Highly Efficient Visible-Light-Driven Photocatalytic Hydrogen Production of CdS-Cluster-Decorated Graphene Nanosheets

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• 作者：Qin Li ; Beidou Guo ; Jiaguo Yu ; Jingrun Ran ; Baohong Zhang ; Huijuan Yan ; Jian Ru Gong
• 刊名：Journal of the American Chemical Society
• 出版年：2011
• 出版时间：July 20, 2011
• 年：2011
• 卷：133
• 期：28
• 页码：10878-10884
• 全文大小：973K
• 年卷期：v.133,no.28(July 20, 2011)
• ISSN：1520-5126

文摘

The production of clean and renewable hydrogen through water splitting using photocatalysts has received much attention due to the increasing global energy crises. In this study, a high efficiency of the photocatalytic H₂ production was achieved using graphene nanosheets decorated with CdS clusters as visible-light-driven photocatalysts. The materials were prepared by a solvothermal method in which graphene oxide (GO) served as the support and cadmium acetate (Cd(Ac)₂) as the CdS precursor. These nanosized composites reach a high H₂-production rate of 1.12 mmol h^鈥? (about 4.87 times higher than that of pure CdS nanoparticles) at graphene content of 1.0 wt % and Pt 0.5 wt % under visible-light irradiation and an apparent quantum efficiency (QE) of 22.5% at wavelength of 420 nm. This high photocatalytic H₂-production activity is attributed predominantly to the presence of graphene, which serves as an electron collector and transporter to efficiently lengthen the lifetime of the photogenerated charge carriers from CdS nanoparticles. This work highlights the potential application of graphene-based materials in the field of energy conversion.