Charge-Transfer Dynamics in Poly(3-hexylthiophene):Perylenediimide-C60 Blend Films Studied by Ultrafast Transient Absorption

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• 作者：Kimmo M. Kaunisto ; Paola Vivo ; Rajeev K. Dubey ; Vladimir I. Chukharev ; Alexander Efimov ; Nikolai V. Tkachenko ; Helge J. Lemmetyinen
• 刊名：Journal of Physical Chemistry C
• 出版年：2014
• 出版时间：May 22, 2014
• 年：2014
• 卷：118
• 期：20
• 页码：10625-10630
• 全文大小：306K
• 年卷期：v.118,no.20(May 22, 2014)
• ISSN：1932-7455

文摘

Electron-transfer characteristics of 1,7-dipyrrolidinyl-substituted perylenediimide-fullerene (PyPDI-C₆₀) dyad were studied in solid films by an ultrafast transient absorption technique. The research was further expanded to study a poly(3-hexylthiophene) (P3HT):PyPDI-C₆₀ blend to reveal the charge-transfer processes that take place in bulk heterojunction films, which are potentially suitable for photovoltaic applications. This knowledge is of paramount importance when designing organic photovoltaics since the performance of thin film devices is affected by mechanisms taking place at the molecular level upon photoexcitation. It was demonstrated that the charge- separated state, formed after an electron transfer from the PyPDI to the fullerene moiety of the dyad, has a lifetime of tens of picoseconds. A charge-separated state in which the hole is localized in the P3HT and the electron is in the fullerene moiety with a lifetime of <1 ps was shown for the blend film. The intermolecular charge-separated state is suggested to recombine via hole transfer to the PyPDI moiety that is followed by an intramolecular charge recombination to the ground state.