亲水性有机硅柔软剂的研制及应用
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摘要
氨基硅油在赋予棉织物优良的柔软性同时,也会使整理织物的亲水性明显变差。为此,人们对氨基硅油进行亲水改性,但目前现有的产品仍难以同时兼具良好的柔软性和亲水性。对此,本文合成了三种不同结构的亲水性有机硅柔软剂——侧链型聚醚改性氨基硅油、端季铵盐型嵌段聚醚聚硅氧烷和新型季铵盐聚醚聚硅氧烷共聚物,研究和比较了这三种整理剂的应用性能。具体研究内容及其结果如下:
第一部分:聚醚改性氨基硅油的制备及应用研究。以氨基硅油和环氧聚醚为原料,制备了可自乳化的聚醚改性氨基硅油(PMAS)。研究氨基硅油氨基与环氧聚醚环氧基的摩尔比、氨基硅油的氨值和粘度对PMAS乳液粒径及其整理棉织物柔软性、亲水性和白度的影响,优化合成反应条件;研究整理剂用量、焙烘温度和焙烘时间对整理织物应用性能的影响,优化整理工艺条件,并与氨基硅油和市场上同类产品进行应用性能比较。研究结果表明:当氨基硅油氨基和环氧聚醚环氧基摩尔比为1:1,氨基硅油的氨值为0.9mmol/g、粘度约1450mPa·s时,所合成的聚醚改性氨基硅油具有自乳化功能且乳液稳定;PMAS应用于棉织物的整理工艺优化条件为整理剂用量10g/L,焙烘温度140℃,焙烘时间50s;相对氨基硅油,聚醚改性氨基硅油整理棉织物具有相当的柔软性,且其亲水性得到了明显提高,但与市场产品相比,亲水性仍有待提高。
第二部分:端季铵盐型嵌段聚醚聚硅氧烷的制备及应用研究。以两端含氢硅油和双端烯丙基聚醚为原料,合成两端含氢型嵌段聚醚聚硅氧烷,再与烯丙基缩水甘油醚通过硅氢加成反应制得端环氧基嵌段聚醚聚硅氧烷,最后与十八叔胺反应合成出端季铵盐型嵌段聚醚聚硅氧烷。研究中间体——两端含氢型嵌段聚醚聚硅氧烷和目标产物——端季铵盐型嵌段聚醚聚硅氧烷的各单元合成反应工艺因素对转化率的影响,优化各单元合成工艺条件;研究端季铵盐型嵌段聚醚聚硅氧烷应用于棉织物的整理工艺因素对整理织物应用性能的影响,优化其整理工艺条件,并与氨基硅油和市场上同类产品进行应用性能比较;采用红外光谱仪、核磁共振仪对中间产物——端环氧基嵌段聚醚聚硅氧烷结构进行分析。研究结果表明:两端含氢型嵌段聚醚聚硅氧烷合成工艺优化条件为:两端含氢硅油和双端烯丙基聚醚的摩尔比为1.2:1,反应温度为75℃,反应时间3 h,催化剂用量为0.10%,溶剂乙酸乙酯用量为35%;端季铵盐型嵌段聚醚聚硅氧烷的合成(端环氧基嵌段聚醚聚硅氧烷季铵化改性)工艺优化条件为反应温度90℃,反应时间4.5h,溶剂异丙醇用量为30%;端季铵盐型嵌段聚醚聚硅氧烷应用于棉织物的整理工艺优化条件为整理剂用量为8g/L,焙烘温度为140℃,焙烘时间为30s。红外、核磁共振分析验证了中间产物——端环氧基嵌段聚醚聚硅氧烷结构。研究表明端季铵盐型嵌段聚醚聚硅氧烷整理剂具有良好的亲水性和柔软性,但相对氨基硅油整理织物,其柔软性及耐洗性有待提高。
第三部分:新型季铵盐聚醚聚硅氧烷共聚物的制备及应用研究。以端含氢硅油和烯丙基缩水甘油醚为原料,合成端环氧基硅油,再与聚醚胺反应制得嵌段聚醚氨基硅油,最后将其与2,3-环氧丙基氯化铵反应制得新型季铵盐聚醚聚硅氧烷共聚物。研究中间体——嵌段聚醚氨基硅油合成工艺因素对产物粘度的影响以及目标产物——新型季铵盐聚醚聚硅氧烷共聚物合成工艺因素对季铵化反应转化率的影响,优化了各单元合成工艺条件;采用FTIR、1HNMR、GPC对端环氧基硅油和嵌段聚醚氨基硅油结构进行表征;最后研究新型季铵盐聚醚聚硅氧烷共聚物应用于棉织物的整理工艺因素对整理织物应用性能的影响,优化其整理工艺条件,并与氨基硅油及其他亲水性有机硅柔软剂进行比较。研究结果表明:端环氧基硅油的合成工艺条件为:两端含氢硅油和烯丙基缩水甘油醚的摩尔比为1:2.2,反应温度80℃,反应时间为4h,催化剂用量0.1%,溶剂甲苯20%;嵌段聚醚氨基硅油的合成工艺优化条件为:端环氧基硅油与聚醚胺摩尔比为1:1.2、反应温度80℃、反应时间5h、溶剂用量30%;FTIR、1HNMR、GPC分析证实了端环氧基硅油和嵌段聚醚氨基硅油结构;新型季铵盐聚醚聚硅氧烷共聚物的合成工艺优化条件为:嵌段聚醚氨基硅油氨基与2,3-环氧丙基氯化铵环氧基摩尔比为1:1.1、反应温度70℃、反应时间5h、溶剂用量15%;新型季铵盐聚醚聚硅氧烷共聚物应用于棉织物的整理工艺优化条件为整理剂用量为6g/L,焙烘温度为140℃,焙烘时间为50s,所合成的新型季铵盐聚醚聚硅氧烷整理织物具有良好的亲水性、柔软性及耐洗性。
比较所合成的改性硅油整理剂整理织物的性能,聚醚改性氨基硅油整理棉织物具有与氨基硅油相当的柔软性,但亲水性较差;端季铵盐嵌段聚醚聚硅氧烷具有优良的亲水性能和一定的柔软性,但耐洗性较差;而新型季铵盐聚醚有机硅共聚物亲水柔软整理剂不仅具有良好的柔软性和亲水性,而且耐洗性好,能达到市场上同类产品水平,此整理剂不失为一种良好的新型亲水性有机硅柔软剂。
Amino-silicone oil finishing agent gives cotton fabric not only excellent softness, however, the hydrophilicity of the treated cotton fabric is reduced. It is necessary to modify Amino-silicone oil with polyether in order to improve the hydrophilicity of the treated fabric. However, the existing product is difficult to give consideration to the softness and hydrophilicity at the same time. Therefore, in this paper, the three kinds of hydrophilic silicone softener finishing agents—the amio-silicone modified with epoxy group polyether, the polydimethylsiloxane-polyether block copolymers terminated quaternary ammonium salt and the novel linear silicone aminopolyalkyleneoxide block copolymer modified by quaternary ammonium salt had been synthesized, and their application property had been also discussed to afford some information in the synthesis of a new better performance hydrophilic silicone softener finishing agent. The contents and results of researchs are as follows:
Part one: Study on preparation and application property of amio-silicone modified with epoxy group polyether. Self-emulsifying amino-silicone modified with epoxy group polyether (PMAS) were prepared with epoxy group polyether and amino-silicone (AS) as the raw material in the presence of isopropyl alcohol. The effect of these factors such as the amino value and the viscosity of AS, and the mole ratio of amino of amino-silicone to the epoxy group of polyether on the particle size of PMAS emulsion and the softness,hydrophilicity and whiteness of fabric finished with PMAS, the conditions of the reaction were optimized. The influence of finishing technology factors such as dosage of PMAS, baking temperature and baking time on the properties of the cotton fabric finished with PMAS were investigated, the finishing technology conditions of PMAS were optimized, and the application properties of the cotton fabric finished with PMAS were tested, and compared with that of AS and similar modified amino-silicone in market. The results indicated that when the amino value and viscosity of AS were 0.9mmol/g and 1450mPa·s, and the mole ratio of the amino of amino-silicone to epoxy group of polyether was 1:1, the synthetic PMAS could self–emulsify, its emulsion possesses good stability, and the optimal pad finishing process of PMAS are as follows: the dosage of PMAS was 10g/L, the baking temperature and baking time was 140℃×50s. The cotton fabric finished with PMAS possessed as good soft as and much better hydrophilic than that of the fabric treated with AS. However, Compared with similar modified amino-silicone in market, the hydrophilicity of AS modified by epoxy group polyether should be improved further.
Part two: Study on preparation and application property of polydimethylsiloxane-polyether block copolymers terminated quaternary ammonium salt.The linear polydimethylsiloxane-polyether block copolymers terminated by quaternary ammonium salt (QASTSP) had been synthesized. Firstly, polydimethylsiloxane -polyether block copolymersterminated epoxy group (ETSP) were prepared with allyl glycidyl ether (AGE) and polydimethylsiloxane-polyether block copolymers terminated by dihydrogen(HTSP) which was prepared with polysiloxanes terminated byα,ω-dihydrogen and polyether terminated byα,ω-allyl (ATP) as the raw materials in the solvent of ethyl acetate. Then QASTSP was obtained by the quaternization between ETSP and octadecyl dimethyl tertiary amine with isopropanol as solvent. The effect of these factors such as the molar ratio of HTSP to ATP, reaction temperature, the reaction time, and the amounts of solvent on the synthesis of the intermediate product——HTSP and the synthesis of the target compound——QASTSP were investigated, the conditions of the reaction were optimized. The structure of the ETSP was determined by FTIR、1HNMR. Finally,these factors such as dosage of QASTSP, baking temperature and baking time, which affect the hydrophilicity and softness of QASTSP were studied, the conditions of pad finishing process of QASTSP were optimized, and the application properties of the cotton fabric finished with QASTSP were tested, and compared with that of AS and similar modified amino-silicone product in market. The results indicated that the optimum conditions of the synthesis of HTSP were that the molar ratio of HTSP to ATP was 1.2:1, the reaction temperature was 75℃, the reaction time was 3h, the catalyst mass content was 0.10%, the amounts of dissolvent was 35%wt.The optimal reaction conditions of the synthesis of QASTSP were that the reaction temperature was 90℃, the reaction time was 4.5h, the amount of dissolvent was 30%wt.The optimum pad finishing process of QASTSP were as follows: dosage of QASTSP was 8g/L, baking temperature and baking time was 140℃×30s. The cotton fabric finished with QASTSP possessed good softness and hydrophilicity. However, compared with amino-silicone softener, the softness and the washing fastness of QASTSP should be improved further.
Part three: Study on preparation and application property of novel linear silicone aminopolyalkyleneoxide block copolymer modified by quaternary ammonium salt. A novel linear silicone aminopolyalkyleneoxide block copolymer modified by quaternary ammonium salt (QAPAMS) was synthesized by three steps. Firstly, epoxy-terminated polydimethylsiloxane (ETPS) was prepared with polydimethylsioxane terminated by hydrogen and allyl glycidyl ether as the raw materials by hydrosilication reaction. Secondly, silicone aminopolyalkyleneoxide block copolymer (SAPB) was synthesized with epoxy-terminated polydimethylsiloxane (ETPS) and polyether terminated by aminopropyl (ED-600) at the present of some solvent. Thirdly, a novel linear silicone aminopolyalkyleneoxide block copolymer modified by quaternary ammonium salt (QAPAMS) was synthesized with glycidtrimethylammonium chloride (EPTAC) and silicone aminopolyalkyleneoxide block copolymer. The effect of these factors of SAPB on its viscosity such as the molar ratio of ETPS to ED-600, reaction temperature, the reaction time, and the amounts of solvent were researched, the synthesis technology factors of novel linear silicone aminopolyalkyleneoxide block copolymers modified by quaternary ammonium salt (QAPAMS) on the conversion were also investigated, and the conditions of these reactions were optimized. The structure of ETPS and SAPB were determined by FTIR、1HNMR、GPC. The influence of these factors such as dosage of finishing, baking temperature and baking time on the application property of QAPAMS were studied, the conditions of finishing process of QAPAMS were optimized, and the application properties of the cotton fabric finished with QAPAMS were tested, and compared with that of AS and other hydrophilic modified amino-silicone. The results indicated that the conditions of the synthesis of SAPB were that the molar ratio was 1.2:1 (ETPS/ED-600), the reaction temperature was 80℃,the reaction time was 5h, and the dissolvent was 30%wt. The optimum conditions of the synthesis of QAPAMS were that the molar ratio of amino of SAPB to the epoxy group of EPTAC was 1:1.1, the reaction temperature was 70℃,the reaction time was 5h,and the dissolvent was15%wt. The optimum conditions of pad finishing process of QAPAMS were that dosage of finishing agent was 6g/L, baking temperature and baking time was 140℃×50s, the softness, hydrophilicity and washing fastness of the fabric treated with QAPAMS was desirable, compared with that of AS, PMAS, QASTSP, and similar hydrophilic modified amino-silicone product in market.
Compared with the application property of AS, PMAS, QASTSP, and similar hydrophilic modified amino-silicone product in market, the cotton fabric finished with PMAS possessed as good soft as and much better hydrophilic than that of the fabric treated with AS. However, the hydrophilicity of AS modified by epoxy group polyether was still poor. The cotton fabric finished with QASTSP possessed good softness and hydrophilicity. However, compared with amino-silicone softener, the washing fastness of QASTSP was poor. The fabric treated with QAPAMS possessed good softness, hydrophilicity and washing fastness, and match to that of similar hydrophilic modified amino-silicone product in market. The results show that the modified method of QAPAMS for silicone softener is fine to synthesize hydrophilic silicone softener.
第一部分:聚醚改性氨基硅油的制备及应用研究。以氨基硅油和环氧聚醚为原料,制备了可自乳化的聚醚改性氨基硅油(PMAS)。研究氨基硅油氨基与环氧聚醚环氧基的摩尔比、氨基硅油的氨值和粘度对PMAS乳液粒径及其整理棉织物柔软性、亲水性和白度的影响,优化合成反应条件;研究整理剂用量、焙烘温度和焙烘时间对整理织物应用性能的影响,优化整理工艺条件,并与氨基硅油和市场上同类产品进行应用性能比较。研究结果表明:当氨基硅油氨基和环氧聚醚环氧基摩尔比为1:1,氨基硅油的氨值为0.9mmol/g、粘度约1450mPa·s时,所合成的聚醚改性氨基硅油具有自乳化功能且乳液稳定;PMAS应用于棉织物的整理工艺优化条件为整理剂用量10g/L,焙烘温度140℃,焙烘时间50s;相对氨基硅油,聚醚改性氨基硅油整理棉织物具有相当的柔软性,且其亲水性得到了明显提高,但与市场产品相比,亲水性仍有待提高。
第二部分:端季铵盐型嵌段聚醚聚硅氧烷的制备及应用研究。以两端含氢硅油和双端烯丙基聚醚为原料,合成两端含氢型嵌段聚醚聚硅氧烷,再与烯丙基缩水甘油醚通过硅氢加成反应制得端环氧基嵌段聚醚聚硅氧烷,最后与十八叔胺反应合成出端季铵盐型嵌段聚醚聚硅氧烷。研究中间体——两端含氢型嵌段聚醚聚硅氧烷和目标产物——端季铵盐型嵌段聚醚聚硅氧烷的各单元合成反应工艺因素对转化率的影响,优化各单元合成工艺条件;研究端季铵盐型嵌段聚醚聚硅氧烷应用于棉织物的整理工艺因素对整理织物应用性能的影响,优化其整理工艺条件,并与氨基硅油和市场上同类产品进行应用性能比较;采用红外光谱仪、核磁共振仪对中间产物——端环氧基嵌段聚醚聚硅氧烷结构进行分析。研究结果表明:两端含氢型嵌段聚醚聚硅氧烷合成工艺优化条件为:两端含氢硅油和双端烯丙基聚醚的摩尔比为1.2:1,反应温度为75℃,反应时间3 h,催化剂用量为0.10%,溶剂乙酸乙酯用量为35%;端季铵盐型嵌段聚醚聚硅氧烷的合成(端环氧基嵌段聚醚聚硅氧烷季铵化改性)工艺优化条件为反应温度90℃,反应时间4.5h,溶剂异丙醇用量为30%;端季铵盐型嵌段聚醚聚硅氧烷应用于棉织物的整理工艺优化条件为整理剂用量为8g/L,焙烘温度为140℃,焙烘时间为30s。红外、核磁共振分析验证了中间产物——端环氧基嵌段聚醚聚硅氧烷结构。研究表明端季铵盐型嵌段聚醚聚硅氧烷整理剂具有良好的亲水性和柔软性,但相对氨基硅油整理织物,其柔软性及耐洗性有待提高。
第三部分:新型季铵盐聚醚聚硅氧烷共聚物的制备及应用研究。以端含氢硅油和烯丙基缩水甘油醚为原料,合成端环氧基硅油,再与聚醚胺反应制得嵌段聚醚氨基硅油,最后将其与2,3-环氧丙基氯化铵反应制得新型季铵盐聚醚聚硅氧烷共聚物。研究中间体——嵌段聚醚氨基硅油合成工艺因素对产物粘度的影响以及目标产物——新型季铵盐聚醚聚硅氧烷共聚物合成工艺因素对季铵化反应转化率的影响,优化了各单元合成工艺条件;采用FTIR、1HNMR、GPC对端环氧基硅油和嵌段聚醚氨基硅油结构进行表征;最后研究新型季铵盐聚醚聚硅氧烷共聚物应用于棉织物的整理工艺因素对整理织物应用性能的影响,优化其整理工艺条件,并与氨基硅油及其他亲水性有机硅柔软剂进行比较。研究结果表明:端环氧基硅油的合成工艺条件为:两端含氢硅油和烯丙基缩水甘油醚的摩尔比为1:2.2,反应温度80℃,反应时间为4h,催化剂用量0.1%,溶剂甲苯20%;嵌段聚醚氨基硅油的合成工艺优化条件为:端环氧基硅油与聚醚胺摩尔比为1:1.2、反应温度80℃、反应时间5h、溶剂用量30%;FTIR、1HNMR、GPC分析证实了端环氧基硅油和嵌段聚醚氨基硅油结构;新型季铵盐聚醚聚硅氧烷共聚物的合成工艺优化条件为:嵌段聚醚氨基硅油氨基与2,3-环氧丙基氯化铵环氧基摩尔比为1:1.1、反应温度70℃、反应时间5h、溶剂用量15%;新型季铵盐聚醚聚硅氧烷共聚物应用于棉织物的整理工艺优化条件为整理剂用量为6g/L,焙烘温度为140℃,焙烘时间为50s,所合成的新型季铵盐聚醚聚硅氧烷整理织物具有良好的亲水性、柔软性及耐洗性。
比较所合成的改性硅油整理剂整理织物的性能,聚醚改性氨基硅油整理棉织物具有与氨基硅油相当的柔软性,但亲水性较差;端季铵盐嵌段聚醚聚硅氧烷具有优良的亲水性能和一定的柔软性,但耐洗性较差;而新型季铵盐聚醚有机硅共聚物亲水柔软整理剂不仅具有良好的柔软性和亲水性,而且耐洗性好,能达到市场上同类产品水平,此整理剂不失为一种良好的新型亲水性有机硅柔软剂。
Amino-silicone oil finishing agent gives cotton fabric not only excellent softness, however, the hydrophilicity of the treated cotton fabric is reduced. It is necessary to modify Amino-silicone oil with polyether in order to improve the hydrophilicity of the treated fabric. However, the existing product is difficult to give consideration to the softness and hydrophilicity at the same time. Therefore, in this paper, the three kinds of hydrophilic silicone softener finishing agents—the amio-silicone modified with epoxy group polyether, the polydimethylsiloxane-polyether block copolymers terminated quaternary ammonium salt and the novel linear silicone aminopolyalkyleneoxide block copolymer modified by quaternary ammonium salt had been synthesized, and their application property had been also discussed to afford some information in the synthesis of a new better performance hydrophilic silicone softener finishing agent. The contents and results of researchs are as follows:
Part one: Study on preparation and application property of amio-silicone modified with epoxy group polyether. Self-emulsifying amino-silicone modified with epoxy group polyether (PMAS) were prepared with epoxy group polyether and amino-silicone (AS) as the raw material in the presence of isopropyl alcohol. The effect of these factors such as the amino value and the viscosity of AS, and the mole ratio of amino of amino-silicone to the epoxy group of polyether on the particle size of PMAS emulsion and the softness,hydrophilicity and whiteness of fabric finished with PMAS, the conditions of the reaction were optimized. The influence of finishing technology factors such as dosage of PMAS, baking temperature and baking time on the properties of the cotton fabric finished with PMAS were investigated, the finishing technology conditions of PMAS were optimized, and the application properties of the cotton fabric finished with PMAS were tested, and compared with that of AS and similar modified amino-silicone in market. The results indicated that when the amino value and viscosity of AS were 0.9mmol/g and 1450mPa·s, and the mole ratio of the amino of amino-silicone to epoxy group of polyether was 1:1, the synthetic PMAS could self–emulsify, its emulsion possesses good stability, and the optimal pad finishing process of PMAS are as follows: the dosage of PMAS was 10g/L, the baking temperature and baking time was 140℃×50s. The cotton fabric finished with PMAS possessed as good soft as and much better hydrophilic than that of the fabric treated with AS. However, Compared with similar modified amino-silicone in market, the hydrophilicity of AS modified by epoxy group polyether should be improved further.
Part two: Study on preparation and application property of polydimethylsiloxane-polyether block copolymers terminated quaternary ammonium salt.The linear polydimethylsiloxane-polyether block copolymers terminated by quaternary ammonium salt (QASTSP) had been synthesized. Firstly, polydimethylsiloxane -polyether block copolymersterminated epoxy group (ETSP) were prepared with allyl glycidyl ether (AGE) and polydimethylsiloxane-polyether block copolymers terminated by dihydrogen(HTSP) which was prepared with polysiloxanes terminated byα,ω-dihydrogen and polyether terminated byα,ω-allyl (ATP) as the raw materials in the solvent of ethyl acetate. Then QASTSP was obtained by the quaternization between ETSP and octadecyl dimethyl tertiary amine with isopropanol as solvent. The effect of these factors such as the molar ratio of HTSP to ATP, reaction temperature, the reaction time, and the amounts of solvent on the synthesis of the intermediate product——HTSP and the synthesis of the target compound——QASTSP were investigated, the conditions of the reaction were optimized. The structure of the ETSP was determined by FTIR、1HNMR. Finally,these factors such as dosage of QASTSP, baking temperature and baking time, which affect the hydrophilicity and softness of QASTSP were studied, the conditions of pad finishing process of QASTSP were optimized, and the application properties of the cotton fabric finished with QASTSP were tested, and compared with that of AS and similar modified amino-silicone product in market. The results indicated that the optimum conditions of the synthesis of HTSP were that the molar ratio of HTSP to ATP was 1.2:1, the reaction temperature was 75℃, the reaction time was 3h, the catalyst mass content was 0.10%, the amounts of dissolvent was 35%wt.The optimal reaction conditions of the synthesis of QASTSP were that the reaction temperature was 90℃, the reaction time was 4.5h, the amount of dissolvent was 30%wt.The optimum pad finishing process of QASTSP were as follows: dosage of QASTSP was 8g/L, baking temperature and baking time was 140℃×30s. The cotton fabric finished with QASTSP possessed good softness and hydrophilicity. However, compared with amino-silicone softener, the softness and the washing fastness of QASTSP should be improved further.
Part three: Study on preparation and application property of novel linear silicone aminopolyalkyleneoxide block copolymer modified by quaternary ammonium salt. A novel linear silicone aminopolyalkyleneoxide block copolymer modified by quaternary ammonium salt (QAPAMS) was synthesized by three steps. Firstly, epoxy-terminated polydimethylsiloxane (ETPS) was prepared with polydimethylsioxane terminated by hydrogen and allyl glycidyl ether as the raw materials by hydrosilication reaction. Secondly, silicone aminopolyalkyleneoxide block copolymer (SAPB) was synthesized with epoxy-terminated polydimethylsiloxane (ETPS) and polyether terminated by aminopropyl (ED-600) at the present of some solvent. Thirdly, a novel linear silicone aminopolyalkyleneoxide block copolymer modified by quaternary ammonium salt (QAPAMS) was synthesized with glycidtrimethylammonium chloride (EPTAC) and silicone aminopolyalkyleneoxide block copolymer. The effect of these factors of SAPB on its viscosity such as the molar ratio of ETPS to ED-600, reaction temperature, the reaction time, and the amounts of solvent were researched, the synthesis technology factors of novel linear silicone aminopolyalkyleneoxide block copolymers modified by quaternary ammonium salt (QAPAMS) on the conversion were also investigated, and the conditions of these reactions were optimized. The structure of ETPS and SAPB were determined by FTIR、1HNMR、GPC. The influence of these factors such as dosage of finishing, baking temperature and baking time on the application property of QAPAMS were studied, the conditions of finishing process of QAPAMS were optimized, and the application properties of the cotton fabric finished with QAPAMS were tested, and compared with that of AS and other hydrophilic modified amino-silicone. The results indicated that the conditions of the synthesis of SAPB were that the molar ratio was 1.2:1 (ETPS/ED-600), the reaction temperature was 80℃,the reaction time was 5h, and the dissolvent was 30%wt. The optimum conditions of the synthesis of QAPAMS were that the molar ratio of amino of SAPB to the epoxy group of EPTAC was 1:1.1, the reaction temperature was 70℃,the reaction time was 5h,and the dissolvent was15%wt. The optimum conditions of pad finishing process of QAPAMS were that dosage of finishing agent was 6g/L, baking temperature and baking time was 140℃×50s, the softness, hydrophilicity and washing fastness of the fabric treated with QAPAMS was desirable, compared with that of AS, PMAS, QASTSP, and similar hydrophilic modified amino-silicone product in market.
Compared with the application property of AS, PMAS, QASTSP, and similar hydrophilic modified amino-silicone product in market, the cotton fabric finished with PMAS possessed as good soft as and much better hydrophilic than that of the fabric treated with AS. However, the hydrophilicity of AS modified by epoxy group polyether was still poor. The cotton fabric finished with QASTSP possessed good softness and hydrophilicity. However, compared with amino-silicone softener, the washing fastness of QASTSP was poor. The fabric treated with QAPAMS possessed good softness, hydrophilicity and washing fastness, and match to that of similar hydrophilic modified amino-silicone product in market. The results show that the modified method of QAPAMS for silicone softener is fine to synthesize hydrophilic silicone softener.
引文
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