离子交换与吸附树脂对重金属废水处理的研究进展
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摘要
随着工业的飞速发展,重金属废水对环境造成的污染问题日益严重,运用离子交换与吸附树脂对重金属废水进行处理的方法得到广泛关注。介绍了近年来国内外采用离子交换与吸附树脂处理重金属废水的研究发展,主要包括树脂接枝官能团与修饰金属两方面来提高树脂对重金属离子的吸附量。
With the rapid development of industry, the pollution caused by heavy metal-containing wastewater to the environment is becoming more and more serious. The treatment of heavy metal-containing wastewater by ion exchange or adsorption resin has received extensive attention. This paper introduced the research and development of heavy metal-containing wastewater treatment by ion exchange or adsorption resins including resins grafting functional groups and modified metal to improve the adsorption capacity of heavy metal ions at home and abroad in recent years.
With the rapid development of industry, the pollution caused by heavy metal-containing wastewater to the environment is becoming more and more serious. The treatment of heavy metal-containing wastewater by ion exchange or adsorption resin has received extensive attention. This paper introduced the research and development of heavy metal-containing wastewater treatment by ion exchange or adsorption resins including resins grafting functional groups and modified metal to improve the adsorption capacity of heavy metal ions at home and abroad in recent years.
引文
[1] Penderg ast M T M, Hoek E M V. A review of water treatment membrane nanotechnologies[J]. Energy&Environmental Science,2011, 4. Ali I, Gupta V K.
[2] Advances in water treatment by adsorption technology[J]. Nature Protocols, 2006, 1(6):2 661-2 667.
[3] Rivera-Utrilla J M. Sánchez-Polo V, Gómez-Serrano, et al.Activated carbon modifications to enhance its water treatment applications. An overview[J]. Journal of Hazardous Materials, 2011,187(1-3):1-23.
[4] Zhou Y F, Haynes R J. Removal of Pb(II), Cr(III)and Cr(VI)from aqueous solutions using alum-derived water treatment sludge[J].Water, Air&Soil Pollution, 2011, 215(1-4):631-643.
[5] Tian Y, Wu M, Liu R, et al. Electrospun membrane of cellulose acetate for heavy metal ion adsorption in water treatment[J].Carbohydrate Polymers, 2011, 83(2):743-748.
[6] Prep aration and application of amino-modified starch for heavy metal ions water treatment[J]. Chemical Industry and Engineering Progress, 2011, 30(4):854-856.
[7] Sheng-Quan Y, Si-Yuan G, Yi-Gang Y, et al. Removal of the heavy metal ion Cr(VI)by soybean hulls in dyehouse wastewater treatment[J]. Desalination&Water Treatment, 2012, 42(1-3):197-201.
[8] Wang T, Song Y, Li B, et al. Chelating-ultrafiltration treatment of some heavy metal ions in aqueous solutions by crosslinking carboxymethyl modified cornstarch[J]. Water, Air&Soil Pollution,2012, 223(2):679-686.
[9]雷兆武,孙颖.离子交换技术在重金属废水处理中的应用[J].环境科学与管理,2008,34(10):82-84.
[10] Chen Q, Xu W, Ge Q. Novel multi-charge hydroacid complexes that effectively remove heavy metal ions from water in forward osmosis processes[J]. Environmental Science&Technology, 2018:52(7):4 464-4 471.
[11] Thatai S, Khurana P, Kumar D. Role of advanced materials as nanosensors in water treatment[M]//Biosensors Nanotechnology.John Wiley&Sons, Inc. 2014.
[12] Li X M, Xu G, Liu Y, et al. Magnetic Fe3O4nanoparticles:synthesis and application in water treatment[J]. Nanoscience&Nanotechnology-Asia, 2011, 1(1):14-24.
[13] Mende M, Schwarz D, Steinbach C, et al. The Influence of Salt Anions on Heavy Metal Ion Adsorption on the Example of Nickel[J]. Materials, 2018, 11(3):373-.375.
[14]龚云表，石安富主编.合成树脂与塑料手册[M].上海:上海科学技术出版社. 1993.
[15] Borodkin S, Sundberg D P. Polycarboxylic acid ion-exchange resin adsorbates for taste coverage in chewable tablets[J]. J Pharm Sci,2010, 60(10):1 523-1 527.
[16] Motycka S, Newth C J, Nairn J G. Preparation and evaluation of microencapsulated and coated ion-exchange resin beads containing theophylline.[J]. Journal of Pharmaceutical Sciences,2010, 74(6):643-646.
[17] Vasiliu S, Bunia I, Racovita S, et al. Adsorption of cefotaxime sodium salt on polymer coated ion exchange resin microparticles:Kinetics, equilibrium and thermodynamic studies[J]. Carbohydrate Polymers, 2011, 85(2):376-387.
[18] Fang D U, Xin-Hua Q I, Ying-Zhao X U, et al. Catalytic conversion of fructose to 5-hydroxymethylfurfural by ion-exchange resin in ionic liquid[J]. Chemical Journal of Chinese Universities,2010, 31(3):548-552.
[19]何炳林，黄文强主编.离子交换与吸附树脂[M].上海:上海科技教育出版社. 1995.
[20] Vila M, Cunill F, Izquierdo J F, et al. The role of by-products formation in methyl tert-butyl ether synthesis catalyzed by a macroporous acidic resin[J]. Applied Catalysis A General, 1994,117(2):99-108.
[21] Wu Z, Zhao R, Wang Q, et al. Synthesis of macroporous resin adsorbents and the study on the removal effectiveness of trace oil in steam condensed water[J]. Industrial Water Treatment, 2012, 32(4):59-61.
[22] Chang X, Luo X, Zhan G, et al. Synthesis and characterization of a macroporous poly(vinyl-aminoacetone)chelating resin for the preconcentration and separation of traces of gold, palladium,rhodium and ruthenium.[J]. Talanta, 1992, 39(8):937-941.
[23] Xiao G, Gao S, Xie X, et al. Synthesis of the hydrophobichydrophilic macroporous poly divinylbenzene/poly(sodium acrylate)IPN resin and adsorption performance for berberine[J]. Polymers for Advanced Technologies, 2010, 20(12):1 157-1 162.
[24] Zhang N Z, Chen Y Y. Synthesis of macroporous ellagitannic acid resin and its chelating rroperties for metal ions[J]. Journal of Macromolecular Science:Part A-Chemistry, 2006, 25(10-11):1 455-1 462.
[25] Zhang L P, Du J, Liu J. Preparation and adsorption properties of macroporous tannin resins[J]. Forest Ecosystems, 2006, 8(3):51-55.
[26] Parmar V S, Jain R, Simonsen O, et al. Synthesis and characterization of strong polar macroporous resin made from cellulose[J]. Advanced Materials Research, 2011, 346(18):743-750.
[27] Arcos-Casarrubias J A, Cruz-Díaz M R, Cardoso-Martínez J, et al.Chromium adsorption into a macroporous resin based on vinylpyridine-divinylbenzene copolymers:thermodynamics,kinetics, and process dynamic in a fixed bed column[J].Adsorption, 2018, 24(1):105-120.
[28]张全兴,李爱民,潘丙才.离子交换与吸附树脂的发展及在工业废水处理与资源化中的应用[J].高分子通报, 2015, 28(9):21-43.
[29]易然,徐静,宋玉栋,等.螯合树脂去除丙烯酸丁酯废水中的二价阳离子[J].化工环保, 2013, 33(4):289-293.
[30]陈达,刘福强,徐超,等.氨基乙酸类螯合树脂对高盐重金属离子废水的高效无害化处理技术研究[J].离子交换与吸附,2015,31(1):1-10.
[31]李福勤,聂文欢,唐玮媛,等. D402树脂对Pb(Ⅱ)、Cd(Ⅱ)的吸附性能及再生试验研究[J].工业安全与环保,2015,41(7):40-42.
[32]陈佑宁,赵维,杨小玲,等.新型偕胺肟基螯合树脂对Ni(Ⅱ)和Cu(Ⅱ)吸附性能研究[J].工业用水与废水, 2018, 49(3):17-21.
[33]薛爱莲,申书昌.聚苯乙烯硫代氨基脲螯合树脂的制备及其对重金属离子的吸附性能研究[J].化工时刊, 2014, 28(12):1-4.
[34]姚树人,晏欣,余红伟,等.多乙烯多胺胺化GMA-TAIC共聚物大孔树脂的合成及对重金属离子的吸附[J].高分子材料科学与工程, 2014, 30(4):11-15.
[35]陈佑宁,高莉,贺茂芳,等.聚乙烯四唑型螯合树脂及其对重金属离子的吸附性能[J].高等学校化学学报, 2014, 35(7):1 596-1 602.
[36]徐超,韩飞,于世涛.系列多胺类螯合树脂的合成及其对重金属离子选择性吸附研究[J].离子交换与吸附, 2017, 33(3):245-259.
[37]曹焕义,王海峰.亚氨基二乙酸鳌合树脂处理氨基酸生产含铜废水[J].水处理技术, 2018, 44(3):121-124,128.
[38]郭润强,柴思琦,毛静涛.一种改性螯合树脂的合成及其对水体Hg~(2+)的吸脱附性能研究[J].环境科技, 2018, 31(4):14-19.
[39]宗黎丹.新型吡啶类螯合树脂在强酸高盐重金属废水处理中的应用研究[A].中国化学会高分子学科委员会.中国化学会第18届反应性高分子学术研讨会论文集[C].中国化学会高分子学科委员会:中国化学会, 2016. 4.
[40]陆继来,曹蕾,周海云,等.离子交换法处理含镍电镀废水工艺研究[J].工业安全与环保, 2013, 39(12):13-15.
[41] Tuzen M, Uluozlu O D, Usta C, et al. Biosorption of copper(II), lead(II), iron(III)and cobalt(II)on Bacillus sphaericus-loaded Diaion SP-850 resin[J]. Analytica Chimica Acta, 2007, 581(2):241-246.
[42]王瑞杰,杨连威.聚丙烯酸-高岭土高吸水性树脂的制备及对重金属离子的吸附性研究[J].化工新型材料, 2011, 39(5):124-126.
[43]李继萍,莫国莉.高吸水性树脂吸附重金属离子的研究[J].广州化工, 2015, 43(24):92-94.
[44]张晓蕾,付渊,吴海霞.羧甲基高吸水树脂合成及对重金属离子的吸附[J].广州化工, 2016, 44(11):90-92.
[45]吴海霞,李纯毅,付渊,等.以羧甲基马铃薯渣为原料的高吸水树脂对Pb~(2+)吸附特性研究[J].胶体与聚合物, 2018, 36(4):163-165.
[46] Soylak M, Tuzen M. Diaion SP-850 resin as a new solid phase extractor for preconcentration-separation of trace metal ions in environmental samples[J]. Journal of Hazardous Materials, 2006,137(3):1 496-1 501.
[47] Soylak M, Topalak Z. Enrichment-separation and determinations of cadmium(II)and lead(II)-1-phenyl-1H-tetrazole-5-thiol chelates on Diaion SP-207 by solid phase extraction-flame atomic absorption spectrometry[J]. Arabian Journal of Chemistry, 2012, 35(5):720-725.
[48] Unsal Y E, Tuzen M, Soylak M. Flame Atomic absorption spectrometric determination of gold after solid phase extraction of its 2-aminobenzothiazole complex on diaion SP-207[J]. Journal of AOAC International, 2019, 99(2):534-538.
[49] Li H, Chen Y, Long J, et al. Simultaneous removal of thallium and chloride from a highly saline industrial wastewater using modified anion exchange resins[J]. Journal of Hazardous Materials, 2017,333:179-185.
[2] Advances in water treatment by adsorption technology[J]. Nature Protocols, 2006, 1(6):2 661-2 667.
[3] Rivera-Utrilla J M. Sánchez-Polo V, Gómez-Serrano, et al.Activated carbon modifications to enhance its water treatment applications. An overview[J]. Journal of Hazardous Materials, 2011,187(1-3):1-23.
[4] Zhou Y F, Haynes R J. Removal of Pb(II), Cr(III)and Cr(VI)from aqueous solutions using alum-derived water treatment sludge[J].Water, Air&Soil Pollution, 2011, 215(1-4):631-643.
[5] Tian Y, Wu M, Liu R, et al. Electrospun membrane of cellulose acetate for heavy metal ion adsorption in water treatment[J].Carbohydrate Polymers, 2011, 83(2):743-748.
[6] Prep aration and application of amino-modified starch for heavy metal ions water treatment[J]. Chemical Industry and Engineering Progress, 2011, 30(4):854-856.
[7] Sheng-Quan Y, Si-Yuan G, Yi-Gang Y, et al. Removal of the heavy metal ion Cr(VI)by soybean hulls in dyehouse wastewater treatment[J]. Desalination&Water Treatment, 2012, 42(1-3):197-201.
[8] Wang T, Song Y, Li B, et al. Chelating-ultrafiltration treatment of some heavy metal ions in aqueous solutions by crosslinking carboxymethyl modified cornstarch[J]. Water, Air&Soil Pollution,2012, 223(2):679-686.
[9]雷兆武,孙颖.离子交换技术在重金属废水处理中的应用[J].环境科学与管理,2008,34(10):82-84.
[10] Chen Q, Xu W, Ge Q. Novel multi-charge hydroacid complexes that effectively remove heavy metal ions from water in forward osmosis processes[J]. Environmental Science&Technology, 2018:52(7):4 464-4 471.
[11] Thatai S, Khurana P, Kumar D. Role of advanced materials as nanosensors in water treatment[M]//Biosensors Nanotechnology.John Wiley&Sons, Inc. 2014.
[12] Li X M, Xu G, Liu Y, et al. Magnetic Fe3O4nanoparticles:synthesis and application in water treatment[J]. Nanoscience&Nanotechnology-Asia, 2011, 1(1):14-24.
[13] Mende M, Schwarz D, Steinbach C, et al. The Influence of Salt Anions on Heavy Metal Ion Adsorption on the Example of Nickel[J]. Materials, 2018, 11(3):373-.375.
[14]龚云表，石安富主编.合成树脂与塑料手册[M].上海:上海科学技术出版社. 1993.
[15] Borodkin S, Sundberg D P. Polycarboxylic acid ion-exchange resin adsorbates for taste coverage in chewable tablets[J]. J Pharm Sci,2010, 60(10):1 523-1 527.
[16] Motycka S, Newth C J, Nairn J G. Preparation and evaluation of microencapsulated and coated ion-exchange resin beads containing theophylline.[J]. Journal of Pharmaceutical Sciences,2010, 74(6):643-646.
[17] Vasiliu S, Bunia I, Racovita S, et al. Adsorption of cefotaxime sodium salt on polymer coated ion exchange resin microparticles:Kinetics, equilibrium and thermodynamic studies[J]. Carbohydrate Polymers, 2011, 85(2):376-387.
[18] Fang D U, Xin-Hua Q I, Ying-Zhao X U, et al. Catalytic conversion of fructose to 5-hydroxymethylfurfural by ion-exchange resin in ionic liquid[J]. Chemical Journal of Chinese Universities,2010, 31(3):548-552.
[19]何炳林，黄文强主编.离子交换与吸附树脂[M].上海:上海科技教育出版社. 1995.
[20] Vila M, Cunill F, Izquierdo J F, et al. The role of by-products formation in methyl tert-butyl ether synthesis catalyzed by a macroporous acidic resin[J]. Applied Catalysis A General, 1994,117(2):99-108.
[21] Wu Z, Zhao R, Wang Q, et al. Synthesis of macroporous resin adsorbents and the study on the removal effectiveness of trace oil in steam condensed water[J]. Industrial Water Treatment, 2012, 32(4):59-61.
[22] Chang X, Luo X, Zhan G, et al. Synthesis and characterization of a macroporous poly(vinyl-aminoacetone)chelating resin for the preconcentration and separation of traces of gold, palladium,rhodium and ruthenium.[J]. Talanta, 1992, 39(8):937-941.
[23] Xiao G, Gao S, Xie X, et al. Synthesis of the hydrophobichydrophilic macroporous poly divinylbenzene/poly(sodium acrylate)IPN resin and adsorption performance for berberine[J]. Polymers for Advanced Technologies, 2010, 20(12):1 157-1 162.
[24] Zhang N Z, Chen Y Y. Synthesis of macroporous ellagitannic acid resin and its chelating rroperties for metal ions[J]. Journal of Macromolecular Science:Part A-Chemistry, 2006, 25(10-11):1 455-1 462.
[25] Zhang L P, Du J, Liu J. Preparation and adsorption properties of macroporous tannin resins[J]. Forest Ecosystems, 2006, 8(3):51-55.
[26] Parmar V S, Jain R, Simonsen O, et al. Synthesis and characterization of strong polar macroporous resin made from cellulose[J]. Advanced Materials Research, 2011, 346(18):743-750.
[27] Arcos-Casarrubias J A, Cruz-Díaz M R, Cardoso-Martínez J, et al.Chromium adsorption into a macroporous resin based on vinylpyridine-divinylbenzene copolymers:thermodynamics,kinetics, and process dynamic in a fixed bed column[J].Adsorption, 2018, 24(1):105-120.
[28]张全兴,李爱民,潘丙才.离子交换与吸附树脂的发展及在工业废水处理与资源化中的应用[J].高分子通报, 2015, 28(9):21-43.
[29]易然,徐静,宋玉栋,等.螯合树脂去除丙烯酸丁酯废水中的二价阳离子[J].化工环保, 2013, 33(4):289-293.
[30]陈达,刘福强,徐超,等.氨基乙酸类螯合树脂对高盐重金属离子废水的高效无害化处理技术研究[J].离子交换与吸附,2015,31(1):1-10.
[31]李福勤,聂文欢,唐玮媛,等. D402树脂对Pb(Ⅱ)、Cd(Ⅱ)的吸附性能及再生试验研究[J].工业安全与环保,2015,41(7):40-42.
[32]陈佑宁,赵维,杨小玲,等.新型偕胺肟基螯合树脂对Ni(Ⅱ)和Cu(Ⅱ)吸附性能研究[J].工业用水与废水, 2018, 49(3):17-21.
[33]薛爱莲,申书昌.聚苯乙烯硫代氨基脲螯合树脂的制备及其对重金属离子的吸附性能研究[J].化工时刊, 2014, 28(12):1-4.
[34]姚树人,晏欣,余红伟,等.多乙烯多胺胺化GMA-TAIC共聚物大孔树脂的合成及对重金属离子的吸附[J].高分子材料科学与工程, 2014, 30(4):11-15.
[35]陈佑宁,高莉,贺茂芳,等.聚乙烯四唑型螯合树脂及其对重金属离子的吸附性能[J].高等学校化学学报, 2014, 35(7):1 596-1 602.
[36]徐超,韩飞,于世涛.系列多胺类螯合树脂的合成及其对重金属离子选择性吸附研究[J].离子交换与吸附, 2017, 33(3):245-259.
[37]曹焕义,王海峰.亚氨基二乙酸鳌合树脂处理氨基酸生产含铜废水[J].水处理技术, 2018, 44(3):121-124,128.
[38]郭润强,柴思琦,毛静涛.一种改性螯合树脂的合成及其对水体Hg~(2+)的吸脱附性能研究[J].环境科技, 2018, 31(4):14-19.
[39]宗黎丹.新型吡啶类螯合树脂在强酸高盐重金属废水处理中的应用研究[A].中国化学会高分子学科委员会.中国化学会第18届反应性高分子学术研讨会论文集[C].中国化学会高分子学科委员会:中国化学会, 2016. 4.
[40]陆继来,曹蕾,周海云,等.离子交换法处理含镍电镀废水工艺研究[J].工业安全与环保, 2013, 39(12):13-15.
[41] Tuzen M, Uluozlu O D, Usta C, et al. Biosorption of copper(II), lead(II), iron(III)and cobalt(II)on Bacillus sphaericus-loaded Diaion SP-850 resin[J]. Analytica Chimica Acta, 2007, 581(2):241-246.
[42]王瑞杰,杨连威.聚丙烯酸-高岭土高吸水性树脂的制备及对重金属离子的吸附性研究[J].化工新型材料, 2011, 39(5):124-126.
[43]李继萍,莫国莉.高吸水性树脂吸附重金属离子的研究[J].广州化工, 2015, 43(24):92-94.
[44]张晓蕾,付渊,吴海霞.羧甲基高吸水树脂合成及对重金属离子的吸附[J].广州化工, 2016, 44(11):90-92.
[45]吴海霞,李纯毅,付渊,等.以羧甲基马铃薯渣为原料的高吸水树脂对Pb~(2+)吸附特性研究[J].胶体与聚合物, 2018, 36(4):163-165.
[46] Soylak M, Tuzen M. Diaion SP-850 resin as a new solid phase extractor for preconcentration-separation of trace metal ions in environmental samples[J]. Journal of Hazardous Materials, 2006,137(3):1 496-1 501.
[47] Soylak M, Topalak Z. Enrichment-separation and determinations of cadmium(II)and lead(II)-1-phenyl-1H-tetrazole-5-thiol chelates on Diaion SP-207 by solid phase extraction-flame atomic absorption spectrometry[J]. Arabian Journal of Chemistry, 2012, 35(5):720-725.
[48] Unsal Y E, Tuzen M, Soylak M. Flame Atomic absorption spectrometric determination of gold after solid phase extraction of its 2-aminobenzothiazole complex on diaion SP-207[J]. Journal of AOAC International, 2019, 99(2):534-538.
[49] Li H, Chen Y, Long J, et al. Simultaneous removal of thallium and chloride from a highly saline industrial wastewater using modified anion exchange resins[J]. Journal of Hazardous Materials, 2017,333:179-185.