钆铝酸盐基发光材料的组合芯片法研究
|
摘要
组合材料芯片技术是功能材料开发研究的全新方法,能够高效、快速地筛选/优化新材料。我们利用这一技术对新型稀土掺杂钆铝酸盐发光材料进行了研究,以期建立钆铝酸盐基发光材料数据库,为发光材料设计提供科学依据。本研究以国内第一个普适性组合技术研究平台—IM100离子束材料芯片沉积仪为主要实验设备,采用离子束顺序沉积技术设计、制备了一系列稀土掺杂钆铝酸盐发光材料芯片。我们针对发光材料体系中影响发光性能的主要因素:基体、发光中心种类、发光中心掺杂浓度、敏化中心种类等,进行了系统地研究;作为开展这一研究的实验基础,我们还进行了稀土掺杂钆铝酸盐发光材料粉体的制备技术研究。主要研究内容和结果如下:
1、稀土掺杂钆铝酸盐发光材料发光性能的研究。凭借芯片技术实现该类发光材料的基体材料和稀土掺杂元素相关光学性能数据的迅速积累,并以第一性原理为研究手段探讨稀土掺杂钆铝酸盐材料的发光共性和规律。实验中以扫描电镜(SEM)、X射线相分析(XRD)、荧光发射和激发谱(PL)、紫外激发发光照相记录等分析方法来表征材料芯片和同步粉体样品。通过组合芯片筛选:发现GdAlO_3(GAP)是一种高效发光基体;完成了Ce、Pr、Sm、Eu、Tb、Dy等稀土离子的单掺杂和共掺杂光谱特性数据的积累;并从众多的稀土掺杂钆铝酸盐发光材料中优选出Eu、Tb离子主掺杂的线索材料。
2、钆铝酸盐薄膜制备工艺研究。按化学计量比顺序沉积晶相薄膜各组元,通过低温扩散过程和高温晶化的两步热处理得到均质单相薄膜。热处理时考虑单层薄膜厚度、温度、时间等条件对薄膜的扩散均匀性的影响,以及在不同烧成温度下薄膜结晶状况。根据扫描电镜二次电子像(SEM)、X射线衍射谱(XRD)、俄歇深度剖析谱(AES)结果发现:当组元单层不大于500(?)时,钆铝酸盐前驱薄膜经低温扩散(400℃/120h)后,再经过高温晶化(Gd_4Al_2O_9(GAM)及GdAlO_3(GAP)在1300℃/4h、Gd_3Al_5O_(12)(GAG)在1200℃/4h的条件下),可得到单相晶化薄膜。
3、稀土掺杂钆铝酸盐基发光材料粉体的制备技术研究。实验以X射线相分析(XRD)、热重-差热(TG-DSC)和计算热力学为分析手段,得到如下实验结果:柠檬酸盐-硝酸盐法制备稀土掺杂钆铝酸盐粉体时,≥900℃/2h可得到GdAlO_3、Gd_4Al_2O_9单相粉末,随着煅烧温度的升高,晶粒发育越完整;Gd_3Al_5O_(12)需要在900℃附近快速煅烧得到,900℃/1h是比较好的煅烧条件,低于或高于此温度都很难得到Gd_3Al_5O_(12)单相粉末。采用醋酸盐—硝酸盐法很难制备Gd_4Al_2O_9单相粉末,而GdAlO_3的单相粉末≥1100℃/2h即可得到;Gd_3Al_5O_(12)这一晶相粉体则需要850℃/2h保温后再900℃/1h煅烧得到。
The combinatorial materials chip method is an excellent innovation for inorganic function material research.The technique is capable of efficiently discovering and screening new materials.In present work,a new luminescence material system, Gadolinium aluminate doped with rare earth ions,was investigated,and a database of this material system was set up.Some major issues associated with luminescence materials,such as host materials,activator and activator/sensitizer concentrations,were well taken into consideration in the process of materials chip design.With the utilization of IM100 ion beam deposition system,which is the first platform for combinatorial materials chip synthesis in China,a series of gadolinium aluminate luminescence materials chips were fabricated.Powder synthesis methods were also studied as the experimental basis.The main content and results of this research work are listed as follows:
1) Gadolinium aluminate luminescence material doped with rare earth ions was studied by combinatorial method,including data collection of the luminescent properties and rule derivation with the first principle calculation.Scanning electron microscopy (SEM),X-ray diffraction phase analysis(XRD),Auger electron spectroscopy(AES) emission and excitation photoluminescence spectra(PL),photoluminescence photos techniques were used as analysis methods.Based on experiments,GdAlO_3(GAP) was selected as the optimal host material in the gadolinium aluminate;luminescence spectra data of rare earth ions(RE=Ce,Pr,Sm,Eu,Tb,Dy) doped gadolinium aluminate were gathered;It was found that the Eu or Tb ion doped gadolinium aluminate can emit strong visible photoluminescence under UV excitation.
2) The most suitable annealing condition for gadolinium aluminate single phase film synthesis was investigated.The stoichiometric gadolinium aluminate multiplayer thinfilm precursors(single layer thickness was less than 500A) were treated at 400℃/120 h+1300℃/4 h,and final products of GdAlO_3(GAP) and Gd_4Al_2O_9(GAM) single phase films were formed.For Gd_3Al_5O_(12)(GAG) phase stoichiometric precursor,the high temperature crystallization should be 1200℃/4h while the low temperature diffusion was the same.The XRD,AES analysis indicated that such two-step annealing processes would form pure single phase films,and the SEM analysis further proved that uniform and dense films were obtained.
3) Powder synthesis for gadolinium aluminate luminescence materials.XRD,TGDSC and thermodynamics calculation were used as analysis methods.After obtaining the precursor powder from citrate-nitrate combustion process,≥900℃/2h annealing could form GAP,GAM single phase powder,the annealing condition should be changed to 900℃/1h(the temperature should be kept precisely at 900℃) when fabricating GAG. Acetate-nitrate combustion was also used to synthesis the gadolinium aluminate luminescence powder.It was found that 1100℃/2h for GAP,and 850℃/2h+900°/1h for GAG were the suitable heat treatment conditions.However,GAM single powder could not be obtained by this method.
1、稀土掺杂钆铝酸盐发光材料发光性能的研究。凭借芯片技术实现该类发光材料的基体材料和稀土掺杂元素相关光学性能数据的迅速积累,并以第一性原理为研究手段探讨稀土掺杂钆铝酸盐材料的发光共性和规律。实验中以扫描电镜(SEM)、X射线相分析(XRD)、荧光发射和激发谱(PL)、紫外激发发光照相记录等分析方法来表征材料芯片和同步粉体样品。通过组合芯片筛选:发现GdAlO_3(GAP)是一种高效发光基体;完成了Ce、Pr、Sm、Eu、Tb、Dy等稀土离子的单掺杂和共掺杂光谱特性数据的积累;并从众多的稀土掺杂钆铝酸盐发光材料中优选出Eu、Tb离子主掺杂的线索材料。
2、钆铝酸盐薄膜制备工艺研究。按化学计量比顺序沉积晶相薄膜各组元,通过低温扩散过程和高温晶化的两步热处理得到均质单相薄膜。热处理时考虑单层薄膜厚度、温度、时间等条件对薄膜的扩散均匀性的影响,以及在不同烧成温度下薄膜结晶状况。根据扫描电镜二次电子像(SEM)、X射线衍射谱(XRD)、俄歇深度剖析谱(AES)结果发现:当组元单层不大于500(?)时,钆铝酸盐前驱薄膜经低温扩散(400℃/120h)后,再经过高温晶化(Gd_4Al_2O_9(GAM)及GdAlO_3(GAP)在1300℃/4h、Gd_3Al_5O_(12)(GAG)在1200℃/4h的条件下),可得到单相晶化薄膜。
3、稀土掺杂钆铝酸盐基发光材料粉体的制备技术研究。实验以X射线相分析(XRD)、热重-差热(TG-DSC)和计算热力学为分析手段,得到如下实验结果:柠檬酸盐-硝酸盐法制备稀土掺杂钆铝酸盐粉体时,≥900℃/2h可得到GdAlO_3、Gd_4Al_2O_9单相粉末,随着煅烧温度的升高,晶粒发育越完整;Gd_3Al_5O_(12)需要在900℃附近快速煅烧得到,900℃/1h是比较好的煅烧条件,低于或高于此温度都很难得到Gd_3Al_5O_(12)单相粉末。采用醋酸盐—硝酸盐法很难制备Gd_4Al_2O_9单相粉末,而GdAlO_3的单相粉末≥1100℃/2h即可得到;Gd_3Al_5O_(12)这一晶相粉体则需要850℃/2h保温后再900℃/1h煅烧得到。
The combinatorial materials chip method is an excellent innovation for inorganic function material research.The technique is capable of efficiently discovering and screening new materials.In present work,a new luminescence material system, Gadolinium aluminate doped with rare earth ions,was investigated,and a database of this material system was set up.Some major issues associated with luminescence materials,such as host materials,activator and activator/sensitizer concentrations,were well taken into consideration in the process of materials chip design.With the utilization of IM100 ion beam deposition system,which is the first platform for combinatorial materials chip synthesis in China,a series of gadolinium aluminate luminescence materials chips were fabricated.Powder synthesis methods were also studied as the experimental basis.The main content and results of this research work are listed as follows:
1) Gadolinium aluminate luminescence material doped with rare earth ions was studied by combinatorial method,including data collection of the luminescent properties and rule derivation with the first principle calculation.Scanning electron microscopy (SEM),X-ray diffraction phase analysis(XRD),Auger electron spectroscopy(AES) emission and excitation photoluminescence spectra(PL),photoluminescence photos techniques were used as analysis methods.Based on experiments,GdAlO_3(GAP) was selected as the optimal host material in the gadolinium aluminate;luminescence spectra data of rare earth ions(RE=Ce,Pr,Sm,Eu,Tb,Dy) doped gadolinium aluminate were gathered;It was found that the Eu or Tb ion doped gadolinium aluminate can emit strong visible photoluminescence under UV excitation.
2) The most suitable annealing condition for gadolinium aluminate single phase film synthesis was investigated.The stoichiometric gadolinium aluminate multiplayer thinfilm precursors(single layer thickness was less than 500A) were treated at 400℃/120 h+1300℃/4 h,and final products of GdAlO_3(GAP) and Gd_4Al_2O_9(GAM) single phase films were formed.For Gd_3Al_5O_(12)(GAG) phase stoichiometric precursor,the high temperature crystallization should be 1200℃/4h while the low temperature diffusion was the same.The XRD,AES analysis indicated that such two-step annealing processes would form pure single phase films,and the SEM analysis further proved that uniform and dense films were obtained.
3) Powder synthesis for gadolinium aluminate luminescence materials.XRD,TGDSC and thermodynamics calculation were used as analysis methods.After obtaining the precursor powder from citrate-nitrate combustion process,≥900℃/2h annealing could form GAP,GAM single phase powder,the annealing condition should be changed to 900℃/1h(the temperature should be kept precisely at 900℃) when fabricating GAG. Acetate-nitrate combustion was also used to synthesis the gadolinium aluminate luminescence powder.It was found that 1100℃/2h for GAP,and 850℃/2h+900°/1h for GAG were the suitable heat treatment conditions.However,GAM single powder could not be obtained by this method.
引文
1. Kennedy K, Stefansky T, Davy G, et al. Rapid method for determining termary-alloy phase diagrams[J]. J Appl Phys, 1965, 36:3808
2. Hanak J J. The "multiple-sample concept" in materials research: synthesis, compositional analysis and testing of entire multicomponent systems[J]. J Mater Sci, 1970, 5:964
3.董安钢,唐颐.浅谈组合化学[J].大学化学,2000,15(5):8
4. Wolf D, Buyevskaya O V, Baerns M. An evolutionary approach in the combinatorial selection and optimization of catalytic materials[J]. Appl Catalysis A:General, 2000, 200:63
5. Jaramillo T F , Ivanovskaya A, McFarland E W. High-throughput screening system for catalytic hydrogen-producing materials[J]. J Comb Chem, 2002,4:17
6. Xiang X D, Sun Xiaodong, et al. A Combinatorial Approach to Materials Discovery[J], Science,1995,268:1738
7. Sun X D, Gao C, Wang J, et al. Identification and optimization of advanced phosphors using combinatorial libraries[J]. Appl Phys Lett., 1997, 70 :3353
8. Sun X D, Xiang X D. New phosphor (Gd_(2-x)Zn_x)O_(3-δ):Eu~(3+) with high luminescent efficiency and superior chromaticity[J]. Appl Phys Lett., 1998, 72 :525
9. Danielson E, Golden J H, et al. A combinatorial approach to the discovery and optimization of luminescent materials[J]. Nature, 1997, 389:944
10. Danielson E, Devenney M, et al. A rare-earth phosphor containing one-dimensional chains identified through combinatorial methods[J]. Science, 1998,279:837
11. Wang J S, Yoo YK et al. Identification of a blue photoluminescent composite material from a combinatorial library[J]. Science, 1998, 279:1712
12. Yoo Y K, Ohnishi T, Wang G, et al. Continuous mapping of structure-property relations in Fc_(1-x)Ni_x metallic alloys fabricated by combinatorial synthesis[J]. Intermetallics, 2001,9(7):541
13. Cremer R, Neuschutx D. Optimization of(Ti, Al)N hard coating by a combinatorial approach[J].Inter J Inor Mater., 2001,3:1181
14. Takahashi R, Matsumoto Y, Koinuma H, et al. Combinatorial optimization of atomically controlled growth for oxide films by the carrousel type laser molecular beam epitaxy[J]. Appl Surf Sci, 2002, 197-198:532
15. Perkins J D, Cueto JA D, Alleman J K, et al. Combinatorial studies of Zn-Al-O and Zn-Sn-O transparent conducting oxide thin films[J]. Thin Solid films, 2002,411:152
16. Laversenne L, Kariouani S, Guyot Y,et al. Correlation between dopant content and excited-state dynamics properties in Er~(3+)-Yb~(3+)-codoped Y_2O_3 by using a new combinatorial method[J].Optical Materials, 2002, 19: 59
17. Grobhans I, Kari H, Stritzker B, Combinatorial synthesis of ZnTe nanocrystals in SiO_2 on silicom y ion implantation[J]. Nucl Instru &Method in Phys ResB, 2002, 190: 865
18. Hasegawa T, Kageyama T, Fukumura T, et al. High-throughput characterization of composition-spread manganese oxide films with a scanning SQUID microscope[J]. Applied Surface Sci.,2002,189:210
19.冯兰,顾明,蔡英文.制备材料芯片的K分分形掩膜策略[J].高技术通讯,2004,6:39
20.Takeuchi I,Chang H,Gao C et al.Combintorial synthesis and evaluation of epitaxial ferroelectric device libraries[J].Appl Phys Lett,1998,73(7):894
21.Chang H,Takeuchi I,Xiang X D.A low-loss composition region identified from a thin-film composition spread of(Ba_(1-x-y)St_xCa_y)TiO_3[J].Appl Phys Lett,1999,74(8):1165
22.Yoo Y K,Tsui F,Continuous phase diagramming of epitaxial films[J].MRS Bulletin,2002,27(4):316
23.Yoo Y K,Duewer F,Yang H,et al.Room-temperature electronic phase transitions in the continuous phase diagrams of perovskite manganites[J].Nature,2000,406(17):704
24.田明波,刘德令.薄膜科学与技术手册[J].机械工业出版社出版,1991
25.Sun X D,Wang K A,Yoo Y K,et al.Solution-phase synthesis of luminescent materials libraries[J].Adv Mater,1997,9(13):1046
26.Evans J RG,Edirisinghe M J,Coveney P V,et al.Combinatorial searches of inorganic materials using the ink-jet printer:science,philosophy and technology[J].J Euro Ceram Soc,2001,21:2291
27.Tay B Y,Edirisinghe M J.Investigation of some phenomena occurring during continuous ink-jet printing of ceramics[J].J Mater Res,2001,16:373
28.Mott M,Song J H,Evans J RG.Microengineering of ceramics by direct ink-jet printing[J].J Am Ceram Soc,1999,82:1653
29.Teng W D,Edirisinghe M J.Development of ceramic inks for direct continuous jet printing[J].J Am Ceram Soc,1998,81:1033
30.Minami H,Itaka K,Kawaji H et al.Rapid synthesis and characterization of(Ca_(1-x)Ba_x)_3Co_4O_9thin films using combinatorial methods[J].Appl.Sur.Sci.,2002,197-198:442
31.Kim T W,Arai N,Kubota H,et al.Re-evaporation effect on the surface morphology of Gd_xY_(1-x)Ca_4O(BO_3)_3 films grown by combinatorial laser molecular-beam epitaxy[J].Appl Sur Sci,2002,197-198:406
32.Koinuma H.Combinatorial materials research projects in Japan[J].Appl Sur Sci.,2002,189:179
33.Matsumoto Y,Murakami M,Hasegawa T,et al.Structural control and combinatorial doping of titanium dioxide thin films by laser molecular beam epitaxy[J].Appl Sur Sci.,2002,189:344
34.Briceno G,ChangH,Sun X D et al.A class of cobalt oxide magnetoresistance materials discovered with combinatorial synthesis[J].Science,1995,270:273
35.Xiang X D.Combinatorial synthesis and high throughput evaluation of functional oxides-A integrated materials chip approach[J].Mater Sci Eng,1998,B56:246
36.Dagani R.A faster route to new materials[J].C&EN,1999,77(10):51
37.Dover RB V,Schneemeyer L F,et al.Discovery of a useful thin-film dielectric using a composition-spread approach.Nature,1998,392:162
38.Takeuchi I.Experimental issues in combinatorial investigation of electronic thin-film materials[J].Appl Sur Sci,2002,189:353
39.Chang K S,Aronova M,Famodu O,et al.Multimode quantitative scanning microwave microscopy of in situ grown epitaxial Ba_(1-x)Sr_xTiO_3 Composition spreads[J].Appl.Phys Lett,2001,79(26):4411
40.Miller N C,Shirn G A.Co-sputtering Au-SiO_2 cermet films[J].Appl Phys Lett,1967,10:86
41.Hornbostel M D,Hyer E J et al.Rational synthesis of metastable skutterudite compounds using multilayer precursors[J].J Am Chem Soc,1997,119:2665
42.Fister L,Johnson D C.Synthesis of Cu_xMo_6Se_8 without Binary Compounds as Intermediates:A study using superlattices to kinetically control a solid-state reaction[J].J Am Chem Soc,1994,116:629
43.Fukumura T,M.Ohtani,J.Nishimura et al.Temperature-gradient and composition-spread deposition of epitaxial oxide films and high throughput characterization.Proceedings of SPIE,2001,4281:8
44.郭杏元,刘庆峰,刘茜.高密度无机功能材料芯片快速表征技术的发展[J].无机材料学报,2002,17(3):392
45.Isaacs E D,Marcus M.Synchrotron x-ray microbeam diagnostics of combinatorial synthesis[J].Appl.Phys Lett.,1998,73:1820
46.Omote K,Kikuchi T,J Harada et al.A convergent beam,parallel detection x-ray diffraction system for characterizing combinatorial epitaxial thin films[J].Proceedings of SPIE,2000,3941:84
47.Takeuchi I,Dover R B V,Koinuma H.Combinatorial synthesis and evaluation of functional inorganic materials using thin-film techniques[J].MRS Bulletin,2002,27(4):301
48.www.Bruker-axs.com
49.高琛,项晓东,吴自勤.发现和优化新材料的集成材料芯片法[J].物理,1999,28(11):675
50.Takahashi R,Kubota H,Murakami M,Yamamoto Y,Matsumoto Y,and Koinuma H.Design of Combinatorial Shadow Masks for Complete Ternary-Phase Diagramming of Solid State Materials[J].J Comb Chem 2004,6:50
51.Takahashi R,Kubota H,Tanigawa T,Murakami M,Yamamoto Y,Matsumoto Y,Koinuma H.Development of a new combinatorial mask for addressable ternary phase diagramming:application to rare earth doped phosphors[J]Applied Surface Science,2004,223:249
52.Hiroyuki Sano,Takahiro Matsumoto,Yuji Matsumoto,Hideomi Koinuma.RECa_4O(BO_3)_3thin films as new Luminescent materials screened by the combinatorial method[J]Journal of Physics and Chemistry of Solids,2005,66:2112
53.Hiroyuki Sano,Yuji Matsumoto,Takahiro Matsumoto,Hideomi Koinuma.A combinatorial approach to the discovery and optimization of YCa_4O(BO_3)_3-based luminescent materials[J].Applied Surface Science,2006,252:2493
54.Jennifer Licia Wu,Earl Danieison,et al.Combinatorial synthesis and screening of cerium doped garnets phosphors for application in White GaN-based LEDS[J].Proc Spie,2001,4445:7
55.Jennifer Licia Wu.A combinatorial chemistry approach to understanding optical properties of cerium doped gamets[D].Doctor thesis of University of California Santa Barbara,2003
56.Chang Hae Kim,Sang Mi Park,Joung Kyu Park,Hee Dong Park,Kee-Sun Sohn,and Joon Taik Park.Combinatorial Synthesis of Tb-Activated Phosphors in the CaO-Gd_2O_3 -Al_2O_3 System[J].Journal of The Electrochemical Society,2002,149(12):H183
57.Soo Yeon Seo,Kee-Sun Sohn,Hee Dong Park,and Seonghoon Lee.Optimization of Gd_2O_3-Based Red Phosphors Using Combinatorial Chemistry Method[J].Journal of The Electrochemical Society,2002,149(1):H12
58.Kee-Sun Sohn,Duk Hyun Park,Sang Ho Cho,Byung Il Kim,and Seong Ihl Woo.Genetic AlgorithmAssisted Combinatorial Search for a New Green Phosphor for Use in Tricolor White LEDs[J].J Comb Chem,2006,8:44
59.Kee-Sun Sohn,Duk Hyun Park,Sang Ho Cho,Joon Seop Kwak,and Ji Sik Kim.Computational Evolutionary Optimization of Red Phosphor for Use in Tricolor White LEDs[J].Chem Mater.2006,18:1768
60.Duk Hyun Park,Sang Ho Cho,Ji Sik Kim,Kee-Sun Sohn.Combinatorial screening of Eu dopedTiO_2 -Y_2O_3 -Gd_2O_3 ternary system at soft UV excitation[J].J Alloys and Compounds,2008,449:196
61.Lei Chen,Jun Bao,and Chen Gao.Combinatorial Synthesis of Insoluble Oxide Library from Ultrafine/Nano Particle Suspension Using a Drop-on-Demand Inkjet Delivery System.J Comb.Chem,2004,6:699
62.Chen Lei,Liu Zhonghai,Shen Lei,et al.Ultrafine/nano suspensionsprepared by rare earth oxides high-energy ballmilled in purewater[J].Acta Phys.Chin.Sin(物理化学学报),2004,20:722.
63.Liu X N,Cui H B,Tang Y,et al.Combinatorial screening for new borophosphateVUV phosphors[J].Appl Surf Sci 2004,223:144
64.Zhen-Lin Luo,Bin Geng,Jun Bao,and Chen Gao.Parallel Solution Combustion Synthesis for Combinatorial Materials Studies[J].J Comb Chem,2005,7:942
65.Ting-Shan Chan,Chia-Chen Kang,Ru-Shi Liu,Lei Chen,Xiao-Nan Liu,Jian-Jun Ding,Jun Bao,and Chen Gao.Combinatorial Study of the Optimization of Y_2O_3:Bi,Eu Red Phosphors[J]J Comb Chem,2007,9:343
1.刘光华.稀土固体材料学[M].北京:机械工业出版社,1995.
2.朱裕贞.工科无机化学[M].上海:华东理工大学出版社,1993
3.方容川.固体光谱学[M].合肥:中国科学技术大学出版社,2001
4.尹民,Khaidukov N M,Krupa J C Site selective excitation and energy transfer in LiKGdF_5crystal co-doped with Er~(3+) and Tb~(3+)[J].J Rare Earths,2004,22(1):22
5.李铭华,黄竹坡.Eu~(2+)在碱土金属氯磷酸盐中的发光[J].中国稀土学报,1990,8(1):26
6.王齐祖,田军.Tb~(3+)、Dy~(2+)激活的LaBO_3发光和能量传递[J].发光学报,1995,16(1):57
7.Dexter D L.A Theory of Sensitized Luminescence in Solids[J].J Chem Phys,1953,21:836
8.Cshin J D,Cooke A H..Magnetic Properties of Antiferromagnetic GdAlO_3[J].J Appl Phys,1968,39:1360
9.Blazey K W,Rohrer H.Antiferromagnetism and magnetic phase diagram of GdAlO_3[J],Rhysical Review,1968,173:574
10.Lo J R,Tseng T Y.Effect of Licl on the crystallization behavior and luminescence of Y_3Al_5O_(12):Tb[J].Mater Sci Comm,1998,57:95
11.Brandle C D,Steinfink H.The Crystal Structure of Eu_4Al_2O_9[J].Inorg Chem,1969,8:1320
12.Baccaro S,Blazek K.Scintillation properties of YAP:Ce[J].Nucl Instrum Meth,1995,A361:205
13.Baryshevsky V G,Korzhik M V.Ce-fast-acting scintillators for detection of ionizingradiation[J].Nucl Instrum Meth,1991,B58:291
14.Andreeta J P,Jovanie B R.Growth and optical properties of Cr~(3+) doped GdAlO_3 single crystals [J].Mater Res,2000,3(2):45
15.Mares J A,Pedrini C,Optical studies of Ce~(3+)-doped gadolinium aluminium perovskite single crystals[J].Chem Phys Lett,1993,206:9
16.Mares J A,Nikl M.Fluorescence and scintillation properties of LuAlO_3:Ce crystal[J].Chem Phys Lett,1995,241(4):311
17.Dorenbos P,Bougrine E.Scintillation properties of GdAlO_3:Ce crystals[J].Radiation Effect and Defects in Solids,1995,135:321.
18.Verweij J W M,Cohen-Adad M Th.Luminescence properties of GdAlO_3:Ce powders.Dependence on reduction conditions[J].Chem Phys Lett,1995,239:51
19.罗岚,徐政,刘庆峰等.GdAlO3:Eu3+荧光粉燃烧法合成及其发光性能[J].同济大学学报(自然科学版),2004,32(11):1476
20.Fu W T,Zandbergen H W,et al.On the red phosphor of nominal compostion Gd_(0.77)Al_(1.23)O_x:Eu_(0.06)(x≈3.1)[J].Material research bulletin,2004,39:909
21.Tsuyoshi Y,Michihiro A,et al.Ce~(3+) centers in YAlO_3(YAP) single crystals[J].J Physical Society of Japan.1995,64:4442
22.Sakurai K J,Guo X M.Mechanical solid-state formation of Y_(1-x)Ce_xAlO_3 and its application as an X-ray scinitillator[J].Mater Sci and Eng,2001,304-306:403
23.Peculiarities of luminescence and sintillation properties of YAP:Ce and LuAP:Ce single crystals and single crystalline films[J].Radiation Measurements,2007,42:528
24.Yasuda K,Usuda S,et al.Properties of a YAP powder scintillator as alpha-ray detector[J].Appl Radi and Iso,2000,52,365
25.Petrosyan A G,Ovanesyan K L,et al.Growth and light yield performance of dense Ce~(3+)-doped (Lu,Y)AlO_3 Solid solution crystals[J].J Crystal Growth,2000,211:252
26.Zerenko Y,Gorbenko V,et at.Luminescence of La~(3+) and Sc~(3+) impurity centers in YAlO_3 single-crystal films[J].J Lumin,2008,128:595
27.Luria E,Rotman S R,et al.Energy transfer between Cr~(3+) and Nd~(3+) in Cr,Nd:YAP[J].J Lumin,1997,72-73:951
28.Lancok J,Jelinek M,et al.Structural and optical characterisation of Nd doped YalO_3 films deposited on sapphire substrate by pulsed laser deposition[J].Thin Solid films,1999,346:284.
29.Akira Y,Martin N,et al.Chanllenge and study for developing of novel single crystalline optical materials using micro-pulling-down method[J].Optical Materials,2007,30:6
30.Han S D,Khatkar S P,et al.Combustion synthesis and luminescent properties of Eu~(3+)- doped LnAlO_3(Ln=Y and Gd) phosphors[J].Material Scienc and Engineering,2006,127:272
31.Luo L,Xu Z,Liu Q F,Liu Q.Preparation of combinatorial libraries of gadolinium aluminate film and its luminescent properties[J].Journal of The Chinese Ceramic Society,2004,32(11):1325
32.Luo L,Xu Z,Liu Q F,Liu Q.Luminescent properties and mechanism of co-doped GdAlO_3:Eu,RE[J].Chinese Physics Letters,2005,22(1):132
33.罗岚,刘庆峰,刘茜.Gd_(1-x)AlO_3:Eu_x~(3+)梯度材料芯片制备及发光性能研究[J].稀有金属材料与工程,2005,34(8):1310
34.Luo L,et al.Preparation and Luminescence properties of Gadolinium Acuminate Phosphor Material Chip[J].Journal of rare earths,2005,23(12)sup:36
35.Luo L,Liu Q F,Liu Q.Synthesis and luminescent properties of GdAlO_3:RE by combustion process[J].Journal of rare earths,2004,22(12)sup:268
36.罗岚,陈栋,等.GdAlO3:Tb,RE中Tb,RE的能量传递研究[J],影像科学与光化学,2008,26(3):233
37.Han S D,Khatkar S P,et al.Combustion synthesis and luminescent properties of Eu~(3+)- doped LnAlO_3(Ln=Y and Gd) phosphors[J].Material Scienc and Engineering,2006,127:272
38.Hreniak D,Strek W,Deren P,et al.Synthesis and luminescence properties of Eu~(3+)-doped LaAlO_3 nanocrystals[J].J Alloys and Compounds,2006,408-412:826
39.Bagnato V S,Nunes L A O,Zilio S C,et al.Infrared electronic transitions of Eu~(3+) in GdAlO_3[J].State Communications,1984,49(1):27
40.Padua S J N,Nunes L A O,et al.absorption and luminsecence spectroscopy of GdAlO_3:Eu~(3+)[J].J Lumin,1989,43:379
41.Lupei A,Lupei V,et al.Mechanisms of enenegy transfer between Nd~(3+) ions in YAG[J].J Lumin,1987,39:35
42.Lupei V,Lupei A,et al.Enenegy transfer between Nd~(3+) ions in YAG[J].Optics communication, 1986,60:59
43.Klimm D,Ganschow S,et al.On the solubility of Nd~(3+) in Y_3Al_5O_(12)[J].J Alloys and Compounds,2007,436:204
44.Van der Ende B M,Brooks R L,et al.Measurement of the ~4F_(5/2) and ~2He(2)_(9/2) manifold lifetime in Nd~(3+):Y_3Al_5O_(12) and Nd~(3+):LaF_3[J].Journal of Luminescence,2007,124:311
45.Sugak D,Matkovskii A.Influence of color centers on optical and lasing properties of the gadilinium gallium garnet single crystals doped with Nd~(3+) ions[J].J Lumin,1999,82,9
46.傅仁武,陈朝,等.单晶Si Nd:YAG激光连续退火的数值计算[J].发光学报,2000,21:320
47.Malinowski M,Frukacz Z,et al.Optical transitions of Ho~(3+) in YAG[J].J Alloys and Compounds,2000,300-301:389
48.Malinowski M,Frukacz Z.Blue up-conversion emission in Yb~(3+) senstized YAG:pr~(3+)[J].J Lumin,1997,75:333
49.Cornacchia F,Alshourbagy M,et al.Growth and spectroscopic properties of Er:YAG crystalline fibers[J].J Crystal Growth,2005,275:534
50.Dobrzycki L,Bulska E et al.Structure of YAG Crystals doped/subsituted with Erbium and Ytterbium[J].Inorg Chen,2004,43:7656
51.Mares J A,Beitlerova A,et al.Scintillation and optical properties of YAG:Ce films grown by liquid phase epitaxy[J].Radiation Measurements,2007,42:533
52.Tumpa B,Swapan K B,et al.Comparative studies of YAG(Ce) and CsI(Tl) scintillators[J].Nuclear Instruments and Methods in Physics Research A 2002,484:364
53.Jose Gracia,Luis Seijo,et al.Abinitio calculations on the local structure and the 4f-5d absorption and emission spectra of Ce~(3+)-doped YAG[J].J Lumin,2008,128:1248
54.Zorenko Y,Gorbenko V,et al.Single crystalline film scintillators based on Ce- and Pr-doped aluminium garnets[J].Radiation Measurements 2007,42:521
55.Kuck S,Petermann K,et al.Electronic and vibronic transitions of the Cr~(4+) -doped garnets Lu_3Al_5O_(12),Y_3Al_5O_(12),Y_3Ga_5O_(12) and Gd_3Ga_5O_(12)[J].J Lumin,1996,68:1
56.Haruo Sawada.Electron Density Study ofGarnets:Y_3X_2Al_5O_(12);X=Al and X=(Al,Cr)[J].J Solid State Chemistry,1997,134:182
57.Wisneiwski K,Koepke C,et al.Excited state absorption in material containing Cr~(3+) and Cr~(4+)ions[J].J Alloy and Compounds,2002,341:349
58.Yang P Z,Deng P Z,et al.Concentration quenching in Yb:YAG[J].J Lumin,2002,97:51
59.Yoshikawa A,Ogino H,et al.Growth and scintillation properties of Yb doped aluminate vanadate and silicate single crystals[J].Optical Materials,2004,26:529
60.Guerassimova A,Garnier N,et al.X-ray-excited charge transfer luminescence in YAG:Yb and YbAG[J].J Lumin,2001,94-95:11
61.Mizunori E,Minoru O.Characterization of Nd:Y_3Al_5O_(12) thin films grown on various substrates by pulsed laser deposition[J].Appl Phys Lett,1996,69(20):2977
62.Gervais M,Douy A.Mater.Solid phase transition temperatures observed during heating and cooling[J].Sci Eng,1996,38:118.
63.Zych E,Brecher C,Wojtowicz A J.Luminescence Properties of Ce-Activated YAG Optical Ceramic Scintillator Materials[J].J Lumin,1997,75:193.
64.Zych E,Brecher C,Wojtowicz A J.Depletion of high-energy carriers in YAG optical ceramic materials[J].Spectrochimica Acta Part A,1998,54:1771.
65.Zych E,Brecher C.Temperature Dependence of Ce-Emission Kinetics in YAG:Ce Optical Ceramic[J].Journal of Alloys and Compound,2000,300-301:495
66.Zych E,Brecher C.Temperature Dependence of Host-Associated Luminescence from YAG Transparent Ceramic Material[J].Journal of Luminescence,2000,90:89
67.Zych E,Brecher C.Host-associated luminescence from YAG optical ceramics under gamma and optical excitation[J].Journal of Luminescence,1998,78(2):121
68.Schlotter P,Schmidt R,Scheider J A.Host-associated luminescence from YAG optical ceramics under gamma and optical excitation[]].Journal of Luminescence,1998,78(2):121
69.Hideki Yagi,Kazunori Takaichi,et al.Influence of annealing conditions on the optical properties of chromium-doped ceramic Y_3Al_5O_(12)[J].Opticai Materials,2006,29:392
70.Hideki Y,Takagimi Y,et al.Characterizations and laser performances of highly transparent Nd~(3+):Y_3Al_5O_(12) laser ceramics[J].Optical Materials,2007,29:1258
71.Akio Ikesue.Polycrystalline Nd:YAG ceramics lasers[J].Optical Materials,2002,19:183
72.Lu Jianren,Ueda Ken-ichi,et al.Neodymium doped yttrium aluminum garnet(Y_3Al_5O_(12))nanocrystalline ceramics-a new generation of solid state laser and optical materials[J].J Alloys and Compounds,2002,341:220
73.Hreniak D,Strek W.Synthesis and optical properties of Nd -doped Y_3Al_5O_(12) nanoceramics[J].J Alloys and Compounds,2002,341:183
74.Chen T M,Chen S C,et al.Preparation and Characterization of Garnet Phosphor Nanoparticles Derived from Oxalate Coprecipitation[J].J Solid Chemistry,1999,144:437
75.Choe J Y,Ravichandran D,et al.Cathodoluminescence study of novel sol-gel derived Y_(3-x)Al_5O_(12):Tb_x phosphors[J].J Lumin,2001,93:119
76.王继业,石士考.精细粒度Y_3Al_5O_(12):Tb荧光材料的燃烧合成及其特性[J].无机材料学报,2003,18:246
77.Turos-Matysiak R,Gryk W,et al.High pressure photoluminescence of Ce-doped(Y_(1.725) Tb _(0.575)Ce_(0.05) Gd_(0.65))Al_5O_(12)[J],Optical Materials,2008,30:722
78.Turos-Matysiak R,Gryk W,et al.Tb~(3+)→Ce~(3+) energytransferinY _(3-x-y)Tb_yGd_x Al_5O_(12)(x=0.65,y=0.575) dopedwith Ce~(3+)[J].Radiation Measurements,2007,42:755
79.Robbins D J,Cockayne B,et al.The Temperature Dependence of Rare-Earth Activated Garnet Phosphors Ⅱ.A Comparative Study of Ce~(3+),Eu~(3+),Tb~(3+) and Gd ~(3+)in Y_3Al_5O_(12)[J].J Electrochem Soc:Solid-state science and technology,1979,126:1221
80.Torfeh M,Desvignes J M,et al.Reciprocal and nonreciprocal high TE-TM modes conversions in Tb,Al and Gd,Ga substituted garnet films[J].J Appl Phys,1978,49:1806
81.Zhou Y H,Lin J,et al.Synthesis-dependent luminescence properties of Y_3Al_5O_(12):Re(Re=Ce,Sm,Tb) phosphors[J].Materials Letters,2002,56:628
82.罗岚,谭敦强,周浪,等.石榴石型铝酸钆基荧光粉体及其制备方法[P].中国,200510056140.1.2007
83.Robbins D J,Cockayne B,et al.The Temperature Dependence of Rare-Earth Activated Garnet Phosphors Ⅱ.A Comparative Study of Ce~(3+),Eu~(3+),Tb~(3+) and Gd ~(3+)in Y_3Al_5O_(12)[J].J Electrochem Soc:Solid-state science and technology,1979,126:1221
84.Setlur A A,Srivastava A M.The nature of Bi~(3+) luminescence in garnet host[J].Optical Material,2006,29:410
85.Zorenko Yu,Gorbenko V,et al.Luminescence of Bi~(3+) ionsinY_3Al_5O_(12):Bi single crystalline films[J].Radiation Measurements,2007,42:882
86.Zhou Y H,Lin J,et al.Preparation of Y_3Al_5O_(12):Eu phosphors by citric-gel method and their luminescent properties[J].Optical Materials,2002,20:13
87.Shi Shikao,Wang Jiye.Combustion synthesis of Eu activated Y_3Al_5O_(12) phosphor nanoparticles[J]Journal of Alloys and Compounds,2001,327:82
88.Park D Y,Yang J M.Fracture behavior of directionally solidified CeO_2 - and Pr_2O_3 -doped Y_3Al_5O_(12)/Al_2O_3 eutectic composites[J].Materials Science and Engineering,2002,332A:276
89.Seong Ju Park,Hui Dong Park,Seo Su.Method for manufactureing cerium dopedyttrium aluminum garnet yellow phosphors for white luminescent devices[P].Korean Patent,200023225,2000
90.Lu Chung Hsin,Jagannathan R.Cerium-ion-doped yttrium aluminumgarnet nanophosphors prepared through sol-gel pyrolysis for luminescent lighting[J].Appl Phys Lett,2002,80(19):3608.
91.李东平,缪春燕,刘停蓝.蓝光转换白光荧光粉YAG:Ce的研究进展[J],江西化工,2005,3,15
92.李东平,缪春燕,等.白光LED用荧光粉YAG:Ce的研究进展[J].液晶与显示,2005,20.526
93.戚发金,朱宪忠,王苏,王海波.气相法制备优质白光LED用YAG荧光粉[J].中国照明电器,2005,4:1
94.Yum J H,Kim S S,Sun Y E.Y_3Al_5O_(12):Ce_(0.05) phosphor coatings on a flexible substrate for use in whitelight-emitting diodes[J].Colloids and Surfaces A:Physicochem Eng Aspects,2004,251:203
95.Pan Y X,Wu M M,Su Q.Tailored photoluminescence of YAG:Ce phosphor through various methods[J].J Physics and Chemistry of Solids,2004,65:845
96.Pan Y X,Wu M M,Su Q.Comparative investigation onsynthesis and photoluminescence ofYAG:Cephosphor[J].Materials Scienceand Engineering B,2004,106:251
97.Vladimir P,Larisa G,Donats M,Tadeusz C.Luminescence of cerium doped YAG nanopowders[J].Radiation Measurements,2007,42:679
98.Li Q,Gao L,Yan D S.The crystal structure and spectra of nano-scale YAG:Ce[J].Materials Chemistry and Physics,2000,64:41
99.Photoluminescence enchancement of PEG-Modified YAG:Ce~(3+) nanocrystal phosphor prepared by glycothermal Method[J].J Phy Chem B,2005,109:22126.
100.Vladimir P,Ladsa G,et al.Luminescence of cerium doped YAG nano powders[J].Radiation Measurements,2007,42:679
101.Zhang K,Hu W B,et al.Photoluminescence investigations of(Y_(1-x)Ln_x)_3Al_5O_(12):Ce~(3+)(Ln~(3+)=Gd~(3+),La~(3+)) nanophosphors[J].Physica B,2008,403:1678
102.张书生,庄卫东,等.助熔剂对Y_3Al_5O_(12):Ce~(3+)荧光粉性能的影响[J].中国稀土学报,2002,20:605
103.Park D Y,Yang J M.Fracture behavior of directionally solidified CeO_2 - and Pr_2O_3 -doped Y_3Al_5O_(12)/Al_2O_3 eutectic composites[J].Materials Science and Engineering,2002,332A:276
104.Zorenko Yu,Gorbenko V,et al.Single-crystalline films of Ce-doped YAG and LuAG phosphors:advantages over bulk crystals analogues[J].J Lumin,2005,114:85
105.Abdullah M,Okuyama K,et al.A polymer solution process for synthesis of(Y,Gd)_3Al_5O_(12):Ce phosphor particles[J].J Non-Crystalline Solids,2005,351:697
106.Babin V,Gorbenko V,et al.Luminescence characteristics of Pb~(2+) centres in undoped and Ce~(3+)-doped Lu_3Al_5O_(12) single-crystalline films and Pb~(2+)-Ce~(3+) energy transfer processes[J].J Lumin,2007,127:384
107.Zorenko Y,Gorbenko V Growth peculiarities of the R_3Al_5O_(12)(R=Lu,Yb,Tb,Eu-Y)single crystalline film phosphors by liquid phase epitaxy[J].Radiation Measurements,2007,42:907
10g.Laguta V V,Slipenyuk A M,et at.Paramagnetic impurity defects in LuAG:Ce thick film scintillators[J].Radiation Measurements,2007,42:835
109.Novosselov A,Yoshikawa A,et al.Shaped single crystal growth and scintillating application of Yb:(Gd,Lu)_3(Ga,Al)_5O_(12) solid solutions[J].Optical Materials,2004,26:541
110.Chiara M,Vincenzo B,et al.Disorder and Nonstoichiometry in Synthetic Garnets A_3B_5O_(12)(A=Y,Lu-La,B=Al,Fe,Ga)A Simulation Study[J].Chem Mater,2004,16:1232
111.Stanek C R,McClellan K J,et al.The effect of intrinsic defects on RE_3Al_5O_(12) garnet scintillator performance[J].Nuclear Instruments and Methods in Physics Research,2007,579A:27
112.Nikl M,Vedda A,et al.Energy transfer and storage processes in scintillators:The role and nature of defects[J].Radiation Measurements,2007,42:509
113.Pari G,Mookerjee A,Bhattacharya A K.First-principles electronic structure calculations of R_3Al_5O_(12)(R being the rare-earth elements Ce-Lu)[J].Physica,2005,365B:163
114.Zorenko Y,Voloshinovskii A,et al.Luminescence of excitons and antisite defects in the phosphors based on garnet compounds[J]Radiation Measurements,2004,38:677
115.Guerassimova A,Garnier N,et al.X-ray-excited charge transfer luminescence in YAG:Yb and YbAG[J].J Lumin,2001,94-95:11
116.Wang H M,Simmonds M C,et al.Manufacturing of YbAG coatings and crystallisation of the pure and Li_2O-doped Yb_2O_3- Al_2O_3 system by a medoified sol-gel method[J].Materials chemistry and physics,2002,77:802
117.Zorenko Y,Gorbenko V.Luminescence and Tb~(3+) -Ce~(3+) -Eu~(3+) ion energy transfer in single-dystalline films of Tb Al_5O_(12):Ce,Eu garnet[J]J Lumin,2008,128:652
118.Zorenko Y,Voznyak T,et al.Energy transfer to Ce~(3+) ions in Tb_3Al_5O_(12):Ce single crystalline films[J].Radiation Measurements,2007,42:648
119.Monique Gervais,Andre Douy.Solid phase transformation and melting of the compounds Ln_4Al_2O_9(Ln=Gd,Dy,Y)[J].Materials Science and Engineering,1996,B38:118
120.Yamane H,Sakamoto T,et al.Preparation and phase transition of Gd_4(Al_(1-x)Ga_x)_2O_9 solid solution[J].J Mater Sci,2001,36:307
121.Hisanori Yamane,Masahiko Shimada.High-Temperature Neutron Diffraction Study of Y_4Al_2O_9[J].J Solid State Chem,1998,141:466
122.Yamane H,Omori M,Okubo A,et al.High-Temperature Phase Transition of Y_4Al_2O_9[J].J Am Ceram S oc,1993,76:2382
123.Yamane H,Ogawara K,Omori M,et al.Thermal Expansion and A thermal Phase Transition of Y_4Al_2O_9 Ceramics J Am Ceram Soc,1995,78:1230
124.Yamane H,Ogawara K,Omori M,et al.Phase Transition of Rare-EarthAluminates(RE_4Al_2O_9)and Rare-Earth Gallates(RE_4Ga_2O_9)[J].J Am Ceram Soc,1995,78:2385.
125.Yamane H,Omori M,Hirai T.Twin Structure of Y_4Al_2O_9[J],J Mat Sci Let,1995,14:561
126.Yamane H,Omori M,Hirai T.Thermogravimetry and Rietveld Analysis for the High-Temperature X-ray Powder Diffraction Pattern of Y_4Al_2O_9[J],J Mat Sci Let,1995,14:470
127.Monique Gervais,Andre Douy.Solid phase transformation and melting of the compounds Ln_4Al_2O_9(Ln=Gd,Dy,Y)[J].Materials Science and Engineering,1996,B38:118
128.Yamane H,Sakamoto T,et al.Preparation and phase transition of Gd_4(Al_(1-x)Ga_x)_2O_9 solid solution[J].J Mater Sci,2001,36:307
129.Liu S L,Su Q.Sol-gel synthesis and luminescence of Y_4Al_2O_9:RE~(3+)(RE=Eu,Tb)[J].J Alloys and Compouds,1997,255:102
130.袁曦明,许永胜,于江波,田熙科.溶胶一凝胶法制备纳米荧光粉Y_4Al_2O_9Eu~(3+)的初步研究[J].地球科学(中国地质大学学报),2002,27:409
131.Chaudhury S,Padda S C,Pillai K T,Singh Mudher K D.High-temperature X-ray diffraction and specific heat studies on GdAlO_3,Gd_3Al_5O_(12) and Gd_4Al_2O_9[J].Journal of Solid State Chemistry,2007,180:2393
132.Lakiza S,Fabrichnaya O,et al.Phase diagram of the ZrO_2-Gd_2O_3-Al_2O_3[J].J Ceram Soc,2006,26:233
133.Lakiza S M,Lopato L M.Stable and metastable phase relations in the system a lumina-zirconia-yttria [J].J Am Ceram Soc,1997,80(4):893.
134.Rouanet A,Foex.Study at high temperatures of the systems formed by ZrO_2 with the Sm_2O_3 and Gd_2O_3[J].C R Acad Sci,1968,C267(15):873.
135.Budnikov P P,Kushakovskij V I,Belevantsev V S.Investigation of the Gd_2O_3,Sm_2O_3 and Al_2O_3system[J].D A N SSSR,1965,165:1075.
136.Mizuno M,Yamada T,Noguchi T.Phase diagram of the systems Al_2O_3-Eu_2O_3 and Al_2O_3-Gd_2O_3at high temperatures[J].J Ceram Soc Jpn,1977,85(11):543
137.Wu P,Pelton A D.Coupled thermo dynamic-phase diagram assessment of the rare earth oxidealuminum oxide binary systems[J].J Alloys Comp,1992,179:259.
138.Shishido T.Phase diagram estimation of the Al_2O_3-SiO_2-Re_2O3 systems[J].J Mater Sci,1979,14:823
139.Kolitsch K,Seifert H J,Aldinger F.Phase relationships in the system Gd_2O_3-Al_2O_3- SiO_2[J].J Alloys Compds,1997,257:104
140.Shishidom T,Okamura K,Yajima S.Gd_3Al_5O_(12) Phase Obtained by Crystallization of Amorphous Gd_2O_3·5/Al_2O_3·3[J].J Am Ceram Soc,1978,61:373
141.Euler F,Bruce J A.Oxygen coordinates of compounds with garnet structure[J].Acta Cryst,1965,19:971
142.Yoshikawa A,Hasegawa K,et al.Phase identification of Al_2O_3/RE_3Al_5O_(12) and Al_2O_3/REAlO_3(RE=Sm-Lu,Y) eutectics[J].J Crystal Growth,2000,218:67
143.Zhang K,Hu W B,et al.Photoluminescence investigations of(Y_(1-x)Ln_x)_3Al_5O_(12):Ce~(3+)(Ln~(3+)=Gd~(3+),La~(3+)) nanophosphors[J].Physica B,2008,403:1678
144.刘茜,罗岚,刘庆峰.钙钛矿型铝酸钆基荧光粉体及制备方法[P].中国,310107829.3,2005
145.刘茜,罗岚,刘庆峰.铝酸钆基发光薄膜材料芯片及其制备技术[P].中国,310107830.6,2005
146.罗岚,周浪,等.一种钐掺杂铝酸钆基荧光粉体及其制备方法[P].中国,200810060965.4,申请中
147.罗岚,刘庆峰,刘茜,等.Gd_(3(1-x))Al_5O_(12):RE_(3x)分立材料芯片制备及发光性能研究[J].感光科学与光化学,2005:23(11):447
148.罗岚,刘庆峰,刘茜,等.Gd_3Al_5O_(12):Eu~(3+)柠檬酸盐硝酸盐燃烧法合成及其发光性能研究[J].感光科学与光化学,2006,24:225
149.罗岚,周浪,等.一种钐掺杂铝酸钆基荧光粉体及其制备方法[P].中国,200810060965.4,申请中
150.罗岚,周浪,魏秀琴.等.单斜型铝酸钆基荧光粉体及其制备方法[P].中国,200510069827.9,2007
1.Kennedy K,Stefansky T,Davy G et al.Rapid method for determining termary-alloy phase diagrams[J].J Appl Phys,1965,36:3808
2.Hanak J J.The "multiple-sample concept" in materials research:synthesis,compositional analysis and testing of entire multi component systems[J].J Mater Sci,1970,5:964
3.董安钢,唐颐.浅谈组合化学[J].大学化学,2000,15(5):8
4.Wolf D,Buyevskaya O V,Baerns M.An evolutionary approach in the combinatorial selection and optimization of catalytic materials[J].Appl Catalysis A:General,2000,200:63
5.Jaramiilo T F,Ivanovskaya A,McFarland E W.High-throughput screening system for catalytic hydrogen-producing materials[J]. J Comb Chem., 2002,4:17
6. Xiang X D, Sun X D et al. A Combinatorial Approach to Materials Discovery[J], Science, 1995,268:1738
7. Sun X D, Gao C, Wang J, et al. Identification and optimization of advanced phosphors using combinatorial libraries[J]. Appl Phys Lett, 1997,70 :3353
8. Sun X D, Xiang X.D. New phosphor (Gd_(2-x)Zn_x)O_(3-δ):Eu~(3+) with high luminescent efficiency and superior chromaticity[J]. Appl Phys Lett., 1998,72 :525
9. Danielson E, Golden J H, et al. A combinatorial approach to the discovery and optimization of luminescent materials [J]. Nature, 1997, 389:944
10. Danielson E, Devenney M, et al. A rare-earth phosphor containing one-dimensional chains identified through combinatorial methods [J]. Science, 1998, 279:837
11. Wang J S, Yoo Y K, et al. Identification of a blue photoluminescent composite material from a combinatorial library[J]. Science, 1998, 279:1712
12. Yoo Y K, Ohnishi T, Wang G, et al. Continuous mapping of structure-property relations in Fe1-xNix metallic alloys fabricated by combinatorial synthesis. Intermetallics[J], 2001, 9(7):541
13. Cremer R, Neuschutx D. Optimization of(Ti, Al)N hard coating by a combinatorial approach[J].Inter J Inorg Mater, 2001, 3:1181
14. Takahashi R, Matsumoto Y, Koinuma H, et al. Combinatorial optimization of atomically controlled growth for oxide films by the carrousel type laser molecular beam epitaxy[J]. Appl Surf Sci, 2002, 197-198:532
15. Perkins J D, Cueto J A del, Alleman J K, et al. Combinatorial studies of Zn-Al-O and Zn-Sn-O transparent conducting oxide thin films. Thin Solid films[J], 2002,411:152
16. Laversenne L, Kariouani S, Guyot Y, et al. Correlation between dopant content and excited-state dynamics properties in Er~(3+)-Yb~(3+)-codoped Y_2O_3 by using a new combinatorial method[J].Optical Materials, 2002, 19: 59
17. Grobhans I, Kari H, Stritzker B. Combinatorial synthesis of ZnTe nanocrystals in SiO_2 on silicom y ion implantation [J]. Nucl Instru and Method in Phys Res B, 2002, 190: 865
18. Hasegawa T, Kageyama T, Fukumura T, et al. High-throughput characterization of composition- spread manganese oxide films with a scanning SQUID microscope[J]. Applied Surface Sci, 2002,189:210
19. Takeuchi I, Wei T, Duewer F, et al. Low temperature scanning-tip microwave near-field microscopy of Yba_2Cu_3O_(7-x) films[J]. Appl Phys Lett, 1997,71(14):2026
20. Briceno G, H Chang, Sun X D, et al. A class of cobalt oxide magnetoresistance materials discovered with combinatorial synthesis [J]. Science, 1995, 270:273
21. Takeuchi I, Chang H, Gao C et al. Combintorial synthesis and evaluation of epitaxial ferroelectric device libraries[J]. Appl Phys Lett., 1998, 73(7): 894
22. Chang H, Gao C, Takeuchi I, et al. Combinatorial synthesis and high throughput evaluation of ferroelectric/dielectric thin-film libraries for microwave applications [J]. Appl Phys Lett., 1998,72(17):2185
23. Chang H, Xiang X D. Improvements in the figure of merit for tunable microwave dielectrics using combinatorial approach [J]. Integ Ferroelectrics, 2000,28(1-4):113
24. Liu X Q, Li Z F, Lu W, et al. Application of the combinatorial approach to the fabrication of a quantum well multiwavelength emitting chip[J]. Appl Phys Lett, 1999, 75:2611
25. Reddington E, Sapienza A, Gurau B, et al. Combinatorial electrochemistry: A highly parallel,optical screening method for discovery of better electrocatalysts [J]. Science, 1998, 280:1735
26. Yoo Y K, Duewer F, Yang H, et al. Room-temperature electronic phase transitions in the continuous phase diagrams of perovskite manganites[J]. Nature, 2000,406(17): 704
27.罗岚,徐政,许业文,刘庆峰,刘茜.物理气相法制备材料芯片的发展[J].材料导报,2004,18(2):69
28.田明波,刘德令编译.薄膜科学与技术手册[M].北京:机械工业出版社出版,1991
29.Hubbard K J,Schlom D G.Thermodynamic stability of binary oxides in contact with silicon[J]J Mater Res,1996,11:2757
30.Chen J C,Shen G H,Chen L Formation of Gd oxide thin films on(111)Si[J]Appl Surf Sci,1999,142:120
31.Kwo J,Hong A R,Kortan A R,et al.High ε gate dielectrics Gd_2O_3 and Y_2O_3 for silicon Appl phys Letter,2000,77:130
32.Gupta J A,Landheer D,Sproule G I.Interfacial layer formation in Gd_2O_3 films deposited directly on Si(100)[J].Applied Surface Science,2000,173:318
1.Kennedy K,Stefansky T,Davy G,et al.Rapid method for determining termary-alloy phase diagrams[J].J Appl Phys,1965,36:3808
2.Hanak J J.The "multiple-sample concept" in materials research:synthesis,compositional analysis and testing of entire muiticomponent systems[J].J Mater Sci,1970,5:964
3.董安钢,唐颐.浅谈组合化学[J].大学化学,2000,15(5):8
4.Wolf D,Buyevskaya O V,Baerns M.An evolutionary approach in the combinatorial selection and optimization of catalytic materials[J].Appl Catalysis A:General,2000,200:63
5.Jaramilio T F,Ivanovskaya A,McFarland E W.High-throughput screening system for catalytic hydrogen-producing materials[J].J Comb Chem,2002,4:17
6.Xiang X D,Sun Xiaodong,et al.A Combinatorial Approach to Materials Discovery[J],Science,1995,268:1738
7.Sun X D,Gao C,Wang J,et al.Identification and optimization of advanced phosphors using combinatorial libraries[J].Appl Phys Lett.,1997,70:3353
8.Sun X D,Xiang X D.New phosphor(Gd_(2-x)Zn_x)O_(3-δ):Eu~(3+) with high luminescent efficiency and superior chromaticity[J].Appl Phys Lett.,1998,72:525李强.稀土化合物纳米荧光特性的研究[D].上海硅酸盐研究所博士学位论文,1997
9.Luckey W G.Process for preparing yttrium oxide and rare earth metal oxide phosphors[P].Canadian Patent,1982,No.1038618
10.Richard C R,Graff E A,et al.Efficient preparation of rare-earth metal oxalate[P].US Patent,1969,No.3420861
11.Bertran C A,Silva N T Da,ThimG P.Citric acid effect on aqueous sol-gel cordierite synthesis[J].J Non-cry Solid.2000.273:140
12.刘雁,潘伟.溶胶凝胶法制备YAG:Eu纳米荧光粉及性能分析[J].稀有金属材料与工程,2002.31:32
13.Roy S,Sigmund W,Aldinger F.Nanostructured yttria powders via gel combustion[J].J Mater Res.,1999,14(4):1524
14.Kingsley J J,Pederson L R.Energetic materials in ceramics synthesis[J].Mat Res Soc Symp Proc,1993,296:361
15.Mckittrick J,Shea L E,Bacalski C F,et al.The influence of processing parameters on luminescent oxides produced by combustion synthesis[J].Displays,1999,19:169
16.Pechini.M P Method of preparing lead and alkaline earth titanates and niobate and coating method using the same to from a capacitor[P].US Patent,1967,No.3330697
17.Kakihana M,Okubo T.Low temperature powder synthesis of LaAlO3 through in situ polymerization route utilizing citric acid and ethylene glycol[J].J Alloy Comp.,1998,266:129
18.Lin S P,Fung K Z,Hon Y M,et al.Crystallization mechanism of LiNiO2 synthesized by Pechini method[J].J Crys Growth,2001,226:148
19.Serra O A,Cicillini S A,Ishiki R R.A new procedure to obtain Eu3+ doped oxide and oxosalt phoshors[J].J Alloy Comp.,2000,303-304:316
20.Choudhary R N P,Mal J.Phase transition in Bi-modified PZT ferroelectrics[J].Mater Lett,2002,54:175
21.Zhou Y H,Lin J,Wang S B,et al.Preparation of Y_3Al_5O_(12):Eu phosphors by citric-gel method and their luminescent properties[J].Optical Mater,2002,20:13
22.Zupan K,Kolar D,Marinsek M.Influence of citrate-nitrate reaction mixture packing on ceramic powder properties[J].J Power Sources,2000,86:417
23.Juarez R E,Lamas D G,Lascalea G E,et al.Synthesis of nanocrystalline zirconia powders for TZP ceramics by a nitrate-citrate combustion route[J].J Euro Ceram Soc.,2000,20:133
24.Paul A Lessing.Mixed-cation oxide powders via polymericprecursorsl[J].Cramic Bulletin,1989,68(5):1002
25.Zeng Y,Lin Y S.Synthesis and properties of copper and samarium doped yttriabismuth oxide powders[J].J Mater Sci,2001,36(5):1271
26.霍地,杨洪才.用柠檬酸溶胶凝胶法合成SrFeCo_(0.05)O_x氧化物[J].东北大学学报,2003,24(1):61
27.Chroma M,Pinkas J,Pakutinskiene I,Beganskiene A,Kareiva A,Ceram Int.Processing and characterization of sol-gel fabricated mixed metal aluminates[J].Ceramics International,2005,31:11
28.罗岚,徐政,刘庆峰等.GdAlO3:Eu~(3+)荧光粉燃烧法合成及其发光性能[J].同济大学学报(自然科学版),2004,32(11):1476
29.Cizauskaite S,Reichlova V,Nenartaviciene G,Beganskiene A,Pinkas J,Kareiva A..Sol-gel preparation and characterization of gadolinium aluminate[J].Materials Chemistry and Physics,2007,102:105
30.Sugiyama A,Araki S J,Sakamoto N,et al.Fabrication of amorphous bulk and multi-phase ceramics by melting method in the HfO_2-Al_2O_3-Gd_2O_3-Eu_2O_3 system[[J].J Electroceram,2006,17:71
31.Lakiza S,Fabrichnaya O et al.Phase diagram of the ZrO_2-Gd_2O_3-Al_2O_3[J].J Ceram Soc,2006,26:233
32.Lakiza S M,Lopato L M.Stable and metastable phase relations in the system a lumina-zirconia-yttria [J].J Am Ceram Soc,1997,80(4):893
33.Rouanet A,Foex.Study at high temperatures of the systems formed by ZrO_2 with the Sm_2O_3 and Gd_2O_3[J].C R Acad Sci,1968,C267(15):873
34.Euler F,Bruce J A.Oxygen coordinates of compounds with garnet structure[J].Acta Cryst.1965,19:971
35.Shishido T.Phase diagram estimation of the Al_2O_(3-)SiO_2-Re_2O_3 systems[J].J Mater Sci,1979,14:823
36.Zych E,Brecher C.Host-associated luminescence from YAG optical ceramics under gamma and optical excitation[J].Journal of Luminescence,1998,78(2):121
37.Schlotter P,Schmidt R,Scheider J A.Host-associated luminescence from YAG optical ceramics under gamma and optical excitation[J].Journal of Luminescence,1998,78(2):121-134.
38.Seong Ju Park,Hui Dong Park,Seo Su.Method for manufactureing cerium dope dyttrium aluminum garnet yellow phosphors for white luminescent devices.[P]Korean Patent, 200023225,2000.
39. Lu Chung Hsin, Jagannathan R. Cerium-ion-doped yttrium aluminum garnet nanophosphors prepared through sol-gel pyrolysis for luminescent lighting[J]. Appl Phys Lett, 2002, 80(19):3608
40. Kolitsch U, Seifert H J, Aldinger F. Phase relationships in the system Gd_2O_3-Al_2O_3- SiO_2 [J]. J Alloys Compds,1997, 257: 104
41. Chaudhury S, Parida S C, Pillai K T, Singh Mudher K D.High-temperature X-ray diffraction and specific heat studies on GdAlO_3, Gd_3Al_5O_(12) and Gd_4Al_2O_9[J]. Journal of Solid State Chemistry,2007,180:2393
42. Kanke Y, Navrotsky A J. Thermo chemistry of Complex Perovskites[J].Solid State Chem, 1998,141:424
43. Kanke Y, Navrotsky A. Thermochemistry of Complex Perovskites[J]. J Solid State Chem, 1998,141:424
44. Budnikov P P, Kushakovskij V I, Belevantsev V S. Investigation of the systems Al_2O_3-Sm_2O_3 and Al_2O_3-Gd_2O_3[J]. Dokl. AN SSSR, 1961, 9(3):744
45. Mizuno M, Yamada T, Noguchi T. Phase Equilibria in the Gd_2O_3-SrAl_2O_4 System[J]. J Ceram Soc Jpn, 1977, 85(11):543
1. Kennedy K, Stefansky T, Davy G et al. Rapid method for determining termary-alloy phase diagrams[J]. J Appl Phys, 1965, 36:3808
2. Hanak J J. The "multiple-sample concept" in materials research: synthesis, compositional analysis and testing of entire multi component systems [J]. J Mater Sci, 1970, 5:964
3. 董安钢,唐颐.浅谈组合化学[J].大学化学, 2000, 15(5): 8
4. Fu W T, Zandbergen H W, et al. On the red phosphor of nominal compostion Gd_(0.77)Al_(1.23)O_x:Eu_(0.06)( x≈3.1) [J]. Material research bulletin, 2004, 39: 909
5. Bagnato V S, Nunes L A O, Zilio S C, et al. Infrared electronic transitions of Eu~(3+) in GdAlO_3[J].State Communications, 1984,49(1):27
6. Padua S J N, Nunes L A O, et al. absorption and luminsecence spectroscopy of GdAlO_3: Eu~(3+)[J].J Lumin, 1989,43:379
7. Kuroiwa Y, Aoyagi S , Sawada A et al. Evidence for Pb-O Covalency in Tetragonal PbTiO_3[J].Phys Rev Lett ,2001, 87: 217601:1
8. Pari G, Mookerjee A , Bhattacharya A K. First-principles electronic structure calculations of R_3 Al_5O_(12) (R being the rare-earth elements Ce-Lu) [J].Physica B,2005,365: 163
9. Chikashi S, Jun Kawai, Masao T, et al. The electronic structure of rare-earth oxides in the creation of the core hole[J]. Chemical Physics, 2000, 253: 27
10. Liu Qing feng. Liu Qian, Luo Lan. Preparation and luminescent properties of Eu-doped Ln_2O_3 (Ln = Gd, Lu) thin film by citrate sol-gel process[J]. Ceramics International,2004,30:1703
11. Narihito Nakagawa , Hideki Ohtsubo, Atsuyuki Mitani, Kazuto shiShimizu, Yoshiharu Waku. High temperature strength and thermal stability for melt growth composite[J]. Journal of the European Ceramic Society,2005,25:1251
12. Yohei Harada, Kazuya Ayabe , Naofumi Uekawa ,Takashi Kojima, Kazuyuki Kakegawa ,SungJin Kim.Formation of GdAlO_3 -A1_2O_3 composite havingfine pseudo-eutectic microstructure[J]. Journal of the European Ceramic Society,2008,28:2941
13. Gouadec G,. Colomban Ph, Piquet N , Trichet M F, Mazerolles L. Raman/Cr~(3+) fluorescence mappingof a melt-grown Al_2O_3/GdAlO_3 -eutectic[J]. Journal of the European Ceramic Society,2005,25:1447
14. Andreeta E RM, Andreeta MRB, Hernandes A C. Laser heated pedestal growth of Al_2O_3/GdAlO_3 eutectic fibers[J] Journal of Crystal Growth,2002, 234: 782
15. Kohn W, Sham L J. Self-consistent equation including exchange and correlation effects[J]. Phys Rev, 1965, 140:A1133
16. Aryasetiawan F. G W method for 3d and 4f systems[J]. Physica B, 1997,237-238 : 321
17. Anisimov V I, Zaanen J, Andersen O K, Band theory and Mott insulators: Hubbard U instead of Stoner[J]. Phys Rev B, 1991,44: 943
18. Anisimov V I, Gunnarsson O, Density-functional calculation of effective Coulomb interactions in metals[J]. Phys Rev B, 1991,43:7570
19. Anisimov V I, et al, Density-functional theory and NiO photoemission spectra[J]. Phys Rev B,1993,48:16929
1.方容川.固体光谱学[M].合肥:中国科学技术大学出版社,2001:134
2. Mares J A, Pedrini C, Optical studies of Ce~ (3+)-doped gadolinium aluminium perovskite single crystals [J]. Chem Phys Lett, 1993,206: 9.
3. Mares J A, Nikl M. Fluorescence and scintillation properties of LuAlO_3:Ce crystal [J]. Chem Phys Lett, 1995,241:311.
4. Dorenbos P, Bougrine E. Scintillation properties of GdAlO_3: Ce crystals[J]. Radiation Effect and Defects in Solids, 1995, 135: 321.
5. 郭常新,柏善岩.Gd_xY_(1-x)P_5O_(14):Ce,Tb的发光和能量传递[J].中国稀土学报, 1995,13(2): 123
6. Lei Bingfu, et al. Pink light emitting long-lasting phosphorescence in Sm~(3+)-dopedCdSiO_3[J].Journal of Solid State Chemistry, 2004, 177: 1333
7. 孙小琳,张桂兰,等.CaS: Sm~(3+)中Sm~(3+)的发光特性与其格位对称性的相关性[J].南开大学(Acta scienitiarum naturalium universitatis nankaiensis), 1999,32(3): 15
8. 黄立辉,等.Sm~(3+)掺杂的镉铝硅酸盐玻璃的光谱特性[J].红外与毫米波学报,2001, 20: 44
9.张晓,等.CaSiO_3:Ce,Mn体系中Ce,Mn的能量传递研究[J],发光学报,1992,13(1):1
10.胡林学,宋功武.稀土五硼酸盐中锰(II)的光致发光研究[J].湖北大学学报(自然科学版),1994,16:82
11. Frumarovaa B, Bilkova M B , et al.Thin films of Sb_2S_3 doped by Sm ions[J]. Journal of Non-Crystalline Solids, 2003, 326-327: 348
12.何志毅,等.(Ca,Sr)S:Eu,Sm的光激励发光和电子俘获机理的研究[J].光电子激光,2003,14(7):729
13.张希艳,刘全生,卢利平,等.CaS:Ce,Sm的制备及性能表征[J].无机化学学报,2005,21(5):667
14.余雪,徐海刚,殷江,张伟风.L~(3+)离子掺杂Gd_2O_3:Sm~(3+)纳米品的发光增强[J].发光学报,2007,28(5):754
15. Zhou Y H, Lin J, et al. Energy transfer and upconversion luminescence properties Y_2O_3:Sm and Gd_2O_3 :Sm phosphors[J]. Journal of Solid State Chemistry , 2003, 171:391
16. Amitava P , Renata R , Harry M. Influence of aluminium oxide on intensities of Sm~(3+) and Pr~(3+)spectral transitions in sol-gel glasses[J]. Materials Letters, 1998,37: 325
17.Chu B L,Guo C F,Su Q.Luminescence andenergy transfer in Gd_2Y_xLn_(7.9-x)(SiO_4)_6O_2(Ln=Sm,Dy,Eu)[J].Materials Chemistry and Physics,2004,84:279
18.Lange S,Kiisk V,et al.Luminescence of RE-ions in HfO_2 thin films and some possible applications[J].Optical Materials,2006,28:1238
19.Kodaira C A,Stefani R,et al.Optical investigation of Y_2O_3:Sm~(3+) nanophosphor prepared by combustion and Pechini methods[J],Journal of Luminescence,2007
20.黎明,刘晓华,陈绍军,王孝东.CeO2:Sm3+荧光粉的发光特性研究[J],中国材料科技与设备,2006,6:43
21.藏竞存,刘燕行,等.ZnWO_4:Sm晶体光谱与上转化发光[J].物理学报,1998,47(1):117
22.Gaft M,Nagli L,et al.Laser-induced time-resolved luminescence of natural titanite CaTiOSiO_4[J].Optical Materials,2003,24:231
23.Yan B,Xiao X Z.Novel YNbO_4:RE~(3+)(RE=Sm,Dy,Er) microcrystalline phosphors:Chemicalco-precipitation synthesis fromhybridprecursor and photoluminescent properties[J].Journal of Alloys and Compounds,2007,433:251
24.Malchukova E,Boizot B,et al.Optical properties and valence state of Sm ions in aluminoborosilicate glass under b-irradiation[J].Journal of Non-Crystalline Solids,2007,353:2397
25.Eugenia Malchukova,Bruno Boizot,et al.Optical properties of pristine and g-irradiated Sm doped borosilicate glasses[J].Nuclear Instruments and Methods in Physics Research,2005,537A:411
26.SouzaFilho A G,MendesFilbo J,et al.Optical properties of Sm~(3+) doped lead fluoroborate glasses[J].Journal of Physics and Chemistry of Solids,2000,61:1535
27.于健,刘又年,陈立妙,黄可龙.Sm3+掺杂CaOSiO2B203发光玻璃的制备、表征及性质[J].无机化学学报,2006,22(2):248
28.李宝祥,韩尧,路冰宇,吕玉华.Sm~(3+)在玻璃中的发光以及Sb~(3+)、Ce~(3+)、Gd~(3+)对Sm~(3+)发光性质的影响[J].发光学报,1993,14(1):53
29.Cooke D W,Muenchausen R E,et al.Spectral emission of rare-earth doped Lu_2SiO_5 single crystals[J].Optical Materials,2005,27:1781
30.Li Y C,Chang Y H,et al.Synthesis and luminescent properties of Ln(Eu~(3+),Sm~(3+),Dy~(3+))-doped lanthanum aluminum germanate LaAlGe_2O_7 phosphors[J].Journal of Alloys and Compounds,2007,439:367
31.Meng Q B,Wuand Z J,et al.The bond ionicity in RBa_2Cu_3O_7(R=Pr,Sm,Eu,Gd,Dy,Y,Ho,Er,Tm)[J].J Phys Condens Matter,1998,10:L85
32.贺香红.LED用红色荧光粉SrZnO_2:Sm~(3+),Li~+的合成与发光性能[J].稀有金属材料与工程,2007,36(9):1574
33.赵春燕,朱连杰,等.BaBeF_4:Sm~(3+)的温和水热合成与光谱特性质研究[J].高等化学学报1998,19(7):1023
34.张国春,吴以成,傅佩珍。,王国富,郭范,陈创天.一种新的非线性光学材料(?)Na3Sm2(BO3)3[J].人工晶体学报,2001,30(3):227
35.杨殿来,林海,侯嫣嫣,等.Sm3+掺杂稀土硼酸盐玻璃的光谱参数计算和荧光光谱分析[J].光谱学与光谱分析,2006,26(1):87
36.郭风瑜.REBO_3中Ce和Bi针对sm致发光的影响[J].无机化学学报,1993,9(1):83
37.Qinghua Zeng,Zhiwu Pei,et al.Luminescence of RE(RE=Sm,Yb) in barium octoborate[J].Materials Research Bulletin,1999,34:1837
38.Stefani R,Maia A D,et al.Photoluminescent behavior of SrB_4O_7:RE(RE=Sm and Eu) prepared by Pechini,combustion and ceramic methods[J]Journal of Solid State Chemistry,2006,179:1086
39.裴治武,苏锵.Dy~(3+),Sm~(3+)和Ce~(3+)离子在M_3la_2(BO_3)_3(M=Ca,Sr,Ba)中光谱性质的研究[J].发光学报,1989,10(3):213
40.Liang H B,Xu J H,et al.The VUV-vis spectroscopic properties of phosphors Ca_3Gd_(2(1-x))Ln_(2x)(BO_3)_4(Ln=Ce,Sm,Eu,Tb)[J].Materials Research Bulletin,2006,41:1468
41.张国春,傅佩珍,王国富,郭范,官向国.Na_3La_2(BO_3)_3:Sm~(3+)的合成及其光谱特性[J].发光学报,2001,22(3):237
42.魏新姣,杨中民,刘粤惠,陈东丹Ce~(3+)/Sm~(3+)掺杂硼硅酸盐玻璃的制备及发光性能分析[J]武汉理工大学学报,2007,29(专辑1):248
43.曲雅焕,于亚勤,张思远.GdP_5O_(14):Sm~(3+),Pr~(3+)晶体生长,光谱和离子间的能量传递[J].应用化学,2000,17(3),341
44.任金生,王庆元,张思远.SmP_5O_(14)晶体中Sm离子能级和晶场参数[J].发光学报,1989,10(3):212
45.Rambabu U,Rajamohan Reddy IK,Annapurna K,Balaji T,et al.Fluorescence spectra of Sm3+-doped lanthanide oxychioride powder phosphors[J].Materials Letters,1996,27:59
46.杨频,等.Sm与Nd离子在LaOX系列基质中的配位场微扰能级及其光谱解析[J].无机化学学报,1991,7(3):338
47.刘金霞,吕树臣,李秀明.纳米晶ZrO2:Pr3+与ZrO2:Pr计,Sm3+发光研究[J].光谱学与光谱分析,2006,26(4):605
48.刘金霞,吕树臣,李秀明.纳米晶ZrO2:Sm3+的制备与发光性质研究[J].中国稀土学报,2004,22(6):867
49.黄立辉,林海,刘行仁,林久令.Sm~(3+)掺杂的镉铝硅酸盐玻璃的光谱特性[J].红外与毫米波学报,2001,(2):201
50.Alberthmeiry T F,Valeria M L,et al.Blue-green and red photoluminescence in CaTiO_3:Sm[J].Journal of Luminescence,207,126:403
51.贺香红,周健,连宁.发光颜色可调谐的新型荧光体Sr2CeO4:RE3+(RE=Eu,Sm,Dy)发光性能[J].稀有金属材料与工程,2007,36(5):759
52.Yap Kang,Wang Mingwen,et al.Effects of Host Doping on Spectral and Long-Lasting Properties of Sm~(3+) -Doped Y_2 O_2 S[J].J rare earth,2006,24:524
53.赵广军,徐军.高光输出快衰减高温无机闪烁晶体的研究与发展[J].人工晶体学报,2002,31(3):291.
54.Baccaro S,Blazek K,De Notaristefani F.Scintillation properties of YAP:Ce[J]J Nucl Instr Meth Phys Res A,1995,361:209.
55.Klamra W,Kerek A,Moszyski M,Norlin L O,et al.Response of BaF2 and YAP:Ce to heavy ions[J].Nucl Instr Meth A,2000,444:626.
56.Slunga E,Cederwall B,Ideguchi E,Kerek A,et al.Scintillation response of BaF2 and YAlO3:Ce(YAPCe)to energetic ions[J].Nucl Instr Meth A,2001,469:70.
57.Hirota K,Toyokawa H,Suzuki M,Kudo T,et al.YAP(ce) imager operated in high energy X-ray region[J].Nucl Instr Meth A,2001,467-468:112
58.ZhydachevskiiY,Suchocki A,Berkowski M,Zakharko Ya.Optically stimulated luminescence of YAlO_3:Mn~(2+) for radiation dosimetry[J].Radiation Measurements,2007,42:625
59.Zhydachevskii Y,Durygin A,Suchocki A,Matkovskii A,et al.Radiation and thermally induced effects in YalO_3:Mn crystals[J]Journal of Luminescence,2004,109:39
60.张晓,等.Ce~(3+)和Mn~(2+)共激活的偏硅酸钙的发光性质和能量传递[J],硅酸盐学报,1989,17(2):140
61.Lei bingfu,et al.Luminescence properties of CdSiO_3:Mn~(2+) phosphor[J].J Lumin,2004,109:215
62.Belsky A N,Krupa J C.Luminsecence excition mechanisms of rare doped phosphors in the VUV range[J].Display,1990,19:185
1.Thiel C W,Cruguel H,Sun Y,et al.LapeyreSystematics of 4f electron energies relative to host bands by resonant photoemission of rare earth doped optical materials[J]Journal of Luminescence,2001,94-95:1
2.Xu Y N,Ching W Y,Brickeen B K,Electronic structure and bonding in garnet crystals Gd_3Sc_2Ga_3O_(12),Gd_3Sc_2Al_3O_(12),and Gd_3Ga_3O_(12) compared to Y_3Al_3O_(12)[J].Phys Rev B,2000,61:1817.
3.Thiel C W,Cruguel H,Wu H,et al.Systematies of 4f electron energies relative to host bands by resonant photoemission of rare-earth ions in aluminum garnets[J].Phys Rev B,2001,64:085107.
4.Yatsimirkii K B,Dacidenko N K.Absorption spectra and structure of lanthanide coordination compounds in solution[J].Coordination Chemistry Reviews,1979,27:223
5.Blasse G,et al.Fluorescence of Eu~(2+) Activated Silicates[J].Philips Res Repts,1968,23:201
6.Blasse G,Bril A.Investigations of Tb~(3+-) activated phosphors[J].Philips Res Repts.,(1967),22,481
7.Dexter D L,Schulman J H.Concentration and excitation effects in multiphonon non-radiative transitions of rare-earth ions[J].J Chem Phys,1954,22(6):1063
8.Dexter D L.A theory of sensitized luminescence in solids[J]J Chem Phys,1953,21:83
9.Perrin F.L'association moleculaire et l'optimum de la fluorescence des solutions.Influence des sels[J].Comptes Rendus,1931,192:1727
10.Forster Th,Annalen der Physik Zwischenmolekulare Energiewanderung und Fluoreszenz [J].1948,6(2):55
2. Hanak J J. The "multiple-sample concept" in materials research: synthesis, compositional analysis and testing of entire multicomponent systems[J]. J Mater Sci, 1970, 5:964
3.董安钢,唐颐.浅谈组合化学[J].大学化学,2000,15(5):8
4. Wolf D, Buyevskaya O V, Baerns M. An evolutionary approach in the combinatorial selection and optimization of catalytic materials[J]. Appl Catalysis A:General, 2000, 200:63
5. Jaramillo T F , Ivanovskaya A, McFarland E W. High-throughput screening system for catalytic hydrogen-producing materials[J]. J Comb Chem, 2002,4:17
6. Xiang X D, Sun Xiaodong, et al. A Combinatorial Approach to Materials Discovery[J], Science,1995,268:1738
7. Sun X D, Gao C, Wang J, et al. Identification and optimization of advanced phosphors using combinatorial libraries[J]. Appl Phys Lett., 1997, 70 :3353
8. Sun X D, Xiang X D. New phosphor (Gd_(2-x)Zn_x)O_(3-δ):Eu~(3+) with high luminescent efficiency and superior chromaticity[J]. Appl Phys Lett., 1998, 72 :525
9. Danielson E, Golden J H, et al. A combinatorial approach to the discovery and optimization of luminescent materials[J]. Nature, 1997, 389:944
10. Danielson E, Devenney M, et al. A rare-earth phosphor containing one-dimensional chains identified through combinatorial methods[J]. Science, 1998,279:837
11. Wang J S, Yoo YK et al. Identification of a blue photoluminescent composite material from a combinatorial library[J]. Science, 1998, 279:1712
12. Yoo Y K, Ohnishi T, Wang G, et al. Continuous mapping of structure-property relations in Fc_(1-x)Ni_x metallic alloys fabricated by combinatorial synthesis[J]. Intermetallics, 2001,9(7):541
13. Cremer R, Neuschutx D. Optimization of(Ti, Al)N hard coating by a combinatorial approach[J].Inter J Inor Mater., 2001,3:1181
14. Takahashi R, Matsumoto Y, Koinuma H, et al. Combinatorial optimization of atomically controlled growth for oxide films by the carrousel type laser molecular beam epitaxy[J]. Appl Surf Sci, 2002, 197-198:532
15. Perkins J D, Cueto JA D, Alleman J K, et al. Combinatorial studies of Zn-Al-O and Zn-Sn-O transparent conducting oxide thin films[J]. Thin Solid films, 2002,411:152
16. Laversenne L, Kariouani S, Guyot Y,et al. Correlation between dopant content and excited-state dynamics properties in Er~(3+)-Yb~(3+)-codoped Y_2O_3 by using a new combinatorial method[J].Optical Materials, 2002, 19: 59
17. Grobhans I, Kari H, Stritzker B, Combinatorial synthesis of ZnTe nanocrystals in SiO_2 on silicom y ion implantation[J]. Nucl Instru &Method in Phys ResB, 2002, 190: 865
18. Hasegawa T, Kageyama T, Fukumura T, et al. High-throughput characterization of composition-spread manganese oxide films with a scanning SQUID microscope[J]. Applied Surface Sci.,2002,189:210
19.冯兰,顾明,蔡英文.制备材料芯片的K分分形掩膜策略[J].高技术通讯,2004,6:39
20.Takeuchi I,Chang H,Gao C et al.Combintorial synthesis and evaluation of epitaxial ferroelectric device libraries[J].Appl Phys Lett,1998,73(7):894
21.Chang H,Takeuchi I,Xiang X D.A low-loss composition region identified from a thin-film composition spread of(Ba_(1-x-y)St_xCa_y)TiO_3[J].Appl Phys Lett,1999,74(8):1165
22.Yoo Y K,Tsui F,Continuous phase diagramming of epitaxial films[J].MRS Bulletin,2002,27(4):316
23.Yoo Y K,Duewer F,Yang H,et al.Room-temperature electronic phase transitions in the continuous phase diagrams of perovskite manganites[J].Nature,2000,406(17):704
24.田明波,刘德令.薄膜科学与技术手册[J].机械工业出版社出版,1991
25.Sun X D,Wang K A,Yoo Y K,et al.Solution-phase synthesis of luminescent materials libraries[J].Adv Mater,1997,9(13):1046
26.Evans J RG,Edirisinghe M J,Coveney P V,et al.Combinatorial searches of inorganic materials using the ink-jet printer:science,philosophy and technology[J].J Euro Ceram Soc,2001,21:2291
27.Tay B Y,Edirisinghe M J.Investigation of some phenomena occurring during continuous ink-jet printing of ceramics[J].J Mater Res,2001,16:373
28.Mott M,Song J H,Evans J RG.Microengineering of ceramics by direct ink-jet printing[J].J Am Ceram Soc,1999,82:1653
29.Teng W D,Edirisinghe M J.Development of ceramic inks for direct continuous jet printing[J].J Am Ceram Soc,1998,81:1033
30.Minami H,Itaka K,Kawaji H et al.Rapid synthesis and characterization of(Ca_(1-x)Ba_x)_3Co_4O_9thin films using combinatorial methods[J].Appl.Sur.Sci.,2002,197-198:442
31.Kim T W,Arai N,Kubota H,et al.Re-evaporation effect on the surface morphology of Gd_xY_(1-x)Ca_4O(BO_3)_3 films grown by combinatorial laser molecular-beam epitaxy[J].Appl Sur Sci,2002,197-198:406
32.Koinuma H.Combinatorial materials research projects in Japan[J].Appl Sur Sci.,2002,189:179
33.Matsumoto Y,Murakami M,Hasegawa T,et al.Structural control and combinatorial doping of titanium dioxide thin films by laser molecular beam epitaxy[J].Appl Sur Sci.,2002,189:344
34.Briceno G,ChangH,Sun X D et al.A class of cobalt oxide magnetoresistance materials discovered with combinatorial synthesis[J].Science,1995,270:273
35.Xiang X D.Combinatorial synthesis and high throughput evaluation of functional oxides-A integrated materials chip approach[J].Mater Sci Eng,1998,B56:246
36.Dagani R.A faster route to new materials[J].C&EN,1999,77(10):51
37.Dover RB V,Schneemeyer L F,et al.Discovery of a useful thin-film dielectric using a composition-spread approach.Nature,1998,392:162
38.Takeuchi I.Experimental issues in combinatorial investigation of electronic thin-film materials[J].Appl Sur Sci,2002,189:353
39.Chang K S,Aronova M,Famodu O,et al.Multimode quantitative scanning microwave microscopy of in situ grown epitaxial Ba_(1-x)Sr_xTiO_3 Composition spreads[J].Appl.Phys Lett,2001,79(26):4411
40.Miller N C,Shirn G A.Co-sputtering Au-SiO_2 cermet films[J].Appl Phys Lett,1967,10:86
41.Hornbostel M D,Hyer E J et al.Rational synthesis of metastable skutterudite compounds using multilayer precursors[J].J Am Chem Soc,1997,119:2665
42.Fister L,Johnson D C.Synthesis of Cu_xMo_6Se_8 without Binary Compounds as Intermediates:A study using superlattices to kinetically control a solid-state reaction[J].J Am Chem Soc,1994,116:629
43.Fukumura T,M.Ohtani,J.Nishimura et al.Temperature-gradient and composition-spread deposition of epitaxial oxide films and high throughput characterization.Proceedings of SPIE,2001,4281:8
44.郭杏元,刘庆峰,刘茜.高密度无机功能材料芯片快速表征技术的发展[J].无机材料学报,2002,17(3):392
45.Isaacs E D,Marcus M.Synchrotron x-ray microbeam diagnostics of combinatorial synthesis[J].Appl.Phys Lett.,1998,73:1820
46.Omote K,Kikuchi T,J Harada et al.A convergent beam,parallel detection x-ray diffraction system for characterizing combinatorial epitaxial thin films[J].Proceedings of SPIE,2000,3941:84
47.Takeuchi I,Dover R B V,Koinuma H.Combinatorial synthesis and evaluation of functional inorganic materials using thin-film techniques[J].MRS Bulletin,2002,27(4):301
48.www.Bruker-axs.com
49.高琛,项晓东,吴自勤.发现和优化新材料的集成材料芯片法[J].物理,1999,28(11):675
50.Takahashi R,Kubota H,Murakami M,Yamamoto Y,Matsumoto Y,and Koinuma H.Design of Combinatorial Shadow Masks for Complete Ternary-Phase Diagramming of Solid State Materials[J].J Comb Chem 2004,6:50
51.Takahashi R,Kubota H,Tanigawa T,Murakami M,Yamamoto Y,Matsumoto Y,Koinuma H.Development of a new combinatorial mask for addressable ternary phase diagramming:application to rare earth doped phosphors[J]Applied Surface Science,2004,223:249
52.Hiroyuki Sano,Takahiro Matsumoto,Yuji Matsumoto,Hideomi Koinuma.RECa_4O(BO_3)_3thin films as new Luminescent materials screened by the combinatorial method[J]Journal of Physics and Chemistry of Solids,2005,66:2112
53.Hiroyuki Sano,Yuji Matsumoto,Takahiro Matsumoto,Hideomi Koinuma.A combinatorial approach to the discovery and optimization of YCa_4O(BO_3)_3-based luminescent materials[J].Applied Surface Science,2006,252:2493
54.Jennifer Licia Wu,Earl Danieison,et al.Combinatorial synthesis and screening of cerium doped garnets phosphors for application in White GaN-based LEDS[J].Proc Spie,2001,4445:7
55.Jennifer Licia Wu.A combinatorial chemistry approach to understanding optical properties of cerium doped gamets[D].Doctor thesis of University of California Santa Barbara,2003
56.Chang Hae Kim,Sang Mi Park,Joung Kyu Park,Hee Dong Park,Kee-Sun Sohn,and Joon Taik Park.Combinatorial Synthesis of Tb-Activated Phosphors in the CaO-Gd_2O_3 -Al_2O_3 System[J].Journal of The Electrochemical Society,2002,149(12):H183
57.Soo Yeon Seo,Kee-Sun Sohn,Hee Dong Park,and Seonghoon Lee.Optimization of Gd_2O_3-Based Red Phosphors Using Combinatorial Chemistry Method[J].Journal of The Electrochemical Society,2002,149(1):H12
58.Kee-Sun Sohn,Duk Hyun Park,Sang Ho Cho,Byung Il Kim,and Seong Ihl Woo.Genetic AlgorithmAssisted Combinatorial Search for a New Green Phosphor for Use in Tricolor White LEDs[J].J Comb Chem,2006,8:44
59.Kee-Sun Sohn,Duk Hyun Park,Sang Ho Cho,Joon Seop Kwak,and Ji Sik Kim.Computational Evolutionary Optimization of Red Phosphor for Use in Tricolor White LEDs[J].Chem Mater.2006,18:1768
60.Duk Hyun Park,Sang Ho Cho,Ji Sik Kim,Kee-Sun Sohn.Combinatorial screening of Eu dopedTiO_2 -Y_2O_3 -Gd_2O_3 ternary system at soft UV excitation[J].J Alloys and Compounds,2008,449:196
61.Lei Chen,Jun Bao,and Chen Gao.Combinatorial Synthesis of Insoluble Oxide Library from Ultrafine/Nano Particle Suspension Using a Drop-on-Demand Inkjet Delivery System.J Comb.Chem,2004,6:699
62.Chen Lei,Liu Zhonghai,Shen Lei,et al.Ultrafine/nano suspensionsprepared by rare earth oxides high-energy ballmilled in purewater[J].Acta Phys.Chin.Sin(物理化学学报),2004,20:722.
63.Liu X N,Cui H B,Tang Y,et al.Combinatorial screening for new borophosphateVUV phosphors[J].Appl Surf Sci 2004,223:144
64.Zhen-Lin Luo,Bin Geng,Jun Bao,and Chen Gao.Parallel Solution Combustion Synthesis for Combinatorial Materials Studies[J].J Comb Chem,2005,7:942
65.Ting-Shan Chan,Chia-Chen Kang,Ru-Shi Liu,Lei Chen,Xiao-Nan Liu,Jian-Jun Ding,Jun Bao,and Chen Gao.Combinatorial Study of the Optimization of Y_2O_3:Bi,Eu Red Phosphors[J]J Comb Chem,2007,9:343
1.刘光华.稀土固体材料学[M].北京:机械工业出版社,1995.
2.朱裕贞.工科无机化学[M].上海:华东理工大学出版社,1993
3.方容川.固体光谱学[M].合肥:中国科学技术大学出版社,2001
4.尹民,Khaidukov N M,Krupa J C Site selective excitation and energy transfer in LiKGdF_5crystal co-doped with Er~(3+) and Tb~(3+)[J].J Rare Earths,2004,22(1):22
5.李铭华,黄竹坡.Eu~(2+)在碱土金属氯磷酸盐中的发光[J].中国稀土学报,1990,8(1):26
6.王齐祖,田军.Tb~(3+)、Dy~(2+)激活的LaBO_3发光和能量传递[J].发光学报,1995,16(1):57
7.Dexter D L.A Theory of Sensitized Luminescence in Solids[J].J Chem Phys,1953,21:836
8.Cshin J D,Cooke A H..Magnetic Properties of Antiferromagnetic GdAlO_3[J].J Appl Phys,1968,39:1360
9.Blazey K W,Rohrer H.Antiferromagnetism and magnetic phase diagram of GdAlO_3[J],Rhysical Review,1968,173:574
10.Lo J R,Tseng T Y.Effect of Licl on the crystallization behavior and luminescence of Y_3Al_5O_(12):Tb[J].Mater Sci Comm,1998,57:95
11.Brandle C D,Steinfink H.The Crystal Structure of Eu_4Al_2O_9[J].Inorg Chem,1969,8:1320
12.Baccaro S,Blazek K.Scintillation properties of YAP:Ce[J].Nucl Instrum Meth,1995,A361:205
13.Baryshevsky V G,Korzhik M V.Ce-fast-acting scintillators for detection of ionizingradiation[J].Nucl Instrum Meth,1991,B58:291
14.Andreeta J P,Jovanie B R.Growth and optical properties of Cr~(3+) doped GdAlO_3 single crystals [J].Mater Res,2000,3(2):45
15.Mares J A,Pedrini C,Optical studies of Ce~(3+)-doped gadolinium aluminium perovskite single crystals[J].Chem Phys Lett,1993,206:9
16.Mares J A,Nikl M.Fluorescence and scintillation properties of LuAlO_3:Ce crystal[J].Chem Phys Lett,1995,241(4):311
17.Dorenbos P,Bougrine E.Scintillation properties of GdAlO_3:Ce crystals[J].Radiation Effect and Defects in Solids,1995,135:321.
18.Verweij J W M,Cohen-Adad M Th.Luminescence properties of GdAlO_3:Ce powders.Dependence on reduction conditions[J].Chem Phys Lett,1995,239:51
19.罗岚,徐政,刘庆峰等.GdAlO3:Eu3+荧光粉燃烧法合成及其发光性能[J].同济大学学报(自然科学版),2004,32(11):1476
20.Fu W T,Zandbergen H W,et al.On the red phosphor of nominal compostion Gd_(0.77)Al_(1.23)O_x:Eu_(0.06)(x≈3.1)[J].Material research bulletin,2004,39:909
21.Tsuyoshi Y,Michihiro A,et al.Ce~(3+) centers in YAlO_3(YAP) single crystals[J].J Physical Society of Japan.1995,64:4442
22.Sakurai K J,Guo X M.Mechanical solid-state formation of Y_(1-x)Ce_xAlO_3 and its application as an X-ray scinitillator[J].Mater Sci and Eng,2001,304-306:403
23.Peculiarities of luminescence and sintillation properties of YAP:Ce and LuAP:Ce single crystals and single crystalline films[J].Radiation Measurements,2007,42:528
24.Yasuda K,Usuda S,et al.Properties of a YAP powder scintillator as alpha-ray detector[J].Appl Radi and Iso,2000,52,365
25.Petrosyan A G,Ovanesyan K L,et al.Growth and light yield performance of dense Ce~(3+)-doped (Lu,Y)AlO_3 Solid solution crystals[J].J Crystal Growth,2000,211:252
26.Zerenko Y,Gorbenko V,et at.Luminescence of La~(3+) and Sc~(3+) impurity centers in YAlO_3 single-crystal films[J].J Lumin,2008,128:595
27.Luria E,Rotman S R,et al.Energy transfer between Cr~(3+) and Nd~(3+) in Cr,Nd:YAP[J].J Lumin,1997,72-73:951
28.Lancok J,Jelinek M,et al.Structural and optical characterisation of Nd doped YalO_3 films deposited on sapphire substrate by pulsed laser deposition[J].Thin Solid films,1999,346:284.
29.Akira Y,Martin N,et al.Chanllenge and study for developing of novel single crystalline optical materials using micro-pulling-down method[J].Optical Materials,2007,30:6
30.Han S D,Khatkar S P,et al.Combustion synthesis and luminescent properties of Eu~(3+)- doped LnAlO_3(Ln=Y and Gd) phosphors[J].Material Scienc and Engineering,2006,127:272
31.Luo L,Xu Z,Liu Q F,Liu Q.Preparation of combinatorial libraries of gadolinium aluminate film and its luminescent properties[J].Journal of The Chinese Ceramic Society,2004,32(11):1325
32.Luo L,Xu Z,Liu Q F,Liu Q.Luminescent properties and mechanism of co-doped GdAlO_3:Eu,RE[J].Chinese Physics Letters,2005,22(1):132
33.罗岚,刘庆峰,刘茜.Gd_(1-x)AlO_3:Eu_x~(3+)梯度材料芯片制备及发光性能研究[J].稀有金属材料与工程,2005,34(8):1310
34.Luo L,et al.Preparation and Luminescence properties of Gadolinium Acuminate Phosphor Material Chip[J].Journal of rare earths,2005,23(12)sup:36
35.Luo L,Liu Q F,Liu Q.Synthesis and luminescent properties of GdAlO_3:RE by combustion process[J].Journal of rare earths,2004,22(12)sup:268
36.罗岚,陈栋,等.GdAlO3:Tb,RE中Tb,RE的能量传递研究[J],影像科学与光化学,2008,26(3):233
37.Han S D,Khatkar S P,et al.Combustion synthesis and luminescent properties of Eu~(3+)- doped LnAlO_3(Ln=Y and Gd) phosphors[J].Material Scienc and Engineering,2006,127:272
38.Hreniak D,Strek W,Deren P,et al.Synthesis and luminescence properties of Eu~(3+)-doped LaAlO_3 nanocrystals[J].J Alloys and Compounds,2006,408-412:826
39.Bagnato V S,Nunes L A O,Zilio S C,et al.Infrared electronic transitions of Eu~(3+) in GdAlO_3[J].State Communications,1984,49(1):27
40.Padua S J N,Nunes L A O,et al.absorption and luminsecence spectroscopy of GdAlO_3:Eu~(3+)[J].J Lumin,1989,43:379
41.Lupei A,Lupei V,et al.Mechanisms of enenegy transfer between Nd~(3+) ions in YAG[J].J Lumin,1987,39:35
42.Lupei V,Lupei A,et al.Enenegy transfer between Nd~(3+) ions in YAG[J].Optics communication, 1986,60:59
43.Klimm D,Ganschow S,et al.On the solubility of Nd~(3+) in Y_3Al_5O_(12)[J].J Alloys and Compounds,2007,436:204
44.Van der Ende B M,Brooks R L,et al.Measurement of the ~4F_(5/2) and ~2He(2)_(9/2) manifold lifetime in Nd~(3+):Y_3Al_5O_(12) and Nd~(3+):LaF_3[J].Journal of Luminescence,2007,124:311
45.Sugak D,Matkovskii A.Influence of color centers on optical and lasing properties of the gadilinium gallium garnet single crystals doped with Nd~(3+) ions[J].J Lumin,1999,82,9
46.傅仁武,陈朝,等.单晶Si Nd:YAG激光连续退火的数值计算[J].发光学报,2000,21:320
47.Malinowski M,Frukacz Z,et al.Optical transitions of Ho~(3+) in YAG[J].J Alloys and Compounds,2000,300-301:389
48.Malinowski M,Frukacz Z.Blue up-conversion emission in Yb~(3+) senstized YAG:pr~(3+)[J].J Lumin,1997,75:333
49.Cornacchia F,Alshourbagy M,et al.Growth and spectroscopic properties of Er:YAG crystalline fibers[J].J Crystal Growth,2005,275:534
50.Dobrzycki L,Bulska E et al.Structure of YAG Crystals doped/subsituted with Erbium and Ytterbium[J].Inorg Chen,2004,43:7656
51.Mares J A,Beitlerova A,et al.Scintillation and optical properties of YAG:Ce films grown by liquid phase epitaxy[J].Radiation Measurements,2007,42:533
52.Tumpa B,Swapan K B,et al.Comparative studies of YAG(Ce) and CsI(Tl) scintillators[J].Nuclear Instruments and Methods in Physics Research A 2002,484:364
53.Jose Gracia,Luis Seijo,et al.Abinitio calculations on the local structure and the 4f-5d absorption and emission spectra of Ce~(3+)-doped YAG[J].J Lumin,2008,128:1248
54.Zorenko Y,Gorbenko V,et al.Single crystalline film scintillators based on Ce- and Pr-doped aluminium garnets[J].Radiation Measurements 2007,42:521
55.Kuck S,Petermann K,et al.Electronic and vibronic transitions of the Cr~(4+) -doped garnets Lu_3Al_5O_(12),Y_3Al_5O_(12),Y_3Ga_5O_(12) and Gd_3Ga_5O_(12)[J].J Lumin,1996,68:1
56.Haruo Sawada.Electron Density Study ofGarnets:Y_3X_2Al_5O_(12);X=Al and X=(Al,Cr)[J].J Solid State Chemistry,1997,134:182
57.Wisneiwski K,Koepke C,et al.Excited state absorption in material containing Cr~(3+) and Cr~(4+)ions[J].J Alloy and Compounds,2002,341:349
58.Yang P Z,Deng P Z,et al.Concentration quenching in Yb:YAG[J].J Lumin,2002,97:51
59.Yoshikawa A,Ogino H,et al.Growth and scintillation properties of Yb doped aluminate vanadate and silicate single crystals[J].Optical Materials,2004,26:529
60.Guerassimova A,Garnier N,et al.X-ray-excited charge transfer luminescence in YAG:Yb and YbAG[J].J Lumin,2001,94-95:11
61.Mizunori E,Minoru O.Characterization of Nd:Y_3Al_5O_(12) thin films grown on various substrates by pulsed laser deposition[J].Appl Phys Lett,1996,69(20):2977
62.Gervais M,Douy A.Mater.Solid phase transition temperatures observed during heating and cooling[J].Sci Eng,1996,38:118.
63.Zych E,Brecher C,Wojtowicz A J.Luminescence Properties of Ce-Activated YAG Optical Ceramic Scintillator Materials[J].J Lumin,1997,75:193.
64.Zych E,Brecher C,Wojtowicz A J.Depletion of high-energy carriers in YAG optical ceramic materials[J].Spectrochimica Acta Part A,1998,54:1771.
65.Zych E,Brecher C.Temperature Dependence of Ce-Emission Kinetics in YAG:Ce Optical Ceramic[J].Journal of Alloys and Compound,2000,300-301:495
66.Zych E,Brecher C.Temperature Dependence of Host-Associated Luminescence from YAG Transparent Ceramic Material[J].Journal of Luminescence,2000,90:89
67.Zych E,Brecher C.Host-associated luminescence from YAG optical ceramics under gamma and optical excitation[J].Journal of Luminescence,1998,78(2):121
68.Schlotter P,Schmidt R,Scheider J A.Host-associated luminescence from YAG optical ceramics under gamma and optical excitation[]].Journal of Luminescence,1998,78(2):121
69.Hideki Yagi,Kazunori Takaichi,et al.Influence of annealing conditions on the optical properties of chromium-doped ceramic Y_3Al_5O_(12)[J].Opticai Materials,2006,29:392
70.Hideki Y,Takagimi Y,et al.Characterizations and laser performances of highly transparent Nd~(3+):Y_3Al_5O_(12) laser ceramics[J].Optical Materials,2007,29:1258
71.Akio Ikesue.Polycrystalline Nd:YAG ceramics lasers[J].Optical Materials,2002,19:183
72.Lu Jianren,Ueda Ken-ichi,et al.Neodymium doped yttrium aluminum garnet(Y_3Al_5O_(12))nanocrystalline ceramics-a new generation of solid state laser and optical materials[J].J Alloys and Compounds,2002,341:220
73.Hreniak D,Strek W.Synthesis and optical properties of Nd -doped Y_3Al_5O_(12) nanoceramics[J].J Alloys and Compounds,2002,341:183
74.Chen T M,Chen S C,et al.Preparation and Characterization of Garnet Phosphor Nanoparticles Derived from Oxalate Coprecipitation[J].J Solid Chemistry,1999,144:437
75.Choe J Y,Ravichandran D,et al.Cathodoluminescence study of novel sol-gel derived Y_(3-x)Al_5O_(12):Tb_x phosphors[J].J Lumin,2001,93:119
76.王继业,石士考.精细粒度Y_3Al_5O_(12):Tb荧光材料的燃烧合成及其特性[J].无机材料学报,2003,18:246
77.Turos-Matysiak R,Gryk W,et al.High pressure photoluminescence of Ce-doped(Y_(1.725) Tb _(0.575)Ce_(0.05) Gd_(0.65))Al_5O_(12)[J],Optical Materials,2008,30:722
78.Turos-Matysiak R,Gryk W,et al.Tb~(3+)→Ce~(3+) energytransferinY _(3-x-y)Tb_yGd_x Al_5O_(12)(x=0.65,y=0.575) dopedwith Ce~(3+)[J].Radiation Measurements,2007,42:755
79.Robbins D J,Cockayne B,et al.The Temperature Dependence of Rare-Earth Activated Garnet Phosphors Ⅱ.A Comparative Study of Ce~(3+),Eu~(3+),Tb~(3+) and Gd ~(3+)in Y_3Al_5O_(12)[J].J Electrochem Soc:Solid-state science and technology,1979,126:1221
80.Torfeh M,Desvignes J M,et al.Reciprocal and nonreciprocal high TE-TM modes conversions in Tb,Al and Gd,Ga substituted garnet films[J].J Appl Phys,1978,49:1806
81.Zhou Y H,Lin J,et al.Synthesis-dependent luminescence properties of Y_3Al_5O_(12):Re(Re=Ce,Sm,Tb) phosphors[J].Materials Letters,2002,56:628
82.罗岚,谭敦强,周浪,等.石榴石型铝酸钆基荧光粉体及其制备方法[P].中国,200510056140.1.2007
83.Robbins D J,Cockayne B,et al.The Temperature Dependence of Rare-Earth Activated Garnet Phosphors Ⅱ.A Comparative Study of Ce~(3+),Eu~(3+),Tb~(3+) and Gd ~(3+)in Y_3Al_5O_(12)[J].J Electrochem Soc:Solid-state science and technology,1979,126:1221
84.Setlur A A,Srivastava A M.The nature of Bi~(3+) luminescence in garnet host[J].Optical Material,2006,29:410
85.Zorenko Yu,Gorbenko V,et al.Luminescence of Bi~(3+) ionsinY_3Al_5O_(12):Bi single crystalline films[J].Radiation Measurements,2007,42:882
86.Zhou Y H,Lin J,et al.Preparation of Y_3Al_5O_(12):Eu phosphors by citric-gel method and their luminescent properties[J].Optical Materials,2002,20:13
87.Shi Shikao,Wang Jiye.Combustion synthesis of Eu activated Y_3Al_5O_(12) phosphor nanoparticles[J]Journal of Alloys and Compounds,2001,327:82
88.Park D Y,Yang J M.Fracture behavior of directionally solidified CeO_2 - and Pr_2O_3 -doped Y_3Al_5O_(12)/Al_2O_3 eutectic composites[J].Materials Science and Engineering,2002,332A:276
89.Seong Ju Park,Hui Dong Park,Seo Su.Method for manufactureing cerium dopedyttrium aluminum garnet yellow phosphors for white luminescent devices[P].Korean Patent,200023225,2000
90.Lu Chung Hsin,Jagannathan R.Cerium-ion-doped yttrium aluminumgarnet nanophosphors prepared through sol-gel pyrolysis for luminescent lighting[J].Appl Phys Lett,2002,80(19):3608.
91.李东平,缪春燕,刘停蓝.蓝光转换白光荧光粉YAG:Ce的研究进展[J],江西化工,2005,3,15
92.李东平,缪春燕,等.白光LED用荧光粉YAG:Ce的研究进展[J].液晶与显示,2005,20.526
93.戚发金,朱宪忠,王苏,王海波.气相法制备优质白光LED用YAG荧光粉[J].中国照明电器,2005,4:1
94.Yum J H,Kim S S,Sun Y E.Y_3Al_5O_(12):Ce_(0.05) phosphor coatings on a flexible substrate for use in whitelight-emitting diodes[J].Colloids and Surfaces A:Physicochem Eng Aspects,2004,251:203
95.Pan Y X,Wu M M,Su Q.Tailored photoluminescence of YAG:Ce phosphor through various methods[J].J Physics and Chemistry of Solids,2004,65:845
96.Pan Y X,Wu M M,Su Q.Comparative investigation onsynthesis and photoluminescence ofYAG:Cephosphor[J].Materials Scienceand Engineering B,2004,106:251
97.Vladimir P,Larisa G,Donats M,Tadeusz C.Luminescence of cerium doped YAG nanopowders[J].Radiation Measurements,2007,42:679
98.Li Q,Gao L,Yan D S.The crystal structure and spectra of nano-scale YAG:Ce[J].Materials Chemistry and Physics,2000,64:41
99.Photoluminescence enchancement of PEG-Modified YAG:Ce~(3+) nanocrystal phosphor prepared by glycothermal Method[J].J Phy Chem B,2005,109:22126.
100.Vladimir P,Ladsa G,et al.Luminescence of cerium doped YAG nano powders[J].Radiation Measurements,2007,42:679
101.Zhang K,Hu W B,et al.Photoluminescence investigations of(Y_(1-x)Ln_x)_3Al_5O_(12):Ce~(3+)(Ln~(3+)=Gd~(3+),La~(3+)) nanophosphors[J].Physica B,2008,403:1678
102.张书生,庄卫东,等.助熔剂对Y_3Al_5O_(12):Ce~(3+)荧光粉性能的影响[J].中国稀土学报,2002,20:605
103.Park D Y,Yang J M.Fracture behavior of directionally solidified CeO_2 - and Pr_2O_3 -doped Y_3Al_5O_(12)/Al_2O_3 eutectic composites[J].Materials Science and Engineering,2002,332A:276
104.Zorenko Yu,Gorbenko V,et al.Single-crystalline films of Ce-doped YAG and LuAG phosphors:advantages over bulk crystals analogues[J].J Lumin,2005,114:85
105.Abdullah M,Okuyama K,et al.A polymer solution process for synthesis of(Y,Gd)_3Al_5O_(12):Ce phosphor particles[J].J Non-Crystalline Solids,2005,351:697
106.Babin V,Gorbenko V,et al.Luminescence characteristics of Pb~(2+) centres in undoped and Ce~(3+)-doped Lu_3Al_5O_(12) single-crystalline films and Pb~(2+)-Ce~(3+) energy transfer processes[J].J Lumin,2007,127:384
107.Zorenko Y,Gorbenko V Growth peculiarities of the R_3Al_5O_(12)(R=Lu,Yb,Tb,Eu-Y)single crystalline film phosphors by liquid phase epitaxy[J].Radiation Measurements,2007,42:907
10g.Laguta V V,Slipenyuk A M,et at.Paramagnetic impurity defects in LuAG:Ce thick film scintillators[J].Radiation Measurements,2007,42:835
109.Novosselov A,Yoshikawa A,et al.Shaped single crystal growth and scintillating application of Yb:(Gd,Lu)_3(Ga,Al)_5O_(12) solid solutions[J].Optical Materials,2004,26:541
110.Chiara M,Vincenzo B,et al.Disorder and Nonstoichiometry in Synthetic Garnets A_3B_5O_(12)(A=Y,Lu-La,B=Al,Fe,Ga)A Simulation Study[J].Chem Mater,2004,16:1232
111.Stanek C R,McClellan K J,et al.The effect of intrinsic defects on RE_3Al_5O_(12) garnet scintillator performance[J].Nuclear Instruments and Methods in Physics Research,2007,579A:27
112.Nikl M,Vedda A,et al.Energy transfer and storage processes in scintillators:The role and nature of defects[J].Radiation Measurements,2007,42:509
113.Pari G,Mookerjee A,Bhattacharya A K.First-principles electronic structure calculations of R_3Al_5O_(12)(R being the rare-earth elements Ce-Lu)[J].Physica,2005,365B:163
114.Zorenko Y,Voloshinovskii A,et al.Luminescence of excitons and antisite defects in the phosphors based on garnet compounds[J]Radiation Measurements,2004,38:677
115.Guerassimova A,Garnier N,et al.X-ray-excited charge transfer luminescence in YAG:Yb and YbAG[J].J Lumin,2001,94-95:11
116.Wang H M,Simmonds M C,et al.Manufacturing of YbAG coatings and crystallisation of the pure and Li_2O-doped Yb_2O_3- Al_2O_3 system by a medoified sol-gel method[J].Materials chemistry and physics,2002,77:802
117.Zorenko Y,Gorbenko V.Luminescence and Tb~(3+) -Ce~(3+) -Eu~(3+) ion energy transfer in single-dystalline films of Tb Al_5O_(12):Ce,Eu garnet[J]J Lumin,2008,128:652
118.Zorenko Y,Voznyak T,et al.Energy transfer to Ce~(3+) ions in Tb_3Al_5O_(12):Ce single crystalline films[J].Radiation Measurements,2007,42:648
119.Monique Gervais,Andre Douy.Solid phase transformation and melting of the compounds Ln_4Al_2O_9(Ln=Gd,Dy,Y)[J].Materials Science and Engineering,1996,B38:118
120.Yamane H,Sakamoto T,et al.Preparation and phase transition of Gd_4(Al_(1-x)Ga_x)_2O_9 solid solution[J].J Mater Sci,2001,36:307
121.Hisanori Yamane,Masahiko Shimada.High-Temperature Neutron Diffraction Study of Y_4Al_2O_9[J].J Solid State Chem,1998,141:466
122.Yamane H,Omori M,Okubo A,et al.High-Temperature Phase Transition of Y_4Al_2O_9[J].J Am Ceram S oc,1993,76:2382
123.Yamane H,Ogawara K,Omori M,et al.Thermal Expansion and A thermal Phase Transition of Y_4Al_2O_9 Ceramics J Am Ceram Soc,1995,78:1230
124.Yamane H,Ogawara K,Omori M,et al.Phase Transition of Rare-EarthAluminates(RE_4Al_2O_9)and Rare-Earth Gallates(RE_4Ga_2O_9)[J].J Am Ceram Soc,1995,78:2385.
125.Yamane H,Omori M,Hirai T.Twin Structure of Y_4Al_2O_9[J],J Mat Sci Let,1995,14:561
126.Yamane H,Omori M,Hirai T.Thermogravimetry and Rietveld Analysis for the High-Temperature X-ray Powder Diffraction Pattern of Y_4Al_2O_9[J],J Mat Sci Let,1995,14:470
127.Monique Gervais,Andre Douy.Solid phase transformation and melting of the compounds Ln_4Al_2O_9(Ln=Gd,Dy,Y)[J].Materials Science and Engineering,1996,B38:118
128.Yamane H,Sakamoto T,et al.Preparation and phase transition of Gd_4(Al_(1-x)Ga_x)_2O_9 solid solution[J].J Mater Sci,2001,36:307
129.Liu S L,Su Q.Sol-gel synthesis and luminescence of Y_4Al_2O_9:RE~(3+)(RE=Eu,Tb)[J].J Alloys and Compouds,1997,255:102
130.袁曦明,许永胜,于江波,田熙科.溶胶一凝胶法制备纳米荧光粉Y_4Al_2O_9Eu~(3+)的初步研究[J].地球科学(中国地质大学学报),2002,27:409
131.Chaudhury S,Padda S C,Pillai K T,Singh Mudher K D.High-temperature X-ray diffraction and specific heat studies on GdAlO_3,Gd_3Al_5O_(12) and Gd_4Al_2O_9[J].Journal of Solid State Chemistry,2007,180:2393
132.Lakiza S,Fabrichnaya O,et al.Phase diagram of the ZrO_2-Gd_2O_3-Al_2O_3[J].J Ceram Soc,2006,26:233
133.Lakiza S M,Lopato L M.Stable and metastable phase relations in the system a lumina-zirconia-yttria [J].J Am Ceram Soc,1997,80(4):893.
134.Rouanet A,Foex.Study at high temperatures of the systems formed by ZrO_2 with the Sm_2O_3 and Gd_2O_3[J].C R Acad Sci,1968,C267(15):873.
135.Budnikov P P,Kushakovskij V I,Belevantsev V S.Investigation of the Gd_2O_3,Sm_2O_3 and Al_2O_3system[J].D A N SSSR,1965,165:1075.
136.Mizuno M,Yamada T,Noguchi T.Phase diagram of the systems Al_2O_3-Eu_2O_3 and Al_2O_3-Gd_2O_3at high temperatures[J].J Ceram Soc Jpn,1977,85(11):543
137.Wu P,Pelton A D.Coupled thermo dynamic-phase diagram assessment of the rare earth oxidealuminum oxide binary systems[J].J Alloys Comp,1992,179:259.
138.Shishido T.Phase diagram estimation of the Al_2O_3-SiO_2-Re_2O3 systems[J].J Mater Sci,1979,14:823
139.Kolitsch K,Seifert H J,Aldinger F.Phase relationships in the system Gd_2O_3-Al_2O_3- SiO_2[J].J Alloys Compds,1997,257:104
140.Shishidom T,Okamura K,Yajima S.Gd_3Al_5O_(12) Phase Obtained by Crystallization of Amorphous Gd_2O_3·5/Al_2O_3·3[J].J Am Ceram Soc,1978,61:373
141.Euler F,Bruce J A.Oxygen coordinates of compounds with garnet structure[J].Acta Cryst,1965,19:971
142.Yoshikawa A,Hasegawa K,et al.Phase identification of Al_2O_3/RE_3Al_5O_(12) and Al_2O_3/REAlO_3(RE=Sm-Lu,Y) eutectics[J].J Crystal Growth,2000,218:67
143.Zhang K,Hu W B,et al.Photoluminescence investigations of(Y_(1-x)Ln_x)_3Al_5O_(12):Ce~(3+)(Ln~(3+)=Gd~(3+),La~(3+)) nanophosphors[J].Physica B,2008,403:1678
144.刘茜,罗岚,刘庆峰.钙钛矿型铝酸钆基荧光粉体及制备方法[P].中国,310107829.3,2005
145.刘茜,罗岚,刘庆峰.铝酸钆基发光薄膜材料芯片及其制备技术[P].中国,310107830.6,2005
146.罗岚,周浪,等.一种钐掺杂铝酸钆基荧光粉体及其制备方法[P].中国,200810060965.4,申请中
147.罗岚,刘庆峰,刘茜,等.Gd_(3(1-x))Al_5O_(12):RE_(3x)分立材料芯片制备及发光性能研究[J].感光科学与光化学,2005:23(11):447
148.罗岚,刘庆峰,刘茜,等.Gd_3Al_5O_(12):Eu~(3+)柠檬酸盐硝酸盐燃烧法合成及其发光性能研究[J].感光科学与光化学,2006,24:225
149.罗岚,周浪,等.一种钐掺杂铝酸钆基荧光粉体及其制备方法[P].中国,200810060965.4,申请中
150.罗岚,周浪,魏秀琴.等.单斜型铝酸钆基荧光粉体及其制备方法[P].中国,200510069827.9,2007
1.Kennedy K,Stefansky T,Davy G et al.Rapid method for determining termary-alloy phase diagrams[J].J Appl Phys,1965,36:3808
2.Hanak J J.The "multiple-sample concept" in materials research:synthesis,compositional analysis and testing of entire multi component systems[J].J Mater Sci,1970,5:964
3.董安钢,唐颐.浅谈组合化学[J].大学化学,2000,15(5):8
4.Wolf D,Buyevskaya O V,Baerns M.An evolutionary approach in the combinatorial selection and optimization of catalytic materials[J].Appl Catalysis A:General,2000,200:63
5.Jaramiilo T F,Ivanovskaya A,McFarland E W.High-throughput screening system for catalytic hydrogen-producing materials[J]. J Comb Chem., 2002,4:17
6. Xiang X D, Sun X D et al. A Combinatorial Approach to Materials Discovery[J], Science, 1995,268:1738
7. Sun X D, Gao C, Wang J, et al. Identification and optimization of advanced phosphors using combinatorial libraries[J]. Appl Phys Lett, 1997,70 :3353
8. Sun X D, Xiang X.D. New phosphor (Gd_(2-x)Zn_x)O_(3-δ):Eu~(3+) with high luminescent efficiency and superior chromaticity[J]. Appl Phys Lett., 1998,72 :525
9. Danielson E, Golden J H, et al. A combinatorial approach to the discovery and optimization of luminescent materials [J]. Nature, 1997, 389:944
10. Danielson E, Devenney M, et al. A rare-earth phosphor containing one-dimensional chains identified through combinatorial methods [J]. Science, 1998, 279:837
11. Wang J S, Yoo Y K, et al. Identification of a blue photoluminescent composite material from a combinatorial library[J]. Science, 1998, 279:1712
12. Yoo Y K, Ohnishi T, Wang G, et al. Continuous mapping of structure-property relations in Fe1-xNix metallic alloys fabricated by combinatorial synthesis. Intermetallics[J], 2001, 9(7):541
13. Cremer R, Neuschutx D. Optimization of(Ti, Al)N hard coating by a combinatorial approach[J].Inter J Inorg Mater, 2001, 3:1181
14. Takahashi R, Matsumoto Y, Koinuma H, et al. Combinatorial optimization of atomically controlled growth for oxide films by the carrousel type laser molecular beam epitaxy[J]. Appl Surf Sci, 2002, 197-198:532
15. Perkins J D, Cueto J A del, Alleman J K, et al. Combinatorial studies of Zn-Al-O and Zn-Sn-O transparent conducting oxide thin films. Thin Solid films[J], 2002,411:152
16. Laversenne L, Kariouani S, Guyot Y, et al. Correlation between dopant content and excited-state dynamics properties in Er~(3+)-Yb~(3+)-codoped Y_2O_3 by using a new combinatorial method[J].Optical Materials, 2002, 19: 59
17. Grobhans I, Kari H, Stritzker B. Combinatorial synthesis of ZnTe nanocrystals in SiO_2 on silicom y ion implantation [J]. Nucl Instru and Method in Phys Res B, 2002, 190: 865
18. Hasegawa T, Kageyama T, Fukumura T, et al. High-throughput characterization of composition- spread manganese oxide films with a scanning SQUID microscope[J]. Applied Surface Sci, 2002,189:210
19. Takeuchi I, Wei T, Duewer F, et al. Low temperature scanning-tip microwave near-field microscopy of Yba_2Cu_3O_(7-x) films[J]. Appl Phys Lett, 1997,71(14):2026
20. Briceno G, H Chang, Sun X D, et al. A class of cobalt oxide magnetoresistance materials discovered with combinatorial synthesis [J]. Science, 1995, 270:273
21. Takeuchi I, Chang H, Gao C et al. Combintorial synthesis and evaluation of epitaxial ferroelectric device libraries[J]. Appl Phys Lett., 1998, 73(7): 894
22. Chang H, Gao C, Takeuchi I, et al. Combinatorial synthesis and high throughput evaluation of ferroelectric/dielectric thin-film libraries for microwave applications [J]. Appl Phys Lett., 1998,72(17):2185
23. Chang H, Xiang X D. Improvements in the figure of merit for tunable microwave dielectrics using combinatorial approach [J]. Integ Ferroelectrics, 2000,28(1-4):113
24. Liu X Q, Li Z F, Lu W, et al. Application of the combinatorial approach to the fabrication of a quantum well multiwavelength emitting chip[J]. Appl Phys Lett, 1999, 75:2611
25. Reddington E, Sapienza A, Gurau B, et al. Combinatorial electrochemistry: A highly parallel,optical screening method for discovery of better electrocatalysts [J]. Science, 1998, 280:1735
26. Yoo Y K, Duewer F, Yang H, et al. Room-temperature electronic phase transitions in the continuous phase diagrams of perovskite manganites[J]. Nature, 2000,406(17): 704
27.罗岚,徐政,许业文,刘庆峰,刘茜.物理气相法制备材料芯片的发展[J].材料导报,2004,18(2):69
28.田明波,刘德令编译.薄膜科学与技术手册[M].北京:机械工业出版社出版,1991
29.Hubbard K J,Schlom D G.Thermodynamic stability of binary oxides in contact with silicon[J]J Mater Res,1996,11:2757
30.Chen J C,Shen G H,Chen L Formation of Gd oxide thin films on(111)Si[J]Appl Surf Sci,1999,142:120
31.Kwo J,Hong A R,Kortan A R,et al.High ε gate dielectrics Gd_2O_3 and Y_2O_3 for silicon Appl phys Letter,2000,77:130
32.Gupta J A,Landheer D,Sproule G I.Interfacial layer formation in Gd_2O_3 films deposited directly on Si(100)[J].Applied Surface Science,2000,173:318
1.Kennedy K,Stefansky T,Davy G,et al.Rapid method for determining termary-alloy phase diagrams[J].J Appl Phys,1965,36:3808
2.Hanak J J.The "multiple-sample concept" in materials research:synthesis,compositional analysis and testing of entire muiticomponent systems[J].J Mater Sci,1970,5:964
3.董安钢,唐颐.浅谈组合化学[J].大学化学,2000,15(5):8
4.Wolf D,Buyevskaya O V,Baerns M.An evolutionary approach in the combinatorial selection and optimization of catalytic materials[J].Appl Catalysis A:General,2000,200:63
5.Jaramilio T F,Ivanovskaya A,McFarland E W.High-throughput screening system for catalytic hydrogen-producing materials[J].J Comb Chem,2002,4:17
6.Xiang X D,Sun Xiaodong,et al.A Combinatorial Approach to Materials Discovery[J],Science,1995,268:1738
7.Sun X D,Gao C,Wang J,et al.Identification and optimization of advanced phosphors using combinatorial libraries[J].Appl Phys Lett.,1997,70:3353
8.Sun X D,Xiang X D.New phosphor(Gd_(2-x)Zn_x)O_(3-δ):Eu~(3+) with high luminescent efficiency and superior chromaticity[J].Appl Phys Lett.,1998,72:525李强.稀土化合物纳米荧光特性的研究[D].上海硅酸盐研究所博士学位论文,1997
9.Luckey W G.Process for preparing yttrium oxide and rare earth metal oxide phosphors[P].Canadian Patent,1982,No.1038618
10.Richard C R,Graff E A,et al.Efficient preparation of rare-earth metal oxalate[P].US Patent,1969,No.3420861
11.Bertran C A,Silva N T Da,ThimG P.Citric acid effect on aqueous sol-gel cordierite synthesis[J].J Non-cry Solid.2000.273:140
12.刘雁,潘伟.溶胶凝胶法制备YAG:Eu纳米荧光粉及性能分析[J].稀有金属材料与工程,2002.31:32
13.Roy S,Sigmund W,Aldinger F.Nanostructured yttria powders via gel combustion[J].J Mater Res.,1999,14(4):1524
14.Kingsley J J,Pederson L R.Energetic materials in ceramics synthesis[J].Mat Res Soc Symp Proc,1993,296:361
15.Mckittrick J,Shea L E,Bacalski C F,et al.The influence of processing parameters on luminescent oxides produced by combustion synthesis[J].Displays,1999,19:169
16.Pechini.M P Method of preparing lead and alkaline earth titanates and niobate and coating method using the same to from a capacitor[P].US Patent,1967,No.3330697
17.Kakihana M,Okubo T.Low temperature powder synthesis of LaAlO3 through in situ polymerization route utilizing citric acid and ethylene glycol[J].J Alloy Comp.,1998,266:129
18.Lin S P,Fung K Z,Hon Y M,et al.Crystallization mechanism of LiNiO2 synthesized by Pechini method[J].J Crys Growth,2001,226:148
19.Serra O A,Cicillini S A,Ishiki R R.A new procedure to obtain Eu3+ doped oxide and oxosalt phoshors[J].J Alloy Comp.,2000,303-304:316
20.Choudhary R N P,Mal J.Phase transition in Bi-modified PZT ferroelectrics[J].Mater Lett,2002,54:175
21.Zhou Y H,Lin J,Wang S B,et al.Preparation of Y_3Al_5O_(12):Eu phosphors by citric-gel method and their luminescent properties[J].Optical Mater,2002,20:13
22.Zupan K,Kolar D,Marinsek M.Influence of citrate-nitrate reaction mixture packing on ceramic powder properties[J].J Power Sources,2000,86:417
23.Juarez R E,Lamas D G,Lascalea G E,et al.Synthesis of nanocrystalline zirconia powders for TZP ceramics by a nitrate-citrate combustion route[J].J Euro Ceram Soc.,2000,20:133
24.Paul A Lessing.Mixed-cation oxide powders via polymericprecursorsl[J].Cramic Bulletin,1989,68(5):1002
25.Zeng Y,Lin Y S.Synthesis and properties of copper and samarium doped yttriabismuth oxide powders[J].J Mater Sci,2001,36(5):1271
26.霍地,杨洪才.用柠檬酸溶胶凝胶法合成SrFeCo_(0.05)O_x氧化物[J].东北大学学报,2003,24(1):61
27.Chroma M,Pinkas J,Pakutinskiene I,Beganskiene A,Kareiva A,Ceram Int.Processing and characterization of sol-gel fabricated mixed metal aluminates[J].Ceramics International,2005,31:11
28.罗岚,徐政,刘庆峰等.GdAlO3:Eu~(3+)荧光粉燃烧法合成及其发光性能[J].同济大学学报(自然科学版),2004,32(11):1476
29.Cizauskaite S,Reichlova V,Nenartaviciene G,Beganskiene A,Pinkas J,Kareiva A..Sol-gel preparation and characterization of gadolinium aluminate[J].Materials Chemistry and Physics,2007,102:105
30.Sugiyama A,Araki S J,Sakamoto N,et al.Fabrication of amorphous bulk and multi-phase ceramics by melting method in the HfO_2-Al_2O_3-Gd_2O_3-Eu_2O_3 system[[J].J Electroceram,2006,17:71
31.Lakiza S,Fabrichnaya O et al.Phase diagram of the ZrO_2-Gd_2O_3-Al_2O_3[J].J Ceram Soc,2006,26:233
32.Lakiza S M,Lopato L M.Stable and metastable phase relations in the system a lumina-zirconia-yttria [J].J Am Ceram Soc,1997,80(4):893
33.Rouanet A,Foex.Study at high temperatures of the systems formed by ZrO_2 with the Sm_2O_3 and Gd_2O_3[J].C R Acad Sci,1968,C267(15):873
34.Euler F,Bruce J A.Oxygen coordinates of compounds with garnet structure[J].Acta Cryst.1965,19:971
35.Shishido T.Phase diagram estimation of the Al_2O_(3-)SiO_2-Re_2O_3 systems[J].J Mater Sci,1979,14:823
36.Zych E,Brecher C.Host-associated luminescence from YAG optical ceramics under gamma and optical excitation[J].Journal of Luminescence,1998,78(2):121
37.Schlotter P,Schmidt R,Scheider J A.Host-associated luminescence from YAG optical ceramics under gamma and optical excitation[J].Journal of Luminescence,1998,78(2):121-134.
38.Seong Ju Park,Hui Dong Park,Seo Su.Method for manufactureing cerium dope dyttrium aluminum garnet yellow phosphors for white luminescent devices.[P]Korean Patent, 200023225,2000.
39. Lu Chung Hsin, Jagannathan R. Cerium-ion-doped yttrium aluminum garnet nanophosphors prepared through sol-gel pyrolysis for luminescent lighting[J]. Appl Phys Lett, 2002, 80(19):3608
40. Kolitsch U, Seifert H J, Aldinger F. Phase relationships in the system Gd_2O_3-Al_2O_3- SiO_2 [J]. J Alloys Compds,1997, 257: 104
41. Chaudhury S, Parida S C, Pillai K T, Singh Mudher K D.High-temperature X-ray diffraction and specific heat studies on GdAlO_3, Gd_3Al_5O_(12) and Gd_4Al_2O_9[J]. Journal of Solid State Chemistry,2007,180:2393
42. Kanke Y, Navrotsky A J. Thermo chemistry of Complex Perovskites[J].Solid State Chem, 1998,141:424
43. Kanke Y, Navrotsky A. Thermochemistry of Complex Perovskites[J]. J Solid State Chem, 1998,141:424
44. Budnikov P P, Kushakovskij V I, Belevantsev V S. Investigation of the systems Al_2O_3-Sm_2O_3 and Al_2O_3-Gd_2O_3[J]. Dokl. AN SSSR, 1961, 9(3):744
45. Mizuno M, Yamada T, Noguchi T. Phase Equilibria in the Gd_2O_3-SrAl_2O_4 System[J]. J Ceram Soc Jpn, 1977, 85(11):543
1. Kennedy K, Stefansky T, Davy G et al. Rapid method for determining termary-alloy phase diagrams[J]. J Appl Phys, 1965, 36:3808
2. Hanak J J. The "multiple-sample concept" in materials research: synthesis, compositional analysis and testing of entire multi component systems [J]. J Mater Sci, 1970, 5:964
3. 董安钢,唐颐.浅谈组合化学[J].大学化学, 2000, 15(5): 8
4. Fu W T, Zandbergen H W, et al. On the red phosphor of nominal compostion Gd_(0.77)Al_(1.23)O_x:Eu_(0.06)( x≈3.1) [J]. Material research bulletin, 2004, 39: 909
5. Bagnato V S, Nunes L A O, Zilio S C, et al. Infrared electronic transitions of Eu~(3+) in GdAlO_3[J].State Communications, 1984,49(1):27
6. Padua S J N, Nunes L A O, et al. absorption and luminsecence spectroscopy of GdAlO_3: Eu~(3+)[J].J Lumin, 1989,43:379
7. Kuroiwa Y, Aoyagi S , Sawada A et al. Evidence for Pb-O Covalency in Tetragonal PbTiO_3[J].Phys Rev Lett ,2001, 87: 217601:1
8. Pari G, Mookerjee A , Bhattacharya A K. First-principles electronic structure calculations of R_3 Al_5O_(12) (R being the rare-earth elements Ce-Lu) [J].Physica B,2005,365: 163
9. Chikashi S, Jun Kawai, Masao T, et al. The electronic structure of rare-earth oxides in the creation of the core hole[J]. Chemical Physics, 2000, 253: 27
10. Liu Qing feng. Liu Qian, Luo Lan. Preparation and luminescent properties of Eu-doped Ln_2O_3 (Ln = Gd, Lu) thin film by citrate sol-gel process[J]. Ceramics International,2004,30:1703
11. Narihito Nakagawa , Hideki Ohtsubo, Atsuyuki Mitani, Kazuto shiShimizu, Yoshiharu Waku. High temperature strength and thermal stability for melt growth composite[J]. Journal of the European Ceramic Society,2005,25:1251
12. Yohei Harada, Kazuya Ayabe , Naofumi Uekawa ,Takashi Kojima, Kazuyuki Kakegawa ,SungJin Kim.Formation of GdAlO_3 -A1_2O_3 composite havingfine pseudo-eutectic microstructure[J]. Journal of the European Ceramic Society,2008,28:2941
13. Gouadec G,. Colomban Ph, Piquet N , Trichet M F, Mazerolles L. Raman/Cr~(3+) fluorescence mappingof a melt-grown Al_2O_3/GdAlO_3 -eutectic[J]. Journal of the European Ceramic Society,2005,25:1447
14. Andreeta E RM, Andreeta MRB, Hernandes A C. Laser heated pedestal growth of Al_2O_3/GdAlO_3 eutectic fibers[J] Journal of Crystal Growth,2002, 234: 782
15. Kohn W, Sham L J. Self-consistent equation including exchange and correlation effects[J]. Phys Rev, 1965, 140:A1133
16. Aryasetiawan F. G W method for 3d and 4f systems[J]. Physica B, 1997,237-238 : 321
17. Anisimov V I, Zaanen J, Andersen O K, Band theory and Mott insulators: Hubbard U instead of Stoner[J]. Phys Rev B, 1991,44: 943
18. Anisimov V I, Gunnarsson O, Density-functional calculation of effective Coulomb interactions in metals[J]. Phys Rev B, 1991,43:7570
19. Anisimov V I, et al, Density-functional theory and NiO photoemission spectra[J]. Phys Rev B,1993,48:16929
1.方容川.固体光谱学[M].合肥:中国科学技术大学出版社,2001:134
2. Mares J A, Pedrini C, Optical studies of Ce~ (3+)-doped gadolinium aluminium perovskite single crystals [J]. Chem Phys Lett, 1993,206: 9.
3. Mares J A, Nikl M. Fluorescence and scintillation properties of LuAlO_3:Ce crystal [J]. Chem Phys Lett, 1995,241:311.
4. Dorenbos P, Bougrine E. Scintillation properties of GdAlO_3: Ce crystals[J]. Radiation Effect and Defects in Solids, 1995, 135: 321.
5. 郭常新,柏善岩.Gd_xY_(1-x)P_5O_(14):Ce,Tb的发光和能量传递[J].中国稀土学报, 1995,13(2): 123
6. Lei Bingfu, et al. Pink light emitting long-lasting phosphorescence in Sm~(3+)-dopedCdSiO_3[J].Journal of Solid State Chemistry, 2004, 177: 1333
7. 孙小琳,张桂兰,等.CaS: Sm~(3+)中Sm~(3+)的发光特性与其格位对称性的相关性[J].南开大学(Acta scienitiarum naturalium universitatis nankaiensis), 1999,32(3): 15
8. 黄立辉,等.Sm~(3+)掺杂的镉铝硅酸盐玻璃的光谱特性[J].红外与毫米波学报,2001, 20: 44
9.张晓,等.CaSiO_3:Ce,Mn体系中Ce,Mn的能量传递研究[J],发光学报,1992,13(1):1
10.胡林学,宋功武.稀土五硼酸盐中锰(II)的光致发光研究[J].湖北大学学报(自然科学版),1994,16:82
11. Frumarovaa B, Bilkova M B , et al.Thin films of Sb_2S_3 doped by Sm ions[J]. Journal of Non-Crystalline Solids, 2003, 326-327: 348
12.何志毅,等.(Ca,Sr)S:Eu,Sm的光激励发光和电子俘获机理的研究[J].光电子激光,2003,14(7):729
13.张希艳,刘全生,卢利平,等.CaS:Ce,Sm的制备及性能表征[J].无机化学学报,2005,21(5):667
14.余雪,徐海刚,殷江,张伟风.L~(3+)离子掺杂Gd_2O_3:Sm~(3+)纳米品的发光增强[J].发光学报,2007,28(5):754
15. Zhou Y H, Lin J, et al. Energy transfer and upconversion luminescence properties Y_2O_3:Sm and Gd_2O_3 :Sm phosphors[J]. Journal of Solid State Chemistry , 2003, 171:391
16. Amitava P , Renata R , Harry M. Influence of aluminium oxide on intensities of Sm~(3+) and Pr~(3+)spectral transitions in sol-gel glasses[J]. Materials Letters, 1998,37: 325
17.Chu B L,Guo C F,Su Q.Luminescence andenergy transfer in Gd_2Y_xLn_(7.9-x)(SiO_4)_6O_2(Ln=Sm,Dy,Eu)[J].Materials Chemistry and Physics,2004,84:279
18.Lange S,Kiisk V,et al.Luminescence of RE-ions in HfO_2 thin films and some possible applications[J].Optical Materials,2006,28:1238
19.Kodaira C A,Stefani R,et al.Optical investigation of Y_2O_3:Sm~(3+) nanophosphor prepared by combustion and Pechini methods[J],Journal of Luminescence,2007
20.黎明,刘晓华,陈绍军,王孝东.CeO2:Sm3+荧光粉的发光特性研究[J],中国材料科技与设备,2006,6:43
21.藏竞存,刘燕行,等.ZnWO_4:Sm晶体光谱与上转化发光[J].物理学报,1998,47(1):117
22.Gaft M,Nagli L,et al.Laser-induced time-resolved luminescence of natural titanite CaTiOSiO_4[J].Optical Materials,2003,24:231
23.Yan B,Xiao X Z.Novel YNbO_4:RE~(3+)(RE=Sm,Dy,Er) microcrystalline phosphors:Chemicalco-precipitation synthesis fromhybridprecursor and photoluminescent properties[J].Journal of Alloys and Compounds,2007,433:251
24.Malchukova E,Boizot B,et al.Optical properties and valence state of Sm ions in aluminoborosilicate glass under b-irradiation[J].Journal of Non-Crystalline Solids,2007,353:2397
25.Eugenia Malchukova,Bruno Boizot,et al.Optical properties of pristine and g-irradiated Sm doped borosilicate glasses[J].Nuclear Instruments and Methods in Physics Research,2005,537A:411
26.SouzaFilho A G,MendesFilbo J,et al.Optical properties of Sm~(3+) doped lead fluoroborate glasses[J].Journal of Physics and Chemistry of Solids,2000,61:1535
27.于健,刘又年,陈立妙,黄可龙.Sm3+掺杂CaOSiO2B203发光玻璃的制备、表征及性质[J].无机化学学报,2006,22(2):248
28.李宝祥,韩尧,路冰宇,吕玉华.Sm~(3+)在玻璃中的发光以及Sb~(3+)、Ce~(3+)、Gd~(3+)对Sm~(3+)发光性质的影响[J].发光学报,1993,14(1):53
29.Cooke D W,Muenchausen R E,et al.Spectral emission of rare-earth doped Lu_2SiO_5 single crystals[J].Optical Materials,2005,27:1781
30.Li Y C,Chang Y H,et al.Synthesis and luminescent properties of Ln(Eu~(3+),Sm~(3+),Dy~(3+))-doped lanthanum aluminum germanate LaAlGe_2O_7 phosphors[J].Journal of Alloys and Compounds,2007,439:367
31.Meng Q B,Wuand Z J,et al.The bond ionicity in RBa_2Cu_3O_7(R=Pr,Sm,Eu,Gd,Dy,Y,Ho,Er,Tm)[J].J Phys Condens Matter,1998,10:L85
32.贺香红.LED用红色荧光粉SrZnO_2:Sm~(3+),Li~+的合成与发光性能[J].稀有金属材料与工程,2007,36(9):1574
33.赵春燕,朱连杰,等.BaBeF_4:Sm~(3+)的温和水热合成与光谱特性质研究[J].高等化学学报1998,19(7):1023
34.张国春,吴以成,傅佩珍。,王国富,郭范,陈创天.一种新的非线性光学材料(?)Na3Sm2(BO3)3[J].人工晶体学报,2001,30(3):227
35.杨殿来,林海,侯嫣嫣,等.Sm3+掺杂稀土硼酸盐玻璃的光谱参数计算和荧光光谱分析[J].光谱学与光谱分析,2006,26(1):87
36.郭风瑜.REBO_3中Ce和Bi针对sm致发光的影响[J].无机化学学报,1993,9(1):83
37.Qinghua Zeng,Zhiwu Pei,et al.Luminescence of RE(RE=Sm,Yb) in barium octoborate[J].Materials Research Bulletin,1999,34:1837
38.Stefani R,Maia A D,et al.Photoluminescent behavior of SrB_4O_7:RE(RE=Sm and Eu) prepared by Pechini,combustion and ceramic methods[J]Journal of Solid State Chemistry,2006,179:1086
39.裴治武,苏锵.Dy~(3+),Sm~(3+)和Ce~(3+)离子在M_3la_2(BO_3)_3(M=Ca,Sr,Ba)中光谱性质的研究[J].发光学报,1989,10(3):213
40.Liang H B,Xu J H,et al.The VUV-vis spectroscopic properties of phosphors Ca_3Gd_(2(1-x))Ln_(2x)(BO_3)_4(Ln=Ce,Sm,Eu,Tb)[J].Materials Research Bulletin,2006,41:1468
41.张国春,傅佩珍,王国富,郭范,官向国.Na_3La_2(BO_3)_3:Sm~(3+)的合成及其光谱特性[J].发光学报,2001,22(3):237
42.魏新姣,杨中民,刘粤惠,陈东丹Ce~(3+)/Sm~(3+)掺杂硼硅酸盐玻璃的制备及发光性能分析[J]武汉理工大学学报,2007,29(专辑1):248
43.曲雅焕,于亚勤,张思远.GdP_5O_(14):Sm~(3+),Pr~(3+)晶体生长,光谱和离子间的能量传递[J].应用化学,2000,17(3),341
44.任金生,王庆元,张思远.SmP_5O_(14)晶体中Sm离子能级和晶场参数[J].发光学报,1989,10(3):212
45.Rambabu U,Rajamohan Reddy IK,Annapurna K,Balaji T,et al.Fluorescence spectra of Sm3+-doped lanthanide oxychioride powder phosphors[J].Materials Letters,1996,27:59
46.杨频,等.Sm与Nd离子在LaOX系列基质中的配位场微扰能级及其光谱解析[J].无机化学学报,1991,7(3):338
47.刘金霞,吕树臣,李秀明.纳米晶ZrO2:Pr3+与ZrO2:Pr计,Sm3+发光研究[J].光谱学与光谱分析,2006,26(4):605
48.刘金霞,吕树臣,李秀明.纳米晶ZrO2:Sm3+的制备与发光性质研究[J].中国稀土学报,2004,22(6):867
49.黄立辉,林海,刘行仁,林久令.Sm~(3+)掺杂的镉铝硅酸盐玻璃的光谱特性[J].红外与毫米波学报,2001,(2):201
50.Alberthmeiry T F,Valeria M L,et al.Blue-green and red photoluminescence in CaTiO_3:Sm[J].Journal of Luminescence,207,126:403
51.贺香红,周健,连宁.发光颜色可调谐的新型荧光体Sr2CeO4:RE3+(RE=Eu,Sm,Dy)发光性能[J].稀有金属材料与工程,2007,36(5):759
52.Yap Kang,Wang Mingwen,et al.Effects of Host Doping on Spectral and Long-Lasting Properties of Sm~(3+) -Doped Y_2 O_2 S[J].J rare earth,2006,24:524
53.赵广军,徐军.高光输出快衰减高温无机闪烁晶体的研究与发展[J].人工晶体学报,2002,31(3):291.
54.Baccaro S,Blazek K,De Notaristefani F.Scintillation properties of YAP:Ce[J]J Nucl Instr Meth Phys Res A,1995,361:209.
55.Klamra W,Kerek A,Moszyski M,Norlin L O,et al.Response of BaF2 and YAP:Ce to heavy ions[J].Nucl Instr Meth A,2000,444:626.
56.Slunga E,Cederwall B,Ideguchi E,Kerek A,et al.Scintillation response of BaF2 and YAlO3:Ce(YAPCe)to energetic ions[J].Nucl Instr Meth A,2001,469:70.
57.Hirota K,Toyokawa H,Suzuki M,Kudo T,et al.YAP(ce) imager operated in high energy X-ray region[J].Nucl Instr Meth A,2001,467-468:112
58.ZhydachevskiiY,Suchocki A,Berkowski M,Zakharko Ya.Optically stimulated luminescence of YAlO_3:Mn~(2+) for radiation dosimetry[J].Radiation Measurements,2007,42:625
59.Zhydachevskii Y,Durygin A,Suchocki A,Matkovskii A,et al.Radiation and thermally induced effects in YalO_3:Mn crystals[J]Journal of Luminescence,2004,109:39
60.张晓,等.Ce~(3+)和Mn~(2+)共激活的偏硅酸钙的发光性质和能量传递[J],硅酸盐学报,1989,17(2):140
61.Lei bingfu,et al.Luminescence properties of CdSiO_3:Mn~(2+) phosphor[J].J Lumin,2004,109:215
62.Belsky A N,Krupa J C.Luminsecence excition mechanisms of rare doped phosphors in the VUV range[J].Display,1990,19:185
1.Thiel C W,Cruguel H,Sun Y,et al.LapeyreSystematics of 4f electron energies relative to host bands by resonant photoemission of rare earth doped optical materials[J]Journal of Luminescence,2001,94-95:1
2.Xu Y N,Ching W Y,Brickeen B K,Electronic structure and bonding in garnet crystals Gd_3Sc_2Ga_3O_(12),Gd_3Sc_2Al_3O_(12),and Gd_3Ga_3O_(12) compared to Y_3Al_3O_(12)[J].Phys Rev B,2000,61:1817.
3.Thiel C W,Cruguel H,Wu H,et al.Systematies of 4f electron energies relative to host bands by resonant photoemission of rare-earth ions in aluminum garnets[J].Phys Rev B,2001,64:085107.
4.Yatsimirkii K B,Dacidenko N K.Absorption spectra and structure of lanthanide coordination compounds in solution[J].Coordination Chemistry Reviews,1979,27:223
5.Blasse G,et al.Fluorescence of Eu~(2+) Activated Silicates[J].Philips Res Repts,1968,23:201
6.Blasse G,Bril A.Investigations of Tb~(3+-) activated phosphors[J].Philips Res Repts.,(1967),22,481
7.Dexter D L,Schulman J H.Concentration and excitation effects in multiphonon non-radiative transitions of rare-earth ions[J].J Chem Phys,1954,22(6):1063
8.Dexter D L.A theory of sensitized luminescence in solids[J]J Chem Phys,1953,21:83
9.Perrin F.L'association moleculaire et l'optimum de la fluorescence des solutions.Influence des sels[J].Comptes Rendus,1931,192:1727
10.Forster Th,Annalen der Physik Zwischenmolekulare Energiewanderung und Fluoreszenz [J].1948,6(2):55