湖南千里山岩体中金红石化学成分标型特征研究
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摘要
金红石是湖南千里山岩体黑云母花岗岩中一种常见的副矿物。本文通过分析千里山黑云母花岗岩中金红石的化学成分,探讨了金红石对岩浆热液演化与钨锡成矿的指示作用。结果表明,金红石主要受热液蚀变作用的影响呈3种形态产出。第1种为形成于黑云母裂隙的他形金红石;第2种是颗粒较大的单晶金红石;第3种是呈集合体产出且粒度不等的条带状金红石。随着黑云母花岗岩的蚀变与成矿作用的不断增强,黑云母花岗岩金红石中的元素钨不断富集,表明金红石中的钨含量可以作为花岗岩成矿能力的判别标志,含钨高的金红石对钨矿的形成富集有一定的指示意义,可作为钨矿找矿的标志之一。
Rutile is a common accessory mineral in the Qianlishan biotite granite. In this paper,the authors investigated chemical significance of rutiles in tracing the magmatic-hydrothermal evolution and W-Sn metalogic process based on their typomorphic features. The results show that three forms of rutiles caused by the influence of the hydrothermal fluid can be identified. The first type of rutile occurs in the biotite fissure,being anhedral rutile,the second type is composed of euhedral crystals with relatively large grain size. The third type of rutile occurs as aggregates with banded and anisomerous structures. The continual increase of tungsten content of rutile with the enhancement of alteration and mineralization suggests that the tungsten content in the rutile can be used as a criterion for the ore-forming capability of granite,and the high tungsten-bearing rutile can indicate the formation and enrichment of the tungsten. In the future,these phenomena can be used as prospecting marks in search for tungsten deposits.
Rutile is a common accessory mineral in the Qianlishan biotite granite. In this paper,the authors investigated chemical significance of rutiles in tracing the magmatic-hydrothermal evolution and W-Sn metalogic process based on their typomorphic features. The results show that three forms of rutiles caused by the influence of the hydrothermal fluid can be identified. The first type of rutile occurs in the biotite fissure,being anhedral rutile,the second type is composed of euhedral crystals with relatively large grain size. The third type of rutile occurs as aggregates with banded and anisomerous structures. The continual increase of tungsten content of rutile with the enhancement of alteration and mineralization suggests that the tungsten content in the rutile can be used as a criterion for the ore-forming capability of granite,and the high tungsten-bearing rutile can indicate the formation and enrichment of the tungsten. In the future,these phenomena can be used as prospecting marks in search for tungsten deposits.
引文
Bai Daoyuan,Huang Jianzhong,Li Jindong,et al.2007.Multiple geological elements constraint on the Mesozoic tectonic evolution of south China:Apocalypse of the Mesozoic geological evolution in Southeastern Hunan and the Hunan border area[J].Geotectonica et Metallogenia,31(1):1~13(in Chinese with English abstract).
Bai Daoyuan,Huang Jianzhong,Liu Yaorong,et al.2005.Framework of Mesozoic tectonic evolution in southeastern Hunan and the HunanGuangdong-Jiangxi border area[J].Geology in China,32(4):557~570(in Chinese with English abstract).
Bai Daoyuan,Huang Jianzhong,Ma Tieqiu,et al.2006.Geologly and Geochemistry of the Penggongmiao granitic pluton in the Southeastern Hunan Province and its implication for tectonic setting[J].Geoscience,20(1):130~140(in Chinese with English abstract).
Bian L,Song M X and Zhou T L.2009.Band gap calculation and photo catalytic activity of rare earths doped rutile Ti O2[J].Journal of Rare Earths,27(3):461~468.
Cai Jianhui,Wang Liben and Li Jinping.2008.Mineralogical characteristics of rutile with different occurrence and genetic types and its significance[J].Mineral Deposits,27(4):531~538(in Chinese with English abstract).
Chen Hui,Lu Anhuai,Li Bin,et al.2018.Study on the typomorphic characteristics of rutile from Shangzhuang and Xiadian gold deposits,Jiaodong[J].Acta Petrologica et Mineralogica,37(5):839~852(in Chinese with English abstract).
Chen Jun,Lu Jianjun,Chen Weifeng,et al.2008.Tungsten-tinniobium-tantalum granite and its mineralization in Nanling area[J].Journal of University Geology,14(4):459~473(in Chinese with English abstract).
Chen Y X,Li H,Sun W D,et al.2016.Generation of Late Mesozoic Qianlishan A2-type granite in Nanling Range,South China:Implications for Shizhuyuan W-Sn mineralization and tectonic evolution[J].Lithos,266:435~452.
Cheng Yongsheng,Tan Ruofa and Wang Yong.2013.Petrological and geochemical characteristics of Qianlishan granite in southern Hunan[J].Journal of Minerals,33(S2):579~580(in Chinese with English abstract).
Cruz-Uribe A M,Feineman M D,Zack T,et al.2014.Metamorphic reaction rates at ca 650~800℃from diffusion of niobium in rutile[J].Geochimica et Cosmochimica Acta,130:63~77.
Dickenson M P and Hess P C.1986.The structural role and homogeneous redox equilibria of iron in peraluminous,metaluminous and peralkaline silicate melts[J].Mineralogy and Petrology,92(2):207~217.
Gao J,John T and Klemd R.2007.Mobilization of Ti-Nb-Ta during subduction:Evidence from rutile-bearing dehydration segregations and veins hosted in eclogite,Tianshan,NW China[J].Geochimica et Cosmochimica Acta,71(20):4 974~4 996.
Hua Renmin.2005.Time difference between diagenesis and mineralization of Mesozoic continental crust remelting granitoids in Nanling and its geological significance[J].Geological Review,51(6):633~639(in Chinese with English abstract).
Kalfoun F,Ionov D and Merlet C.2002.HFSE residence and Nb/Ta ratios in metasomatised,rutile-bearing mantle peridotites.Earth and Planetary Science Letters,199(1~2):49~65.
Li H P,Zhang W and Pan W.2011.Enhanced photocatalytic activity of electrospun Ti O2nanofibers with optimal anatase/rutile ratio[J].the National Natural Science Foundation,94(10):3 184~3 187.
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Mao Jingwen,Li Hongyan and Pei Rongfu.1995.Nd-Sr isotopes and petrogenesis of the Qianlishan granite body,Hunan[J].Mineral Deposits,14(3):235~242(in Chinese with English abstract).
Mao Jingwen,Xie Guiqing,Guo Chunli,et al.2007.Large-scale tungsten-tin polymetallic mineralization in Nanling area:Metallogenic time frame and geodynamic background[J].Acta Petrologica Sinica,23(10):2 329~2 338(in Chinese with English abstract).
Meinhold G.2011.Rutile and its applications in earth sciences[J].Earth-Science Reviews,102(1):1~28.
Peng B,Sun F Y,Li B L,et al.2016.The geochemistry and geochronology of the Xiarihamu II mafic-ultramafic complex,Eastern Kunlun,Qinghai Province,China:Implications for the genesis of magmatic NiCu sulfide deposits[J].Ore Geology Reviews,73:13~28.
Rabbia O M,Laura B H,David H F,et al.2009.The El Teniente porphyry Cu-Mo deposit from a hydrothermal rutile perspective[J].Miner Deposita,1~18.
Rapp J F,Klemme S,Butler I B,et al.2010.Extremely high solubility of rutile in chloride and fluoride-bearing metamorphic fluids:An experimental investigation[J].Geology,38(4):323~326.
Schmidt A,Weyer S and John T.2009.HFSE systematics of rutile-bearing eclogites:New insights into subduction zone processes and implications for the earth’s HFSE budget[J].Geochimica et Cosmochimica Acta,73(2):455~468.
Scott K M.2005.Rutile geochemistry as a guide to porphyry Cu-Au mineralization,Northparkes,New South Wales,Australia[J].Geochemistry:Exploration,Environmen,Analysis,5(3):247~253.
Shannon R D.1976.Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides[J].Acta Crystallographica Section A,(A32):751~767.
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Spandler C,Hermann J and Arculus R.2003.Redistribution of trace elements during prograde metamorphism from lawsonite blueschist to eclogite facies;implications for deep subduction-zone processes[J].Mineralogy and Petrology,146(2):205~222.
Tong Lihua.2013.Discussion on the Genesis and metallogenic Model of Tungsten-tin Metallic Granitoids in Qianli Mountain,Chenzhou,Hunan Province[D].China University of Geosciences(Beijing)(in Chinese with English abstract).
Triebold S,Eynatten H V and Zack T.2012.A recipe for the use of rutile in sedimentary provenance analysis[J].Sedimentary Geology,282:268~275.
Wan Guilong.2013.Constraints on Mineralization of Qianlishan Granite,Hunan[D].China University of Geosciences(Beijing)(in Chinese with English abstract).
Wang Rucheng,Zhu Jinchu,Zhang Wenlan,et al.2008.Mineralogy of tungsten-tin granites in Nanling area:Concepts and examples[J].Geological Journal of China Universities,14(4):485~495(in Chinese with English abstract).
Xiao Yilin,Huang Jian,Liu Lei,et al.2011.Rutile:An important geochemical“information base”[J].Acta Petrologica Sinica,27(2):398~416(in Chinese with English abstract).
Xu Shaokang,Zhou Xixian and Xi Guoqing.2005.Some problems of high-ultrahigh pressure metamorphism and mineralization of rutile[J].Geology of Chemical Minerals,(1):6~14,20(in Chinese).
Zack T,Berezin A V,Melnik A E,et al.2013.In situ LA-ICP-MS investigation of the geochemistry and U-Pb age of rutile from the rocks of the Belomorian mobile belt[J].Geochemistry International,51(2):164~171.
Zack T,Kronz A and Foley S F.2002.Trace element abundances in rutiles from eclogites and associated garnet mica schists[J].Chemical Geology,184(1~2):97~122.
Zhang Rongqing,Lu Jianjun,Wang Rucheng,et al.2011.Determination of Yanshanian biotite granite in Hehuaping tin-lead-zinc ore area,southern Hunan[J].Geological Journal of China Universities,17(4):513~520(in Chinese with English abstract).
Zhang X H,Yuan L L,Xue F H,et al.2015.Early Permian A-type granites from central Inner Mongolia,North China:Magmatic tracer of post-collisional tectonics and oceanic crustal recycling[J].Gondwana Research,28(1):311~327.
Zhao Zhenhua and Yan Shuang.2019.Minerals-mineralization and prospecting[J].Acta Petrologica Sinica,35(1):31~68(in Chinese with English abstract).
Zhou Hongying,Li Huaikun,Cui Yurong,et al.2013.U-Pb isotopic dating of rutile[J].Acta Geologica Sinica,87(9):1 439~1 446(in Chinese with English abstract).
Zhou Xinmin.2003.Some thoughts on the study of granite in South China[J].Geological Journal of China Universities,9(4):556~565(in Chinese with English abstract).
柏道远,黄建中,李金冬,等.2007.华南中生代构造演化过程的多地质要素约束---湘东南及湘粤赣边区中生代地质研究的启示[J].大地构造与成矿学,31(1):1~13.
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Bai Daoyuan,Huang Jianzhong,Ma Tieqiu,et al.2006.Geologly and Geochemistry of the Penggongmiao granitic pluton in the Southeastern Hunan Province and its implication for tectonic setting[J].Geoscience,20(1):130~140(in Chinese with English abstract).
Bian L,Song M X and Zhou T L.2009.Band gap calculation and photo catalytic activity of rare earths doped rutile Ti O2[J].Journal of Rare Earths,27(3):461~468.
Cai Jianhui,Wang Liben and Li Jinping.2008.Mineralogical characteristics of rutile with different occurrence and genetic types and its significance[J].Mineral Deposits,27(4):531~538(in Chinese with English abstract).
Chen Hui,Lu Anhuai,Li Bin,et al.2018.Study on the typomorphic characteristics of rutile from Shangzhuang and Xiadian gold deposits,Jiaodong[J].Acta Petrologica et Mineralogica,37(5):839~852(in Chinese with English abstract).
Chen Jun,Lu Jianjun,Chen Weifeng,et al.2008.Tungsten-tinniobium-tantalum granite and its mineralization in Nanling area[J].Journal of University Geology,14(4):459~473(in Chinese with English abstract).
Chen Y X,Li H,Sun W D,et al.2016.Generation of Late Mesozoic Qianlishan A2-type granite in Nanling Range,South China:Implications for Shizhuyuan W-Sn mineralization and tectonic evolution[J].Lithos,266:435~452.
Cheng Yongsheng,Tan Ruofa and Wang Yong.2013.Petrological and geochemical characteristics of Qianlishan granite in southern Hunan[J].Journal of Minerals,33(S2):579~580(in Chinese with English abstract).
Cruz-Uribe A M,Feineman M D,Zack T,et al.2014.Metamorphic reaction rates at ca 650~800℃from diffusion of niobium in rutile[J].Geochimica et Cosmochimica Acta,130:63~77.
Dickenson M P and Hess P C.1986.The structural role and homogeneous redox equilibria of iron in peraluminous,metaluminous and peralkaline silicate melts[J].Mineralogy and Petrology,92(2):207~217.
Gao J,John T and Klemd R.2007.Mobilization of Ti-Nb-Ta during subduction:Evidence from rutile-bearing dehydration segregations and veins hosted in eclogite,Tianshan,NW China[J].Geochimica et Cosmochimica Acta,71(20):4 974~4 996.
Hua Renmin.2005.Time difference between diagenesis and mineralization of Mesozoic continental crust remelting granitoids in Nanling and its geological significance[J].Geological Review,51(6):633~639(in Chinese with English abstract).
Kalfoun F,Ionov D and Merlet C.2002.HFSE residence and Nb/Ta ratios in metasomatised,rutile-bearing mantle peridotites.Earth and Planetary Science Letters,199(1~2):49~65.
Li H P,Zhang W and Pan W.2011.Enhanced photocatalytic activity of electrospun Ti O2nanofibers with optimal anatase/rutile ratio[J].the National Natural Science Foundation,94(10):3 184~3 187.
Liu Yimao,Wang Changlie,Xu Youzhi,et al.1998.Metallogenic conditions and metallogenic model of Shizhuyuan super-large tungsten polymetallic deposit[J].China Science(Series D:Earth Science),(S2):49~56(in Chinese).
Mao Jingwen,Li Hongyan and Pei Rongfu.1995.Nd-Sr isotopes and petrogenesis of the Qianlishan granite body,Hunan[J].Mineral Deposits,14(3):235~242(in Chinese with English abstract).
Mao Jingwen,Xie Guiqing,Guo Chunli,et al.2007.Large-scale tungsten-tin polymetallic mineralization in Nanling area:Metallogenic time frame and geodynamic background[J].Acta Petrologica Sinica,23(10):2 329~2 338(in Chinese with English abstract).
Meinhold G.2011.Rutile and its applications in earth sciences[J].Earth-Science Reviews,102(1):1~28.
Peng B,Sun F Y,Li B L,et al.2016.The geochemistry and geochronology of the Xiarihamu II mafic-ultramafic complex,Eastern Kunlun,Qinghai Province,China:Implications for the genesis of magmatic NiCu sulfide deposits[J].Ore Geology Reviews,73:13~28.
Rabbia O M,Laura B H,David H F,et al.2009.The El Teniente porphyry Cu-Mo deposit from a hydrothermal rutile perspective[J].Miner Deposita,1~18.
Rapp J F,Klemme S,Butler I B,et al.2010.Extremely high solubility of rutile in chloride and fluoride-bearing metamorphic fluids:An experimental investigation[J].Geology,38(4):323~326.
Schmidt A,Weyer S and John T.2009.HFSE systematics of rutile-bearing eclogites:New insights into subduction zone processes and implications for the earth’s HFSE budget[J].Geochimica et Cosmochimica Acta,73(2):455~468.
Scott K M.2005.Rutile geochemistry as a guide to porphyry Cu-Au mineralization,Northparkes,New South Wales,Australia[J].Geochemistry:Exploration,Environmen,Analysis,5(3):247~253.
Shannon R D.1976.Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides[J].Acta Crystallographica Section A,(A32):751~767.
Shen Weizhou,Wang Dezi,Xie Yonglin,et al.1995.Geochemical characteristics and material sources of the Qianlishan complex granite body,Hunan[J].Acta Petrologica et Mineralogica,14(3):193~202(in Chinese with English abstract).
Shu Liangshu.2006.Pre-Devonian tectonic evolution in South China:from the Cathaysian massif to the Caledonian orogenic belt[J].Geological Journal of China Universities,12(4):418~431(in Chinese with English abstract).
Spandler C,Hermann J and Arculus R.2003.Redistribution of trace elements during prograde metamorphism from lawsonite blueschist to eclogite facies;implications for deep subduction-zone processes[J].Mineralogy and Petrology,146(2):205~222.
Tong Lihua.2013.Discussion on the Genesis and metallogenic Model of Tungsten-tin Metallic Granitoids in Qianli Mountain,Chenzhou,Hunan Province[D].China University of Geosciences(Beijing)(in Chinese with English abstract).
Triebold S,Eynatten H V and Zack T.2012.A recipe for the use of rutile in sedimentary provenance analysis[J].Sedimentary Geology,282:268~275.
Wan Guilong.2013.Constraints on Mineralization of Qianlishan Granite,Hunan[D].China University of Geosciences(Beijing)(in Chinese with English abstract).
Wang Rucheng,Zhu Jinchu,Zhang Wenlan,et al.2008.Mineralogy of tungsten-tin granites in Nanling area:Concepts and examples[J].Geological Journal of China Universities,14(4):485~495(in Chinese with English abstract).
Xiao Yilin,Huang Jian,Liu Lei,et al.2011.Rutile:An important geochemical“information base”[J].Acta Petrologica Sinica,27(2):398~416(in Chinese with English abstract).
Xu Shaokang,Zhou Xixian and Xi Guoqing.2005.Some problems of high-ultrahigh pressure metamorphism and mineralization of rutile[J].Geology of Chemical Minerals,(1):6~14,20(in Chinese).
Zack T,Berezin A V,Melnik A E,et al.2013.In situ LA-ICP-MS investigation of the geochemistry and U-Pb age of rutile from the rocks of the Belomorian mobile belt[J].Geochemistry International,51(2):164~171.
Zack T,Kronz A and Foley S F.2002.Trace element abundances in rutiles from eclogites and associated garnet mica schists[J].Chemical Geology,184(1~2):97~122.
Zhang Rongqing,Lu Jianjun,Wang Rucheng,et al.2011.Determination of Yanshanian biotite granite in Hehuaping tin-lead-zinc ore area,southern Hunan[J].Geological Journal of China Universities,17(4):513~520(in Chinese with English abstract).
Zhang X H,Yuan L L,Xue F H,et al.2015.Early Permian A-type granites from central Inner Mongolia,North China:Magmatic tracer of post-collisional tectonics and oceanic crustal recycling[J].Gondwana Research,28(1):311~327.
Zhao Zhenhua and Yan Shuang.2019.Minerals-mineralization and prospecting[J].Acta Petrologica Sinica,35(1):31~68(in Chinese with English abstract).
Zhou Hongying,Li Huaikun,Cui Yurong,et al.2013.U-Pb isotopic dating of rutile[J].Acta Geologica Sinica,87(9):1 439~1 446(in Chinese with English abstract).
Zhou Xinmin.2003.Some thoughts on the study of granite in South China[J].Geological Journal of China Universities,9(4):556~565(in Chinese with English abstract).
柏道远,黄建中,李金冬,等.2007.华南中生代构造演化过程的多地质要素约束---湘东南及湘粤赣边区中生代地质研究的启示[J].大地构造与成矿学,31(1):1~13.
柏道远,黄建中,刘耀荣,等.2005.湘东南及湘粤赣边区中生代地质构造发展框架的厘定[J].中国地质,32(4):557~570.
柏道远,黄建中,马铁球,等.2006.湘东南志留纪彭公庙花岗岩体的地质地球化学特征及其构造环境[J].现代地质,20(1):130~140.
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