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SiCp/6061Al基复合材料超声频脉冲等离子弧原位合金化焊接的研究
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摘要
颗粒增强铝基复合材料以其高的比强度、比刚度、比模量、优异的耐磨性能以及在性能和加工方面较强的可设计性等特点,在航天、航空、汽车工业、光学仪器和体育用品等领域具有重要的应用价值。但是,铝基复合材料的焊接性很差,是其走向工业化必须克服的“瓶颈”。为此,本研究提出了一种超声频脉冲等离子弧原位合金化焊接的新方法,为铝基复合材料的应用探索了一条新思路。
     通过将小功率超声频脉冲电源与等离子焊机并联,超声频交流信号经过阻容耦合进入焊接回路,建立了超声频脉冲等离子弧焊接系统,使等离子焊接电弧受外加高频调制,其作为焊接热源的同时成为一种可控的超声发射源。本文以SiCp/6061Al MMCs为研究对象,研究了超声频脉冲等离子弧原位合金化焊接工艺对接头组织与性能的影响,并对焊接冶金机理进行了系统的分析。利用金相显微镜、扫描电镜及X射线衍射分析仪研究了不同焊接工艺下铝基复合材料的焊接接头组织及成分的变化,进行硬度及拉伸试验,探讨了影响等离子弧焊接接头力学性能的因素。
     试验结果表明,将超声频激励信号引入SiCp/6061Al基复合材料等离子弧原位合金化工艺过程中,以Ti-60Al为填充材料,Ar+N_2为离子气,Ar为保护气,能有效抑制脆性相Al_4C_3的形成,在焊缝中形成了Al_3Ti、TiC、TiN等新生增强相;在脉冲调制频率30KHz的情况下对等离子焊接电弧施以超声频调制,可以激励出相应频率的超声信号,较之未施加激励信号时,由于超声振动直接作用于焊接熔池,明显细化了焊缝区组织,使得增强颗粒趋向于均匀分布,提高了焊接接头的强度,达到了240MPa。
     对不同激励频率作用下焊缝中的增强颗粒分布情况进行观察,发现随着超声频率的提高,颗粒分布越均匀。尤其是在谐振区间内的40KHz、50KHz时,颗粒分布较其他频率段均匀,直接影响了接头强度的提高,在40KHz时焊接接头的强度最大达到了263MPa。
Aluminum metal matrix composites are more and more widely applied in aerospace,spaceflight,auto manufacturing due to their excellent combination properties of high specific strength,high specific stiffness,high elastic modulus, better wear-resistance.But Aluminum metal matrix composites is not applied widely in industry because of its poor welding ability.The welding technique is the key to expand its industry application for Aluminum metal matrix composites.Therefore,we propose a new method named ultrasonic frequency pulse "in-situ" plasma arc welding to make an exploration for the application of SiCp/6061Al MMCs.
     Combining low-power ultrasonic frequency pulse power and plasma welding,we set up a ultrasonic frequency pulse arc welding system,so that the plasma arc welding is modulated by high frequency to be a kind of controllable ultrasound emission source at the same time as a welding heat source.The effects of this welding process on microstructures and mechanical properties(Ar and N_2 as ionized gas,Ar as fielded gas) of SiCp/6061Al MMCs and mechanism of its alloying process is investigated in the present work.The changes of microstructure and composition of fusion welded joints of composites was in observation with OM(optics microscopy),SEM(scanning microscopy) and XRD(X-ray diffraction).And mechanical properties of fusion welded joints were measured by microhardness and tensile tests.
     The experimental results show that the same frequency arc-ultrasonic could be excited.The formation of Al_4C_3 was effectively prohibited and the new weld reinforced such as Al_3Ti、TiC、TiN was produced.Compared with not modulated,the arc-ultrasonic could significantly reduce the size of the reinforced and also improve its distribution to make the welding joints denser.The hardness of the weld middle zone had become lower and the strength of welding joints had been increased, reaching 240MPa.
     Observing the distribution of the reinforce on different exciting frequency,we found the distribution become more uniform.Especially in the resonant interval 40KHz、50KHz,the distribution was better and the strength of welding joints was bigger.And the strength reached 263MPa at 40KHz.
引文
[1]C.G.Long.Particle reinforced aluminum magnesium composites[J].International Materials Reviews.1994,39(1):1-22
    [2]游志勇,张永忠,赵浩峰.金属基复合材料及其发展现状[J].山西机械.2003,120(3):5-8.
    [3]J.V.Wood,P.Davies,J.L.F.Kellie.Properties of reactively cast aluminum TiB_2 alloy [J].Materials Science and Technology.1993,9(10):833-840
    [4]吴人杰.下世纪我国复合材料的发展机遇与挑战[J].复合材料学报.2000,17(1):1-4
    [5]牛济泰,刘黎明.铝基复合材料焊接研究现状及展望[J].哈尔滨工业大学学报.1999,31(1):130-136
    [6]Ells M B D.Joining of aluminum based metal matrix composites[J].International Materials Reviews.1996,41(2):41-58
    [7]雷玉成,袁为进,朱飞,等.等离子弧焊接SiCp/Al基复合材料焊缝“原位”合金化分析[J].焊接学报.2005,26(12):13-16
    [8]吴敏生,何龙标,李路明,等.电弧超声焊接技术[J].焊接学报.2005,26(6):40-44
    [9]张春雷,吴敏生.埋弧焊电弧超声激励及其热动力学效应[J].焊接.2003.8:8-12
    [10]何龙标,郝红伟,等.电弧超声对Q235A的SMAW焊缝组织和性能的影响[J].热加工工艺.2006,35(3):11-13
    [11]许志武,闫久春,杨士勤.Al2O3/6061Al超声振动液相焊接技术研究[C].第十一次全国焊接会议论文集.1-121-1-124
    [12]Sharma.Siddharth R.Mechanical behavior of friction stir welded powder metallurgy aluminum alloys and composete[J].Friction Stir Welding and Processing.2001:151-157
    [13]Kohn.G.Laser-assisted friction stir welding[J].Welding Journal.2002,81(2):46-48
    [14]Cook,George E,Smartt,et al.Controlling robotic friction stir welding[J].Welding Journal(Miami,Fla).2003,82(6):28-34
    [15]Chang.Woong-Seong.Joint properties and thermal behaviors of friction stir welded age hardenable 6061Al alloy[J].Materials Science Forum.2003,426-432(4):2953-2958
    [16]Du.Suigeng.FEA coupled with thermo-mechanical effect on fricton welding[J].Chinese Journal of Mechanical Engineering.2002,38(6):77-82
    [17]牛济泰,刘黎明,孟庆昌,刘兴秋.Al_2O_3/6061Al复合材料焊接工艺参数的优化及接头组织[J].焊接学报.1999,20(1):28-33
    [18]广赖明夫.金属基复合材料の结合[J].溶接学会志.1996,65(4):1692-1698
    [19]唐逸民.金属基复合材料焊接的研究进展问题及对策[J].焊接研究与生产.1998,(1):5-12
    [20]孙大谦,刘卫红,吴建红,等.铝基复合材料瞬间液相扩散连接接头的组织与力学性能[J].焊接学报.2002,23(5):65-68
    [21]Lee C S,Li H,Chandel R S.Vacuum-free diffusion bonding of aluminium metal matrix composite[J].Journal of Materials Processing Technology.1999,89-90(5):326-330
    [22]Lee C S,Li H,Chandel R S.Stimulation model for the vacuum-free diffusion bonding of aluminum metal matrix composite[J].Journal of Materials Processing Technology.1999,89-90(5):344-349
    [23]O.T.Midling.A process mode for friction welding of Al-Si-Mg alloys and Al-SiC MMCs[J].Metal Mater.1994,42(5):1595-1609
    [24]Ahearn.J.S.Mart in Marietta laboratories[C].NSWC Contract No.N60921-80-c-0064,1981
    [25]林丽华,唐逸明,顾明元,等.金属基复合材料焊接技术及发展动向[J].材料科学与工程.1997,59(3):23-28
    [26]Kenndy J R.Microstructure observations of arc welded boron-aluminum composites[J].Welding Journal.1973(3):120-124
    [27]陈彦宾,张德库,牛济泰,等.激光焊接铝基复合材料钛的原位增强作用[J].应用激光.2002,22(3):320-322
    [28]A.Hirose.Joining process for structure application of continuous fiber reinforced MMC[J].Key EngiMter.1995,104-107
    [29]陈永来,于利根,王华明.SiCp/6061Al金属基复合材料焊缝“原位”合金化激光焊接研究[J].中国激光.2001,28(1):85-88
    [30]陈永来,于利根,王华明.合金化填充材料Ni对SiCp/6061Al复合材料激光焊接焊缝显微组织的影响[J].复合材料学报.2000,17(4):63-65
    [31]徐九华,范炯,林祥丰.金属基复合材料激光诱发反应焊接研究[J].航空学报.1999, 20(6):573-576
    [32]Wang H M,Chen Y L,Yu L G."In-Situ" weld-alloying /laser beam welding of SiCp/6061Al MMC[J].Materials Science& Engineering A.2000,A293(1-2):1-6
    [33]林丽华.碳化硅颗粒增强铝基复合材料的钎焊机理[J].焊接学报.1997,18(1):12-14
    [34]W.P.Weng,T.H.Chuang.Interfacial characteristics for brazing of Aluminum matrix composites with Al-12Si filler metals[J].Metallurgical and Materials Transaction A.1997,28A:26-73
    [35]W.C.Moshier,J.S.Ahearn and D.C.Cooke.Interaction of Al-Si,Al-Ge,and Zn-Al eutectic alloys with SiC/Al discontinuously reinforced metal matrix composites[J].Journal of materials science.1987,22:115
    [36]Khorunor V.E,kuchuk-latsenko V.S,Dykhno I.S,et al.Brazing of sheet composite materials with Aluminum matrix[J].Proceedings of the International Conference.1990,(A92-54851)23-37
    [37]Moshier W C,Aheam J S,Cooke D C.Internaction of Al-Si,Al-Ge,and Zn-Al eutectic Alloys with SiC/Al discontinuously reinforced metal-matrix composite[J].Journal of Materials Science.1987,(22):115-122
    [38]马晓春,唐逸民,等.碳化硅颗粒增强铝基复合材料的钎焊机理研究[J].焊接学报.1997,18(1):12-17
    [39]吕世雄.SiCw/6061Al复合材料无钎剂低温搅拌加压钎焊方法的研究[D].哈尔滨:哈尔滨工业大学硕士论文,2000:19-28
    [40]张新平,魏巍,权高峰.非连续替SiC增强铝基复合材料的真空钎焊[c].第八次全国焊接会议论文集(第一册).中国机械工程学会焊接学会.北京:机械工业出版社,1997:264-267
    [41]M.S.Hersh.Resistance Welding of Metal Matrix Composite[J].Welding Journal.1986,47(9):404-409
    [42]M.S.Hersh.Correlation Between B/Al Sheet Quality and Resistance Weld Quality and Strength[J].Welding Journal.1971,50(12):515-521
    [43]M.S.Hersh.Resistance Spot Welding of Metal Matrix Composite[J].Welding Journal.1970,49(6):254-258s
    [44]M.S.Hersh.Resistance Diffusion Bonding B/Al Composite to Ti[J].Welding Journal.1973,52(8):370-376s
    [45]V.L.Ryazantsev.Selection of the Resistance Spot-Welding Conditions in Relation to the Content of B Fibers in a Composite Material[J].Wel Pro.1981,(5):19-26
    [46]黄金日,薛立勤,赵忠兴,等.超声波对铸造合金组织和机械性能的影响[J].湖北工学院学报.1996,11(4):29-33
    [47]林书玉.功率超声技术的研究现状及其最新发展[J].陕西师范大学学报(自然科学版).2001,29(1):101-106
    [48]冯若,李化茂.声化学及其应用[M].合肥:安徽科学技术出版社.1992
    [49]温俊杰,李荐.超声波强化冶金过程研究进展[J].四川有色金属.2002(4):17-20
    [50]Eskin G I.Cavitation Mechanism of Ultrasonic Melt Degassing[J].Ultrasonics Sonochemistry.1995,10(2):137-141
    [51]白晓清,李东辉,张林,等.流动液体中夹杂物超声去除的影响因素[J].金属学报.2002,38(5):483-489
    [52]Eskin G I,Eskin D G.Production of Natural and Synthesized Aluminum-based composite Materials with the Aid of Ultrasonic Cavitations[J].Treatment of the Melt Ultrasonic's Son chemistry.2003,10(4-57:297-301
    [53]胡化文,陈康华.超声波熔体处理对铝合金组织和性能的影响[J].特种铸造及有色合金.2004(4):11-13
    [54]李应龙,高彩茹,王玉贵.铝硅合金的振动变质研究[J].轻合金加工技术.1999,27(11):8-18
    [55]李应龙,李宝绵,刘永涛,等.功率超声对Al-Si合金组织和性能的影响[J].中国有色金属学报.1999,9(4):719-722
    [56]王俊,周尧和,舒光冀,等.用高能超声制备金属基复合材料的现状与发展[J].铸造.1997(12):40-42
    [57]王俊,陈峰,孙宝德.高能超声在制备颗粒增强金属基复合材料中的作用[J].上海交通大学学报.1999,33(7):813-816
    [58]王俊,陈峰,张力宁.高能超声制备Al_2O_3-ZA22复合材料与性能研究[J].铸造.1997(5):1-3
    [59]马立群,陈锋,舒光冀.用高能超声法制备微细颗粒增强金属基复合材料[J].材料研究学报.1995,9(4):372-375
    [60]吴敏生,张雁军,李路明,等.电弧超声对09MnNiDR钢焊接接头冲击性能的影响[J].清华大学学报(自然科学版).2006,46(2):161-164
    [61]张雁军,李路明,吴敏生.电弧超声对09MnNiDR钢焊接接头性能的影响[J].福州大学学报(自然科学版).2006,34(4):533-538
    [62]杨博宇,郝红伟,李路明,等.电弧超声埋弧焊改善09MnNiDR焊缝组织性能[J].热加工工艺.2006,35(7):1-3
    [63]杜敬磊,李路明,等.焊接过程中电弧超声对细化晶粒的影响[J].电焊机.2002,32(3):6-8
    [64]周荣林,郭德伦,李从卿,等.TC4钛合金电弧超声TIG焊[J].焊接学报.2004,25(6):97-98
    [65]张雁军,周荣林,吴敏生.电弧超声改善Ti6Al4V焊接接头性能的研究[J].电焊机.2005,35(9):27-29
    [66]文雄伟,李路明,等.等离子弧激发超声改变陶瓷涂层结构的研究[C].2004年高能束流加工技术国际研讨会.2004,225-227
    [67]马骏,张华堂,等.超声频率对等离子喷涂热障涂层结合强度的影响[C].2007年全国真空冶金与表面工程学术会议论文摘要集.2007
    [68]吴敏生,段向阳,陈以方,等.受激电弧超声发射实验研究[J].焊接.1999(5):10-19
    [69]胡星,郝红伟,文雄伟,等.影响电弧超声激发强度的参数[J].焊接学报.2007,28(4):73-76
    [70]邱灵,范成磊,等.高频脉冲变极性焊接电源及电弧压力分析[J].焊接学报.2007,28(11):81-84
    [71]Szekely J.Flow phenomena mixing and mass transfer in argon-stirred ladles[J].Iron Making & Steel Making,1979,10(6):285-292
    [72]N.FRAGE,N.FRUMIN,L.LEVIN,etal.High-temperature phase equilibria in the Al-rich corner of the Al-Ti-C system[J].Metal trans A 1998 Vol29.A.April:1341-1345
    [73]LEI Yu-cheng,YUAN Wei-jin,CHEN Xi-zhang,et al.In-situ weld-alloying plasma arc welding of SiCp/Al MMCs[J].Trans.Nonferrous Met.Soc.China.2007,17(2):313-317
    [74]赵玉厚,严文,周敬恩.Si、Mg对原位铝基复合材料中增强体Al_3Ti形貌的影响[J].兵器材料科学与工程.2001,24(2):34-37
    [75]Abramov O V.Ultrasound in Liquid and Solid Metals[M].CRC Press.1994
    [76]赵忠兴,穆光华,等.超声波对铸造合金组织和性能的影响[J].铸造.1996,(3):21
    [77]Puskar A.The use of high-intensity ultrasonic Elsevier[J].Materials Science Monographs.1982,Volume 13,302p
    [78]葛晓陵,吴东棣.Al/SiCp复合材料断裂失效的微观机理[J].复合材料学报.1994,11(4):44-48

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