Metal–Organic Frameworks Modulated by Doping Er3+ for Up-Conversion Luminescence

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• 作者：Xindan Zhang ; Bin Li ; Heping Ma ; Liming Zhang ; Haifeng Zhao
• 刊名：ACS Applied Materials & Interfaces
• 出版年：2016
• 出版时间：July 13, 2016
• 年：2016
• 卷：8
• 期：27
• 页码：17389-17394
• 全文大小：413K
• 年卷期：0
• ISSN：1944-8252

文摘

Here we present metal–organic frameworks prepared by a one-step synthesis method, possessing both architectural properties of MOF building and up-conversion luminescence of rare earth Er³⁺ (hereafter denoted as Up-MOFs). Up-MOFs have characteristic up-conversion emissions at 520, 540, and 651 nm under the excitation of 980 nm owing to the multiple photon absorption. The up-conversion mechanism of these Up-MOFs has been discussed, and it can be attributed to the excited state absorption process. The design and synthesis of Up-MOF materials possessing near-infrared region excitation and up-conversion luminescence are fully expected to be candidates for the advancement of applications in bioimaging, sensors, optoelectronics, and energy conversion/storage devices.