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Geochemical Characteristics and Identification Significance of Coal Type Gas in Various Geneses
详细信息   
摘要


     Based on the statistic study of 324groups of published coal type gas geochemical data from 21basins or areas from all over the world,stratigraphic distribution,stable carbon and hydrogen isotopic composition,and spatial distribution of coal type gas in various genesis are analyzed.Multiple charts for identifying the genetic types of coal type gas are established.And the feasibility of these charts is demonstrated by an example.The results show that biogenic gases that generated from coal seam are not the same as normal biogascompared with normal gas.The most significant difference is theδ13CCH4value of microbial gases lower than that of normal biogas.The stable isotopic composition of microbial gases fall within the following ranges:δ13CCH4)<-60,while for thermogenic gases,δ13CCH4)>-40.And for mixed gases,δ13CCH4ranges from-60to-40.There is a tendency that from biogenic gases to thermogenic gases,δ13CCH4,δ13CCO2-CH4,δ13CC2 H6-CH4,and CH4 /C2 H6 C3 H8gradually become heavier with the increase of the maturity of organic matter.An obvious positive correlation exists among aforementioned parameters.It is concluded that the charts ofδ13 CCH4andδ13CCO2-CH4,δ13 CCH4andδ13 CC2 H6-CH4,andδ13 CCH4and CH4 /C2 H6 C3 H8are the most reliable charts for classifying the genetic type of coal type gas.

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