炼化企业污水场含烃恶臭气体处理技术进展
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摘要
针对炼化企业污水场含烃恶臭气体排放量大、气体中非甲烷总烃质量高且浓度波动大等问题,综述了含烃恶臭气体处理技术,指出单一技术主要有吸附法、吸收法、催化燃烧法和生物法,重点分析了生物法-活性炭吸附法、微乳液吸收法-生物法、活性炭吸附法-深冷/生物法、催化燃烧法/生物法等组合技术的工艺流程和优缺点,并提出了选择相应处理技术的建议。
According to the problems of high discharge of hydrocarbonaceous ordor gas, high and fluctuated concentration of nonmethane hydrocarbons in the gas, the processing technologies of hydrocarbon odorous gas were summarized. It was pointed out that the single treatment technologies mainly were adsorption, absorption, catalytic combustion and biological methods, and the combined treatment technologies were biological and activated carbon adsorption method, DMA and biological method, activated carbon adsorption and deep cooling/biological method, catalytic combustion and biological method, etc. The advantages and disadvantages of technologies above were analyzed and the corresponding suggestions were proposed.
According to the problems of high discharge of hydrocarbonaceous ordor gas, high and fluctuated concentration of nonmethane hydrocarbons in the gas, the processing technologies of hydrocarbon odorous gas were summarized. It was pointed out that the single treatment technologies mainly were adsorption, absorption, catalytic combustion and biological methods, and the combined treatment technologies were biological and activated carbon adsorption method, DMA and biological method, activated carbon adsorption and deep cooling/biological method, catalytic combustion and biological method, etc. The advantages and disadvantages of technologies above were analyzed and the corresponding suggestions were proposed.
引文
[1]孙晓犁.石化污水处理场挥发性有机物排放状况研究[J].环境科技,2010,23(Z 1):72-85.
[2]闫松,尹天亚,单广波,等.炼油企业污水处理厂恶臭污染分布特征及规律[J].环境检测管理与技术,2010,22(4):61-62.
[3]李凌波,韩丛碧,郭兵兵,等.炼油厂恶臭污染源综合监测与评价[J].石油炼制与化工,2013,44(1):95-100.
[4]方向晨,刘忠生,王学海.炼油企业恶臭气体治理技术[J].石油化工安全环保技术,2008,24(5):48-62.
[5]杨昌竹.环境工程原理[M].北京:冶金工业出版社,1994:164-166.
[6]Chiang Y C,Chiang P C,Huang C P. Effects of pore structure and temperature on VOC adsorption on activated carbon [J].Carbon,2001,39(4):523-534.
[7]龚朝兵,陈伟,李海华.炼厂污水处理场恶臭气体治理实践[J].石油化工技术与经济,2016,32(5):37-40.
[8]王刚.炼油恶臭污染治理技术在中国石化天津分公司的应用实例[J].化工环保,2014,34(3):235-239.
[9]刘恋,朱艳华,田森林.微乳液和混合表面活性剂对甲苯的增溶作用[J].环境科学与技术,2010,33(9):150-154.
[10]Prince L M.Microemulsion:Theory and practice[M].New York:Academic Press,1997.
[11]赵保卫,朱利中.微乳液对难溶有机物的增溶作用及影响因素[J].中国环境科学,2003,23(5):493-497.
[12]Hoar T P,Schulman J H.Transparent water-in-oil dispersions:The oleopathic hydro-micelle[J].Nature,1943,152:102-103.
[13]Zhu L Z,Zhao B L,Li Z L.Water solubility enhancements of PAHs by sodium castor oil sulfonate microemulsions[J].Environ Sci,2003,15:583-589.
[14]田森林,刘恋,宁平. 填料塔-微乳液增溶吸收法净化甲苯废气[J].环境工程学报,2010,4(11):2552-2556.
[15]余倩,邓欣,李俊,等.活性炭吸附技术对VOCs净化处理的研究进展[J].材料研究与应用,2010,4(4):368-371.
[16]吴德礼,朱申红.新型吸附剂的发展与应用[J].矿产综合利用,2002(1):36-40.
[17]李守信,金平,张文智,等.采用活性炭纤维吸附装置回收VOC的优点分析[J].化工环保,2004,24(Z 1):274-276.
[18]李婕,羌宁.挥发性有机物(VOCs)活性炭吸附回收技术综述[J].四川环境,2007,26(6):101-106.
[19]刘永斌,陈俊梅,陈彬彬.催化燃烧技术在炼油污水处理场恶臭治理中的应用[J].炼油技术与工程,2011,41(11):54-57.
[20]王本勇,赵磊,王新.石化污水处理场VOCs废气催化氧化处理实验研究[J].环境科学导刊,2017,36(2):97-100.
[21]Yin C F,Lei L,Ming G. Improved catalytic capability of mesoporous TiO2 microspheres and photodecomposition of toluene[J].Materials & Interfaces,2010,11(2):3134-3140.
[22]Lin H L,Toshihiro L,et al. Processing and photo-catalytic properties of Cu-grafted TiO2 powder from acid treated BaTiO3[J].Materials Research Bulletin,2011(46):175-184.
[23]李英杰,李建军.催化燃烧技术处理有机废气进展[J].山东化工,2017,46(12):66-69.
[24]张力,张俊广,杨仲卿,等.超低浓度甲烷在Cu/γ-Al2O3催化颗粒流化床中的燃烧特性[J].燃料化学学报,2012,40(7):886-891.
[25]Fant D B,Jackson G S,Karim H. Status of catalytic combustion R&D for the department of energy advanced turbine systems program[J].Journal of Engineering for Gas Turbines and Power,2000(122):293-300.
[26]Kolodziej A,lojewska J. Optimization of structured catalyst carriers for VOC combustion[J].Catalysis Today,2005,105(3):378-384.
[27]韩金枝,赵洪梅,付腾飞.污水处理厂除臭方法及工艺选择[J].能源与环境,2011(2):86-87.
[28]陈玉香,刘忠生,王新,等.石化污水处理场废气催化燃烧处理工业应用[J].当代化工,2006,35(6):425-428.
[29]赵成,梁芳.国内VOCs 末端治理技术现状及组合工艺分析[J].上海环境科技,2016,35(5):223-228.
[30]Chao B S,Yi J. Simulation and optimization on the regenerative thermal oxidation of volatile organic compounds[J].Chemical Engineering Journal,2000,76(2):103-114.
[31]郦琪,曹文平,张学杨,等.生物膜法在废气中有机物去除的应用现状及发展趋势[J].广州化学,2014,42(3):18-20.
[2]闫松,尹天亚,单广波,等.炼油企业污水处理厂恶臭污染分布特征及规律[J].环境检测管理与技术,2010,22(4):61-62.
[3]李凌波,韩丛碧,郭兵兵,等.炼油厂恶臭污染源综合监测与评价[J].石油炼制与化工,2013,44(1):95-100.
[4]方向晨,刘忠生,王学海.炼油企业恶臭气体治理技术[J].石油化工安全环保技术,2008,24(5):48-62.
[5]杨昌竹.环境工程原理[M].北京:冶金工业出版社,1994:164-166.
[6]Chiang Y C,Chiang P C,Huang C P. Effects of pore structure and temperature on VOC adsorption on activated carbon [J].Carbon,2001,39(4):523-534.
[7]龚朝兵,陈伟,李海华.炼厂污水处理场恶臭气体治理实践[J].石油化工技术与经济,2016,32(5):37-40.
[8]王刚.炼油恶臭污染治理技术在中国石化天津分公司的应用实例[J].化工环保,2014,34(3):235-239.
[9]刘恋,朱艳华,田森林.微乳液和混合表面活性剂对甲苯的增溶作用[J].环境科学与技术,2010,33(9):150-154.
[10]Prince L M.Microemulsion:Theory and practice[M].New York:Academic Press,1997.
[11]赵保卫,朱利中.微乳液对难溶有机物的增溶作用及影响因素[J].中国环境科学,2003,23(5):493-497.
[12]Hoar T P,Schulman J H.Transparent water-in-oil dispersions:The oleopathic hydro-micelle[J].Nature,1943,152:102-103.
[13]Zhu L Z,Zhao B L,Li Z L.Water solubility enhancements of PAHs by sodium castor oil sulfonate microemulsions[J].Environ Sci,2003,15:583-589.
[14]田森林,刘恋,宁平. 填料塔-微乳液增溶吸收法净化甲苯废气[J].环境工程学报,2010,4(11):2552-2556.
[15]余倩,邓欣,李俊,等.活性炭吸附技术对VOCs净化处理的研究进展[J].材料研究与应用,2010,4(4):368-371.
[16]吴德礼,朱申红.新型吸附剂的发展与应用[J].矿产综合利用,2002(1):36-40.
[17]李守信,金平,张文智,等.采用活性炭纤维吸附装置回收VOC的优点分析[J].化工环保,2004,24(Z 1):274-276.
[18]李婕,羌宁.挥发性有机物(VOCs)活性炭吸附回收技术综述[J].四川环境,2007,26(6):101-106.
[19]刘永斌,陈俊梅,陈彬彬.催化燃烧技术在炼油污水处理场恶臭治理中的应用[J].炼油技术与工程,2011,41(11):54-57.
[20]王本勇,赵磊,王新.石化污水处理场VOCs废气催化氧化处理实验研究[J].环境科学导刊,2017,36(2):97-100.
[21]Yin C F,Lei L,Ming G. Improved catalytic capability of mesoporous TiO2 microspheres and photodecomposition of toluene[J].Materials & Interfaces,2010,11(2):3134-3140.
[22]Lin H L,Toshihiro L,et al. Processing and photo-catalytic properties of Cu-grafted TiO2 powder from acid treated BaTiO3[J].Materials Research Bulletin,2011(46):175-184.
[23]李英杰,李建军.催化燃烧技术处理有机废气进展[J].山东化工,2017,46(12):66-69.
[24]张力,张俊广,杨仲卿,等.超低浓度甲烷在Cu/γ-Al2O3催化颗粒流化床中的燃烧特性[J].燃料化学学报,2012,40(7):886-891.
[25]Fant D B,Jackson G S,Karim H. Status of catalytic combustion R&D for the department of energy advanced turbine systems program[J].Journal of Engineering for Gas Turbines and Power,2000(122):293-300.
[26]Kolodziej A,lojewska J. Optimization of structured catalyst carriers for VOC combustion[J].Catalysis Today,2005,105(3):378-384.
[27]韩金枝,赵洪梅,付腾飞.污水处理厂除臭方法及工艺选择[J].能源与环境,2011(2):86-87.
[28]陈玉香,刘忠生,王新,等.石化污水处理场废气催化燃烧处理工业应用[J].当代化工,2006,35(6):425-428.
[29]赵成,梁芳.国内VOCs 末端治理技术现状及组合工艺分析[J].上海环境科技,2016,35(5):223-228.
[30]Chao B S,Yi J. Simulation and optimization on the regenerative thermal oxidation of volatile organic compounds[J].Chemical Engineering Journal,2000,76(2):103-114.
[31]郦琪,曹文平,张学杨,等.生物膜法在废气中有机物去除的应用现状及发展趋势[J].广州化学,2014,42(3):18-20.
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