Compound class="boldFont">1, which crystalizes in P21, present Z' = 4 as result of packing forces.
Compound class="boldFont">2 crystalizes with Z' = 0.5 because part of its molecular backbone lies in the Pnma mirror plane.
Compounds class="boldFont">3 and class="boldFont">4, which crystalize in P21/c, present with Z' = 2 as result of conformerism.
The conformation of benzyl moiety is responsible for the non-centrosymmetric space group of class="boldFont">1.
The crystal packing of the compounds is marked by double catemer motif.
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