TJNJ港区含油污水处理改造工程技术经济分析
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摘要
天津市为贯彻落实《国务院关于落实科学发展观和加强环境保护的决定》和《国务院关于推进滨海新区开发开放有关问题的意见》的关于“城镇污水处理厂排水要达到国家《城镇污水处理厂污染物排放标准》(GB18918-2002)一级排放标准。”的规定,对企业污水排放标准限值进行了调整。根据天津市政府的要求,TJNJ港区的原有污水处理系统需要进行技术改造,以达到污水排放新标准。
本文首先对TJNJ港区含油污水处理原有系统进行深入调研分析,得出了TJNJ港区含油污水处理原有系统达到新的污水排放标准存在的主要问题;其次,在分析含油污水处理工艺和技术进展和发展趋势基础上,提出了两种原有含油污水处理系统改造工程的方案,分别为物化处理系统-Fenton氧化处理方案(方案一)、生化处理系统-膜生物反应器(MBR)方案(方案二);最后,以技术经济指标评价和比选两个改造工程方案,并对优化改造工程方案进行了财务评价和国民经济评价。
改造工程实践结果证明,TJNJ港区含油污水处理系统改造工程取得了很好的经济效益和环境效益,污水排放指标达到和超过了新的排放标准。
To implement the "State Council on the implementation of scientific development and strengthening environmental protection decision" and "the State Council on promoting the development and opening of Binhai New Area, the views of the relevant issues" on the "urban sewage treatment plant effluent to meet the national" pollution of urban sewage treatment plant emission standard "(GB18918-2002) an emission standard.",Tianjin has adjusted the corporate limits of the effluent standards.According to the requirements of the Tianjin municipal government , the original sewage treatment system of TJNJ port need to carry out a technological transformation to meet the new standard for sewage discharge.
At first,this paper has made a depth investigation and analysis of the original oil wastewater treatment system of the TJNJ port,and get the the main problems that exsit on the rode of the original oil wastewater treatment system of the TJNJ port to reach a new effluent discharge standards;second, based on the analysis of the progress and development trends of the oily wastewater treatment processes and technologies, we propose two programs to transform the original oil wastewater,one is called Physico-chemical treatment systems-Fenton oxidation treatment program(program 1),the other is called Biological treatment system– membrane bioreactor(MBR)program(program 2); third,make a comparison of two transformation projects with the sum of evaluation of the Technical and economic indicators,and aslo make a financial evaluation and National economy evaluation for optimizing the transformation project.
The practice results of the transformation project turns out that the Oily Wastewater Treatment System Improvement Project of TJNJ Port has achieved good economic and environmental benefits,wastewater emission indicators have meet and even exceed the new emission standards.
本文首先对TJNJ港区含油污水处理原有系统进行深入调研分析,得出了TJNJ港区含油污水处理原有系统达到新的污水排放标准存在的主要问题;其次,在分析含油污水处理工艺和技术进展和发展趋势基础上,提出了两种原有含油污水处理系统改造工程的方案,分别为物化处理系统-Fenton氧化处理方案(方案一)、生化处理系统-膜生物反应器(MBR)方案(方案二);最后,以技术经济指标评价和比选两个改造工程方案,并对优化改造工程方案进行了财务评价和国民经济评价。
改造工程实践结果证明,TJNJ港区含油污水处理系统改造工程取得了很好的经济效益和环境效益,污水排放指标达到和超过了新的排放标准。
To implement the "State Council on the implementation of scientific development and strengthening environmental protection decision" and "the State Council on promoting the development and opening of Binhai New Area, the views of the relevant issues" on the "urban sewage treatment plant effluent to meet the national" pollution of urban sewage treatment plant emission standard "(GB18918-2002) an emission standard.",Tianjin has adjusted the corporate limits of the effluent standards.According to the requirements of the Tianjin municipal government , the original sewage treatment system of TJNJ port need to carry out a technological transformation to meet the new standard for sewage discharge.
At first,this paper has made a depth investigation and analysis of the original oil wastewater treatment system of the TJNJ port,and get the the main problems that exsit on the rode of the original oil wastewater treatment system of the TJNJ port to reach a new effluent discharge standards;second, based on the analysis of the progress and development trends of the oily wastewater treatment processes and technologies, we propose two programs to transform the original oil wastewater,one is called Physico-chemical treatment systems-Fenton oxidation treatment program(program 1),the other is called Biological treatment system– membrane bioreactor(MBR)program(program 2); third,make a comparison of two transformation projects with the sum of evaluation of the Technical and economic indicators,and aslo make a financial evaluation and National economy evaluation for optimizing the transformation project.
The practice results of the transformation project turns out that the Oily Wastewater Treatment System Improvement Project of TJNJ Port has achieved good economic and environmental benefits,wastewater emission indicators have meet and even exceed the new emission standards.
引文
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[2] Rubio J,Souza M L,Smith R W. Overview of flotation as a wastewater treatment technique[J]. Minerals Engineering,2002,15(3):139-155.
[3]唐善法,刘芬.气浮技术处理聚合物驱含油污水研究[J].石油天然气学报,2006,28 (4):131-133.
[4] Li Xiaobing,Liu Jiongtian,Wang Yongtian,et,al. Separation of oil from wastewater by column flotation [J]. Journal of China University of Mining and Technology,2007,17 (4):546-551,577.
[5] Hami Malik L,Al-Hashimi M A,Al-Doori M M. Effect of activated carbon on BOD and COD removal in a dissolved air flotation unit treating refinery wastewater [J]. Desalination,2007,216 (1-3):116-122.
[6] Ahmad A L,Sumathi S,Hameed B H. Coagulation of residue oil and suspended solid in palm oil mill effluent by chitosan,alum and PAC [J]. Chemical Engineering Journal,2006,118(1-2):99-105.
[7] Zeng Defang,Wu Juanjuan,Kennedy John F. Application of a chitosan flocculant to water treatment [J]. Carbohydrate Polymers,2008,71 (1):135-139.
[8] Pinotti A,Zaritzky N. Effect of aluminum sulfate and cationic polyelectrolytes on the destabilization of emulsified wastes [J]. Waste Management,2001,21 (6):535-542.
[9] Owen A T,Fawell P D,Swift J D. The preparation and ageing of acrylamide/acrylate copolymer flocculant solutions [J]. International Journal of Mineral Processing,2007,84 (1-4):3-14.
[10] Zeng Yubin,Yang Changzhu,Zhang Jingdong,et al. Feasibility investigation of oily wastewater treatment by combination of zinc and PAM in coagulation/flocculation [J]. Journal of Hazardous Materials,2007,147 (3):991-996.
[11]蔺爱国,刘培勇,刘刚,等.膜分离技术在油田含油污水处理中的应用研究进展[J].工业水处理,2006,26 (1):5-8.
[12] Yu Shuili,Lu Yan,Chai Baoxiang. Treatment of oily wastewater by organic–inorganic composite tubular ultrafiltration (UF) membranes [J]. Desalination,2006,196 (1-3):76-83.
[13] Song Chengwen ,Wang Tonghua , Pan Yanqiu. Preparation of coal-based microfiltration carbon membrane and application in oily wastewater treatment [J]. Separation and Purification Technology,2006,51 (1):80-84.
[14] Um Mi-Jung,Yoon Seong-Hoon,Lee Chung-Hak. Flux enhancement with gas injection in crossflow ultrafiltration of oily wastewater [J].Water Research,2001,35 (17):4095-4101.
[15] Tomaszewska Maria,Orecki Aleksander,Karakulski Krzysztof. Treatment of bilge water using a combination of ultrafiltration and reverse osmosis [J]. Desalination,2005,185 (1-3):203-212.
[16] Hua F L,Tsang Y F,Wang Y J,et al. Performance study of ceramic microfiltration membrane for oily wastewater treatment [J]. ChemicalEngineering Journal,2007,128 (2-3):169-175.
[17] Ca?izares Pablo,Martínez Fabiola,Lobato Justo,et al. Break-up of oil-in-water emulsions by electrochemical techniques [J]. Journal of Hazardous Materials,2007,145(1-2):233-240.
[18] Ofir E,Oren Y,Adin A. Comparing pretreatment by iron of electro-flocculation and chemical flocculation [J]. Desalination,2007,204 (1-3):87-93.
[19] Yang Chenlu. Electrochemical coagulation for oily water demulsification [J]. Separation and Purification Technology,2007,54 (3):388-395.
[20] Ivonne Linares-Hernández,Carlos Barrera-Díaz,Gabriela Roa-Morales, et al. A combined electrocoagulation–sorption process applied to mixed industrial wastewater [J]. Journal of Hazardous Materials,2007,144 (1-2):240-248.
[21]任连锁,郑杰.电气浮处理含油废水技术研究与应用[J].小型油气藏,2006,11 (1):58-61.
[22] Jiang Jiaqian , Graham Nigel , AndréCecile. Laboratory study ofelectro-coagulation–flotation for water treatment [J]. Water Research,2002,36 (16):4064-4078.
[23] Mostefa N Moulai,Tir M. Coupling flocculation with electroflotation for waste oil/water emulsion treatment. Optimization of the operating conditions [J]. Centre Universitaire Yahia Fares,2004,161 (2):115-121.
[24] Murugananthan M,Bhaskar Raju G,Prabhakar S. Removal of sulfide,sulfate and sulfite ions by electro coagulation[J]. Journal of Hazardous Materials,2004,109 (1-3):37-44.
[25]王东莉,梁政.电磁油田废水处理[J].设计与研究,2006,33 (5):13-15.
[26]刘佳鑫,龚萍.电磁脉冲水处理技术在重钢浊环水系统的应用[J].冶金动力,2007 (4):59-61.
[27] Li Yijiu,Wang Feng,Zhou Guoding. Aniline degradation by eletrocatalytic oxidation [J]. Chemosphere,2003,53 (10):1229-1234.
[28] Koper Marc T M. Combining experiment and theory for understanding electrocatalysis [J]. Journal of Electroanalytical Chemistry,2005,574 (2):375-386.
[29] Feng Y J,Li X Y. Electro-catalytic oxidation of phenol on several metal-oxide electrodes in aqueous solution [J]. Water Research,2003,37 (10):2399-2407.
[30] Trasatti S. Electrocatalysis:understanding the success of DSA [J]. Electrochimica Acta,2000,45 (15-16):2377-2385.
[31]汪文兵,龙晋明,郭忠诚.钛基金属氧化物涂层电极的研究进展[J].电镀与涂饰,2006,25 (7):46-48.
[32] Santos Marcos R G,Goulart Marilia O F,Tonholo Josealdo, et al. The application ofelectrochemical technology to the remediation of oily wastewater [J]. Chemosphere,2006,64 (3):393-399.
[33] Iniesta J,Michaud P A,Panizza M,et al. Electrochemical oxidation of phenol at boron-doped diamond electrode [J]. Electrochimica Acta,2001,46 (23):3573-3578.
[34] Pacheco M J,Mor?o A,Lopes A,et al. Degradation of phenols using boron-doped diamond electrodes:A method for quantifying the extent of combustion [J]. Electrochimica Acta,2007,53(2):629-636.
[35] Bellagamba R,Michaud P A,Comninellis Ch,et al. Electrocombustion of polyacrylates with boron-doped diamond anodes [J]. Electrochemistry Communications,2002,4 (2):171-176.
[36] Chen Guohua. Electrochemical technologies in wastewater treatment [J]. Separation and Purification Technology,2004,38 (1):11-41.
[37]徐海生,肖传发,赵建宏,等.板框式电化学反应器流动规律及对反应的影响[J].化学反应工程与工艺,2006,22 (1):27-32.
[38] Nierhaus Thomas,Vanden Abeele David,Deconinck Herman. Direct numerical simulation of bubbly flow in the turbulent boundary layer of a horizontal parallel plate electrochemical reactor [J]. International Journal of Heat and Fluid Flow,2007,28 (4):542-551.
[39] Sakairi Masatoshi,Yamada Masashi,Kikuchi Tastuya,et al. Development of three-electrode type micro-electrochemical reactor on anodized aluminum with photon rupture and electrochemistry [J]. Electrochimica Acta,2007,52 (21):6268-6274.
[40] Perez M,Rodriguez-Cano R,Romero L I,et al. Performance of anaerobic thermophilic fluidized bed in the treatment of cutting-oil wastewater [J]. Bioresource Technology,2007,98 (18):3456-3463.
[41] de Francesco Maurizio,Costamagna Paola. On the design of electrochemical reactors for the treatment of polluted water [J]. Journal of Cleaner Production,2004,12 (2):159-163.
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