纳米铜食品抗菌包装材料的研究进展
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摘要
目的介绍纳米铜在食品抗菌包装材料中的研究现状。方法总结纳米铜食品抗菌包装材料在制备、应用、迁移及安全方面的研究进展,探讨纳米铜抗菌包装材料未来的研究方向。结论纳米铜的尺寸、形貌、化学组成、分散性、添加量等都会对复合包装材料的力学性能、光学性能、热力学性能等产生影响。纳米铜的加入同时会使复合材料具有抗菌性。纳米铜向食品中的迁移可能会影响食品安全,但目前对纳米铜迁移规律和安全评价的研究不足,需要深入系统地探讨。
The work aims to introduce the progress of nano-copper in food antimicrobial composite packaging material. The development of nano-copper composite packaging material was summarized in fabrication, application, migration and safety, and the future development direction was discussed. The size, morphology, disperse uniformity, chemical constitution and concentration of the nano-copper can affect mechanical, optical, thermodynamic properties of the composite material. Besides, the addition of nano-copper can also endow the composite with antibacterial capability. The migration of nano-copper from the material to the food can be a risk for the food safety. However, the research on the law of migration and the safety assessment is insufficient. Therefore, the deeper researches need to be made in the future.
The work aims to introduce the progress of nano-copper in food antimicrobial composite packaging material. The development of nano-copper composite packaging material was summarized in fabrication, application, migration and safety, and the future development direction was discussed. The size, morphology, disperse uniformity, chemical constitution and concentration of the nano-copper can affect mechanical, optical, thermodynamic properties of the composite material. Besides, the addition of nano-copper can also endow the composite with antibacterial capability. The migration of nano-copper from the material to the food can be a risk for the food safety. However, the research on the law of migration and the safety assessment is insufficient. Therefore, the deeper researches need to be made in the future.
引文
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[2]GABBAY J,BORKOW G.Copper,an Ancient Remedy Returning to Fight Microbial,Fungal and Viral Infections[J].Current Chemical Biology,2009,3(3):272-278.
[3]BEETON M L,ALDRICHWRIGHT J R,BOLHUIS A.The Antimicrobial and Antibiofilm Activities of Copper(II)Complexes[J].Journal of Inorganic Biochemistry,2014,140(11):167-172.
[4]BEN-SASSON M,ZODROW K R,QI G,et al.Surface Functionalization of Thin-film Composite Membranes with Copper Nanoparticles for Antimicrobial Surface Properties[J].Environmental Science&Technology,2014,48(1):384-393.
[5]BOGDANOVI?U,LAZI?V,VODNIK V,et al.Copper Nanoparticles with High Antimicrobial Activity[J].Materials Letters,2014,128(128):75-78.
[6]TAMAYO L,AZóCAR M,KOGAN M,et al.Copper-polymer Nanocomposites:an Excellent and Cost-effective Biocide for Use on Antibacterial Surfaces[J].Materials Science&Engineering C,2016,69:1391-1409.
[7]ARAúJO I,SILVA R R,PACHECO G,et al.Hydrothermal Synthesis of Bacterial Cellulose-copper Oxide Nanocomposites and Evaluation of Their Antimicrobial Activity[J].Carbohydr Polym,2017,179:341-349.
[8]CASTRO M J L,CABEDO M L,SáNCHEZ M G.Antimicrobial Nanocomposites and Electrospun Coatings Based on Poly(3-hydroxybutyrate-co-3-hydroxyvalerate)and Copper Oxide Nanoparticles for Active Packaging and Coating Applications[J].Journal of Applied Polymer Science,2017,135(2):1-11.
[9]MIRANDA C,RODRíGUEZ-LLAMAZARES S,CASTA?O J,et al.Cu Nanoparticles/PVC Composites:Thermal,Rheological and Antibacterial Properties[J].Advances in Polymer Technology,2018,37(3):937-942.
[10]REN X,CHEN D,TANG F.Shape-controlled Synthesis of Copper Colloids with a Simple Chemical Route[J].Journal of Physical Chemistry B,2005,109(33):15803-15807.
[11]NIU W,ZHANG L,XU G.Seed-mediated Growth of Noble Metal Nanocrystals:Crystal Growth and Shape Control[J].Nanoscale,2013,5(8):3172-3181.
[12]B?NNEMANN H,RICHARDS R M.Nanoscopic Metal Particles-synthetic Methods and Potential Applications[J].European Journal of Inorganic Chemistry,2001,10:2455-2480.
[13]SOLANKI J N,SENGUPTA R,MURTHY Z V P.Synthesis of Copper Sulphide and Copper Nanoparticles with Microemulsion Method[J].Solid State Sciences,2010,12(9):1560-1566.
[14]WEN J,LI J,LIU S,et al.Preparation of Copper Nanoparticles in a Water/Oleic Acid Mixed Solvent via Two-step Reduction Method[J].Colloids&Surfaces APhysicochemical&Engineering Aspects,2011,373(1):29-35.
[15]MANCIER V,DALTIN A L,LECLERCQ D.Synthesis and Characterization of Copper Oxide(I)Nanoparticles Produced by Pulsed Sonoelectrochemistry[J].Ultrasonics-sonochemistry,2008,15(3):157-163.
[16]MANCIER V,ROUSSE-BERTRAND C,DILLE J,et al.Sono and Electrochemical Synthesis and Characterization of Copper Core-silver Shell Nanoparticles[J].Ultrasonics Sonochemistry,2010,17(4):690-696.
[17]NAZAR N,BIBI I,KAMAL S,et al.Cu Nanoparticles Synthesis Using Biological Molecule of P.Granatum Seeds Extract as Reducing and Capping Agent:Growth Mechanism and Photo-catalytic Activity[J].International Journal of Biological Macromolecules,2018,106:1203-1210.
[18]RAJESH K M,AJITHA B,REDDY Y A K,et al.Assisted Green Synthesis of Copper Nanoparticles Using Syzygium Aromaticum Bud Extract:Physical,Optical and Antimicrobial Properties[J].Optik-international Journal for Light and Electron Optics,2018,154:593-600.
[19]GHORBANI H R.Biological and Non-biological Methods for Fabrication of Copper Nanoparticles[J].Chemical Engineering Communications,2015,202(11):1463-1467.
[20]RAJA M,SUBHA J,ALI F B,et al.Synthesis of Copper Nanoparticles by Electroreduction Process[J].Advanced Manufacturing Processes,2008,23(8):782-785.
[21]PONCE A A,KLABUNDE K J.Chemical and Catalytic Activity of Copper Nanoparticles Prepared via Metal Vapor Synthesis[J].Journal of Molecular Catalysis A Chemical,2005,225(1):1-6.
[22]SEN P,GHOSH J,ABDULLAH A,et al.Preparation of Cu,Ag,Fe and Al Nanoparticles by the Exploding Wire Technique[J].Journal of Chemical Sciences,2003,115(5/6):499-508.
[23]SIMON P,CHAUDHRY Q,BAKO?D.Migration of Engineered Nanoparticles from Polymer Packaging to Food-A Physicochemical View[J].Journal of Food&Nutrition Research,2008,47(47):105-113.
[24]NOONAN G O,WHELTON A J,CARLANDER D,et al.Measurement Methods to Evaluate Engineered Nanomaterial Release from Food Contact Materials[J].Comprehensive Reviews in Food Science&Food Safety,2014,13(4):679-692.
[25]MAYER A B R,BEGUM S.Polymer Nanocomposites with Metal Dispersions[M].Reference Module in Materials Science and Materials Engineering,2017.
[26]?ULCE A,BULKE F,SCHOWALTER M,et al.Reactive Oxygen Species(ROS)Formation Ability and Stability of Small Copper(Cu)Nanoparticles(NPs)[J].RSC Advances,2016,6(80):76980-76988.
[27]CHATTERJEE A K,CHAKRABORTY R,BASU T.Mechanism of Antibacterial Activity of Copper Nanoparticles[J].Nanotechnology,2014,25(13):12-23.
[28]LOMATE G B,DANDI B,MISHRA S.Development of Antimicrobial LDPE/Cu Nanocomposite Food Packaging Film for Extended Shelf Life of Peda[J].Food Packaging&Shelf Life,2018,16:211-219.
[29]PALZA H,QUIJADA R,DELGADO K.Antimicrobial Polymer Composites with Copper Micro-and Nanoparticles:Effect of Particle Size and Polymer Matrix[J].Journal of Bioactive&Compatible Polymers,2015,30(4):366-380.
[30]CáRDENAS G,DíAZ V J,MELéNDREZ M F,et al.Colloidal Cu Nanoparticles/Chitosan Composite Film Obtained by Microwave Heating for Food Package Applications[J].Polymer Bulletin,2009,62(4):511-524.
[31]ZHANG A,ZHANG Y,PAN G,et al.In Situ Formation of Copper Nanoparticles in Carboxylated Chitosan Layer:Preparation and Characterization of Surface Modified TFC Membrane with Protein Fouling Resistance and Long-lasting Antibacterial Properties[J].Separation&Purification Technology,2017,176:164-172.
[32]JIA B,YAN M,LI C,et al.Preparation of Copper Nanoparticles Coated Cellulose Films with Antibacterial Properties through One-step Reduction[J].ACS Applied Materials&Interfaces,2012,4(6):2897-2902.
[33]MUTHULAKSHMI L,RAJINI N,NELLAIAH H,et al.Preparation and Properties of Cellulose Nanocomposite Films with in Situ Generated Copper Nanoparticles Using Terminalia Catappa Leaf Extract[J].International Journal of Biological Macromolecules,2016,95:1064-1071.
[34]TAMAYO L A,ZAPATA P,RABAGLIATI F,et al.Antibacterial and Non-cytotoxic Effect of Nanocomposites Based in Polyethylene and Copper Nanoparticles[J].Journal of Materials Science:Materials in Medicine,2015,26(3):129-134.
[35]PALZA H,DELGADO K,MORAGA N,et al.Polypropylene in the Melt State as a Medium for in Situ Synthesis of Copper Nanoparticles[J].Aiche Journal,2015,60(10):3406-3411.
[36]PALZA H,GUTIéRREZ S,DELGADO K,et al.Toward Tailor-made Biocide Materials Based on Poly(Propylene)/Copper Nanoparticles[J].Macromolecular Rapid Communications,2010,31(6):563-567.
[37]BIKIARIS D N,TRIANTAFYLLIDIS K S.HDPE/Cu-nanofiber Nanocomposites with Enhanced Antibacterial and Oxygen Barrier Properties Appropriate for Food Packaging Applications[J].Materials Letters,2013,93(7):1-4.
[38]GRIGORIADOU I,PARASKEVOPOULOS K M,KARAVASILI M,et al.HDPE/Cu-nanofiber Nanocomposites with Enhanced Mechanical and UV Stability Properties[J].Composites Part B,2013,55(12):407-420.
[39]ZHANG W,ZHANG Y H,JI J H,et al.Antimicrobial Properties of Copper Plasma-modified Polyethylene[J].Polymer,2006,47(21):7441-7445.
[40]BECERRA A,RODRIGUEZ-LLAMAZARES S,CARRASCO C,et al.Preparation of Poly(Vinyl Chloride)/Copper Nanocomposite Films with Reduced Bacterial Adhesion[J].High Performance Polymers,2013,25(1):51-60.
[41]WACHARAWICHANANT S,THONGYAI S,PHUTT-HAPHAN A,et al.Effect of Particle Sizes of Zinc Oxide on Mechanical,Thermal and Morphological Properties of Polyoxymethylene/Zinc Oxide Nanocomposites[J].Polymer Testing,2008,27(8):971-976.
[42]AMINA M,HASSAN M S,MUSAYEIB N M A,et al.Improved Antibacterial Activity of HAP Garlanded PLGA Ultrafine Fibers Incorporated with CuO:Synthesis and Characterization[J].Journal of Sol-gel Science and Technology,2014,71(1):43-49.
[43]ESPA?A-SáNCHEZ B L,áVILA-ORTA C A,PADILLA-VACA F,et al.Enhanced Antibacterial Activity of Melt Processed Poly(Propylene)Ag and Cu Nanocomposites by Argon Plasma Treatment[J].Plasma Processes&Polymers,2014,11(4):353-365.
[44]DUNCAN T V,PILLAI K.Release of Engineered Nanomaterials from Polymer Nanocomposites:Diffusion,Dissolution and Desorption[J].ACS Appl Mater Interfaces,2015,7(1):2-19.
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