Azido-Directed Formation of An Unprecedented Mn(II)-Organic Framework with Nanoscale Cubic Cage Units
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- 作者：Jiong-Peng Zhao ; Ran Zhao ; Wei-Chao Song ; Qian Yang ; Fu-Chen Liu ; Xian-He Bu
- 刊名：Crystal Growth & Design
- 出版年：2013
- 出版时间：February 6, 2013
- 年：2013
- 卷：13
- 期：2
- 页码：437-439
- 全文大小：266K
- 年卷期：v.13,no.2(February 6, 2013)
- ISSN：1528-7505
文摘
A bcu topological three-dimensional Mn(II)-organic framework [Mn22(N3)8(L)12(H2O)26路5H2O]鈭?/sub> (1) (L = 1,2,3-triazole-4,5-dicarboxylate) based on an unprecedented nanoscale cage has been hydrothermally synthesized. Dominating antiferromagnetic interactions were detected between the MnII ions in 1.
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