柔性太阳能电池的研究进展和应用前景
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摘要
相对于刚性太阳能电池,柔性太阳能电池具有柔韧性好、成本低、低温快速制备、便于携带等优势。在此,主要论述了柔性非晶硅太阳能电池、柔性有机太阳能电池、柔性钙钛矿太阳能电池的国内外研究进展,并就改善器件结构、引入新型光敏材料、优化界面修饰层、改进镀膜工艺等提升电池效率和稳定性的方面进行了重点探讨。另外,对柔性太阳能电池的应用情况和前景作了展望。随着卷对卷、印刷等技术的不断成熟,柔性太阳能电池的商业化前景光明。
Compared with rigid solar cells, flexible solar cells have the advantages of flexibility, rapid preparation at low temperature, low cost and are easy to carry. In this paper, the research progress of flexible amorphous silicon solar cells, flexible organic solar cells and flexible perovskite solar cells at home and abroad is reviewed. The aspects of improving the efficiency and stability of solar cells, such as optimizing device structure, introducing new photosensitive materials, optimizing the interface modification layer and improving the coating process, are discussed in details. In addition, the application and prospects of flexible solar cells are prospected in this paper. With the continuous maturity of roll-to-roll technology and printing technology, the commercial prospects of flexible solar cells are bright.
Compared with rigid solar cells, flexible solar cells have the advantages of flexibility, rapid preparation at low temperature, low cost and are easy to carry. In this paper, the research progress of flexible amorphous silicon solar cells, flexible organic solar cells and flexible perovskite solar cells at home and abroad is reviewed. The aspects of improving the efficiency and stability of solar cells, such as optimizing device structure, introducing new photosensitive materials, optimizing the interface modification layer and improving the coating process, are discussed in details. In addition, the application and prospects of flexible solar cells are prospected in this paper. With the continuous maturity of roll-to-roll technology and printing technology, the commercial prospects of flexible solar cells are bright.
引文
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[15] 杨少鹏,韩凌洁,赵艳新,等.基于PCDTBT:PC_(71)BM的半透明高效聚合物太阳能电池[J].科学通报,2012(30):2836-2841.
[16] Tsang S W,Drolet N,Tse S C,et al.Impact of Interfacial Dipole on Carrier Transport in Bulk Heterojunction Poly(3-hexylthiophene) and [6,6]-phenyl C 61 -butyric acid Methyl Ester Blends[J].Applied Physics Letter,2010(15):153306-153306-3.
[17] Kojima A,Teshima K,Shirai Y,et al.Organometal Halide Perovskites as Visible-Light Sensitizers for Photovoltaic Cells [J].Journal of the American Chemical Society,2009(17):6050-6051.
[18] Kim H S,Lee C R,Im J H,et al.Lead Iodide Perovskite Sensitized All-Solid-State Submicron Thin Film Mesoscopic Solar Cell with Efficiency Exceeding 9% [J].Science Report,2012(2):591.
[19] Heo J H,Lee M H,Han H J,et al.Highly Efficient Low Temperature Solution Processable Planar Type CH3NH3PbI3 Perovskite Flexible Solar Cells [J].Journal of Materials Chemistry A,2016(4):1572-1578.
[20] Xiangyang Liu,Xiaodu Yang,Xinsheng Liu,et al.High Efficiency Flexible Perovskite Solar Cells Using SnO2/graphene Electron Selective Layer and Silver Nanowires Electrode[J].Applied Physics Letter,2018:203903.
[21] 陈海宁.碳基钙钛矿太阳能电池的研究进展[J].应用化学,2018(8):916-924.
[22] 刘大超,崔运超,李光,等.阳极界面修饰对钙钛矿太阳能电池性能的影响[J].光子学报,2017(2):203-210.
[23] You J,Hong Z,Yang Y,et al.Low-Temperature Solution-Processed Perovskite Solar Cells with High Efficiency and Flexibility[J].ACS Nano,2014(2):1674-1680.
[2] Parida B,Iniyan S,Goic R.A Review of Solar Photovoltaic Technologies[J].Renewable and Sustainable Energy Reviews,2011(3):1625-1636.
[3] Singh M,Haverinen M,Dhaga P,et al.Inkjet Printing-Process and Its Applications[J].Advanced Materials,2010(6):673-685.
[4] Ichikawa Y,Yoshida T,Hama T,et al.Product Ion Technology for Amorphous Silicon-based Flexible Solar Cells[J].Solar Energy Materials and Solar Cells,2001(1-4):107-115.
[5] Watson T,Reynolds G,Wragg D,et al.Corrosion Monitoring of Flexible Metallic Substrates for Dye-Sensitized Solar Cells[J].International Journal of Photoenergy,2013(8):1-8.
[6] 李旺,朱登华,刘石勇,等.基于柔性玻璃衬底ZnO:B薄膜的非晶硅太阳能电池的制备及其光电性能研究[J].人工晶体学报,2015(8):2057-2062.
[7] Soderstrom T,Haug F ,Niquille X,et al.Asymmetric Intermediate Reflector for Tandem Micromorph Thin Film Silicon Solar Cells[J].Applied Physics Letter,2009(6):063501.
[8] Schropp E,Li H,Rath K,et al.Thin Film Nanocrystalline Silicon and Nanostructured Interfaces for Multibandgap Triple Junction Solar Cells[J].Surface and Interface Analysis,2008(6-7):970-973.
[9] Ramakrishna M,Juhi Kumari,Venkanna K,et al.Hydrogenated Amorphous Silicon Solar Cells Fabricated at Low Substrate Temperature 110 °C on Flexible PET Substrate[A].AIP Conference Proceedings,2018:178-186.
[10] 倪牮,薛俊明,曹丽冉,等.PET塑料衬底非晶/微晶硅叠层太阳能电池研究[J].光电子·激光,2009(6):738-741.
[11] Baojie Yan,Jeffrey Yang,Subhendu Guha.Amorphous and Nanocrystalline Silicon Thin Film Photovoltaic Technology on Flexible Substrates[J].Journal of Vacuum Science & Technology,2012(4):04D108-04D108-10.
[12] Tobias Stubhan,Tayebeh Ameri,Michael Salinas,et al.High Shunt Resistance in Polymer Solar Cells Comprising a MoO3 Hole Extraction Layer Processed from Nanoparticle Suspension[J].Applied Physics Letters,2011(25):253-308.
[13] Ta-Ya Chu,Salima Alem,Pierre G Verly.Highly Efficient Polycarbazole-based Organic Photovoltaic Devices [J].Applied Physics Letter,2009(6):063304-063304-3.
[14] Lijun Huo,Jianhui Hou,Shaoqing Zhang,et al.A Polybenzo[1,2-b:4,5-b’]dithiophene Derivative with Deep HOMO Level and Its Application in High-Performance Polymer Solar Cells [J].Angew.Chem.Int.Ed,2012(4):119.
[15] 杨少鹏,韩凌洁,赵艳新,等.基于PCDTBT:PC_(71)BM的半透明高效聚合物太阳能电池[J].科学通报,2012(30):2836-2841.
[16] Tsang S W,Drolet N,Tse S C,et al.Impact of Interfacial Dipole on Carrier Transport in Bulk Heterojunction Poly(3-hexylthiophene) and [6,6]-phenyl C 61 -butyric acid Methyl Ester Blends[J].Applied Physics Letter,2010(15):153306-153306-3.
[17] Kojima A,Teshima K,Shirai Y,et al.Organometal Halide Perovskites as Visible-Light Sensitizers for Photovoltaic Cells [J].Journal of the American Chemical Society,2009(17):6050-6051.
[18] Kim H S,Lee C R,Im J H,et al.Lead Iodide Perovskite Sensitized All-Solid-State Submicron Thin Film Mesoscopic Solar Cell with Efficiency Exceeding 9% [J].Science Report,2012(2):591.
[19] Heo J H,Lee M H,Han H J,et al.Highly Efficient Low Temperature Solution Processable Planar Type CH3NH3PbI3 Perovskite Flexible Solar Cells [J].Journal of Materials Chemistry A,2016(4):1572-1578.
[20] Xiangyang Liu,Xiaodu Yang,Xinsheng Liu,et al.High Efficiency Flexible Perovskite Solar Cells Using SnO2/graphene Electron Selective Layer and Silver Nanowires Electrode[J].Applied Physics Letter,2018:203903.
[21] 陈海宁.碳基钙钛矿太阳能电池的研究进展[J].应用化学,2018(8):916-924.
[22] 刘大超,崔运超,李光,等.阳极界面修饰对钙钛矿太阳能电池性能的影响[J].光子学报,2017(2):203-210.
[23] You J,Hong Z,Yang Y,et al.Low-Temperature Solution-Processed Perovskite Solar Cells with High Efficiency and Flexibility[J].ACS Nano,2014(2):1674-1680.