Fast Response and High Sensitivity Europium Metal Organic Framework Fluorescent Probe with Chelating Terpyridine Sites for Fe3+

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• 作者：Min Zheng ; Huaqiao Tan ; Zhigang Xie ; Ligong Zhang ; Xiabin Jing ; Zaicheng Sun
• 刊名：ACS Applied Materials & Interfaces
• 出版年：2013
• 出版时间：February 13, 2013
• 年：2013
• 卷：5
• 期：3
• 页码：1078-1083
• 全文大小：407K
• 年卷期：v.5,no.3(February 13, 2013)
• ISSN：1944-8252

文摘

Iron is one of the most important elements in the metabolic process for all living system. However, both its deficiency and excess from normal permissible limits can induce serious disorders. We synthesized a europium-based metal鈥搊rganic framework (Eu-MOF), EuL₃ (L = 4鈥?(4-carboxyphenyl)-2,2鈥? 6鈥?2鈥?terpyridine), under hydrothermal conditions, and used it as a solid luminescence sensor for Fe³⁺ ions. The robust EuL₃ shows fast response ( 1 min) and high sensitivity (Stern鈥揤olmer constant K_SV = 4.1 脳 10³ L/mol) for Fe³⁺ ions in aqueous solution or biological systems due to the existence of chelating terpyridine and open channels. The simple and portable test paper based on the EuL₃ fluorescent sensor system provides a convenient and reliable detection of Fe³⁺ in every day applications. This pioneering work contributes to extend the potential application of Ln-MOFs to the biological and environmental areas.

Keywords:

terpyridine; europium metal organic framework; fluorescent probe; Fe³⁺ ion; Fe³⁺ test paper; open channel