赵贤广,李武,王金龙,李国平,王小平,徐炎华.高浓度氨氮废水处理与氨资源化新技术[J].工业水处理,2011,31(12):31-34.Zhao X G,Li W,Wang J L,Li G P,Wang X P,Xu Y H.New treatment technique for highly concentrated ammonia-nitrogen wastewater and ammonia recovery[J].Industrial Water Treatment,2011,31(12):31-34.
[50] 周友新,祁建祥.吹脱法处理稀土冶炼高氨氮废水试验[J].煤炭技术,2010,29(12):207-209.Zhou Y X,Q J X.Blow-Off experimentation on treating high ammonia nitrogen wastewater in rare-earth smelting [J].Coal Technology,2010,29(12):207-209.
[51] 黄海明,傅忠,肖贤明,晏波.反渗透处理稀土氨氮废水试验研究[J].环境工程学报,2009,3(8):1443-1446.Huang H M,Fu Z,Xiao X M,Yan B.Study on treatment of rare earth ammonium nitrogen wastewater by reverse osmosis [J].Chinese Journal of Environmental Engineering,环境工程学报,2009,3(8):1443-1446.
[52] 雷春生,王桂玉,姚倩,唐璐,王侃.化学沉淀法预处理高质量浓度的氨氮废水[J].常州大学学报(自然科学版),2010,22(3):46-48.Lei C S,Wang G Y,Yao Q,Tang L,Wang K.Study of the pretreatment of highly concentrated ammonia-nitrogen wastewater by chemical precipitation[J].Journal of Changzhou University(Natural Science Edition),2010,22(3):46-48.
[53] 柳召刚,司吉星,李梅,胡艳宏,常宏涛.稀土产业氨氮废水处理现状及建议[J].现代化工,2010,30(S2):13-16.Liu Z G,Si J X,Li M,Hu Y H,Chang H T.Recent advances and suggestions for treatment of rare earth ammonia-nitrogen wastewater[J].Modern Chemical Industry,2010,30(S2):13-16.
[54] 罗嗣海,黄群群,王观石,胡世丽,洪本根.离子型稀土浸矿过程中渗透性变化规律的试验研究[J].有色金属科学与工程,2014,5(2):95-99.Luo S H,Huang Q Q,Wang G S,Hu S L,Hong B G.Permeability change rule of ion-adsorption rare-earth in ore leaching process [J].Nonferrous Metals Science and Engineering,2014,5(2):95-99.
[55] 金解放,邱灿,陶伟,郭钟群.毛细上升渗透系数的确定及在离子型稀土毛细上升中的应用[J].有色金属科学与工程,2015,6(4):104-110.Jin J F,QIU C,Tao W,Guo Z Q.Determination of the capillary permeability coefficient and its application to capillary rise on ionic rare earth [J].Nonferrous Metals Science and Engineering,2015,6(4):104-110.
[56] 金解放,陶伟,邱灿,郭钟群.离子型稀土一维垂直入渗规律及最大粒径的影响试验研究[J].有色金属科学与工程,2015,6(6):125-131.Jin J F,Tao W,Qiu C,Guo Z Q.Experimental research on the one dimensional vertical infiltration rule of ionic rare earth and the effects of maximum particle size [J].Nonferrous Metals Science and Engineering,2015,6(6):125-131.
[57] 王晓军,卓毓龙,邓书强,廖声银,李永欣.化学置换过程中稀土矿强度特性演化规律试验研究[J].江西理工大学学报,2016,37(3):56-60.Wang X J,Zhuo Y L,Deng S Q,Liao S Y,Li Y X.Experimental study on the evolution law of the strength characteristics of REO in displacement reaction[J].Journal of Jiangxi University of Science and Technology,2016,37(3):56-60.
[58] 吴爱祥,尹升华,李建锋.离子型稀土矿原地溶浸溶浸液渗流规律的影响因素[J].中南大学学报(自然科学版),2005,36(3):506-510.WU A X,YIN S H,LI J F.Influential factors of permeability rule of leaching solution in ion-absorbed rare earth deposits with in-situ leaching[J].Journal of Central South University(Science and Technology),2005,36(3):506-510.
[59] 饶睿,李明才,张树标,饶运章,钟健民.离子型稀土原地浸矿采场滑坡特征及防控试验研究[J].稀土,2016,37(6):26-31.Rao R,Li M C,Zhang S B,Rao Y Z,Zhong J M.Experimental study on landslide features and countermeasures of in-itu leaching stope of ion-type rare earth mines[J].Chinese Rare Earths,2016,37(6):26-31.
[60] 张树标,李明才,饶运章,饶睿,钟健民.离子型稀土原地浸矿采场山体滑坡防控试验研究[J].有色金属科学与工程,2015,6(4):116-120.Zhang S B,Li M C,Rao Y Z,Rao R,Zhong J M.On landslide prevention and control of in-situ leaching stope of ion-adsorbed rare earth [J].Nonferrous Metals Science and Engineering,2015,6(4):116-120.
[2] 池汝安,田君.风化壳淋积型稀土矿评述[J].中国稀土学报,2007,25(6):641-650.Chi R A,Tian J.Review of weathered crust rare earth ore [J].Journal of the Society of Chinese Rare Earths,2007,25(6):641-650.
[3] 郭钟群,金解放,赵奎,王晓军,陈国梁.离子吸附型稀土开采工艺与理论研究现状[J].稀土,2018,39(1):132-141.Guo Z Q,Jin J F,Zhao K,Wang X J,Chen G L.Status of leaching technology and theory of ion adsorption type rare earth ores [J].Chinese Rare Earths,2018,39(1):132-141.
[4] 饶振华,武立群,袁源明.离子型稀土发现、命名与提取工艺发明大解密[J].中国金属通报,2007,(29):8-15.Rao Z H,WU L Q,Yuan Y M.Ion type rare earth discovery,naming and extraction technology invention decryption [J].China Metal Bulletin,2007,(29):8-15.
[5] 罗仙平,钱有军,梁长利.从离子型稀土矿浸取液中提取稀土的技术现状与展望[J].有色金属科学与工程,2012,3 (5):50-53.Luo X P,Qian Y J,Liang C L.Research progress and developing trend of rare earth extraction from ionic rare earth leach solution [J].Nonferrous Metals Science and Engineering,2012,3 (5):50-53.
[6] 李永绣,张玲,周新木.南方离子型稀土的资源和环境保护性开采模式[J].稀土,2010,31(2):80-85.Li Y X,Zhang L,Zhou X M.Resource and environment protected exploitation model for ion-type rare earth deposit in southern of China [J].Chinese Rare Earths,2010,31(2):80-85.
[7] 郭钟群,金解放,秦艳华,王晓军,钟文,赵奎.南方离子型稀土一维水平入渗规律试验研究[J].有色金属科学与工程,2017,8(2):102-106.Guo Z Q,Jin J F,Qin Y H,Wang X J,Zhong W,Zhao K.Experimental research on one-dimensional horizontal infiltration rules of ion-adsorption rare earth[J].Nonferrous Metals Science and Engineering,2017,8(2):102-106.
[8] 李永绣.稀土开发的环境工程模式[J].中国金属通报,2010(1):38-39.Li Y X.Environment protected exploitation model for ion-type rare earth deposit [J].China Metal Bulletin,2010(1):38-39.
[9] 郭钟群,金解放,王观石,秦艳华,王晓军,赵奎.风化壳淋积型稀土矿浸取动力学基础理论研究[J].有色金属科学与工程,2017,8(5):102-108.Guo Z Q,Jin J F,Wang G S,Qin Y H,Wang X J,Zhao K.Basic theory of leaching kinetics on the weathered crust elution-deposited rare earth ores[J].Nonferrous Metals Science and Engineering,2017,8(5):102-108.
[10] 田君,唐学昆,尹敬群,罗仙平.风化壳淋积型稀土矿浸取过程中基础理论研究现状[J].有色金属科学与工程,2012,3(4):48-52.Tian J,Tang X K,Yin J Q,Luo X P.Present situation of fundamental theoretical research on leaching process of weathered crust elution-deposited rare earth ore[J].Nonferrous Metals Science and Engineering,2012,3(4):48-52.
[11] 郭伟,付瑞英,赵仁鑫,赵文静,郭江源,毕娜,张君.稀土开发导致的环境问题及土壤稀土污染治理措施初探[J].安全与环境学报,2014,14(5):245-251.Guo W,Fu R Y,Zhao R X,Zhao W J,Guo J Y,Bi N,Zhang J.Eco-environment contaminations caused by the rare earth mining and the related controlling measures [J].Journal of Safety and Environment,2014,14(5):245-251.
[12] 林河成.稀土生产中的“三废”治理及环境保护[J].稀土,1996,17 (6):54-58.Lin H C.Waste disposal and environment protection in rare earth production[J].Chinese Rare Earths,1996,17 (6):54-58.
[13] 高志强,周启星.稀土矿露天开采过程的污染及对资源和生态环境的影响[J].生态学杂志,2011,30 (12):2915-2922.Gao Z Q,Zhou Q X.Contamination from rare earth ore strip mining and ins impacts on resources and eco-environment[J].Chinese Journal of Ecology,2011,30 (12):2915-2922.
[14] 肖子捷,刘祖文,张念.离子型稀土采选工艺环境影响分析与控制技术[J].稀土,2014,35 (6):56-61.Xiao Z J,Liu Z W,Zhang N.Environmental impact analysis and control technology of ion rare earth mining in south of Jiangxi province [J].Chinese Rare Earths,2014,35 (6):56-61.
[15] 兰荣华.赣南离子型稀土矿环境问题及防治对策[J].求是,2004,(6):174-175.Lan R H.The environmental problems and prevention treatment of rare earth minerals in south Jiangxi province[J].QiuShi,2004,(6):174-175.
[16] 彭冬水.赣南稀土矿水土流失特点及防治技术[J].亚热带水土保持,2005,17(3):14-15.Peng D S.Characteristics of soil erosion and prevention and control of rare earth minerals in south Jiangxi[J].Subtropical Soil and Water Conservation,2005,17(3):14-15.
[17] 汤洵忠,李茂楠,杨殿.离子型稀土矿原地浸析采场滑坡及其对策[J].金属矿山,2000,(7):5-8.Tang X Z,Li M N,Yang D.Stope slide in in-situ leaching of ionic type rare earth ore and its countermeasures[J].Metal Mine,2000,(7):5-8.
[18] 黄紫彬,蔡昶,袁宪强,王强.浅析原地浸矿开采的离子型稀土矿山安全问题[J].稀土,2013,34(4):99-102.Huang Z B,Cai C,Yuan X Q,Wang Q.Analysis of safety problems of ion type rare earth mine during in-situ leaching [J].Chinese Rare Earths,2013,34(4):99-102.
[19] 雷国静,刘少峰,程三友.遥感在稀土矿区植被污染信息提取中的应用[J].江西有色金属,2006,20(2):1-5.Lei G J,Liu S F,Chen S Y,et al.Application of remote sensing data on extraction of contaminating vegetation on rare earth minerals area [J].Jiangxi Nonferrous Metals,2006,20(2):1-5.
[20] 王陶,刘衍宏,王平,刘少峰.多源多时相遥感分类技术在赣州稀土矿区环境变化检测中的应用[J].中国矿业,2009,18(11):88-91,109.Wang T,Liu Y H,Wang P,Liu S F.Application of multi-source and multi-temporal RS image classification method in REE mineral development and environment variation in the Ganzhou mineral district [J].China Mining Magazine,2009,18(11):88-91,109.
[21] 彭燕,何国金,张兆明,江威,欧阳志云,王桂周.赣南稀土矿开发区生态环境遥感动态监测与评估[J].生态学报,2016,36(6):1676-1685.Pen Y,He G J,Zhang Z M,Jiang W,Ouyang Z Y,Wang G Z.Eco-environmental dynamic monitoring and assessment of rare earth mining area in Southern Ganzhou using remote sensing[J].Acta Ecologica Sinica,2016,36(6):1676-1685.
[22] 代晶晶,王登红,陈郑辉,于扬.IKONOS遥感数据在离子吸附型稀土矿区环境污染调查中的应用研究—以赣南寻乌地区为例[J].地球学报,2013,34(3):354-360.Dai J J,Wang D H,Chen Z H,Yu Y.Environment contamination investigation of ion-absorbed rare earth ore districts based on ikonos remote sensing data:a case study of xunwu area in south Jiangxi [J].Acta Geoscientica Sinica,2013,34(3):354-360.
[23] 黄铁兰,吴海陆,黄华谷.基于多源多时相遥感数据的稀土开采状况与地质环境问题监测[J].华南地质与矿产,2014,30(2):169-175.Huang T L,Wu H L,Huang H G.Motoring of exploitation status and geological environment problem of rare earth elements ore mining base on multi-source and multi-temporal remote sensing data in northern Guangdong province[J].Geology and Mineral Resources of South China,2014,30(2):169-175.
[24] 李恒凯,吴立新,熊云飞,徐露.基于RUSLE模型的离子稀土矿区土壤侵蚀时空演变分析——以岭北矿区为例[J].稀土,2016,37(4):35-44.Li H K,Wu L X,Xiong Y F,Xu L.Spatiotemporal change of soil erosion in rare earth mining area based on RUSLE model:a case in lingbei mining area [J].Chinese Rare Earths,2016,37(4):35-44.
[25] 李恒凯,雷军,杨柳.基于Landsat影像的离子稀土矿区植被覆盖度提取及景观格局分析[J].农业工程学报,2016,32(10):267-276.Li H K,Lei J,Yang L,et al.Extraction of vegetation coverage and analysis of landscape pattern in rare earth mining area based on Landsat image [J].Transactions of the Chinese Society of Agricultural Engineering,2016,32(10):267-276.
[26] 李芹,李恒凯,杨柳,雷军.离子稀土开采扰动下的矿区荒漠化遥感监测分析——以岭北矿区为例[J].有色金属科学与工程,2017,8(3):114-120.Li Q,Li H K,Yang L,Lei J.Remote sensing monitoring of mining area desertification under disturbance of ionic rare earth mining:using Lingbei rare earth mining area as the case [J].Nonferrous Metals Science and Engineering,2017,8(3):114-120.
[27] 李恒凯,吴立新,刘小生.稀土矿区地表环境变化多时相遥感监测研究——以岭北矿区为例[J].中国矿业大学学报,2014,43(6):1087-1094.Li H K,Wu L X,Liu X S.Change detection of ground-surface environment in rare earth mining area based on multi-temporal remote sensing:a case in Lingbei rare earth mining area[J].Journal of China University of Mining & Technology,2014,43(6):1087-1094.
[28] 彭高辉,陈守余.模糊ISODATA聚类在矿山环境评价中的应用[J].安全与环境工程,2004,11(1):7-8.Peng G H,Chen S Y.The Application of fuzzy ISODATA clustering method to mine environment assessment[J].Safety and Environmental Engineering,2004,11(1):7-8.
[29] 王炳强,沈智慧,白喜庆.层次分析法(AHP)在矿山环境地质评价中的应用[J].中国煤田地质,2007,19(S2):57-59.Wang B Q,Shen Z H,Bai X Q,et al.Application of AHP in mine environmental geological evaluation[J].Coal Geology of China,2007,19(S2):57-59.
[30] 李东,周可法,孙卫东,王金林,于浩,刘慧.BP神经网络和SVM在矿山环境评价中的应用分析[J].干旱区地理,2015,38(1):128-134.Li D,Zhou K F,Sun W D,Wang J L,Yu H,Liu H.Application of BP neural network and SVM in mine environmental assessment[J].Arid Land Geography,2015,38(1):128-134.
[31] 陈奇,武强,徐佳成.专家系统在矿山环境治理中的应用研究[J].水文地质工程地质,2010,37(5):113-117.Chen Q,Wu Q,Xu J C.Application of the expert system to mine environment treatment[J].Hydrogeology & Engineering Geology,2010,37(5):113-117.
[32] 陈建平,范立民,李成,宁建民.基于模糊综合评判和 GIS 技术的矿山地质环境影响评价[J].中国煤炭地质,2014,26(2):43-48.Chen J P,Fan L M,Li C,Ning J M.Mine geological environment impact assessment based on fuzzy comprehensive evaluation and GIS technology [J].Coal Geology of China,2014,26(2):43-48.
[33] 吕铁硬,郝多虎,梅军军.赣南地区离子型稀土矿山地质环境问题评价方法探讨[J].河南科技,2013,(10):180-181.Lv T Y,Hao D H,Mei J J.Discussion on evaluation method of geological environment problems of ion type rare earth mines in South Jiangxi [J].Journal of Henan Science and Technology,2013,(10):180-181.
[34] 姚栋伟,程莉,汪洋,李天慈.基于BP神经网络和GIS的矿山地质环境评价方法[J].采矿技术,2016,16(3):56-58.Yao D W,Chen L,Wang Y,Li T C.Evaluation method of mine geological environment based on BP neural network and GIS[J].Mining Technology,2016,16(3):56-58.
[35] 王婷茹.基于MapGIS的岗下稀土矿山地质环境评价与分区[J].金属矿山,2016,(2):167-171.Wang T R.Evaluation and division of the geological environment of gangxia rare earth mine based on mapGIS [J].Metal Mine,2016,(2):167-171.
[36] 马伟,徐素宁,王润生,赵珍梅,文元亮.基于证据权法的赣南稀土矿山地质环境评价[J].地球学报,2015,36(1):103-110.Ma W,Xu S N,Wang R S,Zhao Z M,Wen Y L.Geo-environmental quality assessment of rare-earth mines in southern jiangxi province using weights-of-evidence modeling [J].Acta Geoscientica Sinica,2015,36(1):103-110.
[37] 何书,陈飞,江文才,薛国栋,袁子婷.稀土原地浸矿区地下水污染风险评价方法研究[J].有色金属科学与工程,2015,6(2):136-142.He S,Chen F,Jiang W C,Xue G D,Yuan Z T.Risk assessment of groundwater pollution in the in-situ leaching mining area of rare earth[J].Nonferrous Metals Science and Engineering,2015,6(2):136-142.
[38] 于扬,王登红,田兆雪,黄凡,赵芝,孙艳,李德先,何晗晗,邓茂春.稀土矿区环境调查SMAIMA方法体系、评价模型及其应用—以赣南离子吸附型稀土矿山为例[J].地球学报,2017,38(3):335-344.Yu Y,Wang D H,Tian Z X,Huang F,Zhao Z,Sun Y,Li D X,He H H,Deng M C.Establishment and application of SMAIMA working method system and environment evaluation model for rare earth elements mine:a case study of ion-absorption type ree mines in southern Jiangxi province [J].Acta Geoscientica Sinica,2017,38(3):335-344.
[39] 环境保护部,国家质量监督检验检疫总局.GB 26451-2011.稀土工业污染物排放标准[S].北京:中国环境科学出版社,2011.Ministry of Environment Protection of the People’s Republic of China,General Administration of Quality Supervision,Inspection and Quarantine of the People’s Republic of China.GB 26451-2011.Emission standard of pollutants for rare earths industry [S].Beijing:China Environmental Science Press,2011.
[40] 陈熙,蔡奇英,余祥单,刘以珍,葛刚,吴兰,王秀峰.赣南离子型稀土矿山土壤环境因子垂直分布—以龙南矿区为例[J].稀土,2015,36(1):23-28.Chen X,Cai Q Y,Yu X S,Liu Y Z,Ge G,Wu L,Wang X F.Vertical distributions of soil environmental factors in ion-type rare earth mining of southern Jiangxi:a case study in Longnan rare earth mining area [J].Chinese Rare Earths,2015,36(1):23-28.
[41] 刘斯文,黄园英,韩子金,刘晓端.离子型稀土矿山土壤生态修复研究与实践[J].环境工程,2015(11):160-165.Liu S W,Huang Y Y,Han Z J,Liu X R.Practices of the soil ecological remediation in ion-absorbed rare earth mine[J].Environmental Engineering,2015(11):160-165.
[42] 李永绣.离子型吸附型稀土资源与绿色提取[M].北京:化学工业出版社,2014:280.Li Y X.Ion adsorption rare earth resources and their green extraction [M].Beijing:Chemical Industry Press,2014:280.
[43] 陈振金,郑大增.稀土尾矿场土地复垦技术研究[J].上海环境科学,1998,17(9):28-31.Chen Z J,Zheng D Z.Study on land reclamation of rare earth trailing sites[J].Shanghai Environmental Sciences,1998,17(9):28-31.
[44] 李德荣,董闻达,廖汉民,利隆橙,李文煜,赖俊明.治理稀土尾砂中百喜草的生长和促苗措施的研究[J].江西农业大学学报,2001,23(1):93-95.Li D R,Dong W D,Liao H M,Li L C,Li W Y,Lai J M.A study on the growth and seedling improvement of bahia grass in the tail mineral slag of rare earth [J].Acta AgricuIturae Universitatis Jiangxiensis,2001,23(1):93-95.
[45] 曹学章,李小青,池明茹,张赶年,陈昌春.4种草用于南方稀土尾砂地种植的适宜性之比较[J].江西农业大学学报,2012,34(3):603-608.Cao X Z,Li X Q,Chi M R,Zhang G N,Chen C C.Comparison of planting suitability of four herbaceous plants on rare earth tailings in south China [J].Acta AgricuIturae Universitatis Jiangxiensis,2012,34(3):603-608.
[46] 蔡奇英,刘以珍,管毕财,吴兰,葛刚.南方离子型稀土矿的环境问题及生态重建途径[J].国土与自然资源研究,2013(5):52-54.Cai Q Y,Liu Y Z,Guan B C,Wu L,Ge G.Environmental issues and ecological restoration of ion-absorbed-type rare earth deposit in south China [J].Territory and natural resources study,2013(5):52-54.
[47] 罗才贵,罗仙平,苏佳,陈春飞,韩冬雪.离子型稀土矿山环境问题及其治理方法[J].金属矿山,2014,(6):91-96.Luo C G,Luo X P,Su J,Chen C F,Han D X.Environmental problems and treatment measures in ionic-type rare earth mine [J].Metal Mine,2014,(6):91-96.
[48] 魏娟萍,王海宁,晏江波.南方离子型稀土矿开采的环境损伤及防治[J].有色金属科学与工程,2016,7(1):125-132.Wei J P,Wang H N,Yan J B,et al.Environmental damages and control measures in exploiting ion-absorbed rare earth of south China [J].Nonferrous Metals Science and Engineering,2016,7(1):125-132.
[49] 赵贤广,李武,王金龙,李国平,王小平,徐炎华.高浓度氨氮废水处理与氨资源化新技术[J].工业水处理,2011,31(12):31-34.Zhao X G,Li W,Wang J L,Li G P,Wang X P,Xu Y H.New treatment technique for highly concentrated ammonia-nitrogen wastewater and ammonia recovery[J].Industrial Water Treatment,2011,31(12):31-34.
[50] 周友新,祁建祥.吹脱法处理稀土冶炼高氨氮废水试验[J].煤炭技术,2010,29(12):207-209.Zhou Y X,Q J X.Blow-Off experimentation on treating high ammonia nitrogen wastewater in rare-earth smelting [J].Coal Technology,2010,29(12):207-209.
[51] 黄海明,傅忠,肖贤明,晏波.反渗透处理稀土氨氮废水试验研究[J].环境工程学报,2009,3(8):1443-1446.Huang H M,Fu Z,Xiao X M,Yan B.Study on treatment of rare earth ammonium nitrogen wastewater by reverse osmosis [J].Chinese Journal of Environmental Engineering,环境工程学报,2009,3(8):1443-1446.
[52] 雷春生,王桂玉,姚倩,唐璐,王侃.化学沉淀法预处理高质量浓度的氨氮废水[J].常州大学学报(自然科学版),2010,22(3):46-48.Lei C S,Wang G Y,Yao Q,Tang L,Wang K.Study of the pretreatment of highly concentrated ammonia-nitrogen wastewater by chemical precipitation[J].Journal of Changzhou University(Natural Science Edition),2010,22(3):46-48.
[53] 柳召刚,司吉星,李梅,胡艳宏,常宏涛.稀土产业氨氮废水处理现状及建议[J].现代化工,2010,30(S2):13-16.Liu Z G,Si J X,Li M,Hu Y H,Chang H T.Recent advances and suggestions for treatment of rare earth ammonia-nitrogen wastewater[J].Modern Chemical Industry,2010,30(S2):13-16.
[54] 罗嗣海,黄群群,王观石,胡世丽,洪本根.离子型稀土浸矿过程中渗透性变化规律的试验研究[J].有色金属科学与工程,2014,5(2):95-99.Luo S H,Huang Q Q,Wang G S,Hu S L,Hong B G.Permeability change rule of ion-adsorption rare-earth in ore leaching process [J].Nonferrous Metals Science and Engineering,2014,5(2):95-99.
[55] 金解放,邱灿,陶伟,郭钟群.毛细上升渗透系数的确定及在离子型稀土毛细上升中的应用[J].有色金属科学与工程,2015,6(4):104-110.Jin J F,QIU C,Tao W,Guo Z Q.Determination of the capillary permeability coefficient and its application to capillary rise on ionic rare earth [J].Nonferrous Metals Science and Engineering,2015,6(4):104-110.
[56] 金解放,陶伟,邱灿,郭钟群.离子型稀土一维垂直入渗规律及最大粒径的影响试验研究[J].有色金属科学与工程,2015,6(6):125-131.Jin J F,Tao W,Qiu C,Guo Z Q.Experimental research on the one dimensional vertical infiltration rule of ionic rare earth and the effects of maximum particle size [J].Nonferrous Metals Science and Engineering,2015,6(6):125-131.
[57] 王晓军,卓毓龙,邓书强,廖声银,李永欣.化学置换过程中稀土矿强度特性演化规律试验研究[J].江西理工大学学报,2016,37(3):56-60.Wang X J,Zhuo Y L,Deng S Q,Liao S Y,Li Y X.Experimental study on the evolution law of the strength characteristics of REO in displacement reaction[J].Journal of Jiangxi University of Science and Technology,2016,37(3):56-60.
[58] 吴爱祥,尹升华,李建锋.离子型稀土矿原地溶浸溶浸液渗流规律的影响因素[J].中南大学学报(自然科学版),2005,36(3):506-510.WU A X,YIN S H,LI J F.Influential factors of permeability rule of leaching solution in ion-absorbed rare earth deposits with in-situ leaching[J].Journal of Central South University(Science and Technology),2005,36(3):506-510.
[59] 饶睿,李明才,张树标,饶运章,钟健民.离子型稀土原地浸矿采场滑坡特征及防控试验研究[J].稀土,2016,37(6):26-31.Rao R,Li M C,Zhang S B,Rao Y Z,Zhong J M.Experimental study on landslide features and countermeasures of in-itu leaching stope of ion-type rare earth mines[J].Chinese Rare Earths,2016,37(6):26-31.
[60] 张树标,李明才,饶运章,饶睿,钟健民.离子型稀土原地浸矿采场山体滑坡防控试验研究[J].有色金属科学与工程,2015,6(4):116-120.Zhang S B,Li M C,Rao Y Z,Rao R,Zhong J M.On landslide prevention and control of in-situ leaching stope of ion-adsorbed rare earth [J].Nonferrous Metals Science and Engineering,2015,6(4):116-120.
© 2004-2018 中国地质图书馆版权所有 京ICP备05064691号 京公网安备11010802017129号 地址：北京市海淀区学院路29号 邮编：100083 电话：办公室：(+86 10)66554848；文献借阅、咨询服务、科技查新：66554700 |