大环草酰胺配体配合物的合成、结构及其弱相互作用研究
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摘要
大环配位化学是跨越物理、化学、材料科学和生命科学等诸多学科的最为活跃的前沿研究领域之一,引起了人们的广泛关注。
(1)本论文得到一个大环草酰胺单核配合物的同质多晶体,解析了这个晶体的结构,并对其进行了溶液紫外、固体紫外、IR谱表征。
(2)设计、合成了两个少见的、含八配位锰(II)和镍(II)的异五核配合物,解析了其单晶结构,并对其进行溶液紫外、固体紫外、热分析、IR谱表征。这两个八配位配合物中均只形成半配位键,金属离子处于很弱的配位环境中,多种超分子作用共同稳定了反常高的配位数和特别长的配位键。
(3)合成出一个新的大环配合物配体及其一个三核配合物,解析了三核配合物的晶体结构,并进行了IR谱表征。X-射线单晶衍射分析表明,产物中结合上的环己二胺都是顺式构型的。
Macrocyclic coordination chemistry is an active fields of research at the cross point of chemistry, physics, biology and material sciences and has attracted considerable attention.
(1)A new polymorph of a reported mononuclear macrocyclic oxamido complex was synthesized and characterized by X-ray single crystal diffraction, UV spectra and IR spectra.
(2)Two novel eight-semi-coordinate Ni(II) and Mn(II) complexes were synthesized and characterized by X-ray single crystal diffraction, UV spectra, TG methods and IR spectra. The abnormally long coordination bonds and high coordination numbers were rationalized as being stabilized by intermorlecular interactions.
(3) One new mononuclear Ni(II) complex ligand and a trinuclear complex of this complex ligand were synthesized. The trinuclear complex was characterized by X-ray single crystal diffraction.
(1)本论文得到一个大环草酰胺单核配合物的同质多晶体,解析了这个晶体的结构,并对其进行了溶液紫外、固体紫外、IR谱表征。
(2)设计、合成了两个少见的、含八配位锰(II)和镍(II)的异五核配合物,解析了其单晶结构,并对其进行溶液紫外、固体紫外、热分析、IR谱表征。这两个八配位配合物中均只形成半配位键,金属离子处于很弱的配位环境中,多种超分子作用共同稳定了反常高的配位数和特别长的配位键。
(3)合成出一个新的大环配合物配体及其一个三核配合物,解析了三核配合物的晶体结构,并进行了IR谱表征。X-射线单晶衍射分析表明,产物中结合上的环己二胺都是顺式构型的。
Macrocyclic coordination chemistry is an active fields of research at the cross point of chemistry, physics, biology and material sciences and has attracted considerable attention.
(1)A new polymorph of a reported mononuclear macrocyclic oxamido complex was synthesized and characterized by X-ray single crystal diffraction, UV spectra and IR spectra.
(2)Two novel eight-semi-coordinate Ni(II) and Mn(II) complexes were synthesized and characterized by X-ray single crystal diffraction, UV spectra, TG methods and IR spectra. The abnormally long coordination bonds and high coordination numbers were rationalized as being stabilized by intermorlecular interactions.
(3) One new mononuclear Ni(II) complex ligand and a trinuclear complex of this complex ligand were synthesized. The trinuclear complex was characterized by X-ray single crystal diffraction.
引文
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