稀土镨激活的钛酸钙长余辉材料的合成及发光性能
|
摘要
稀土离子镨激活的碱土金属钛酸盐是一类化学性能稳定、发光强和色纯度高的红色发光材料,并且其余辉呈慢衰减的特性。本文综述了稀土金属离子镨激活的碱土钛酸盐红色长余辉材料的常用制备方法,介绍了其发光机制及发光性能的影响因素,并采用如下合成方法合成性能良好的长余辉材料。
以乙醇为溶剂、柠檬酸为螯合剂,采用溶胶-凝胶法合成红色长余辉材料CaTiO_3: Pr~(3+),Al~(3+)。用热重和差热联用仪对干凝胶进行了失重分析,用XRD粉末衍射仪、透射电镜、荧光光度计和屏幕亮度计分别对样品晶形、粒径分布、光谱特性进行了测定。热重分析曲线及X射线衍射分析结果表明溶胶-凝胶法合成的样品在700℃灼烧5个小时可得到晶相较好的钙钛矿型CaTiO_3,激发和发射光谱及余辉衰减曲线显示干凝胶在900℃下灼烧时具有较好的余辉性能,溶胶-凝胶法合成的样品余辉性能明显优于高温固相法合成的余辉材料。溶胶-凝胶法合成余辉材料过程中使用超声分散技术能提高产物余辉性能。
以钛酸四丁酯、硝酸钙为原料,采用改进的固相法合成了稀土镨掺杂的钛酸钙长余辉材料。用热重和差热联用仪对前驱体进行了失重分析,用XRD粉末衍射仪、透射电镜、分别对样品晶形、粒径等特性进行了测定。目标产物的发光性能表明前驱体在900℃的温度下灼烧时具有较好的性能。
以尿素为燃料、硼酸为助熔剂,采用燃烧法成功地合成了稀土镨和铝掺杂的钛酸钙红色长余辉材料。研究了尿素、硼酸的用量以及初始炉温对长余辉材料性能的影响。结果表明,在一定范围内尿素的用量对余辉性能影响不明显;而硼酸的加入能显著地提高余辉材料地发光性能,其最合适的加入量为硼酸与硝酸钙摩尔比为0.4;在400到900℃的初始炉温范围内,随着初始炉温的升高其发光性能也相应的增高。
采用草酸盐沉淀法合成了钛酸钙长余辉材料,所得目标产物颗粒分布均匀,其余辉性能随着后期灼烧温度的升高而增强。
Rare earth praseodymium doped calcium titanate persistent phosphor is chemically and thermally stable complex oxide, which is known for several years as a red emitting phosphor characterized by a single emission peak with chromaticity coordinates, very close to the coordinates of the“ideal red”. In this paper, the preparation methods, luminescence mechanism and influence factors of praseodymium doped calcium titanates were introduced. The various synthesis methods (including sol-gel, modified solid-state, combustion and coprecipitation methods) were employed to prepare the persistent phosphors.
Red CaTiO_3: Pr~(3+), Al~(3+) persistent phosphors have been synthesized by sol-gel method using ethanol as solvent and citric acid as a chelating agent. TG-DTG curves and X-ray diffraction analysis indicate that crystalline calcium titanate has been synthesized at calcining temperature of 700℃for 5 hours. Photoluminescence and decay curves indicate that the luminescence properties of phosphors synthesized by sol-gel method are better than that prepared by solid-state reaction and the sample heated at 900℃exhibits the optimal luminous property. Using ultrasonic dispersing technique improved the luminescence properties of phosphors.
Using tetra-n-butyl titanate and calcium nitrate as raw materials, the praseodymium-doped calcium titanates have been synthesized via a modified solid-state reaction. The decomposition process of the precursor, crystallization, and particle sizes of CaTiO_3: Pr~(3+) have been investigated by using thermal analysis, powder X-ray diffraction and transmission electron microscopy. TG-DTG curves and X-ray diffraction analysis indicate that crystalline calcium titanate has been synthesized at calcining temperature of 600℃for 2 hours. Photoluminescence and decay curves show that the sample obtained at the sintering temperature of 900℃exhibited the optimal luminous property.
Using urea as fuel and boric acid as flux material, red persistent phosphors CaTiO_3: Pr~(3+),Al~(3+) have been successfully synthesized by combustion method. The process lasted for less than 5 min and led to the formation of voluminous white powder. The photoluminescence, crystallinity and particle morphology of persistent phosphors were investigated by using luminescence spectrometer, X-ray diffractometer (XRD) and transmission electron microscopy (TEM), respectively. The results showed that the boric acid was effective in improving the photoluminescence intensity of CaTiO_3: Pr~(3+), Al~(3+) phosphor particles and the optimum molar ratio of boric acid to calcium nitrate was about 0.4. The luminescent properties and crystallinity of phosphors increased with increasing initiating temperature.
Using tetra-n-butyl titanate, calcium nitrate and oxalic acid as raw materials, the praseodymium-doped calcium titanates have been synthesized via calcinations of oxalate coprecipitated precursors. The decomposition process of the precursor, crystallization, and particle sizes of praseodymium-doped calcium titianates have been investigated by using thermal analysis, powder X-ray diffraction and transmission electron microscopy, respectively. Photoluminescence of the sample obtained at 900℃was examined by luminescence spectrometer, and the brightness of persistent phosphors indicate that the luminous property of the samples was enhanced with increasing sintering temperature.
以乙醇为溶剂、柠檬酸为螯合剂,采用溶胶-凝胶法合成红色长余辉材料CaTiO_3: Pr~(3+),Al~(3+)。用热重和差热联用仪对干凝胶进行了失重分析,用XRD粉末衍射仪、透射电镜、荧光光度计和屏幕亮度计分别对样品晶形、粒径分布、光谱特性进行了测定。热重分析曲线及X射线衍射分析结果表明溶胶-凝胶法合成的样品在700℃灼烧5个小时可得到晶相较好的钙钛矿型CaTiO_3,激发和发射光谱及余辉衰减曲线显示干凝胶在900℃下灼烧时具有较好的余辉性能,溶胶-凝胶法合成的样品余辉性能明显优于高温固相法合成的余辉材料。溶胶-凝胶法合成余辉材料过程中使用超声分散技术能提高产物余辉性能。
以钛酸四丁酯、硝酸钙为原料,采用改进的固相法合成了稀土镨掺杂的钛酸钙长余辉材料。用热重和差热联用仪对前驱体进行了失重分析,用XRD粉末衍射仪、透射电镜、分别对样品晶形、粒径等特性进行了测定。目标产物的发光性能表明前驱体在900℃的温度下灼烧时具有较好的性能。
以尿素为燃料、硼酸为助熔剂,采用燃烧法成功地合成了稀土镨和铝掺杂的钛酸钙红色长余辉材料。研究了尿素、硼酸的用量以及初始炉温对长余辉材料性能的影响。结果表明,在一定范围内尿素的用量对余辉性能影响不明显;而硼酸的加入能显著地提高余辉材料地发光性能,其最合适的加入量为硼酸与硝酸钙摩尔比为0.4;在400到900℃的初始炉温范围内,随着初始炉温的升高其发光性能也相应的增高。
采用草酸盐沉淀法合成了钛酸钙长余辉材料,所得目标产物颗粒分布均匀,其余辉性能随着后期灼烧温度的升高而增强。
Rare earth praseodymium doped calcium titanate persistent phosphor is chemically and thermally stable complex oxide, which is known for several years as a red emitting phosphor characterized by a single emission peak with chromaticity coordinates, very close to the coordinates of the“ideal red”. In this paper, the preparation methods, luminescence mechanism and influence factors of praseodymium doped calcium titanates were introduced. The various synthesis methods (including sol-gel, modified solid-state, combustion and coprecipitation methods) were employed to prepare the persistent phosphors.
Red CaTiO_3: Pr~(3+), Al~(3+) persistent phosphors have been synthesized by sol-gel method using ethanol as solvent and citric acid as a chelating agent. TG-DTG curves and X-ray diffraction analysis indicate that crystalline calcium titanate has been synthesized at calcining temperature of 700℃for 5 hours. Photoluminescence and decay curves indicate that the luminescence properties of phosphors synthesized by sol-gel method are better than that prepared by solid-state reaction and the sample heated at 900℃exhibits the optimal luminous property. Using ultrasonic dispersing technique improved the luminescence properties of phosphors.
Using tetra-n-butyl titanate and calcium nitrate as raw materials, the praseodymium-doped calcium titanates have been synthesized via a modified solid-state reaction. The decomposition process of the precursor, crystallization, and particle sizes of CaTiO_3: Pr~(3+) have been investigated by using thermal analysis, powder X-ray diffraction and transmission electron microscopy. TG-DTG curves and X-ray diffraction analysis indicate that crystalline calcium titanate has been synthesized at calcining temperature of 600℃for 2 hours. Photoluminescence and decay curves show that the sample obtained at the sintering temperature of 900℃exhibited the optimal luminous property.
Using urea as fuel and boric acid as flux material, red persistent phosphors CaTiO_3: Pr~(3+),Al~(3+) have been successfully synthesized by combustion method. The process lasted for less than 5 min and led to the formation of voluminous white powder. The photoluminescence, crystallinity and particle morphology of persistent phosphors were investigated by using luminescence spectrometer, X-ray diffractometer (XRD) and transmission electron microscopy (TEM), respectively. The results showed that the boric acid was effective in improving the photoluminescence intensity of CaTiO_3: Pr~(3+), Al~(3+) phosphor particles and the optimum molar ratio of boric acid to calcium nitrate was about 0.4. The luminescent properties and crystallinity of phosphors increased with increasing initiating temperature.
Using tetra-n-butyl titanate, calcium nitrate and oxalic acid as raw materials, the praseodymium-doped calcium titanates have been synthesized via calcinations of oxalate coprecipitated precursors. The decomposition process of the precursor, crystallization, and particle sizes of praseodymium-doped calcium titianates have been investigated by using thermal analysis, powder X-ray diffraction and transmission electron microscopy, respectively. Photoluminescence of the sample obtained at 900℃was examined by luminescence spectrometer, and the brightness of persistent phosphors indicate that the luminous property of the samples was enhanced with increasing sintering temperature.
引文
[1]孙家跃, 杜海燕, 胡文祥. 固体发光材料[M]. 北京: 化学工业出版社, 2003.
[2] Qiu J, Miura K, Inouye H, et al. Femtosecond laser induced three dimensional bright and long lasting phosphorescence inside calcium aluminosilicate glasses doped with rare earth ions [J ]. Applied Physics Letters, 1998, 73: 1763-1765.
[3] Su Qiang, Li Chengyu, Lu Yuehua. Preparation of the glasses and glass ceramics with long lasting phosphorescence and photo stimulated long lasting phosphorescence for optical memory [P]. CN Patent, 02117958. 1.
[4] Kowatari M, Koyama D, Satoh Y, et al. The temperature dependence of luminescence from a long lasting phosphors exposed to ionizing radiation [J]. Nuclear Instruments and Methods in Physics Research A, 2002, 480: 431-439.
[5]Yuanhua Lin, Zilong Tang, Zhongtai Zhang, et al. Preparation and properties of photoluminescent rare earth doped SrO–MgO–B2O_3–SiO2 glass [J]. Materials Science and Engineering: B, 2001, 86: 79–82
[6] 朱爱玲,廉世勋,李承志,等. 绿色长余辉发光玻璃的合成和性质[J]. 光谱实验室,2003, 20 (1) : 23-27.
[7] 杨志平,刘冲,郭智,等. CaTiO_3: Pr~(3+)长余辉玻璃的制备与发光性能[J]. 发光学报,2005, 26 (4): 493-496.
[8] Eric Pinel, Philippe Boutinaud, Genevieve Bertrand, et al. Preparation and characterization of luminescent films of Pr~(3+) -doped CaTiO_3 processed by sol-gel technique [J]. Journal of Alloys and Compounds, 2004, 374: 202-206.
[9] Sung Mook Chung, Sang hyuk Han, Kuk Hyun Song, et al. Luminescent properties of CaTiO_3: Pr~(3+) thin-film phosphor deposited on ZnO/ITO/glass substrate [J]. Journal of Luminescence, 2005, 114: 227-233.
[10] K. Sato, S. Komuro, T. Morikawa, et al. Long afterglow characteristics of thin filmphosphor fabricated by laser ablation [J]. Journal of Crystal Growth, 2005, 275: 137–141.
[11] Chang Chengkang, Mao Dali, Shen Jianfeng, et al. Preparation of long persistent SrO·2Al2O_3 ceramics and their luminescent properties [J]. Journal of Alloys and Compounds, 2003, 348: 224–230.
[12] C.K. Chang, L. Jiang, D.L. Mao, et al. Photoluminescence of 4SrO.7Al2O_3 ceramics sintered with the aid of B2O_3 [J]. Ceramics International, 2004, 30: 285–290.
[13] Yi Jia, Ming Yei, Weiyi Jia. Stress-induced mechanoluminescence in SrAl2O4:Eu~(2+), Dy~(3+). Optical Materials, 2006, 28(8-9): 974-979.
[14]Changliang Zhao, Donghua Chen, Yuhong Yuan ,et al. Synthesis of Sr4Al14O25:Eu~(2+), Dy~(3+) phosphor nanometer powders by combustion processes and its optical properties. Materials Science and Engineering: B, 2006, 133 (1-3):200-204.
[15] Lei Wang, Yuhua Wang. Effects of B_2O_3 and SiO_2 on the persistent luminescence property of CaAl2O4:Eu~(2+), Nd~(3+). Physics B: Condensed Matter, 2007, 393(1-2): 147-152.
[16] Changliang Zhao, Donghua Chen. Synthesis of CaAl_2O_4: Eu, Nd long persistent phosphor by combustion processes and its optical properties. Materials Letters, (2007),doi:10.1016/j.matlet.2006.12.015.
[17] 孙家跃,夏志国,杜海燕. 稀土红色长余辉发光材料研究进展[J]. 中国稀土学报,2005,23(3):257-265.
[18] P.T.Diallo, P.Boutinaud, R.Mahiou, et al. Red Luminescence in Pr~(3+)-Doped Calcium Titanates [J]. Physica Status Solidi A-Applied Research, 1997, 160: 255.
[19] Royce M R ,Matsuda S ,Tamaki H. Red emitting long decay phosphors [P] .US Patent: 5650094, 1997, 07, 22.
[20] 刘利民,曾立华,廉世勋,等. CaTiO_3: Pr~(3+)的合成及发光特性[J]. 湖南有色金属,1998, 14(9): 45-47.
[21] P.T.Diallo, K.Jeanlouis, P.Boutinaud, et al. Improvement of the optical performance of Pr~(3+) in CaTiO_3 [J]. Journal of Alloys and Compounds, 2001, 323-324: 218-222.
[22] YueXiao Pan, Qing Su, Huifang Xu, et al. Synthesis and red luminescence of Pr~(3+)-doped CaTiO_3 nano-phosphor from polymer precursor [J]. Journal of Solid State Chemistry,2003, 174: 69-73.
[23] 李秀英,廉世勋,朱爱玲等. 红色长余辉发光材料Ca2Zn4Ti15O_36∶Pr~(3+) 的合成和发光性质[J]. 中国稀土学报, 2005, 23(1): 16-20.
[24] Bing Yan, Kun Zhou, In situ sol-gel composition of inorfanic/organic polymeric hybrid precursors to synthesize red-luminescence CaTiO_3:Pr~(3+) and CaTi0.5Zr0.5O_3:Pr~(3+) phosphors [J]. Journal of Alloys and Compounds, 2005, 398: 165-169.
[25] Yun Chan Kang, Jeong Su Choi, Seung Bin Park, et al. Preparation of CaTiO_3:Pr phosphor by spraypyrolysis using filterexpansion aerosolgeneator [J]. Journal of Aerosol Science, 1997, 28: 541-542.
[26] K.H. Kim, J.K. Park, C.H. Kim, et al. Synthesis of SrTiO_3: Pr, Al by ultrasonic spray pyrolysis [J]. Ceramics International, 2002, 28: 29–36.
[27] Zifeng Qiu, Yuanyuan Zhou, Mengkai Lü, et al. Combustion synthesis of long-persistent luminescent MAl2O4: Eu~(2+), R~(3+) (M = Sr, Ba, Ca, R = Dy, Nd and La) nanoparticles and luminescence mechanism research [J]. Acta Materialia, 2007, 55(8): 2615-2620.
[28] Yanbin Sun, Guanming Qin, Xikun Li, et al. Synthesis of SrAl_2O_4Eu~(2+),Dy~(3+) phosphors by the coupling route of microemulsion with coprecipitation method [J]. Rare Metal, 2006, 25(6):615-619.
[29] Xiaojie Li, Yandong Qu, Xinghua Xie, et al. Preparation of SrAl2O4: Eu~(2+), Dy~(3+) nanometer phosphors by detonation method [J]. Materials Letters, 2006, 60(29-30): 3673-3677.
[30] Tianyou Peng, Liu Huajun, Huanping Yang, et al. Synthesis of SrAl_2O_4: Eu, Dy phosphor nanometer powders by sol–gel processes and its optical properties [J]. Materials Chemistry and Physics, 2004, 85(1): 68-72.
[31] Kinoshita T, Yamazaki M, Kawazoe H. Long - lasting phosphorescence and photostimulated luminescence in Tb- ion - activated reduced calcium aluminate glasses [J]. Journal of Applied Physics, 1999, 86: 3729-3733
[32] Zhang T, Su Q. Rare-earth materials used in dark [J]. Journal of the ID, 2000, 8 (1): 27-30.
[33] Zhang Tianzhi, Su Qiang, Wang Shubin. Studies on the properties of the long-lasting phosphorescence of MAl2O4 ∶E u~(2+) , RE~(3+) [J ] . Chinese of Journal of Luminescence,1999, 20:170-175.
[34] 杨志平, 王文杰, 郭 智, 等. 红色长余辉材料CaTiO_3∶Pr~(3+)中两种电子陷阱的研究[J]. 光电子·激光, 2004,15 (3): 332.
[35] P. Boutinaud, E. Pinel, M.Dubois, et al. UV-to-red relaxation pathways in CaTiO_3: Pr~(3+)[J]. Journal of Luminescence, 2005, 111: 69-80.
[36] W. Jia, D. Jia, T.Rodrigurez, et al. UV excitation and trapping centers in CaTiO_3:Pr~(3+) [J]. Journal of Luminescence 2006, 119-120: 13-18.
[37] 杨志平, 郭 智, 王文杰, 等. Pr~(3+)摩尔浓度对CaTiO_3:Pr~(3+)红色长余辉材料的影响[J]. 功能材料与器件学报,2003,9 (4): 473-476.
[38] Zhang Xiyan, Cheng Guang, Mi Xiaoyun, et al. Preparation and Long Persistence Red Luminescence of M0. 2Ca0. 8TiO_3∶Pr~(3+) (M= Mg~(2+), Sr~(2+), Ba~(2+), Zn~(2+))[J]. Rare Earths, 2004, 22 (1):137.
[39] 廉世勋, 林建华, 苏勉曾. Ca1 - xZnxTiO_3∶Pr3 +, R+ (R+ = Li +, Na +, K+, Rb+, Cs +, Ag+ ) 的合成和发光性质[J]. 中国稀土学报, 2001,19 (6): 602-605.
[40] 杨志平,朱胜超, 郭智,等. 锌对CaTiO_3∶Pr~(3+)发光亮度和余辉时间的影响[J]. 中国稀土学报,2002,20: 42-45.
[41] 李秀英,廉世勋,朱爱玲,等. 掺Pr~(3+)钛酸盐红色长余辉发光性质比较[J]. 湖南师范大学自然科学学报 2005, 28 (1): 48-51.
[42] 洪樟连,张朋越,王民权. Ca1 - xZnxTiO_3:Pr3 +的固溶特性及其发光性能[J]. 中国稀土学报,2005, 23 (6): 659-694.
[43] Weiyi Jia, Wuliang Xu, Iris Rivera, et al. Effects of compositional phase transitions on luminescenc of Sr1-xCaxTiO_3:Pr~(3+) [J]. Solid State Communication, 2003, 126: 153-157.
[44] Weiyi Jia, Ange′lica Pe′rez-Andu′ jar, Iris Rivera. Energy Transfer Between Bi~(3+) and Pr~(3+) in Doped CaTiO_3 [J]. Journal of the Electrochemical Society, 2003, 150: 161-164.
[45] S.Okamoto, H. Kobayashi. Enhancement of characteristic red emission from SrTiO_3:Pr~(3+) by Al addition [J]. Journal of Applied physics, 1999, 86: 5594-5597.
[46] S.Okamoto. Characteristic enhancement of emission from SrTiO_3:Pr~(3+) by addition of group-Ⅲb ions [J]. Applied Physics Letters, 2001, 78: 655-657.
[47] S.Okamoto. Emission from BaTiO_3:Pr~(3+) controlled by ionic radius of added trivalent ion [J]. Journal of Applied Physics, 2002, 91: 5492-5495.
[48] Lianhua Tian, Sun-il Mho. Ehanced luminescence of SrTiO_3:Pr~(3+) by incorporation of Li+ ion [J]. Solid State Communication, 2003, 125: 647-651.
[49] K.-A. Hyeona, S.-H. Byeona, J.-C. Parkb, et al. Highly enhanced photoluminescence of SrTiO_3: Pr by substitution of (Li0.5, La0.5) pair for Sr [J]. Solid State Communication, 2000, 115: 99-104.
[50] Jinfeng Tang, Xibin Yu, Liangzhun Yang, et al. Preparation and Al~(3+) enhanced photoluminescence properties of CaTiO_3: Pr~(3+) [J]. Materials letters, 2006, 60: 326-329.
[51] 李治霞, 张玉奇, 廖亮. CaTiO_3:Pr~(3+) 红色磷光体余辉性能的改进 [J]. 重庆大学学报,2004, 27 (7): 53-55.
[52] Xianmin Zhang, Jiahua Zhang, Xia Zhang, et al. Enhancement of red fluorescence and afterglow in CaTiO_3: Pr~(3+) by addition of Lu_2O_3 [J]. Journal of Luminescence, 2007, 122-123: 958-960.
[53] Yuanhua Lin, Zhongtai Zhang, Feng Zhang,et al. Preparation of the ultrafine SrAl2O4: Eu, Dy needle-like phosphor and its optical properties [J]. Materials Chemistry and Physics, 2000, 65: 103–106.
[54] 尹盛玉,赵长亮,宋华杰,等. 长余辉材料余辉性能测试的影响因素 [J]. 中南民族大学学报(自然科学版),2006,26(4): 5-7.
[55] Shengyu Yin, Donghua Chen, Wanjun Tang, et al. Synthesis of CaTiO_3: Pr, Al phosphors by sol-gel method and their luminescence properties [J]. Journal of Materials Science, 2007, 42 (8):2886-2890.
[56] 宋华杰,尹盛玉,赵长亮,等. H_3BO_3 对 SrAl_2O_4: Eu~(2+), Dy~(2+), Nd~(3+)长余辉发光材料性能的影响[J]. 中南民族大学学报(自然科学版),2006, 25(3): 16-19.
[57] 赵长亮,尹盛玉,徐咏钗,等. SrAl_2O_4:Eu~(2+),Dy~(3+),Ho~(3+)长余辉发光材料的燃烧法合成及其发光性能研究[J].中南民族大学学报(自然科学版),2007, 26 (2).
[58] 徐咏钗, 宋华杰, 尹盛玉,等. 燃烧法合成 Eu~(2+), Dy ~(3+), Nd ~(3+)共掺杂的硅酸盐长余辉发光材料 Sr2MgSi2O7和 Sr2ZnSi2O7[J]. 中南民族大学学报(自然科学版),2007, 26 (1): 20-22.
[59] J.McKittrick, L. E. Shea, C. F. Bacalski, et al. The influence of processing parameters on luminescent oxides produced by combustion synthesis [J]. Displays, 1999,19: 169-172.
[60] J.J. Kingsley, K.C. Patil. A novel combustion process for the synthesis of fine particleα-alumina and related oxide materials [J]. Materials Letters, 1988, 6:427-432.
[61] Dae Soo Jung, Seung Kwon Hong, Hyo Jin Lee, et al. Gd2O_3: Eu phosphor particles prepared from spray solution containing boric acid flux and polymeric precursor by spray pyrolysis[J]. Optical Materials, 2006, 28:530-535.
[62] Dae Soo Jung, Seung Kwon Hong, Hyo Jin Lee, et al. Effect of boric acid flux on the characteristics of (CeTb)MgAl11O19 phosphor particles prepared by spray pyrolysis[J]. Journal of Alloys and Compounds, 2005, 398: 309-314.
[63] H.S. Potdar, S.B. Deshpande, S.K. Date, Chemical coprecipitation of mixed (Ba + Ti) oxalates precursor leading to BaTiO_3 powders [J]. Materials Chemistry and Physics, 1999, 58:121-127.
[64] B. Guiffard, M. Troccaz. Low temperature synthesis of stoichiometric and homogeneous lead zirconate titanate powder by oxalate and hydroxide coprecipitation [J]. Material Research Bulletin, 1998, 33:1759-1768.
[65] F. Zhang, T. Karaki, M. Adachi, Synthesis of anzosized (Pb, Sr)TiO_3 perovskite powders by coprecipitation processing[J]. Powder Technology, 2005, 159: 13-16.
[66]Y.B. Khollam, S.V. Bhoraskar, S.B. Deshpande, et al. Simple chemical route for the quantitative precipitation of barium-strontium titanyl oxalate precursor leading to Ba1-xSrTiO_3 powder [J]. Materials Letters, 2003, 57: 1871-1879.
[67]S. Suasmoro, S. Pratapa, D. Hartanto, et al. The characterization of mixed titanate Ba1-xSrxTiO_3 phase formation from oxalate coprecipitated precursor [J]. Journal of European Ceramic Society, 2000, 20: 309-314.
[2] Qiu J, Miura K, Inouye H, et al. Femtosecond laser induced three dimensional bright and long lasting phosphorescence inside calcium aluminosilicate glasses doped with rare earth ions [J ]. Applied Physics Letters, 1998, 73: 1763-1765.
[3] Su Qiang, Li Chengyu, Lu Yuehua. Preparation of the glasses and glass ceramics with long lasting phosphorescence and photo stimulated long lasting phosphorescence for optical memory [P]. CN Patent, 02117958. 1.
[4] Kowatari M, Koyama D, Satoh Y, et al. The temperature dependence of luminescence from a long lasting phosphors exposed to ionizing radiation [J]. Nuclear Instruments and Methods in Physics Research A, 2002, 480: 431-439.
[5]Yuanhua Lin, Zilong Tang, Zhongtai Zhang, et al. Preparation and properties of photoluminescent rare earth doped SrO–MgO–B2O_3–SiO2 glass [J]. Materials Science and Engineering: B, 2001, 86: 79–82
[6] 朱爱玲,廉世勋,李承志,等. 绿色长余辉发光玻璃的合成和性质[J]. 光谱实验室,2003, 20 (1) : 23-27.
[7] 杨志平,刘冲,郭智,等. CaTiO_3: Pr~(3+)长余辉玻璃的制备与发光性能[J]. 发光学报,2005, 26 (4): 493-496.
[8] Eric Pinel, Philippe Boutinaud, Genevieve Bertrand, et al. Preparation and characterization of luminescent films of Pr~(3+) -doped CaTiO_3 processed by sol-gel technique [J]. Journal of Alloys and Compounds, 2004, 374: 202-206.
[9] Sung Mook Chung, Sang hyuk Han, Kuk Hyun Song, et al. Luminescent properties of CaTiO_3: Pr~(3+) thin-film phosphor deposited on ZnO/ITO/glass substrate [J]. Journal of Luminescence, 2005, 114: 227-233.
[10] K. Sato, S. Komuro, T. Morikawa, et al. Long afterglow characteristics of thin filmphosphor fabricated by laser ablation [J]. Journal of Crystal Growth, 2005, 275: 137–141.
[11] Chang Chengkang, Mao Dali, Shen Jianfeng, et al. Preparation of long persistent SrO·2Al2O_3 ceramics and their luminescent properties [J]. Journal of Alloys and Compounds, 2003, 348: 224–230.
[12] C.K. Chang, L. Jiang, D.L. Mao, et al. Photoluminescence of 4SrO.7Al2O_3 ceramics sintered with the aid of B2O_3 [J]. Ceramics International, 2004, 30: 285–290.
[13] Yi Jia, Ming Yei, Weiyi Jia. Stress-induced mechanoluminescence in SrAl2O4:Eu~(2+), Dy~(3+). Optical Materials, 2006, 28(8-9): 974-979.
[14]Changliang Zhao, Donghua Chen, Yuhong Yuan ,et al. Synthesis of Sr4Al14O25:Eu~(2+), Dy~(3+) phosphor nanometer powders by combustion processes and its optical properties. Materials Science and Engineering: B, 2006, 133 (1-3):200-204.
[15] Lei Wang, Yuhua Wang. Effects of B_2O_3 and SiO_2 on the persistent luminescence property of CaAl2O4:Eu~(2+), Nd~(3+). Physics B: Condensed Matter, 2007, 393(1-2): 147-152.
[16] Changliang Zhao, Donghua Chen. Synthesis of CaAl_2O_4: Eu, Nd long persistent phosphor by combustion processes and its optical properties. Materials Letters, (2007),doi:10.1016/j.matlet.2006.12.015.
[17] 孙家跃,夏志国,杜海燕. 稀土红色长余辉发光材料研究进展[J]. 中国稀土学报,2005,23(3):257-265.
[18] P.T.Diallo, P.Boutinaud, R.Mahiou, et al. Red Luminescence in Pr~(3+)-Doped Calcium Titanates [J]. Physica Status Solidi A-Applied Research, 1997, 160: 255.
[19] Royce M R ,Matsuda S ,Tamaki H. Red emitting long decay phosphors [P] .US Patent: 5650094, 1997, 07, 22.
[20] 刘利民,曾立华,廉世勋,等. CaTiO_3: Pr~(3+)的合成及发光特性[J]. 湖南有色金属,1998, 14(9): 45-47.
[21] P.T.Diallo, K.Jeanlouis, P.Boutinaud, et al. Improvement of the optical performance of Pr~(3+) in CaTiO_3 [J]. Journal of Alloys and Compounds, 2001, 323-324: 218-222.
[22] YueXiao Pan, Qing Su, Huifang Xu, et al. Synthesis and red luminescence of Pr~(3+)-doped CaTiO_3 nano-phosphor from polymer precursor [J]. Journal of Solid State Chemistry,2003, 174: 69-73.
[23] 李秀英,廉世勋,朱爱玲等. 红色长余辉发光材料Ca2Zn4Ti15O_36∶Pr~(3+) 的合成和发光性质[J]. 中国稀土学报, 2005, 23(1): 16-20.
[24] Bing Yan, Kun Zhou, In situ sol-gel composition of inorfanic/organic polymeric hybrid precursors to synthesize red-luminescence CaTiO_3:Pr~(3+) and CaTi0.5Zr0.5O_3:Pr~(3+) phosphors [J]. Journal of Alloys and Compounds, 2005, 398: 165-169.
[25] Yun Chan Kang, Jeong Su Choi, Seung Bin Park, et al. Preparation of CaTiO_3:Pr phosphor by spraypyrolysis using filterexpansion aerosolgeneator [J]. Journal of Aerosol Science, 1997, 28: 541-542.
[26] K.H. Kim, J.K. Park, C.H. Kim, et al. Synthesis of SrTiO_3: Pr, Al by ultrasonic spray pyrolysis [J]. Ceramics International, 2002, 28: 29–36.
[27] Zifeng Qiu, Yuanyuan Zhou, Mengkai Lü, et al. Combustion synthesis of long-persistent luminescent MAl2O4: Eu~(2+), R~(3+) (M = Sr, Ba, Ca, R = Dy, Nd and La) nanoparticles and luminescence mechanism research [J]. Acta Materialia, 2007, 55(8): 2615-2620.
[28] Yanbin Sun, Guanming Qin, Xikun Li, et al. Synthesis of SrAl_2O_4Eu~(2+),Dy~(3+) phosphors by the coupling route of microemulsion with coprecipitation method [J]. Rare Metal, 2006, 25(6):615-619.
[29] Xiaojie Li, Yandong Qu, Xinghua Xie, et al. Preparation of SrAl2O4: Eu~(2+), Dy~(3+) nanometer phosphors by detonation method [J]. Materials Letters, 2006, 60(29-30): 3673-3677.
[30] Tianyou Peng, Liu Huajun, Huanping Yang, et al. Synthesis of SrAl_2O_4: Eu, Dy phosphor nanometer powders by sol–gel processes and its optical properties [J]. Materials Chemistry and Physics, 2004, 85(1): 68-72.
[31] Kinoshita T, Yamazaki M, Kawazoe H. Long - lasting phosphorescence and photostimulated luminescence in Tb- ion - activated reduced calcium aluminate glasses [J]. Journal of Applied Physics, 1999, 86: 3729-3733
[32] Zhang T, Su Q. Rare-earth materials used in dark [J]. Journal of the ID, 2000, 8 (1): 27-30.
[33] Zhang Tianzhi, Su Qiang, Wang Shubin. Studies on the properties of the long-lasting phosphorescence of MAl2O4 ∶E u~(2+) , RE~(3+) [J ] . Chinese of Journal of Luminescence,1999, 20:170-175.
[34] 杨志平, 王文杰, 郭 智, 等. 红色长余辉材料CaTiO_3∶Pr~(3+)中两种电子陷阱的研究[J]. 光电子·激光, 2004,15 (3): 332.
[35] P. Boutinaud, E. Pinel, M.Dubois, et al. UV-to-red relaxation pathways in CaTiO_3: Pr~(3+)[J]. Journal of Luminescence, 2005, 111: 69-80.
[36] W. Jia, D. Jia, T.Rodrigurez, et al. UV excitation and trapping centers in CaTiO_3:Pr~(3+) [J]. Journal of Luminescence 2006, 119-120: 13-18.
[37] 杨志平, 郭 智, 王文杰, 等. Pr~(3+)摩尔浓度对CaTiO_3:Pr~(3+)红色长余辉材料的影响[J]. 功能材料与器件学报,2003,9 (4): 473-476.
[38] Zhang Xiyan, Cheng Guang, Mi Xiaoyun, et al. Preparation and Long Persistence Red Luminescence of M0. 2Ca0. 8TiO_3∶Pr~(3+) (M= Mg~(2+), Sr~(2+), Ba~(2+), Zn~(2+))[J]. Rare Earths, 2004, 22 (1):137.
[39] 廉世勋, 林建华, 苏勉曾. Ca1 - xZnxTiO_3∶Pr3 +, R+ (R+ = Li +, Na +, K+, Rb+, Cs +, Ag+ ) 的合成和发光性质[J]. 中国稀土学报, 2001,19 (6): 602-605.
[40] 杨志平,朱胜超, 郭智,等. 锌对CaTiO_3∶Pr~(3+)发光亮度和余辉时间的影响[J]. 中国稀土学报,2002,20: 42-45.
[41] 李秀英,廉世勋,朱爱玲,等. 掺Pr~(3+)钛酸盐红色长余辉发光性质比较[J]. 湖南师范大学自然科学学报 2005, 28 (1): 48-51.
[42] 洪樟连,张朋越,王民权. Ca1 - xZnxTiO_3:Pr3 +的固溶特性及其发光性能[J]. 中国稀土学报,2005, 23 (6): 659-694.
[43] Weiyi Jia, Wuliang Xu, Iris Rivera, et al. Effects of compositional phase transitions on luminescenc of Sr1-xCaxTiO_3:Pr~(3+) [J]. Solid State Communication, 2003, 126: 153-157.
[44] Weiyi Jia, Ange′lica Pe′rez-Andu′ jar, Iris Rivera. Energy Transfer Between Bi~(3+) and Pr~(3+) in Doped CaTiO_3 [J]. Journal of the Electrochemical Society, 2003, 150: 161-164.
[45] S.Okamoto, H. Kobayashi. Enhancement of characteristic red emission from SrTiO_3:Pr~(3+) by Al addition [J]. Journal of Applied physics, 1999, 86: 5594-5597.
[46] S.Okamoto. Characteristic enhancement of emission from SrTiO_3:Pr~(3+) by addition of group-Ⅲb ions [J]. Applied Physics Letters, 2001, 78: 655-657.
[47] S.Okamoto. Emission from BaTiO_3:Pr~(3+) controlled by ionic radius of added trivalent ion [J]. Journal of Applied Physics, 2002, 91: 5492-5495.
[48] Lianhua Tian, Sun-il Mho. Ehanced luminescence of SrTiO_3:Pr~(3+) by incorporation of Li+ ion [J]. Solid State Communication, 2003, 125: 647-651.
[49] K.-A. Hyeona, S.-H. Byeona, J.-C. Parkb, et al. Highly enhanced photoluminescence of SrTiO_3: Pr by substitution of (Li0.5, La0.5) pair for Sr [J]. Solid State Communication, 2000, 115: 99-104.
[50] Jinfeng Tang, Xibin Yu, Liangzhun Yang, et al. Preparation and Al~(3+) enhanced photoluminescence properties of CaTiO_3: Pr~(3+) [J]. Materials letters, 2006, 60: 326-329.
[51] 李治霞, 张玉奇, 廖亮. CaTiO_3:Pr~(3+) 红色磷光体余辉性能的改进 [J]. 重庆大学学报,2004, 27 (7): 53-55.
[52] Xianmin Zhang, Jiahua Zhang, Xia Zhang, et al. Enhancement of red fluorescence and afterglow in CaTiO_3: Pr~(3+) by addition of Lu_2O_3 [J]. Journal of Luminescence, 2007, 122-123: 958-960.
[53] Yuanhua Lin, Zhongtai Zhang, Feng Zhang,et al. Preparation of the ultrafine SrAl2O4: Eu, Dy needle-like phosphor and its optical properties [J]. Materials Chemistry and Physics, 2000, 65: 103–106.
[54] 尹盛玉,赵长亮,宋华杰,等. 长余辉材料余辉性能测试的影响因素 [J]. 中南民族大学学报(自然科学版),2006,26(4): 5-7.
[55] Shengyu Yin, Donghua Chen, Wanjun Tang, et al. Synthesis of CaTiO_3: Pr, Al phosphors by sol-gel method and their luminescence properties [J]. Journal of Materials Science, 2007, 42 (8):2886-2890.
[56] 宋华杰,尹盛玉,赵长亮,等. H_3BO_3 对 SrAl_2O_4: Eu~(2+), Dy~(2+), Nd~(3+)长余辉发光材料性能的影响[J]. 中南民族大学学报(自然科学版),2006, 25(3): 16-19.
[57] 赵长亮,尹盛玉,徐咏钗,等. SrAl_2O_4:Eu~(2+),Dy~(3+),Ho~(3+)长余辉发光材料的燃烧法合成及其发光性能研究[J].中南民族大学学报(自然科学版),2007, 26 (2).
[58] 徐咏钗, 宋华杰, 尹盛玉,等. 燃烧法合成 Eu~(2+), Dy ~(3+), Nd ~(3+)共掺杂的硅酸盐长余辉发光材料 Sr2MgSi2O7和 Sr2ZnSi2O7[J]. 中南民族大学学报(自然科学版),2007, 26 (1): 20-22.
[59] J.McKittrick, L. E. Shea, C. F. Bacalski, et al. The influence of processing parameters on luminescent oxides produced by combustion synthesis [J]. Displays, 1999,19: 169-172.
[60] J.J. Kingsley, K.C. Patil. A novel combustion process for the synthesis of fine particleα-alumina and related oxide materials [J]. Materials Letters, 1988, 6:427-432.
[61] Dae Soo Jung, Seung Kwon Hong, Hyo Jin Lee, et al. Gd2O_3: Eu phosphor particles prepared from spray solution containing boric acid flux and polymeric precursor by spray pyrolysis[J]. Optical Materials, 2006, 28:530-535.
[62] Dae Soo Jung, Seung Kwon Hong, Hyo Jin Lee, et al. Effect of boric acid flux on the characteristics of (CeTb)MgAl11O19 phosphor particles prepared by spray pyrolysis[J]. Journal of Alloys and Compounds, 2005, 398: 309-314.
[63] H.S. Potdar, S.B. Deshpande, S.K. Date, Chemical coprecipitation of mixed (Ba + Ti) oxalates precursor leading to BaTiO_3 powders [J]. Materials Chemistry and Physics, 1999, 58:121-127.
[64] B. Guiffard, M. Troccaz. Low temperature synthesis of stoichiometric and homogeneous lead zirconate titanate powder by oxalate and hydroxide coprecipitation [J]. Material Research Bulletin, 1998, 33:1759-1768.
[65] F. Zhang, T. Karaki, M. Adachi, Synthesis of anzosized (Pb, Sr)TiO_3 perovskite powders by coprecipitation processing[J]. Powder Technology, 2005, 159: 13-16.
[66]Y.B. Khollam, S.V. Bhoraskar, S.B. Deshpande, et al. Simple chemical route for the quantitative precipitation of barium-strontium titanyl oxalate precursor leading to Ba1-xSrTiO_3 powder [J]. Materials Letters, 2003, 57: 1871-1879.
[67]S. Suasmoro, S. Pratapa, D. Hartanto, et al. The characterization of mixed titanate Ba1-xSrxTiO_3 phase formation from oxalate coprecipitated precursor [J]. Journal of European Ceramic Society, 2000, 20: 309-314.
© 2004-2018 中国地质图书馆版权所有 京ICP备05064691号 京公网安备11010802017129号 地址：北京市海淀区学院路29号 邮编：100083 电话：办公室：(+86 10)66554848；文献借阅、咨询服务、科技查新：66554700 |