改进型纳米TiO_2复合膜的光生阴极保护研究
|
摘要
纳米TiO_2薄膜独特的光电化学性质,已受到广泛的关注,并成功应用于光催化处理污染物、超双亲自清洁、太阳能转换和储存等高科技领域。TiO_2的光电特性在金属腐蚀防护方面表现出诱人的应用前景,正日益受到人们的重视。然而,TiO_2是宽禁带半导体化合物,只吸收λ＜387nm的紫外光,太阳能利用率仅为3-4%,而且光生电子—空穴对快速复合,光转化效率还很低,通常在暗态下难以对金属基体起到有效的光生阴极保护作用。
本论文侧重发展多种纳米TiO_2复合膜及表面改性技术,探索纳米涂覆层表面均一化、消除各种物理缺陷的有效技术,以期在TiO_2纳米覆盖膜材料的制备和改性方面有所突破。发展环境友好的水热法制备特殊纳米结构的TiO_2薄膜,研究在金属防护中可能的应用,考察相关的影响因素和规律性,揭示TiO_2表面结构和光电性质的相关性。结合掺杂和半导体复合技术有效地延长TiO_2光生电子-空穴对的寿命,强化暗态下的光生阴极保护作用,并探索纳米TiO_2复合膜光生阴极保护的作用机理。主要的研究进展及成果如下:
1.发展了溶胶.凝胶法和浸渍一提拉技术,在316L SS表面分别构筑N、S和Cl改性的纳米TiO_2复合膜。经不同的无机离子改性的TiO_2纳米膜的表面形貌、微结构和结晶度存在明显差异。N改性的纳米TiO_2膜结晶度良好,膜表面更均一和致密,平均的晶粒尺寸为25 nm。在相同的测试条件下,N改性的TiO_2纳米膜具有较高的光电响应。
2.N改性的TiO_2纳米膜在0.5 mol/L NaCl溶液中具有较好的表面阻挡层作用。在白光的照射下,N-TiO_2复合膜可为金属基体提供有效的阴极保护,而在暗态下,阻挡层发挥主要作用,可有效地保护金属免遭腐蚀.纳米N-TiO_2薄膜对金属基体有双重的保护作用。
3.采用溶胶-凝胶法制备非金属B掺杂的CeO_2,B原子固溶于CeO_2晶隙中,形成了B-Ce-O键。结合半导体复合技术,在不锈钢表面构筑(外)TiO_2|(内)B-CeO_2纳米复合膜。光电化学测试结果表明,在白光照射下,TiO_2|B-CeO_2复合膜可使金属基体处于阴极保护状态,而且当停止光照后,纳米TiO_2 | B-CeO_2复合膜可实现持续的光生阴极保护作用,即暗态下TiO_2| B-CeO_2 | 316L SS电极的电位可稳定在-0.10V_(SCE)附近(低于316L SS的自然腐蚀电位),并保持一段较长的时间(～7h)。另一方面,TiO_2 | B-CeO_2复合膜作为阻挡层也有较好的保护性能,复合膜光生阴极保护和阻挡层双重作用的有机结合可更好地实现对金属的有效防护。
4.发展环境友好、成本低廉、操作简便的水热合成法,并结合简单的后处理技术,在Ti基底表面制备了锐钛矿型纳米TiO_2薄膜。对水热反应的温度和时间工艺参数的调节可实现对纳米TiO_2薄膜的表面结构和厚度的可控。不同表面结构和厚度的纳米TiO_2薄膜具有不同的光电响应行为。在膜厚一致的条件下,在白光照射下,水热合成的网络状结构的TiO_2纳米膜和电化学阳极氧化制备的TiO_2纳米管阵列膜均可提供有效的光生阴极保护作用。
5.发展低温水热法制备特定晶型纳米TiO_2薄膜。与常规高温煅烧(450℃,2h)制备锐钛矿型TiO_2的方法相比,环境友好的水热法可在低温(170℃)下制得结晶度良好的锐钛矿型TiO_2。通过改变水热工艺参数,可控制TiO_2的结晶程度和表面形貌。在模拟海水介质中,与常规450℃热处理2h所制备的TiO_2纳米膜相比,170℃水热反应4h获得的结晶度高、结构致密的TiO_2纳米膜对金属基体具有更好的防护性能。
Nano TiO_2 thin films,due to their unique photoelectrochemical properties,have been world-wide attractive,and extensively applied in many hi-tech fields,such as photocatalysis,surper-hydrophilic self-cleaning,solar cells and so on.The investigation of TiO_2 for photogenerated cathode protection of metals has received great attention.However,due to the wide band gap of TiO_2 semiconductor,it is only excited by ultraviolet light(λ＜387nm),and only 3-4%solar energy can be utilized. And the recombination rate of photogenerated electron-hole pairs in TiO_2 is high and the quantum efficiency is low,it is usually impossible to offer a distinctly photogenerated cathode protection for metal substrates under dark conditions.
In this dissertation,the various techniques have been developed to prepare nano TiO_2 composite films combining with the surface modifications in order to achieve an optimal barrier resistance and efficient photo-generated cathodic protection to corrosion of metals.An environmentally friendly hydrothermal method has been developed to synthesize special nanostructured TiO_2 thin films and their dual functions of barrier resistance and photo-generated cathode protection to corrosion of metals have been investigated.The results have been discussed in terms of the structure of TiO_2 film and its performance of photogenerated cathode protection.The emphases have been made to efficiently last the life of electron-hole pairs in nano TiO_2 composite films by doping and coupling to another semiconductor,and enhance the photogenerated cathode protection for metals in dark.The mechanism of nano TiO_2 composite films for photogenerated cathode protection has been further examined as well.The main results and progresses of this work are outlined as following:
1.A sol-gel and dip-coating technique has been developed to prepare nano TiO_2 films modified with anions of nitrogen,sulfur and chlorine supplied on the surface of 316L stainless steel,respectively.When modified with the different anions,the surface morphology,structure and the degree of crystallization of TiO_2 films are remarkably different.The N-modified TiO_2 nano-coatings show higher photocurrent under the same measurement conditions.
2.N-modified TiO_2 nano-films are able to act as an optimal barrier layer to metallic substrates in 0.5 M NaCl solution.And N-modified TiO_2 nano-films provide a distinctly photogenerated cathode protection for 316L SS under the white light illumination.When the illumination is stopped,the N-modified TiO_2 nano-films still exhibit a protective barrier layer for metals,showing a dual function in corrosion protection of metals.
3.A sol-gel technique is used to prepare CeO_2 doped by B element,which is found to exist in the interstitial space of CeO_2 crystal lattice by forming B-Ce-O bond. Bilayer coatings consisting of a B-doped CeO_2 inner layer and a TiO_2 outer layer are made on 316L SS substrate(316L SS｜B-CeO_2｜TiO_2) by coupling.Based on the photoelectrochemical measurements,the TiO_2｜B-CeO_2 films provide a distinctly photogenerated cathode protection for 316L SS under the white light illumination,and sustain the photoeffect for nearly 7 hours when the illumination is stopped,indicating that TiO_2｜B-CeO_2 films are able to continue photogenerated cathode protection for a long period of time in dark.On the other hand,the TiO_2｜B-CeO_2 films still exhibit a good barrier layer for metals, both protective performances of TiO_2｜B-CeO_2 films can offer better protection for metals in a corrosive environment.
4.A simple,low-cost and environmentally friendly hydrothermal method followed by a facile post-treatment has been developed to prepare anatase TiO_2 thin film on the Ti substrate.The morphology and thickness of the as-attained TiO_2 film can be successfully controlled by varying the hydrothermal reaction temperature and time.The TiO_2 films with different surface morphology or thickness show different photocurrent maximum.When the thickness of TiO_2 films is comparable,the net-like structured TiO_2 film obtained with a low-temperature hydrothermal process and the TiO_2 nanotube(TN) array film prepared by electrochemical anodization both offer a distinctly photogenerated cathode protection for 316L SS under the white light illumination.
5.A low-temperature hydrothermal method has been developed to prepare TiO_2 thin films with certain crystallization.Different from the common method, namely,calcination at 450℃for 2h,it is facile for a hydrothermal method to attain anatase TiO_2 with high crystallization at a low temperature of 170℃.The surface morphology and the degree of crystallization of the as-attained TiO_2 film can be successfully controlled by varying the temperature and time of hydrothermal reaction.Compared with TiO_2 film derived by calcined at 450℃for 2h,the TiO_2 film derived by hydrothermal reaction at 170℃for 4h exhibits better barrier resistance to corrosion in simulated seawater.
本论文侧重发展多种纳米TiO_2复合膜及表面改性技术,探索纳米涂覆层表面均一化、消除各种物理缺陷的有效技术,以期在TiO_2纳米覆盖膜材料的制备和改性方面有所突破。发展环境友好的水热法制备特殊纳米结构的TiO_2薄膜,研究在金属防护中可能的应用,考察相关的影响因素和规律性,揭示TiO_2表面结构和光电性质的相关性。结合掺杂和半导体复合技术有效地延长TiO_2光生电子-空穴对的寿命,强化暗态下的光生阴极保护作用,并探索纳米TiO_2复合膜光生阴极保护的作用机理。主要的研究进展及成果如下:
1.发展了溶胶.凝胶法和浸渍一提拉技术,在316L SS表面分别构筑N、S和Cl改性的纳米TiO_2复合膜。经不同的无机离子改性的TiO_2纳米膜的表面形貌、微结构和结晶度存在明显差异。N改性的纳米TiO_2膜结晶度良好,膜表面更均一和致密,平均的晶粒尺寸为25 nm。在相同的测试条件下,N改性的TiO_2纳米膜具有较高的光电响应。
2.N改性的TiO_2纳米膜在0.5 mol/L NaCl溶液中具有较好的表面阻挡层作用。在白光的照射下,N-TiO_2复合膜可为金属基体提供有效的阴极保护,而在暗态下,阻挡层发挥主要作用,可有效地保护金属免遭腐蚀.纳米N-TiO_2薄膜对金属基体有双重的保护作用。
3.采用溶胶-凝胶法制备非金属B掺杂的CeO_2,B原子固溶于CeO_2晶隙中,形成了B-Ce-O键。结合半导体复合技术,在不锈钢表面构筑(外)TiO_2|(内)B-CeO_2纳米复合膜。光电化学测试结果表明,在白光照射下,TiO_2|B-CeO_2复合膜可使金属基体处于阴极保护状态,而且当停止光照后,纳米TiO_2 | B-CeO_2复合膜可实现持续的光生阴极保护作用,即暗态下TiO_2| B-CeO_2 | 316L SS电极的电位可稳定在-0.10V_(SCE)附近(低于316L SS的自然腐蚀电位),并保持一段较长的时间(～7h)。另一方面,TiO_2 | B-CeO_2复合膜作为阻挡层也有较好的保护性能,复合膜光生阴极保护和阻挡层双重作用的有机结合可更好地实现对金属的有效防护。
4.发展环境友好、成本低廉、操作简便的水热合成法,并结合简单的后处理技术,在Ti基底表面制备了锐钛矿型纳米TiO_2薄膜。对水热反应的温度和时间工艺参数的调节可实现对纳米TiO_2薄膜的表面结构和厚度的可控。不同表面结构和厚度的纳米TiO_2薄膜具有不同的光电响应行为。在膜厚一致的条件下,在白光照射下,水热合成的网络状结构的TiO_2纳米膜和电化学阳极氧化制备的TiO_2纳米管阵列膜均可提供有效的光生阴极保护作用。
5.发展低温水热法制备特定晶型纳米TiO_2薄膜。与常规高温煅烧(450℃,2h)制备锐钛矿型TiO_2的方法相比,环境友好的水热法可在低温(170℃)下制得结晶度良好的锐钛矿型TiO_2。通过改变水热工艺参数,可控制TiO_2的结晶程度和表面形貌。在模拟海水介质中,与常规450℃热处理2h所制备的TiO_2纳米膜相比,170℃水热反应4h获得的结晶度高、结构致密的TiO_2纳米膜对金属基体具有更好的防护性能。
Nano TiO_2 thin films,due to their unique photoelectrochemical properties,have been world-wide attractive,and extensively applied in many hi-tech fields,such as photocatalysis,surper-hydrophilic self-cleaning,solar cells and so on.The investigation of TiO_2 for photogenerated cathode protection of metals has received great attention.However,due to the wide band gap of TiO_2 semiconductor,it is only excited by ultraviolet light(λ＜387nm),and only 3-4%solar energy can be utilized. And the recombination rate of photogenerated electron-hole pairs in TiO_2 is high and the quantum efficiency is low,it is usually impossible to offer a distinctly photogenerated cathode protection for metal substrates under dark conditions.
In this dissertation,the various techniques have been developed to prepare nano TiO_2 composite films combining with the surface modifications in order to achieve an optimal barrier resistance and efficient photo-generated cathodic protection to corrosion of metals.An environmentally friendly hydrothermal method has been developed to synthesize special nanostructured TiO_2 thin films and their dual functions of barrier resistance and photo-generated cathode protection to corrosion of metals have been investigated.The results have been discussed in terms of the structure of TiO_2 film and its performance of photogenerated cathode protection.The emphases have been made to efficiently last the life of electron-hole pairs in nano TiO_2 composite films by doping and coupling to another semiconductor,and enhance the photogenerated cathode protection for metals in dark.The mechanism of nano TiO_2 composite films for photogenerated cathode protection has been further examined as well.The main results and progresses of this work are outlined as following:
1.A sol-gel and dip-coating technique has been developed to prepare nano TiO_2 films modified with anions of nitrogen,sulfur and chlorine supplied on the surface of 316L stainless steel,respectively.When modified with the different anions,the surface morphology,structure and the degree of crystallization of TiO_2 films are remarkably different.The N-modified TiO_2 nano-coatings show higher photocurrent under the same measurement conditions.
2.N-modified TiO_2 nano-films are able to act as an optimal barrier layer to metallic substrates in 0.5 M NaCl solution.And N-modified TiO_2 nano-films provide a distinctly photogenerated cathode protection for 316L SS under the white light illumination.When the illumination is stopped,the N-modified TiO_2 nano-films still exhibit a protective barrier layer for metals,showing a dual function in corrosion protection of metals.
3.A sol-gel technique is used to prepare CeO_2 doped by B element,which is found to exist in the interstitial space of CeO_2 crystal lattice by forming B-Ce-O bond. Bilayer coatings consisting of a B-doped CeO_2 inner layer and a TiO_2 outer layer are made on 316L SS substrate(316L SS｜B-CeO_2｜TiO_2) by coupling.Based on the photoelectrochemical measurements,the TiO_2｜B-CeO_2 films provide a distinctly photogenerated cathode protection for 316L SS under the white light illumination,and sustain the photoeffect for nearly 7 hours when the illumination is stopped,indicating that TiO_2｜B-CeO_2 films are able to continue photogenerated cathode protection for a long period of time in dark.On the other hand,the TiO_2｜B-CeO_2 films still exhibit a good barrier layer for metals, both protective performances of TiO_2｜B-CeO_2 films can offer better protection for metals in a corrosive environment.
4.A simple,low-cost and environmentally friendly hydrothermal method followed by a facile post-treatment has been developed to prepare anatase TiO_2 thin film on the Ti substrate.The morphology and thickness of the as-attained TiO_2 film can be successfully controlled by varying the hydrothermal reaction temperature and time.The TiO_2 films with different surface morphology or thickness show different photocurrent maximum.When the thickness of TiO_2 films is comparable,the net-like structured TiO_2 film obtained with a low-temperature hydrothermal process and the TiO_2 nanotube(TN) array film prepared by electrochemical anodization both offer a distinctly photogenerated cathode protection for 316L SS under the white light illumination.
5.A low-temperature hydrothermal method has been developed to prepare TiO_2 thin films with certain crystallization.Different from the common method, namely,calcination at 450℃for 2h,it is facile for a hydrothermal method to attain anatase TiO_2 with high crystallization at a low temperature of 170℃.The surface morphology and the degree of crystallization of the as-attained TiO_2 film can be successfully controlled by varying the temperature and time of hydrothermal reaction.Compared with TiO_2 film derived by calcined at 450℃for 2h,the TiO_2 film derived by hydrothermal reaction at 170℃for 4h exhibits better barrier resistance to corrosion in simulated seawater.
引文
[1]樊美宫等,光化学基本原理与光子学材料科学[M],北京:科学出版社,2001.
[2]张立德,牟季美,纳米材料和纳米结构[M],北京:科学出版社,2001.
[3]刘守新,刘鸿,光催化及光电催化基础与应用[M],北京:化学工业出版社.
[4]M.L.Sterigerwald,et al.,Synthesis,stanilization and electronic structure of quantum semiconductor nanoclusters[J],Annv.Rev.Mater.Sci,1989,19:471.
[5]Y.Wang,et al.,Linear and nonlinear optical properties of semiconductor clusters[J],J.Opt.Soc.Am.B,1989,6:808.
[6]R.Rosseti,et al.,Size effects in the excited electronic states of small colloidal CdS crystallities[J],J.Chem.Phys,1983,80(9):4464.
[7]Y.Wang,et al.,Nanometer-sized semiconductor clusters:Materials synthesis,quantum size effects and photophysical properties[J],J.Phys.Chem,1991,95:525.
[8]M.Anpo,et al.,Photocatalytic hydrogenation of CH_3CCH with H_2O on small-particle TiO_2:Size quantization efficts and reaction intermediates[J],J.Phys.Chem,1987,91:4305.
[9]Nakajima,K.Hashimoto,T.Watanabe,et al.,Transparent superhydrophobic thin films with self-cleaning properties[J],Langmuir,2000,16:7044.
[10]M.Miyauchi,A.Nakajima,Watanabe,et al.,Photocatalysis and photoinduced hydrophilicity of Vaious metal oxide thin films[J],Chem.Mater.,2002,14:2812.
[11]张肇富,新型太阳能电池问世[J],能源技术,1999,4:57.
[12]高濂,郑珊,张青红著,纳米氧化钛光催化材料及应用[M],北京:化学工业出版社,2002.
[13]张红平,有序纳米结构导电聚合物膜和半导体微粒膜的电化学组装及表征[D],2000.
[14]黄怀国,导电聚合物-纳米半导体微粒复合膜的制备和性能研究[D],2001.
[15]胡春,王怡中,汤鸿霄,多相光催化氧化的理论与实践发展[J],环境科学与发展,1995,3(1):55.
[16]B.O'Regan,J.Moser,M.Gratzel et al.,Vectorial electron injectionin to transparent semiconductor membrane and electricfield effects on the dynamic so flight induced charged separation[J],J Phys.Chem.,1990,94(24):8720.
[17]B.O'Regan,M.Gratzel.A low-cost,high-efficiency solar cell based on dyesesitized colloidal TiO_2 film[J],Nature,1991,353(24):737.
[18]Fujishima,K.Hashimoto,Electrochemical photolysis of water at a semicondouctor electrode,Nature[J],1972,238:37.
[19]胡智学,戴松元,王孔嘉等,染料在纳米TiO_2薄膜表面吸附性能的研究[J],化学研究 与应用,2002,14(3):277.
[20]秦东元,王晶晶,邹英华等,TiO_2的联吡啶-钌化合物敏化及电子转移过程[J],物理化学学报,1998,14(6):520.
[21]L.Bahadur,P.Srivastava,Improved performance of 2-imidazolin-5-one as sensitizer at nanocrystalline ZnO thin film electrode in acetonitrile solution[J],Semicond.Sci.Tech.,2004,19(3):531.
[22]贺北平,王占生,张锡辉,半导体光催化有机物的研究现状及发展趋势[J],环境科学,1993,15(3):80.
[23]王海,陈德文,王素华等,二氧化钛胶体界面芳香化学物的光催化分解[J],化学物理学报,1995,8(4):146.
[24]K.Nagaveni,G.Sivalingam,M.S.Hedge,et al.,Solar photocatalytic degradation of dyes:high activity of combustion synthesized nano TiO_2[J],Appl.Catai.B-Environ.,2004,48(2):83.
[25]Ilisz,A.Dombi,K.Mogyorosi,et al.,Photoeatalytie water treatment with different TiO_2nanoparticles and hydrophilic/hydrophobic layer silicate adsorbents[J],Collid Surface A,2003,230(1-3):89.
[26]M.C.Barnes,A.R.Gerson,S.Kumar,et al.,The mechanism of TiO_2 deposition by direct current magnetron reactive sputtering[J],Thin Solid Films,2004,446(1):29.
[27]S.Malato,J.Blanco,A.Vidal,et al.,Applied studies in solar photoeatalytic detoxification:an overview[J],Sol.Energy,2003,75(4):329.
[28]K.Teramura,T.Tanaka,M.Kani,et al.,Selective photo-oxidation of neat cyclohexane in the liquid phase over V_2O_5/Al_2O_3[J],J Mol.Catal.A-Chem.,2004,208(1-2):299.
[29]D.S.Ren,X.L.Cui,J.Shen,et al.,Study on the superhydrophilicity of the SiO_2-TiO_2 thin films prepared by sol-gel method at room temperature[J],J Sol-Gel Sci.Tech.,2004,29(3):131.
[30]T.L.Sun,G.J.Wang,L.Feng,et al.,Reversible switching between superhydrophilicity and superhydrophobicity[J],Angew Chem.Int.Edit.,2004,43(3):357.
[31]R.J.Zeng,Q.Pang,Z.H.Lin,et al.,Effects of y3+ dopant on the photoinduced superhydrophilicity of thin nanostructured titania films and its mechanism[J],Chin.J.Inorg.Chem.,2003,19(7):678.
[32]曾人杰,林仲华,方智敏,光诱导纳米二氧化钛超亲水薄膜SPM图像分析和氧空位浓度理论探讨[J],电化学,2001,7(4):413.
[33]R.Wang,K.Hashimoto,A.Fujishima,et al.,Photogeneration of highly amphiphilic TiO_2surfaces[J],Adv.Maters.,1998,10(2):135.
[34]R.Wang,K.Hashimoto,A.Fujishima,et al.,Light induced amphiphilic surfaces[J],Nature,1997,388:431.
[35]王洪梅,赵中一,陈莉莉,二氧化钛亲水性技术现状[J],环境科学动态,2003,2:36.
[36]K.Katsumata,A.Nakajima,H.Yoshikawa,T.Shiota,N.Yoshida,T.Watanabe,Y.Kameshima,K.Okada,Effect of microstructure on photoinduced hydrophilicity of transparent anatase thin films[J],Surf.Sci.,2005,579(2-3):123.
[37]N.Sakai,R.Wang,A.Fujishima,T.Watanabe,K.Hashimoto,Effect of ultrasonic treatment on highly hydrophilic TiO2 surfaces[J],Langmuir,1998,14(20):5918.
[38]M.Miyauchi,A.Nakajima,T.Watanabe,K.Hashimoto,Photocatalysis and photoinduced hydrophilicity of various metal oxide thin films[J],Chem.Mater.,2002,14(6):2812.
[39]何宇亮,纳米半导体器件与纳米电子学[J],半导体杂志,1994,19(4):9.
[40]薛增泉,纳米电子器件[J],真空科学与技术,1998,18(6):395.
[41]S.M.Goodnick,J.Bird,Quantum-effect and single-electron devices[J],Ieee Transaction on Nanotechnology,2003,2(4):368.
[42]M.Porti,X.Blasco,M.Nafria,et al.,Electrical characterization and fabrication of SiO_2based metal-oxide-semiconductor nanoelectronic devices with atomic force microscopy[J],Nanotechnology,2003,14(6):584.
[43]林明,范以宁,刘浏,许波连,胡征,陈懿,高能机械球磨法制备V_2P_5-TiO_2超细微粒催化剂[J],催化学报,2001,22:585.
[44]高镰,郑珊,张青红,纳米氧化钛光催化材料及应用[M],北京:化学工业出版社,2002.
[45]杨合,薛向欣,赵娜,左良,半导体多相光催化研究进展及应用技术[J],材料与冶金学报,2003,2:16.
[46]杨海堃,气相氢氧焰水解法生产超微细二氧化钛[J],中国粉体技术,2000,2:30.
[47]M.Keshmiri,M.Mohseni,T.Troczynski,Development of novel TiO_2 sol-gel-derived composite and its photocatalytic activities for trichloroethylene oxidation[J],Appl.Catal.B-Environ.,2004,53:209.
[48]C.Su,B.Y.Hong,C.M.Tseng,Sol-gel preparation and photocatalysis of titanium dioxide [J],Catal.Today,2004,96:119.
[49]刘双怀,周根陶,许菱,彭定坤,单分散二氧化钛超微粒子的制备[J],应用化学,1994,11:36.
[50]高濂,陈锦元,黄军华.严东生,醇盐水解法制备二氧化钛纳米粉体[J],无机材料学报,1995,10:423.
[51]S.C.Pillai,P.Periyat,R.George,D.E.McCormack,M.K.Seery,H.Hayden,J.Colreavy,D.Corr,S.J.Hinder,Synthesis of high-temperature stable anatase TiO2 photocatalyst[J],J.Phys.Chem.C,2007,111:1605.
[52]包南,孙剑,张锋,马志会,刘峰,N掺杂TiO_2纳米晶:水热.热分解法制备及光催化活性[J],无机化学学报,2007,1:101.
[53]丘永梁,陈洪龄,汪效祖,徐南平,水热法制备纳米TiO_2及其等电点的研究[J],高校 化学工程学报,2005,19:129.
[54]牛新书,许亚杰,张学治,刘国光,蒋凯,微乳液法制备纳米二氧化钛及其光催化活性[J],功能材料,2003,34:548.
[55]M.S.Lee,G.D.Lee,C.S.Ju,S.S.Hong,Preparations of nanosized TiO_2 in reverse microemulsion and their photocatalytic activity[J],Sol.Energy Mater.Sol.Cells,2005,88:389.
[56]潘峰,范殿,柳百新,纳米磁性多层膜进展[J],物理,199l,22:9.
[57]李强勇,纳米薄膜研究的进展[J],真空与低温,1994,13(3):162.
[58]柳闽生,詹寿发,谢宝华等,纳米技术及其在环境保护中的应用[J],九江师专学报(自然科学),2002,5:23.
[59]吴振华,离子参数对物理气相沉积薄膜微结构的影响[J],电工电能新技术,1994,4:10.
[60]柳襄怀,杨根庆,王曦等,离子束增强沉积形成梯度薄膜[J],材料研究学报,1994,8(1):61.
[61]柳襄怀,离子束增强沉积薄膜合成及其在材料表面优化中的应用[J],上海有色金属,1994,15(4):65.
[62]Z.Tokei,F.Iacopi,O.Richard,et al.,Barrier studies on porous silk semiconductor dielectric[J],Microelection Eng.,2003,70(2-4):352.
[63]J.M.Correia-Pires,J.B.Almeida,V.Teixeira,Gas-sensitive response of SnO_2 thin-film sensors produced by reactive DC magnetron sputtering[J],Key Eng.Mater.,2002,230:388.
[64]李鹏兴,CVD与PVD硬涂层研究的进展[J],上海金属,1994,15(2):55.
[65]孙一军,夏冠群,张良莹,姚熹,高取向锐钛矿TiO_2薄膜的MOCVD法制备与表征[J],功能材料与器件学报,1998,4:208.
[66]H.Yoshitake,T.Sugihara,T.Tatsumi,Preparation of wormhole-like mesoporous TiO_2 with an extremely large surface area and stabilization of its surface by chemical vapor deposition [J],Chem.Mater.,2002,14:1023.
[67]Q.Fang,M.Meier,J.J.Yu,et al.,FTIR and XPS investigation of Er-doped SiO_2-TiO_2 films [J],Mat.Sci.Eng.B-Sold,2003,105(1-3):209.
[68]B.H.Kim,J.Y.Lee,Y.H.Choa,M.Higuchi,N.Mizutani,Preparation of TiO_2 thin film by liquid sprayed mist CVD method[J],Mat.Sci.Eng.B-Sold.,2004,107:289.
[69]D.H.Kuo,C.N.Shueh,Growth of chemical vapor deposition aluminum titanate films at different CO_2/H_2 and aluminum butoxide inputs[J],J.Vac.Sci.Technol.A,2004,22:151.
[70]V.G.Bessergenev,R.J.F.Pereira,M.C.Mateus,I.V.Khmelinskii,D.A.Vasconcelos,R.Nicula,E.Burkel,A.M.Botelho do Rego,A.I.Saprykin,Study of physical and photocatalytic properties of titanium dioxide thin films prepared from complex precursors by chemical vapour deposition[J],Thin Solid Films,2006,503:29.
[71]林君,庞茂林,韩银花等,溶胶-凝胶工艺制备发光薄膜研究进展[J],无机化学学报,2001,17(2):153.
[72]于向阳,程继健,杜永娟,TiO_2光催化薄膜的制备法[J],玻璃与搪瓷,2001,29:37.
[73]郭建辉,杨建军,李庆霖等,纳米薄膜光催化剂的制备与表面态研究[J],化学研究,2003,14(2):13.
[74]K.Jamting,J.M.Bell,M.V.Swain,L.S.Wielunski,R.Clissold,Measurement of the micro mechanical properties of sol-gel TiO2 films[J],Thin Solid Films,1998,332:189.
[75]T.Watanabe,S.Fukayama,M.Miyauchi,A.Fujishima,K.Hashimoto,Photocatalytic activity and photo-induced wettability conversion of TiO_2 thin film prepared by sol-gel process on a soda-lime glass[J],J.Sol-Gel.Sci.Technol.,2000,19:71.
[76]M.J.Alam,D.C.Cameron,Preparation and characterization of TiO_2 thin films by sol-gel method[J],J.Sol-Gel.Sci.Technol.,2002,25:137.
[77]孙志华,刘明辉,应用电沉积方法制备纳米多层膜的研究现状[J],腐蚀与防护,2002,23:114.
[78]王震林,王太宏,基于阳极氧化法的纳米结构加工和纳米器件的制备[J],微电子技术,2001,29:17.
[79]V.Zwilling,M.Aucouturier,E.Darque-Ceretti,Anodie oxidation of titanium and TA6V alloy in chromic media,an electrochemical approach[J],Electrochim.Acta,1999,45:921.
[80]刘惠玲,周定,李湘中,余秉涛,网状Ti/TiO_2电极光电催化氧化若丹B[J],环境科学,2002.23:47.
[81]D.Gong,C.A.Grimes,O.K.Varghese,W.Hu,R.S.Singh,Z.Chen,E.C.Dickey,Titanium oxide nanotube arrays prepared by anodic oxidation[J],J.Mater.Res.,2001,16:3331.
[82]J.M.Macak,H.Tsuchiya,P.Schmuki,High-aspect-ratio TiO_2 nanotubes by anodization of titanium[J],Angew.Chem.Int.Ed.,2005,44:2100.
[83]邱建斌,曹亚安,马颖,管自生,姚建年,担载材料对TiO_2薄膜光催化性的影响[J],物理化学学报,2000,16:1.
[84]M.Dolata,P.Kedzierzawki,J.Augustynski,Comparative impedance spectroscopy study of rutile and anatase TiO_2 film electrodes[J],Electrochim.Acta,1996,41:1287.
[85]冷文华,张昭,成少安,张鉴清,曹楚南,直接热氧化制备氧化钛薄膜电极的研究Ⅰ:制备、结构和电化学性质[J],化学物理学报,2001,14:705.
[86]Y.V.Kolen'ko,V.D.Maximov,A.V.Garshev,et al.,Hydrothermal synthesis of nanocrystalline and mesoporous titania from aqueous complex titanyl oxalate acid solutions [J],Chem.Phys.Lett.,2004,388(4-6):411.
[87]Z.Y.Yuan,X.B.Zhang,B.L.Su,Moderate hydrothermal synthesis of potassium titanate nanowires[J],Appl.Phys.A-Mater.,2004,78(7):1063.
[88]S.Uchida,R.Chiba,M.Tomiha,et al.,Application of titania nanotubes to a dye-sensitized solar cell[J],Electrochemistry,2002,70(6):418.
[89]H.Nagayama,H.Honda,H.Kawahara,J.Electrochem Soc.,1988,135(8):2013.
[90]周磊,刘昌,赵文宽,胡翎,方佑龄,液相沉积法制备光催化活性掺铁TiO_2薄膜[J],催化学报,2003,24:359.
[91]王晓平,于云,高濂,胡行方,TiO_2薄膜的液相沉积法制备及其性能表征[J],无机材料学报,2000,15:573.
[92]H.Yu,S.C.Lee,J.Yu,C.H.Ao,Photocatalytic activity of dispersed TiO_2 particles deposited on glass fibers[J],J.Mol.Catal.A-Chem.,2006,246:206.
[93]T.H.Kim,B.H.Sohn,Photocatalytic thin films containing TiO_2 nanoparticles by the layer-by-layer self-assembling method[J],Appl.Surf.Sci.,2002,201:109.
[94]J.Jin,L.S.Li,Y.Li,X.Chen,L.Jiang,Y.Y.Zhao,T.J.Li,Preparation of titanium dioxide and barium titanate nanothick film by Langmuir-Blodgett technique[J],Thin Solid Films,2000,379:218.
[95]郝维昌,潘锋,王天民,郑树凯,TiO_2/PSS自组装薄膜的光催化性能[J],稀有金属材料与工程,2004,33:63.
[96]Sopyan,M.Watanabe,S.Murasawa,K.Hashimoto,A.Fujishima,A film-type photocatalyst incorporating highly active TiO_2 power and fluororesin binder:photocatalytic activity and long-term stability[J],J.Electroanal.Chem.,1996,415:183.
[97]吴光佑著,阴极保护的原理和应用[M],机械工业出版社,北京,1965.
[98]S.R.Morrison,Electrochemistry at Semiconductor and Oxided Metal Electrodes,Plenum,New York,1980,p 49.
[99]P.M.Natishan,E.McCafferty,G.K.Hubler,Surface change condersions in the pitting of ion- implanted aluminum[J],J.Electrochem.Soc.,1988,135:321.
[100]N.Sato,Boshoku Gijutsu,1990,39:495.
[101]K.Sugimoto,Tetsu To Hagne,1991,77:258.
[102]Y.Hayashi,M.Masuda,J.Lee,et al.,Study on corrosion properties of sputter coating of oxides on the stainless steel[J],Mater.Sci.Eng.A,1995,198:71.
[103]J.Masalski,J.Gluszek,J.Zabrzeski,K.Nitsch,P.Gluszek,Improvement in corrosion resistance of the 316L stainless steel by means of Al_2O_3 coatings deposited by the sol-gel method[J],Thin solid films,1999,349(1-2):186.
[104]R.J.Solar,Corrosion resistance of titanium surgical implant alloys:A Review[A].In:Syreet B C,Acharya A,eds.Corrosion and degradation of implant materials,ASTM STP684[C],Philadelphia.
[105]G.X.Shen,Y.C.Chen,L.Lin,C.J.Lin,D.Scantlebury,Study on a hydrophobic nano-TiO_2 coating and its properties for corrosion protection of metals[J],Electrochim.Acta,2005,50:5083.
[106]W.Brandle,C.Gendig,corrosion behaviour of hybrid coatings[J],thin solid films,1996, 290-291:343.
[107]Z.L.Tang,E H.Wang,W.T.Wu,Effect of Al_2O_3 and enamel coatings on 900℃ oxidation and hot corrosion behaviors of gamma-TiAl[J],Mater.Sci.Eng.A,2000,276:70.
[108]E.Szalkowska,J.Gluszek,J.Masalski,et al.,Structure and protective properties of TiO_2coatings obtained using the sol-gel technique[J],J Mater.Sci.Lett.,2001,20(6):495.
[109]J.Gluszek,J.Masalski,P.Furman,et al.,Structural and electrochemical examinations of PACVD TiO_2 films in ringer solution[J],Biomater.,1997,18:789.
[110]肖正伟,曾振欧,赵国鹏,田志斌,纳米TiO_2涂层的制备及其在金属腐蚀防护中的应用[J],腐蚀与防护,2007,28:33.
[111]Y.Ohko,S.Saitoh,T.Tatsuma,A.Fujishima,Photoelectrochemical Anticorrosion and Self-Cleaning Effects of a TiO_2 Coating for Type 304 Stainless Steel[J],J Electrochem.Soc.,2001,148:B24.
[112]徐群杰,齐航,丁斯婧,李春香,周小晶,光电化学技术在金属腐蚀研究中应用新进展[J],上海电力学院学报,2008,24(1):73.
[113]H.Park,K.Y.Kim,W.Choi,A novel photoelectrochemical method of metal corrosion prevention using a TiO2 solar panel[J],Chem.Comm.,2001,281.
[114]W.Choi,A.Termin,M.R.Hoffmann,Effects of metal-ion dopants on the photoeatalytic reactivity of quantum-sized TiO_2 particles[J],Angew.Chem.-Int.Edit.,1994,33:1091.
[115]籍宏伟,马万红,黄应平,赵进才,王正平,可见光诱导TiO_2光催化的研究进展[J],科学通报,2003,48:2199.
[116]廖学红,王小佳,Bi_2O_3/TiO_2纳米复合物的微波合成及光催化性质[J],纳米材料与结构,2008,45(4):209.
[117]Y.Suda,H.Kawasaki,T.Ueda,T.Ohshima,Preparation of nitrogen-doped titanium oxide thin film using a PLD method as parameters of target material and nitrogen concentration ratio in nitrogen/oxygen gas mixture[J],Thin Solid Films.,2005,475:337.
[118]H.Irie,S.Washizuka,Y.Watanabe,T.Kako and K.Hashimoto,Photoinduced hydrophilic and electrochemical properties of nitrogen-doped TiO_2 films[J],J.Electrochem.Sot.,2005,152:E351.
[119]S.Sato,R.Nakamura,S.Abe,Visible-light sensitization of TiO_2 photocatalysts by wet-method N doping[J],Appl.Catal.A-Gen.,2005,284:131.
[120]R.Asahi,T.Morikawa,T.Ohwaki,K.Aoki,Y.Taga,Visible-light photocatalysis in nitrogen-doped titanium oxides[J],Science,2001,293:269.
[121]S.Yin,H.Yamaki,Q.Zhang,M.Komatsu,J.Wang,Q.Tang,F.Saito,T.Sato,Mechanochemical synthesis of nitrogen-doped titania and its visible light induced NOx destruction ability[J],Solid State Ion,2004,172:205.
[122]庄惠芳,赖跃坤,李静,孙岚,林昌健,氮掺杂TiO_2纳米管阵列的制备及其可见光光电催化活性研究[J],电化学,2007,13:284.
[123]K.Shankar,K.C.Tep,G K.Mor,C.A.Grimes,An electrochemical strategy to incorporate nitrogen in nanostructured TiO_2 thin films:modification of bandgap and photoelectrochemical properties[J],J.Phys.D-Appl.Phys.,2006,39(11):2361.
[124]H.Irie,Y.Watanabe,K.Hashimoto,Carbon-doped anatase TiO_2 powders as a visible-light sensitive photocatalyst[J],Chem.Lett.,2003,32:772.
[125]C.H.Ao,S.C.Lee,Combination effect of activated carbon with TiO_2 for the photodegradation of binary pollutants at typical indoor air level[J],J.Photochem.Photobio.A-Chem.,2004,161:131.
[126]S.U.M.Khan,M.AI-Shahry,W.B.Ingler Jr.,Efficient photochemical water splitting by a chemically modified n-TiO_2[J],Science,2002,297:2243.
[127]T.Ohno,T.Mitsui,M.Matsumura,Photocatalytic activity of S-doped TiO_2 photocatalyst under visible light[J],Chem.Lett.,2003,32:364.
[128]T.Umebayashi,T.Yamaki,S.Tanaka,K.Asai,Visible light-induced degradation of methylene blue on S-doped TiO_2[J],Chem.Lett.,2003,32:330.
[129]T.Yamaki,T.Umebayashi,T.Sumita,S.Yamanoto,M.Maekawa,A.Kawasuso,H.Itoh,Fluorine-doping in titanium dioxide by ion implantation technique[J],Nucl.Instrum.Methods Phys.Res.B-Beam Interact.Mater.Atoms,2003,206:254.
[130]J.C.Yu,Ji.Yu,W.Ho,Z.Jiang,L.Zhang,Effects ofF-doping on the photocatalytic activity and microstructures of nanocrystalline TiO_2 powders[J],Chem.Mater.,2002,14:3808.
[131]H.M.Lu,T.Takata,Y.Lee,Photocatalytic activity enhancing for titanium dioxide by co-doping with bromine and chlorine[J],Chem.Mater.,2004,16:846.
[132]H.Y.Liu,L.Gao,Codoped futile TiO_2 as a new photocatalyst for visible light irradation[J],Chem.Lett.,2004,33:730.
[133]冯光建,刘素文,修志亮,俞娇仙,罗杰,氮离子和稀土离子共掺杂纳米TiO_2光催化性能的研究[J],中国稀土学报,2008,26(2):148.
[134]D.G.Huang,S.J.Liao,J.M.Liu,et al.,Preparation of visible light responsive N-F codoped TiO_2 photocatalyst by a sol-gel solvothermal method[J],J.Photochem.Photobio.A-Chem.,2006,184:282.
[135]C.C.Pan,J.C.S.Wu,Visible-light response Cr~(2+) doped TiO_(2-x)N_x photocatalyst[J],Mater.Chem.Phys.,2006,100(1):102.
[136]胡红坡,赵宏生,郭子斌,氮掺杂TiO_2光催化剂研究进展[J],材料导报,2008,22(2):39.
[137]T.Wu,G,Liu,J.Zhao,H,Hidaka,N.Serpone,Photoassisted degradation of dye pollutants V.self-photosensitized oxidative transformation of rhodamine B under visible light irradiation in aqueous TiO_2 dispersions[J],J.Phys.Chem.B,102:5845.
[138]S.S.Kim,J.H.Yum,Y.E.Sung,Improved performance of a dye-sensitized solar cell using a TiO_2/ZnO/Eosin Y electrode[J],Sol.Energy Mater.Sol.Cells,2003,79:495.
[139]Y.Amao,Y.Yamada,K.Aoki,Preparation and properties of dye-sensitized solar cell using chlorophyll derivative immobilized TiO_2 film electrode[J],J.Photochem.Photobio.A:Chem.,2004,164:47.
[140]R.Dillert,A.E.Cassano,R.Goslich,D.Bahnemann,Large scale studies in solar catalytic wastewater treatment[J],Catal.Today,1999,54:267.
[141]李明,方亚男,洪樟连,陈胡星,表面敏化改性纳米晶TiO_2的光谱响应特性研究及其应用进展[J],材料导报,2007,21:15.
[142]H.Kusama,H.Orita,H.Sugihara,DFT investigation of the band shift by nitrogen-containing heterocycle adsorption and implication on dye-sensitized solar cell performance[J],Sol.Energy Mater.Sol.Cells,2008,92:84.
[143]H.E.Chao,Y.U.Yun,H.U.Xingfang,A.Larbot,Effect of silver doping on the phase transformation and grain growth of sol-gel titania powder[J],J.European Ceram.Sot.,2003,23:1457.
[144]T.Lopez,R.Gomez,G.Pecci,P.Reyes,X.Bokhimi,O.Novaro,Effect of pH on the incorporation of platinum into the lattice of sol-gel titania phases[J],Mater.Lett.,1999,40:59.
[145]S.Rengaraj,X.Z.Li,Enhanced photoeatalytic activity of TiO_2 by doping with Ag for degradation of 2,4,6-trichlorophenol in aqueous suspension[J],J.Mol.Catal.A-Chem.,2006,243:60.
[146]J.Yu,J.Xiong,B.Cheng,S.Liu,Fabrication and characterization of Ag-TiO_2 multiphase nanocomposite thin films with enhanced photocatalytic activity[J],Appl.Catal.B-Environ.,2005,60:211.
[147]刘守新,曲振平,韩秀文,孙承林,包信和,Ag担载对TiO_2光催化活性的影响[J],催化学报,2004,25:133.
[148]C.M.Wang,A.Heller,H.Gerischer,Palladium catalysis of O_2 reduction by elections accumulated on TiO_2 particles during photoassisted oxidation of organic compounds[J],J.Am.Chem.Soc.,1992,114:5230.
[149]F.B.Li,X.Z.Li,The enhancement of photodegradation efficiency using Pt-TiO_2 catalyst [J],Chemosphere,2002,48:1103.
[150]史月萍,杨祝红,冯新,郑仲,陆小华,掺铂二氧化钛纤维光催化降解氯仿的研究[J],催化学报,2003,24:663.
[151]Berko,T.Biro,F.Solymosi,Formation and migration of carbon produced in the dissociation of CO on Rh/TiO_2(110)-(1×2) model catalyst:a scanning tunneling microscopy study[J],J.Phys.Chem.B,2000,104:2506.
[152]J.M.Macak,P.J.Barczuk,H.Tsuchiya,M.Z.Nowakowska,A.Ghicov,M.Chojak,S.Bauer,S.Virtanen,P.J.Kulesza,P.Schmuki,Self-organized nanotubular TiO_2 matrix as support for dispersed Pt/Ru nanoparticles:Enhancement of the electrocatalytic oxidation of methanol[J],Electrochem.Commun.,2005,7:1417.
[153]姚平平,甘玉琴,徐景坤,杨平,杜玉扣,银纳米颗粒负载复合膜的光催化活性及其光 电流性质[J],感光科学与光化学,2006,24(1):44.
[154]张彭义,余刚,蒋展鹏,半导体光催化剂及其改性技术进展[J],环境科学进展,1997,5(3):1.
[155]S.J.Liao,D.G Huang,D.H.Yu,Y.L.Su,G.Q.Yuan,Preparation characterization of ZnO/TiO_2,SO4~(2-)/ZnO/TiO_2 photocatalyst and their photocatalysis[J],J.Photochem.Photobiol.A-Chem.,2004,168:7.
[156]S.W.Ding,L.Y.Wang,S.Y.Zhang,Q.X.Zhou,Y.Ding,S.J.Liu,Y.C.Liu,Q.Y.Kang,Hydrothermal synthesis,structure and photocatalytic property of nano-TiO_2-MnO_2[J],Sci.China Set.B-Chem.,2003,46:542.
[157]E.Celik,A.Y.Yildiz,N.F.A.Azem,M.Tanoglu,M.Toparli,O.F.Emrullahoglu,I.Ozdemir,Preparation and characterization of Fe_2OP_3-TiO_2 thin films on glass substrate for photocatalytic applications[J],Mater.Sci.Eng.B-Solid State Mater.Adv.Technol.,2006,129:193.
[158]Y.Bcssekhouad,D.Robert,J.V.Weber,Bi_2S_3/TiO_2 and CdS/TiO_2 hctcrojunctions as an available configuration for photocatalytic degradation of organic pollutant[J],J.Photochem.Photobio.A- Chem.,2004,163:569.
[159]李芳柏,古国榜,李新军,万洪富,WO_3-TiO_2纳米材料的制备及光催化性能[J],物理化学学报,2000,16:997.
[160]T.Tatsuma,S.Satioh,P.Ngaotrakanwiwat,et al.,Energy storage of TiO_2-WO_3photocatalysis systems in the gas phase[J],Langmuir,2002,18:7777.
[161]T.Tatsuma,S.Satioh,Y.Ohko,et al.,TiO_2-WO_3 photoclcctrochcmical anticorrosion system with an energy storage ability[J],Chem.Mater.,2001,13:2838.
[162]Z.Y.Liu,K.Pan,M.J.Wang,et al.,Influence of the mixed ratio on the photocurrcnt of the TiO_2/SnO_2 composite photoelectrodes sensitized by mcrcurochrome[J],J.Photochem.Photobio.A:Chem.,2003,157:39.
[163]施利毅,古宏晨,李春忠,房鼎业,张怡,华彬,SnO_2-TiO_2复合光催化剂的制备和性能[J],催化学报,1999,20:338.
[164]R.Subasri,S.Deshpande,S.Seal,T.Shinohara,Evaluation of the Performance of TiO_2-CeO_2 Bilayer Coatings as Photoanodes for Corrosion Protection of Copper[J],Electrochem.Solid-State Lett.,2006,9(1):B1.
[165]张天永,朱丹丹,付强,赵进才,纳米光催化氧化降解染料污染物的进展[J],染料与染色,2004,41:238.
[166]T.Jin,T.Yamaguchi,K.Tanabe,Mechanism of acidity generation on sulfur-promoted metal oxides[J],J.Phys.Chem.1986,90:4794.
[167]杜金菊,徐安武,祝静艳,固体超强酸SO_4~(2-)/TiO_2制备及其光催化氧化性能[J],中山大学学报,2001,40:48.
[168]S.Yamazaki,S.Matsunaga,K.Hori,Photocatalytic degradation of trichloroethylene in water using TiO_2 pellets[J],Water Res.,2001,35:1022.
[169]查振林,罗亚田,纳米TiO_2的改性及应用研究[J],北方环境,2004,29:30.
[170]X.Li,C.Chen,J.Zhao,Mechanism of photodecomposition of H_2O_2 on TiO_2 surface under visible light irradiation[J],Langmuir,2001,17:4118.
[1]M.Koelsch,S.Cassaignon,J.F.Guillemoles,et al.,Comparison of optical and electrochemical properties of anatase and brookite TiO synthesized by the sol-gel method [J],Thin Solid Films,2002,403-404:312.
[2]J.X.Qiu,M.Y.Gu,Magnetic nanocomposite thin films of BaFe_(12)O_(19) and TiO_2 prepared by sol-gel method[J],Appl.Surf.Sci.,2005,252(4):888.
[3]T.Kasuga,M.Hiramatsu,A.Hoson,T.Sekino,K.Niihara,Formation of Titanium Oxide Nanotube[J],Langmuir,1998,14:3160.
[4]Q.Chen,W.Z.Zhou,G.H.Du,et al.,Trititanate nanotubes made via a single alkali treatment[J],Adv.Maters.,2002,14(17):1208.
[5]Y.F.Chen,C.Y.Lee,M.Y.Yeng,et al.,Preparing titanium oxide with various morphologies[J],2003,81(1):39.
[6]Sieber,B.Kannan,P.Schmuki,Self-assembled porous tantalum oxide prepared in H_2SO_4/HF electrolytes[J],Electrochem.Solid-State Lett.,2005,8:J10.
[7]H.Tsuchiya,J.M.Macak,I.Sieber,L.Taveira,A.Ghicov,K.Sirotna,P.Schmuki,Self-organized porous WO3 formed in NaF electrolytes[J],Electrochem.Commun.,2005,7:295.
[8]H.Tsuchiya,P.Schmuki,Thick self-organized porous zirconium oxide formed in H_2SO_4/NH_4F electrolytes[J],Eleetrochem.Commun.2004,6:1131.
[9]H.Tsuchiya and P.Schmuki,Self-organized high aspect ratio porous hafnium oxide prepared by electrochemical anodization[J],Electrochem.Commun.,2005,7:49.
[10]J.M.Macak,H.Tsuchiya,P.Schmuki,High-aspect-ratio TiO_2 nanotubes by anodization of titanium[J],Angewandte Chemie-Intemational Edition 2005,44(14):2100.
[11]D Birggs著,桂琳琳,黄惠忠,郭国霖译,X射线与紫外光电子能谱[M],北京:北京大学出版社,1984.
[12]陈体衔,实验电化学[M],科学出版社,北京,1995.
[13]M.Stem,A.L.Greary,Electrochemical polarization I.Atheoretical analysis of the shape of polarization curves[J],J.Electrochem.Sco.,1957,104:56.
[14]史美伦,交流阻抗谱原理及应用[M],国防工业出版社,北京,2001.
[15]曹楚南,张鉴清,电化学阻抗谱导论[M],科学出版社,北京,2002.
[16]H.Park,K.Y.Kim,W.Choi,A novel photoelectrochemical method of metal corrosion prevention using a TiO_2 solar panel[J],Chem.Comm.,2001,3:281.
[17]H.Park,K.Y.Kim,W.Choi,Photoelectrochemical approach for metal corrosion pretection using a semiconductor photoanode[J],J Phys.Chem.B,2002,106:4775.
[18]P.Schmuki,From Bacon to barriers:a review on the passivity of metals and alloys[J],J.Solid State Chem.,2002,6(3):145.
[19]G.Goodlet,S.Faty,S.Cardoso,P.P.Freitas,A.M.P.Simoes,M.G.S.Ferreira,M.D.Belo,The electronic properties of sputtered chromium and iron oxide films[J],Corro.Sci.,2004,46(6):1479.
[20]钱新明,宋庆,白玉白等,CdS敏化对TiO_2纳米薄膜电极光生电荷转移特性的影响[J],高等学校化学学报,2000,21(2):295.
[21]L.A.Lyon,J.T.Hupp,Energetics of the nanocrystalline titanium dioxide aqueous solution interface:Approximate conduction band edge variations between H-0=-10 and H-=+26[J],J.Phys.Chem.B,1999,103(22):4623.
[22]Z.H.Zhang,Y.Yuan,Y.J.Fang,L.H.Liang,H.C.Ding,G.Y.Shi,L.T.Jin,Photoelectrochemical oxidation behavior of methanol on highly ordered TiO_2 nanotube array electrodes[J],Journal of Electroanalytical Chemistry,2007,610(2):179.
[1]T.L.Metroke,L.Robert,et al.,Passivation of metal alloy using sol-gel-derived materials a review[J],Prog.Org.Coat.,2001,41:233.
[2]刘娅莉,于占锋,周树学,武利民,自组装单分子膜技术在金属防护中的应用[J],涂料工业,2004,34(9):27.
[3]L.S.Kasten,J.T.Grant,N.Grebasch,N.Voevodin,F.E.Amold,M.S.Donley,An XPS study of cerium dopants in sol - gel coatings for aluminum 2024-T3[J],Surf.Coat.Technol,2001,140(1):11.
[4]S.Hamdy,D.P.Butt,Environmentally compliant silica conversion coatings prepared by sol-gel method for aluminum alloys[J],Surf.Coat.Technol,2006,201(1-2):401
[5]F.J.Jing,F.Y.Jin,Y.W.Liu,et al.,Corrosion resistance and antithrombogenic behavior of La and Nd ion implanted stainless steels[J],J.Vac.Sci.Technol.,2006,24(5):1790.
[6]X.Q.Hu,C.H.Liang,N.B.Huang,Anticorrosion performance of carbon steel in 55%LiBr solution containing PMA/SbBr3 inhibitor[J],J.Iron Steel.Res.Int.,2006,13(4):56.
[7]C.S.Lin,C.S.Ke,H.Peng,Corrosion of CrN and CrN/TiN coated heat-resistant steels in molten A356 aluminum alloy[J],Surf.Coat.Technol.,2001,164:168.
[8]Y.Choi,N.I.Baik,J.S.Lee,et al.,Corrosion and wear properties of TiC/Ni-Mo composites produced by direct consolidation during a self-propagating high-temperature reaction[J],Compos.Sci.Technol.,2001,61(7):981.
[9]R.Caruso,F.Pla,A.D.Parralejo,et al.,Multilayer coatings preparation of zirconia-based by sol-gel route;microstructural and mechanical characterization[J],Revista De Metalurgia,2001,37(2):311.
[10]T.Kubota,N.Hara,K.Sugimoto,Real time spectroscopic ellipsometry study on growth processes of ZrO_2 thin films in metallorganic chemical vapor deposition[J],J.Electrochem.Sco.,2001,148(9):C632.
[11]G.X.Shen,Y.C.Chen,C.J.Lin,Corrosion protection of 316 L stainless steel by a TiO_2nanoparticle coating prepared by sol-gel method[J],Thin Solid Films,2005,489:130.
[12]K.Meinert,C.Uerpmann,J.Matschullat,G.K.Wolf,Corrosion and leaching of silver doped ceramic IBAD coatings on SS 316L under simulated physiological conditions[J],Surf.Coat.Technol,1998,103-104:58.
[13]J.Yuan,S.Tsujikawa,Characterization of Sol-Gel-Derived TiO_2 coating and their photoeffects on copper substrates[J],J.Electrochem.Sot.,1995,142:3444.
[14]A.Nakajima,S.Koizumi,T.Watanabe,et al.,Effect of repeated photo-illumination on the wettability conversion of titanium dioxide[J],J.Photochem.Photobiol.A:Chem.,2001,146(1-2):129.
[15]U.Diebold,The surface science of titanium dioxide[J],Surf.Sci.Rep.,2003,48(5-8):53.
[16] J. Huang, T. Shinohara, S. Tsujikawa, Zario-to-kankyo, 1997,46: 651.
[17] M. G. Mahmoud, R. G. Wang, M. Kato, et al., Influence of ultraviolet light irradiation on corrosion behavior of weathering steel with and without TiO_2Vcoating in 3 mass% NaCl solution [J], Scripta Mater., 2005, 53 (11): 1303.
[18] Y. Ohko, S. Saitoh, T. Tatsuma, A. Fujishima, Photoelectrochemical Anticorrosion and Self-Cleaning Effects of a TiO_2 Coating for Type 304 Stainless Steel [J], J Electrochem. Soc, 2001,148: B24.
[19] M. C. Li, S. Z. Luo, P. F. Wu, J. N. Shen, Photocathodic protection effect of TiO_2 films for carbon steel in 3% NaCl solutions [J], Electrochim. Acta, 2005, 50 (16-17): 3401.
[20] R. Subasri, S. Deshpande, S. Seal, T. Shinohara, Evaluation of the Performance of TiO_2-CeO_2 Bilayer Coatings as Photoanodes for Corrosion Protection of Copper [J], Electrochem. Solid-State Lett., 2006,9 (1): B1.
[21] E. Szalkowska, J. Gluszek, J. Masalski, et al., Structure and protective properties of TiO_2 coatings obtained using the sol-gel technique [J], J. Mater. Sci. Lett., 2001,20 (6): 495.
[22] G. X. Shen, Y. C. Chen, L. Lin, C. J. Lin, D. Scantlebury, Study on a hydrophobic nano-TiO_2 coating and its properties for corrosion protection of metals [J], Electrochim. Acta, 2005, 50: 5083.
[23] M. R. Hoffmann, S. T. Martin, W. Choi, D. W. Bahnemann, Environmental Applications of Semiconductor Photocatalysis [J], Chem. Rev., 1995,95: 69.
[24] L. Linsebigler, G. Q. Lu, J. T. Yates, Photocatalysis on TiO_2 Surfaces: Principles, Mechanisms, and Selected Results [J], Chem. Rev., 1995,95: 735.
[25] Y. J. Chen, D. D. Dionysiou, Correlation of structural properties and film thickness to photocatalytic activity of thick TiO_2 films coated on stainless steel [J], Appl. Catal. B: Environ., 2006, 69 (1-2): 24.
[26] H. M. Yates, M. G. Nolan, D. W. Sheel, et al., The role of nitrogen doping on the development of visible light-induced photocatalytic activity in thin TiO_2 films grown on glass by chemical vapour deposition [J], J. Photochem. Photobiol. A: Chem, 2006, 179 (1-2):213.
[27] C. K. Jung, I.-S. Bae, Y.-H. Song, J.-H. Boo, Plasma surface modification of TiO_2 photocatalysts for improvement of catalytic efficiency [J], Surf. Coat. Technol, 2005, 200 (5-6): 1320.
[28] A. Kitiyanan, S. Ngamsinlapasathian, S. Pavasupree, S. Yoshikawa, The preparation and characterization of nanostructured TiO_2-ZrO_2 mixed oxide electrode for efficient dye-sensitized solar cells [J], J. Solid State Chem., 2005, 178 (4): 1044.
[29] K. S. Guan, Relationship between photocatalytic activity, hydrophilicity and self-cleaning effect of TiO_2/SiO_2 films [J], Surf. Coat. Technol, 2005,191 (2-3): 155.
[30] K. R. Wu, J. J. Wang, W. C. Liu, et al., Deposition of graded TiO_2 films featured both hydrophobic and photo-induced hydrophilic properties [J], Appl. Surf. Sci., 2006, 252 (16): 5829.
[31]X.Z.Ding,X.H.Liu,Synthesis and microstructure control of nanocrystalline titania powders via a sol-gel process[J],Mater.Sei.Eng.A,1997,224(1-2):210.
[32]Bertoti,Characterization of nitride coatings by XPS[J],Surf.Coat.Technol.,2002,151:194.
[33]熊兆贤,无机材料研究方法:合成制备、分析表征与性能检测[M],厦门:厦门大学出版社,2001.
[34]M.J.Velasco,F.Rubio,J.Rubio,et al.,DSC and FT-IR analysis of the drying process of titanium alkoxide derived precipitates[J],Thermochim.Acta,1999,326(1-2):91.
[35]S.Doeu,M.Henry,C.Sanehez,J.Livage,J.Non-Cryst.Solids,1987,89:206.
[36]R.Urlaub,U.Posset,R.Thull,FT-IR spectroscopic investigations on sol-gel-derived coatings from acid-modified titanium alkoxides[J],J.Non-Cryst.Solids,2000,265(3):276.
[37]S.K.Samantaray,T.Mishra,K.M.Parida,Studies on anion promoted Titania 2:Preparation,characterisation and catalytic activity towards aromatic alkylation over sulfated titania[J],J.Mol.Catal.A:Chem.,2000,156(1-2):267.
[38]E.Ortiz-Islas,R.Gomez,T.Lopez,et al.,Effect of the crystallite size in the structural and textural properties of sulfated and phosphated titania[J],Appl.Surf.Sci.,2005,252(3):807.
[39]沈俊,罗妮,张明俊,田从学,张昭,介孔TiO_2-SO_4~(2-)的合成及表征[J],催化学报,2007,28(3):264.
[40]尹荔松,陈永平,谭敏,范海陆,硫酸处理对TiO_2薄膜光催化降解亚甲基兰溶液的影响[J],电子器件,2007,30(6):2007.
[4l]戴文新,王绪绪,付贤智,刘平,林华香,卤素离子对TiO_2薄膜光致亲水性的影响[J],物理化学学报,2005,21(11):1274.
[42]R.Asahi,T.Morikawa,T.Ohwaki,K.Aoki,Y.Taga,Visible-light photocatalysis in nitrogen-doped titanium oxides[J],Science,2001,293:269.
[43]J.Q.Li,L.Zheng,L.P.Li,Y.Z.Xian,L.T.Jin,Fabrication of TiO_2/Ti electrode by laser-assisted anodic oxidation and its application on photoelectrocatalytic degradation of methylene blue[J],J.Hazard.Mater.B,2007,39:72.
[44]吕红辉,汤钧,白玉白,钱新明,董绍俊,TiO_2纳米晶薄膜电极的瞬态光电流特性[J],吉林大学自然科学学报,2001,3:99.
[45]吕红辉,文子,刘艳梅,钱新明,汤心颐,白玉白,表面态对TiO_2纳米晶薄膜光电流的影响[J],吉林大学自然科学学报,2001,2:95.
[46]F.Cao,G.Oskam,P.C.Searson,et al.,Electrical and Optical Properties of Porous anocrystalline TiO_2 Film[J],J.Phys.Chem.,1995,99:11974.
[47]S.Sodergren,A.Hagfeldf,J.Dsson,et al.,Theoretical Models for the Action Spectrum and the Current-Voltage Characteristics of Microporous Semiconductor Films in Photoelect rochemical Cells[J],J Phys.Chem,1994,98:5552.
[48]杨大纲,李秋叶,张顺利,金振声,张治军,二氧化钛纳米膜电极的形貌和光电化学性质[J],化学研究,2004,15(4):6.
[49]Y.B.Xie,L.M.Zhou,H.T.Huang,Enhanced photoelectrochemical current response of titania nanotube array[J],Mater.Lett.,2006,60:3558.
[50]姚平平,甘玉琴,徐景坤,杨平,杜玉扣,银纳米颗粒负载复合膜的光催化活性及其光电流性质[J],感光科学与光化学,2006,24(1):44.
[51]李贺,姚素薇,张卫国,王宏智,贲宇恒,二氧化钛纳米管阵列电极的光电化学性能研究[J],稀有金属材料与工程,2007,36(10):1749.
[52]S.U.M.Khan,M.Al-Shahry,W.B.Ingler Jr.,Efficient photochemical water splitting by a chemically modified n-TiO_2[J],Science,2002,297:2243.
[53]T.Zajac,M.Radecka,M.Rekas,Photoelectrochemical properties of Nb-doped titanium dioxide[J],Physica B,2007,399:55.
[54]谢建辉,吴荫顺,朱日彰,316L不锈钢在模拟体液内腐蚀疲劳裂纹萌生和扩展过程中的应力的作用[J],中国腐蚀与防护学报,1997,17(1):31.
[55]梁成浩,牟战旗,模拟体液中3 16L不锈钢和Co-Cr合金生物材料腐蚀行为研究[J],中国生物医学工程学报,2000,19(4):432.
[56]汪轩义,吴荫顺,张琳等,3 16L不锈钢钝化膜在CI介质中的防蚀机制[J],腐蚀科学与防护技术,2000,12(6):311.
[57]B.S.Liu,X.J.Zhao,L.P.Wen,A simple route to the water-repellent surface based on chemical N modified Ti-O structure films[J],Surf.Coat.Technol,2006,201(6):3606.
[58]王宜超,刘中清,燕青芝,李振华,葛昌纯,可见光响应氮掺杂TiO_2光催化剂的水热法制备与性能[J],北京科技大学学报,2008,30(5):540.
[59]C.Xie,Q.J.Yang,Z.L.Xu,X.J.Liu,Y.G.Du,New Route to Synthesize Highly Active Nanocrystalline Sulfated Titania-Silica:Synergetic Effects between Sulfate Species and Silica in Enhancing the Photocatalysis Efficiency[J],J.Phys.Chem.B,2006,110:8587.
[60]N.C.Saha,H.G.Tompkins,Titanium nitride oxidation chemistry:An x-ray photoelectron spectroscopy study[J],J.Appl.Phys.,1992,72:3072.
[61]C.E.B.Marino,P.A.P.Nascente,S.R.Biaggio,R.C.Rocha-Filho,N.Bocchi,XPS characterization of anodic titanium oxide films grown in phosphate buffer solutions[J],Thin Solid Films,2004,468(1-2):109.
[62]Justicia,P.Ordej6n,G.Canto,J.L.Mozos,J.Fraxedas,G.A.Battiston,R.Gerbasi,A.Figueras,Designed Self-Doped Titanium Oxide Thin Films for Efficient Visible-Light Photocatalysis[J],Adv.Mater.,2002,14(19):1399.
[1]J.Yuan,S.Tsujikawa,Characterization of Sol-Gel-Derived TiO_2 coating and their photoeffects on copper substrates[J],J.Electrochem.Soc.,1995,142:3444.
[2]T.Imokawa,R.Fujisawa,A.Suda,et al.,Zairyo-to-Kankyo,1994,43:482-486(in Japanese).
[3]T.Konishi,S.Tsujikawa,Zairyo-to-Kankyo,1997,46:709-716(in Japanese).
[4]J.Yuan,S.Tsujikawa,Zairyo-to-Kankyo,1995,44:524-542(in Japanese).
[5]J.Huang,T.Shinohara,S.Tsujikawa,Zairyo-to-Kankyo,1997,46:651-661(in Japanese).
[6]J.Huang,T.Konishi,T.Shinohara,et al,Zairyo-to-Kankyo,1998,47:193-199(in Japanese).
[7]T.Fukuda,N.Kubota,M.Ayabe,et al,Fushoku Boshuoku Koenshu 1996,101-104(in Japanese).
[8]Park H,Kyoo Y K,Choi W,A novel photoelectrochemical method of metal corrosion using a TiO_2 solar panel[J],Chem.Comm.,2001,281.
[9]J.Huang,T.Shinohara,S.Tsujikawa,Zairyo-to-Kankyo,1999,48:575-582.
[10]T.Tatsuma,S.Saitoh,Y.Ohko,et al.,TiO_2-WO_3 photoelectrochemical anticorrosion system with an energy storage ability[J],Chem.Mater.,2001,13:2838.
[11]T.Tatsuma,S.Satioh,P.Ngaotra kanwiwat,et al.,Energy.storage of TiO_2-WO_3photocatalysis systems in the gas phase[J],Langmuir,2002,18:7777.
[12]Z.Y.Liu,K.Pan,M.J.Wang,et al.,Influence of the mixed ratio on the photocurrent of the TiO_2/SnO_2 composite photoelectrodes sensitized by mercurochrome[J],J.Photochem.Photobio.A:Chem.,2003,157:39.
[13]S.Raghavan,S.Tadashi,Investigations on SnO_2-TiO_2 composite photoelectrodes for corrosion protection[J],Electrechem.Commun.,2003,5:897.
[14]R.Subasri,S.Deshpande,S.Seal,T.Shinohara,Evaluation of the Performance of TiO_2-CeO_2 Bilayer Coatings as Photoanodes for Corrosion Protection of Copper[J],Electrochem.Solid-State Lett.,2006,9(1):B1.
[15]H.Park,Y.K.Kim,W.Choi,Photoelectrochemical approach for metal corrosion prevention using a semiconductor photoanode[J],J.Phys.Chem.B,2002,106:4775.
[16]李大成,周大利,任成军,刘恒,张萍,张云,龚家竹,纳米TiO_2的修饰改性[J],材料导报,2003,17(12):52.
[17]沈广霞,纳米TiO_2复合膜的制备及双重防腐蚀功能的研究[D],厦门大学博士学位论文,2004.
[18]李贺,姚素薇,张卫国,王宏智,贲宇恒,二氧化钛纳米管阵列电极的光电化学性能研究[J],稀有金属材料与工程,2007,36(10):1749.
[19]崔晓莉,江志裕,紫外光照下纳米TiO_2电极的电化学行为[J],物理化学学报,2002,18(11):1014.
[20]刘鸿,吴鸣,吴含进,孙福侠,郑云,李文钊,氢处理二氧化钛的光催化性能及电化学阻抗谱[J],物理化学学报,2001,17(3):286.
[21]张青龙,沈毅,吴国友,李真,朱华,纳米TiO_2的掺杂改性及应用进展研究[J],稀有金属快报,2005,24(12):6.
[22]许佩瑶,吴扬,李海宗纳米TiO_2的改性技术及其应用前景[J],广东化工,2005,9:37.
[23]王静,赵珊,池勇志,费学宁,TiO_2光催化剂改性技术研究新进展[J],天津城市建设学院学报,2006,12(2):116.
[24]F.E.Ghodsi,E Z.Tepehan,t2 GTepehan,Optical and electrochromie properties of sol-gel made CeO_2 TiO_2 thin films[J],Eleetroehim.Acta,1999,44:3127.
[25]J.Arana,O.González Díaz,M.Miranda Saracho,J.M.Dona Rodriguez,J.A.Herrera Meliáin,J.Pérez Pena,Photocatalytic degradation of formic acid using Fe/TiO_2 catalysts:the role of Fe~(3+)/Fe~(2+) ions in the degradation mechanism[J],Appl.Catal.B,2001,32(1-2):49.
[26]李振宏,伍虹,我国稀土应用的现状与前景[J],稀土,1996,17(6):48.
[27]罗改霞,路战胜,杨宗献,M(Al,Cu,Pd,Pt,Rh,Zr)掺杂CeO_2的第一性原理研究[J],中国稀土学报,2007,25:40.
[28]王嵩龄,刘钧云,贾江涛,廖春生,严纯华,大粒度、高表观比重氧化铈的合成[J],中国稀土学报,2008,26(1):117.
[29]Lars Baetz Reutergadh,Mallika Iangphasuk,Photocatalytic decolourization of reactive azo dye:A comparison between TiO_2 and us photoeatalysis[J],Chemosphere,1997,35(3):585.
[30]F.E.Ghodsi,F.Z.Tepehan,G.G.Tepehan,Optical and electrochromic properties of sol-gel made CeO_2-TiO_2 thin films[J],Eleetroehim.Acta,1999,44(18):3127.
[31]岳林海,水淼,徐铸德,郑遗凡,稀土掺杂二氧化钛的相变和光催化活性[J],浙江大学学报(理学版),2000,27(1):69.
[32]于向阳,程继健,杜永娟,稀土元素掺杂对TiO_2相组成和光催化性能的影响[J],玻璃与搪瓷,2000,28(2):15.
[33]钱斯文,王智宇,王民权,La~(3+)掺杂对纳米TiO_2微观结构及光催化性能的影响[J],材料与工程学报,2003,21(1):48.
[34]刘奎仁,于会文,韩庆,魏德洲,稀土掺杂TiO_2光催化材料的制备和性能[J],材料研究学报,2006,20(5):459.
[35]尹荔松,朱剑,闻立时,杨硕,谢琦谓,稀土-金属共掺杂纳米TiO_2的制备及其光催化性能[J],世界科技研究与发展,2008,30(2):122.
[36]孙海健,刘惠玲,铈掺杂TiO_2/Ti光电极制备及可见光下光电催化性能的研究[J],无机材料学报,2007,22(6):1065.
[37]B.S.Liu,X.J.Zhao,N.Z.Zhang,et al.,Photocatalytic mechanism of TiO_2-CeO_2 films prepared by magnetron sputtering under UV and visible light[J],Surf.Sci,2005,595(1-3):203.
[38]刘雪峰,张利,涂铭旌,载铈纳米TiO_2粉体的制备及其反射光谱特性研究[J],光谱学与光谱分析,2005,25(2):274.
[39]Z.L.Liu,B.Guo,L.Hong,et al.,Preparation and characterization of cerium oxide doped TiO_2 nanoparticles[J],J.Phys.Chem.Solids,2005,66(1):161.
[40]雷波,徐悦华,郭来秋,罗海燕,Ce-TiO_2/硅藻土的制备、表征及其光催化活性[J],中国有色金属学报,2007,17(5):795.
[41]P.Stefanov,G.Tanasova,D.Stoychev,T.Marinova,Electrochemical deposition of CeO_2 on ZrO_2 and Al_2O_3 thin films formed on stainless steel[J],Surf.Coat.Technol.2004,180 -181:446.
[42]S.Y.Zheng,A.M.Andersson-Faldt,B.Stjema,C.G.Granqvist,Appl.Optics,1993,32:6303.
[43]R.M.Bueno,J.M.Martinez-Duart,M.Hernandez-Velez,L.Vazquez,Optical and structural characterization of rf sputtered CeO_2 thin films[J],J.Mater.Sci.,1997,32(7):1861.
[44]M.S.Mattsson,A.Azens,G.A.Niklasson,C.G.Granqvist,J.Purans,Li intercalation in transparent Ti-Ce oxide films:Energetics and ion dynamics[J],J.Appi.Phys.1997,81(9):6432.
[45]S.Kanakaraju,S.Mohan,A.K.Sood,Optical and structural properties of reactive ion beam sputter deposited CeO_2 films[J],Thin Solid Films,1997,305(1-2):191.
[46]T.Ami,M.Suzuki,MOCVD growth of(100)-oriented CeO_2 thin films on hydrogen-terminated S si(100) substrates[J],Mater.Sci.Eng.B,1998,54(1-2):84.
[47]K.Jarrendahl,H.Arwin,Multiple sample analysis of spectroscopic ellipsometry data of semi-transparent films[J],Thin Solid Films,1998,313-314:114.
[48]F.Varsano,F.Decker,E.Massetti,F.Cardellini,A.Licciuli,Optical and electrochemical properties of cerium-zirconium mixed oxide thin films deposited by sol-gel and r.f.sputtering[J],Electrochim.Acta,1999,44(18):3149.
[49]S.Logothetidis,P.Patsalas,E.K.Evangelou,N.Konofaos,I.Tsiaoussis,N.Frangis,Dielectric properties and electronic transitions of porous and nanostructured cerium oxide films[J],Mater.Sci.Eng.B,2004,109(1-3):69.
[50]P.Baudry,A.C.M.Rodrigues,M.Aegerter,L.O.Bulhoes,Dip-coated TiO_2-CeO_2 films as transparent counter-electrode for transmissive electrochromic devices[J],J.Non Crys.Solids 1990,121(1-3):319.
[51]W.B.Carter,G.W.Book,T.A.Policy,D.W.Stollberg,J.M.Hampikian,Combustion chemical vapor deposition of CeO_2 film[J],Thin Solid Films,1999,347(1-2):25.
[52]K.D.Develos,M.Kusunoki,S.Ohshima,Studies on the surface morphology and orientation of CeO_2 films deposited by pulsed laser ablation [J], Jpn. J. Appl. Phys. 1998,37 (11): 6161.
[53] U. L. Stangar, U. Opara, B. Orel, Structural and electrochemical properties of sol-gel derived Mo: CeO_2, Si: Mo: Ce)_2 and Si: CeO_2 nanocrystalline films for electrochromic devices [J], J. Sol-Gel. Sci. Tech., 1997, 8 (1-3): 751.
[54] Z. C. Orel, Spectroscopic characterization of sol-gel dip-coating CeO_2 and CeO_2/SnO_2 films [J], Appl. Spectroscopy, 1999, 53 (2): 241.
[55] U. O. Krasovec, B. Orel, R. Reisfeld, Electrochromism of CeVO_4 and Ce/V-oxide ion-storage films prepared by the sol-gel route [J], Electrochem. Solid-State Lett., 1998, 1 (2): 104.
[56] U. O. Krasovec, B. Orel, A. Surca, N. Bukovec, R. Reisfeld, Structural and spectroelectrochemical investigations of tetragonal CeVO_4 and Ce/V-oxide sol-gel derived ion-storage films [J], Solid State Ionics, 1999,118 (3-4): 195.
[57] G Picardi, F. Varsano, F. Decker, U. O. Krasovec, A. Surca, B. Orel, Electrochemical characterization of optically passive CeVO_4 counterelectrodes [J], Electrochim. Acta, 1999, 44 (18): 3157.
[58] A. Vermaa, A. K. Bakhshib, S. A. Agnihotry, Effect of citric acid on properties of CeO_2 films for electrochromic windows [J], Sol. Energy Mater. Sol. Cells, 2006, 90 (11): 1640.
[59] M. L. Lavcevic, A. Turkovic, P. Dubcek, S. Bernstorff, Nanostructured CeO_2 thin films: A SAXS study of the interface between grains and pores [J], Thin Solid Films, 2007, 515 (14):5624.
[60] J. P. Gomilsek, I. K. Skofic, N. Bukovec, A. Kodre, X-Ray absorption study of CeO_2 and Ce/V mixed oxide thin films obtained by sol-gel deposition [J], Thin Solid Films, 2004,446 (1):117.
[61] G. S. Wu, T. Xie, X. Y. Yuan, B. C. Cheng, L. D. Zhang, An improved sol-gel template synthetic route to large-scale CeO_2 nanowires [J], Mater. Res. Bulletin, 2004, 39 (7-8):1023.
[62] N. Ozer, Optical properties and electrochromic characterization of sol-gel deposited ceria films [J], Sol. Energy Mater. Sol. Cells, 2001,68 (3-4): 391.
[63] A. Turkovic, P. Dubcek, S. Bernstorff, Grazing-incidence small-angle and wide-angle scattering of synchrotron radiation on nanosized CeO_2 thin films [J], Mater. Sci. Eng. B,1999, 58 (3): 263.
[64] A. Verma, A. K. Bakhshi, S. A. Agnihotry, Effect of different precursor sols on the properties of CeO_2-TiO_2 films for electrochromic window applications [J], Electrochim. Acta, 2006, 51 (22): 4639.
[65] Z. Assefa, R. G. Haire, D. L. Caulder, D. K. Shuh, Correlation of the oxidation state of cerium in sol-gel glasses as a function of thermal treatment via optical spectroscopy and XANES studies [J], Spectroc. Acta Pt. A-Molec. Biomolec. Spectr., 2004,60 (8-9): 1873.
[66]T.Ohsaka,Temperature dependence of the Raman spectrum anatase TiO_2[J],Jpn.J.Phys.Soc.,1980,48:1661.
[67]梁德荣,纳米TiO_2的制备及其光催化性能的研究[J],山西化工,2008,28(3):17.
[68]Y.B.Xie,C.W.Yuan,Rare earth ion modified TiO_2 sols for photocatalysis application under visible light excitation[J],Rare Metals,2004,23(1):20.
[69]奚丽荷,江海军,朱忠其,张瑾,柳清菊,CeO_2掺杂TiO_2光催化剂的性能研究[J],功能材料,2007,38(7):1146.
[70]吕卫星,方方,郭卫华,何平笙,LB膜法制备Y_2O_3掺杂的CeO_2超薄陶瓷膜的X光电子能谱(XPS)研究[J],光谱学与光谱分析,2002,22(1):16.
[71]杜新华,刘振祥,谢侃,溅射二氧化铈氧敏薄膜的XPS研究[J],功能材料,1998,29:6.
[72]F.B.Li,X.Z.Li,M.F.Hou,K.W.Cheah,W.C.H.Choy,Enhanced photocatalytic activity of Ce~(3+)-TiO_2 for 2-mercapto-benzothiazole degradation in aqueous suspension for odour control[J],Appl.Catal.A,2005,285(1-2):181.
[73]F.Zhang,P.Wang,J.Koberstein,S.Khalid,S.W.Chan,Cerium oxidation state in ceria nanoparticles studied with X-ray photoelectron spectroscopy and absorption near edge spectroscopy[J],Surf.Sci.,2004,563(1-3):74.
[74]庞松,侯书恩,张涛,刘贺年,Y_2O_3和CeO_2复合掺杂ZrO_2纳米晶的制备与表征[J],中国稀土学报,2007,25(6):755.
[75]W.Zhao,W.Ma,C.Chen,J.C.Zhao,Z.C.Shuai,Efficient degradation of toxic organic pollution with Ni_2O_3/TiO_2-xBx under visible light irradiation[J],J.Am.Chem.Soc.,2004,126(15):4782.
[76]赵燕宁,刘岗,孙成华,李峰,逯高清,成会明,硼在纳米晶氧化钛中的掺杂状态[J],材料研究学报,2008,22(2):125.
[77]魏凤玉,倪良锁,硼硫共掺杂TiO_2的光催化性能及掺杂机理[J],催化学报,2007,28(10):905.
[78]于夏,白令君,电子顺磁共振谱仪Bruker EMX EPR简介[J],现代仪器,2001,3:21.
[79]L.Pidol,O.Guillot-Noe"l,A.Kahn-Harari,B.Viana,D.Pelenc,D.Gourier,EPR study of Ce~(3+) ions in lutetium silicate scintillators Lu_2Si_2O_7 and Lu_2SiO_5[J],Journal of Physics and Chemistry of Solids,2006,67:643.
[1]肖正伟,曾振欧,赵国鹏,邱国平,304不锈钢上纳米TiO_2涂层的制备与防腐蚀性能研究[J],电镀与涂饰,2007,26(7):35.
[2]肖正伟,曾振欧,赵国鹏,纳米TiO_2涂层在低碳钢上的防腐蚀性能[J],电镀与涂饰,2006,25(12):33.
[3]Yoshihisa,S.Shuichi,T.Tetsu,F.Akira,Photoelectrochemical Anticorrosion and Self-Cleaning Effects of a TiO_2 Coating for Type 304 Stainless Steel[J],J.Electrochem.Soc.,2001,148(1):B24.
[4]T.Tetsu,S.Shuichi,O.Yoshihisa,F.Akira,TiO_2-WO_3 Photoelectrochemical Anticorrosion System with an Energy Storage Ability[J],Chem.Mater.,2001,13:2838.
[5]G.X.Shen,Y.C.Chen,C.J.Lin,Corrosion protection of 316L stainless steel by a TiO_2nanoparticle coating prepared by sol-gel method[J],Thin Solid Films,2005,489:130.
[6]S.Raghavan,S.Tadashi,M.Kazuhiko,TiO_2-Based Photoanodes for Cathodic Protection of Copper[J],J.Electrochem.Soc.,2005,152(3):B105.
[7]S.Raghavan,S.Tadashi,Investigations on SnO_2-TiO_2 composite photoelectrodes for corrosion protection[J],Electrochem.Commun.,2003,5:897.
[8]S.Raghavan,D.Sameer,S.Sudipta,S.Tadashi,Evaluation of the Performance of TiO_2-CeO_2 Bilayer Coatings as Photoanodes for Corrosion Protection of Copper[J],Electrochem.Solid State Lett.,2006,9(1):B1.
[9]Park,Y.K.Kim,W.Choi,Photoelectrochemical approach for metal corrosion prevention using a semiconductor photoanode[J],J.Phys.Chem.B,2002,106:4775.
[10]M.C.Li,S.Z.Luo,P.F.Wu,J.N.Shen,Photocathodic protection effect of TiO_2 films for carbon steel in 3%NaCl solutions[J],Electrochim.Acta,2005,50:3401.
[11]H.B.Li,X.D.Bai,Y.H.Ling,J.Li,D.L.Zhang,J.S.Wang,Fabrication of Titania Nanotubes as Cathode Protection for Stainless Steel[J],Electrochem.Solid State Lett.,2006,9(5):B28.
[12]J.Li,H.Yun,C.J.Lin,A Photoelectrochemical Study of n-Doped TiO_2 Nanotube Arrays as the Photoanodes for Cathodic Protection of SS[J],J.Electrochem.Soc.,2007,154(11):C631.
[13]D.Gong,C.A.Grimes,O.K.Varghese,W.C.Hu,R.S.Singh,Z.Chen,E.C.Dickey,Titanium oxide nanotube arrays prepared by anodic oxidation[J],J.Mater.Res.,2001,16(12):3331.
[14]T.Kasuga,M.Hiramatsu,A.Hoson,T.Sekino,K.Niihara,Formation of titanium oxide nanotube[J],Langmuir,1998,14(12):3160.
[15]T.Kasuga,M.Hiramatsu,A.Hoson,T.Sekino,K.Niihara,Titania nanotubes prepared by chemical processing[J],Adv.Mater.,1999,11(15):1307.
[16] G. Demazeau, Solvothermal processes: a route to the stabilization of new materials [J], J. Mater. Chem., 1999, 9 (1): 15.
[17] Z. Y. Yuan, W. Zhou, B. L. Su, Hierarchical interlinked structure of titanium oxide nanofibers [J], Chem. Commun., 2002,11:1202.
[18] Q. Chen, W. Zhou, G.H. Du, L.M. Peng, Trititanate nanotubes made via a single alkali treatment [J], Adv. Mater., 2002,14 (17) : 1208.
[19] X. Sun, Y. Li, Synthesis and characterization of ion-exchangeable titanate nanotubes [J], Chem. Eur. J., 2003,9 (10): 2229.
[20] B. D. Yao, Y. F. Chan, X. Y. Zhang, W. F. Zhang, Z.Y. Yang, N. Wang, Formation mechanism of TiO_2 nanotubes [J], Appl. Phys. Lett., 2003, 82 (2) : 281.
[21] Y. V. Kolen'ko, B. R. Churagulov, M. Kunst, L. Mazerolles, C. Colbeau-Justin, Photocatalytic properties of titania powders prepared by hydrothermal method [J], Appl. Catal. B: Environ., 2004, 54 (1): 51.
[22] Y. V. Kolen'ko, V. D. Maximov, A. V. Garshev, P. E. Meskin, N. N. Oleynikov, B. R. Churagulov, Hydrothermal synthesis of nanocrystalline and mesoporous titania from aqueous complex titanyl oxalate acid solutions [J], Chem. Phys. Lett., 2004, 388 (4-6): 411.
[23] H. G. Yu, J. G. Yu, B. Cheng, M. H. Zhou, Effects of hydrothermal post-treatment on microstructures and morphology of titanate nanoribbons [J], J. Solid State Chem., 2006, 179 (2): 349.
[24] J. G. Yu, G. H. Wang, B. Cheng, M. H. Zhou, Effects of hydrothermal temperature and time on the photocatalytic activity and microstructures of bimodal mesoporous TiO_2 powders [J], Appl. Catal. B: Environ., 2007, 69 (3-4): 171.
[25] D. V. Bavykin, V. N. Parmon, A. A. Lapkin, The effect of hydrothermal conditions on the mesoporous structure of TiO_2 nanotubes [J], J. Mater. Chem., 2004, 14 (22): 3370.
[26] M. Yada, Y. Inoue, M. Uota, T. Torikai, T. Watari, I. Noda, T. Hotokebuchi, Plate, wire, mesh, microsphere, and microtube composed of sodium titanate nanotubes on a titanium metal template [J], Langmuir, 2007, 23 (5): 2815.
[27] Z. R. Tian, J. A.Voigt, J. Liu, B. Mckenzie, H. F. Xu, Large oriented arrays and continuous films of TiO_2-based nanotubes [J], J. Am. Chem. Soc, 2003, 125 (41): 12384.
[28] Y. P. Guo, N-H. Lee, H-J. Oh, C-R. Yoon, K-S. Park, H-G. Lee, K-S. Lee, S-J. Kim, Structure-tunable synthesis of titanate nanotube thin films via a simple hydrothermal process [J], Nanotechnology, 2007, 18 (29): 295608.
[29] G. H. Du, Q. Chen, R. C. Che, Preparation and structure analysis of titanium oxide nanotubes [J], Appl. Phys. Lett., 2001, 79 (22): 3702.
[30] R. Z. Ma, Y. Bando, T. Sasaki, Nanotubes of lepidocrocite titanates [J], Chem. Phys. Lett., 2003, 380 (5-6): 577.
[31] Y. B. Mao, S. S. Wong, Size- and shape-dependent transformation of nanosized titanate into analogous anatase titania nanostructures [J], J. Am. Chem. Soc, 2006, 128 (25): 8217.
[32]R.Armstrong,G.Armstrong,J.Canales,P.G.Bruce,TiO_2-B nanowires[J],Angew.Chem.Int.Ed.,2004,43(17):2286.
[33]M.Zhang,Z.S.Jin,J.W.Zhang,X.Y.Guo,J.J.Yang,W.Li,X.D.Wang,Z.J.Zhang,Effect of annealing temperature on morphology,structure and photocatalytic behavior of nanotubed H_2Ti_2O_4(OH)_2[J],J.Mol.Catal.A,2004,217(1-2):203.
[34]R.Yoshida,Y.Suzuki,S.Yoshikawa,Syntheses of TiO_2(B) nanowires and TiO_2 anatase nanowires by hydrothermal and post-heat treatments[J],J.Solid State Chem.,2005,178(7):2179.
[35]R.Yoshida,Y.Suzuki,S.Yoshikawa,Effects of synthetic conditions and heat-treatment on the structure of partially ion-exchanged titanate nanotubes[J],Mater.Chem.Phys.,2005,91(2-3):409.
[36]Thorne,A.Kruth,D.Tunstall,J.T.S.Irvine,W.Z.Zhou,Formation,structure,and stability of titanate nanotubes and their proton conductivity[J],J.Phys.Chem.B,2005,109(12):5439.
[37]C.Tsai,H.Teng,Structural features of nanotubes synthesized from NaOH treatment on TiO_2 with different post-treatments[J],Chem.Mater.,2006,18(2):367.
[38]Y.B.Mao,M.Kanungo,H-B.Tirandai,S.S.Wong,Synthesis and growth mechanism of titanate and titania one-dimensional nanostructures self-assembled into hollow micrometer-scale spherical aggregates[J],J.Phys.Chem.B,2006,110(2):702.
[39]Y.K.Lai,L.Sun,C.Chen,C.G.Nie,J.Zuo,C.J.Lin,Optical and electrical characterization of TiO_2 nanotube arrays on titanium substrate[J],Appl.Surf.Sci.,2005,252(4):1101.
[40]Y.K.Lai,L.Sun,Y.C.Chen,H.F.Zhuang,C.J.Lin,W.C.Joannie,Effects of the structure of TiO_2 nanotube array on Ti substrate on its photocatalytic activity[J],J.Electrochem.Soc.,2006,153(7):D123.
[41]D.Bersani,G.Antonioli,P.P.Lottici,T.Lopez,Raman study of nanosized titania prepared by sol-gel route[J],J.Non-Cryst.Solids,1998,232-234:175.
[42]陈云霞,何鑫,刘超,谢毅,一维纳米结构TiO_2制备方法研究进展[J],中国陶瓷,2007,43(2):7.
[43]吕康乐,刘松翠,卢春山,水热合成法制备特定形貌的二氧化钛及光催化性能[J],中南民族大学学报(自然科学版),2008,27(1):18.
[44]郝彦忠,韩文涛,钛酸盐纳米管的制备及光电性能研究[J],物理化学学报,2006,22(2):221.
[45]C.E.B.Marino,P.A.P.Nascente,S.R.Biaggio,C.R-F.Romeu,N.Bocchi,XPS characterization of anodic titanium oxide films grown in phosphate buffer solutions[J],Thin Solid Films,2004,468(1-2):109.
[46]H.Yun,J.Li,H.B.Chen,C.J.Lin,A study on the N~-,S~- and Cl~- modified nano-TiO_2coatings for corrosion protection of stainless steel[J],Electrochim.Acta,2007,52(24): 6679.
[47]Matsuda,T.Matoda,T.Kogure,K.Tadanaga,T.Minami,M.Tatsumisago,Formation and characterization of titania nanosheet-precipitated coatings via sol-gel process with hot water treatment under vibration[J],Chem.Mater.,2005,17(4):749.
[48]T.Zajac,M.Radecka,M.Rekas,Photoelectrochemical properties of Nb-doped titanium dioxide[J],Physica B,2007,399:55.
[49]S.Berger,H.Tsuchiya,A.Ghicov,P.Schmuki,High photocurrent conversion efficiency in self-organized porous WO_3[J],Appl.Phys.Lett.,2006,88:119.
[50]G.K.Mor,K.Shankar,M.Paulose,O.K.Varghese,C.A.Grimes,Use of highly-ordered TiO_2 nanotube arrays in dye-sensitized solar cells[J],Nano Lett.,2006,6:215.
[51]J.H.Park,S.Kim,A.J.Bard,Novel carbon-doped TiO_2 nanotube arrays with high aspect ratios for efficient solar water splitting[J],Nano Lett.,2006,6:24.
[52]武朋飞,李谋成,沈嘉年,肖美群,刘东,阳极氧化二氧化钛薄膜的光电化学防腐蚀特性[J],中国腐蚀与防护学报,2005,25(1):53.
[53]曹楚南,张鉴清,电化学阻抗谱导论[M],北京,科学出版社,2002.
[54]吕德义,王晖,郇昌永,周春晖,葛忠华,水热晶化法制备纳米TiO_2的动力学研究[J],浙江工业大学学报,2004,32(1):41.
[55]肖奇,邱冠周,胡岳华,纳米TiO_2制备及其应用新进展[J],材料导报,2000,14(8):35.
[56]Y.Paz,Z.Luo,L.Rabenberg,A.Heller,Photooxidative self-cleaning transparent titanium dioxide films on glass[J],J.Mater.Res.,1995,10:2842.
[57]R.Fretwell,P.Douglas,An active,robust and transparent nanocrystalline anatase TiO_2 thin film- preparation,characterization and the kinetics of photodegradation of model pollutants [J],J.Photochem.Photobiol.A,2001,143:229.
[58]Mills,S-K.Lee,A.Lepre,I.P.Parkin,S.A.O'Neill,Spectral and photocatalytic characteristics of TiO_2 CVD films on quartz[J],Photochem.Photobiol.Sci.,2002,1:865.
[59]Mills,A.Lepre,N.Elliot,S.Bhopal,O.P.Parkin,S.A.O'Neill,Characterisation of the photocatalyst Piikington Activ~(TM):a reference film photocatalyst?[J],J.Photochem.Photobiol.A,2003,160(3):213.
[60]K.Takagi,T.Makimoto,H.Hiraiwa,T.Negishi,Photocatalytie,antifogging mirror[J],J.Vac.Sci.Technol.A Vac.Surf.Films,2001,19(6):2931.
[61]H.Choi,E.Stathatos,D.Dionysiou,Synthesis of nanocrystalline photocatalytic TiO_2 thin films and particles using sol-gel method modified with nonionic surfactants[J],Thin Solid Films,2006,510(1-2):107.
[62]P.Arnal,R.J.P.Corrriu,D.Leclercq,et al.,A solution chemistry study of nonhydrolytic sol-gel routes to titania[J],Chem.Mater.,1997,9(3):694.
[63]Y.Mori,Y.Okastu,Y.Tsujimoto,Titanium dioxide nanoparticles produced in water-in-oil emulsion[J].J.Nano.Res,2001,3(2-3):219.
[64]陈洪龄,王延儒,时钧,单分散超细二氧化钛颗粒的制备及粒径控制[J],物理化学学报,2001,17(8):713.
[65]仇雁翎,赵建夫,李田,朱志良,热处理温度对TiO_2光催化膜性能的影响[J],同济大学学报(自然科学版)2008,36(6):764.
[66]H.J.Lee,S.H.Hahn,E.J.Kim,et al.,Influence of calcination temperature on structural and optical properties of TiO_2-SiO_2 thin films prepared by sol-gel dip coating[J],J.Mater.Sci.,2004,39(11):3683.
[67]王鹤峰,季秀燕,张洪涛,不锈钢基底上TiO_2薄膜的制备和结构分析[J],太原理工大学学报,2008,39(1):17.
[68]孟凡明,周明飞,蔡琪,孙兆奇,纳米TiO_2薄膜的制备与表面形貌研究[J],真空科学与技术学报,2008,28(1):72.
[69]黄晖,罗宏杰,姚熹,水热法制备TiO_2薄膜的研究[J],物理学报,2002,51(8):1881.
[70]Q.W.Chen,Y.T.Qian,Z.Y.Chen,et al.,Appl.Phys.Lett.,1995,66:1608.
[71]W.S.Cho,M.Yoshimura,Hydrothermal synthesis of PbTiO_3 films[J],J.Mater.Res.,1997,12(3):833.
[72]C.Y.Cho,E.W.Shi,M.S.Jang,et al.,J.Appl.Phys.Part,1994,33:4984.
[73]D.S.Kim,S.-Y.Kwak,The hydrothermal synthesis of mesoporous TiO_2 with high crystallinity,thermal stability,large surface area,and enhanced photocatalytic activity[J],Applied Catalysis A:General,2007,323:110.
[74]H.G.Yu,J.G.Yu,B.Cheng,M.H.Zhou,Effects of hydrothermal post-treatment on microstructures and morphology of titanate nanoribbons[J],J.Solid State Chem.,2006,179:349.
[75]李竟先,吴基球,庄志强,TiO_2纳米颗粒水热法制备研究进展及反应机理的初步研究[J],中国陶瓷工业,2001,8(2):29.
[76]A.Matsuda,Y.Kotani,T.Kogure,M.Tatsumisago,T.Minami,Transparent anatase nanocomposite films by the sol-gel process at low temperatures[J],J.Am.Ceram.Soc.,2000,83(1):229.
[77]Y.Kotani,A.Matsuda,T.Kogure,M.Tatsumisago,T.Minami,Effects of addition of poly(ethylene glycol) on the formation of anatase nanocrystals in SiO_2-TiO_2 gel films with hot water treatment[J],Chem.Mater.,2001,13(6):2144.
[78]H.Imai,H.Hirashima,K.Awazu,Alternative modification methods for sol-gel coatings of silica,titania and silica-titania using ultraviolet irradiation and water vapor[J],Thin Solid Films,1999,351(1-2):91.
[79]H.Imai,H.Hirashima,Preparation of porous anatase coating from sol-gel-derived titanium dioxide and titanium dioxide-silica by water-vapor exposure[J],J.Am.Ceram.Soc.,1999,82(9):2301.
[80]N.Uekawa,J.Kajiwara,K.Miyatake,K.Kakegawa,Y.Sasaki,Low temperature synthesis of titania gel containing anatase and rutile[J],Chem.Lett.,2000,4:382.
[81]C.J.Brinker,A.J.Hurd,J.Phys.Ⅲ,1994,4:1231.
[82]M.Burgos,M.Langlet,Condensation and densification mechanism of sol-gel TiO_2 layers at low temperature[J],J.Sol-Gel Sci.Technol.,1999,16(3):267.
[83]M.Langlet,M.Burgos,C.Couthier,C.Jimenez,C.Morant,M.Manso,Low temperature preparation of high refractive index and mechanically resistant sol-gel TiO_2 films for muitilayer antireflective coating applications[J],J.Sol-Gel Sci.Technol.,2001,22(I-2):139.
[84]K.I.Gnanasekar,V.Subramanian,J.Robinson,J.C.Jiang,F.E.Posey,B.Rambabu,Direct conversion of TiO_2 sol to nanocrystalline anatase at 85 degrees C[J],J.Mater.Res.,2002,17(6):1507.
[85]Y.Djaoued,S.Badilescu,P.V.Ashrit,D.Bersani,P.P.Lottici,R.Bruning,Low temperature sol-gel preparation of nanocrystalline TiO_2 thin films[J],J.Sol-Gel Sci.Technol.,2002,24(3):247.
[86]M.Langlet,A.Kim,M.Audier,J.M.Hermann,Sol-gel preparation of photocatalytic TiO_2films on polymer substrates[J],J.Sol-Gel Sci.Technol.,2002,25(3):223.
[87]Z.Wang,U.Helmersson,P.O.Kall,Optical properties of anatase TiO_2 thin films prepared by aqueous sol-gel process at low temperature[J],Thin Solid Films,2002,405(1-2):50.
[88]Y.Gao,Y.Masuda,Z.Peng,T.Yonezawa,K.Koumoto,Room temperature deposition of a TiO_2 thin film from aqueous peroxotitanate solution[J],J.Mater.Chem.,2003,13(3):608.
[89]梁德荣,纳米TiO)2的制备及其光催化性能的研究[J],山西化工,2008,28(3):17.
[90]B.Zielinska,J.Grzechulska,B.Grzmil,et al.,Photocatalytic degradation of reactive black 5:a comparison between TiO_2-tytanpol A11 and TiO_2-degussa P25 photocatalysts[J],Appl.Catal B:Environ,2001,35:1.
[91]B.Ohtani,Y.Ogawa,S.Nishimoto,Photocatalytic activity of amorphous-anatase mixture of titanium(Ⅳ) oxide particles suspended in aqueous solutions[J],J.Phys.Chem B,1997,101:3746.
[92]K.Byrappa,M.Yoshimura,Handbook ofhydrothermal technology:a technology for crystal growth and materials processing,1st edition[M].New York:William Andrew Publishing,2001,1-8.
[93]罗薇,万洪富,黄莺,侯梅芳,环境修复新型纳米TiO_2材料的合成因素探讨[J],生态环境,2007,16(6):1807.
[94]李汶军,郑燕青,施尔畏,TiO_2和Al_2O_3晶体的生长习性[J],无机材料学报,2000,15(6):968.
[95]M.Gopal,W.J.M.Chan,J.L.C.De,Room temperature synthesis of crystalline metal oxides[J],J.Mater.Sci.,1997,32(22):6001.
[96]包定华,顾豪爽,邝安祥,Sol-gel法合成TiO_2纳米粉末和薄膜[J],无机材料学报,1996,11(3):453.
[97]H.M.Cheng,J.M.Ma,Z.G.Zhao,et al.,Hydrothermal preparation of uniform nanosize rutile and anatase particles[J],Chem.Mater.,1995,7:663.
[98]T.Nagase,T.Ebina,T.Iwasaki,K.Hayashi,Y.Onodera,M.Chatterjee,Hydrothermal synthesis of brookite[J],Chem.Lett.,1999,9:911.
[99]N.Uekawa,J.Kajiwara,K.Kakegawa,Y.Sasaki,Low temperature synthesis and characterization of porous anatase TiO_2 Nanoparticles[J],J.Colloid Interface Sci.,2002,250(2):285.
[100]M.Tang,G.Z.Wang,L.D.Zhang,Thermal desorption in nanocrystalline TiO_2[J],J.Appl.Phy,1996,80(2):15.
[101]X.Turrillas,P.Barnes,S.E.Tarling,Neutron thermodiffractometry and synchrton energydispersive diffraction stedies of zirconium hydroxide calcinations[J].J.Mster.Sci.Lett.,1993.12:223.
[102]陈武,季寿元编,矿物学导论,北京:地质出版社,1985,112.
[103]R.D.Shannon,J.A.Pask,Kinetics of the anatase-rutile transformation[J],J.Am.Ceram Soc,1965,48:391.
[104]郑燕青,施尔畏,元如林,李汶军,王步国,仲维卓,胡行方,二氧化钛晶粒的水热制备及其形成机理研究[J],中国科学(E辑),1999,29(3):206.
[105]黄军华,高濂,陈锦元,纳米TiO_2粉体制备过程中结晶度的控制[J],无机材料学报,1996,11(1):51.
[106]T.Ohsaka,Temperature dependence of the Raman spectrum anatase TiO_2[J],Jpn.J.Phys.Soc,1980,48:1661.
[107]汪国忠,汪春昌,张立德,纳米TiO_2的制备和性能[J],材料研究学报,1997,11(5):527.
[108]石金娥,闫吉昌,王悦宏,闫福成,陈大伟,王莹,赵凯,李晓坤,崔晓莹,翟玉娟,不同形貌TiO_2的水热合成及对苯酚的降解研究[J],高等学校化学学报,2006,27(8):1513.
[109]谢德明,胡吉明,童少平,多道环氧涂层在NaCl溶液中的电化学阻抗谱[J],材料研究学报,2004,18(2):96.
[110刘旭文,熊金平,曹京宜,左禹,无机/有机复合涂层体系在3.5%NaCl溶液中的EIS [J],化工学报,2007,58(9):2282.
[111]G.Grundmeier,W.Schmidt,M.Stratmann,Corrosion protection by organic coatings:electrochemical mechanism and novel methods of investigation[J],Electrochimica Acta,2000,45(15-16):2515.
[112]张鉴清,曹楚南,电化学阻抗谱方法研究评价有机涂层[J],腐蚀与防护,1998,19(3):99.
[113]陈群尧,涂层及其腐蚀失效机理的研究方向和方法[J],中国腐蚀与防护学报,1997,17(4):307.
[114]阎瑞,吴行,环氧铝粉涂层在3.5%NaCl介质中的失效机理研究[J],中国表面工程,2007,20(4):29.
[115]周陈亮,肖利秋,窦贤飞,电化学方法在涂层/金属体系耐蚀性能评估中的应用[J],涂料工业,1998(9):42.
[116]P.Campestrini,E.P.M.Van Westing,De Wit J H W,Influence of surface preparation on performance of chromate conversion coatings on Al clad 2024 aluminium alloy - Part Ⅱ:EIS investigation[J],Electrochim.Acta,2001,46(17):2631.
[117]Y.Y.Shi,Z.Zhang,J.X.Su,et al.,EIS study on 2024-T3 aluminum alloy corrosion in simulated acid rain under cyclic wet- dry conditions[J],Mater.Corros.,2005,56(10):701.
[118]M.L.Zheludkevich,K.A.Yasakau,S.K.Poznyak,et al.,Triazole and thiazole derivatives as corrosion inhibitors for AA2024 aluminium alloy[J],Corros.Sci.,2005,47(12):3368.
[119]尹燕萍,罗江财,杨晓波,何伟全,光电材料的俄歇电子谱分析[J],半导体光电,2000,21:84.
[120]仇满德,姚子华,纳米Ti02薄膜表面微区分析的研究进展[J],材料导报,2007,2l:51.
[121]伍彦,姚文清,朱永法,Ta_2O_5/Si薄膜界面结构及光催化活性[J],物理化学学报,2007,23(5):625.
[122]朱永法,李巍,不锈钢丝网上薄膜TiO_2光催化剂的Rarnan光谱研究[J],光谱学与光谱分析,2003,23(3):494.
[123]Y.F.Zhu,L.Zhang,L.Wang,Y.Fu,L.L.Cao,The preparation and chemical structure of TiO_2 film photocatalysts supported on stainless steel substrates via the sol-gel method[J],J.Mater.Chem.,2001,11(7):1864.
[124]朱永法,张利,王莉,付艳,曹立礼,不锈钢基底上TiO_2薄膜型光催化剂的制备和化学结构[J],化学学报,2000,58(4):467.
[125]X.Zhao,M.H.Liu,Y.F.Zhu,Fabrication of porous TiO_2 film via hydrothermal method and its photocatalytic performances[J],Thin Solid Films,2007,515(18):7127.
[2]张立德,牟季美,纳米材料和纳米结构[M],北京:科学出版社,2001.
[3]刘守新,刘鸿,光催化及光电催化基础与应用[M],北京:化学工业出版社.
[4]M.L.Sterigerwald,et al.,Synthesis,stanilization and electronic structure of quantum semiconductor nanoclusters[J],Annv.Rev.Mater.Sci,1989,19:471.
[5]Y.Wang,et al.,Linear and nonlinear optical properties of semiconductor clusters[J],J.Opt.Soc.Am.B,1989,6:808.
[6]R.Rosseti,et al.,Size effects in the excited electronic states of small colloidal CdS crystallities[J],J.Chem.Phys,1983,80(9):4464.
[7]Y.Wang,et al.,Nanometer-sized semiconductor clusters:Materials synthesis,quantum size effects and photophysical properties[J],J.Phys.Chem,1991,95:525.
[8]M.Anpo,et al.,Photocatalytic hydrogenation of CH_3CCH with H_2O on small-particle TiO_2:Size quantization efficts and reaction intermediates[J],J.Phys.Chem,1987,91:4305.
[9]Nakajima,K.Hashimoto,T.Watanabe,et al.,Transparent superhydrophobic thin films with self-cleaning properties[J],Langmuir,2000,16:7044.
[10]M.Miyauchi,A.Nakajima,Watanabe,et al.,Photocatalysis and photoinduced hydrophilicity of Vaious metal oxide thin films[J],Chem.Mater.,2002,14:2812.
[11]张肇富,新型太阳能电池问世[J],能源技术,1999,4:57.
[12]高濂,郑珊,张青红著,纳米氧化钛光催化材料及应用[M],北京:化学工业出版社,2002.
[13]张红平,有序纳米结构导电聚合物膜和半导体微粒膜的电化学组装及表征[D],2000.
[14]黄怀国,导电聚合物-纳米半导体微粒复合膜的制备和性能研究[D],2001.
[15]胡春,王怡中,汤鸿霄,多相光催化氧化的理论与实践发展[J],环境科学与发展,1995,3(1):55.
[16]B.O'Regan,J.Moser,M.Gratzel et al.,Vectorial electron injectionin to transparent semiconductor membrane and electricfield effects on the dynamic so flight induced charged separation[J],J Phys.Chem.,1990,94(24):8720.
[17]B.O'Regan,M.Gratzel.A low-cost,high-efficiency solar cell based on dyesesitized colloidal TiO_2 film[J],Nature,1991,353(24):737.
[18]Fujishima,K.Hashimoto,Electrochemical photolysis of water at a semicondouctor electrode,Nature[J],1972,238:37.
[19]胡智学,戴松元,王孔嘉等,染料在纳米TiO_2薄膜表面吸附性能的研究[J],化学研究 与应用,2002,14(3):277.
[20]秦东元,王晶晶,邹英华等,TiO_2的联吡啶-钌化合物敏化及电子转移过程[J],物理化学学报,1998,14(6):520.
[21]L.Bahadur,P.Srivastava,Improved performance of 2-imidazolin-5-one as sensitizer at nanocrystalline ZnO thin film electrode in acetonitrile solution[J],Semicond.Sci.Tech.,2004,19(3):531.
[22]贺北平,王占生,张锡辉,半导体光催化有机物的研究现状及发展趋势[J],环境科学,1993,15(3):80.
[23]王海,陈德文,王素华等,二氧化钛胶体界面芳香化学物的光催化分解[J],化学物理学报,1995,8(4):146.
[24]K.Nagaveni,G.Sivalingam,M.S.Hedge,et al.,Solar photocatalytic degradation of dyes:high activity of combustion synthesized nano TiO_2[J],Appl.Catai.B-Environ.,2004,48(2):83.
[25]Ilisz,A.Dombi,K.Mogyorosi,et al.,Photoeatalytie water treatment with different TiO_2nanoparticles and hydrophilic/hydrophobic layer silicate adsorbents[J],Collid Surface A,2003,230(1-3):89.
[26]M.C.Barnes,A.R.Gerson,S.Kumar,et al.,The mechanism of TiO_2 deposition by direct current magnetron reactive sputtering[J],Thin Solid Films,2004,446(1):29.
[27]S.Malato,J.Blanco,A.Vidal,et al.,Applied studies in solar photoeatalytic detoxification:an overview[J],Sol.Energy,2003,75(4):329.
[28]K.Teramura,T.Tanaka,M.Kani,et al.,Selective photo-oxidation of neat cyclohexane in the liquid phase over V_2O_5/Al_2O_3[J],J Mol.Catal.A-Chem.,2004,208(1-2):299.
[29]D.S.Ren,X.L.Cui,J.Shen,et al.,Study on the superhydrophilicity of the SiO_2-TiO_2 thin films prepared by sol-gel method at room temperature[J],J Sol-Gel Sci.Tech.,2004,29(3):131.
[30]T.L.Sun,G.J.Wang,L.Feng,et al.,Reversible switching between superhydrophilicity and superhydrophobicity[J],Angew Chem.Int.Edit.,2004,43(3):357.
[31]R.J.Zeng,Q.Pang,Z.H.Lin,et al.,Effects of y3+ dopant on the photoinduced superhydrophilicity of thin nanostructured titania films and its mechanism[J],Chin.J.Inorg.Chem.,2003,19(7):678.
[32]曾人杰,林仲华,方智敏,光诱导纳米二氧化钛超亲水薄膜SPM图像分析和氧空位浓度理论探讨[J],电化学,2001,7(4):413.
[33]R.Wang,K.Hashimoto,A.Fujishima,et al.,Photogeneration of highly amphiphilic TiO_2surfaces[J],Adv.Maters.,1998,10(2):135.
[34]R.Wang,K.Hashimoto,A.Fujishima,et al.,Light induced amphiphilic surfaces[J],Nature,1997,388:431.
[35]王洪梅,赵中一,陈莉莉,二氧化钛亲水性技术现状[J],环境科学动态,2003,2:36.
[36]K.Katsumata,A.Nakajima,H.Yoshikawa,T.Shiota,N.Yoshida,T.Watanabe,Y.Kameshima,K.Okada,Effect of microstructure on photoinduced hydrophilicity of transparent anatase thin films[J],Surf.Sci.,2005,579(2-3):123.
[37]N.Sakai,R.Wang,A.Fujishima,T.Watanabe,K.Hashimoto,Effect of ultrasonic treatment on highly hydrophilic TiO2 surfaces[J],Langmuir,1998,14(20):5918.
[38]M.Miyauchi,A.Nakajima,T.Watanabe,K.Hashimoto,Photocatalysis and photoinduced hydrophilicity of various metal oxide thin films[J],Chem.Mater.,2002,14(6):2812.
[39]何宇亮,纳米半导体器件与纳米电子学[J],半导体杂志,1994,19(4):9.
[40]薛增泉,纳米电子器件[J],真空科学与技术,1998,18(6):395.
[41]S.M.Goodnick,J.Bird,Quantum-effect and single-electron devices[J],Ieee Transaction on Nanotechnology,2003,2(4):368.
[42]M.Porti,X.Blasco,M.Nafria,et al.,Electrical characterization and fabrication of SiO_2based metal-oxide-semiconductor nanoelectronic devices with atomic force microscopy[J],Nanotechnology,2003,14(6):584.
[43]林明,范以宁,刘浏,许波连,胡征,陈懿,高能机械球磨法制备V_2P_5-TiO_2超细微粒催化剂[J],催化学报,2001,22:585.
[44]高镰,郑珊,张青红,纳米氧化钛光催化材料及应用[M],北京:化学工业出版社,2002.
[45]杨合,薛向欣,赵娜,左良,半导体多相光催化研究进展及应用技术[J],材料与冶金学报,2003,2:16.
[46]杨海堃,气相氢氧焰水解法生产超微细二氧化钛[J],中国粉体技术,2000,2:30.
[47]M.Keshmiri,M.Mohseni,T.Troczynski,Development of novel TiO_2 sol-gel-derived composite and its photocatalytic activities for trichloroethylene oxidation[J],Appl.Catal.B-Environ.,2004,53:209.
[48]C.Su,B.Y.Hong,C.M.Tseng,Sol-gel preparation and photocatalysis of titanium dioxide [J],Catal.Today,2004,96:119.
[49]刘双怀,周根陶,许菱,彭定坤,单分散二氧化钛超微粒子的制备[J],应用化学,1994,11:36.
[50]高濂,陈锦元,黄军华.严东生,醇盐水解法制备二氧化钛纳米粉体[J],无机材料学报,1995,10:423.
[51]S.C.Pillai,P.Periyat,R.George,D.E.McCormack,M.K.Seery,H.Hayden,J.Colreavy,D.Corr,S.J.Hinder,Synthesis of high-temperature stable anatase TiO2 photocatalyst[J],J.Phys.Chem.C,2007,111:1605.
[52]包南,孙剑,张锋,马志会,刘峰,N掺杂TiO_2纳米晶:水热.热分解法制备及光催化活性[J],无机化学学报,2007,1:101.
[53]丘永梁,陈洪龄,汪效祖,徐南平,水热法制备纳米TiO_2及其等电点的研究[J],高校 化学工程学报,2005,19:129.
[54]牛新书,许亚杰,张学治,刘国光,蒋凯,微乳液法制备纳米二氧化钛及其光催化活性[J],功能材料,2003,34:548.
[55]M.S.Lee,G.D.Lee,C.S.Ju,S.S.Hong,Preparations of nanosized TiO_2 in reverse microemulsion and their photocatalytic activity[J],Sol.Energy Mater.Sol.Cells,2005,88:389.
[56]潘峰,范殿,柳百新,纳米磁性多层膜进展[J],物理,199l,22:9.
[57]李强勇,纳米薄膜研究的进展[J],真空与低温,1994,13(3):162.
[58]柳闽生,詹寿发,谢宝华等,纳米技术及其在环境保护中的应用[J],九江师专学报(自然科学),2002,5:23.
[59]吴振华,离子参数对物理气相沉积薄膜微结构的影响[J],电工电能新技术,1994,4:10.
[60]柳襄怀,杨根庆,王曦等,离子束增强沉积形成梯度薄膜[J],材料研究学报,1994,8(1):61.
[61]柳襄怀,离子束增强沉积薄膜合成及其在材料表面优化中的应用[J],上海有色金属,1994,15(4):65.
[62]Z.Tokei,F.Iacopi,O.Richard,et al.,Barrier studies on porous silk semiconductor dielectric[J],Microelection Eng.,2003,70(2-4):352.
[63]J.M.Correia-Pires,J.B.Almeida,V.Teixeira,Gas-sensitive response of SnO_2 thin-film sensors produced by reactive DC magnetron sputtering[J],Key Eng.Mater.,2002,230:388.
[64]李鹏兴,CVD与PVD硬涂层研究的进展[J],上海金属,1994,15(2):55.
[65]孙一军,夏冠群,张良莹,姚熹,高取向锐钛矿TiO_2薄膜的MOCVD法制备与表征[J],功能材料与器件学报,1998,4:208.
[66]H.Yoshitake,T.Sugihara,T.Tatsumi,Preparation of wormhole-like mesoporous TiO_2 with an extremely large surface area and stabilization of its surface by chemical vapor deposition [J],Chem.Mater.,2002,14:1023.
[67]Q.Fang,M.Meier,J.J.Yu,et al.,FTIR and XPS investigation of Er-doped SiO_2-TiO_2 films [J],Mat.Sci.Eng.B-Sold,2003,105(1-3):209.
[68]B.H.Kim,J.Y.Lee,Y.H.Choa,M.Higuchi,N.Mizutani,Preparation of TiO_2 thin film by liquid sprayed mist CVD method[J],Mat.Sci.Eng.B-Sold.,2004,107:289.
[69]D.H.Kuo,C.N.Shueh,Growth of chemical vapor deposition aluminum titanate films at different CO_2/H_2 and aluminum butoxide inputs[J],J.Vac.Sci.Technol.A,2004,22:151.
[70]V.G.Bessergenev,R.J.F.Pereira,M.C.Mateus,I.V.Khmelinskii,D.A.Vasconcelos,R.Nicula,E.Burkel,A.M.Botelho do Rego,A.I.Saprykin,Study of physical and photocatalytic properties of titanium dioxide thin films prepared from complex precursors by chemical vapour deposition[J],Thin Solid Films,2006,503:29.
[71]林君,庞茂林,韩银花等,溶胶-凝胶工艺制备发光薄膜研究进展[J],无机化学学报,2001,17(2):153.
[72]于向阳,程继健,杜永娟,TiO_2光催化薄膜的制备法[J],玻璃与搪瓷,2001,29:37.
[73]郭建辉,杨建军,李庆霖等,纳米薄膜光催化剂的制备与表面态研究[J],化学研究,2003,14(2):13.
[74]K.Jamting,J.M.Bell,M.V.Swain,L.S.Wielunski,R.Clissold,Measurement of the micro mechanical properties of sol-gel TiO2 films[J],Thin Solid Films,1998,332:189.
[75]T.Watanabe,S.Fukayama,M.Miyauchi,A.Fujishima,K.Hashimoto,Photocatalytic activity and photo-induced wettability conversion of TiO_2 thin film prepared by sol-gel process on a soda-lime glass[J],J.Sol-Gel.Sci.Technol.,2000,19:71.
[76]M.J.Alam,D.C.Cameron,Preparation and characterization of TiO_2 thin films by sol-gel method[J],J.Sol-Gel.Sci.Technol.,2002,25:137.
[77]孙志华,刘明辉,应用电沉积方法制备纳米多层膜的研究现状[J],腐蚀与防护,2002,23:114.
[78]王震林,王太宏,基于阳极氧化法的纳米结构加工和纳米器件的制备[J],微电子技术,2001,29:17.
[79]V.Zwilling,M.Aucouturier,E.Darque-Ceretti,Anodie oxidation of titanium and TA6V alloy in chromic media,an electrochemical approach[J],Electrochim.Acta,1999,45:921.
[80]刘惠玲,周定,李湘中,余秉涛,网状Ti/TiO_2电极光电催化氧化若丹B[J],环境科学,2002.23:47.
[81]D.Gong,C.A.Grimes,O.K.Varghese,W.Hu,R.S.Singh,Z.Chen,E.C.Dickey,Titanium oxide nanotube arrays prepared by anodic oxidation[J],J.Mater.Res.,2001,16:3331.
[82]J.M.Macak,H.Tsuchiya,P.Schmuki,High-aspect-ratio TiO_2 nanotubes by anodization of titanium[J],Angew.Chem.Int.Ed.,2005,44:2100.
[83]邱建斌,曹亚安,马颖,管自生,姚建年,担载材料对TiO_2薄膜光催化性的影响[J],物理化学学报,2000,16:1.
[84]M.Dolata,P.Kedzierzawki,J.Augustynski,Comparative impedance spectroscopy study of rutile and anatase TiO_2 film electrodes[J],Electrochim.Acta,1996,41:1287.
[85]冷文华,张昭,成少安,张鉴清,曹楚南,直接热氧化制备氧化钛薄膜电极的研究Ⅰ:制备、结构和电化学性质[J],化学物理学报,2001,14:705.
[86]Y.V.Kolen'ko,V.D.Maximov,A.V.Garshev,et al.,Hydrothermal synthesis of nanocrystalline and mesoporous titania from aqueous complex titanyl oxalate acid solutions [J],Chem.Phys.Lett.,2004,388(4-6):411.
[87]Z.Y.Yuan,X.B.Zhang,B.L.Su,Moderate hydrothermal synthesis of potassium titanate nanowires[J],Appl.Phys.A-Mater.,2004,78(7):1063.
[88]S.Uchida,R.Chiba,M.Tomiha,et al.,Application of titania nanotubes to a dye-sensitized solar cell[J],Electrochemistry,2002,70(6):418.
[89]H.Nagayama,H.Honda,H.Kawahara,J.Electrochem Soc.,1988,135(8):2013.
[90]周磊,刘昌,赵文宽,胡翎,方佑龄,液相沉积法制备光催化活性掺铁TiO_2薄膜[J],催化学报,2003,24:359.
[91]王晓平,于云,高濂,胡行方,TiO_2薄膜的液相沉积法制备及其性能表征[J],无机材料学报,2000,15:573.
[92]H.Yu,S.C.Lee,J.Yu,C.H.Ao,Photocatalytic activity of dispersed TiO_2 particles deposited on glass fibers[J],J.Mol.Catal.A-Chem.,2006,246:206.
[93]T.H.Kim,B.H.Sohn,Photocatalytic thin films containing TiO_2 nanoparticles by the layer-by-layer self-assembling method[J],Appl.Surf.Sci.,2002,201:109.
[94]J.Jin,L.S.Li,Y.Li,X.Chen,L.Jiang,Y.Y.Zhao,T.J.Li,Preparation of titanium dioxide and barium titanate nanothick film by Langmuir-Blodgett technique[J],Thin Solid Films,2000,379:218.
[95]郝维昌,潘锋,王天民,郑树凯,TiO_2/PSS自组装薄膜的光催化性能[J],稀有金属材料与工程,2004,33:63.
[96]Sopyan,M.Watanabe,S.Murasawa,K.Hashimoto,A.Fujishima,A film-type photocatalyst incorporating highly active TiO_2 power and fluororesin binder:photocatalytic activity and long-term stability[J],J.Electroanal.Chem.,1996,415:183.
[97]吴光佑著,阴极保护的原理和应用[M],机械工业出版社,北京,1965.
[98]S.R.Morrison,Electrochemistry at Semiconductor and Oxided Metal Electrodes,Plenum,New York,1980,p 49.
[99]P.M.Natishan,E.McCafferty,G.K.Hubler,Surface change condersions in the pitting of ion- implanted aluminum[J],J.Electrochem.Soc.,1988,135:321.
[100]N.Sato,Boshoku Gijutsu,1990,39:495.
[101]K.Sugimoto,Tetsu To Hagne,1991,77:258.
[102]Y.Hayashi,M.Masuda,J.Lee,et al.,Study on corrosion properties of sputter coating of oxides on the stainless steel[J],Mater.Sci.Eng.A,1995,198:71.
[103]J.Masalski,J.Gluszek,J.Zabrzeski,K.Nitsch,P.Gluszek,Improvement in corrosion resistance of the 316L stainless steel by means of Al_2O_3 coatings deposited by the sol-gel method[J],Thin solid films,1999,349(1-2):186.
[104]R.J.Solar,Corrosion resistance of titanium surgical implant alloys:A Review[A].In:Syreet B C,Acharya A,eds.Corrosion and degradation of implant materials,ASTM STP684[C],Philadelphia.
[105]G.X.Shen,Y.C.Chen,L.Lin,C.J.Lin,D.Scantlebury,Study on a hydrophobic nano-TiO_2 coating and its properties for corrosion protection of metals[J],Electrochim.Acta,2005,50:5083.
[106]W.Brandle,C.Gendig,corrosion behaviour of hybrid coatings[J],thin solid films,1996, 290-291:343.
[107]Z.L.Tang,E H.Wang,W.T.Wu,Effect of Al_2O_3 and enamel coatings on 900℃ oxidation and hot corrosion behaviors of gamma-TiAl[J],Mater.Sci.Eng.A,2000,276:70.
[108]E.Szalkowska,J.Gluszek,J.Masalski,et al.,Structure and protective properties of TiO_2coatings obtained using the sol-gel technique[J],J Mater.Sci.Lett.,2001,20(6):495.
[109]J.Gluszek,J.Masalski,P.Furman,et al.,Structural and electrochemical examinations of PACVD TiO_2 films in ringer solution[J],Biomater.,1997,18:789.
[110]肖正伟,曾振欧,赵国鹏,田志斌,纳米TiO_2涂层的制备及其在金属腐蚀防护中的应用[J],腐蚀与防护,2007,28:33.
[111]Y.Ohko,S.Saitoh,T.Tatsuma,A.Fujishima,Photoelectrochemical Anticorrosion and Self-Cleaning Effects of a TiO_2 Coating for Type 304 Stainless Steel[J],J Electrochem.Soc.,2001,148:B24.
[112]徐群杰,齐航,丁斯婧,李春香,周小晶,光电化学技术在金属腐蚀研究中应用新进展[J],上海电力学院学报,2008,24(1):73.
[113]H.Park,K.Y.Kim,W.Choi,A novel photoelectrochemical method of metal corrosion prevention using a TiO2 solar panel[J],Chem.Comm.,2001,281.
[114]W.Choi,A.Termin,M.R.Hoffmann,Effects of metal-ion dopants on the photoeatalytic reactivity of quantum-sized TiO_2 particles[J],Angew.Chem.-Int.Edit.,1994,33:1091.
[115]籍宏伟,马万红,黄应平,赵进才,王正平,可见光诱导TiO_2光催化的研究进展[J],科学通报,2003,48:2199.
[116]廖学红,王小佳,Bi_2O_3/TiO_2纳米复合物的微波合成及光催化性质[J],纳米材料与结构,2008,45(4):209.
[117]Y.Suda,H.Kawasaki,T.Ueda,T.Ohshima,Preparation of nitrogen-doped titanium oxide thin film using a PLD method as parameters of target material and nitrogen concentration ratio in nitrogen/oxygen gas mixture[J],Thin Solid Films.,2005,475:337.
[118]H.Irie,S.Washizuka,Y.Watanabe,T.Kako and K.Hashimoto,Photoinduced hydrophilic and electrochemical properties of nitrogen-doped TiO_2 films[J],J.Electrochem.Sot.,2005,152:E351.
[119]S.Sato,R.Nakamura,S.Abe,Visible-light sensitization of TiO_2 photocatalysts by wet-method N doping[J],Appl.Catal.A-Gen.,2005,284:131.
[120]R.Asahi,T.Morikawa,T.Ohwaki,K.Aoki,Y.Taga,Visible-light photocatalysis in nitrogen-doped titanium oxides[J],Science,2001,293:269.
[121]S.Yin,H.Yamaki,Q.Zhang,M.Komatsu,J.Wang,Q.Tang,F.Saito,T.Sato,Mechanochemical synthesis of nitrogen-doped titania and its visible light induced NOx destruction ability[J],Solid State Ion,2004,172:205.
[122]庄惠芳,赖跃坤,李静,孙岚,林昌健,氮掺杂TiO_2纳米管阵列的制备及其可见光光电催化活性研究[J],电化学,2007,13:284.
[123]K.Shankar,K.C.Tep,G K.Mor,C.A.Grimes,An electrochemical strategy to incorporate nitrogen in nanostructured TiO_2 thin films:modification of bandgap and photoelectrochemical properties[J],J.Phys.D-Appl.Phys.,2006,39(11):2361.
[124]H.Irie,Y.Watanabe,K.Hashimoto,Carbon-doped anatase TiO_2 powders as a visible-light sensitive photocatalyst[J],Chem.Lett.,2003,32:772.
[125]C.H.Ao,S.C.Lee,Combination effect of activated carbon with TiO_2 for the photodegradation of binary pollutants at typical indoor air level[J],J.Photochem.Photobio.A-Chem.,2004,161:131.
[126]S.U.M.Khan,M.AI-Shahry,W.B.Ingler Jr.,Efficient photochemical water splitting by a chemically modified n-TiO_2[J],Science,2002,297:2243.
[127]T.Ohno,T.Mitsui,M.Matsumura,Photocatalytic activity of S-doped TiO_2 photocatalyst under visible light[J],Chem.Lett.,2003,32:364.
[128]T.Umebayashi,T.Yamaki,S.Tanaka,K.Asai,Visible light-induced degradation of methylene blue on S-doped TiO_2[J],Chem.Lett.,2003,32:330.
[129]T.Yamaki,T.Umebayashi,T.Sumita,S.Yamanoto,M.Maekawa,A.Kawasuso,H.Itoh,Fluorine-doping in titanium dioxide by ion implantation technique[J],Nucl.Instrum.Methods Phys.Res.B-Beam Interact.Mater.Atoms,2003,206:254.
[130]J.C.Yu,Ji.Yu,W.Ho,Z.Jiang,L.Zhang,Effects ofF-doping on the photocatalytic activity and microstructures of nanocrystalline TiO_2 powders[J],Chem.Mater.,2002,14:3808.
[131]H.M.Lu,T.Takata,Y.Lee,Photocatalytic activity enhancing for titanium dioxide by co-doping with bromine and chlorine[J],Chem.Mater.,2004,16:846.
[132]H.Y.Liu,L.Gao,Codoped futile TiO_2 as a new photocatalyst for visible light irradation[J],Chem.Lett.,2004,33:730.
[133]冯光建,刘素文,修志亮,俞娇仙,罗杰,氮离子和稀土离子共掺杂纳米TiO_2光催化性能的研究[J],中国稀土学报,2008,26(2):148.
[134]D.G.Huang,S.J.Liao,J.M.Liu,et al.,Preparation of visible light responsive N-F codoped TiO_2 photocatalyst by a sol-gel solvothermal method[J],J.Photochem.Photobio.A-Chem.,2006,184:282.
[135]C.C.Pan,J.C.S.Wu,Visible-light response Cr~(2+) doped TiO_(2-x)N_x photocatalyst[J],Mater.Chem.Phys.,2006,100(1):102.
[136]胡红坡,赵宏生,郭子斌,氮掺杂TiO_2光催化剂研究进展[J],材料导报,2008,22(2):39.
[137]T.Wu,G,Liu,J.Zhao,H,Hidaka,N.Serpone,Photoassisted degradation of dye pollutants V.self-photosensitized oxidative transformation of rhodamine B under visible light irradiation in aqueous TiO_2 dispersions[J],J.Phys.Chem.B,102:5845.
[138]S.S.Kim,J.H.Yum,Y.E.Sung,Improved performance of a dye-sensitized solar cell using a TiO_2/ZnO/Eosin Y electrode[J],Sol.Energy Mater.Sol.Cells,2003,79:495.
[139]Y.Amao,Y.Yamada,K.Aoki,Preparation and properties of dye-sensitized solar cell using chlorophyll derivative immobilized TiO_2 film electrode[J],J.Photochem.Photobio.A:Chem.,2004,164:47.
[140]R.Dillert,A.E.Cassano,R.Goslich,D.Bahnemann,Large scale studies in solar catalytic wastewater treatment[J],Catal.Today,1999,54:267.
[141]李明,方亚男,洪樟连,陈胡星,表面敏化改性纳米晶TiO_2的光谱响应特性研究及其应用进展[J],材料导报,2007,21:15.
[142]H.Kusama,H.Orita,H.Sugihara,DFT investigation of the band shift by nitrogen-containing heterocycle adsorption and implication on dye-sensitized solar cell performance[J],Sol.Energy Mater.Sol.Cells,2008,92:84.
[143]H.E.Chao,Y.U.Yun,H.U.Xingfang,A.Larbot,Effect of silver doping on the phase transformation and grain growth of sol-gel titania powder[J],J.European Ceram.Sot.,2003,23:1457.
[144]T.Lopez,R.Gomez,G.Pecci,P.Reyes,X.Bokhimi,O.Novaro,Effect of pH on the incorporation of platinum into the lattice of sol-gel titania phases[J],Mater.Lett.,1999,40:59.
[145]S.Rengaraj,X.Z.Li,Enhanced photoeatalytic activity of TiO_2 by doping with Ag for degradation of 2,4,6-trichlorophenol in aqueous suspension[J],J.Mol.Catal.A-Chem.,2006,243:60.
[146]J.Yu,J.Xiong,B.Cheng,S.Liu,Fabrication and characterization of Ag-TiO_2 multiphase nanocomposite thin films with enhanced photocatalytic activity[J],Appl.Catal.B-Environ.,2005,60:211.
[147]刘守新,曲振平,韩秀文,孙承林,包信和,Ag担载对TiO_2光催化活性的影响[J],催化学报,2004,25:133.
[148]C.M.Wang,A.Heller,H.Gerischer,Palladium catalysis of O_2 reduction by elections accumulated on TiO_2 particles during photoassisted oxidation of organic compounds[J],J.Am.Chem.Soc.,1992,114:5230.
[149]F.B.Li,X.Z.Li,The enhancement of photodegradation efficiency using Pt-TiO_2 catalyst [J],Chemosphere,2002,48:1103.
[150]史月萍,杨祝红,冯新,郑仲,陆小华,掺铂二氧化钛纤维光催化降解氯仿的研究[J],催化学报,2003,24:663.
[151]Berko,T.Biro,F.Solymosi,Formation and migration of carbon produced in the dissociation of CO on Rh/TiO_2(110)-(1×2) model catalyst:a scanning tunneling microscopy study[J],J.Phys.Chem.B,2000,104:2506.
[152]J.M.Macak,P.J.Barczuk,H.Tsuchiya,M.Z.Nowakowska,A.Ghicov,M.Chojak,S.Bauer,S.Virtanen,P.J.Kulesza,P.Schmuki,Self-organized nanotubular TiO_2 matrix as support for dispersed Pt/Ru nanoparticles:Enhancement of the electrocatalytic oxidation of methanol[J],Electrochem.Commun.,2005,7:1417.
[153]姚平平,甘玉琴,徐景坤,杨平,杜玉扣,银纳米颗粒负载复合膜的光催化活性及其光 电流性质[J],感光科学与光化学,2006,24(1):44.
[154]张彭义,余刚,蒋展鹏,半导体光催化剂及其改性技术进展[J],环境科学进展,1997,5(3):1.
[155]S.J.Liao,D.G Huang,D.H.Yu,Y.L.Su,G.Q.Yuan,Preparation characterization of ZnO/TiO_2,SO4~(2-)/ZnO/TiO_2 photocatalyst and their photocatalysis[J],J.Photochem.Photobiol.A-Chem.,2004,168:7.
[156]S.W.Ding,L.Y.Wang,S.Y.Zhang,Q.X.Zhou,Y.Ding,S.J.Liu,Y.C.Liu,Q.Y.Kang,Hydrothermal synthesis,structure and photocatalytic property of nano-TiO_2-MnO_2[J],Sci.China Set.B-Chem.,2003,46:542.
[157]E.Celik,A.Y.Yildiz,N.F.A.Azem,M.Tanoglu,M.Toparli,O.F.Emrullahoglu,I.Ozdemir,Preparation and characterization of Fe_2OP_3-TiO_2 thin films on glass substrate for photocatalytic applications[J],Mater.Sci.Eng.B-Solid State Mater.Adv.Technol.,2006,129:193.
[158]Y.Bcssekhouad,D.Robert,J.V.Weber,Bi_2S_3/TiO_2 and CdS/TiO_2 hctcrojunctions as an available configuration for photocatalytic degradation of organic pollutant[J],J.Photochem.Photobio.A- Chem.,2004,163:569.
[159]李芳柏,古国榜,李新军,万洪富,WO_3-TiO_2纳米材料的制备及光催化性能[J],物理化学学报,2000,16:997.
[160]T.Tatsuma,S.Satioh,P.Ngaotrakanwiwat,et al.,Energy storage of TiO_2-WO_3photocatalysis systems in the gas phase[J],Langmuir,2002,18:7777.
[161]T.Tatsuma,S.Satioh,Y.Ohko,et al.,TiO_2-WO_3 photoclcctrochcmical anticorrosion system with an energy storage ability[J],Chem.Mater.,2001,13:2838.
[162]Z.Y.Liu,K.Pan,M.J.Wang,et al.,Influence of the mixed ratio on the photocurrcnt of the TiO_2/SnO_2 composite photoelectrodes sensitized by mcrcurochrome[J],J.Photochem.Photobio.A:Chem.,2003,157:39.
[163]施利毅,古宏晨,李春忠,房鼎业,张怡,华彬,SnO_2-TiO_2复合光催化剂的制备和性能[J],催化学报,1999,20:338.
[164]R.Subasri,S.Deshpande,S.Seal,T.Shinohara,Evaluation of the Performance of TiO_2-CeO_2 Bilayer Coatings as Photoanodes for Corrosion Protection of Copper[J],Electrochem.Solid-State Lett.,2006,9(1):B1.
[165]张天永,朱丹丹,付强,赵进才,纳米光催化氧化降解染料污染物的进展[J],染料与染色,2004,41:238.
[166]T.Jin,T.Yamaguchi,K.Tanabe,Mechanism of acidity generation on sulfur-promoted metal oxides[J],J.Phys.Chem.1986,90:4794.
[167]杜金菊,徐安武,祝静艳,固体超强酸SO_4~(2-)/TiO_2制备及其光催化氧化性能[J],中山大学学报,2001,40:48.
[168]S.Yamazaki,S.Matsunaga,K.Hori,Photocatalytic degradation of trichloroethylene in water using TiO_2 pellets[J],Water Res.,2001,35:1022.
[169]查振林,罗亚田,纳米TiO_2的改性及应用研究[J],北方环境,2004,29:30.
[170]X.Li,C.Chen,J.Zhao,Mechanism of photodecomposition of H_2O_2 on TiO_2 surface under visible light irradiation[J],Langmuir,2001,17:4118.
[1]M.Koelsch,S.Cassaignon,J.F.Guillemoles,et al.,Comparison of optical and electrochemical properties of anatase and brookite TiO synthesized by the sol-gel method [J],Thin Solid Films,2002,403-404:312.
[2]J.X.Qiu,M.Y.Gu,Magnetic nanocomposite thin films of BaFe_(12)O_(19) and TiO_2 prepared by sol-gel method[J],Appl.Surf.Sci.,2005,252(4):888.
[3]T.Kasuga,M.Hiramatsu,A.Hoson,T.Sekino,K.Niihara,Formation of Titanium Oxide Nanotube[J],Langmuir,1998,14:3160.
[4]Q.Chen,W.Z.Zhou,G.H.Du,et al.,Trititanate nanotubes made via a single alkali treatment[J],Adv.Maters.,2002,14(17):1208.
[5]Y.F.Chen,C.Y.Lee,M.Y.Yeng,et al.,Preparing titanium oxide with various morphologies[J],2003,81(1):39.
[6]Sieber,B.Kannan,P.Schmuki,Self-assembled porous tantalum oxide prepared in H_2SO_4/HF electrolytes[J],Electrochem.Solid-State Lett.,2005,8:J10.
[7]H.Tsuchiya,J.M.Macak,I.Sieber,L.Taveira,A.Ghicov,K.Sirotna,P.Schmuki,Self-organized porous WO3 formed in NaF electrolytes[J],Electrochem.Commun.,2005,7:295.
[8]H.Tsuchiya,P.Schmuki,Thick self-organized porous zirconium oxide formed in H_2SO_4/NH_4F electrolytes[J],Eleetrochem.Commun.2004,6:1131.
[9]H.Tsuchiya and P.Schmuki,Self-organized high aspect ratio porous hafnium oxide prepared by electrochemical anodization[J],Electrochem.Commun.,2005,7:49.
[10]J.M.Macak,H.Tsuchiya,P.Schmuki,High-aspect-ratio TiO_2 nanotubes by anodization of titanium[J],Angewandte Chemie-Intemational Edition 2005,44(14):2100.
[11]D Birggs著,桂琳琳,黄惠忠,郭国霖译,X射线与紫外光电子能谱[M],北京:北京大学出版社,1984.
[12]陈体衔,实验电化学[M],科学出版社,北京,1995.
[13]M.Stem,A.L.Greary,Electrochemical polarization I.Atheoretical analysis of the shape of polarization curves[J],J.Electrochem.Sco.,1957,104:56.
[14]史美伦,交流阻抗谱原理及应用[M],国防工业出版社,北京,2001.
[15]曹楚南,张鉴清,电化学阻抗谱导论[M],科学出版社,北京,2002.
[16]H.Park,K.Y.Kim,W.Choi,A novel photoelectrochemical method of metal corrosion prevention using a TiO_2 solar panel[J],Chem.Comm.,2001,3:281.
[17]H.Park,K.Y.Kim,W.Choi,Photoelectrochemical approach for metal corrosion pretection using a semiconductor photoanode[J],J Phys.Chem.B,2002,106:4775.
[18]P.Schmuki,From Bacon to barriers:a review on the passivity of metals and alloys[J],J.Solid State Chem.,2002,6(3):145.
[19]G.Goodlet,S.Faty,S.Cardoso,P.P.Freitas,A.M.P.Simoes,M.G.S.Ferreira,M.D.Belo,The electronic properties of sputtered chromium and iron oxide films[J],Corro.Sci.,2004,46(6):1479.
[20]钱新明,宋庆,白玉白等,CdS敏化对TiO_2纳米薄膜电极光生电荷转移特性的影响[J],高等学校化学学报,2000,21(2):295.
[21]L.A.Lyon,J.T.Hupp,Energetics of the nanocrystalline titanium dioxide aqueous solution interface:Approximate conduction band edge variations between H-0=-10 and H-=+26[J],J.Phys.Chem.B,1999,103(22):4623.
[22]Z.H.Zhang,Y.Yuan,Y.J.Fang,L.H.Liang,H.C.Ding,G.Y.Shi,L.T.Jin,Photoelectrochemical oxidation behavior of methanol on highly ordered TiO_2 nanotube array electrodes[J],Journal of Electroanalytical Chemistry,2007,610(2):179.
[1]T.L.Metroke,L.Robert,et al.,Passivation of metal alloy using sol-gel-derived materials a review[J],Prog.Org.Coat.,2001,41:233.
[2]刘娅莉,于占锋,周树学,武利民,自组装单分子膜技术在金属防护中的应用[J],涂料工业,2004,34(9):27.
[3]L.S.Kasten,J.T.Grant,N.Grebasch,N.Voevodin,F.E.Amold,M.S.Donley,An XPS study of cerium dopants in sol - gel coatings for aluminum 2024-T3[J],Surf.Coat.Technol,2001,140(1):11.
[4]S.Hamdy,D.P.Butt,Environmentally compliant silica conversion coatings prepared by sol-gel method for aluminum alloys[J],Surf.Coat.Technol,2006,201(1-2):401
[5]F.J.Jing,F.Y.Jin,Y.W.Liu,et al.,Corrosion resistance and antithrombogenic behavior of La and Nd ion implanted stainless steels[J],J.Vac.Sci.Technol.,2006,24(5):1790.
[6]X.Q.Hu,C.H.Liang,N.B.Huang,Anticorrosion performance of carbon steel in 55%LiBr solution containing PMA/SbBr3 inhibitor[J],J.Iron Steel.Res.Int.,2006,13(4):56.
[7]C.S.Lin,C.S.Ke,H.Peng,Corrosion of CrN and CrN/TiN coated heat-resistant steels in molten A356 aluminum alloy[J],Surf.Coat.Technol.,2001,164:168.
[8]Y.Choi,N.I.Baik,J.S.Lee,et al.,Corrosion and wear properties of TiC/Ni-Mo composites produced by direct consolidation during a self-propagating high-temperature reaction[J],Compos.Sci.Technol.,2001,61(7):981.
[9]R.Caruso,F.Pla,A.D.Parralejo,et al.,Multilayer coatings preparation of zirconia-based by sol-gel route;microstructural and mechanical characterization[J],Revista De Metalurgia,2001,37(2):311.
[10]T.Kubota,N.Hara,K.Sugimoto,Real time spectroscopic ellipsometry study on growth processes of ZrO_2 thin films in metallorganic chemical vapor deposition[J],J.Electrochem.Sco.,2001,148(9):C632.
[11]G.X.Shen,Y.C.Chen,C.J.Lin,Corrosion protection of 316 L stainless steel by a TiO_2nanoparticle coating prepared by sol-gel method[J],Thin Solid Films,2005,489:130.
[12]K.Meinert,C.Uerpmann,J.Matschullat,G.K.Wolf,Corrosion and leaching of silver doped ceramic IBAD coatings on SS 316L under simulated physiological conditions[J],Surf.Coat.Technol,1998,103-104:58.
[13]J.Yuan,S.Tsujikawa,Characterization of Sol-Gel-Derived TiO_2 coating and their photoeffects on copper substrates[J],J.Electrochem.Sot.,1995,142:3444.
[14]A.Nakajima,S.Koizumi,T.Watanabe,et al.,Effect of repeated photo-illumination on the wettability conversion of titanium dioxide[J],J.Photochem.Photobiol.A:Chem.,2001,146(1-2):129.
[15]U.Diebold,The surface science of titanium dioxide[J],Surf.Sci.Rep.,2003,48(5-8):53.
[16] J. Huang, T. Shinohara, S. Tsujikawa, Zario-to-kankyo, 1997,46: 651.
[17] M. G. Mahmoud, R. G. Wang, M. Kato, et al., Influence of ultraviolet light irradiation on corrosion behavior of weathering steel with and without TiO_2Vcoating in 3 mass% NaCl solution [J], Scripta Mater., 2005, 53 (11): 1303.
[18] Y. Ohko, S. Saitoh, T. Tatsuma, A. Fujishima, Photoelectrochemical Anticorrosion and Self-Cleaning Effects of a TiO_2 Coating for Type 304 Stainless Steel [J], J Electrochem. Soc, 2001,148: B24.
[19] M. C. Li, S. Z. Luo, P. F. Wu, J. N. Shen, Photocathodic protection effect of TiO_2 films for carbon steel in 3% NaCl solutions [J], Electrochim. Acta, 2005, 50 (16-17): 3401.
[20] R. Subasri, S. Deshpande, S. Seal, T. Shinohara, Evaluation of the Performance of TiO_2-CeO_2 Bilayer Coatings as Photoanodes for Corrosion Protection of Copper [J], Electrochem. Solid-State Lett., 2006,9 (1): B1.
[21] E. Szalkowska, J. Gluszek, J. Masalski, et al., Structure and protective properties of TiO_2 coatings obtained using the sol-gel technique [J], J. Mater. Sci. Lett., 2001,20 (6): 495.
[22] G. X. Shen, Y. C. Chen, L. Lin, C. J. Lin, D. Scantlebury, Study on a hydrophobic nano-TiO_2 coating and its properties for corrosion protection of metals [J], Electrochim. Acta, 2005, 50: 5083.
[23] M. R. Hoffmann, S. T. Martin, W. Choi, D. W. Bahnemann, Environmental Applications of Semiconductor Photocatalysis [J], Chem. Rev., 1995,95: 69.
[24] L. Linsebigler, G. Q. Lu, J. T. Yates, Photocatalysis on TiO_2 Surfaces: Principles, Mechanisms, and Selected Results [J], Chem. Rev., 1995,95: 735.
[25] Y. J. Chen, D. D. Dionysiou, Correlation of structural properties and film thickness to photocatalytic activity of thick TiO_2 films coated on stainless steel [J], Appl. Catal. B: Environ., 2006, 69 (1-2): 24.
[26] H. M. Yates, M. G. Nolan, D. W. Sheel, et al., The role of nitrogen doping on the development of visible light-induced photocatalytic activity in thin TiO_2 films grown on glass by chemical vapour deposition [J], J. Photochem. Photobiol. A: Chem, 2006, 179 (1-2):213.
[27] C. K. Jung, I.-S. Bae, Y.-H. Song, J.-H. Boo, Plasma surface modification of TiO_2 photocatalysts for improvement of catalytic efficiency [J], Surf. Coat. Technol, 2005, 200 (5-6): 1320.
[28] A. Kitiyanan, S. Ngamsinlapasathian, S. Pavasupree, S. Yoshikawa, The preparation and characterization of nanostructured TiO_2-ZrO_2 mixed oxide electrode for efficient dye-sensitized solar cells [J], J. Solid State Chem., 2005, 178 (4): 1044.
[29] K. S. Guan, Relationship between photocatalytic activity, hydrophilicity and self-cleaning effect of TiO_2/SiO_2 films [J], Surf. Coat. Technol, 2005,191 (2-3): 155.
[30] K. R. Wu, J. J. Wang, W. C. Liu, et al., Deposition of graded TiO_2 films featured both hydrophobic and photo-induced hydrophilic properties [J], Appl. Surf. Sci., 2006, 252 (16): 5829.
[31]X.Z.Ding,X.H.Liu,Synthesis and microstructure control of nanocrystalline titania powders via a sol-gel process[J],Mater.Sei.Eng.A,1997,224(1-2):210.
[32]Bertoti,Characterization of nitride coatings by XPS[J],Surf.Coat.Technol.,2002,151:194.
[33]熊兆贤,无机材料研究方法:合成制备、分析表征与性能检测[M],厦门:厦门大学出版社,2001.
[34]M.J.Velasco,F.Rubio,J.Rubio,et al.,DSC and FT-IR analysis of the drying process of titanium alkoxide derived precipitates[J],Thermochim.Acta,1999,326(1-2):91.
[35]S.Doeu,M.Henry,C.Sanehez,J.Livage,J.Non-Cryst.Solids,1987,89:206.
[36]R.Urlaub,U.Posset,R.Thull,FT-IR spectroscopic investigations on sol-gel-derived coatings from acid-modified titanium alkoxides[J],J.Non-Cryst.Solids,2000,265(3):276.
[37]S.K.Samantaray,T.Mishra,K.M.Parida,Studies on anion promoted Titania 2:Preparation,characterisation and catalytic activity towards aromatic alkylation over sulfated titania[J],J.Mol.Catal.A:Chem.,2000,156(1-2):267.
[38]E.Ortiz-Islas,R.Gomez,T.Lopez,et al.,Effect of the crystallite size in the structural and textural properties of sulfated and phosphated titania[J],Appl.Surf.Sci.,2005,252(3):807.
[39]沈俊,罗妮,张明俊,田从学,张昭,介孔TiO_2-SO_4~(2-)的合成及表征[J],催化学报,2007,28(3):264.
[40]尹荔松,陈永平,谭敏,范海陆,硫酸处理对TiO_2薄膜光催化降解亚甲基兰溶液的影响[J],电子器件,2007,30(6):2007.
[4l]戴文新,王绪绪,付贤智,刘平,林华香,卤素离子对TiO_2薄膜光致亲水性的影响[J],物理化学学报,2005,21(11):1274.
[42]R.Asahi,T.Morikawa,T.Ohwaki,K.Aoki,Y.Taga,Visible-light photocatalysis in nitrogen-doped titanium oxides[J],Science,2001,293:269.
[43]J.Q.Li,L.Zheng,L.P.Li,Y.Z.Xian,L.T.Jin,Fabrication of TiO_2/Ti electrode by laser-assisted anodic oxidation and its application on photoelectrocatalytic degradation of methylene blue[J],J.Hazard.Mater.B,2007,39:72.
[44]吕红辉,汤钧,白玉白,钱新明,董绍俊,TiO_2纳米晶薄膜电极的瞬态光电流特性[J],吉林大学自然科学学报,2001,3:99.
[45]吕红辉,文子,刘艳梅,钱新明,汤心颐,白玉白,表面态对TiO_2纳米晶薄膜光电流的影响[J],吉林大学自然科学学报,2001,2:95.
[46]F.Cao,G.Oskam,P.C.Searson,et al.,Electrical and Optical Properties of Porous anocrystalline TiO_2 Film[J],J.Phys.Chem.,1995,99:11974.
[47]S.Sodergren,A.Hagfeldf,J.Dsson,et al.,Theoretical Models for the Action Spectrum and the Current-Voltage Characteristics of Microporous Semiconductor Films in Photoelect rochemical Cells[J],J Phys.Chem,1994,98:5552.
[48]杨大纲,李秋叶,张顺利,金振声,张治军,二氧化钛纳米膜电极的形貌和光电化学性质[J],化学研究,2004,15(4):6.
[49]Y.B.Xie,L.M.Zhou,H.T.Huang,Enhanced photoelectrochemical current response of titania nanotube array[J],Mater.Lett.,2006,60:3558.
[50]姚平平,甘玉琴,徐景坤,杨平,杜玉扣,银纳米颗粒负载复合膜的光催化活性及其光电流性质[J],感光科学与光化学,2006,24(1):44.
[51]李贺,姚素薇,张卫国,王宏智,贲宇恒,二氧化钛纳米管阵列电极的光电化学性能研究[J],稀有金属材料与工程,2007,36(10):1749.
[52]S.U.M.Khan,M.Al-Shahry,W.B.Ingler Jr.,Efficient photochemical water splitting by a chemically modified n-TiO_2[J],Science,2002,297:2243.
[53]T.Zajac,M.Radecka,M.Rekas,Photoelectrochemical properties of Nb-doped titanium dioxide[J],Physica B,2007,399:55.
[54]谢建辉,吴荫顺,朱日彰,316L不锈钢在模拟体液内腐蚀疲劳裂纹萌生和扩展过程中的应力的作用[J],中国腐蚀与防护学报,1997,17(1):31.
[55]梁成浩,牟战旗,模拟体液中3 16L不锈钢和Co-Cr合金生物材料腐蚀行为研究[J],中国生物医学工程学报,2000,19(4):432.
[56]汪轩义,吴荫顺,张琳等,3 16L不锈钢钝化膜在CI介质中的防蚀机制[J],腐蚀科学与防护技术,2000,12(6):311.
[57]B.S.Liu,X.J.Zhao,L.P.Wen,A simple route to the water-repellent surface based on chemical N modified Ti-O structure films[J],Surf.Coat.Technol,2006,201(6):3606.
[58]王宜超,刘中清,燕青芝,李振华,葛昌纯,可见光响应氮掺杂TiO_2光催化剂的水热法制备与性能[J],北京科技大学学报,2008,30(5):540.
[59]C.Xie,Q.J.Yang,Z.L.Xu,X.J.Liu,Y.G.Du,New Route to Synthesize Highly Active Nanocrystalline Sulfated Titania-Silica:Synergetic Effects between Sulfate Species and Silica in Enhancing the Photocatalysis Efficiency[J],J.Phys.Chem.B,2006,110:8587.
[60]N.C.Saha,H.G.Tompkins,Titanium nitride oxidation chemistry:An x-ray photoelectron spectroscopy study[J],J.Appl.Phys.,1992,72:3072.
[61]C.E.B.Marino,P.A.P.Nascente,S.R.Biaggio,R.C.Rocha-Filho,N.Bocchi,XPS characterization of anodic titanium oxide films grown in phosphate buffer solutions[J],Thin Solid Films,2004,468(1-2):109.
[62]Justicia,P.Ordej6n,G.Canto,J.L.Mozos,J.Fraxedas,G.A.Battiston,R.Gerbasi,A.Figueras,Designed Self-Doped Titanium Oxide Thin Films for Efficient Visible-Light Photocatalysis[J],Adv.Mater.,2002,14(19):1399.
[1]J.Yuan,S.Tsujikawa,Characterization of Sol-Gel-Derived TiO_2 coating and their photoeffects on copper substrates[J],J.Electrochem.Soc.,1995,142:3444.
[2]T.Imokawa,R.Fujisawa,A.Suda,et al.,Zairyo-to-Kankyo,1994,43:482-486(in Japanese).
[3]T.Konishi,S.Tsujikawa,Zairyo-to-Kankyo,1997,46:709-716(in Japanese).
[4]J.Yuan,S.Tsujikawa,Zairyo-to-Kankyo,1995,44:524-542(in Japanese).
[5]J.Huang,T.Shinohara,S.Tsujikawa,Zairyo-to-Kankyo,1997,46:651-661(in Japanese).
[6]J.Huang,T.Konishi,T.Shinohara,et al,Zairyo-to-Kankyo,1998,47:193-199(in Japanese).
[7]T.Fukuda,N.Kubota,M.Ayabe,et al,Fushoku Boshuoku Koenshu 1996,101-104(in Japanese).
[8]Park H,Kyoo Y K,Choi W,A novel photoelectrochemical method of metal corrosion using a TiO_2 solar panel[J],Chem.Comm.,2001,281.
[9]J.Huang,T.Shinohara,S.Tsujikawa,Zairyo-to-Kankyo,1999,48:575-582.
[10]T.Tatsuma,S.Saitoh,Y.Ohko,et al.,TiO_2-WO_3 photoelectrochemical anticorrosion system with an energy storage ability[J],Chem.Mater.,2001,13:2838.
[11]T.Tatsuma,S.Satioh,P.Ngaotra kanwiwat,et al.,Energy.storage of TiO_2-WO_3photocatalysis systems in the gas phase[J],Langmuir,2002,18:7777.
[12]Z.Y.Liu,K.Pan,M.J.Wang,et al.,Influence of the mixed ratio on the photocurrent of the TiO_2/SnO_2 composite photoelectrodes sensitized by mercurochrome[J],J.Photochem.Photobio.A:Chem.,2003,157:39.
[13]S.Raghavan,S.Tadashi,Investigations on SnO_2-TiO_2 composite photoelectrodes for corrosion protection[J],Electrechem.Commun.,2003,5:897.
[14]R.Subasri,S.Deshpande,S.Seal,T.Shinohara,Evaluation of the Performance of TiO_2-CeO_2 Bilayer Coatings as Photoanodes for Corrosion Protection of Copper[J],Electrochem.Solid-State Lett.,2006,9(1):B1.
[15]H.Park,Y.K.Kim,W.Choi,Photoelectrochemical approach for metal corrosion prevention using a semiconductor photoanode[J],J.Phys.Chem.B,2002,106:4775.
[16]李大成,周大利,任成军,刘恒,张萍,张云,龚家竹,纳米TiO_2的修饰改性[J],材料导报,2003,17(12):52.
[17]沈广霞,纳米TiO_2复合膜的制备及双重防腐蚀功能的研究[D],厦门大学博士学位论文,2004.
[18]李贺,姚素薇,张卫国,王宏智,贲宇恒,二氧化钛纳米管阵列电极的光电化学性能研究[J],稀有金属材料与工程,2007,36(10):1749.
[19]崔晓莉,江志裕,紫外光照下纳米TiO_2电极的电化学行为[J],物理化学学报,2002,18(11):1014.
[20]刘鸿,吴鸣,吴含进,孙福侠,郑云,李文钊,氢处理二氧化钛的光催化性能及电化学阻抗谱[J],物理化学学报,2001,17(3):286.
[21]张青龙,沈毅,吴国友,李真,朱华,纳米TiO_2的掺杂改性及应用进展研究[J],稀有金属快报,2005,24(12):6.
[22]许佩瑶,吴扬,李海宗纳米TiO_2的改性技术及其应用前景[J],广东化工,2005,9:37.
[23]王静,赵珊,池勇志,费学宁,TiO_2光催化剂改性技术研究新进展[J],天津城市建设学院学报,2006,12(2):116.
[24]F.E.Ghodsi,E Z.Tepehan,t2 GTepehan,Optical and electrochromie properties of sol-gel made CeO_2 TiO_2 thin films[J],Eleetroehim.Acta,1999,44:3127.
[25]J.Arana,O.González Díaz,M.Miranda Saracho,J.M.Dona Rodriguez,J.A.Herrera Meliáin,J.Pérez Pena,Photocatalytic degradation of formic acid using Fe/TiO_2 catalysts:the role of Fe~(3+)/Fe~(2+) ions in the degradation mechanism[J],Appl.Catal.B,2001,32(1-2):49.
[26]李振宏,伍虹,我国稀土应用的现状与前景[J],稀土,1996,17(6):48.
[27]罗改霞,路战胜,杨宗献,M(Al,Cu,Pd,Pt,Rh,Zr)掺杂CeO_2的第一性原理研究[J],中国稀土学报,2007,25:40.
[28]王嵩龄,刘钧云,贾江涛,廖春生,严纯华,大粒度、高表观比重氧化铈的合成[J],中国稀土学报,2008,26(1):117.
[29]Lars Baetz Reutergadh,Mallika Iangphasuk,Photocatalytic decolourization of reactive azo dye:A comparison between TiO_2 and us photoeatalysis[J],Chemosphere,1997,35(3):585.
[30]F.E.Ghodsi,F.Z.Tepehan,G.G.Tepehan,Optical and electrochromic properties of sol-gel made CeO_2-TiO_2 thin films[J],Eleetroehim.Acta,1999,44(18):3127.
[31]岳林海,水淼,徐铸德,郑遗凡,稀土掺杂二氧化钛的相变和光催化活性[J],浙江大学学报(理学版),2000,27(1):69.
[32]于向阳,程继健,杜永娟,稀土元素掺杂对TiO_2相组成和光催化性能的影响[J],玻璃与搪瓷,2000,28(2):15.
[33]钱斯文,王智宇,王民权,La~(3+)掺杂对纳米TiO_2微观结构及光催化性能的影响[J],材料与工程学报,2003,21(1):48.
[34]刘奎仁,于会文,韩庆,魏德洲,稀土掺杂TiO_2光催化材料的制备和性能[J],材料研究学报,2006,20(5):459.
[35]尹荔松,朱剑,闻立时,杨硕,谢琦谓,稀土-金属共掺杂纳米TiO_2的制备及其光催化性能[J],世界科技研究与发展,2008,30(2):122.
[36]孙海健,刘惠玲,铈掺杂TiO_2/Ti光电极制备及可见光下光电催化性能的研究[J],无机材料学报,2007,22(6):1065.
[37]B.S.Liu,X.J.Zhao,N.Z.Zhang,et al.,Photocatalytic mechanism of TiO_2-CeO_2 films prepared by magnetron sputtering under UV and visible light[J],Surf.Sci,2005,595(1-3):203.
[38]刘雪峰,张利,涂铭旌,载铈纳米TiO_2粉体的制备及其反射光谱特性研究[J],光谱学与光谱分析,2005,25(2):274.
[39]Z.L.Liu,B.Guo,L.Hong,et al.,Preparation and characterization of cerium oxide doped TiO_2 nanoparticles[J],J.Phys.Chem.Solids,2005,66(1):161.
[40]雷波,徐悦华,郭来秋,罗海燕,Ce-TiO_2/硅藻土的制备、表征及其光催化活性[J],中国有色金属学报,2007,17(5):795.
[41]P.Stefanov,G.Tanasova,D.Stoychev,T.Marinova,Electrochemical deposition of CeO_2 on ZrO_2 and Al_2O_3 thin films formed on stainless steel[J],Surf.Coat.Technol.2004,180 -181:446.
[42]S.Y.Zheng,A.M.Andersson-Faldt,B.Stjema,C.G.Granqvist,Appl.Optics,1993,32:6303.
[43]R.M.Bueno,J.M.Martinez-Duart,M.Hernandez-Velez,L.Vazquez,Optical and structural characterization of rf sputtered CeO_2 thin films[J],J.Mater.Sci.,1997,32(7):1861.
[44]M.S.Mattsson,A.Azens,G.A.Niklasson,C.G.Granqvist,J.Purans,Li intercalation in transparent Ti-Ce oxide films:Energetics and ion dynamics[J],J.Appi.Phys.1997,81(9):6432.
[45]S.Kanakaraju,S.Mohan,A.K.Sood,Optical and structural properties of reactive ion beam sputter deposited CeO_2 films[J],Thin Solid Films,1997,305(1-2):191.
[46]T.Ami,M.Suzuki,MOCVD growth of(100)-oriented CeO_2 thin films on hydrogen-terminated S si(100) substrates[J],Mater.Sci.Eng.B,1998,54(1-2):84.
[47]K.Jarrendahl,H.Arwin,Multiple sample analysis of spectroscopic ellipsometry data of semi-transparent films[J],Thin Solid Films,1998,313-314:114.
[48]F.Varsano,F.Decker,E.Massetti,F.Cardellini,A.Licciuli,Optical and electrochemical properties of cerium-zirconium mixed oxide thin films deposited by sol-gel and r.f.sputtering[J],Electrochim.Acta,1999,44(18):3149.
[49]S.Logothetidis,P.Patsalas,E.K.Evangelou,N.Konofaos,I.Tsiaoussis,N.Frangis,Dielectric properties and electronic transitions of porous and nanostructured cerium oxide films[J],Mater.Sci.Eng.B,2004,109(1-3):69.
[50]P.Baudry,A.C.M.Rodrigues,M.Aegerter,L.O.Bulhoes,Dip-coated TiO_2-CeO_2 films as transparent counter-electrode for transmissive electrochromic devices[J],J.Non Crys.Solids 1990,121(1-3):319.
[51]W.B.Carter,G.W.Book,T.A.Policy,D.W.Stollberg,J.M.Hampikian,Combustion chemical vapor deposition of CeO_2 film[J],Thin Solid Films,1999,347(1-2):25.
[52]K.D.Develos,M.Kusunoki,S.Ohshima,Studies on the surface morphology and orientation of CeO_2 films deposited by pulsed laser ablation [J], Jpn. J. Appl. Phys. 1998,37 (11): 6161.
[53] U. L. Stangar, U. Opara, B. Orel, Structural and electrochemical properties of sol-gel derived Mo: CeO_2, Si: Mo: Ce)_2 and Si: CeO_2 nanocrystalline films for electrochromic devices [J], J. Sol-Gel. Sci. Tech., 1997, 8 (1-3): 751.
[54] Z. C. Orel, Spectroscopic characterization of sol-gel dip-coating CeO_2 and CeO_2/SnO_2 films [J], Appl. Spectroscopy, 1999, 53 (2): 241.
[55] U. O. Krasovec, B. Orel, R. Reisfeld, Electrochromism of CeVO_4 and Ce/V-oxide ion-storage films prepared by the sol-gel route [J], Electrochem. Solid-State Lett., 1998, 1 (2): 104.
[56] U. O. Krasovec, B. Orel, A. Surca, N. Bukovec, R. Reisfeld, Structural and spectroelectrochemical investigations of tetragonal CeVO_4 and Ce/V-oxide sol-gel derived ion-storage films [J], Solid State Ionics, 1999,118 (3-4): 195.
[57] G Picardi, F. Varsano, F. Decker, U. O. Krasovec, A. Surca, B. Orel, Electrochemical characterization of optically passive CeVO_4 counterelectrodes [J], Electrochim. Acta, 1999, 44 (18): 3157.
[58] A. Vermaa, A. K. Bakhshib, S. A. Agnihotry, Effect of citric acid on properties of CeO_2 films for electrochromic windows [J], Sol. Energy Mater. Sol. Cells, 2006, 90 (11): 1640.
[59] M. L. Lavcevic, A. Turkovic, P. Dubcek, S. Bernstorff, Nanostructured CeO_2 thin films: A SAXS study of the interface between grains and pores [J], Thin Solid Films, 2007, 515 (14):5624.
[60] J. P. Gomilsek, I. K. Skofic, N. Bukovec, A. Kodre, X-Ray absorption study of CeO_2 and Ce/V mixed oxide thin films obtained by sol-gel deposition [J], Thin Solid Films, 2004,446 (1):117.
[61] G. S. Wu, T. Xie, X. Y. Yuan, B. C. Cheng, L. D. Zhang, An improved sol-gel template synthetic route to large-scale CeO_2 nanowires [J], Mater. Res. Bulletin, 2004, 39 (7-8):1023.
[62] N. Ozer, Optical properties and electrochromic characterization of sol-gel deposited ceria films [J], Sol. Energy Mater. Sol. Cells, 2001,68 (3-4): 391.
[63] A. Turkovic, P. Dubcek, S. Bernstorff, Grazing-incidence small-angle and wide-angle scattering of synchrotron radiation on nanosized CeO_2 thin films [J], Mater. Sci. Eng. B,1999, 58 (3): 263.
[64] A. Verma, A. K. Bakhshi, S. A. Agnihotry, Effect of different precursor sols on the properties of CeO_2-TiO_2 films for electrochromic window applications [J], Electrochim. Acta, 2006, 51 (22): 4639.
[65] Z. Assefa, R. G. Haire, D. L. Caulder, D. K. Shuh, Correlation of the oxidation state of cerium in sol-gel glasses as a function of thermal treatment via optical spectroscopy and XANES studies [J], Spectroc. Acta Pt. A-Molec. Biomolec. Spectr., 2004,60 (8-9): 1873.
[66]T.Ohsaka,Temperature dependence of the Raman spectrum anatase TiO_2[J],Jpn.J.Phys.Soc.,1980,48:1661.
[67]梁德荣,纳米TiO_2的制备及其光催化性能的研究[J],山西化工,2008,28(3):17.
[68]Y.B.Xie,C.W.Yuan,Rare earth ion modified TiO_2 sols for photocatalysis application under visible light excitation[J],Rare Metals,2004,23(1):20.
[69]奚丽荷,江海军,朱忠其,张瑾,柳清菊,CeO_2掺杂TiO_2光催化剂的性能研究[J],功能材料,2007,38(7):1146.
[70]吕卫星,方方,郭卫华,何平笙,LB膜法制备Y_2O_3掺杂的CeO_2超薄陶瓷膜的X光电子能谱(XPS)研究[J],光谱学与光谱分析,2002,22(1):16.
[71]杜新华,刘振祥,谢侃,溅射二氧化铈氧敏薄膜的XPS研究[J],功能材料,1998,29:6.
[72]F.B.Li,X.Z.Li,M.F.Hou,K.W.Cheah,W.C.H.Choy,Enhanced photocatalytic activity of Ce~(3+)-TiO_2 for 2-mercapto-benzothiazole degradation in aqueous suspension for odour control[J],Appl.Catal.A,2005,285(1-2):181.
[73]F.Zhang,P.Wang,J.Koberstein,S.Khalid,S.W.Chan,Cerium oxidation state in ceria nanoparticles studied with X-ray photoelectron spectroscopy and absorption near edge spectroscopy[J],Surf.Sci.,2004,563(1-3):74.
[74]庞松,侯书恩,张涛,刘贺年,Y_2O_3和CeO_2复合掺杂ZrO_2纳米晶的制备与表征[J],中国稀土学报,2007,25(6):755.
[75]W.Zhao,W.Ma,C.Chen,J.C.Zhao,Z.C.Shuai,Efficient degradation of toxic organic pollution with Ni_2O_3/TiO_2-xBx under visible light irradiation[J],J.Am.Chem.Soc.,2004,126(15):4782.
[76]赵燕宁,刘岗,孙成华,李峰,逯高清,成会明,硼在纳米晶氧化钛中的掺杂状态[J],材料研究学报,2008,22(2):125.
[77]魏凤玉,倪良锁,硼硫共掺杂TiO_2的光催化性能及掺杂机理[J],催化学报,2007,28(10):905.
[78]于夏,白令君,电子顺磁共振谱仪Bruker EMX EPR简介[J],现代仪器,2001,3:21.
[79]L.Pidol,O.Guillot-Noe"l,A.Kahn-Harari,B.Viana,D.Pelenc,D.Gourier,EPR study of Ce~(3+) ions in lutetium silicate scintillators Lu_2Si_2O_7 and Lu_2SiO_5[J],Journal of Physics and Chemistry of Solids,2006,67:643.
[1]肖正伟,曾振欧,赵国鹏,邱国平,304不锈钢上纳米TiO_2涂层的制备与防腐蚀性能研究[J],电镀与涂饰,2007,26(7):35.
[2]肖正伟,曾振欧,赵国鹏,纳米TiO_2涂层在低碳钢上的防腐蚀性能[J],电镀与涂饰,2006,25(12):33.
[3]Yoshihisa,S.Shuichi,T.Tetsu,F.Akira,Photoelectrochemical Anticorrosion and Self-Cleaning Effects of a TiO_2 Coating for Type 304 Stainless Steel[J],J.Electrochem.Soc.,2001,148(1):B24.
[4]T.Tetsu,S.Shuichi,O.Yoshihisa,F.Akira,TiO_2-WO_3 Photoelectrochemical Anticorrosion System with an Energy Storage Ability[J],Chem.Mater.,2001,13:2838.
[5]G.X.Shen,Y.C.Chen,C.J.Lin,Corrosion protection of 316L stainless steel by a TiO_2nanoparticle coating prepared by sol-gel method[J],Thin Solid Films,2005,489:130.
[6]S.Raghavan,S.Tadashi,M.Kazuhiko,TiO_2-Based Photoanodes for Cathodic Protection of Copper[J],J.Electrochem.Soc.,2005,152(3):B105.
[7]S.Raghavan,S.Tadashi,Investigations on SnO_2-TiO_2 composite photoelectrodes for corrosion protection[J],Electrochem.Commun.,2003,5:897.
[8]S.Raghavan,D.Sameer,S.Sudipta,S.Tadashi,Evaluation of the Performance of TiO_2-CeO_2 Bilayer Coatings as Photoanodes for Corrosion Protection of Copper[J],Electrochem.Solid State Lett.,2006,9(1):B1.
[9]Park,Y.K.Kim,W.Choi,Photoelectrochemical approach for metal corrosion prevention using a semiconductor photoanode[J],J.Phys.Chem.B,2002,106:4775.
[10]M.C.Li,S.Z.Luo,P.F.Wu,J.N.Shen,Photocathodic protection effect of TiO_2 films for carbon steel in 3%NaCl solutions[J],Electrochim.Acta,2005,50:3401.
[11]H.B.Li,X.D.Bai,Y.H.Ling,J.Li,D.L.Zhang,J.S.Wang,Fabrication of Titania Nanotubes as Cathode Protection for Stainless Steel[J],Electrochem.Solid State Lett.,2006,9(5):B28.
[12]J.Li,H.Yun,C.J.Lin,A Photoelectrochemical Study of n-Doped TiO_2 Nanotube Arrays as the Photoanodes for Cathodic Protection of SS[J],J.Electrochem.Soc.,2007,154(11):C631.
[13]D.Gong,C.A.Grimes,O.K.Varghese,W.C.Hu,R.S.Singh,Z.Chen,E.C.Dickey,Titanium oxide nanotube arrays prepared by anodic oxidation[J],J.Mater.Res.,2001,16(12):3331.
[14]T.Kasuga,M.Hiramatsu,A.Hoson,T.Sekino,K.Niihara,Formation of titanium oxide nanotube[J],Langmuir,1998,14(12):3160.
[15]T.Kasuga,M.Hiramatsu,A.Hoson,T.Sekino,K.Niihara,Titania nanotubes prepared by chemical processing[J],Adv.Mater.,1999,11(15):1307.
[16] G. Demazeau, Solvothermal processes: a route to the stabilization of new materials [J], J. Mater. Chem., 1999, 9 (1): 15.
[17] Z. Y. Yuan, W. Zhou, B. L. Su, Hierarchical interlinked structure of titanium oxide nanofibers [J], Chem. Commun., 2002,11:1202.
[18] Q. Chen, W. Zhou, G.H. Du, L.M. Peng, Trititanate nanotubes made via a single alkali treatment [J], Adv. Mater., 2002,14 (17) : 1208.
[19] X. Sun, Y. Li, Synthesis and characterization of ion-exchangeable titanate nanotubes [J], Chem. Eur. J., 2003,9 (10): 2229.
[20] B. D. Yao, Y. F. Chan, X. Y. Zhang, W. F. Zhang, Z.Y. Yang, N. Wang, Formation mechanism of TiO_2 nanotubes [J], Appl. Phys. Lett., 2003, 82 (2) : 281.
[21] Y. V. Kolen'ko, B. R. Churagulov, M. Kunst, L. Mazerolles, C. Colbeau-Justin, Photocatalytic properties of titania powders prepared by hydrothermal method [J], Appl. Catal. B: Environ., 2004, 54 (1): 51.
[22] Y. V. Kolen'ko, V. D. Maximov, A. V. Garshev, P. E. Meskin, N. N. Oleynikov, B. R. Churagulov, Hydrothermal synthesis of nanocrystalline and mesoporous titania from aqueous complex titanyl oxalate acid solutions [J], Chem. Phys. Lett., 2004, 388 (4-6): 411.
[23] H. G. Yu, J. G. Yu, B. Cheng, M. H. Zhou, Effects of hydrothermal post-treatment on microstructures and morphology of titanate nanoribbons [J], J. Solid State Chem., 2006, 179 (2): 349.
[24] J. G. Yu, G. H. Wang, B. Cheng, M. H. Zhou, Effects of hydrothermal temperature and time on the photocatalytic activity and microstructures of bimodal mesoporous TiO_2 powders [J], Appl. Catal. B: Environ., 2007, 69 (3-4): 171.
[25] D. V. Bavykin, V. N. Parmon, A. A. Lapkin, The effect of hydrothermal conditions on the mesoporous structure of TiO_2 nanotubes [J], J. Mater. Chem., 2004, 14 (22): 3370.
[26] M. Yada, Y. Inoue, M. Uota, T. Torikai, T. Watari, I. Noda, T. Hotokebuchi, Plate, wire, mesh, microsphere, and microtube composed of sodium titanate nanotubes on a titanium metal template [J], Langmuir, 2007, 23 (5): 2815.
[27] Z. R. Tian, J. A.Voigt, J. Liu, B. Mckenzie, H. F. Xu, Large oriented arrays and continuous films of TiO_2-based nanotubes [J], J. Am. Chem. Soc, 2003, 125 (41): 12384.
[28] Y. P. Guo, N-H. Lee, H-J. Oh, C-R. Yoon, K-S. Park, H-G. Lee, K-S. Lee, S-J. Kim, Structure-tunable synthesis of titanate nanotube thin films via a simple hydrothermal process [J], Nanotechnology, 2007, 18 (29): 295608.
[29] G. H. Du, Q. Chen, R. C. Che, Preparation and structure analysis of titanium oxide nanotubes [J], Appl. Phys. Lett., 2001, 79 (22): 3702.
[30] R. Z. Ma, Y. Bando, T. Sasaki, Nanotubes of lepidocrocite titanates [J], Chem. Phys. Lett., 2003, 380 (5-6): 577.
[31] Y. B. Mao, S. S. Wong, Size- and shape-dependent transformation of nanosized titanate into analogous anatase titania nanostructures [J], J. Am. Chem. Soc, 2006, 128 (25): 8217.
[32]R.Armstrong,G.Armstrong,J.Canales,P.G.Bruce,TiO_2-B nanowires[J],Angew.Chem.Int.Ed.,2004,43(17):2286.
[33]M.Zhang,Z.S.Jin,J.W.Zhang,X.Y.Guo,J.J.Yang,W.Li,X.D.Wang,Z.J.Zhang,Effect of annealing temperature on morphology,structure and photocatalytic behavior of nanotubed H_2Ti_2O_4(OH)_2[J],J.Mol.Catal.A,2004,217(1-2):203.
[34]R.Yoshida,Y.Suzuki,S.Yoshikawa,Syntheses of TiO_2(B) nanowires and TiO_2 anatase nanowires by hydrothermal and post-heat treatments[J],J.Solid State Chem.,2005,178(7):2179.
[35]R.Yoshida,Y.Suzuki,S.Yoshikawa,Effects of synthetic conditions and heat-treatment on the structure of partially ion-exchanged titanate nanotubes[J],Mater.Chem.Phys.,2005,91(2-3):409.
[36]Thorne,A.Kruth,D.Tunstall,J.T.S.Irvine,W.Z.Zhou,Formation,structure,and stability of titanate nanotubes and their proton conductivity[J],J.Phys.Chem.B,2005,109(12):5439.
[37]C.Tsai,H.Teng,Structural features of nanotubes synthesized from NaOH treatment on TiO_2 with different post-treatments[J],Chem.Mater.,2006,18(2):367.
[38]Y.B.Mao,M.Kanungo,H-B.Tirandai,S.S.Wong,Synthesis and growth mechanism of titanate and titania one-dimensional nanostructures self-assembled into hollow micrometer-scale spherical aggregates[J],J.Phys.Chem.B,2006,110(2):702.
[39]Y.K.Lai,L.Sun,C.Chen,C.G.Nie,J.Zuo,C.J.Lin,Optical and electrical characterization of TiO_2 nanotube arrays on titanium substrate[J],Appl.Surf.Sci.,2005,252(4):1101.
[40]Y.K.Lai,L.Sun,Y.C.Chen,H.F.Zhuang,C.J.Lin,W.C.Joannie,Effects of the structure of TiO_2 nanotube array on Ti substrate on its photocatalytic activity[J],J.Electrochem.Soc.,2006,153(7):D123.
[41]D.Bersani,G.Antonioli,P.P.Lottici,T.Lopez,Raman study of nanosized titania prepared by sol-gel route[J],J.Non-Cryst.Solids,1998,232-234:175.
[42]陈云霞,何鑫,刘超,谢毅,一维纳米结构TiO_2制备方法研究进展[J],中国陶瓷,2007,43(2):7.
[43]吕康乐,刘松翠,卢春山,水热合成法制备特定形貌的二氧化钛及光催化性能[J],中南民族大学学报(自然科学版),2008,27(1):18.
[44]郝彦忠,韩文涛,钛酸盐纳米管的制备及光电性能研究[J],物理化学学报,2006,22(2):221.
[45]C.E.B.Marino,P.A.P.Nascente,S.R.Biaggio,C.R-F.Romeu,N.Bocchi,XPS characterization of anodic titanium oxide films grown in phosphate buffer solutions[J],Thin Solid Films,2004,468(1-2):109.
[46]H.Yun,J.Li,H.B.Chen,C.J.Lin,A study on the N~-,S~- and Cl~- modified nano-TiO_2coatings for corrosion protection of stainless steel[J],Electrochim.Acta,2007,52(24): 6679.
[47]Matsuda,T.Matoda,T.Kogure,K.Tadanaga,T.Minami,M.Tatsumisago,Formation and characterization of titania nanosheet-precipitated coatings via sol-gel process with hot water treatment under vibration[J],Chem.Mater.,2005,17(4):749.
[48]T.Zajac,M.Radecka,M.Rekas,Photoelectrochemical properties of Nb-doped titanium dioxide[J],Physica B,2007,399:55.
[49]S.Berger,H.Tsuchiya,A.Ghicov,P.Schmuki,High photocurrent conversion efficiency in self-organized porous WO_3[J],Appl.Phys.Lett.,2006,88:119.
[50]G.K.Mor,K.Shankar,M.Paulose,O.K.Varghese,C.A.Grimes,Use of highly-ordered TiO_2 nanotube arrays in dye-sensitized solar cells[J],Nano Lett.,2006,6:215.
[51]J.H.Park,S.Kim,A.J.Bard,Novel carbon-doped TiO_2 nanotube arrays with high aspect ratios for efficient solar water splitting[J],Nano Lett.,2006,6:24.
[52]武朋飞,李谋成,沈嘉年,肖美群,刘东,阳极氧化二氧化钛薄膜的光电化学防腐蚀特性[J],中国腐蚀与防护学报,2005,25(1):53.
[53]曹楚南,张鉴清,电化学阻抗谱导论[M],北京,科学出版社,2002.
[54]吕德义,王晖,郇昌永,周春晖,葛忠华,水热晶化法制备纳米TiO_2的动力学研究[J],浙江工业大学学报,2004,32(1):41.
[55]肖奇,邱冠周,胡岳华,纳米TiO_2制备及其应用新进展[J],材料导报,2000,14(8):35.
[56]Y.Paz,Z.Luo,L.Rabenberg,A.Heller,Photooxidative self-cleaning transparent titanium dioxide films on glass[J],J.Mater.Res.,1995,10:2842.
[57]R.Fretwell,P.Douglas,An active,robust and transparent nanocrystalline anatase TiO_2 thin film- preparation,characterization and the kinetics of photodegradation of model pollutants [J],J.Photochem.Photobiol.A,2001,143:229.
[58]Mills,S-K.Lee,A.Lepre,I.P.Parkin,S.A.O'Neill,Spectral and photocatalytic characteristics of TiO_2 CVD films on quartz[J],Photochem.Photobiol.Sci.,2002,1:865.
[59]Mills,A.Lepre,N.Elliot,S.Bhopal,O.P.Parkin,S.A.O'Neill,Characterisation of the photocatalyst Piikington Activ~(TM):a reference film photocatalyst?[J],J.Photochem.Photobiol.A,2003,160(3):213.
[60]K.Takagi,T.Makimoto,H.Hiraiwa,T.Negishi,Photocatalytie,antifogging mirror[J],J.Vac.Sci.Technol.A Vac.Surf.Films,2001,19(6):2931.
[61]H.Choi,E.Stathatos,D.Dionysiou,Synthesis of nanocrystalline photocatalytic TiO_2 thin films and particles using sol-gel method modified with nonionic surfactants[J],Thin Solid Films,2006,510(1-2):107.
[62]P.Arnal,R.J.P.Corrriu,D.Leclercq,et al.,A solution chemistry study of nonhydrolytic sol-gel routes to titania[J],Chem.Mater.,1997,9(3):694.
[63]Y.Mori,Y.Okastu,Y.Tsujimoto,Titanium dioxide nanoparticles produced in water-in-oil emulsion[J].J.Nano.Res,2001,3(2-3):219.
[64]陈洪龄,王延儒,时钧,单分散超细二氧化钛颗粒的制备及粒径控制[J],物理化学学报,2001,17(8):713.
[65]仇雁翎,赵建夫,李田,朱志良,热处理温度对TiO_2光催化膜性能的影响[J],同济大学学报(自然科学版)2008,36(6):764.
[66]H.J.Lee,S.H.Hahn,E.J.Kim,et al.,Influence of calcination temperature on structural and optical properties of TiO_2-SiO_2 thin films prepared by sol-gel dip coating[J],J.Mater.Sci.,2004,39(11):3683.
[67]王鹤峰,季秀燕,张洪涛,不锈钢基底上TiO_2薄膜的制备和结构分析[J],太原理工大学学报,2008,39(1):17.
[68]孟凡明,周明飞,蔡琪,孙兆奇,纳米TiO_2薄膜的制备与表面形貌研究[J],真空科学与技术学报,2008,28(1):72.
[69]黄晖,罗宏杰,姚熹,水热法制备TiO_2薄膜的研究[J],物理学报,2002,51(8):1881.
[70]Q.W.Chen,Y.T.Qian,Z.Y.Chen,et al.,Appl.Phys.Lett.,1995,66:1608.
[71]W.S.Cho,M.Yoshimura,Hydrothermal synthesis of PbTiO_3 films[J],J.Mater.Res.,1997,12(3):833.
[72]C.Y.Cho,E.W.Shi,M.S.Jang,et al.,J.Appl.Phys.Part,1994,33:4984.
[73]D.S.Kim,S.-Y.Kwak,The hydrothermal synthesis of mesoporous TiO_2 with high crystallinity,thermal stability,large surface area,and enhanced photocatalytic activity[J],Applied Catalysis A:General,2007,323:110.
[74]H.G.Yu,J.G.Yu,B.Cheng,M.H.Zhou,Effects of hydrothermal post-treatment on microstructures and morphology of titanate nanoribbons[J],J.Solid State Chem.,2006,179:349.
[75]李竟先,吴基球,庄志强,TiO_2纳米颗粒水热法制备研究进展及反应机理的初步研究[J],中国陶瓷工业,2001,8(2):29.
[76]A.Matsuda,Y.Kotani,T.Kogure,M.Tatsumisago,T.Minami,Transparent anatase nanocomposite films by the sol-gel process at low temperatures[J],J.Am.Ceram.Soc.,2000,83(1):229.
[77]Y.Kotani,A.Matsuda,T.Kogure,M.Tatsumisago,T.Minami,Effects of addition of poly(ethylene glycol) on the formation of anatase nanocrystals in SiO_2-TiO_2 gel films with hot water treatment[J],Chem.Mater.,2001,13(6):2144.
[78]H.Imai,H.Hirashima,K.Awazu,Alternative modification methods for sol-gel coatings of silica,titania and silica-titania using ultraviolet irradiation and water vapor[J],Thin Solid Films,1999,351(1-2):91.
[79]H.Imai,H.Hirashima,Preparation of porous anatase coating from sol-gel-derived titanium dioxide and titanium dioxide-silica by water-vapor exposure[J],J.Am.Ceram.Soc.,1999,82(9):2301.
[80]N.Uekawa,J.Kajiwara,K.Miyatake,K.Kakegawa,Y.Sasaki,Low temperature synthesis of titania gel containing anatase and rutile[J],Chem.Lett.,2000,4:382.
[81]C.J.Brinker,A.J.Hurd,J.Phys.Ⅲ,1994,4:1231.
[82]M.Burgos,M.Langlet,Condensation and densification mechanism of sol-gel TiO_2 layers at low temperature[J],J.Sol-Gel Sci.Technol.,1999,16(3):267.
[83]M.Langlet,M.Burgos,C.Couthier,C.Jimenez,C.Morant,M.Manso,Low temperature preparation of high refractive index and mechanically resistant sol-gel TiO_2 films for muitilayer antireflective coating applications[J],J.Sol-Gel Sci.Technol.,2001,22(I-2):139.
[84]K.I.Gnanasekar,V.Subramanian,J.Robinson,J.C.Jiang,F.E.Posey,B.Rambabu,Direct conversion of TiO_2 sol to nanocrystalline anatase at 85 degrees C[J],J.Mater.Res.,2002,17(6):1507.
[85]Y.Djaoued,S.Badilescu,P.V.Ashrit,D.Bersani,P.P.Lottici,R.Bruning,Low temperature sol-gel preparation of nanocrystalline TiO_2 thin films[J],J.Sol-Gel Sci.Technol.,2002,24(3):247.
[86]M.Langlet,A.Kim,M.Audier,J.M.Hermann,Sol-gel preparation of photocatalytic TiO_2films on polymer substrates[J],J.Sol-Gel Sci.Technol.,2002,25(3):223.
[87]Z.Wang,U.Helmersson,P.O.Kall,Optical properties of anatase TiO_2 thin films prepared by aqueous sol-gel process at low temperature[J],Thin Solid Films,2002,405(1-2):50.
[88]Y.Gao,Y.Masuda,Z.Peng,T.Yonezawa,K.Koumoto,Room temperature deposition of a TiO_2 thin film from aqueous peroxotitanate solution[J],J.Mater.Chem.,2003,13(3):608.
[89]梁德荣,纳米TiO)2的制备及其光催化性能的研究[J],山西化工,2008,28(3):17.
[90]B.Zielinska,J.Grzechulska,B.Grzmil,et al.,Photocatalytic degradation of reactive black 5:a comparison between TiO_2-tytanpol A11 and TiO_2-degussa P25 photocatalysts[J],Appl.Catal B:Environ,2001,35:1.
[91]B.Ohtani,Y.Ogawa,S.Nishimoto,Photocatalytic activity of amorphous-anatase mixture of titanium(Ⅳ) oxide particles suspended in aqueous solutions[J],J.Phys.Chem B,1997,101:3746.
[92]K.Byrappa,M.Yoshimura,Handbook ofhydrothermal technology:a technology for crystal growth and materials processing,1st edition[M].New York:William Andrew Publishing,2001,1-8.
[93]罗薇,万洪富,黄莺,侯梅芳,环境修复新型纳米TiO_2材料的合成因素探讨[J],生态环境,2007,16(6):1807.
[94]李汶军,郑燕青,施尔畏,TiO_2和Al_2O_3晶体的生长习性[J],无机材料学报,2000,15(6):968.
[95]M.Gopal,W.J.M.Chan,J.L.C.De,Room temperature synthesis of crystalline metal oxides[J],J.Mater.Sci.,1997,32(22):6001.
[96]包定华,顾豪爽,邝安祥,Sol-gel法合成TiO_2纳米粉末和薄膜[J],无机材料学报,1996,11(3):453.
[97]H.M.Cheng,J.M.Ma,Z.G.Zhao,et al.,Hydrothermal preparation of uniform nanosize rutile and anatase particles[J],Chem.Mater.,1995,7:663.
[98]T.Nagase,T.Ebina,T.Iwasaki,K.Hayashi,Y.Onodera,M.Chatterjee,Hydrothermal synthesis of brookite[J],Chem.Lett.,1999,9:911.
[99]N.Uekawa,J.Kajiwara,K.Kakegawa,Y.Sasaki,Low temperature synthesis and characterization of porous anatase TiO_2 Nanoparticles[J],J.Colloid Interface Sci.,2002,250(2):285.
[100]M.Tang,G.Z.Wang,L.D.Zhang,Thermal desorption in nanocrystalline TiO_2[J],J.Appl.Phy,1996,80(2):15.
[101]X.Turrillas,P.Barnes,S.E.Tarling,Neutron thermodiffractometry and synchrton energydispersive diffraction stedies of zirconium hydroxide calcinations[J].J.Mster.Sci.Lett.,1993.12:223.
[102]陈武,季寿元编,矿物学导论,北京:地质出版社,1985,112.
[103]R.D.Shannon,J.A.Pask,Kinetics of the anatase-rutile transformation[J],J.Am.Ceram Soc,1965,48:391.
[104]郑燕青,施尔畏,元如林,李汶军,王步国,仲维卓,胡行方,二氧化钛晶粒的水热制备及其形成机理研究[J],中国科学(E辑),1999,29(3):206.
[105]黄军华,高濂,陈锦元,纳米TiO_2粉体制备过程中结晶度的控制[J],无机材料学报,1996,11(1):51.
[106]T.Ohsaka,Temperature dependence of the Raman spectrum anatase TiO_2[J],Jpn.J.Phys.Soc,1980,48:1661.
[107]汪国忠,汪春昌,张立德,纳米TiO_2的制备和性能[J],材料研究学报,1997,11(5):527.
[108]石金娥,闫吉昌,王悦宏,闫福成,陈大伟,王莹,赵凯,李晓坤,崔晓莹,翟玉娟,不同形貌TiO_2的水热合成及对苯酚的降解研究[J],高等学校化学学报,2006,27(8):1513.
[109]谢德明,胡吉明,童少平,多道环氧涂层在NaCl溶液中的电化学阻抗谱[J],材料研究学报,2004,18(2):96.
[110刘旭文,熊金平,曹京宜,左禹,无机/有机复合涂层体系在3.5%NaCl溶液中的EIS [J],化工学报,2007,58(9):2282.
[111]G.Grundmeier,W.Schmidt,M.Stratmann,Corrosion protection by organic coatings:electrochemical mechanism and novel methods of investigation[J],Electrochimica Acta,2000,45(15-16):2515.
[112]张鉴清,曹楚南,电化学阻抗谱方法研究评价有机涂层[J],腐蚀与防护,1998,19(3):99.
[113]陈群尧,涂层及其腐蚀失效机理的研究方向和方法[J],中国腐蚀与防护学报,1997,17(4):307.
[114]阎瑞,吴行,环氧铝粉涂层在3.5%NaCl介质中的失效机理研究[J],中国表面工程,2007,20(4):29.
[115]周陈亮,肖利秋,窦贤飞,电化学方法在涂层/金属体系耐蚀性能评估中的应用[J],涂料工业,1998(9):42.
[116]P.Campestrini,E.P.M.Van Westing,De Wit J H W,Influence of surface preparation on performance of chromate conversion coatings on Al clad 2024 aluminium alloy - Part Ⅱ:EIS investigation[J],Electrochim.Acta,2001,46(17):2631.
[117]Y.Y.Shi,Z.Zhang,J.X.Su,et al.,EIS study on 2024-T3 aluminum alloy corrosion in simulated acid rain under cyclic wet- dry conditions[J],Mater.Corros.,2005,56(10):701.
[118]M.L.Zheludkevich,K.A.Yasakau,S.K.Poznyak,et al.,Triazole and thiazole derivatives as corrosion inhibitors for AA2024 aluminium alloy[J],Corros.Sci.,2005,47(12):3368.
[119]尹燕萍,罗江财,杨晓波,何伟全,光电材料的俄歇电子谱分析[J],半导体光电,2000,21:84.
[120]仇满德,姚子华,纳米Ti02薄膜表面微区分析的研究进展[J],材料导报,2007,2l:51.
[121]伍彦,姚文清,朱永法,Ta_2O_5/Si薄膜界面结构及光催化活性[J],物理化学学报,2007,23(5):625.
[122]朱永法,李巍,不锈钢丝网上薄膜TiO_2光催化剂的Rarnan光谱研究[J],光谱学与光谱分析,2003,23(3):494.
[123]Y.F.Zhu,L.Zhang,L.Wang,Y.Fu,L.L.Cao,The preparation and chemical structure of TiO_2 film photocatalysts supported on stainless steel substrates via the sol-gel method[J],J.Mater.Chem.,2001,11(7):1864.
[124]朱永法,张利,王莉,付艳,曹立礼,不锈钢基底上TiO_2薄膜型光催化剂的制备和化学结构[J],化学学报,2000,58(4):467.
[125]X.Zhao,M.H.Liu,Y.F.Zhu,Fabrication of porous TiO_2 film via hydrothermal method and its photocatalytic performances[J],Thin Solid Films,2007,515(18):7127.
© 2004-2018 中国地质图书馆版权所有 京ICP备05064691号 京公网安备11010802017129号 地址：北京市海淀区学院路29号 邮编：100083 电话：办公室：(+86 10)66554848；文献借阅、咨询服务、科技查新：66554700 |