摘要
采用SEM、TEM、EBSD等分析了Nb-Mo微合金化对δ-TRIP钢力学性能、组织结构的影响。结果表明:Nb-Mo微合金化试验钢及对照钢均为复相组织,主要由δ铁素体、贝氏体、α铁素体和残留奥氏体等构成。添加微量Nb-Mo元素后,试验钢组织中残留奥氏体含量略有增加,同时伴随着大量纳米级Nb-Mo碳化物析出;并且试验钢的力学性能明显改善,其抗拉强度达到1044 MPa,伸长率为22. 4%。微观组织表征结果表明:其主要强化机制为残留奥氏体的相变诱发塑性(TRIP)效应以及纳米尺寸Nb、Mo碳化物通过钉扎晶界和位错,从而达到细晶强化和第二相颗粒强化。
The influence of Nb-Mo microalloying on the mechanical property and microstructure of δ-TRIP steel was analyzed by scanning electron microscope( SEM),transmission electron microscope( TEM),electron back-scattered diffraction( EBSD).The result indicates that the microstructure of both the steels with and without Nb-Mo microalloying contain delta-ferrite,bainite,alpha-ferrite and retained austenite phases.After adding trace Nb-Mo,the volume fraction of retained austenite slightly increases and a mass of nano-size Nb-Mo carbides precipitate out.Further,the mechanical properties of the Nb-Mo steel are signally promoted with the tensile strength of 1044 MPa and the elongation of 22.4%.The microstructure characterization shows that the major strengthening mechanisms of the Nb-Mo microalloying steel are the transformation-induced plasticity( TRIP) effect of retained austenite,as well as the fine-grain strengthening and second-phase strengthening caused by Nb-Mo carbide pinning grain boundaries or dislocations.
引文
[1]Sohn S S,Lee B J,Lee S,et al.Effect of annealing temperature on microstructural modification and tensile properties in 0.35C-3.5Mn-5.8Al lightweight steel[J].Acta Materialia,2013,61(13):5050-5066.
[2]Choi H,Lee S,Lee J,et al.Characterization of fracture in medium Mn steel[J].Materials Science and Engineering A,2017,687:200-210.
[3]Rana R,Liu C,Ray R K.Evolution of microstructure and mechanical properties during thermomechanical processing of a low-density multiphase steel for automotive application[J].Acta Materialia,2014,75:227-245.
[4]Chatterjee S,Murugananth M,Bhadeshia H K D H.δ-TRIP steel[J].Materials Science and Technology,2007,23(7):819-827.
[5]Yi H L,Lee K Y,Bhadeshia H K D H.Stabilisation of ferrite in hot rolledδ-TRIP steel[J].Materials Science and Technology,2011,27(2):525-529.
[6]Choi Y J,Suh D W,Bhadeshia H K D H.Retention of delta-ferrite in aluminium-alloyed TRIP-assisted steels[J].Proceedings of the Royal Society A,2012,468(2146):2904-2914.
[7]Xiong X C,Sun L,Wang J F,et al.Properties assessment of the first industrial coils of low-density duplexδ-TRIP steel[J].Materials Science and Technology,2016,32(13):1403-1408.
[8]Rana R,Liu C,Ray R K.Low-density low-carbon Fe-Al ferritic steels[J].Scripta Materialia,2013,68(6):354-359.
[9]Wang J F,Yang Q,Wang X D,et al.Effect of coiling temperature on microstructure and tensile behavior of a hot-rolled ferritic lightweight steel[J].Metallurgical and Materials Transactions A,2016,47A(12):5918-5931.
[10]Yi H L,Lee K Y,Lim J H,et al.Spot weldability ofδ-TRIP steel containing 0.4wt%C[J].Science and Technology of Welding and Joining,2013,15(7):619-624.
[11]Yi H L,Chen P,Bhadeshia H K D H.Optimizing the morphology and stability of retained austenite in aδ-TRIP steel[J].Metallurgical and Materials Transactions A,2014,45(8):3512-3518.
[12]Wang J F,Wang Z G,Wang X D,et al.Strengthening effect of nanoscale precipitation and transformation induced plasticity in a hot rolled copper-containing ferrite-based lightweight steel[J].Scripta Materialia,2017,129:25-29.
[13]Hui W J,Shao C W,Zhang Y J,et al.Microstructure and mechanical properties of medium Mn steel containing 3%Al processed by warm rolling[J].Materials Science and Engineering A,2017,707:501-510.
[14]Tonizzo Q,Gourgues-Lorenzon A F,Maziere M,et al.Microstructure,plastic flow and fracture behavior of ferrite-austenite duplex low density medium Mn steel[J].Materials Science and Engineering A,2017,706:217-226.
[15]Cao J C,Yong Q L,Liu Q Y,et al.Precipitation of MC phase and precipitation strengthening in hot rolled Nb-Mo and Nb-Ti steels[J].Journal of Materials Science,2007,42(24):10080-10084.
[16]Yi H L,Lee K Y,Bhadeshia H K D H.Mechanical stabilisation of retained austenite inδ-TRIP steel[J].Materials Science and Engineering:A,2011,528(18):5900-5903.
[17]Emo J,Maugis P,Perlade A.Austenite growth and stability in medium Mn,medium Al Fe-C-Mn-Al steels[J].Computational Materials Science,2016,125:206-217.