聚电解质溶液性质、层层自组装膜的构筑及渗透汽化性能研究
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摘要
通过层层自组装(layer-by-layer self-assembly,LbL SA)技术,将带相反电荷的两种聚电解质组装在基片上,形成厚度和组成比较均一的聚电解质多层复合膜(Polyelectrolyte multilayer membrane,PEM)是近年来许多领域研究的热点之一。本文从聚电解质种类及其溶液性质出发,重点研究聚电解质自组装过程中各种内外因素对溶液性质和自组装膜的表面性质、吸附量及其异丙醇脱水的分离性能影响,进而完善和深化层层自组装的机理。
选用两种水溶性的强电解质聚(二甲基二烯丙基氯化铵)(PDDA)和聚苯乙烯磺酸钠(PSS)为研究对象,通过改变电解质溶液中离子强度、pH、溶剂性质及组装温度,用乌氏粘度计测定聚电解质在各组装溶液中的特性粘数及用紫外-可见光谱仪(UV)和石英微晶天平(QCM)测定由各种组装溶液所得PDDA/PSS多层膜聚电解质吸附量。实验结果发现,聚电解质在各种组装液中的特性粘数(链尺寸)和组装膜的吸附量基本上呈现反比关系。原子力显微镜(AFM)结果显示,当溶液中的聚电解质链尺寸减小时所得组装膜的表面更为粗糙,也呈现聚电解质在溶液中的特性粘数与其组装膜的表面粗糙度呈负相关的现象。
选用水溶性的强电解质PDDA和非水溶性的不同磺化度和分子量的磺化聚砜(SPSF)为研究对象,以N,N-二甲基甲酰胺(DMF)及N,N-二甲基甲酰胺-水(DMF-H_2O)混合溶剂为SPSF的溶剂,分别用乌氏粘度计和电导率仪测定了SPSF在不同组成的DMF-H_2O混合溶剂中的特性粘数及不同磺化度SPSF在各DMF-H_2O混合溶剂中的电导率。实验结果显示,由水溶性的强电解质PDDA与非水溶性不同磺化度SPSF所得组装膜的厚度强烈依赖于SPSF的电荷密度(磺化度)及组装混合溶剂中DMF的体积分数(φ_(DMF))。当_(DMF)为0.8和0.9时,两种PDDA/SPSF多层膜,PDDA/SPSF65和PDDA/SPSF85,厚度都呈极大值,而当φ_(DMF)约为0.6～0.7时,两种PDDA/SPSF多层膜的厚度都呈极小值;在相同组装层数下,电荷密度较小的PDDA/SPSF65膜的厚度比电荷密度较大的PDDA/SPSF85多层膜的厚度更大;多层膜的厚度随组装层数增加呈线性增长;另外,PDDA/SPSF多层膜的接触角及表面粗糙度也随厚度的增加而上升。实验结果证明PDDA/SPSF多层膜的性质受到SPSF在不同φ_(DMF)中的线团尺寸及电离度影响。同时DMF-H_2O混合溶剂的性质强烈地影响SPSF溶液的性质,从而进一步影响了在不同φ_(DMF)下PDDA/SPSF多层膜的性质。
以带负电的聚酰胺反渗透膜为底膜,在不同NaCl离子强度下制备了PDDA/PSS聚电解质多层膜。扫描电镜(SEM)测试结果表明,随组装溶液中NaCl浓度增大单层膜厚度增加,膜表面变得平坦光滑。渗透汽化结果表明,增加盐的浓度能大大提高组装膜的分离选择性。在35℃的操作温度下(PDDA/PSS)_6PDDA多层膜用于分离含水5 wt%的异丙醇-水混合溶液,组装液中NaCl浓度为0.1 M和1 M时,膜的通量分别为2.57 kg.m~(-2).h~(-1)和1.67 kg.m~(-2).h~(-1),而分离因子则从46上升到246。随着组装层数的增加,组装膜的表面变得光滑,分离因子升高而通量下降。在盐浓度较高情况下提高外加盐浓度比增加组装层数对提高膜的分离因子更有效。操作温度和料液组成对PDDA/PSS聚电解质多层膜的分离性能有很大影响。随着组装溶液中水含量的增多,PDDA/PSS聚电解质多层膜的通量迅速上升,透过液的水含量略有下降。PDDA/PSS聚电解质多层膜分离含水5 wt%的异丙醇-水混合液时,发现组装膜的通量和分离因子随着操作温度的上升同步上升,呈反“trade-off”现象。在分离水含量较高混合液(水含量20～30 wt%)时由于聚电解质膜溶胀性增加,反“trade-off”现象消失。
在电场下制备了三种聚电解质层层自组装膜,PDDA/PSS,PDDA/PAA和PEI/PAA电场促进自组装膜(EPEM)。考察了组装条件对各种自组装膜的表面形貌及其渗透汽化性能的影响。实验结果证明,沿着电场力方向组装的PEI单层膜表面粗糙度增大,渗透汽化分离性能有明显提高,这表明电场加快组装速度和增大聚电解质吸附量,从而提高了膜的选择性。由PEI单层膜组装的表面粗糙度及渗透汽化实验确立了最佳组装时间为15 min,最佳组装电压为5 V。PDDA/PSS,PDDA/PAA和PEI/PAA三种膜优先透水的选择性依次递增;电场促进自组装多层膜(EPEM)的表面粗糙度比相同组装条件下普通自组装多层膜(PEM)粗糙度低,用于分离异丙醇-水混合溶液时有很高的分离性能。渗透汽化分离实验显示,几个双层的PEI/PAA EPEM用于分离异丙醇-水混合溶液时,在较大操作温度(40～70℃)及料液浓度范围内(水含量5～30 wt%)都具选择性高,渗透通量大、重复性好以及高稳定性的特点。例如(PEI/PAA)_4PEI EPEM,在渗透汽化操作温度为70℃用于分离含水10 wt%的异丙醇-水体系时,其通量高达4.05 kg.m~(-2)·h~(-1),分离因子为1075;在70℃分离分离含水30 wt%的异丙醇-水体系时,其通量高达7.65 kg.m~(-2).h~(-1),透过液水含量仍保持94.38 wt%。
In the past decade,the layer-by-layer(LbL)self-assembly of polyelectrolytes(PE) has been considered to be the simplest and most convenient way for fabricating thin multilayer membranes with a well-defined thickness and chemical composition. However,due to its short developing history,many things are still uncertain for this novel technology which limits its application in many aspects.In order to further discover the rule of PEM during the LbL process,a series of protocols were established to investigate the properties of PEMs.Solution properties of PEs and properties of multilayer membranes were investigated to discover the relation between the surface properties,membrane thickness and separation performance.
Self-assembly layer-by-layer multilayer membranes of two typical PEs,poly (dimethyl diallylammonium chloride)(PDDA)and poly(styrenesulfonate sodium salt) (PSS)were fabricated from dipping solutions with different added salt concentrations, pH,solvent compositions and temperature respectively.The absorption amount of PDDA/PSS self-assembled multilayer membranes in designed dipping solvents was measured by UV-vis-spectroscopy(UV)and quartz crystal microbalance(QCM). Intrinsic viscosities of PDDA and PSS in corresponding dipping solvents were determined by an Ubbloheode viscometer.The adsorption amount of PDDA/PSS multilayer membranes increases with decreasing the intrinsic viscosity of PDDA or PSS in different corresponding dipping solvents.That is,a negative relation between the adsorption amount of PDDA/PSS multilayer membranes and the chain dimension of PDDA and PSS in the dipping solvents exhibits for all assembly systems of PDDA and PSS except for that of PSS in the media with pH_(PSS)＞10.The negative relation is trusty in spite of the designed dipping solvent for only PDDA or PSS and for both of them.The high adsorption amount of PDDA/PSS multilayer membranes could be attributed to low excluded volume of the compact chain with low intrinsic viscosity of the polyelectrolyte in the dipping solvent.The AFM images show that polyelectrolyte with compact chains in solutions would form thick membranes with rough surfaces.
Two sulfonated poly(sulphone)sodium salts(SPSFs)with different molecular weights and ionic exchange capacities in a N,N-dimethyl formamide/water(DMF-H_2O) mixed solvent with various DMF contents(φ_(DMF))were selected as a model system for investigating the influences of solvent composition,solution properties,and charge density of polyelectrolytes on the layer-by-layer(LbL)self-assembly of water-insoluble polyelectrolytes.PDDA in aqueous solution was used as the counterpart.Intrinsic viscosity and conductivity of SPSF(ηSPSF and L_(SPSF))in solutions with differentφ_(DMF)were investigated.The PDDA/SPSF multilayer membranes grew nearly linearly with the layer numbers regardless of theφ_(DMF)in the SPSF solutions. The total absorption amount of the PDDA/SPSF multilayer membranes was strongly dependent on the charge density of the SPSF molecules and theφ_(DMF)value of the SPSF solutions.Minimum values and maximum values of absorption amount were observed atφ_(DMF)0.6～0.7 andφ_(DMF)0.8～0.9 respectively.On the other hand,the SPSF with a lower ionic exchange capacity led to thicker multilayer membranes for any givenφ_(DMF)value in the SPSF solutions.The average thickness of each bilayer was about 3.5～7.5 nm for PDDA/SPSF85 or 5.6～13.3 nm for PDDA/SPSF65,depending on the solvent composition.Surface roughness and contact angle of PDDA/SPSF increase with increasing membrane thickness.The results indicate that the molecular structures of the DMF-H_2O mixed solvent strongly affect the solution properties of SPSF,which in turn determine the growth behavior and physical properties of the PDDA/SPSF multilayer membranes.
PDDA and PSS in solutions with different NaCl concentrations were self-assembled onto a polyamide reverse osmosis membrane and used for dehydration water from isopropanol.The influences of NaCl concentration of the dipping solutions, number of the bilayers and feed temperature on the pervaporation performance of PDDA/PSS multilayer membranes were investigated.Scanning electron microscope (SEM)experiment showed that the membrane surface becomes smoother with increasing NaCl concentration in dipping solutions.The results of the pervaporation tests showed that the PDDA/PSS membranes assembled in high NaCl concentration have good pervaporation performance.The separation factor is 345 and permeate flux is 2.51 kg.m~(-2).h~(-1)for(PDDA/PSS)_6PDDA multilayer membrane assembled in 1 M NaCl used for pervaporation of 95 wt%isopropanol isopropanol-water mixtures at 35℃.With increasing operation temperature,both the flux and separation factor increase.However,the separation factor decreases with increasing operation temperature when increases the water percent in feed.An anti-"trade-off" phenomenon is found in low water percent in feed and explained in term of both solvent interaction and structure of LbL membrane.
An electric field enhanced method is developed for fabricating layer-by-layer (LbL)self-assembly polyelectrolyte multilayer membranes.Three kinds of electric field enhanced polyelectrolyte multilayer membranes(EPEMs),poly(diallyl dimethylammonium chloride)/poly(styrenesulfonate sodium salt)(PDDA/PSS),poly (diallyldimethylammonium chloride)/poly(acrylic acid sodium salt)(PDDA/PAA) and polyethylenimine/poly(acrylic acid sodium salt)(PEI/PAA),were self-assembled on a polyamide reverse osmosis membrane.The pervaporation performances of EPEMs for separating isopropranol-water mixtures(90/10,w/w)are all superior to those of corresponding normal self-assembled polyelectrolytes membranes(PEMs), and the selectivity increases with PDDA/PSS,PDDA/PAA and PEI/PAA in order. The surface properties and pervaporation performance of PEI/PAA EPEM fabricated in different conditions were investigated.The results show that the electric field can improve the self-assembly process.The best dipping time of each layer is 15 min and the best applied voltage is 5 V.The PEI/PAA EPEM shows high performance and good selectivity in a large-scale temperature(40～70℃)and water feed concentration (water in feed:5～30 wt%).For(PEI/PAA)_4PEI EPEM,the separation factor is 1075 and permeation flux is 4.05 kg.m~(-2)·h~(-1)for separating isopropranol-water mixtures(90/10,w/w)at 70℃.
选用两种水溶性的强电解质聚(二甲基二烯丙基氯化铵)(PDDA)和聚苯乙烯磺酸钠(PSS)为研究对象,通过改变电解质溶液中离子强度、pH、溶剂性质及组装温度,用乌氏粘度计测定聚电解质在各组装溶液中的特性粘数及用紫外-可见光谱仪(UV)和石英微晶天平(QCM)测定由各种组装溶液所得PDDA/PSS多层膜聚电解质吸附量。实验结果发现,聚电解质在各种组装液中的特性粘数(链尺寸)和组装膜的吸附量基本上呈现反比关系。原子力显微镜(AFM)结果显示,当溶液中的聚电解质链尺寸减小时所得组装膜的表面更为粗糙,也呈现聚电解质在溶液中的特性粘数与其组装膜的表面粗糙度呈负相关的现象。
选用水溶性的强电解质PDDA和非水溶性的不同磺化度和分子量的磺化聚砜(SPSF)为研究对象,以N,N-二甲基甲酰胺(DMF)及N,N-二甲基甲酰胺-水(DMF-H_2O)混合溶剂为SPSF的溶剂,分别用乌氏粘度计和电导率仪测定了SPSF在不同组成的DMF-H_2O混合溶剂中的特性粘数及不同磺化度SPSF在各DMF-H_2O混合溶剂中的电导率。实验结果显示,由水溶性的强电解质PDDA与非水溶性不同磺化度SPSF所得组装膜的厚度强烈依赖于SPSF的电荷密度(磺化度)及组装混合溶剂中DMF的体积分数(φ_(DMF))。当_(DMF)为0.8和0.9时,两种PDDA/SPSF多层膜,PDDA/SPSF65和PDDA/SPSF85,厚度都呈极大值,而当φ_(DMF)约为0.6～0.7时,两种PDDA/SPSF多层膜的厚度都呈极小值;在相同组装层数下,电荷密度较小的PDDA/SPSF65膜的厚度比电荷密度较大的PDDA/SPSF85多层膜的厚度更大;多层膜的厚度随组装层数增加呈线性增长;另外,PDDA/SPSF多层膜的接触角及表面粗糙度也随厚度的增加而上升。实验结果证明PDDA/SPSF多层膜的性质受到SPSF在不同φ_(DMF)中的线团尺寸及电离度影响。同时DMF-H_2O混合溶剂的性质强烈地影响SPSF溶液的性质,从而进一步影响了在不同φ_(DMF)下PDDA/SPSF多层膜的性质。
以带负电的聚酰胺反渗透膜为底膜,在不同NaCl离子强度下制备了PDDA/PSS聚电解质多层膜。扫描电镜(SEM)测试结果表明,随组装溶液中NaCl浓度增大单层膜厚度增加,膜表面变得平坦光滑。渗透汽化结果表明,增加盐的浓度能大大提高组装膜的分离选择性。在35℃的操作温度下(PDDA/PSS)_6PDDA多层膜用于分离含水5 wt%的异丙醇-水混合溶液,组装液中NaCl浓度为0.1 M和1 M时,膜的通量分别为2.57 kg.m~(-2).h~(-1)和1.67 kg.m~(-2).h~(-1),而分离因子则从46上升到246。随着组装层数的增加,组装膜的表面变得光滑,分离因子升高而通量下降。在盐浓度较高情况下提高外加盐浓度比增加组装层数对提高膜的分离因子更有效。操作温度和料液组成对PDDA/PSS聚电解质多层膜的分离性能有很大影响。随着组装溶液中水含量的增多,PDDA/PSS聚电解质多层膜的通量迅速上升,透过液的水含量略有下降。PDDA/PSS聚电解质多层膜分离含水5 wt%的异丙醇-水混合液时,发现组装膜的通量和分离因子随着操作温度的上升同步上升,呈反“trade-off”现象。在分离水含量较高混合液(水含量20～30 wt%)时由于聚电解质膜溶胀性增加,反“trade-off”现象消失。
在电场下制备了三种聚电解质层层自组装膜,PDDA/PSS,PDDA/PAA和PEI/PAA电场促进自组装膜(EPEM)。考察了组装条件对各种自组装膜的表面形貌及其渗透汽化性能的影响。实验结果证明,沿着电场力方向组装的PEI单层膜表面粗糙度增大,渗透汽化分离性能有明显提高,这表明电场加快组装速度和增大聚电解质吸附量,从而提高了膜的选择性。由PEI单层膜组装的表面粗糙度及渗透汽化实验确立了最佳组装时间为15 min,最佳组装电压为5 V。PDDA/PSS,PDDA/PAA和PEI/PAA三种膜优先透水的选择性依次递增;电场促进自组装多层膜(EPEM)的表面粗糙度比相同组装条件下普通自组装多层膜(PEM)粗糙度低,用于分离异丙醇-水混合溶液时有很高的分离性能。渗透汽化分离实验显示,几个双层的PEI/PAA EPEM用于分离异丙醇-水混合溶液时,在较大操作温度(40～70℃)及料液浓度范围内(水含量5～30 wt%)都具选择性高,渗透通量大、重复性好以及高稳定性的特点。例如(PEI/PAA)_4PEI EPEM,在渗透汽化操作温度为70℃用于分离含水10 wt%的异丙醇-水体系时,其通量高达4.05 kg.m~(-2)·h~(-1),分离因子为1075;在70℃分离分离含水30 wt%的异丙醇-水体系时,其通量高达7.65 kg.m~(-2).h~(-1),透过液水含量仍保持94.38 wt%。
In the past decade,the layer-by-layer(LbL)self-assembly of polyelectrolytes(PE) has been considered to be the simplest and most convenient way for fabricating thin multilayer membranes with a well-defined thickness and chemical composition. However,due to its short developing history,many things are still uncertain for this novel technology which limits its application in many aspects.In order to further discover the rule of PEM during the LbL process,a series of protocols were established to investigate the properties of PEMs.Solution properties of PEs and properties of multilayer membranes were investigated to discover the relation between the surface properties,membrane thickness and separation performance.
Self-assembly layer-by-layer multilayer membranes of two typical PEs,poly (dimethyl diallylammonium chloride)(PDDA)and poly(styrenesulfonate sodium salt) (PSS)were fabricated from dipping solutions with different added salt concentrations, pH,solvent compositions and temperature respectively.The absorption amount of PDDA/PSS self-assembled multilayer membranes in designed dipping solvents was measured by UV-vis-spectroscopy(UV)and quartz crystal microbalance(QCM). Intrinsic viscosities of PDDA and PSS in corresponding dipping solvents were determined by an Ubbloheode viscometer.The adsorption amount of PDDA/PSS multilayer membranes increases with decreasing the intrinsic viscosity of PDDA or PSS in different corresponding dipping solvents.That is,a negative relation between the adsorption amount of PDDA/PSS multilayer membranes and the chain dimension of PDDA and PSS in the dipping solvents exhibits for all assembly systems of PDDA and PSS except for that of PSS in the media with pH_(PSS)＞10.The negative relation is trusty in spite of the designed dipping solvent for only PDDA or PSS and for both of them.The high adsorption amount of PDDA/PSS multilayer membranes could be attributed to low excluded volume of the compact chain with low intrinsic viscosity of the polyelectrolyte in the dipping solvent.The AFM images show that polyelectrolyte with compact chains in solutions would form thick membranes with rough surfaces.
Two sulfonated poly(sulphone)sodium salts(SPSFs)with different molecular weights and ionic exchange capacities in a N,N-dimethyl formamide/water(DMF-H_2O) mixed solvent with various DMF contents(φ_(DMF))were selected as a model system for investigating the influences of solvent composition,solution properties,and charge density of polyelectrolytes on the layer-by-layer(LbL)self-assembly of water-insoluble polyelectrolytes.PDDA in aqueous solution was used as the counterpart.Intrinsic viscosity and conductivity of SPSF(ηSPSF and L_(SPSF))in solutions with differentφ_(DMF)were investigated.The PDDA/SPSF multilayer membranes grew nearly linearly with the layer numbers regardless of theφ_(DMF)in the SPSF solutions. The total absorption amount of the PDDA/SPSF multilayer membranes was strongly dependent on the charge density of the SPSF molecules and theφ_(DMF)value of the SPSF solutions.Minimum values and maximum values of absorption amount were observed atφ_(DMF)0.6～0.7 andφ_(DMF)0.8～0.9 respectively.On the other hand,the SPSF with a lower ionic exchange capacity led to thicker multilayer membranes for any givenφ_(DMF)value in the SPSF solutions.The average thickness of each bilayer was about 3.5～7.5 nm for PDDA/SPSF85 or 5.6～13.3 nm for PDDA/SPSF65,depending on the solvent composition.Surface roughness and contact angle of PDDA/SPSF increase with increasing membrane thickness.The results indicate that the molecular structures of the DMF-H_2O mixed solvent strongly affect the solution properties of SPSF,which in turn determine the growth behavior and physical properties of the PDDA/SPSF multilayer membranes.
PDDA and PSS in solutions with different NaCl concentrations were self-assembled onto a polyamide reverse osmosis membrane and used for dehydration water from isopropanol.The influences of NaCl concentration of the dipping solutions, number of the bilayers and feed temperature on the pervaporation performance of PDDA/PSS multilayer membranes were investigated.Scanning electron microscope (SEM)experiment showed that the membrane surface becomes smoother with increasing NaCl concentration in dipping solutions.The results of the pervaporation tests showed that the PDDA/PSS membranes assembled in high NaCl concentration have good pervaporation performance.The separation factor is 345 and permeate flux is 2.51 kg.m~(-2).h~(-1)for(PDDA/PSS)_6PDDA multilayer membrane assembled in 1 M NaCl used for pervaporation of 95 wt%isopropanol isopropanol-water mixtures at 35℃.With increasing operation temperature,both the flux and separation factor increase.However,the separation factor decreases with increasing operation temperature when increases the water percent in feed.An anti-"trade-off" phenomenon is found in low water percent in feed and explained in term of both solvent interaction and structure of LbL membrane.
An electric field enhanced method is developed for fabricating layer-by-layer (LbL)self-assembly polyelectrolyte multilayer membranes.Three kinds of electric field enhanced polyelectrolyte multilayer membranes(EPEMs),poly(diallyl dimethylammonium chloride)/poly(styrenesulfonate sodium salt)(PDDA/PSS),poly (diallyldimethylammonium chloride)/poly(acrylic acid sodium salt)(PDDA/PAA) and polyethylenimine/poly(acrylic acid sodium salt)(PEI/PAA),were self-assembled on a polyamide reverse osmosis membrane.The pervaporation performances of EPEMs for separating isopropranol-water mixtures(90/10,w/w)are all superior to those of corresponding normal self-assembled polyelectrolytes membranes(PEMs), and the selectivity increases with PDDA/PSS,PDDA/PAA and PEI/PAA in order. The surface properties and pervaporation performance of PEI/PAA EPEM fabricated in different conditions were investigated.The results show that the electric field can improve the self-assembly process.The best dipping time of each layer is 15 min and the best applied voltage is 5 V.The PEI/PAA EPEM shows high performance and good selectivity in a large-scale temperature(40～70℃)and water feed concentration (water in feed:5～30 wt%).For(PEI/PAA)_4PEI EPEM,the separation factor is 1075 and permeation flux is 4.05 kg.m~(-2)·h~(-1)for separating isopropranol-water mixtures(90/10,w/w)at 70℃.
引文
[1]Cragg,L.H.,The terminology of intrinsic viscosity and related functions[J]J.Colloid.Sci.,1946,1,261-269
[2]Huggins,M.L.,The Viscosity of Dilute Solutions of Long-Chain Molecules.Ⅳ.Dependence on Concentration[J]J.Am.Chem.Soc.1942,64,2716-2720.
[3]Cragg,L.H.,Bigelow,c.c.,The viscosity slope constant k'-ternary systems:polymer-polymer-solvent[J].J.Polymer.Sci.1955,16,177-191
[4]M.Bohdanechy,J.Kovar,Viscosity of Polymer Solutions,Elsevier-Scientific,Amsterdam,1982
[5]Flory,R J.Principles of Polymer Chemistry,Cornell University Press:New York,1953
[6]程铬时,粘数据的外推和从一个浓度的溶液粘度计算特性粘数,分子通讯,1960,4:159-163
[7]Qian,J.W.,Du,Z.Q.,A new one-point intrinsic viscosity equation applying to the polymersolvent systems with higher values of Huggins' constant(K')[J].Acta Polymerica Sinica,1988,2:113-117
[8]Gennes,P.G.,Scaling Concepts in Polymer Physics,Chap 3,Ithaca,New York:Cornell University Press,1979.
[9]Qian,R.,Benoit H.,Rempp,R,Eds.,Macromolecules,New York:Pergamom Press,1982,159
[10]Cheng,R.,Yan,X.,Size-exclusion chromatographic evidence for the existence of a critical concentration for coil shrinking in polymer solutions[J]J.Appl.Polym.Sci.,Appl Polym Symp,1991,48,123-132.
[11]Wu,C.,Light-scattering evidence of a "critical" concentration for polymer coil shrinking in dilute solution[J].J.Polym.Sci.,Polym Phys,1994,32,1503-1509.
[12]Cheng,R.,On the concentration regimes of a flexible-chain polymer solution[J].Macromol Symp,1997,124,27-34
[13]潘雁,程镕时,高分子稀溶液粘度的浓度依赖性,高分子通报,2000,2,10-17
[14]Graessley,W.W.,Polymer 21,1980,258,Flory,P.J.,Principles of Polymer Chemistry,Cornell University Press,New York,1953,p.611-617
[15]Choukchou-Braham,E.,Benabadji,I.,Mansri,A.,Francois,J.,Molecular weight influence on viscosimetric parameters of poly(4-vinylpyridine)polymers[J].Eur Polym,J.2003,39(2),297-303
[16]Blodgett,K.B.,Films built by depositing successive monomolecular layers on a solid surface[J].J.Am.Chem.Soc.,1935,57:1007-1010
[17]Lee,H.,Kepley,L.J.,Hong,H.G..,Akhter,S.,Mallouk,T.E.,Adsorption of ordered zirconium phosphonate multilayer films on silicon and gold surfaces[J].J.Phys.Chem.,1988,92:2597-2601
[18]Decher,G..,Hong,J.D.,Buildup of ultrathin multilayer films by a self-assembly process.Ⅱ.Consecutive adsorpt ion of anionic and cationic bipolar amphiphiles and polyelectrolytes on charged surfaces[J].Ber.Bunsen Ges.Phys.Chem.1991,95:1430-1433
[19]Decher,G..,Science,Fuzzy nanoassemblies:toward layered polymeric multicomposites[J].1997,227:1232-1237
[20]Langmuir,I.,The constitution and fundamental properties of solids and liquids.Ⅱ.liquids[J].J.Am.Chem.Soc.,1917,39:1848-1906
[2l]宣理静.聚电解质PDDA/PSS自组装机理及渗透气化性能研究[硕士论文].杭州:浙江大学.2006
[22]张宏宇.基于氢键的聚合物多层膜的构筑与结构调控[博士论文].长春:吉林大学.2005
[23]Bigelow,W.C.,Pickett,D.L.,Zisman,W.A.,Oleophobic monolayers I.Films adsorbed from solution in non-polar liquids[J].J.Colloid Interface Sci.,1946,1:513-538
[24]Kuhn,H.,Ulman,A.,Thin Films.New York,Academic Press,1995,20
[25]Sagiv,J.,Organized monolayers by adsorption.1.Formation and structure ofoleophobic mixed monolayers on solid surfaces[J].J.Am.Chem.Soc.,1980,102:92-98
[26]Nuzzo,R.G.,Allara,D,L.,Adsorption of bifunctional organic disulfides on gold surfaces[J].J.Am.Chem.Soc.,1983,105:4481-4483
[27]Iler,R,L.,Multimayers of colloidal particles,J Colloid Interface Sci.[J],1966,21(6):569-594
[28]Kamineni,V.K.,Lvov,Y.M.,Dobbins,T.A.Layer-by-Layer Nanoassembly of Polyelectrolytes Using Formamide as the Working Medium[J].Langmuir,2007,23,7423-7427
[29]Samokhina,L.,Schrinner,M.,Ballauff,M.,Drechsler,M.Binding of Oppositely Charged Surfactants to Spherical Polyelectrolyte Brushes:A Study by Cryogenic Transmission Electron Microscopy[J].Langmuir 2007,23,3615-3619
[30]Ferreira,M.,Cheung,J.H.,Rubner,M.F.,Molecular self-assembly of conjugated polyions:a new process for fabricating multilayer thin film heterostructures[J].Thin solid Films,1994,244:806-809
[31]Cooper,T.,Campbell,A.,Crane,R.Formation ofpolypeptide-dye multilayers by electro static self-assembly technique[J].Langmuir 1995,11,2713-2718
[32]Kozt,J.,Kosmella,S.,Beitz,T.,Self-assembled polyelelctrolyte systems[j].Prog.Polym.Sci.,2001,26:1199-1232
[33] Saremi, F., Lange, G.., Tieke, B., Deeply colored self-assembled multilayers of anionic DPP bolamphiphiles and cationic polyelectrolytes [J]. Adv. Mater. 1996, 8, 923-926
[34] Ariga, K., Lvov, Y., Kunitake, T., Assembling alternate dye-polyion molecular films by electrostatic layer-by-layer adsorption[J]. J. Am. Chem. Soc. 1997, 119, 2224-2231
[35] Donth, E., Walther, D., Shilov, V. N., Kanippel, E., Budde, A., Lowack, K., Helm, C. A., Moehwald, H., Nonlinear Hairy Layer Theory of Electrophoretic Fingerprinting Applied to Consecutive Layer by Layer Polyelectrolyte Adsorption onto Charged Polystyrene Latex Particles[J]. Langmuir 1997,13, 5294-5305
[36] Kong, W., Zhang, X., Gao, M. L., Zhou, H., Li, W., Shen, J.C., A new kind of immobilized enzyme multilayer based on cationic and anionic interaction[J]. Macromol. Rapid Commun., 1994,15:405-409
[37] Lvov, Y., Lu, Z., Schenkman, J. B., Zu, X., Rusling, J.F., Direct electrochemistry of myoglobin and cytochrome P450cam in alternate layer-by-layer films with DNA and other polyions [J]. J. Am. Chem. Soc, 1998,120:4073-4080
[38] Zhou, Y. L., Li, Y.Z., Layer-by-layer self-assembly of multilayer films containing DNA and Eu~(3+): their characteristics and interactions with small molecules[J]. Langmuir, 2004, 20: 7208-7214
[39]Dootz, R., Nie, J., Du, B., Herminghaus, S., Pfohl, T., Raman and Surface Enhanced Raman Microscopy of Micro structured Polyethylenimine/DNA Multilayers [J]. Langmuir 2006, 22,1735-1741
[40] Lvov, Y., Haas, H., Decher, G., Mohwald, H., Mikhailov, A., Mtchedlishvily, B., Morgunova, E., Vainshtein, B., Successive deposition of alternate layers of polyelectrolytes and a charged virus[J]. Langmuir, 1994,10: 4232-4236
[41] Lvov, Y., Ariga, K., Ichinose, I., Kunitake, T., Assembly of multicomponent protein films by means of electrostatic layer-by-layer adsorption[J]. J. Am. Chem. Soc., 1995,117:6117-6123
[42] Forzani, E.S., Perez, M.A., Teijelo, M.L., Calvo, E.J., Redox driven swelling of layer-by-layer enzyme-polyelectrolyte multilayers[J]. Langmuir, 2002,18: 9867-9873
[43] Kong, W., Wang, L. P., Gao, M.L., Zhou, H., Zhang, X., Li, W., Shen, J.C., Immobilized bilayer glucose isomerase in porous trimethylamine polystyrene based on molecular deposition[J]. J. Chem. Soc. Chem., Commun., 1994,1297-1300
[44] Caruso, F., Hollow capsule processing through colloidal templating and self-assembly [J]. Chem Eur J 2000,6: 413-419
[45] Caruso, F., Nanoengineering of particle surfaces[J]. Adv Mater 2001,13:11-22
[46] Caruso, F., Caruso, R.A., Mohwald. H., Nanoengineering of inorganic and hybrid hollow spheres by colloidal templating [J]. Science 1998,282:1111-1114
[47] Donath, E., Sukhorukow, G.B., Caruso, F., Davis, S.A., Mo¨hwald, H., Novel hollow polymer shells by colloidtemplated assembly of polyelectrolytes[J]. Angew Chem Int Ed 1998,37:2201-2205
[48] Wu, Z. Y., Guan, L. N.,Shen G. L.,Yu, R.,Renewable urea sensor based on a self-assembled polyelectrolyte layer[J]. Analyst, 2002,127: 391-395
[49] Lowack, K., Helm, C. A., Molecular mechanisms controlling the self-assembly process of polyelectrolyte multiayers[J].Macromolecules, 1998,31(3):823-833
[50] Wang, L.Y., Wang, Z.Q., Zhang. X., Shen, J.C., Chi. L.F., Fuchs, H., Anew approach for the fabrication of an alternating multilayer film of poly(4-vinylpyridine) and poly(acrylic acid) based on hydrogen bonding[J]. Macromol. Rapid Commun., 1997,18: 509-514
[51] Stockton, W.B., Rubner, M.F., Molecular-level processing of conjugated polymers. 4. layer-by-layer manipulation of polyaniline via hydrogen-bonding interactions[J]. Macromolecules, 1997, 30:2717-2725
[52] Wang, L.Y., Fu, Y, Wang, Z.Q., Fan, Y,G,., Zhang, X., Investigation into an alternating multilayer film of poly(4-vinylpyridine) and poly(acrylic acid) based on hydrogen bonding[J]. Langmuir, 1999,15:1360-1363
[53]Lee, H., Kepley, L.J., Hong, H.G., Akhter, S., Mallouk, T.E., Adsorption oforderedzirconium phosphonate multilayer films on silicon and gold surfaces[J]. J. Phys.Chem., 1988,92: 2597-2601
[54]Mallouk, T.E., Gavin, J.A., Molecular recognition in lamellar solids and thin films[J]. Acc.Chem.Res.,1998,31: 209-217
[55]Cao, G.., Hong, H-G., Mallouk, T.E., Layered metal phosphates and phosphonates: from crystals to monolayers[J]. Acc.Chem.Res., 1992,25:420-427
[56] Kohli, P., Blanchard, G.J., Design and growth of robust layered polymer assemblies with molecular thickness control[J]. Langmuir, 1999, 15: 1418-1422
[57] Kohli, P., Blanchard, G.J., Probing interfaces and surface reactions of zirconium phosphate/phosphonate multilayers using P NMR spectrometry[J]. Langmuir, 2000,16: 695-701
[58] Kohli, P., Blanchard, G. J., Design and demonstration of hybrid multilayerstructures: layer-by-layer mixed covalent and ionic interlayer linking chemistry[J]. Langmuir, 2000, 16: 8518-8524
[59] Major, J.S., Blanchard, G.J., Covalently bound polymer multilayers for efficient metal ion sorption [J]. Langmuir, 2001, 17: 1163-1169
[60] Shimazaki, Y., Mitsuishi, M., Ito, S., Yamamoto, M., Preparation and characterization of the Layer-by-layer deposited ultrathin film based on the charge-transfer interaction in orgnaic solvents [J]. Langmuir, 1998,14,2768
[61] Shimazaki, Y., Mitsuishi, M., Ito, S., Yamamoto, M., Alternate adsorption of polymers on a gold surface through the charge-transfer interaction [J]. Macromolecules, 1999, 32, 8220-8223
[62]Shimazaki.Y.,Mitsuishi,M.,Ito,S.,Yamamoto,M.,Inaki,Y.,Preparation of the nucleoside-containing nanolayered film by the layer-by-layer deposition technique[J].Thin Solid Films,1998,333,5-8
[63]Cochin,D.,Laschewsky,A.,Layer-by-layer self-assembly of hydrophobically modified polyelectrolytes[J].Macromolecular Chemsitry and Physics,1999,200,609-615
[64]Kotov N.A.,Layer-by-layer self-assembly:The contribution of hydrophobic interactions Nanostructrued Mater.,1999,12,789-796
[65]Dubas,S.,Joseph,T.,Schlenoff,B.,Factors of controlling the growth of polyelectrolyte multilayers[J].Macromolecules 1999,32,8153-8160
[66]Alexei A.Antipov,Gleb B.Sukhorukov,H.Mohwald.Influence of the ionic strength on the polyelectrolyte multilayers' permeability[J].Langmuir 2003,19,2444-2448
[67]Svetlana A.Sukhishvili,Eugenia Kharlampieva,Vladimir Izumrudov.Where polyelectrolyte multilayers and polyelectrolyte complexes meet[J].Macromolecules 2006,39,8873-8881
[68]Clark,S.L.,Montague,M.F.,Hammond,P.T.,The effect of ion type and ionic content on templating patterned ionic multilayers[J].Acs.Sym.Ser,1998,695:206-219
[69]陈幼芳.疏水性药物微胶囊的自组装构筑及其缓释性能研究[博士论文].杭州:浙江大学.2006
[70]Ruths,J.,Essler,F.,Decher,G.,Riegler,H.,Polyelectrolytes I:polyanion/polycation multilayers at the air/monolayer/water interface as elements for quantitative polymer adsorption studies and preparation of hetero-superlattices on solid surfaces [J].Langmuir,2000,16:8871-8878
[71]Lavalle R,Gergely C.,Cuisinier F.J.G.,Decher,G.,Schaaf,P.,Voegel,J.C.,Picart,C.,Comparison of the structure ofpolyelectrolyte multilayer films exhibiting a linear and an exponential growth regime:An in situ atomic force microscopy study[J].Macromolecules,2002,35:4458-4465
[72]Schoeler,B.,Kumaraswamy,G.,Caruso,F.,Investigation of the influence of polyelectrolyte charge density on the growth of multilayer thin films prepared by the layer-by-layer technique[J].Macromolecules,2002 35(3):889-897
[73]Fleer,G.,Hoogeveen,N.G.,Cohen Stuart,M.A.,Bohmer,M.R.,Formation and stability ofmultilayers ofpolyelectrolytes[J].Langmuir 1996,12,3675-3681
[74]Hoogeveen,N.G.,Cohen Stuart,M.A.,Fleer,G.,Polyelectrolyte adsorption on oxides.I.Kinetics and adsorbed amounts[J].J.Colloid Interface Sci.1996,182,133-145
[75]Arys,X.,Jonas,A.M.,Laguitton,B.,Legras,R.,Laschewsky,A.,Wischerhoff, E.,Structural studies on thin organic coatings built by repeated adsorption of polyelectrolytes[J].Prog.Org.Coat.1998,34,108-118
[76]Bertrand,P.,Jonas,A.,Laschewsky,A.,Legras,R.Ultrathin polymer coatings by complexation of polyelectrolytes at interfaces:suitable materials,structure and properties[J].Macromol.Rapid Commun.2000,21,319-348
[77]Fischer,P.,Laschewsky,A.,Wischerhoff,E.,Arys,X.,Jonas,A.,Legras,R.,Polyelectrolytes bearing azobenzenes for the functionalization of multilayers[J].Macromol.Symp.1999,137,1-8
[78]Shiratori,S.S.,Rubner,M.F.,pH-Dependent thickness behavior of sequentially adsorbed layers of weak polyelectrolytes[J].Macromolecules 2000,33,4213-4219
[79]Krasemann,L.,Toutianoush,A.,Tieke,B.,Self-assembled polyelectrolyte multilayer membranes with highly improved pervaporation separation of ethanol/water mixtures[J].J.Membr.Sci.2001,181:221-228
[80]Dobrynin,A.V.,Rubinstein,M.,Obukhov,S.P.,Cascade of transitions of polyelectrolytes in o poor solvents[J].Macromolecules 1996,29,2974-2979
[81]Lyulin,A.V.,Dunweg,B.,Borisov,O.V.,Darinskii,A.A.,Computer simulation studies of a single polyelectrolyte chain in poor solvent [J].Macromolecules 1999,32,3264-3278
[82]Micka,U.,Holm,C.,Kremer,K.,Strongly charged flexible polyelectrolytes in poor solvents:molecular dynamics simulations[J].Langmuir 1999,15,4033-4044
[83]Poptoshev,E.,Schoeler,B.,Caruso,F.,Influence of solvent quality on the growth ofpolyelectrolyte multilayers[J].Langmuir 2004,20:829-834
[84]Serizawa,T.,Satoko,K.,Kawanishi,N.,Akashi,M.,Layer-by-layer assembly of poly(vinyl alcohol)and hydrophobic polymers based on their physical adsorption on surfaces[J].Langmuir,2002,18:8381-8385
[85]何曼君 高分子物理.上海:复旦大学出版社.2005
[86]Salomaki,M.,Vinokurov,I.A.,Kankare,J.,Effect of temperature on the buildup ofpolyelectrolyte multilayers[J].Langmuir 2005,21:11232-11240
[87]Sui,Z.J.,Salloum,D.,Schlenoff,J.B.,Effect of molecular weight on the construction of polyelectrolyte multilayers:stripping versus sticking[J].Langmuir 2003,19,2491-2495
[88]Lenk,T.J.,Hakknarj V.M.,Rabolt J.F.,Haeussling,L.,Ringsdorf,H.,Formation and characterization of self-assembled films of sulfur-derivatized poly(methyl methacrylates)on gold[J].Macromolecules,1993,26(4):1230-1237
[89]江秀明.聚电电解多层膜构筑及其表面HRP应用组装基础研究[博士论文].杭州:浙江大学.2005
[90]Gao,C.Y.,Leporatti,S.,Moya,S.,Donath,E.,Mohwald,H.,Stability and mechanical properties of polyelectrolyte capsules obtained by stepwise assembly of poly(styrenesulfonate sodium salt)and poly(diallyldimethyl ammonium)chloride onto melamine resin particles[J].Langmuir,2001,17(11):3491-3495
[91]Gao,C.,Donath,E.,Moya,S.,Dudnik,V.,Mohwald,H.,Elasticity of hollow polyelectrolyte capsules prepared by the layer-by-layer technique[J].Eur.Phys.J.E,2001,5(1):21-27
[92]DeLongchamp,D.M.,Kastantin,M.,Hammond,P.T.,High-contrast electrochromism from layer-by-layer polymer films[J].Chem.Mar.,2003,15(8):1575-1586
[93]Cho,J.,Char,K.,Kim,D.Y.,Change in the quantum efficiency due to relative thickness variation of hole transport and emitting layers in a self-assembled device[J].Thin Solid Films,2002,415(1-2):303-307
[94]Baur,J.W.,Baur,J.W.,Balanda,P.B.,Thin-film light-emitting devices based on sequentially adsorbed multilayers of water-soluble poly(p-phenylene)s[J].Adv.Mater.,1998,10(17):1452-1455
[95]Wu,A.,Yoo,D.,Lee,J.K.,Rubner,M.F.,Myocardial production of aldosterone and corticosterone in the rat[J].J.Ant.Chem.Soc.,1999,121(20):4883-4891
[96]Han,S.,Briseno,A.L.,Shi,X.,Mah,D.A.,Zhou,F.,Polyelectrolytecoated nanosphere lithographic patterning of surfaces:fabrication and characterization of electropolymerized thin polyaniline honeycomb films[J].J Phys Chem B 2002,106:6465-6472
[97]Wang,D.Y.,Caruso,R.A.,Caruso.F.,Synthesis of macroporous titania and inorganic composite materials from coated colloidal spheres—a novel route to tune pore morphology[J].Chem Mater 2001,13:364-371
[98]Krasemarm,L.,Tieke,B.,Ultrathin self-assembled polyelectrolyte membranes for pervaporation[J].J.Membr.Sci.1998,150:23-30
[99]Krasemann,L.,Toutianoush,A.,Tieke,B.,Slef-assembled polyelectrolyte mutilayer membranes with highly improved pervaporation separation of ethanol/water mixtures[J].J.Membr.Sci.2001,181:221-228
[100]Toutianoush,A.,Tieke,B.,Pervaporation separation of alcohol/water mixtures using self-assembled polyelectrolyte multilayer membranes of high charge density[J].Mater.Sci.Eng.,C 2002,22:459-463
[101]Meier-Haack,J.,Lenk,W.,Lehmann,D.,Lunkwitz,K.,Pervaporation separation of water/alcohol mixtures using composite membranes based on polyelectrolyte multilayer assemblies[J].J.Membr.Sci.2001,184:233-243
[102]E1-Hashani,A.,Toutianoush,A.,Tieke,B.,Layer-by-layer assembled membranes of protonated 18-azacrown-6 and polyvinylsulfate and their application for highly efficient anion separation[J].J.Phys.Chem.B 2007,111:8582-8588
[103]Krasemann,L.,Tieke,B.,Selective ion transport across self-assembled alternating multilayers of cationic and anionic polyelectrolytes[J].Langmuir 2000,16:287-290
[104]Harris,J.J.,Stair,J.L.,Bruening,M.L.,Layered polyelectrolyte films as selective,ultrathin barriers to anion transport[J].Chem.Mater 2000,12:1941-1946
[105]Toutianoush,A.,Tieke,B.,In novel methods to study interfacial layers,Moebius,D.,Miller,R.,Eds.,Studies in Surface Science Series,Amsterdam:Elsevier,2001,p416
[106]Stair,J.L.,Harris,J.J.,Bruening,M.L.,Uniaxial alignment of polycyclic aromatic hydrocarbons by solution processing[J].Chem.Mater.2001,13:2641-2647
[107]Jin,W.,Toutianoush,A.,Tieke,B.,Use of polyelectrolyte layer-by-layer assemblies as nanofiltration and reverse osmosis membranes[J].Langmuir 2003,19:2550-2553
[108]Toutianoush,A.,Jin,W.,Deligoz,H.,Tieke,B.,Polyelectrolyte multilayer membranes for desalination of aqueous salt solutions and seawater under reverse osmosis conditions[J].Appl.Surf.Sci.2005,246:437-443
[109]Jin,W.,Toutianoush,A.,Tieke,B.,Size- and charge-selective transport of aromatic compounds across polyelectrolyte multilayer membranes[J].Appl.Surf.Sci.2005,246:444-450
[110]Tieke,B.,Toutianoush,A.,Jin,W.Q.,Selective transport of ions and molecules across layer-by-layer assembled membranes of polyelectrolytes,p-sulfonato-calix[n]arenes and Prussian Blue-type complex salts[J].Advances in Colloid and Interface Science,2005,116:121-131
[111]Juha-Matti,L.,Thomas,J.M.,Poly(4-methyl-1-pentene)-supported polyelectrolyte multilayer films:preparation and gas permeability[J].Macromolecules 1997,30:1752-1757
[112]时钧,袁权,高丛楷,膜技术手册,化学工业出版社,北京,2001.
[113]刘茉娥,陈欢林.新型分离技术基础.浙江大学出版社.浙江,1999.
[114]郑领英,王雪松.膜技术.化学工业出版社,北京,2000.
[115]白云翔.共聚物渗透汽化膜的制备、结构及分离水中微量有机物性能的研究[博士论文].杭州:浙江大学.2006
[116]胡云光.膜生物反应器在石油化工中的应用.石油化工,1994,6:400-406
[117]薛德明.膜分离技术在医药食品工业中的应用.中国海洋药物,1994,5:247-253
[118]尹沛松.微孔膜滤器在医药工业中的应用.过滤与分离,1998,4:32-34
[119]顾瑾,郑成.膜分离在生物工程应用中存在的问题及对策.合肥工业大学学报(自然科学版),1998,2:102-108
[120]徐又一.聚烯烃中空纤维膜及其分离新技术在环保工程中的开发、应用.中国环保产业,1996,Z1:38-40
[121]Abraham,K.M.,Alamgir,M.,Hoffman,D.K.,Polymer electrolytes reinforced by Celgard membrane[J].J.Electroehem.Soc.,1995,142:683-687
[122]孙晓辉,郝建飞,王竞.膜技术在醋酸生产中的应用.中国调味品,1995,4:6-7
[122]于丁一,陈培祺,呼丙辰.我国膜法海水淡化技术现状与发展前景.给水排水,1994,8:15-18
[123]徐又一,徐志康.高分子膜材料.化学工业出版社,北京,2005.
[124]Mulder,M.,李琳译,膜技术基本原理,清华大学出版社,北京,1999.
[125]Kober,P A.,Pervaporation,perstillation and percrystallisation[J].J.Am.Chem.Soc.1917,39:944-948
[126]Rautendach,R.,Albecht,R.,Membrane Processes.New York:John Wiley Sons,1989
[127]Huang,R Y M.,ed,Pevaporation Membrane separation Processes.Amsterdam:Elsevier,1991
[128]Ho,W.S.W.,Sirkar,K.K.,ed.Membrane Handbook.New York:Van Nostrand Reinold,1992
[129]刘茉娥.膜分离技术.北京:化学工业出版社,1998
[130]Bining,R.C.,James,E E.,New sepatate by membrane permeate[J].Petrol Refiner,1958,37(5):214-215
[131]Bining,R.C.,James,F.E.,Sepatation by membrane permeate[J].Oil Gas J.1958,56(21):104-105
[132]Neel,J.,Nguyen,Q.T.,Clement,R.,Le Blanc,L.,Fractionation of a binary liquid mixture by continuous pervaporation[J].J.Membr.Sci.1983,15:43-62
[133]Rautenbach,R.,Albrecht,R.,Separation of organic binary mixtures by pervaporation[J].J.Membr.Sci.1980,7:203-223
[134]Rautenbach,R.,Albrecht,R.,On the behaviour of asymmetric membranes in pervaporation[J].J Membr Sci.1984,19:1-12
[135]Schmittecker,B.,Lichtenthaler,R,N.,Proceeding of the 1~(st)international conference on pervaporation in the chemical industry[J].Bakish Red.Atlanta,Georgia:1986.96-100
[136]Bruschke H D.EP 0096340.1983
[137]Bruschke H D.EP 0096339.1983
[138]陈翠仙,韩宾兵,朗宁威.渗透蒸发和蒸汽渗透.北京:化学工业出版社,2004
[139]Bining R.C.,James F.E.,Now separate by membrane permeation[J].Petrol. Refiner., 1958, 37: 214-215
[140] Bining R.C., James F.E., Separation by membrane permeate [J]. Oil gas J., 1958, 56:104-105
[141]Lipnizkia, F., Hausmannsb, S., Tena, P. K., Fielda, R.W., Organophilic pervaporation: prospects and performance [J]. Chem. Eng. J., 1999,73:113-29
[142] Baker, R.W., Cussler, E. L, Membrane separation systems: Recent development and future directions. New Jersey: Noyes Data Corporation, 1991, 56-85.
[143] Krasemann, L., Kompositmembranen mit selbstorganisierter, Dissertation, University zu Koln, 1999
[144] Zhu, Z., Feng, X., Penlidis, A., Self-assembled nano-structured polyelectrolyte composite membranes for pervaporation [J]. Mater. Sci. Eng. C. 2006,26: 1-8
[145] Zhang, G. J., Gu, W. L., Ji, S. L., Liu, Z. Z., Peng, Y. L., Wang, Z., Preparation of polyelectrolyte multilayer membranes by dynamic layer-by-layer process for pervaporation separation of alcohol/water mixtures[J]. J. Membr. Sci. 2006, 280: 727-733.
[146] Zhang, G. J., Yan, H. H., Ji, S. L., Liu, Z. Z., Self-assembly of polyelectrolyte multilayer pervaporation membranes by a dynamic layer-by-layer technique on a hydrolyzed polyacrylonitrile ultrafiltration membrane[J]. J. Membr. Sci. 2007, 292: 1-8
[147] Salomaki, M., Tervasmaki, P., Areva, S. and Kankare, J., The hofmeister anion effect and the growth of polyelectrolyte multilayers [J]. Langmuir, 2004, 20: 3679-3683
[148] Salomaki, M., Vinokurov, I. A., Kankare, J., Effect of temperature on the buildup of polyelectrolyte multilayers [J]. Langmuir, 2005,21:11232-11240
[149] Yang, S., Zhang, Y., Zhang, X., Xu, J., The influence of pH on a hydrogen-bonded assembly film [J]. Soft Matter, 2007, 3:463-469
[150] Bai, Y. X., Qian, J. W., An, Q. F., Zhu, Z. H., Zhang, P., Pervaporation characteristics of ethylene-vinyl acetate copolymer membranes with different composition for recovery of ethyl acetate from aqueous solution[J]. J. Membr. Sci. 2007,305:152-159
[151] Qian, J. W., Zhou, G.. H., Li, J., Yang, W. Y., Conformational inversion of olyethylene-polyvinyl acetate graft copolymer in selective solvent by viscometry [J]. Eur. Polym. J. 2001, 37: 1871-1875
[152] Sauerbrey, G. Z., The use of quartz oscillators for weighing thin layers and microweighing [J]. Phys. 1959, 155,206-222
[153] Lvov, Y., In protein architecture: Interfacing molecular assembliesand immobilization biotechnology, Lvov, Y, Mohwald, H., Eds., Marcel Dekker: New York, 2000, pp 125-166
[154] Ghimici, L., Dragan, S., Behaviour of cationic polyelectrolytes upon binding of electrolytes:effects of polycation structure,counterions and nature of the solvent[J].Colloid.Polym.Sci.,2002,280:130-134
[155]Yan.X.J.,Deng,Y.H.,Wang,X.G.,pH effect on electrostatic layer-by-layer self-assembly of a side-chain azo polyelectrolyte[J].Acta Polymerica Sinica,2007,5:440-445
[156]陈幼芳,钱锦文,杨平,林贤福,PSS/PDDA自组装膜形成过程中的临界浓度效应.高等学校化学学报,2005,26:787-789
[157]Nakata,M.,Nakano,Y.,Kawate,K.,Light-scattering study of three-component systems 3:0 Point for poly(methyl methacrylate)in the binary mixture 1-chlorobutane +2-butanol[J].Macromolecules,1988,21:2509-2514
[158]朱平平,任琳,杨海洋,刘远立,混合溶剂中高分子的尺寸,功能高分子学报,2003,16:261-268
[159]Tan,H.L.,McMurdo,M.J.,Pan,G.,Van Patten,P.G.,Temperature dependence of polyelectrolyte multilayer assembly[J].Langmuir,2003,19:9311-9314
[160]Buscher,K.,Graf,K.,Ahrens,H.,Helm,C.A.,Influence of adsorption conditions on the structure of polyelectrolyte multilayers[J].Langmuir,2002,18:3585-3591
[161]Leporatti,S.,Gao,C.,Voigt,A.,Donath,E.,Mohwald,H.,Elasticity of hollow polyelectrolyte capsules prepared by the layer-by-layer technique[J].Eur.Phys.J.E.,2001 5:13-21
[162]McAloney,R.A.,Dudnik,V.,Goh,M.C.,Kinetics of salt-induced annealing of a polyelectrolyte multilayer film morphology[J].Langmuir,2003,19:3947-3952
[163]Steitz,R.,Jaeger,W.,Von Klitzing,R.,Influence of charge density and ionic strength on the multilayer formation of strong polyelectrolytes[J].Langmuir 2001,17:4471-4474
[164]Stockton,W.B.,Rubner,M.F.,Molecular-level processing of conjugated polymers.3.layer-by-layer manipulation of polyaniline via electrostatic interactions [J].Macromolecules 1997,30:2712-2716
[165]Fu,Y.,Chen,H.,Qiu,D.L.,Wang,Z.Q.,Zhang,X.,Multilayer assemblies of poly(4-vinylpyridine)and poly(acrylic acid)bearing photoisomeric spironaphthoxazine via hydrogen bonding[J].Langmuir 2002,18:4989-4995
[166]Zhang,H.Y.,Wang,D.,Wang,Z.Q.,Zhang,X.,Hydrogen bonded layer-by-layer assembly of poly(2-vinylpyridine)and poly(acrylic acid):Influence of molecular weight on the formation of microporous film by post-base treatment[J].Eur.Polym.J.2007,43:2784-2791
[167]Sukhishvili,S.A.,Granick,S.,Investigation of the influence ofpolyelectrolyte charge density on the growth of multilayer thin films prepared by the layer-by-layer technique[J].Macromolecules 2002,35:889-897
[168]Lvov,Y.,Ariga,K.,Kunitake,T.Formation of ultrathin multilayer and hydrated gel from montmorillonite and linear polycations[J].Langmuir 1996,12:3038-3044
[169]Caruso,F.,Furlong,D.N.,Ariga,K.,Ichinose,I.,Kunitake,T.,Characterization of polyelectrolyte-protein multilayer films by atomic force microscopy,scanning electron microscopy,and fourier transform infrared reflection-absorption spectroscopy[J].Langmuir 1998,14:4559-4565
[170]Onda,M.,Ariga,K.,Kunitake,T.J.,Activity and stability of glucose oxidase in molecular films assembled alternately with polyions[J].Biosci.Bioeng.1999,87:69-75
[171]宣理静,钱锦文,陈幼芳,张鹏,化学进展,2006,18:950-956
[172]Ackern,F.V.,Krasemann,L.,Tieke,B.,Ultrathin membranes for gas separation and pervaporation prepared upon electrostatic self-assembly of polyelectrolytes[J].Thin Solid Films,1998,327-329:762-766
[173]Dobrynin,A.V.,Rubinstein,M.,Adsorption of hydrophobic polyelectrolytes at oppositely charged surfaces[J].Macromolecules,2002,35:2754-2768
[174]Zhang,H.,Wang,Z.,Zhang,Y.,Zhang,X.,Hydrogen-bonding-directed layer-by-layer assembly of poly(4-vinylpyridine)and poly(4-vinylphenol):Effect of solvent composition on multilayer buildup[J].Langmuir 2004,20:9366-9370
[175]Wang,H.,He,Y.,Yuo,X.,Wang,X.,Sequentially adsorbed electrostatic multilayers of branched side-chain polyelectrolytes bearing donor-acceptor type azo chromophores[J].Macromolecules 2004,37:135-146
[176]Hong,J.,Jung,B.,Kim,C.H.,Kim,K.,Effects of spacer chain lengths on layered nanostructures assembled with main-chain azobenzene ionenes and polyelectrolytes[J].Macromolecules 2000,33:7905-7911
[177]代化,管蓉,汪丽娟,燃料电池用磺化聚砜类质子交换膜研究,化学进展,2006,18,:36-44
[178]Brandrup,J.,Immergut,E.H.,Grulke,E.A.,Polymer Handbook(Fourth Edition)1999 Ⅶ 498
[179]Scharlin,E,Steinby,K.,Domanska,U.J.,Volumetric properties of binary mixtures of N,N-dimethylformamide with water or water-d_2 at temperatures fi'om 277.13 Kto 318.15 K[J].Chem.Thermodynamics 2002,34:927-957
[180]Bougard,J,Jadot,R.,Octamethylcyclotetrasiloxane azeotropes[J].J.Chem.Thermodynamics 1975,7:1185-1194
[181]Garcia,B.,Alcalde,R.,Leal,J.M.,Matos,J.S.,Solute-solvent interactions in amide-water mixed solvents[J].J.Phys.Chem.B 1997,101:7991-7997
[182]雷毅.生物素的全合成及其结构—功能关系研究[博士论文].杭州:浙江大学.2004
[183]Lei,Y.,Li,H.,Pan,H.,Han,S.,Structures and hydrogen bonding analysis of N,N-dimethylformamide and N,N-dimethylformamide-water mixtures by molecular dynamics simulations[J].J.Phys.Chem.A2003,107:1574-1583
[184]Yoo,D.,Shiratori,S.S.,Rubner,M.F.,Controlling bilayer composition and surface wettability of sequentially adsorbed multilayers of weak polyelectrolytes [J].Macromolecules 1998,31:4309-4318
[185]Chalaris,M,Koufou,A,Samios,J.Molecular dynamics simulations of the liquid mixtures N,N-dimethylformamide-water using available potential models[J].Journal of Molecular Liquids 2002,101:69-79
[186]董永全,张林,侯同刚,陈欢林.高等学校化学学报,2007,28(12):2422-2426
[187]李晓东,沈家骢,高等学校化学学报,2007,28(10):2000-2005
[188]杨晓峰,李晓东,沈家骢.高等学校化学学报[J],2007,28(5):974-977
[189]Zhang,P.,Qian J.W.,An Q.F.,Du,B.,Liu,X.Q.,Zhao,Q.,Influences of solution property and charge density on the self-assembly behavior of water-insoluble polyelectrolyte sulfonated poly(sulphone)sodium salts[J].Langmuir,2008,24:2110-2117
[190]Krasemann L.,Tieke B.,Ultrathin self-assembled polyelectrolyte membranes for pervaporation[J].J.Membr.Sci.1998,150:23-30
[191]Krasemann L.,Toutianoush A.,Tieke B.Self-assembled polyelectrolyte multilayer membranes with highly improved pervaporation separation of ethanol/water mixtures[J].J.Membr.Sci.2001,181:221-228
[192]Zhu Z.Q.,Feng X.S.,Penlidis A.Self-assembled nano-structured polyelectrolyte composite membranes for pervaporation[J].Mater.Sci.Eng.C 2006,26:1-8
[193]Zhang,P,Qian,J.W.,Yang,Y.,Bai Y.X.,An,Q.F.,Yan,W.D.,Swelling behavior of palygorskite-polyacrylamide hybrid membrane in xylene mixtures and its pervaporation performance for separating the xylene isomers[J].J.Membr.Sci.2007,288:280-287
[194]Toutianoush A.,Krasemann L.,Tieke B.,Polyelectrolyte multilayer membranes for pervaporation separation of alcohol/water mixtures[J].Colloids Surf.A 2002,198-200:881-889
[195]Zhao Q.,Qian J.W.,An Q.F.,Zhu,Z.H.,Zhang,Peng.,Bai,Y.X.,Studies on pervaporation characteristics of polyacrylonitrile-b-poly(ethylene-glycol)-b-polyacrylonitrile block copolymer membrane for dehydration of aqueous acetone solutions[J].J.Membr.Sci.2008,311:284-293
[196]Klitzingl,R.,Tieke,B.,Polyelectrolyte membranes[J].Adv.Polym.Sci.2004,165:177-210
[197]Zhao,Q.,Qian,J.w.,An,Q.F.,Zhu,Z.H.,Zhang,P.,Bai,Y.X.,Studies on pervaporation characteristics of polyacrylonitrile-b-poly(ethylene glycol)-b- polyacrylonitrile block copolymer membrane for dehydration of aqueous acetone solutions[J]. J. Membr. Sci. 2008,311: 284-293
[198] Bai, Y. X., Qian, J. W., An, Q. F, Zhu, Z. H., Zhang, P, Pervaporation characteristics of ethylene-vinyl acetate copolymer membranes with different composition for recovery of ethyl acetate from aqueous solution[J]. J. Membr. Sci. 2007,305: 152-159
[199] Xiao, S., Feng, X. S., Huang, R. Y.M., Trimesoyl chloride crosslinked chitosan membranes for CO_2/N_2 separation and pervaporation dehydration of isopropanol[J]. J. Membr. Sci. 2007, 306: 36-46
[200] Dobrynin, A. V., Rubinstein, M., Theory of polyelectrolytes in solutions and at surfaces [J]. Prog. Polym. Sci. 2005, 30:1049-1118
[201] Besra, L., Liu, M. L., A review on fundamentals and applications of electrophoretic deposition (EPD) [J]. Progress in Materials Science 52,2007: 1-61
[202] Zhang, G. J., Gao, X., Ji, S. L., Liu, Z. Z., Electric field-improved assembly of polyelectrolyte composite membranes[J]. J. Membr. Sci. 307,2008:151-155
[202] Ray, S.K., Sawant, S.B., Joshi, J.B., Pangarkar, V.G., Development of new synthetic membranes for separation of benzene-cyclohexane mixtures by pervaporation: a solubility parameter approach [J]. Ind. Eng. Chem. Res., 1997, 36: 5265-5276
[203] Huang R.Y.M., Pal R., Moon G.Y., Pervaporation dehydration of aqueous ethanol and isopropanol mixtures through alginate/chitoson two composite membranes supported by poly(vinylidene fluoride) porous membrane[J]. J. Membr. Sci, 2000,167: 275-289
[2]Huggins,M.L.,The Viscosity of Dilute Solutions of Long-Chain Molecules.Ⅳ.Dependence on Concentration[J]J.Am.Chem.Soc.1942,64,2716-2720.
[3]Cragg,L.H.,Bigelow,c.c.,The viscosity slope constant k'-ternary systems:polymer-polymer-solvent[J].J.Polymer.Sci.1955,16,177-191
[4]M.Bohdanechy,J.Kovar,Viscosity of Polymer Solutions,Elsevier-Scientific,Amsterdam,1982
[5]Flory,R J.Principles of Polymer Chemistry,Cornell University Press:New York,1953
[6]程铬时,粘数据的外推和从一个浓度的溶液粘度计算特性粘数,分子通讯,1960,4:159-163
[7]Qian,J.W.,Du,Z.Q.,A new one-point intrinsic viscosity equation applying to the polymersolvent systems with higher values of Huggins' constant(K')[J].Acta Polymerica Sinica,1988,2:113-117
[8]Gennes,P.G.,Scaling Concepts in Polymer Physics,Chap 3,Ithaca,New York:Cornell University Press,1979.
[9]Qian,R.,Benoit H.,Rempp,R,Eds.,Macromolecules,New York:Pergamom Press,1982,159
[10]Cheng,R.,Yan,X.,Size-exclusion chromatographic evidence for the existence of a critical concentration for coil shrinking in polymer solutions[J]J.Appl.Polym.Sci.,Appl Polym Symp,1991,48,123-132.
[11]Wu,C.,Light-scattering evidence of a "critical" concentration for polymer coil shrinking in dilute solution[J].J.Polym.Sci.,Polym Phys,1994,32,1503-1509.
[12]Cheng,R.,On the concentration regimes of a flexible-chain polymer solution[J].Macromol Symp,1997,124,27-34
[13]潘雁,程镕时,高分子稀溶液粘度的浓度依赖性,高分子通报,2000,2,10-17
[14]Graessley,W.W.,Polymer 21,1980,258,Flory,P.J.,Principles of Polymer Chemistry,Cornell University Press,New York,1953,p.611-617
[15]Choukchou-Braham,E.,Benabadji,I.,Mansri,A.,Francois,J.,Molecular weight influence on viscosimetric parameters of poly(4-vinylpyridine)polymers[J].Eur Polym,J.2003,39(2),297-303
[16]Blodgett,K.B.,Films built by depositing successive monomolecular layers on a solid surface[J].J.Am.Chem.Soc.,1935,57:1007-1010
[17]Lee,H.,Kepley,L.J.,Hong,H.G..,Akhter,S.,Mallouk,T.E.,Adsorption of ordered zirconium phosphonate multilayer films on silicon and gold surfaces[J].J.Phys.Chem.,1988,92:2597-2601
[18]Decher,G..,Hong,J.D.,Buildup of ultrathin multilayer films by a self-assembly process.Ⅱ.Consecutive adsorpt ion of anionic and cationic bipolar amphiphiles and polyelectrolytes on charged surfaces[J].Ber.Bunsen Ges.Phys.Chem.1991,95:1430-1433
[19]Decher,G..,Science,Fuzzy nanoassemblies:toward layered polymeric multicomposites[J].1997,227:1232-1237
[20]Langmuir,I.,The constitution and fundamental properties of solids and liquids.Ⅱ.liquids[J].J.Am.Chem.Soc.,1917,39:1848-1906
[2l]宣理静.聚电解质PDDA/PSS自组装机理及渗透气化性能研究[硕士论文].杭州:浙江大学.2006
[22]张宏宇.基于氢键的聚合物多层膜的构筑与结构调控[博士论文].长春:吉林大学.2005
[23]Bigelow,W.C.,Pickett,D.L.,Zisman,W.A.,Oleophobic monolayers I.Films adsorbed from solution in non-polar liquids[J].J.Colloid Interface Sci.,1946,1:513-538
[24]Kuhn,H.,Ulman,A.,Thin Films.New York,Academic Press,1995,20
[25]Sagiv,J.,Organized monolayers by adsorption.1.Formation and structure ofoleophobic mixed monolayers on solid surfaces[J].J.Am.Chem.Soc.,1980,102:92-98
[26]Nuzzo,R.G.,Allara,D,L.,Adsorption of bifunctional organic disulfides on gold surfaces[J].J.Am.Chem.Soc.,1983,105:4481-4483
[27]Iler,R,L.,Multimayers of colloidal particles,J Colloid Interface Sci.[J],1966,21(6):569-594
[28]Kamineni,V.K.,Lvov,Y.M.,Dobbins,T.A.Layer-by-Layer Nanoassembly of Polyelectrolytes Using Formamide as the Working Medium[J].Langmuir,2007,23,7423-7427
[29]Samokhina,L.,Schrinner,M.,Ballauff,M.,Drechsler,M.Binding of Oppositely Charged Surfactants to Spherical Polyelectrolyte Brushes:A Study by Cryogenic Transmission Electron Microscopy[J].Langmuir 2007,23,3615-3619
[30]Ferreira,M.,Cheung,J.H.,Rubner,M.F.,Molecular self-assembly of conjugated polyions:a new process for fabricating multilayer thin film heterostructures[J].Thin solid Films,1994,244:806-809
[31]Cooper,T.,Campbell,A.,Crane,R.Formation ofpolypeptide-dye multilayers by electro static self-assembly technique[J].Langmuir 1995,11,2713-2718
[32]Kozt,J.,Kosmella,S.,Beitz,T.,Self-assembled polyelelctrolyte systems[j].Prog.Polym.Sci.,2001,26:1199-1232
[33] Saremi, F., Lange, G.., Tieke, B., Deeply colored self-assembled multilayers of anionic DPP bolamphiphiles and cationic polyelectrolytes [J]. Adv. Mater. 1996, 8, 923-926
[34] Ariga, K., Lvov, Y., Kunitake, T., Assembling alternate dye-polyion molecular films by electrostatic layer-by-layer adsorption[J]. J. Am. Chem. Soc. 1997, 119, 2224-2231
[35] Donth, E., Walther, D., Shilov, V. N., Kanippel, E., Budde, A., Lowack, K., Helm, C. A., Moehwald, H., Nonlinear Hairy Layer Theory of Electrophoretic Fingerprinting Applied to Consecutive Layer by Layer Polyelectrolyte Adsorption onto Charged Polystyrene Latex Particles[J]. Langmuir 1997,13, 5294-5305
[36] Kong, W., Zhang, X., Gao, M. L., Zhou, H., Li, W., Shen, J.C., A new kind of immobilized enzyme multilayer based on cationic and anionic interaction[J]. Macromol. Rapid Commun., 1994,15:405-409
[37] Lvov, Y., Lu, Z., Schenkman, J. B., Zu, X., Rusling, J.F., Direct electrochemistry of myoglobin and cytochrome P450cam in alternate layer-by-layer films with DNA and other polyions [J]. J. Am. Chem. Soc, 1998,120:4073-4080
[38] Zhou, Y. L., Li, Y.Z., Layer-by-layer self-assembly of multilayer films containing DNA and Eu~(3+): their characteristics and interactions with small molecules[J]. Langmuir, 2004, 20: 7208-7214
[39]Dootz, R., Nie, J., Du, B., Herminghaus, S., Pfohl, T., Raman and Surface Enhanced Raman Microscopy of Micro structured Polyethylenimine/DNA Multilayers [J]. Langmuir 2006, 22,1735-1741
[40] Lvov, Y., Haas, H., Decher, G., Mohwald, H., Mikhailov, A., Mtchedlishvily, B., Morgunova, E., Vainshtein, B., Successive deposition of alternate layers of polyelectrolytes and a charged virus[J]. Langmuir, 1994,10: 4232-4236
[41] Lvov, Y., Ariga, K., Ichinose, I., Kunitake, T., Assembly of multicomponent protein films by means of electrostatic layer-by-layer adsorption[J]. J. Am. Chem. Soc., 1995,117:6117-6123
[42] Forzani, E.S., Perez, M.A., Teijelo, M.L., Calvo, E.J., Redox driven swelling of layer-by-layer enzyme-polyelectrolyte multilayers[J]. Langmuir, 2002,18: 9867-9873
[43] Kong, W., Wang, L. P., Gao, M.L., Zhou, H., Zhang, X., Li, W., Shen, J.C., Immobilized bilayer glucose isomerase in porous trimethylamine polystyrene based on molecular deposition[J]. J. Chem. Soc. Chem., Commun., 1994,1297-1300
[44] Caruso, F., Hollow capsule processing through colloidal templating and self-assembly [J]. Chem Eur J 2000,6: 413-419
[45] Caruso, F., Nanoengineering of particle surfaces[J]. Adv Mater 2001,13:11-22
[46] Caruso, F., Caruso, R.A., Mohwald. H., Nanoengineering of inorganic and hybrid hollow spheres by colloidal templating [J]. Science 1998,282:1111-1114
[47] Donath, E., Sukhorukow, G.B., Caruso, F., Davis, S.A., Mo¨hwald, H., Novel hollow polymer shells by colloidtemplated assembly of polyelectrolytes[J]. Angew Chem Int Ed 1998,37:2201-2205
[48] Wu, Z. Y., Guan, L. N.,Shen G. L.,Yu, R.,Renewable urea sensor based on a self-assembled polyelectrolyte layer[J]. Analyst, 2002,127: 391-395
[49] Lowack, K., Helm, C. A., Molecular mechanisms controlling the self-assembly process of polyelectrolyte multiayers[J].Macromolecules, 1998,31(3):823-833
[50] Wang, L.Y., Wang, Z.Q., Zhang. X., Shen, J.C., Chi. L.F., Fuchs, H., Anew approach for the fabrication of an alternating multilayer film of poly(4-vinylpyridine) and poly(acrylic acid) based on hydrogen bonding[J]. Macromol. Rapid Commun., 1997,18: 509-514
[51] Stockton, W.B., Rubner, M.F., Molecular-level processing of conjugated polymers. 4. layer-by-layer manipulation of polyaniline via hydrogen-bonding interactions[J]. Macromolecules, 1997, 30:2717-2725
[52] Wang, L.Y., Fu, Y, Wang, Z.Q., Fan, Y,G,., Zhang, X., Investigation into an alternating multilayer film of poly(4-vinylpyridine) and poly(acrylic acid) based on hydrogen bonding[J]. Langmuir, 1999,15:1360-1363
[53]Lee, H., Kepley, L.J., Hong, H.G., Akhter, S., Mallouk, T.E., Adsorption oforderedzirconium phosphonate multilayer films on silicon and gold surfaces[J]. J. Phys.Chem., 1988,92: 2597-2601
[54]Mallouk, T.E., Gavin, J.A., Molecular recognition in lamellar solids and thin films[J]. Acc.Chem.Res.,1998,31: 209-217
[55]Cao, G.., Hong, H-G., Mallouk, T.E., Layered metal phosphates and phosphonates: from crystals to monolayers[J]. Acc.Chem.Res., 1992,25:420-427
[56] Kohli, P., Blanchard, G.J., Design and growth of robust layered polymer assemblies with molecular thickness control[J]. Langmuir, 1999, 15: 1418-1422
[57] Kohli, P., Blanchard, G.J., Probing interfaces and surface reactions of zirconium phosphate/phosphonate multilayers using P NMR spectrometry[J]. Langmuir, 2000,16: 695-701
[58] Kohli, P., Blanchard, G. J., Design and demonstration of hybrid multilayerstructures: layer-by-layer mixed covalent and ionic interlayer linking chemistry[J]. Langmuir, 2000, 16: 8518-8524
[59] Major, J.S., Blanchard, G.J., Covalently bound polymer multilayers for efficient metal ion sorption [J]. Langmuir, 2001, 17: 1163-1169
[60] Shimazaki, Y., Mitsuishi, M., Ito, S., Yamamoto, M., Preparation and characterization of the Layer-by-layer deposited ultrathin film based on the charge-transfer interaction in orgnaic solvents [J]. Langmuir, 1998,14,2768
[61] Shimazaki, Y., Mitsuishi, M., Ito, S., Yamamoto, M., Alternate adsorption of polymers on a gold surface through the charge-transfer interaction [J]. Macromolecules, 1999, 32, 8220-8223
[62]Shimazaki.Y.,Mitsuishi,M.,Ito,S.,Yamamoto,M.,Inaki,Y.,Preparation of the nucleoside-containing nanolayered film by the layer-by-layer deposition technique[J].Thin Solid Films,1998,333,5-8
[63]Cochin,D.,Laschewsky,A.,Layer-by-layer self-assembly of hydrophobically modified polyelectrolytes[J].Macromolecular Chemsitry and Physics,1999,200,609-615
[64]Kotov N.A.,Layer-by-layer self-assembly:The contribution of hydrophobic interactions Nanostructrued Mater.,1999,12,789-796
[65]Dubas,S.,Joseph,T.,Schlenoff,B.,Factors of controlling the growth of polyelectrolyte multilayers[J].Macromolecules 1999,32,8153-8160
[66]Alexei A.Antipov,Gleb B.Sukhorukov,H.Mohwald.Influence of the ionic strength on the polyelectrolyte multilayers' permeability[J].Langmuir 2003,19,2444-2448
[67]Svetlana A.Sukhishvili,Eugenia Kharlampieva,Vladimir Izumrudov.Where polyelectrolyte multilayers and polyelectrolyte complexes meet[J].Macromolecules 2006,39,8873-8881
[68]Clark,S.L.,Montague,M.F.,Hammond,P.T.,The effect of ion type and ionic content on templating patterned ionic multilayers[J].Acs.Sym.Ser,1998,695:206-219
[69]陈幼芳.疏水性药物微胶囊的自组装构筑及其缓释性能研究[博士论文].杭州:浙江大学.2006
[70]Ruths,J.,Essler,F.,Decher,G.,Riegler,H.,Polyelectrolytes I:polyanion/polycation multilayers at the air/monolayer/water interface as elements for quantitative polymer adsorption studies and preparation of hetero-superlattices on solid surfaces [J].Langmuir,2000,16:8871-8878
[71]Lavalle R,Gergely C.,Cuisinier F.J.G.,Decher,G.,Schaaf,P.,Voegel,J.C.,Picart,C.,Comparison of the structure ofpolyelectrolyte multilayer films exhibiting a linear and an exponential growth regime:An in situ atomic force microscopy study[J].Macromolecules,2002,35:4458-4465
[72]Schoeler,B.,Kumaraswamy,G.,Caruso,F.,Investigation of the influence of polyelectrolyte charge density on the growth of multilayer thin films prepared by the layer-by-layer technique[J].Macromolecules,2002 35(3):889-897
[73]Fleer,G.,Hoogeveen,N.G.,Cohen Stuart,M.A.,Bohmer,M.R.,Formation and stability ofmultilayers ofpolyelectrolytes[J].Langmuir 1996,12,3675-3681
[74]Hoogeveen,N.G.,Cohen Stuart,M.A.,Fleer,G.,Polyelectrolyte adsorption on oxides.I.Kinetics and adsorbed amounts[J].J.Colloid Interface Sci.1996,182,133-145
[75]Arys,X.,Jonas,A.M.,Laguitton,B.,Legras,R.,Laschewsky,A.,Wischerhoff, E.,Structural studies on thin organic coatings built by repeated adsorption of polyelectrolytes[J].Prog.Org.Coat.1998,34,108-118
[76]Bertrand,P.,Jonas,A.,Laschewsky,A.,Legras,R.Ultrathin polymer coatings by complexation of polyelectrolytes at interfaces:suitable materials,structure and properties[J].Macromol.Rapid Commun.2000,21,319-348
[77]Fischer,P.,Laschewsky,A.,Wischerhoff,E.,Arys,X.,Jonas,A.,Legras,R.,Polyelectrolytes bearing azobenzenes for the functionalization of multilayers[J].Macromol.Symp.1999,137,1-8
[78]Shiratori,S.S.,Rubner,M.F.,pH-Dependent thickness behavior of sequentially adsorbed layers of weak polyelectrolytes[J].Macromolecules 2000,33,4213-4219
[79]Krasemann,L.,Toutianoush,A.,Tieke,B.,Self-assembled polyelectrolyte multilayer membranes with highly improved pervaporation separation of ethanol/water mixtures[J].J.Membr.Sci.2001,181:221-228
[80]Dobrynin,A.V.,Rubinstein,M.,Obukhov,S.P.,Cascade of transitions of polyelectrolytes in o poor solvents[J].Macromolecules 1996,29,2974-2979
[81]Lyulin,A.V.,Dunweg,B.,Borisov,O.V.,Darinskii,A.A.,Computer simulation studies of a single polyelectrolyte chain in poor solvent [J].Macromolecules 1999,32,3264-3278
[82]Micka,U.,Holm,C.,Kremer,K.,Strongly charged flexible polyelectrolytes in poor solvents:molecular dynamics simulations[J].Langmuir 1999,15,4033-4044
[83]Poptoshev,E.,Schoeler,B.,Caruso,F.,Influence of solvent quality on the growth ofpolyelectrolyte multilayers[J].Langmuir 2004,20:829-834
[84]Serizawa,T.,Satoko,K.,Kawanishi,N.,Akashi,M.,Layer-by-layer assembly of poly(vinyl alcohol)and hydrophobic polymers based on their physical adsorption on surfaces[J].Langmuir,2002,18:8381-8385
[85]何曼君 高分子物理.上海:复旦大学出版社.2005
[86]Salomaki,M.,Vinokurov,I.A.,Kankare,J.,Effect of temperature on the buildup ofpolyelectrolyte multilayers[J].Langmuir 2005,21:11232-11240
[87]Sui,Z.J.,Salloum,D.,Schlenoff,J.B.,Effect of molecular weight on the construction of polyelectrolyte multilayers:stripping versus sticking[J].Langmuir 2003,19,2491-2495
[88]Lenk,T.J.,Hakknarj V.M.,Rabolt J.F.,Haeussling,L.,Ringsdorf,H.,Formation and characterization of self-assembled films of sulfur-derivatized poly(methyl methacrylates)on gold[J].Macromolecules,1993,26(4):1230-1237
[89]江秀明.聚电电解多层膜构筑及其表面HRP应用组装基础研究[博士论文].杭州:浙江大学.2005
[90]Gao,C.Y.,Leporatti,S.,Moya,S.,Donath,E.,Mohwald,H.,Stability and mechanical properties of polyelectrolyte capsules obtained by stepwise assembly of poly(styrenesulfonate sodium salt)and poly(diallyldimethyl ammonium)chloride onto melamine resin particles[J].Langmuir,2001,17(11):3491-3495
[91]Gao,C.,Donath,E.,Moya,S.,Dudnik,V.,Mohwald,H.,Elasticity of hollow polyelectrolyte capsules prepared by the layer-by-layer technique[J].Eur.Phys.J.E,2001,5(1):21-27
[92]DeLongchamp,D.M.,Kastantin,M.,Hammond,P.T.,High-contrast electrochromism from layer-by-layer polymer films[J].Chem.Mar.,2003,15(8):1575-1586
[93]Cho,J.,Char,K.,Kim,D.Y.,Change in the quantum efficiency due to relative thickness variation of hole transport and emitting layers in a self-assembled device[J].Thin Solid Films,2002,415(1-2):303-307
[94]Baur,J.W.,Baur,J.W.,Balanda,P.B.,Thin-film light-emitting devices based on sequentially adsorbed multilayers of water-soluble poly(p-phenylene)s[J].Adv.Mater.,1998,10(17):1452-1455
[95]Wu,A.,Yoo,D.,Lee,J.K.,Rubner,M.F.,Myocardial production of aldosterone and corticosterone in the rat[J].J.Ant.Chem.Soc.,1999,121(20):4883-4891
[96]Han,S.,Briseno,A.L.,Shi,X.,Mah,D.A.,Zhou,F.,Polyelectrolytecoated nanosphere lithographic patterning of surfaces:fabrication and characterization of electropolymerized thin polyaniline honeycomb films[J].J Phys Chem B 2002,106:6465-6472
[97]Wang,D.Y.,Caruso,R.A.,Caruso.F.,Synthesis of macroporous titania and inorganic composite materials from coated colloidal spheres—a novel route to tune pore morphology[J].Chem Mater 2001,13:364-371
[98]Krasemarm,L.,Tieke,B.,Ultrathin self-assembled polyelectrolyte membranes for pervaporation[J].J.Membr.Sci.1998,150:23-30
[99]Krasemann,L.,Toutianoush,A.,Tieke,B.,Slef-assembled polyelectrolyte mutilayer membranes with highly improved pervaporation separation of ethanol/water mixtures[J].J.Membr.Sci.2001,181:221-228
[100]Toutianoush,A.,Tieke,B.,Pervaporation separation of alcohol/water mixtures using self-assembled polyelectrolyte multilayer membranes of high charge density[J].Mater.Sci.Eng.,C 2002,22:459-463
[101]Meier-Haack,J.,Lenk,W.,Lehmann,D.,Lunkwitz,K.,Pervaporation separation of water/alcohol mixtures using composite membranes based on polyelectrolyte multilayer assemblies[J].J.Membr.Sci.2001,184:233-243
[102]E1-Hashani,A.,Toutianoush,A.,Tieke,B.,Layer-by-layer assembled membranes of protonated 18-azacrown-6 and polyvinylsulfate and their application for highly efficient anion separation[J].J.Phys.Chem.B 2007,111:8582-8588
[103]Krasemann,L.,Tieke,B.,Selective ion transport across self-assembled alternating multilayers of cationic and anionic polyelectrolytes[J].Langmuir 2000,16:287-290
[104]Harris,J.J.,Stair,J.L.,Bruening,M.L.,Layered polyelectrolyte films as selective,ultrathin barriers to anion transport[J].Chem.Mater 2000,12:1941-1946
[105]Toutianoush,A.,Tieke,B.,In novel methods to study interfacial layers,Moebius,D.,Miller,R.,Eds.,Studies in Surface Science Series,Amsterdam:Elsevier,2001,p416
[106]Stair,J.L.,Harris,J.J.,Bruening,M.L.,Uniaxial alignment of polycyclic aromatic hydrocarbons by solution processing[J].Chem.Mater.2001,13:2641-2647
[107]Jin,W.,Toutianoush,A.,Tieke,B.,Use of polyelectrolyte layer-by-layer assemblies as nanofiltration and reverse osmosis membranes[J].Langmuir 2003,19:2550-2553
[108]Toutianoush,A.,Jin,W.,Deligoz,H.,Tieke,B.,Polyelectrolyte multilayer membranes for desalination of aqueous salt solutions and seawater under reverse osmosis conditions[J].Appl.Surf.Sci.2005,246:437-443
[109]Jin,W.,Toutianoush,A.,Tieke,B.,Size- and charge-selective transport of aromatic compounds across polyelectrolyte multilayer membranes[J].Appl.Surf.Sci.2005,246:444-450
[110]Tieke,B.,Toutianoush,A.,Jin,W.Q.,Selective transport of ions and molecules across layer-by-layer assembled membranes of polyelectrolytes,p-sulfonato-calix[n]arenes and Prussian Blue-type complex salts[J].Advances in Colloid and Interface Science,2005,116:121-131
[111]Juha-Matti,L.,Thomas,J.M.,Poly(4-methyl-1-pentene)-supported polyelectrolyte multilayer films:preparation and gas permeability[J].Macromolecules 1997,30:1752-1757
[112]时钧,袁权,高丛楷,膜技术手册,化学工业出版社,北京,2001.
[113]刘茉娥,陈欢林.新型分离技术基础.浙江大学出版社.浙江,1999.
[114]郑领英,王雪松.膜技术.化学工业出版社,北京,2000.
[115]白云翔.共聚物渗透汽化膜的制备、结构及分离水中微量有机物性能的研究[博士论文].杭州:浙江大学.2006
[116]胡云光.膜生物反应器在石油化工中的应用.石油化工,1994,6:400-406
[117]薛德明.膜分离技术在医药食品工业中的应用.中国海洋药物,1994,5:247-253
[118]尹沛松.微孔膜滤器在医药工业中的应用.过滤与分离,1998,4:32-34
[119]顾瑾,郑成.膜分离在生物工程应用中存在的问题及对策.合肥工业大学学报(自然科学版),1998,2:102-108
[120]徐又一.聚烯烃中空纤维膜及其分离新技术在环保工程中的开发、应用.中国环保产业,1996,Z1:38-40
[121]Abraham,K.M.,Alamgir,M.,Hoffman,D.K.,Polymer electrolytes reinforced by Celgard membrane[J].J.Electroehem.Soc.,1995,142:683-687
[122]孙晓辉,郝建飞,王竞.膜技术在醋酸生产中的应用.中国调味品,1995,4:6-7
[122]于丁一,陈培祺,呼丙辰.我国膜法海水淡化技术现状与发展前景.给水排水,1994,8:15-18
[123]徐又一,徐志康.高分子膜材料.化学工业出版社,北京,2005.
[124]Mulder,M.,李琳译,膜技术基本原理,清华大学出版社,北京,1999.
[125]Kober,P A.,Pervaporation,perstillation and percrystallisation[J].J.Am.Chem.Soc.1917,39:944-948
[126]Rautendach,R.,Albecht,R.,Membrane Processes.New York:John Wiley Sons,1989
[127]Huang,R Y M.,ed,Pevaporation Membrane separation Processes.Amsterdam:Elsevier,1991
[128]Ho,W.S.W.,Sirkar,K.K.,ed.Membrane Handbook.New York:Van Nostrand Reinold,1992
[129]刘茉娥.膜分离技术.北京:化学工业出版社,1998
[130]Bining,R.C.,James,E E.,New sepatate by membrane permeate[J].Petrol Refiner,1958,37(5):214-215
[131]Bining,R.C.,James,F.E.,Sepatation by membrane permeate[J].Oil Gas J.1958,56(21):104-105
[132]Neel,J.,Nguyen,Q.T.,Clement,R.,Le Blanc,L.,Fractionation of a binary liquid mixture by continuous pervaporation[J].J.Membr.Sci.1983,15:43-62
[133]Rautenbach,R.,Albrecht,R.,Separation of organic binary mixtures by pervaporation[J].J.Membr.Sci.1980,7:203-223
[134]Rautenbach,R.,Albrecht,R.,On the behaviour of asymmetric membranes in pervaporation[J].J Membr Sci.1984,19:1-12
[135]Schmittecker,B.,Lichtenthaler,R,N.,Proceeding of the 1~(st)international conference on pervaporation in the chemical industry[J].Bakish Red.Atlanta,Georgia:1986.96-100
[136]Bruschke H D.EP 0096340.1983
[137]Bruschke H D.EP 0096339.1983
[138]陈翠仙,韩宾兵,朗宁威.渗透蒸发和蒸汽渗透.北京:化学工业出版社,2004
[139]Bining R.C.,James F.E.,Now separate by membrane permeation[J].Petrol. Refiner., 1958, 37: 214-215
[140] Bining R.C., James F.E., Separation by membrane permeate [J]. Oil gas J., 1958, 56:104-105
[141]Lipnizkia, F., Hausmannsb, S., Tena, P. K., Fielda, R.W., Organophilic pervaporation: prospects and performance [J]. Chem. Eng. J., 1999,73:113-29
[142] Baker, R.W., Cussler, E. L, Membrane separation systems: Recent development and future directions. New Jersey: Noyes Data Corporation, 1991, 56-85.
[143] Krasemann, L., Kompositmembranen mit selbstorganisierter, Dissertation, University zu Koln, 1999
[144] Zhu, Z., Feng, X., Penlidis, A., Self-assembled nano-structured polyelectrolyte composite membranes for pervaporation [J]. Mater. Sci. Eng. C. 2006,26: 1-8
[145] Zhang, G. J., Gu, W. L., Ji, S. L., Liu, Z. Z., Peng, Y. L., Wang, Z., Preparation of polyelectrolyte multilayer membranes by dynamic layer-by-layer process for pervaporation separation of alcohol/water mixtures[J]. J. Membr. Sci. 2006, 280: 727-733.
[146] Zhang, G. J., Yan, H. H., Ji, S. L., Liu, Z. Z., Self-assembly of polyelectrolyte multilayer pervaporation membranes by a dynamic layer-by-layer technique on a hydrolyzed polyacrylonitrile ultrafiltration membrane[J]. J. Membr. Sci. 2007, 292: 1-8
[147] Salomaki, M., Tervasmaki, P., Areva, S. and Kankare, J., The hofmeister anion effect and the growth of polyelectrolyte multilayers [J]. Langmuir, 2004, 20: 3679-3683
[148] Salomaki, M., Vinokurov, I. A., Kankare, J., Effect of temperature on the buildup of polyelectrolyte multilayers [J]. Langmuir, 2005,21:11232-11240
[149] Yang, S., Zhang, Y., Zhang, X., Xu, J., The influence of pH on a hydrogen-bonded assembly film [J]. Soft Matter, 2007, 3:463-469
[150] Bai, Y. X., Qian, J. W., An, Q. F., Zhu, Z. H., Zhang, P., Pervaporation characteristics of ethylene-vinyl acetate copolymer membranes with different composition for recovery of ethyl acetate from aqueous solution[J]. J. Membr. Sci. 2007,305:152-159
[151] Qian, J. W., Zhou, G.. H., Li, J., Yang, W. Y., Conformational inversion of olyethylene-polyvinyl acetate graft copolymer in selective solvent by viscometry [J]. Eur. Polym. J. 2001, 37: 1871-1875
[152] Sauerbrey, G. Z., The use of quartz oscillators for weighing thin layers and microweighing [J]. Phys. 1959, 155,206-222
[153] Lvov, Y., In protein architecture: Interfacing molecular assembliesand immobilization biotechnology, Lvov, Y, Mohwald, H., Eds., Marcel Dekker: New York, 2000, pp 125-166
[154] Ghimici, L., Dragan, S., Behaviour of cationic polyelectrolytes upon binding of electrolytes:effects of polycation structure,counterions and nature of the solvent[J].Colloid.Polym.Sci.,2002,280:130-134
[155]Yan.X.J.,Deng,Y.H.,Wang,X.G.,pH effect on electrostatic layer-by-layer self-assembly of a side-chain azo polyelectrolyte[J].Acta Polymerica Sinica,2007,5:440-445
[156]陈幼芳,钱锦文,杨平,林贤福,PSS/PDDA自组装膜形成过程中的临界浓度效应.高等学校化学学报,2005,26:787-789
[157]Nakata,M.,Nakano,Y.,Kawate,K.,Light-scattering study of three-component systems 3:0 Point for poly(methyl methacrylate)in the binary mixture 1-chlorobutane +2-butanol[J].Macromolecules,1988,21:2509-2514
[158]朱平平,任琳,杨海洋,刘远立,混合溶剂中高分子的尺寸,功能高分子学报,2003,16:261-268
[159]Tan,H.L.,McMurdo,M.J.,Pan,G.,Van Patten,P.G.,Temperature dependence of polyelectrolyte multilayer assembly[J].Langmuir,2003,19:9311-9314
[160]Buscher,K.,Graf,K.,Ahrens,H.,Helm,C.A.,Influence of adsorption conditions on the structure of polyelectrolyte multilayers[J].Langmuir,2002,18:3585-3591
[161]Leporatti,S.,Gao,C.,Voigt,A.,Donath,E.,Mohwald,H.,Elasticity of hollow polyelectrolyte capsules prepared by the layer-by-layer technique[J].Eur.Phys.J.E.,2001 5:13-21
[162]McAloney,R.A.,Dudnik,V.,Goh,M.C.,Kinetics of salt-induced annealing of a polyelectrolyte multilayer film morphology[J].Langmuir,2003,19:3947-3952
[163]Steitz,R.,Jaeger,W.,Von Klitzing,R.,Influence of charge density and ionic strength on the multilayer formation of strong polyelectrolytes[J].Langmuir 2001,17:4471-4474
[164]Stockton,W.B.,Rubner,M.F.,Molecular-level processing of conjugated polymers.3.layer-by-layer manipulation of polyaniline via electrostatic interactions [J].Macromolecules 1997,30:2712-2716
[165]Fu,Y.,Chen,H.,Qiu,D.L.,Wang,Z.Q.,Zhang,X.,Multilayer assemblies of poly(4-vinylpyridine)and poly(acrylic acid)bearing photoisomeric spironaphthoxazine via hydrogen bonding[J].Langmuir 2002,18:4989-4995
[166]Zhang,H.Y.,Wang,D.,Wang,Z.Q.,Zhang,X.,Hydrogen bonded layer-by-layer assembly of poly(2-vinylpyridine)and poly(acrylic acid):Influence of molecular weight on the formation of microporous film by post-base treatment[J].Eur.Polym.J.2007,43:2784-2791
[167]Sukhishvili,S.A.,Granick,S.,Investigation of the influence ofpolyelectrolyte charge density on the growth of multilayer thin films prepared by the layer-by-layer technique[J].Macromolecules 2002,35:889-897
[168]Lvov,Y.,Ariga,K.,Kunitake,T.Formation of ultrathin multilayer and hydrated gel from montmorillonite and linear polycations[J].Langmuir 1996,12:3038-3044
[169]Caruso,F.,Furlong,D.N.,Ariga,K.,Ichinose,I.,Kunitake,T.,Characterization of polyelectrolyte-protein multilayer films by atomic force microscopy,scanning electron microscopy,and fourier transform infrared reflection-absorption spectroscopy[J].Langmuir 1998,14:4559-4565
[170]Onda,M.,Ariga,K.,Kunitake,T.J.,Activity and stability of glucose oxidase in molecular films assembled alternately with polyions[J].Biosci.Bioeng.1999,87:69-75
[171]宣理静,钱锦文,陈幼芳,张鹏,化学进展,2006,18:950-956
[172]Ackern,F.V.,Krasemann,L.,Tieke,B.,Ultrathin membranes for gas separation and pervaporation prepared upon electrostatic self-assembly of polyelectrolytes[J].Thin Solid Films,1998,327-329:762-766
[173]Dobrynin,A.V.,Rubinstein,M.,Adsorption of hydrophobic polyelectrolytes at oppositely charged surfaces[J].Macromolecules,2002,35:2754-2768
[174]Zhang,H.,Wang,Z.,Zhang,Y.,Zhang,X.,Hydrogen-bonding-directed layer-by-layer assembly of poly(4-vinylpyridine)and poly(4-vinylphenol):Effect of solvent composition on multilayer buildup[J].Langmuir 2004,20:9366-9370
[175]Wang,H.,He,Y.,Yuo,X.,Wang,X.,Sequentially adsorbed electrostatic multilayers of branched side-chain polyelectrolytes bearing donor-acceptor type azo chromophores[J].Macromolecules 2004,37:135-146
[176]Hong,J.,Jung,B.,Kim,C.H.,Kim,K.,Effects of spacer chain lengths on layered nanostructures assembled with main-chain azobenzene ionenes and polyelectrolytes[J].Macromolecules 2000,33:7905-7911
[177]代化,管蓉,汪丽娟,燃料电池用磺化聚砜类质子交换膜研究,化学进展,2006,18,:36-44
[178]Brandrup,J.,Immergut,E.H.,Grulke,E.A.,Polymer Handbook(Fourth Edition)1999 Ⅶ 498
[179]Scharlin,E,Steinby,K.,Domanska,U.J.,Volumetric properties of binary mixtures of N,N-dimethylformamide with water or water-d_2 at temperatures fi'om 277.13 Kto 318.15 K[J].Chem.Thermodynamics 2002,34:927-957
[180]Bougard,J,Jadot,R.,Octamethylcyclotetrasiloxane azeotropes[J].J.Chem.Thermodynamics 1975,7:1185-1194
[181]Garcia,B.,Alcalde,R.,Leal,J.M.,Matos,J.S.,Solute-solvent interactions in amide-water mixed solvents[J].J.Phys.Chem.B 1997,101:7991-7997
[182]雷毅.生物素的全合成及其结构—功能关系研究[博士论文].杭州:浙江大学.2004
[183]Lei,Y.,Li,H.,Pan,H.,Han,S.,Structures and hydrogen bonding analysis of N,N-dimethylformamide and N,N-dimethylformamide-water mixtures by molecular dynamics simulations[J].J.Phys.Chem.A2003,107:1574-1583
[184]Yoo,D.,Shiratori,S.S.,Rubner,M.F.,Controlling bilayer composition and surface wettability of sequentially adsorbed multilayers of weak polyelectrolytes [J].Macromolecules 1998,31:4309-4318
[185]Chalaris,M,Koufou,A,Samios,J.Molecular dynamics simulations of the liquid mixtures N,N-dimethylformamide-water using available potential models[J].Journal of Molecular Liquids 2002,101:69-79
[186]董永全,张林,侯同刚,陈欢林.高等学校化学学报,2007,28(12):2422-2426
[187]李晓东,沈家骢,高等学校化学学报,2007,28(10):2000-2005
[188]杨晓峰,李晓东,沈家骢.高等学校化学学报[J],2007,28(5):974-977
[189]Zhang,P.,Qian J.W.,An Q.F.,Du,B.,Liu,X.Q.,Zhao,Q.,Influences of solution property and charge density on the self-assembly behavior of water-insoluble polyelectrolyte sulfonated poly(sulphone)sodium salts[J].Langmuir,2008,24:2110-2117
[190]Krasemann L.,Tieke B.,Ultrathin self-assembled polyelectrolyte membranes for pervaporation[J].J.Membr.Sci.1998,150:23-30
[191]Krasemann L.,Toutianoush A.,Tieke B.Self-assembled polyelectrolyte multilayer membranes with highly improved pervaporation separation of ethanol/water mixtures[J].J.Membr.Sci.2001,181:221-228
[192]Zhu Z.Q.,Feng X.S.,Penlidis A.Self-assembled nano-structured polyelectrolyte composite membranes for pervaporation[J].Mater.Sci.Eng.C 2006,26:1-8
[193]Zhang,P,Qian,J.W.,Yang,Y.,Bai Y.X.,An,Q.F.,Yan,W.D.,Swelling behavior of palygorskite-polyacrylamide hybrid membrane in xylene mixtures and its pervaporation performance for separating the xylene isomers[J].J.Membr.Sci.2007,288:280-287
[194]Toutianoush A.,Krasemann L.,Tieke B.,Polyelectrolyte multilayer membranes for pervaporation separation of alcohol/water mixtures[J].Colloids Surf.A 2002,198-200:881-889
[195]Zhao Q.,Qian J.W.,An Q.F.,Zhu,Z.H.,Zhang,Peng.,Bai,Y.X.,Studies on pervaporation characteristics of polyacrylonitrile-b-poly(ethylene-glycol)-b-polyacrylonitrile block copolymer membrane for dehydration of aqueous acetone solutions[J].J.Membr.Sci.2008,311:284-293
[196]Klitzingl,R.,Tieke,B.,Polyelectrolyte membranes[J].Adv.Polym.Sci.2004,165:177-210
[197]Zhao,Q.,Qian,J.w.,An,Q.F.,Zhu,Z.H.,Zhang,P.,Bai,Y.X.,Studies on pervaporation characteristics of polyacrylonitrile-b-poly(ethylene glycol)-b- polyacrylonitrile block copolymer membrane for dehydration of aqueous acetone solutions[J]. J. Membr. Sci. 2008,311: 284-293
[198] Bai, Y. X., Qian, J. W., An, Q. F, Zhu, Z. H., Zhang, P, Pervaporation characteristics of ethylene-vinyl acetate copolymer membranes with different composition for recovery of ethyl acetate from aqueous solution[J]. J. Membr. Sci. 2007,305: 152-159
[199] Xiao, S., Feng, X. S., Huang, R. Y.M., Trimesoyl chloride crosslinked chitosan membranes for CO_2/N_2 separation and pervaporation dehydration of isopropanol[J]. J. Membr. Sci. 2007, 306: 36-46
[200] Dobrynin, A. V., Rubinstein, M., Theory of polyelectrolytes in solutions and at surfaces [J]. Prog. Polym. Sci. 2005, 30:1049-1118
[201] Besra, L., Liu, M. L., A review on fundamentals and applications of electrophoretic deposition (EPD) [J]. Progress in Materials Science 52,2007: 1-61
[202] Zhang, G. J., Gao, X., Ji, S. L., Liu, Z. Z., Electric field-improved assembly of polyelectrolyte composite membranes[J]. J. Membr. Sci. 307,2008:151-155
[202] Ray, S.K., Sawant, S.B., Joshi, J.B., Pangarkar, V.G., Development of new synthetic membranes for separation of benzene-cyclohexane mixtures by pervaporation: a solubility parameter approach [J]. Ind. Eng. Chem. Res., 1997, 36: 5265-5276
[203] Huang R.Y.M., Pal R., Moon G.Y., Pervaporation dehydration of aqueous ethanol and isopropanol mixtures through alginate/chitoson two composite membranes supported by poly(vinylidene fluoride) porous membrane[J]. J. Membr. Sci, 2000,167: 275-289
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