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Surface Environmental Enrichment of Some Elements and Its Relationship between Anthropogenic Activity and Elemental Distribution in Soil in Jiangsu Province
详细信息   
摘要


     Whole multi-target regional geochemistry survey of 1250000 on Quaternary sediments had been accomplished in Jiangsu Province by 2007,and a large number of geochemical data from soil samples have been obtained.As the first eco-geochemical surveying harvest covering a provincial whole land in China,its further research has been regarded very highly.In this paper,elements concentration and its distribution in typical sedimentary profiles of soil and relevant eco-geochemical surveying data have been studied.These data are from 24186 top-soil samples and 6127 deep-soil samples,and every samples tested total contents of 52 elements,including Si,Al,Mg,Ca,Fe,K,Na,C,N,P,S,Se,B,Mn,Ti,V,Co,Cr,Ni,Cu,Pb,Zn,Cd,As,Sb,Bi,Hg,Mo,W,Sn,Ag,Au,Sr,Ba,La,Ce,Y,Sc,Zr,Th,U,Ga,Ge,Tl,Li,Be,Rb,Nb,F,Cl,Br and I,pH and total organic carbonTOC,in total 54.The above stated samples are evenly distributed in whole soil,and there is a sample within per 4km2 scopes in top-soil and its sampling depth is 0-20cm,yet there is a sample within per 16km2 scopes in deep-soil and its sampling depth is 150-200cm.The present study summarizes distributive characteristics of relevant elements within soil from different areas of Jiangsu Province,calculates and analyses typical elements enriched factors EFs in surface environmental soil,describes anthropogenic environmental enrichment phenomenon of some elements so Cd,Hg,Se,S,C,and so on,discusses effects of artificial activities on soil element distribution,and induces or sums up causes of anthropogenic environmental enrichment of typical elements in soil.From the study,the following conclusions can be made 1following typical elements formed significant anthropogenic environmental enrichment and soil acidification,as Cd,Se,S,Hg,Sn,C,N,P,Br,Pb,Zn,Sb,Bi,Au,Cu,Cl,TOC,etc;2Cd,Se,Hg,Sn,Br,N,S,C,P,TOC,pH,Pb and Zn are the most sensitive tracer or characteristic indicator reflecting human activities effect to elemental distribution in soil,enriched depths of these elements are not beyond 40cm in the edaphic sedimentary column at most cases,and their distributions are normally uneven in soil and the varied coefficientsCvof elements content are larger than 0.5.The above stated 13 indicators can be used as a long-term study of human activities on soil environment influence in the Jiangsu Province;3above 50% of the samples show enriched factorsEFsin anthropogenic environmental soil are larger than 2.0 as to the following elements,for N,S,TOC,Hg,Se,Br,etc.There are higher proportion polluted by Cd,Hg and Pb in soil around some large city;and 4there are obvious positive correlated relationship between the population density and mean anthropogenic environmental added content of Se,Hg,Cd and Sor so mean ΔSe,ΔHg,ΔCd and ΔS;Δ=topsoil-deep soilin soil from 13 cities of the Jiangsus,the Jiangsus administrative areas consist of 13 cities including Nanjing City,Suzhou City,Wuxi City,Changzhou City,Zhenjiang City,Yangzhou City,Taizhou City,Nantong City,Yancheng City,Huaian City,Suqian City,Xuzhou City,and Lianyungang City,and this pertinence pointed out impact on edaphic environmental evolution in recent industry development because of consuming coal resources on a large scale.Furthermore,with the enforcement of artificial activities on soil environment,the effect and significance related to elemental anthropogenic environmental enrichment will become more and more obvious and important in soil.

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