含酚废水处理技术研究进展
|
摘要
石油化工、炼油、焦化等行业不断发展,除了带来经济上的发展,还产生大量的含酚废水,对水体构成严重污染,很难被降解。含酚废水中的主要物质苯酚及其衍生物是一种原生质毒物,不仅对饮用水水源有危害作用,其毒性还会对水生生物产生不利的影响,因此含酚废水的治理不容忽视。国内外学者针对这个问题分别在物理、化学及生物方面进行了研究,提出了吸附、气提、电化学氧化法、还原、生物膜、固定化微生物技术等方法,不断完善含酚废水的处理途径。
The petrochemical,refining,coking and other industries continue to develop. In addition to bringing economic development,a large amount of phenol-containing wastewater is produced, which poses serious pollution to water bodies and is difficult to be degraded. Phenol and its derivatives, the main substance in phenol-containing wastewater, are a protoplasmic poison, which not only has harmful effect on drinking water sources, but also has adverse effect on aquatic organisms. Therefore, the treatment of phenol-containing wastewater cannot be ignored. Domestic and foreign scholars have studied the physical, chemical and biological methods to solve this problem, and adsorption, stripping, electrochemical oxidation, reduction, biofilm, and immobilized microbial technologies were developed to continuously improve the treatment of phenol-containing wastewater.
The petrochemical,refining,coking and other industries continue to develop. In addition to bringing economic development,a large amount of phenol-containing wastewater is produced, which poses serious pollution to water bodies and is difficult to be degraded. Phenol and its derivatives, the main substance in phenol-containing wastewater, are a protoplasmic poison, which not only has harmful effect on drinking water sources, but also has adverse effect on aquatic organisms. Therefore, the treatment of phenol-containing wastewater cannot be ignored. Domestic and foreign scholars have studied the physical, chemical and biological methods to solve this problem, and adsorption, stripping, electrochemical oxidation, reduction, biofilm, and immobilized microbial technologies were developed to continuously improve the treatment of phenol-containing wastewater.
引文
[1]王子,马鲁铭.催化铁还原技术在工业废水处理中的应用进展[J].中国给水排水,2009,25(06):9-13+18.
[2]高超,王启山.吸附法处理含酚废水的研究进展[J].水处理技术,2011,37(01):1-4.
[3]何宗健,刘敏,沈越,等.降解高浓度含酚废水菌株的筛选及性能的研究[J].水处理技术,2009,35(12):84-87.
[4]秦胜东,郭嘉昒,刘玉存,等.固定化微生物技术研究进展及其在水处理中的应用[J].水处理技术,2014,40(10):6-11.
[5]刘俊逸,张宇,张蕾,等.含酚工业废水处理技术的研究进展[J].工业水处理,2018,38(10):12-16.
[6]王昌朋,董双建,董松祥,等.气提法脱除聚异丁烯基酚中的苯酚[J].石油化工,2018,47(10):1098-1102
[7]王方朝,张宁,朱建航,等.生物质基活性炭处理含酚废水研究进展[J].水处理技术,2017,43(07):17-21.
[8]吴悦,张彩云,蔡泽煌,等.载铜活性炭对含酚废水的吸附性能[J].净水技术,2018,37(09):101-105.
[9]Zhao Wenkai,Liang Yuji,Wu Yonghong,el al.Removal of phenol andphosphoric acid from wastewater by microfiltration carbon membranes[J].Chemical Engineering Communications,2018,205(10):1432-1441.
[10]乔鑫龙,方梦祥,岑建孟,等.萃取法处理含酚废水的研究进展[J].水处理技术,2016,42(04):7-11+16.
[11]张晓辉,皮科武,胡林,等.A/O-混凝工艺处理氰酚废水的研究[J].工业水处理,2009,29(11):56-58.
[12]孙宇,刘建华,刘鹤楠.混凝-Fenton氧化联合工艺处理有机废水的试验研究[J].东北电力大学学报,2015,35(03):64-67.
[13]李鹏,赵跃民,王立章,等.TiO2-AC电催化氧化含酚废水[J].环境工程学报,2014,8(11):4643-4649.
[14]滕厚开,谢陈鑫.电解催化氧化法处理含酚废水技术及机理研究[J].工业水处理,2016,36(12):90-93.
[15]敬双怡,李海洋,韩剑宏,等.吸附-S/A/SMBBR工艺处理含酚高纯溶剂生产废水[J].中国给水排水,2018,34(07):113-117+123.
[16]姚显阳,梁英,梁家豪,等.升流式厌氧污泥床反应器处理含酚废水研究进展[J].水处理技术,2017,43(07):12-16+21.
[17]王元超,骆学艳.A/O-O法处理焦化废水的运行温度控制措施[J].环境科学导刊,2018,37(04):58-60.
[18]董自斌,王开春,刘志奎,等.络合萃取+蒸发+A/O处理癸二酸生产含酚废水[J].工业水处理,2015,35(10):94-96.
[19]方芳,姜和,曾虹燕,等.固定化高效复合菌群JHD降解苯酚特性及其动力学研究[J].水处理技术,2011,37(12):51-53+58.
[20]尹艳娥,胡中华,李秋瑜.固定化生物活性炭纤维小球处理苯酚废水研究[J].中国给水排水,2006(03):93-95+100.
[21]胡龙兴,张仲燕.酶催化氧化处理含酚废水的研究[J].环境科学,1992(04):40-44+94.
[22]Amir Kaffash,Hamid R.Zare and Khosrow Rostami.Highly sensitive biosensing of phenol based on the adsorption of the phenol enzymatic oxidation product on the surface of an electrochemically reduced graphene oxide-modified electrode.Anal Methods,2018,10:2731-2739.
[23]王图锦,潘瑾,刘雪莲.高效苯酚降解菌群的选育及降解特性研究[J].工业水处理,2017,37(03):65-68.
[24]蒙小俊,张玉秀,杜海迪,等.Diaphorobacter P2菌株酚降解特性及其在焦化废水中的除酚作用[J].环境化学,2014,33(05):789-793.
[2]高超,王启山.吸附法处理含酚废水的研究进展[J].水处理技术,2011,37(01):1-4.
[3]何宗健,刘敏,沈越,等.降解高浓度含酚废水菌株的筛选及性能的研究[J].水处理技术,2009,35(12):84-87.
[4]秦胜东,郭嘉昒,刘玉存,等.固定化微生物技术研究进展及其在水处理中的应用[J].水处理技术,2014,40(10):6-11.
[5]刘俊逸,张宇,张蕾,等.含酚工业废水处理技术的研究进展[J].工业水处理,2018,38(10):12-16.
[6]王昌朋,董双建,董松祥,等.气提法脱除聚异丁烯基酚中的苯酚[J].石油化工,2018,47(10):1098-1102
[7]王方朝,张宁,朱建航,等.生物质基活性炭处理含酚废水研究进展[J].水处理技术,2017,43(07):17-21.
[8]吴悦,张彩云,蔡泽煌,等.载铜活性炭对含酚废水的吸附性能[J].净水技术,2018,37(09):101-105.
[9]Zhao Wenkai,Liang Yuji,Wu Yonghong,el al.Removal of phenol andphosphoric acid from wastewater by microfiltration carbon membranes[J].Chemical Engineering Communications,2018,205(10):1432-1441.
[10]乔鑫龙,方梦祥,岑建孟,等.萃取法处理含酚废水的研究进展[J].水处理技术,2016,42(04):7-11+16.
[11]张晓辉,皮科武,胡林,等.A/O-混凝工艺处理氰酚废水的研究[J].工业水处理,2009,29(11):56-58.
[12]孙宇,刘建华,刘鹤楠.混凝-Fenton氧化联合工艺处理有机废水的试验研究[J].东北电力大学学报,2015,35(03):64-67.
[13]李鹏,赵跃民,王立章,等.TiO2-AC电催化氧化含酚废水[J].环境工程学报,2014,8(11):4643-4649.
[14]滕厚开,谢陈鑫.电解催化氧化法处理含酚废水技术及机理研究[J].工业水处理,2016,36(12):90-93.
[15]敬双怡,李海洋,韩剑宏,等.吸附-S/A/SMBBR工艺处理含酚高纯溶剂生产废水[J].中国给水排水,2018,34(07):113-117+123.
[16]姚显阳,梁英,梁家豪,等.升流式厌氧污泥床反应器处理含酚废水研究进展[J].水处理技术,2017,43(07):12-16+21.
[17]王元超,骆学艳.A/O-O法处理焦化废水的运行温度控制措施[J].环境科学导刊,2018,37(04):58-60.
[18]董自斌,王开春,刘志奎,等.络合萃取+蒸发+A/O处理癸二酸生产含酚废水[J].工业水处理,2015,35(10):94-96.
[19]方芳,姜和,曾虹燕,等.固定化高效复合菌群JHD降解苯酚特性及其动力学研究[J].水处理技术,2011,37(12):51-53+58.
[20]尹艳娥,胡中华,李秋瑜.固定化生物活性炭纤维小球处理苯酚废水研究[J].中国给水排水,2006(03):93-95+100.
[21]胡龙兴,张仲燕.酶催化氧化处理含酚废水的研究[J].环境科学,1992(04):40-44+94.
[22]Amir Kaffash,Hamid R.Zare and Khosrow Rostami.Highly sensitive biosensing of phenol based on the adsorption of the phenol enzymatic oxidation product on the surface of an electrochemically reduced graphene oxide-modified electrode.Anal Methods,2018,10:2731-2739.
[23]王图锦,潘瑾,刘雪莲.高效苯酚降解菌群的选育及降解特性研究[J].工业水处理,2017,37(03):65-68.
[24]蒙小俊,张玉秀,杜海迪,等.Diaphorobacter P2菌株酚降解特性及其在焦化废水中的除酚作用[J].环境化学,2014,33(05):789-793.