外送粉电弧喷涂复合涂层工艺与性能的研究
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摘要
电弧喷涂具有操作简单、成本低、涂层化学成分易调节等特点,因此,电弧喷涂的应用范围相当广泛。实心丝材的种类少、成分难以调节,应用范围也受到了限制;粉芯丝材受到金属外皮的限制,拉拔困难、成本高,成分调节困难等。
由于实心丝材和粉芯丝材各有其自身的缺点,因此本文采用外送粉电弧喷涂,用实心丝材作为燃烧丝,配合外送的陶瓷粉进行喷涂,制备金属基陶瓷复合涂层。利用扫描电子显微镜(SEM)、能谱仪(EDAX)、X射线衍射仪(XRD)等测试方法对电弧喷涂涂层的显微组织结构、磨损表面进行了分析。其研究成果如下:
采用SEM和EDAX分析了外送粉电弧喷涂涂层的微观结构和外送陶瓷粉的沉积情况。涂层的显微组织呈现典型的层状结构,组织致密并伴随少量的孔隙,在涂层中检测到了陶瓷粉的存在,说明陶瓷粉是可以进入到涂层当中的。
工艺参数对涂层显微硬度的影响由主到次依次为:喷涂电流、喷涂距离、雾化空气压力、喷涂电压。涂层显微硬度的分布规律为:靠近基体材料,硬度为537HV,当距离为150 m时,达到最高为569HV,随着距离的增加硬度出现波动,越靠近涂层表面硬度越低。工艺参数对涂层结合强度的影响由主到次依次为:喷涂距离、雾化空气压力、喷涂电压、喷涂电流。涂层的磨损试验表明:在干摩擦磨损时,以犁沟磨损为主,并伴随着黏着磨损;油摩擦磨损时,以黏着磨损为主,并伴随着犁沟磨损。
Features of arc Spraying Technology are: simple operation, low cost, easy to adjust chemical composition of coatings, etc. Therefore, the arc spraying are wide range of applications. Types of solid wire less ingredients are difficult to regulate, the application scope has been limited; cored wire by metal skin of the restrictions, drawing difficulty, high cost, composition adjustment difficulties.
As the solid wire and cored wires have their own drawbacks, so this paper carry outgoing arc spraying powder, using a solid wire as the burning of wire to meet the outgoing carry out spraying of ceramic powder to prepare metal matrix ceramic composite coatings. Using scanning electron microscopy (SEM), energy dispersive spectrometer (EDAX), X-ray diffraction (XRD) test methods, arc-sprayed coating microstructure on the organizational structure of the worn surface were analyzed. Results of their research are as follows:
Using SEM and EDAX analysis outgoing arc spraying powder coating microstructure and outgoing deposition of ceramic powder. Microstructure of the coating showed a typical layered structure, organization, and dense with a small amount of pores in the coating detected the presence of ceramic powder, indicating ceramic powder into the coating can be among the.
Of process parameters on micro-hardness of coatings from the primary to the meeting were: spray current, spraying distance, atomization air pressure, spray voltage. Coating micro-hardness distribution law as follows: near the substrate material, the hardness of 537HV, when the distance of 150 m, the highest for the 569HV, the increase in hardness with the distance fluctuations, the more close to the lower surface of the coating hardness. Of process parameters on the bonding strength of coating from the primary to the meeting were: spray distance, atomization air pressure, spray voltage, spray current. Coating wear tests showed: In the dry friction and wear, when to wear the main furrow, and accompanied by adhesive wear; oil when the friction and wear to adhesive wear of the main, and accompanied by plowing wear.
由于实心丝材和粉芯丝材各有其自身的缺点,因此本文采用外送粉电弧喷涂,用实心丝材作为燃烧丝,配合外送的陶瓷粉进行喷涂,制备金属基陶瓷复合涂层。利用扫描电子显微镜(SEM)、能谱仪(EDAX)、X射线衍射仪(XRD)等测试方法对电弧喷涂涂层的显微组织结构、磨损表面进行了分析。其研究成果如下:
采用SEM和EDAX分析了外送粉电弧喷涂涂层的微观结构和外送陶瓷粉的沉积情况。涂层的显微组织呈现典型的层状结构,组织致密并伴随少量的孔隙,在涂层中检测到了陶瓷粉的存在,说明陶瓷粉是可以进入到涂层当中的。
工艺参数对涂层显微硬度的影响由主到次依次为:喷涂电流、喷涂距离、雾化空气压力、喷涂电压。涂层显微硬度的分布规律为:靠近基体材料,硬度为537HV,当距离为150 m时,达到最高为569HV,随着距离的增加硬度出现波动,越靠近涂层表面硬度越低。工艺参数对涂层结合强度的影响由主到次依次为:喷涂距离、雾化空气压力、喷涂电压、喷涂电流。涂层的磨损试验表明:在干摩擦磨损时,以犁沟磨损为主,并伴随着黏着磨损;油摩擦磨损时,以黏着磨损为主,并伴随着犁沟磨损。
Features of arc Spraying Technology are: simple operation, low cost, easy to adjust chemical composition of coatings, etc. Therefore, the arc spraying are wide range of applications. Types of solid wire less ingredients are difficult to regulate, the application scope has been limited; cored wire by metal skin of the restrictions, drawing difficulty, high cost, composition adjustment difficulties.
As the solid wire and cored wires have their own drawbacks, so this paper carry outgoing arc spraying powder, using a solid wire as the burning of wire to meet the outgoing carry out spraying of ceramic powder to prepare metal matrix ceramic composite coatings. Using scanning electron microscopy (SEM), energy dispersive spectrometer (EDAX), X-ray diffraction (XRD) test methods, arc-sprayed coating microstructure on the organizational structure of the worn surface were analyzed. Results of their research are as follows:
Using SEM and EDAX analysis outgoing arc spraying powder coating microstructure and outgoing deposition of ceramic powder. Microstructure of the coating showed a typical layered structure, organization, and dense with a small amount of pores in the coating detected the presence of ceramic powder, indicating ceramic powder into the coating can be among the.
Of process parameters on micro-hardness of coatings from the primary to the meeting were: spray current, spraying distance, atomization air pressure, spray voltage. Coating micro-hardness distribution law as follows: near the substrate material, the hardness of 537HV, when the distance of 150 m, the highest for the 569HV, the increase in hardness with the distance fluctuations, the more close to the lower surface of the coating hardness. Of process parameters on the bonding strength of coating from the primary to the meeting were: spray distance, atomization air pressure, spray voltage, spray current. Coating wear tests showed: In the dry friction and wear, when to wear the main furrow, and accompanied by adhesive wear; oil when the friction and wear to adhesive wear of the main, and accompanied by plowing wear.
引文
[1]徐滨士.《表面工程与维修》.北京:机械工业出版社,1996: 303~304
[2]刘新田.《表面工程》.河南:河南大学出版社,2000: 1~3
[3]赵文轸.《材料表面工程导论》.西安:西安交通大学出版社,1998: 25~26
[4]陈学定,韩文正.《表面喷涂技术》.北京:机械工业出版社,1994: 237~239
[5]徐滨士,张伟,梁秀兵.热喷涂材料的应用于发展.材料工程,2001, 3(12):3~7
[6]张健全,徐晋勇,高清,等.热喷涂技术的发展及应用.山西焦煤科技,2006, 12(8):19~22
[7]徐滨士,朱绍华.《表面工程的理论与技术》.北京:国防工业出版社,1999: 266
[8]张平.《热喷涂材料》.北京:国防工业出版社,2006: 178~180
[9]徐滨士,马世宁.电弧喷涂技术的应用和发展.铁道物资科学管理,1997, 15(3):34~35
[10] Kelkar M. Modeling of wire are spraying. Ph.D.Thesis,University of Minnesota, 1998, 24:153~154
[11] E Pfender. Fundamental studies assoeiated with the plasma spraying proeess. Surf. Coat & Teehnol, 1998, 34: 8~14
[12]钱苗根,姚寿山,张少宗.《现代表面技术》.北京:机械工业出版社,2002: 215~216
[13]徐滨士.《表面工程的理论与技术》.北京:国防工业出版社,1999: 73~75
[14]梁春永,陈学广.电弧喷涂技术的研究状况及发展方向.金属成形工艺,2003, 13(6):58~61
[15]陈文威.《金属表面涂层技术及应用》.北京:人民交通出版社,1996: 195~198
[16]谭吕瑶,王钧石.《使用表面工程技术》.北京:新时代出版社,1998: 235~242
[17]谢铁兵,刘宪军.电弧喷涂管状丝材新发展及应用.表面技术,1999, 19(9):30~33
[18]秦颢.高硬度耐磨粉芯线材的研制:[硕士学位论文].北京:北京工业大学,1999
[19]刘松.电弧喷涂设备及其发展趋势.电焊机,2004, 34(3):34~37
[20]杜小红.电弧喷涂技术在中国的发展及应用.表面技术,2000, 25(9):21~23
[21] Drzeniek H, et al. Introduction of cored wires to arc spraying. International Thermal Spraying Conference 10th, 1983: 136~138
[22] Elliot Sampson. Advances in thermal spray coatings broaden their applications. Welding Journal, 1993, 7: 39~41
[23]邓世均.高科技时代的热喷涂技术.材料保护,1995, 28(8):32~36
[24] Borisov Y, et al. Composite flux cored wires for thermal spraying. Proceeding of ITSC 95.kobe, 1995, 5: 1115~1118
[25] Hallum D L. Metal-cored wires : what you should know. Welding Design & Fabrication, 1992, 10: 22~28
[26]杜贵平,黄石生.电弧喷涂设备的现状与展望.表面技术,2001, 30(6):22~33
[27]田保红,徐滨士,马世宁,等.电弧喷涂金属基复合材料涂层.沈阳工学院学报,1999, 25(4):12~16
[28]贺定勇,蒋建敏,闫玉芹,等.电弧及火焰喷涂用粉芯线材的研究及应用.焊接技术,2001, 20(6):39~40
[29]贾焕丽,孙宏飞,李梅广,等.新型电弧喷涂粉芯丝材的现状与发展前景.表面技术,2005,34(6):4~6
[30]朱子新,徐滨士,马世宁,等.高速电弧喷涂铁铝涂层的组织和性能.金属热处理,2002, 27(3):12~14
[31]徐滨士,梁秀兵,马世宁.新型高速电弧喷涂枪的开发研究.中国表面工程,1998, 11(3):16~19
[32]汤顺意.电弧喷涂制备铁基耐磨陶瓷涂层的工艺优化.工艺装备,2007, 5(4):26~28
[33]贺定勇《.电弧喷涂粉芯丝材及涂层的磨损特性研究》.北京:北京工业大学,2004: 10~11
[34]谢铁兵.电弧喷涂粉芯丝材的新发展及应用.表面技术,1999, 28(3):30~32
[35]温瑾林.管状丝材的电弧喷涂.沈阳工业大学学报,1997, 19(2):1~2
[36]田保红.电弧喷涂金属基复合材料涂层.洛阳工学院学报,1999, 20(4):14~15
[37]李淑青.电弧喷涂TiB2陶瓷涂层Ni含量对其耐磨粒磨损性能的影响.材料保护,2009, 42(3):73~75
[38]孟凡刚,王勇,董立先,等.电弧喷涂药芯丝材涂层的组织和高温冲蚀性能.中国石油大学学报,2009, 33(2):123~126
[39]魏增菊,贾焕丽.高速电弧喷涂铁基Cr3C2复合涂层组织及磨损特性的研究.材料热处理技术,2009, 16(38):75~78
[40] Wira K, Lim C W, Loh N L. Microstructure and wear properties of arc sprayed tungsten carbide coating. Proc of 14th ITSC Kobe, Japan, 1995: 465~470
[41] Dallaire S, Levert H. Phenomenology of reactive core wire arc spraying. Proc of the 13th ITSC. Orlando, Florida,1992: 207~212
[42] Wang B Q. Elevated temperature erosion resistance of several experimental amorphous thermal spray coatings. Proc of the 15th ITSC. Nice, France, 1998: 151~155
[43]徐维普,徐滨士,张伟,等.增强相对高速电弧喷涂Fe-Al涂层性能的影响.上海交通大学学报,2005, 39(1):36~40
[44]朱子新,徐滨士,马世宁,等.高速电弧喷涂Fe-Al/WC复合涂层的摩擦学特性.摩擦学学报,2003, 23(3):174~178
[45]徐维普,徐滨士,张伟,等.高速电弧喷涂Fe2Al/Cr3C2复合涂层的组织与性能.金属热处理,2004, 29(5):5~8
[46]刘谦,马世宁,戴庆荣,等.新型防滑防腐耐磨复合涂层制备工艺.新技术新工艺,2003, 31(8):43~44
[47]贺定勇,蒋建敏.电弧及火焰喷涂用粉芯丝材的研究及应用.焊接技术,2001, 30(5):30~40
[48]贺定勇,蒋建敏,闫玉芹,等.电弧及火焰喷涂用粉芯线材的研究及应用.焊接设备与材料,2001, 30(5):39~40
[2]刘新田.《表面工程》.河南:河南大学出版社,2000: 1~3
[3]赵文轸.《材料表面工程导论》.西安:西安交通大学出版社,1998: 25~26
[4]陈学定,韩文正.《表面喷涂技术》.北京:机械工业出版社,1994: 237~239
[5]徐滨士,张伟,梁秀兵.热喷涂材料的应用于发展.材料工程,2001, 3(12):3~7
[6]张健全,徐晋勇,高清,等.热喷涂技术的发展及应用.山西焦煤科技,2006, 12(8):19~22
[7]徐滨士,朱绍华.《表面工程的理论与技术》.北京:国防工业出版社,1999: 266
[8]张平.《热喷涂材料》.北京:国防工业出版社,2006: 178~180
[9]徐滨士,马世宁.电弧喷涂技术的应用和发展.铁道物资科学管理,1997, 15(3):34~35
[10] Kelkar M. Modeling of wire are spraying. Ph.D.Thesis,University of Minnesota, 1998, 24:153~154
[11] E Pfender. Fundamental studies assoeiated with the plasma spraying proeess. Surf. Coat & Teehnol, 1998, 34: 8~14
[12]钱苗根,姚寿山,张少宗.《现代表面技术》.北京:机械工业出版社,2002: 215~216
[13]徐滨士.《表面工程的理论与技术》.北京:国防工业出版社,1999: 73~75
[14]梁春永,陈学广.电弧喷涂技术的研究状况及发展方向.金属成形工艺,2003, 13(6):58~61
[15]陈文威.《金属表面涂层技术及应用》.北京:人民交通出版社,1996: 195~198
[16]谭吕瑶,王钧石.《使用表面工程技术》.北京:新时代出版社,1998: 235~242
[17]谢铁兵,刘宪军.电弧喷涂管状丝材新发展及应用.表面技术,1999, 19(9):30~33
[18]秦颢.高硬度耐磨粉芯线材的研制:[硕士学位论文].北京:北京工业大学,1999
[19]刘松.电弧喷涂设备及其发展趋势.电焊机,2004, 34(3):34~37
[20]杜小红.电弧喷涂技术在中国的发展及应用.表面技术,2000, 25(9):21~23
[21] Drzeniek H, et al. Introduction of cored wires to arc spraying. International Thermal Spraying Conference 10th, 1983: 136~138
[22] Elliot Sampson. Advances in thermal spray coatings broaden their applications. Welding Journal, 1993, 7: 39~41
[23]邓世均.高科技时代的热喷涂技术.材料保护,1995, 28(8):32~36
[24] Borisov Y, et al. Composite flux cored wires for thermal spraying. Proceeding of ITSC 95.kobe, 1995, 5: 1115~1118
[25] Hallum D L. Metal-cored wires : what you should know. Welding Design & Fabrication, 1992, 10: 22~28
[26]杜贵平,黄石生.电弧喷涂设备的现状与展望.表面技术,2001, 30(6):22~33
[27]田保红,徐滨士,马世宁,等.电弧喷涂金属基复合材料涂层.沈阳工学院学报,1999, 25(4):12~16
[28]贺定勇,蒋建敏,闫玉芹,等.电弧及火焰喷涂用粉芯线材的研究及应用.焊接技术,2001, 20(6):39~40
[29]贾焕丽,孙宏飞,李梅广,等.新型电弧喷涂粉芯丝材的现状与发展前景.表面技术,2005,34(6):4~6
[30]朱子新,徐滨士,马世宁,等.高速电弧喷涂铁铝涂层的组织和性能.金属热处理,2002, 27(3):12~14
[31]徐滨士,梁秀兵,马世宁.新型高速电弧喷涂枪的开发研究.中国表面工程,1998, 11(3):16~19
[32]汤顺意.电弧喷涂制备铁基耐磨陶瓷涂层的工艺优化.工艺装备,2007, 5(4):26~28
[33]贺定勇《.电弧喷涂粉芯丝材及涂层的磨损特性研究》.北京:北京工业大学,2004: 10~11
[34]谢铁兵.电弧喷涂粉芯丝材的新发展及应用.表面技术,1999, 28(3):30~32
[35]温瑾林.管状丝材的电弧喷涂.沈阳工业大学学报,1997, 19(2):1~2
[36]田保红.电弧喷涂金属基复合材料涂层.洛阳工学院学报,1999, 20(4):14~15
[37]李淑青.电弧喷涂TiB2陶瓷涂层Ni含量对其耐磨粒磨损性能的影响.材料保护,2009, 42(3):73~75
[38]孟凡刚,王勇,董立先,等.电弧喷涂药芯丝材涂层的组织和高温冲蚀性能.中国石油大学学报,2009, 33(2):123~126
[39]魏增菊,贾焕丽.高速电弧喷涂铁基Cr3C2复合涂层组织及磨损特性的研究.材料热处理技术,2009, 16(38):75~78
[40] Wira K, Lim C W, Loh N L. Microstructure and wear properties of arc sprayed tungsten carbide coating. Proc of 14th ITSC Kobe, Japan, 1995: 465~470
[41] Dallaire S, Levert H. Phenomenology of reactive core wire arc spraying. Proc of the 13th ITSC. Orlando, Florida,1992: 207~212
[42] Wang B Q. Elevated temperature erosion resistance of several experimental amorphous thermal spray coatings. Proc of the 15th ITSC. Nice, France, 1998: 151~155
[43]徐维普,徐滨士,张伟,等.增强相对高速电弧喷涂Fe-Al涂层性能的影响.上海交通大学学报,2005, 39(1):36~40
[44]朱子新,徐滨士,马世宁,等.高速电弧喷涂Fe-Al/WC复合涂层的摩擦学特性.摩擦学学报,2003, 23(3):174~178
[45]徐维普,徐滨士,张伟,等.高速电弧喷涂Fe2Al/Cr3C2复合涂层的组织与性能.金属热处理,2004, 29(5):5~8
[46]刘谦,马世宁,戴庆荣,等.新型防滑防腐耐磨复合涂层制备工艺.新技术新工艺,2003, 31(8):43~44
[47]贺定勇,蒋建敏.电弧及火焰喷涂用粉芯丝材的研究及应用.焊接技术,2001, 30(5):30~40
[48]贺定勇,蒋建敏,闫玉芹,等.电弧及火焰喷涂用粉芯线材的研究及应用.焊接设备与材料,2001, 30(5):39~40