大型氯化胆碱粉剂制备技术及成套装置的研究与应用
摘要
氯化胆碱是动物生长不可缺少的一种水溶性纤维素,在饲料产业中需求量巨大,氯化胆碱粉体干燥技术对于产品质量的保证和该行业的发展至关重要。本文以实现生产规模1.5万吨/年含量50%氯化胆碱粉剂制备装置的工业应用为目标,针对规模化氯化胆碱干燥技术及装备开发中存在的问题,进行了系统的技术研究和装备开发,研究内容主要包括以下四个方面:
1、对自清理回转圆筒干燥装置进行了系统的研究,对该装置的基本工作原理、筒体内的传质传热过程和抄板结构、链条结构及位置进行了分析研究,确定了自清理回转圆筒在氯化胆碱干燥中的工艺计算和设计方法。
2、通过实验研究确定实验技术路线。通过对氯化胆碱的小试、中试和工业化实验,研究不同的转速、风速、风温等对干燥过程的影响,确定了设计依据。装置确定了物料与热介质逆流接触、冷却采用水冷式回转圆筒的封闭干燥工艺。
3、在工艺研究和理论分析的基础上进行了装备研究开发。研究干燥机的结构,设计合理的抄板链条结构,选择合理的冷却设备,完成干燥机关键部件的确定,研制开发了节能、连续性好、安全稳定的大型氯化胆碱粉剂制备装置,很好的解决了热粘性氯化胆碱在干燥过程中的粘壁、搓球、结块、糊化变质的问题。技术在山东某公司进行了成功的生产应用,达到了预期的指标。
4、进行了大型氯化胆碱粉剂制备技术与装备的工业应用研究。结合工程应用对技术和装备的可行性和经济评价进行了分析,确立了进一步市场应用推广的基础。
本研究将自清理回转干燥机用于具有热敏性物料氯化胆碱粉剂的干燥,干燥强度大,解决了粉剂氯化胆碱在干燥过程中的问题,取得了较好的经济效益和社会效益。
Choline Chloride animal growth is indispensable for a water-soluble cellulose, In great demand in the feed industry, Choline Chloride powder drying technology for product quality assurance and the development of the industry is essential. In this paper, in order to achieve the scale of production 15,000 tons per year of Choline Chloride powder in 50% of the industrial applications for the device target, in view of the scale of Choline Chloride drying technology and equipment development of the existing problems in a systematic and technology research and Equipment Development, Research includes the following four aspects:
1. Since the liquidation of the rotating cylinder drying devices on the system, the device's basic principle of cylinders in the mass transfer and heat transfer process copied board structure, the structure and location of the chain were analyzed to determine the clean-up since the rotary circle Choline Chloride in the drying cylinder in the method of calculation and design.
2. Experimental study determined through experiments technical route. Choline Chloride through the small test, trial and industrialization of experiments on different speed, the wind speed, air temperature, and so the impact of the drying process to determine the design basis. Identified the materials and devices medium heat countercurrent contact cooling water-cooled rotating cylinders closed drying process.
3. In process research and theoretical analysis on the basis of the research and development equipment. Dryer on the structure, design reasonable copy plate chain structure, a reasonable choice of the cooling equipment, the completion of key components of the dryer identification, research and development of energy-saving, continuity, and the security and stability of large-scale installations of Choline Chloride powder, good viscous solution of the heat in the drying process of Choline Chloride in the visco-wall, Guoqiu, caking, pasting the issue of eradicating corruption. Technology Ltd. in Shandong Aokete a successful production applications, thus achieving the expected targets.
4. A large-scale preparation of Choline Chloride powder technology and equipment, industrial applied research. Application of the technology and equipment of the evaluation of the feasibility and economic analysis, and established the further promotion of the basis of market applications.
1、对自清理回转圆筒干燥装置进行了系统的研究,对该装置的基本工作原理、筒体内的传质传热过程和抄板结构、链条结构及位置进行了分析研究,确定了自清理回转圆筒在氯化胆碱干燥中的工艺计算和设计方法。
2、通过实验研究确定实验技术路线。通过对氯化胆碱的小试、中试和工业化实验,研究不同的转速、风速、风温等对干燥过程的影响,确定了设计依据。装置确定了物料与热介质逆流接触、冷却采用水冷式回转圆筒的封闭干燥工艺。
3、在工艺研究和理论分析的基础上进行了装备研究开发。研究干燥机的结构,设计合理的抄板链条结构,选择合理的冷却设备,完成干燥机关键部件的确定,研制开发了节能、连续性好、安全稳定的大型氯化胆碱粉剂制备装置,很好的解决了热粘性氯化胆碱在干燥过程中的粘壁、搓球、结块、糊化变质的问题。技术在山东某公司进行了成功的生产应用,达到了预期的指标。
4、进行了大型氯化胆碱粉剂制备技术与装备的工业应用研究。结合工程应用对技术和装备的可行性和经济评价进行了分析,确立了进一步市场应用推广的基础。
本研究将自清理回转干燥机用于具有热敏性物料氯化胆碱粉剂的干燥,干燥强度大,解决了粉剂氯化胆碱在干燥过程中的问题,取得了较好的经济效益和社会效益。
Choline Chloride animal growth is indispensable for a water-soluble cellulose, In great demand in the feed industry, Choline Chloride powder drying technology for product quality assurance and the development of the industry is essential. In this paper, in order to achieve the scale of production 15,000 tons per year of Choline Chloride powder in 50% of the industrial applications for the device target, in view of the scale of Choline Chloride drying technology and equipment development of the existing problems in a systematic and technology research and Equipment Development, Research includes the following four aspects:
1. Since the liquidation of the rotating cylinder drying devices on the system, the device's basic principle of cylinders in the mass transfer and heat transfer process copied board structure, the structure and location of the chain were analyzed to determine the clean-up since the rotary circle Choline Chloride in the drying cylinder in the method of calculation and design.
2. Experimental study determined through experiments technical route. Choline Chloride through the small test, trial and industrialization of experiments on different speed, the wind speed, air temperature, and so the impact of the drying process to determine the design basis. Identified the materials and devices medium heat countercurrent contact cooling water-cooled rotating cylinders closed drying process.
3. In process research and theoretical analysis on the basis of the research and development equipment. Dryer on the structure, design reasonable copy plate chain structure, a reasonable choice of the cooling equipment, the completion of key components of the dryer identification, research and development of energy-saving, continuity, and the security and stability of large-scale installations of Choline Chloride powder, good viscous solution of the heat in the drying process of Choline Chloride in the visco-wall, Guoqiu, caking, pasting the issue of eradicating corruption. Technology Ltd. in Shandong Aokete a successful production applications, thus achieving the expected targets.
4. A large-scale preparation of Choline Chloride powder technology and equipment, industrial applied research. Application of the technology and equipment of the evaluation of the feasibility and economic analysis, and established the further promotion of the basis of market applications.
引文
[1]李宝春,王惠英,氯化胆碱几种常用测定方法之比较,中国饲料,2003,(4):23
[2]朱亚伟,周斌,氯化胆碱合成新工艺,化工生产与技术,2003,10,(5),15~17
[3]唐桂芬,兰尊海,彭爱娟,50%氯化胆碱粉剂中氯化胆碱含量的快速测定,饲料工业,1999,20(10):40~41
[4]邢召良,李铁,倪春琳等,50%粉剂氯化胆碱干燥工艺的选择,饲料工业,2007,28(9):1~3
[5]韩友文,胆碱和氯化胆碱,饲料博览,2004,(9):45~46
[6]常碧影,张丽英,当前氯化胆碱的质量与有关应用的几个问题,饲料广角,2004,(6):31~34
[7]高传慧,丁丽,郭传森等,反应萃取法生产氯化胆碱,当代化工,2006,35(6):380~385
[8]梁学庆,聂建荣,粉剂氯化胆碱含量的简易测定法,中国饲料,2002,(14):32~33
[9]韩书霞,林晶,粉剂氯化胆碱中三甲胺含量的测定,饲料研究,2005,(8):51~53
[10]徐淑倩,李跃,刘树年等,氯化胆碱的市场前景分析,饲料广角,2007,(10):16~17
[11]骆浩文,氯化胆碱的应用研究,饲料博览,2001,(1):10~11
[12]高占友,马玲,氯化胆碱粉剂含量测定的新方法,饲料研究,2000,(9):33~34
[13]王芬,氯化胆碱含量测定的几种方法与分析探讨,饲料广角,2002,(22):19~21
[14]厉风华,氯化胆碱含量测定方法探讨,湖南饲料,2003,(2):29~31
[15]唐执文,周永红,氯化胆碱含量测定方法探讨,中国饲料,2002,(10):18~20
[16]胡京枝,魏红,任红等,氯化胆碱含量常用测定方法比较,中国饲料,2003,(20):19~20
[17]张少钢,氯化胆碱合成反应的模拟及工艺条件优化,化学反应工程与工艺,2002,18(4),339~343
[18]徐永江,氯化胆碱合成模试试验,上海石油化工股份公司研究院, 1992
[19]崔玉民,杨高文,氯化胆碱合成工艺的研究,化学反应工程与工艺,2003,19(2),155~159
[20]常碧影,丁永胜,廖志勇等,饲料添加剂氯化胆碱中氯化胆碱的测定新国家标准的研制,中国饲料, 2002,(9): 23
[21]尹国强,崔英德,廖列文等,氯化胆碱合成工艺研究,广州化工,2000,28,(4)56~58
[22]刘艳,徐丽,李杰等,微囊化氯化胆碱的制备工艺,工艺与设备,2003,(9):21~22.
[23]史勇春,柴本银,中国干燥技术现状及发展趋势,通用机械,2006,(10): 10~14
[24]潘永康,中国现代干燥技术发展概况,第十届全国干燥会论文集,2005. 1~5
[25]伍沅,干燥技术的进展和应用,化学工程,1995,23(3):18~20
[26]刘广文,干燥设备选型及采购指南,北京:中国石化出版社,2004.
[27]曹恒武,干燥技术及其工业应用,北京:中国石化出版社,2003.
[28]黄志刚,毛志怀,转筒干燥器的现状及发展趋势,食品科学,2003,24(8):185~187
[29]潘永康,王喜忠,刘相东等,现代干燥技术(第二版),化学工业出版社,2007.
[30]张鑫,回转圆筒烘干机的应用与发展,建材工业技术,1992,7(4):1~5
[31]金国淼,干燥设备,化学工业出版社,2002
[32]李慧,王宏,任泽林等,胆碱的研究进展,饲料工业,2007,28(20):7~10
[33]王敏奇,胆碱在饲料工业中的研究应用进展,粮食与饲料工业,2001,(11):24~25
[34]秦鹏,氯化胆碱的生产与应用,饲料博览,2007,(9):38~41
[35]徐淑倩,李跃,刘树年等,氯化胆碱的市场前景分析,饲料广角,2007,(10):16~17
[36]李建雨,不同水平氯化胆碱在生长猪中的应用效果,现代畜牧兽医,2006,(3):16~17
[37]黄晶译,关于饲料的胆碱含量,World Poultry,2002,118,(9):18~19
[38] Arun S.Mujumdar,工业干燥的革新现状与研发需求,干燥技术与设备,2007,5(2):60~69
[39]黄立新,陈国华,Arun S.Mujumdar等,干燥技术最新研究进展和展望,干燥技术与设备,2007,5(5):215~219
[40]孙黎,稳定性氯化胆碱的研究,饲料工业,2001,22(6):25~27
[41]隆厚今,胆碱营养研究进展,湖南饲料,2002(2):8~10
[42]冷向军,李小勤,水产动物的胆碱营养,饲料研究,2005,(2):44~46
[2]朱亚伟,周斌,氯化胆碱合成新工艺,化工生产与技术,2003,10,(5),15~17
[3]唐桂芬,兰尊海,彭爱娟,50%氯化胆碱粉剂中氯化胆碱含量的快速测定,饲料工业,1999,20(10):40~41
[4]邢召良,李铁,倪春琳等,50%粉剂氯化胆碱干燥工艺的选择,饲料工业,2007,28(9):1~3
[5]韩友文,胆碱和氯化胆碱,饲料博览,2004,(9):45~46
[6]常碧影,张丽英,当前氯化胆碱的质量与有关应用的几个问题,饲料广角,2004,(6):31~34
[7]高传慧,丁丽,郭传森等,反应萃取法生产氯化胆碱,当代化工,2006,35(6):380~385
[8]梁学庆,聂建荣,粉剂氯化胆碱含量的简易测定法,中国饲料,2002,(14):32~33
[9]韩书霞,林晶,粉剂氯化胆碱中三甲胺含量的测定,饲料研究,2005,(8):51~53
[10]徐淑倩,李跃,刘树年等,氯化胆碱的市场前景分析,饲料广角,2007,(10):16~17
[11]骆浩文,氯化胆碱的应用研究,饲料博览,2001,(1):10~11
[12]高占友,马玲,氯化胆碱粉剂含量测定的新方法,饲料研究,2000,(9):33~34
[13]王芬,氯化胆碱含量测定的几种方法与分析探讨,饲料广角,2002,(22):19~21
[14]厉风华,氯化胆碱含量测定方法探讨,湖南饲料,2003,(2):29~31
[15]唐执文,周永红,氯化胆碱含量测定方法探讨,中国饲料,2002,(10):18~20
[16]胡京枝,魏红,任红等,氯化胆碱含量常用测定方法比较,中国饲料,2003,(20):19~20
[17]张少钢,氯化胆碱合成反应的模拟及工艺条件优化,化学反应工程与工艺,2002,18(4),339~343
[18]徐永江,氯化胆碱合成模试试验,上海石油化工股份公司研究院, 1992
[19]崔玉民,杨高文,氯化胆碱合成工艺的研究,化学反应工程与工艺,2003,19(2),155~159
[20]常碧影,丁永胜,廖志勇等,饲料添加剂氯化胆碱中氯化胆碱的测定新国家标准的研制,中国饲料, 2002,(9): 23
[21]尹国强,崔英德,廖列文等,氯化胆碱合成工艺研究,广州化工,2000,28,(4)56~58
[22]刘艳,徐丽,李杰等,微囊化氯化胆碱的制备工艺,工艺与设备,2003,(9):21~22.
[23]史勇春,柴本银,中国干燥技术现状及发展趋势,通用机械,2006,(10): 10~14
[24]潘永康,中国现代干燥技术发展概况,第十届全国干燥会论文集,2005. 1~5
[25]伍沅,干燥技术的进展和应用,化学工程,1995,23(3):18~20
[26]刘广文,干燥设备选型及采购指南,北京:中国石化出版社,2004.
[27]曹恒武,干燥技术及其工业应用,北京:中国石化出版社,2003.
[28]黄志刚,毛志怀,转筒干燥器的现状及发展趋势,食品科学,2003,24(8):185~187
[29]潘永康,王喜忠,刘相东等,现代干燥技术(第二版),化学工业出版社,2007.
[30]张鑫,回转圆筒烘干机的应用与发展,建材工业技术,1992,7(4):1~5
[31]金国淼,干燥设备,化学工业出版社,2002
[32]李慧,王宏,任泽林等,胆碱的研究进展,饲料工业,2007,28(20):7~10
[33]王敏奇,胆碱在饲料工业中的研究应用进展,粮食与饲料工业,2001,(11):24~25
[34]秦鹏,氯化胆碱的生产与应用,饲料博览,2007,(9):38~41
[35]徐淑倩,李跃,刘树年等,氯化胆碱的市场前景分析,饲料广角,2007,(10):16~17
[36]李建雨,不同水平氯化胆碱在生长猪中的应用效果,现代畜牧兽医,2006,(3):16~17
[37]黄晶译,关于饲料的胆碱含量,World Poultry,2002,118,(9):18~19
[38] Arun S.Mujumdar,工业干燥的革新现状与研发需求,干燥技术与设备,2007,5(2):60~69
[39]黄立新,陈国华,Arun S.Mujumdar等,干燥技术最新研究进展和展望,干燥技术与设备,2007,5(5):215~219
[40]孙黎,稳定性氯化胆碱的研究,饲料工业,2001,22(6):25~27
[41]隆厚今,胆碱营养研究进展,湖南饲料,2002(2):8~10
[42]冷向军,李小勤,水产动物的胆碱营养,饲料研究,2005,(2):44~46