絮凝—膜分离法处理含油废水的技术研究
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摘要
含油废水危害人体健康和生存环境,必须妥善处理。在已有的研究基础上,针对含油废水的水质特点,本文设计了絮凝-膜分离的方法进行含油废水的处理研究。
本文以水溶性淀粉为基体,选用a-甲基丙烯酸对其进行接枝聚合改性,在最佳合成条件下得到了一种新型高效絮凝剂,接枝效率达到60.3%。考察了接枝聚合引发剂用量、反应温度、反应时间以及丙烯酸单体用量等因素对接枝效率的影响。
采用改性淀粉絮凝剂与复合无机絮凝剂配合使用处理含油废水。对此进行了单一条件优化实验,设计正交实验进行系统优化,得到最优水平条件。通过絮凝沉降处理,水中油含量降低75%,COD降低83.06%。
本文采用卷式超滤膜处理经过絮凝沉降的含油废水,水中油去除率由75%增加到91%,COD去除率近于100%。
It is very important to treat oily wastewater because oily wastewater endangers human health and environment. We designed the method of flocculation-membrane separation for the treatment of oily wastewater according to water quality characteristics of oily wastewater and former study.
In this dissertation, we obtained a new flocculent with high efficiency by grafting and copolymerizing a-methacrylic acid on to starch. Under the optimal synthesize conditions, the efficiency of grafting reached as high as 60.3%. We investigated the effect of the quantity of starch, a-methacrylic acid and initiator, temperature, time of reaction on the efficiency of grafting.
The developed modified starch flocculent cooperating inorganic complex flocculent was also successfully applied to the treatment of oily wastewater. Every condition was optimized by experiment. And orthogonal experiment was designed for optimizing system, the optimal conditions had been obtained finally. Under this condition, the removal efficiency of the system is good that the removal rate for oil is 75% and COD is 83.06% through the treatment of flocculation.
We used coil hyperfiltration film to treat above oily wastewater. The removal rate for oil increase from 75% to 91% and COD is close to 100%.
本文以水溶性淀粉为基体,选用a-甲基丙烯酸对其进行接枝聚合改性,在最佳合成条件下得到了一种新型高效絮凝剂,接枝效率达到60.3%。考察了接枝聚合引发剂用量、反应温度、反应时间以及丙烯酸单体用量等因素对接枝效率的影响。
采用改性淀粉絮凝剂与复合无机絮凝剂配合使用处理含油废水。对此进行了单一条件优化实验,设计正交实验进行系统优化,得到最优水平条件。通过絮凝沉降处理,水中油含量降低75%,COD降低83.06%。
本文采用卷式超滤膜处理经过絮凝沉降的含油废水,水中油去除率由75%增加到91%,COD去除率近于100%。
It is very important to treat oily wastewater because oily wastewater endangers human health and environment. We designed the method of flocculation-membrane separation for the treatment of oily wastewater according to water quality characteristics of oily wastewater and former study.
In this dissertation, we obtained a new flocculent with high efficiency by grafting and copolymerizing a-methacrylic acid on to starch. Under the optimal synthesize conditions, the efficiency of grafting reached as high as 60.3%. We investigated the effect of the quantity of starch, a-methacrylic acid and initiator, temperature, time of reaction on the efficiency of grafting.
The developed modified starch flocculent cooperating inorganic complex flocculent was also successfully applied to the treatment of oily wastewater. Every condition was optimized by experiment. And orthogonal experiment was designed for optimizing system, the optimal conditions had been obtained finally. Under this condition, the removal efficiency of the system is good that the removal rate for oil is 75% and COD is 83.06% through the treatment of flocculation.
We used coil hyperfiltration film to treat above oily wastewater. The removal rate for oil increase from 75% to 91% and COD is close to 100%.
引文
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