过渡金属—羧酸配位聚合物的合成、结构及其形貌传递研究
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摘要
本论文致力于利用不同类型的芳香羧酸配体,与过渡金属离子构筑新型的一维链结构配合物,研究配体结构与合成条件对一维链结构形成的影响,探讨其结构与性能的关系。研究以一维链结构配合物作为前驱体转化为无机纳米晶的形貌传递机理和规律,为一维氧化物纳米结构材料的控制合成开辟新的思路。
论文主要研究了苯二甲酸、异烟酸配体与过渡金属离子构筑的具有一维链结构的配位聚合物的合成、结构及其性能;对利用具有一维链状结构的配位聚合物作为前驱体通过固相转化合成氧化物纳米线的方法做了重点的研究和讨论。
以苯二甲酸为配体利用溶剂热方法合成了3个配位聚合物[C_8H_6CdO_5]_n(1)、[C_8H_(10)CdO_7]_n·4H_2O(2)和[C_8H_6CdO_5]_n(3),利用单晶X-射线衍射方法确定了其晶体结构。结构分析表明配合物(2)具有一维链结构,(1)和(3)为三维网状结构。固态荧光光谱分析表明三个配位聚合物均表现出较强的蓝色荧光。以异烟酸为配体利用溶剂热方法合成了4个异质同构的超分子化合物[C_(12)H_(16)MN_2O_8](M=Co(4),Zn(5),Cd(6),Mn(7))和两个配位聚合物[C_2H_6CoO_6]_n(8)、[C_(12)H_(10)CoN_2O_4]_n(9),利用单晶X-射线衍射确定了其晶体结构。结构分析表明配合物(4-7)为单核结构,单核结构之间通过氢键作用形成三维超分子结构。配合物(8)和(9)为三维网状结构。荧光光谱分析表明由Zn~(2+)、Cd~(2+)两种金属离子形成的配合物(5)和(6)发射出较强的蓝色荧光。
以所合成的具有一维链结构的镉配位聚合物作为前驱体,通过控制一定的条件实现了从一维链结构的配位聚合物前驱体到CdO纳米晶的转化,得到了尺寸均匀的超长CdO纳米线,分别对其做了XRD、TEM、EDX、HRTEM以及光学性能表征,并讨论了纳米线的生长机理。该结果表明,前驱体在分子尺度上的一维链几何形态在固相转化过程中被传递下来,揭示了从分子尺度上的形貌向纳米尺度形貌进行传递的可能性,为从分子尺度上实现纳米材料形貌的控制提供了思路。
The aim of this thesis is to synthesize new coordination polymer with one-dimensional chain structure on the basis of aromatic carboxylic acid ligands and transition metal ions, to study the influence of ligands structure and synthetic conditions to the formation of one-dimensional chain, and to explore the relationships between structure and property. Another aim of this thesis is to study the morphology transfer mechanism and rules of coordination compound precursors with one-dimensional chain transformed to inorganic nano-crystals, to find a new way for the controlling synthesis of one-dimensional nano-structural materials.
This thesis investigated the synthesis, structure and property of coordination polymers with one-dimensional chain structure constructed from benzene-dicarboxylic acid, iso-nicotinic acid and transition metal ion; the procedure via solid-state transformation of coordination polymer with one-dimensional chain to synthesize oxide nanowires has been especially investigated and discussed.
Three coordination polymers: [C_8H_6CdO_5]_n(1), [C_8H_(10)CdO_7]_n·4H_2O (2) and [C_8H_6ZnO_5]_n (3) on the basis of benzene-dicarboxylic acid were synthesized by sovol-thermal method and characterized by single crystal X-ray diffraction. Structural analysis revealed that compound (2) displayed one-dimensional chain structure and compound (2) and (3) were three-dimensional network structure. Solid-state fluorescent spectrum revealed that three compounds all displayed strong blue fluorescent. Four iso-structural supra-molecular compounds [C_(12)H_(16)MN_2O_8]_n(M = Co (4), Zn (5), Cd (6), Mn (7)) and two coordination polymers [C_2H_6CoO_6]_n(7), [C_(12)H_(10)CoN_2O_4]_n (8) on the basis of iso-nicotinic acid were synthesized by sovol-thermal method and characterized by single crystal X-ray diffraction. Structural analysis revealed that compound (4-7) were three-dimensional network constructed from hydrogen-bonding interaction between mononuclear structure, compound (8) and (9) were three-dimensional network structure. Solid-state fluorescent spectrum revealed that two compounds (5 and 6) formed by Zn~(2+) and Cd~(2+) displayed strong blue fluorescence.
To control reaction condition, the transformation from coordination polymer to supra-long CdO nano-wires with average diameter was achieved by using synthesized cadmium coordination polymer with one-dimensional structure as precursors. The prepared nano-wires were characterized using XRD, TEM, EDX, HRTEM and its optical properties were examined, and the growth mechanism of nano-wires was discussed. The results indicated that the one-dimensional chain geometry of molecular scale was inherited during the solid-state transformation course. The successful preparation of CdO nano-wires from coordination polymer with one-dimensional chain structure made it possible of morphology transfer from molecular scale to nano-scale and provided a new way for the controlling synthesis of nano-materials in molecular dimensionality.
论文主要研究了苯二甲酸、异烟酸配体与过渡金属离子构筑的具有一维链结构的配位聚合物的合成、结构及其性能;对利用具有一维链状结构的配位聚合物作为前驱体通过固相转化合成氧化物纳米线的方法做了重点的研究和讨论。
以苯二甲酸为配体利用溶剂热方法合成了3个配位聚合物[C_8H_6CdO_5]_n(1)、[C_8H_(10)CdO_7]_n·4H_2O(2)和[C_8H_6CdO_5]_n(3),利用单晶X-射线衍射方法确定了其晶体结构。结构分析表明配合物(2)具有一维链结构,(1)和(3)为三维网状结构。固态荧光光谱分析表明三个配位聚合物均表现出较强的蓝色荧光。以异烟酸为配体利用溶剂热方法合成了4个异质同构的超分子化合物[C_(12)H_(16)MN_2O_8](M=Co(4),Zn(5),Cd(6),Mn(7))和两个配位聚合物[C_2H_6CoO_6]_n(8)、[C_(12)H_(10)CoN_2O_4]_n(9),利用单晶X-射线衍射确定了其晶体结构。结构分析表明配合物(4-7)为单核结构,单核结构之间通过氢键作用形成三维超分子结构。配合物(8)和(9)为三维网状结构。荧光光谱分析表明由Zn~(2+)、Cd~(2+)两种金属离子形成的配合物(5)和(6)发射出较强的蓝色荧光。
以所合成的具有一维链结构的镉配位聚合物作为前驱体,通过控制一定的条件实现了从一维链结构的配位聚合物前驱体到CdO纳米晶的转化,得到了尺寸均匀的超长CdO纳米线,分别对其做了XRD、TEM、EDX、HRTEM以及光学性能表征,并讨论了纳米线的生长机理。该结果表明,前驱体在分子尺度上的一维链几何形态在固相转化过程中被传递下来,揭示了从分子尺度上的形貌向纳米尺度形貌进行传递的可能性,为从分子尺度上实现纳米材料形貌的控制提供了思路。
The aim of this thesis is to synthesize new coordination polymer with one-dimensional chain structure on the basis of aromatic carboxylic acid ligands and transition metal ions, to study the influence of ligands structure and synthetic conditions to the formation of one-dimensional chain, and to explore the relationships between structure and property. Another aim of this thesis is to study the morphology transfer mechanism and rules of coordination compound precursors with one-dimensional chain transformed to inorganic nano-crystals, to find a new way for the controlling synthesis of one-dimensional nano-structural materials.
This thesis investigated the synthesis, structure and property of coordination polymers with one-dimensional chain structure constructed from benzene-dicarboxylic acid, iso-nicotinic acid and transition metal ion; the procedure via solid-state transformation of coordination polymer with one-dimensional chain to synthesize oxide nanowires has been especially investigated and discussed.
Three coordination polymers: [C_8H_6CdO_5]_n(1), [C_8H_(10)CdO_7]_n·4H_2O (2) and [C_8H_6ZnO_5]_n (3) on the basis of benzene-dicarboxylic acid were synthesized by sovol-thermal method and characterized by single crystal X-ray diffraction. Structural analysis revealed that compound (2) displayed one-dimensional chain structure and compound (2) and (3) were three-dimensional network structure. Solid-state fluorescent spectrum revealed that three compounds all displayed strong blue fluorescent. Four iso-structural supra-molecular compounds [C_(12)H_(16)MN_2O_8]_n(M = Co (4), Zn (5), Cd (6), Mn (7)) and two coordination polymers [C_2H_6CoO_6]_n(7), [C_(12)H_(10)CoN_2O_4]_n (8) on the basis of iso-nicotinic acid were synthesized by sovol-thermal method and characterized by single crystal X-ray diffraction. Structural analysis revealed that compound (4-7) were three-dimensional network constructed from hydrogen-bonding interaction between mononuclear structure, compound (8) and (9) were three-dimensional network structure. Solid-state fluorescent spectrum revealed that two compounds (5 and 6) formed by Zn~(2+) and Cd~(2+) displayed strong blue fluorescence.
To control reaction condition, the transformation from coordination polymer to supra-long CdO nano-wires with average diameter was achieved by using synthesized cadmium coordination polymer with one-dimensional structure as precursors. The prepared nano-wires were characterized using XRD, TEM, EDX, HRTEM and its optical properties were examined, and the growth mechanism of nano-wires was discussed. The results indicated that the one-dimensional chain geometry of molecular scale was inherited during the solid-state transformation course. The successful preparation of CdO nano-wires from coordination polymer with one-dimensional chain structure made it possible of morphology transfer from molecular scale to nano-scale and provided a new way for the controlling synthesis of nano-materials in molecular dimensionality.
引文
[1] M. Eddaoudi, D. B. Moler, H. L. Li, B. L. Chen, T. M. Reineke, O. M. Yaghi. Modular chemistry: Secondary building units as a basis for the design of highly porous and robust metal-organic carboxylate frameworks. Acc. Chem. Res., 2001, 34: 319-330.
[2] S. R. Batten, B. F. Hosins, B. Moubaraki, K. S. Murray, R. Robson. Crystal structures and magnetic properties of the interpenetrating rutile-related compounds M(tcm)(2) [M= octahedral, divalent metal; tcm(-) = tricyanomethanide, C(CN)(3)(-)] and the sheet structures of [M(tcm)(2)(EtOH)(2)] (M = Co or Ni). J. Chem. Soc. Dalton Trans., 1999: 2977-2986.
[3] M. J. Plater, M. R. St, J. Foreman, T. Gelbrich, M. B. Hursthouse. Synthesis and characterisation of infinite di- and tri-nuclear zinc co-ordination networks with flexible dipyridyl ligands. J. Chem. Soc. Dalton Trans., 2000,1995.
[4] J. L. C. Rowsell, O. M. Yaghi. Metal-organic frameworks: a new class of porous materials. Micro. Meso. Mater. 2004, 73: 3-14.
[5] Jun Tao, Jian-Xin Shi, Ming-Liang Tong, Xiao-Xia Zhang, Xiao-Ming Chen. A New Inorganic-Organic Photoluminescent Material Constructed with Helical [Zn3(μ_3-OH)(μ_3-OH)] Chains. Inorg. Chem. 2001,40: 6328-6330.
[6] Jun Tao, Ming-Liang Tong, Jian-Xin Shi, Xiao-Ming Chen. Blue photoluminescent zinc coordination polymers with supertetranuclear cores. Chem. Commun. 2000: 2043-2044.
[7] Hong-Ling Gao, Long Yi, Bin Zhao, Xiao-Qing Zhao, Peng Cheng, Dai-Zheng Liao, Shi-Ping Yan. Synthesis and Characterization of Metal-Organic Frameworks Based on 4-Hydroxypyridine-2,6-dicarboxylic Acid and Pyridine-2,6-dicarboxylic Acid Ligands. Inorg. Chem. 2006,45: 5980-5988.
[8] Jing-Cao Dai, Xin-Tao Wu, Zhi-Yong Fu, Chuan-Peng Cui, Sheng-Min Hu, Wen-Xin Du, Li-Ming Wu, Han-Hui Zhang, Rui-Qing Sun. Synthesis, Structure, and Fluorescence of the Novel Cadmium(Ⅱ)-Trimesate Coordination Polymers with Different Coordination Architectures. Inorg. Chem. 2002,41: 1391-1396.
[9] Shu-Mei Yue, Hong-Bin Xu, Jian-Fang Ma, Zhong-Min Su, Yu-He Kan, Heng-Jun Zhang. Design and syntheses of blue luminescent zinc(Ⅱ) and cadmium(Ⅱ) complexes with bidentate or tridentate pyridyl-imidazole ligands. Polyhedron. 2006, 25: 635-644.
[10] Ge Tian, Guangshan Zhu, Qianrong Fang, Xiaodan Guo, Ming Xue, Jinyu Sun, Shilun Qiu. Design, synthesis and fluorescence of two-dimensional pillared layers by connecting infinite one-dimensional chains via 4,40-bipyridine. J. Mol. Stru. 2006, 787: 45-49.
[11]Arpi Majumder, Matthias Westerhausen, Alexander N.Kneifel, Jean-Pascal Sutter, Nathalie Daro, Samiran Mitra.A manganese(Ⅱ) dichloro-bridged one-dimensional polymer: Structural, fluorescence and low-temperature magnetic study.Inorg.Chi.Acta.2006, 359:3841-3846.
[12]Firas F.Awwadi a, Christopher P.Landee, Mark M.Turnbull, Brendan Twamley, Brian M.Wells.Low-dimensional quantum magnetic systems: Synthesis, structure and magnetic behavior of (2,5-dimethylpyrazine)copper(Ⅱ) chloride and synthesis and magnetic behavior of bis(2,6-dirnethylpyrazine)copper(Ⅱ) chloride.Polyhedron.2005,24:2153-2159.
[13]P.Bhuina, U.S.Ray, G.Mostafa, J.Ribas, C.Sinha.One-dimensional azido bridge [1-ethyl-2-(phenylazo)imidazole]-manganese(Ⅱ): Structure of low bridge angle system and magnetism.Inorg.Chi.Acta.2006, 359: 4660-4666.
[14]Tapas Kumar Maji, Inamur Rahaman Laskar, Golam Mostafa, Alan J.Welch, Partha Sarathi Mukherjee, Nirmalendu Ray Chaudhuri.AID thiocyanato bridge nickel(Ⅱ) system: crystal structure and magnetic property.Polyhedron.2001, 20: 651-655.
[15]Hitoshi Kumagai, Yoshimi Oka, Katsuya Inoue, Mohamedally Kurmoo.Hydrothermal synthesis, structure and magnetism of square-grid cobalt(Ⅱ)-carboxylate layered compounds with and without pillars.J.Chem.Soc.Dalton Trans.2002: 3442-3446.
[16]Hee K.Chae, Diana Y.Siberio-Pe'rez, Jaheon Kim, YongBok Go, Mohamed Eddaoudi, Adam J.Matzger, Michael O'Keeffe, Omar M.Yaghi.A route to high surface area, porosity and inclusion of large molecules in crystals.Nature.2004, 427: 523-527.
[17]Tina Duren, Lev Sarkisov, Omar M.Yaghi, Randall Q.Snurr.Design of New Materials for Methane Storage.Langmuir.2004,20: 2683-2689.
[18]Danil N.Dybtsev, Hyungphil Chun, Sun Hong Yoon, Dongwoo Kim, Kimoon Kim.Microporous Manganese Formate: A Simple Metal-Organic Porous Material with High Framework Stability and Highly Selective Gas Sorption Properties.J.Am.Chem.Soc.2004,126: 32-33.
[19]K.Seki, W.Mori.Syntheses and Characterization of Microporous Coordination Polymers with Open Frameworks.J.Phys.Chem.B 2002,106: 1380-1385.
[20]Wenbin Lin, Ling Ma, Owen R.Evans.NLO-active zinc(Ⅱ) and cadmium(Ⅱ) coordination networks with 8-fold diamondoid structures.Chem.Commun.2000: 2263-2264.
[21]Hongwei Hou, Yinglin Song, Yaoting Fan, Linping Zhang, Chenxia Du, Yu Zhu.A novel coordination polymer [Co(NCS)2(bpms)2]? (bpms=l,2-bis(4-pyridylmethyl)disulfenyl): synthesis, crystal structure and third-order nonlinear optical properties.Inorg.Chi.Acta.2001, 316: 140-144.
[22]Yu-Biao Chen, Jian Zhang, Jian-Kai Cheng, Yao Kang, Zhao-Ji Li, Yuan-Gen Yao.1D chain structure, NLO and luminescence properties of [Zn_2(bpp)(pht)_2]_n.Inorg.Chem.Commun.2004, 7: 1139-1141.
[23]Xiangru Meng, Yinglin Song, Hongwei Hou, Yaoting Fan, Gang Li, Yu Zhu.Novel Pb and Zn Coordination Polymers: Synthesis, Molecular Structures, and Third-Order Nonlinear Optical Properties.Inorg.Chem.2003,42: 1306-1315.
[24]Hongwei Hou, Yongli Wei, Yinglin Song, Yu Zhu, Linke Li, Yaoting Fan.Two novel two-dimensional double-sheet layered manganese(Ⅱ) coordination polymers: synthesis,crystal structures and third-order nonlinear optical properties.J.Mater.Chem.2002,12:838-843.
[25]Jung Soo Seo, Dongmok Whang, Hyoyoung Lee, Sung Im Jun, Jinho Oh, Young Jin Jeon, Kimoon Kim.A homochiral metal-organic porous material for enantioselective separation and catalysis.Nature.2000,404: 982-986.
[26]Marta Abrantes, Anabela A.Valente, Isabel S.Goncalves, Martyn Pillinger, Carlos C.Romao.Organotin-oxomolybdate coordination polymers as catalysts for the epoxidation of cyclooctene.J.Mol.Catal.A2005,238: 51-55.
[27]Sang-Kun Yoo, Ji Young Ryu, Jun Yong Lee, Cheal Kim, Sung-Jin Kim, Youngmee Kim.Synthesis, structure and heterogeneous catalytic activity of a coordination polymer containing tetranuclear Cu(Ⅱ)-btp units connected by nitrates.Dalton Trans.2003: 1454-1456.
[28]Wells A.F.Three Dimensional Nets and Polyhedra [M]New York, 1977
[29]Wells A.F.Structrual Inorganic Chemistry, 5thed[M].Oxford Univ.Press, 1983
[30]Hoskins B F, Robson R.Infinite polymeric framework consisting of three-dimensinal linked rod-like segments.J Am Chem Soc,1989,l 11:5962-5964.
[31]L.Carlucci, G.Ciani, P.Macchi, DM Proserpio, S.Rizzato.Complex interwoven polymeric frames from the self-assembly of silver(I) cations and sebaconitrile.Chem.Eur.J.1999, 5: 237-243..
[32]E.Y.Lee, M.P.Suh.A robust porous material constructed of linear coordination polymer chains: Reversible single-crystal to single-crystal transformations upon dehydration and rehydration.Angew.Chem.Int.Ed.2004,43: 2798-2801.
[33]H.R.Moon, J.H.Kim, M.P.Suh.Redox-active porous metal-organic framework producing silver nanoparticles from Ag-I ions at room temperature.Angew.Chem.Int.Ed.2005,44: 1261-1265.
[34]K.T.Holman, H.H.Hammud, S.Isber, M.Tabbal.One-dimensional coordination polymer [Co(H20)4(pyz)](N03)(2)center dot 2H(2)0 (pyz = pyrazine) with intra- and inter-chain H-bonds: structure, electronic spectral studies and magnetic properties Polyhedron.2005, 24: 221-228.
[35]L.Carlucci, G.Ciani, A.Gramaccioli, S.Maggini, D.M.Proserpio.Metal-organic coordination frameworks assembled with the long flexible ligand 4,4 '-bis(imidazol-l-ylmethyl)biphenyl.CrystEngComm.2008,10: 1191-1203.
[36]Y.H.Li, C.Y.Cu, A.M.Goforth, K.D.Shimizu, et al.The first 'two-over/two-under'(20/2U) 2D weave structure assembled from Hg-containing 1D coordination polymer chains.Chem.Commun.2003: 1630-1631.
[37]H.Zhu, C.Huang, W.Huang, S.H.Gou.Anovel coordination polymer constructed from ID neutral chains via inter-chain pi-pi stacking and hydrogen bonding.Inorg.Chem.Commun.2004, 7: 1095-1099.
[38]B.O.Patrick, C.L.Stevens, A.Storr, R.C.Thompson.Structural and magnetic properties of three copper(Ⅱ) pyridine-2,3-dicarboxylate coordination polymers incorporating the same chain motif.Polyhedron.2003,22: 3025-3035.
[39]R.Horikoshi, M.Mikuriya.Self-assembly of repeated rhomboidal coordination polymers from 4,4 "-dipyridyl disulfide and ZnX2 salts (X = SCN, N03, C104) Cryst.Growth Des.2005, 5: 223-230.
[40]Ruiz-Perez, P.Lorenzo-Luis, M.Hernandez-Molina, M.M.Laz, F.S.Delgado.1,2,4,5-benzenetetracarboxylic acid and 4,4 '-bipyridine as ligands in designing low-dimensional coordination polymers.Eur.J.Inorg.Chem.2004: 3873-3879.
[41]J.W.Lee, E.A.Kim, Y.J.Kim, Y.A.Lee, Y.Park, O.S.Jung.Relationship between the ratio of ligand to metal and the coordinating ability of anions.Synthesis and structural properties of AgX-bearing bis(4-pyridyl)dimethylsilane (X- = N02-, N03-, CF3S03-, and PF6(-)).Inorg.Chem.2005,44: 3151-3155.
[42]A.Erxleben.Synthesis and structure of {[Ag(SalGly)]center dot 0.33H(2)O}(n): An infinite double helical coordination polymer.Inorg.Chem.2001, 40: 2928-2931.
[43]X.M.Chen, G F.Liu.Chem.Eur.J.Double-Stranded Helices and Molecular Zippers Assembled from Single-Stranded Coordination Polymers Directed by Supramolecular Interactions.Chem.Eur.J.2002, 8, 4811-4817.
[44]P.Grosshans, A.Jouaiti, V.Bulach, J.M.Planeix, M.W.Hosseini, J.F.Nicoud.Molecular tectonics: from enantiomerically pure sugars to enantiomerically pure triple stranded helical coordination network.Chem.Commun.2003: 1336-1337.
[45] Y. Cui, H. L. Ngo, W. B. Lin. A homochiral triple helix constructed from an axially chiral bipyridine. Chem. Commun. 2003: 1388-1389.
[46] X. J. Luan, Y. Y. Wang, D. S. Li, P. Liu, H. M. Hu, Q. Z. Shi, S. M. Peng. Self-assembly of an interlaced triple-stranded molecular braid with an unprecedented topology through hydrogen-bonding interactions. Angew. Chem. Int. Ed. 2005,44: 3864-3867.
[47] X. J. Luan, X. H. Cai, Y. Y. Wang, D. S. Li, C. J. Wang, P. Liu, H. M. Hu. An investigation of the self-assembly of neutral, interlaced, triple-stranded molecular braids. Chem. Eur. J. 2006,12: 6281-6289.
[48] Y. Cui, S. J. Lee, W. Lin. Interlocked chiral nanotubes assembled from quintuple helices J. Am. Chem. Soc. 2003,125: 6014-6015.
[49] A. J. Blake, M. T. Brett, N. R. Champness, A. Khlobystov, D. L. Long, C. Wilson, et al. Inorganic-organic interpenetrating frameworks: 4,4 '-bipyridine N,N '-dioxide as a bridging hydrogen-bond acceptor. Chem. Commun. 2001: 2258-2259.
[50] M. Maekawa, H. Kanoka, Y. Suenage, T. Kuroda-Sowa, M. Munakata. A variety of one-, two- and three-dimensional copper(Ⅰ) and silver(Ⅰ) co-ordination polymers assembled by l,4-bis(4-pyridyl)butadiyne and 1,4-bis(2-pyridyl)butadiyne. J. Chem. Soc. Dalton. Trans. 2000: 4160-4166.
[51] M. B. Zaman, M. D. Smith, D. M. Ciurtin, H. Loye. Zur. New Cd(Ⅱ)-, Co(Ⅱ)-, and Cu(Ⅱ)-containing coordination polymers synthesized by using the rigid ligand 1,2-bis(3-pyridyl)ethyne (3,3'-DPA). Inorg. Chem. 2002: 41: 4895-4903.
[52] Y. B. Dong, R. C. Layland, M. D. Smith, N. G. Pschirer, H. Loye. Zur. Syntheses and characterizations of one-dimensional coordination polymers generated from cadmium nitrate and bipyridine ligands. Inorg. Chem. 1999, 38: 3056-3060.
[53] E. Q. Gao, Y. X. Xu, C. H. Yan. Two square grid coordination polymers with manganese(Ⅱ) and l,4-bis(imidazole-l-ylmethyl) benzene. CrystEngCommun. 2004, 6: 298-302.
[54] Y. R. Xie, H. Zhao, X. S. Wang, Z. R. Qu, R. G Xiong, X. A. Xue, et al. 2D chiral uranyl(Ⅵ) coordination polymers with second-harmonic generation response and ferroelectric properties. Eur. J. Inorg. Chem. 2003: 3712-3715.
[55] K. Uemura, S. Kitagawa, K. Fukui, K. Fukui, K. Saito. A contrivance for a dynamic porous framework: Cooperative guest adsorption based on square grids connected by amide-amide hydrogen bonds. J. Am. Chem. Soc. 2004,126: 3817-3828.
[56] Z. Spichal, M. Necas, J. Pinkas, J. Novosad. The synthesis and crystal structures of two-dimensional coordination polymers of Ph2P(O)-CH2CH2-P(O)Ph-2 and Ph2P(0)-C5H3N-P(0)Ph-2 with praseodymium.Inorg.Chem.2004,43: 2776-2778.
[57]X.M.Ouyang, B.L.Fei, T.A.Okamura, H.W.Bu, W.Y.Sun, W.X.Tang, et al.Syntheses, crystal structures, and properties of four two-dimensional network complexes with multidentate bis(Schiff base) ligands.Eur.J.Inorg.Chem.2003: 618-627.
[58]G.B.Gardener, D.Venkataraman, J.S.Moore, S.Lee.Spontaneous assembly of a hinged coordination network.Nature.1995, 374,792-795.
[59]D.M.Whang, K.M.Park, J.Heo, P.Ashton, K.Kim.Molecular necklace: Quantitative self-assembly of a cyclic oligorotaxane from nine molecules.J.Am.Chem.Soc.1998,120:4899-4900.
[60]J.F.Ma, J.F.Liu, Y.Xing, H.Q.Jia, Y.H.Lin.Networks with hexagonal circuits in co-ordination polymers of metal ions (Zn-Ⅱ, Cd-Ⅱ) with 1,1 '-(l,4-butanediyl)bis(imidazole).J.Chem.Soc.Dalton.Trans.2000: 2403-2407.
[61]J.H.Luo, M.C.Hong, R.H.Wang, R.Cao, L.Han, Z.Z.Lin.Eur.J.Inorg.Chem.2003: 2705-2710.
[62]A.M.Madalan, V.C.Kravtsov, Y.A.Simonov, V.Voronkovo, L.Korobchenko, N.Avarari, et al.A unique diamondoid network resulting from the convolution of pi-pi stacking and lipophilic interactions.Crystal Growth & Design.2005, 5: 45-47.
[63]X.J.Li, R.Cao, D.F.W, H.Bi, Y.Q.Wang, X, Li, et al.Syntheses and characterizations of zinc(Ⅱ) compounds containing three-dimensional interpenetrating diamondoid networks constructed by mixed ligands.Crystal Growth & Design.2004,4: 775-780.
[64]K.A.Hirsch, S.R.Wilson, J.S.Moore.A Packing Model for Interpenetrated Diamondoid Structures - an Interpretation Based on the Constructive Interference of Supramolecular Networks.Chemistry - A European Journal.2006, 3: 765-771.
[65]S.Subramanian, M.J.Zaworotko.Porous Solids by Design: [Zn(4,4 -bpy)2(SiF6)]_n·xDMF, a Single Framework Octahedral Coordination Polymer with Large Square Channels.Angew.Chem.Int.Ed.2003, 34: 2127-2129.
[66]L.Carlucci, G Ciani, D.M.Proserpio, A.Sironi.Polymeric networks of silver(I) and copper(I) ions linked by an anionic acetonyl derivative of tetracyanoethylene.Angew.Chem.Int.Ed.1996,35:1088-1090.
[67]A.Rujiwatra, C.J.Kepert, M.J.Rosseinsky.The organo-pillared porous magnetic framework Co-4(SO4)(OH)(6)(H2NC2H4NH2)(0.5)center dot 3H(2)0.Chem.Commun.1999: 2307-2308.
[68]R.Kitaura, K.Seki, G Akiyama, S.Kitagawa.Porous coordination-polymer crystals with gated channels specific for supercritical gases.Angew.Chem.Int.Ed.2003, 42: 428-431.
[69] J. C. Dai, X. T. Wu, S. M. Hu, Z. Y. Fu, J. J. Zhang, W. X. Du, H. H. Zhang, et al. Crystal engineering of the coordination architecture of metal polycarboxylate complexes by hydrothermal synthesis: Assembly and characterization of four novel cadmium polycarboxylate coordination polymers based on mixed ligands. Eur. J. Inorg. Chem. 2004: 2096-2106.
[70] X. C. Huang, Y. Y. Lin, J. P. Zhang, X. M. Chen. Ligand-directed strategy for zeolite-type metal-organic frameworks: Zinc(II) imidazolates with unusual zeolitic topologies. Angew. Chem. Int. Ed. 2006,45: 1557-1559.
[71] Y. Q. Tian, C. X. Cai, Y. Ji, X. Z. You, S. M. Peng, G. H. Lee. [Co_5(im)_(10)·2MB]_∞: A Metal-Organic Open-Framework with Zeolite-Like Topology. Angew. Chem. Int. Ed. 2002, 41: 1384-1386.
[72] Y. G. Li, N. Hao, Y. Lu, E. B. Wang, Z. H. Kang, C. W. Hu. New Two-Dimensional Metal-Organic Networks Constructed from 1,2,4,5-Benzenetetracarboxylate and Chelate Ligands. Inorg. Chem. 2003,42, 3119-3124.
[73] S Noro, R Kitaura, M Kondo. Framework engineering by anions and porous functionalities of Cu(Ⅱ)/4,4'-bpy coordination polymers. J. Am. Chem. Soc. 2002,124: 2568-2571.
[74] O. M. Yaghi, H. L. Lian, T. L. Groy. A Molecular Railroad with Large Pores: Synthesis and Structure of Ni(4,4'-bpy)_(2.5)(H_2O)_2(ClO_4)_2·1.5(4,4'-bpy)·2H_2O. Inorg. Chem. 1997, 36: 4292-4293.
[75] K Biradha, M Fujita. A springlike 3D-coordination network that shrinks or swells in a crystal-to-crystal manner upon guest removal or readsorption. Angew. Chem. Int. Ed. 2002, 41:3392-3396.
[76] Y.H.Liu, Y.L.Lu, H. C.Wu, J.C.Wang, K. L. Lu. [Cd(Ⅱ)(bpdc)H_2O]_n: a robust, thermally stable porous framework through a combination of a 2-D grid and a cadmium dicarboxylate cluster chain (H_2bpdc = 2,2'-Bipyridyl-4,4'-dicarboxylic acid). Inorg. Chem. 2002,41:2592-2597.
[77] M. Nakash, Z. Clyde-Waston, N. Feeder, S. J. Teat, J. K. M. Sanders. Hydrogen-bonding clusters leading to formation of a supramolecular dimmers of metalloporphyrin receptors: modulation of Lewis acidity by π-π interactions. Chem. Eur. J. 2000, 6: 2112-2119.
[78]陈晓明,童明良。羧基配位结构——共面与非共面。大学化学,1997,12:24-27.
[79] Xin-Yi Wang, Hai-Yan Wei, Zhe-Ming Wang, Zhi-Da Chen, Song Gao. Formate-The Analogue of Azide: Structural and Magnetic Properties of M(HCOO)_2(4,4'-bpy)·H_2O (M = Mn, Co, Ni; n = 0, 5). Inorg. Chem. 2005, 44: 572-583.
[80]D.Czakis-Sulikowska, J.Radwa_ska-Doczekalska* A.Czylkowska, M.Markiewicz A.Broniarczyk.New Complexes of Mn(Ⅱ), Co(Ⅱ), Ni(Ⅱ) and Cu(Ⅱ) with 2,2' or 2,4'-Bipyridine and Formats: Synthesis, thermal and other properties.J.Therm.Anal.Cal.2006, 86: 327-335.
[81]Wei Huang, Dahua Hua, Shaohua Gou, Suchada Chantrapromma, Hoong-Kun Fun, Yan Xu, Qinjing Meng.Two formate-bridging coordination polymers containing dinuclear zinc(Ⅱ) macrocyclic components.Inorg.Chi.Acta.2003, 342: 9-15.
[82]Zheming Wang, Bin Zhang, Katsuya Inoue, Hideki Fujiwara, Takeo Otsuka,Hayao Kobayashi, Mohamedally Kurmoo.Occurrence of a Rare 49-66 Structural Topology,Chirality, and Weak Ferromagnetism in the [NH4][M~Ⅱ(HCOO)_3](M = Mn, Co, Ni) Frameworks.Inorg.Chem.2007,46: 437-445.
[83]Danil N.Dybtsev, Hyungphil Chun, Sun Hong Yoon, Dongwoo Kim, Kimoon Kim.Microporous Manganese Formate: A Simple Metal-Organic Porous Material with High Framework Stability and Highly Selective Gas Sorption Properties.J.Am.Chem.Soc.2004, 126: 32-33.
[84]Yanqin Wang, Rong Cao, Wenhua Bi, Xing Li, Daqiang Yuan, Daofeng Sun.Four novel porous frameworks constructed by formate ligand.Microporous and Mesoporous Materials.2006,91:215-220.
[85]R.Kuhlman, G.L.Schimek, J.W.Kolis.An extended solid from the solvothermal decomposition Co(Acac)3: Stucture and characterization of Co_5(OH)_2(O_2CCH_3)_8·2H_2O.Inorg.Chem.1999,38:194-196.
[86]E.Coronado, J.R.Galan-Maseallros, C.J.Comez-Garcia, J.Ensling, P.Giitlich.Hybrid molecular magnets obtained by insertion of deeamethylmetalloeenium cations into layered,bimetallicoxalate complexes: [ZinCp*2][MnM(ox)3](Z = Co, Fe; M11 = Mn, Fe, Co, Zn; ox =oxalate; Cp* = PentamethyleycloPentadieny).Chem.Eur.J.2000, 6: 552-563.
[87]R.Vaidhyanathan, S.Natarajan, C.N.R.Rao.Aliphatic dicarboxylates with three-dimensional metal-organic frameworks possessing hydrophobic channels.J.Chem.Soc,DaltonTrans.2003, 8: 1459-1464.
[88]R.Vaidhyanathan, S.Natarajan, C.N.R.Rao.Open-framework cadmium succinates of different dimensionalities.Inorg.Chem.2002,41: 5226-5234.
[89]B.Rather, M.J.Zaworotko.A 3-D metal-organic network, [Cu2(glutarate)2(4,4'-bipyridine)], that exhibits single-crystal dehydration and rehydration.Chem.Commun.2003, 7: 830-831.
[90]Hailian Li, Mohamed Eddaoudi, M.O'Keeffe, O.M.Yaghi.Design and synthesis of an exceptionally stable and highly porous metal-organic framework.Nature.1999, 402: 276-279.
[91]Hee K.Chae, Jaheon Kim, Mohamed Eddaoudi, Omar M.Yaghi.A route to high surface area, porosity and inclusion of large molecules in crystals.Nature, 2004,427: 523-527.
[92]Banglin Chen, Mohamed Eddaoudi, Omar M.Yaghi.Interwoven metal-organic framework on aperiodic minimal surface with extra-large pores.Science.2001,291:1021-1023.
[93]T.M.Reineke, M.Eddaoudi, Omar M.Yaghi.From condensed lanthanide coordination solids to microporous frameworks having accessible metal sites.J.Am.Chem.Soc.1999,121:1651-1657.
[94]Mohamed Eddaoudi, Jaheon Kim, Nathaniel Rosi, Omar M.Yaghi.Systematic design of pore size and functionality in isoreticular MOFs and their application in methane storage.Science.2002,295: 469-472.
[95]S S Y Chi, S M F Lo, J P H Charmant.A chemically functionalizable nanoporous material [Cu_3(TMA)_2(H_2O)_3]n.Science.1999, 378: 703-708.
[96]O M Yaghi, G Li, H L Li.Selective binding and removal of guests in a microporous metal-organic framework.Nature.1995, 378: 703-706.
[97]B L Chen, M Eddaoudi, T M Reineke.Cu_2(ATC).6H_2O: Design of open metal sites in porous metal-organic crystals (ATC: 1,3,5,7-adamantane tetracarboxylate).J.Am.Chem.Soc.2000,122:11559-11562.
[98]S.R.J.John.Copper as possible active forms of the antiarthritie agents.J.Med.Chem.1976,19: 135-148.
[99]R.G.Xiong, S.R.Wilson, W.B.Lin.Bis(isonicotinato)iron(Ⅱ): a rare, neutral three-dimensional iron coordination polymer.J.Chem.Soc, Dalton Trans.1998,24:4089-4090.
[100]Jin-Yu.Sun, Lin-hongWeng, Ya-ming Zhou, Jin-xi Chen, Zhen-xia Chen, Zhi-cheng Liu, Dong-yuan Zhao.QMOF-1 and QMOF-2: Three-Dimensional Metal-Organic Open Frameworks with a Quartzlike Topology**.Angew.Chem.Int.Ed.2002,41: 4471-4473.
[101]Mary E.Chapman, Ponnaiyan Ayyappan, Bruce M.Foxman, Gordon T.Yee, Wenbin Lin.Synthesis, X-ray Structures, and Magnetic Properties of Copper(Ⅱ) Pyridinecarboxylate Coordination Networks.Crystal Growth & Design.2001, 1: 159-163.
[102]Liang Y,Cao R,Su W.Syntheses, Structures and Magnetic Properties of Two Gadolinium(Ⅲ)-Copper(Ⅱ) Coordination Polymers by a Hydrothermal Reaction.Angew.Chem.Int.Ed.2000, 39: 3304-3307.
[103]Bin Zhao, Peng Cheng, Yan Dai, Cai Cheng, Dai-Zheng Liao, Shi-Ping Yan, et al.A Nanotubelar 3D Coordination Polymer Based on a 3d-4f Heterometallic Assembly.Angew.Chem.Int.Ed.2003,42: 934-936.
[104]X.M.Zhang, X.M.Chen.A New Porous 3-D Framework Constructed From Fivefold arallel Interpenetration of 2-D (6,3) Nets: A Mixed-Valence Copper(I, Ⅱ) Coordination Polymer [Cu_2~ⅠCu~Ⅱ(4,4'-bpy)_2(pydc)_2]-4H_2O.Eur.J.Inorg.Chem.2003,413-417.
[105]X.Wang, C.Qin, E.B.Wang, Y.Li, N.Hao, C.Hu, L.Xu.Synthesis, structures, andphotoluminescence of a novel class of d10 metal complexes constructed from pyridine-3,4-dicarboxylic acid with different coordination architectures.Inorg.Chem.2004, 43: 1850-1856.
[106]L.Lu, E.Shen, Y.Li, D.Xiao, E.B.Wang, L.Xu.A novel pillar-layered organic-inorganic hybrid based on lanthanide polymer and polyomolybdate clusters: new opportunity toward the design and synthesis of porous framework.Cryst.Growth.Des.2005,5: 65-67.
[107]S.I.Noro, S.Kitagawa, M.Yamashita, T.Wada.New microporous coordination polymer affording guest-coordination sites at channel walls.Chem.Commun.2002, 3:222-223.
[108]S.Kitagawa, R.Kitaura, S.I.Noro.Functional porous coordination polymers.Angew.Chem.Int.Ed.2004,43: 2334-2375.
[109]M.Kondo, T.Okubo, A.Asami, S.Noro, T.Yoshitomi, S.Kitagawa, T.Ishii, H.Matsuzaka, K.Seki.Rational synthesis of stable channel-like cavities with methane gas adsorption properties: [{Cu_2(pzdc)_2(L)}_n](pzdc = pyrazine-2,3-dicarboxylate; L = a pillar ligand).Angew.Chem.Int.Ed.1999, 38: 140-143.
[110]S.Konar, S.C.Manna, E.Zangrando, N.R.Chaudhuri.Crystal structure and magnetic behavior of a copper(Ⅱ)-(pyrazine-2,3-dicarboxylate) coordination polymer: 3D architecture stabilized by H-bonding.Inorg.Chi.Acta.2004, 357: 1593-1597.
[111]O.R.Evans, W.B.Lin.Crystal engineering of nonlinear optical materials based on interpenetrated diamondoid coordination networks.Chem.Mater.2001,13: 2705-2712.
[112]M.Du, X.J.Zhao, Y.Wang.Crystal engineering of a versatile building block toward the design of novel inorganic-organic coordination architectures.J.Chem.Soc, Dalton Trans.2004,14:2065-2072.
[113]M.Du, C.P.Li, X.J.Zhao.Metal-controlled assembly of coordination polymers with the flexible building block 4-pyridylacetic acid (Hypa).Cryst.Growth.Des.2006, 6: 335-341.
[114]Z.H.Zhang, T.Okamura, Y.Hasegawa, H.Kawaguchi, L.Y.Kong, W.Y.Sun, N.Ueyama.Synthesis, structures, and luminescent and magnetic properties of novel three-dimensional lanthanide complexes with 1,3,5-benzenetriacetate.Inorg.Chem.2005,44:6219-6227.
[115]Z.H.Zhang, Z.L.Shen, T.Okamura, H.F.Zhu, W.Y.Sun, N.Ueyama.Synthesis and structures of two series of coordination frameworks based on the assembly of 1,3,5-benzenetriacetic acid with lanthanide metal salts.Crystal Growth & Design.2005, 5:1191-1197.
[116]H.F.Zhu, J.Fan, T.Okamura, Z.H.Zhang, G X.Liu, K.B.Yu, W.Y.Sun, N.Ueyama.Metal-organic architectures of silver(I), cadmium(Ⅱ), and copper(Ⅱ) with a flexible tricarboxylate ligand.Inorg.Chem.2006,45: 3941-3948.
[117]H.F.Zhu, Z.H.Zhang, W.Y.Sun, T.Okamura, N.Ueyama.Synthesis, structures, and properties of two-dimensional alkaline earth metal complexes with flexible tripodal tricarboxylate ligands.Crystal Growth & Design.2005, 5: 177-182.
[118]Klabunde,Kenneth J．纳米材料化学．第一版．北京：化学工业出版社,2004．
[119]J.T.Hu, T.W.Odom, C.M.Lieber.Chemistry and physics in one dimension:Synthesis and properties of nanowires and nanotubes.Ace.Chem.Res.1999, 32 : 435-445.
[120]Y Huang, X.F.Duan, Y.Cui, L.J.Lauhon, K.H.Kim, C.M.Lieber.Logic gates and computation from assembled nanowire building blocks.Science, 2001, 294: 1313-1317.
[121]Bachtold A, Hadley P, Nakanishi T, Dekker C.Logic circuits with carbon nanotube transistors.Science.2001,294: 1317-1320.
[122]Collier CP, Vossmeyer T, JR Heath.Nanocrystal superlattices.Annu.Rev.Phys.Chem.1998,49:371-404.
[123]Y.W.Wang, L.D.Zhang, G.Z.Wang, X.S.Peng, Z.Q.Chu, C.H.Liang.Catalytic growth of semiconducting zinc oxide nanowires and their photoluminescence properties.Journal of Crystal Growth.2002,234: 171-175.
[124]C.C.Tang, S.S.Fan, Marc Lamy de la Chapelle, P.Li.Silica-assisted catalytic growth of oxide and nitride nanowires.Chemical Physics Letters.2001, 333: 12～15.
[125]J.Zhou, S.Z.Deng, J.Chen, J.C.She, NS Xu.Synthesis of crystalline alumina nanowires and nanotrees.Chemical Physics Letters.2002, 365: 505-508.
[126]J.K.Jian, X.L.Chen, W.J.Wang, L.Dai, Y.P.Xu.Growth and morphologies of large-scale SnO_2 nanowires, nanobelts and nanodendrites.Applied Physics.2003, A76: 291-294.
[127]C.K.Xu, G.D.Xu, Y.K.Liu, G.H.Wang.A simple and novel route for the preparation of ZnO nanorods.Solid State Communications.2002,122: 175-179.
[128]C.K.Xu, Y.K.Liu, G.D.Xu, G.H.Wang.Preparation and characterization of CuO nanorods by thermal decomposition of CuC_2O_4 precursor.Mater.Res.Bull.2002, 37: 2365-2372.
[129]C.K.Xu, G.D.Xu, Y.K.Liu, G.H.Wang.Preparation and characterization of SnO_2 nanorods by thermal decomposition of SnC_2O_4 precursor.Scripta Materialia.2002,46 (1):789-794.
[130]Brinda B.Lakshmi, Charles J.Patrissi, Charles R.Martin.Sol-Gel Template Synthesis of Semiconductor Oxide Micro- and Nanostructures.Chemistry of Materials.1997,9:2544-2550.
[131]S.J.Limmer, S.Seraji, Y.Wu, T.P.Chou, C.Nguyen, G.Z.Cao.Template-Based Growth of Various Oxide Nanorods by Sol-Gel Electrophoresis.Advanced Functional Materials.2002,12: 59-64.
[132]B.C.Satishkumar, A.Govindaraj, M.Nath, C.N.R.Rao.Synthesis of metal oxide nanorods using carbon nanotubes as templates.Joural of Materials Chemistry.2000,10:2115-2119.
[133]Y.K.Liu, C.R.Yin, W.Z.Wang, Y.J.Zhan, G.H.Wang.Synthesis of cadmium oxide nanowires by calcining precursors prepared in a novel inverse microemulsion.J.Mater.Sci.Lett.2002, 21: 137-139.
[134]Y.K.Liu, C.L.Zheng, W.Z.Wang, C.R.Yin, G.H.Wang.Synthesis and Characterization of Rutile SnO_2 Nanorods.Advanced Materials.2001,13: 1883-1887.
[135]L.Gu, Z.H Wu, T.Liu, W.D.Wang, H.S.Zhu.Synthesis of novel Sb_2O_3 and Sb_2O_5 nanorods.Chemical Physics Letter.2000, 318:49-52.
[136]X.Wang, Y.D.Li.Selected-Control Hydrothermal Synthesis of a- and P-MnO_2 Single Crystal Nanowires.J.Am.Chem.Soc.2002,124: 2880-2881.
[137]Z.W.Pan, Z.R.Dai, Z.L.Wang.Nanobelts of Semiconducting Oxides.Science.2001,291: 1947-1949.
[138]W.Z.Wang, Y.J.Zhan, G.H.Wang.One-step, solid-state reaction to the synthesis of copper oxide nanorods in the presence of a suitable surfactant.Chem.Commun.2001: 727-728.
[139]Cheng-Yong Su, Andrea M.Goforth, Mark D.Smith, P.J.Pellechia, Hans-Conrad zur Loye.Exceptionally Stable, Hollow Tubular Metal-Organic Architectures: Synthesis,Characterization, and Solid-State Transformation Study.J.Am.Chem.Soc.2004,126:3576-3586.
[140]Haijun Niu, Mingyuan Gao.Diameter-Tunable CdTe Nanotubes Templated by 1D Nanowires of Cadmium Thiolate Polymer.Angew.Chem.Int.Ed.2006, 45: 6462-6466.
[141] Yujie Xiong, Zhengquan Li, Rong Zhang, Yi Xie, Jun Yang, Changzheng Wu. From Complex Chains to 1D Metal Oxides: A Novel Strategy to Cu_2O Nanowires. J. Phys. Chem. B 2003,107: 3697-3702.
[142] Yujie Xiong, Yi Xie, Zhengquan Li, Changzheng Wu. Growth of Well-Aligned γ-MnO_2 Monocrystalline Nanowires through a Coordination-Polymer-Precursor Route. Chem. Eur. J. 2003,9: 1645-1651.
[143] Zhengquan Li, Yujie Xiong Yi Xie. Selective growth of ZnO nanostructures with coordination polymers. Nanotechnology. 2005,16: 2303-2308.
[144] Xuanjun Zhang, Yi Xie, Qingrui Zhao, Yupeng Tian. 1-D coordination polymer template approach to CdS and HgS aligned-nanowire bundles. New J. Chem. 2003,27: 827-830.
[145] J. Y. Wu, C. H. Chang, T. W. Tseng, K. L. Lu. Synthesis of two-dimensional metal-organic networks from 1,10-phenanthroline-chelated cadmium complex and polycarboxylate. J. Mol. Stru. 2006, 796: 69-75.
[146] T. K. Maji, I. R. Lasker, G. Mostafa, A. J. Welch, P. S. Mukherjee, N. R. Chaudhuri. A ID thiocyanato bridge nickel(Ⅱ) system: crystal structure and magnetic property. Polyhedron. 2001,20:651-655.
[147] A. Majumder, M. Westerhausen, A. N. Kneifel, J. P. Sutler, N. Daro, S. Mitra. A manganese(Ⅱ) dichloro-bridged one-dimensional polymer: structural, fluorescence and low-temperature magnetic study. Inorg. Chi. Acta. 2006, 359: 3841-3846.
[148] P. Bhuina, U. S. Ray, G. Mostafa, J. Ribas, C. Sinha. One-dimensional azido bridge [1-ethyl-2-(phenylazo)imidazole]-manganese(Ⅱ): Structure of low bridge angle system and magnetism. Inorg. Chi. Acta. 2006, 359: 4660-4666.
[149] Q. Shi, R. Cao, D. F. Sun, M. C. Hong, Y. C. Liang. Solvothermal synthesis and crystal structures of two metal coordination polymer with double-chain structures. Polyhedron. 2001, 20: 3287-3293.
[150] H. B. Chen, H. Zhang, J. M. Yang, Z. H. Zhou. Transformation of maleato manganese(Ⅱ): temperature effect and coordination modes. Polyhedron. 2004, 23: 987-991.
[151] Yangguang Li, Na Hao, Ying Lu, Enbo Wang, Zhenhui Kang, Changwen Hu. New Two-Dimensional Metal-Organic Networks Constructed from 1,2,4,5-Benzenetetracarboxylate and Chelate Ligands. Inorg. Chem. 2003, 42: 3119-3124.
[152] Xiaojun Gu, Yanhui Chen, Jun Peng, Zhenyu Shi, Enbo Wang, Ninghai Hu. A new 1D metal-organic coordination polymer with blue fluorescent emission: [Cd_2(1,10'-phen)_2(betc)(H_2O)]n. J. Mol. Stru. 2004, 697: 231-235.
[153]Jing-Yun Wu, Che-Hao Chang, Tien-Wen Tseng, Kuang-Lieh Lu.Synthesis oftwo-dimensional metal-organic networks from 1,10-phenanthroline-chelated cadmium complex and polycarboxylate.J.Mol.Stru.2006,796: 69-75.
[154]Yanjuan Qi, Yonghui Wang, Changwen Hu, Minhua Cao, Li Mao, Enbo Wang.A New Type of Single-Helix Coordination Polymer with Mixed Ligands [M_2(phen)_2(e,a-cis-l,4-chdc)_2(H_2O)_2]n (M = Co and Ni; phen = 1,10-phenanthroline; chdc =cyclohexanedicarboxylate).Inorg.Chem.2003,42: 8519-8523.
[155]Xin-Long Wang, Chao Qin, En-Bo Wang, Lin Xu, Zhong-Min Su, Chang-Wen Hu.Interlocked and Interdigitated Architectures from Self-Assembly of Long Flexible Ligands and Cadmium Salts.Angew.Chem.Int.Ed.2004,43: 5036-5040.
[156]YongBok Go, Xiqu Wang, Ekaterina V.Anokhina, Allan J.Jacobson.A Chain of Changes: Influence of Noncovalent Interactions on the One-Dimensional Structures of Nickel(Ⅱ) Dicarboxylate Coordination Polymers with Chelating Aromatic Amine Ligands.Inorg.Chem.2004,43: 5360-5367.
[157]Xiao-Ming Chen, Gao-Feng Liu.Double-stranded helices and molecular zippers assembled from single-stranded coordination polymers directed by supramolecular interactions.Chem.Eur.J.2002, 8:4811-4816.
[158]O.M.Yaghi, M.O'Keeffe, N.W.Ockwig, H.K.Chae, M.eddaoudi, J.Kim.Reticular synthesis and the design of new materials.Nature.2003,423: 705-714.
[159]M.Eddaoudi, J.Kim, J.B.Wachter, H.K.Chae, M.O'Keeffe, O.M.Yaghi.Porous Metal-Organic Polyhedra: 25 A Cuboctahedron Constructed from 12 Cu_2(CO_2)_4 Paddle-Wheel Building Blocks.J.Am.Chem.Soc.2001,123: 4368-4369.
[160]Hailian Li, Mohamed Eddaoudi, Thomas L.Groy, O.M.Yaghi.Establishing icroporosity in Open Metal-Organic Frameworks: Gas Sorption Isotherms for Zn(BDC)(BDC=l,4-Benzenedicarboxylate).J.Am.Chem.Soc.1998,120: 8571-8572
[161]Andrea C.Sudik, Adrien P.Cote, O.M.Yaghi.Metal-Organic Framework Based on Trigonal Prismatic Building Blocks and the New "acs" Topology.Inorg.Chem.2005, 44:2998-3000.
[162]Lili Wen, Yizhi Li, Dongbin Dang, Zhengfang Tian, Zhaoping Ni, Qingjin Meng.Syntheses, crystal structures and luminescent properties of two new 1D d~(10) coordination polymers constructed from 2,20-bibenzimidazole and 1,4-benzenedicarboxylate.J.Solid.State.Chem.2005,178: 3336-3341.
[163]T.R.Whitfield, X.Q.Wang, L.M.Liu, A.J.Jacobson.Metal-organic frameworks based on iron oxide octahedral chains connected by benzenedicarboxylate dianions.Solid State Sciences.2005,7: 1096-1103.
[164]R.L.Sang, L.Xu.Supramolecular architectures of cadmium(Ⅱ) built of 2,2'-biimmidazole and bifunctional carboxylates: Synthesis, crystal structure and properties.Inorg.Chi.Acta.2006, 359: 525-532.
[165]J.Y.Sun, Y.M.Zhou, Q.R.Fang, Z.X.Chen, L.H.Weng, G.S.Zhu, et al.Construction of 3D Layer-pillared homoligand coordination polymers from a 2D layered precursor.Inorg.Chem.2006,45: 8677-8684.
[166]Ge Tian, Guangshan Zhu, Qianrong Fang, Xiaodan Guo, Ming Xue, Jinyu Sun, Shilun Qiu.Design, synthesis and fluorescence of two-dimensional pillared layers by connecting infinite one-dimensional chains via 4,4'-bipyridine.J.Mol.Struc.2006, 787: 45-49.
[167]Brian Moulton, Michael J.Zaworotko.From Molecules to Crystal Engineering: Supramolecular Isomerism and Polymorphism in Network Solids.Chem.Rev.2001,101:1629-1658.
[168]B.F.Abrahams, M.Moylan, S.D.Orchard.Zinc Saccharate: A Robust, 3D Coordination Network with Two Types of Isolated, Parallel Channels, One Hydrophilic and the other Hydrophobic.Angew.Chem.Int.Ed.2003,42:1848-1851.
[169]O.M.Yaghi, Z.Sun, D.A.Richardson.Directed Transformation of Molecules to Solids: Synthesis of a Microporous Sulfide from Molecular Germanium Sulfide Cages.J.Am.Chem.Soc.1994,116: 807-808.
[170]H.K.Fun, S.S.Sundara Raj, R.G.Xiong, J.L.Zuo, Z.Yu, X.Z.You.A three-dimensional network coordination polymer, (terephthalato)(pyridine)cadmium, with blue fluorescent emission.J.Chem.Soc, Dalton Trans.1999,1915-1916.
[171]C.Jiang, Z.P.Yu, C.Jiao, S.J.Wang, J.M.Li, Z.Y.Wang.Luminescent Zn and Cd Coordination Polymers.Eur.J.Inorg.Chem.2004,4669-4674.
[172]Y.H.Li, Y.Z.Tang, X.F.Huang, R.G.Xiong.The Crystal Structure of a Gatifloxacin Complex and its Fluorescent Property.Z.Anorg.Allg.Chem.2005, 631: 639-641.
[173]N.Hao, E.H.Shen, Y.G.Li, E.B.Wang, C.W.Hu, L.Xu.Novel Cadmium(Ⅱ) Adipate Coordination Polymers With Structural Transformation via Oxalate Ligand: Synthesis, Structures and Fluorescence Properties.Eur.J.Inorg.Chem.2004,4102-4107.
[174]J.H.Luo, M.C.Hong, R.H.Wang, R.Cao, L.Han, Z.Z.Lin.Synthesis, Crystal Structure and Fluorescence of Two Novel Mixed-Ligand Cadmium Coordination Polymers with Different Structural Motifs.Eur.J.Inorg.Chem.2003, 2705-2710.
[175]J.Zhang, Y.R.Xie, Q.Ye, R.G.Xiong, Z.L.Xue, X.Z.You.Blue to Red Fluorescent Emission Tuning of a Cadmium Coordination Polymer by Conjugated Ligands.Eur.J.Inorg. Chem. 2003,2572-2577.
[176] X, Z. Sun, Z. L. Huang, H. Z. Wang, B. H. Ye, X. M. Chen. Synthesis and Crystal Structure of Cadmium Complexes with Thiophene-dicarboxylate and Bipyridine-like Ligands. Z. Anorg. Allg. Chem. 2005, 631: 919-923.
[177] B. Valeur, Molecular Fluorescence: Princeples and Applications, Wiley-VCH, Weiheim, 2002.
[178]毛红艳.多吡啶、多羧酸构筑的功能性配合物的结构和性能研究.东北师范大学博士学位论文.2005,28.
[179] S. Noro, S. Kitagawa, M. Kondo, K. Seki, Angew. Chem. Int. Ed., 39 (2000) 2081.
[180] J. Soo, D. Whang, H. Lee, S. I. Jun, J. Oh, Y. J. Jeon, K. Kim, Nature., 402 (2000) 982.
[181] C. B. Aakeroy, A. M. Beatty, D. S. Leinen, Angew. Chem. Int. Ed., 38 (1999) 1815.
[182] C. B. Aakeroy, A. M. Beatty, D. S. Leinen, K. R. Lorimer, Chem. Commun., (2000) 935.
[183] R. Sekiya, S. Nishikiori, Chem. Commun., (2002) 2612.
[184] J. G. Mao, H. J. Zhang, J. Z. Ni, S. B. Wang, TCW Mak. Structural characterization and luminescence studies of new lanthanide(Ⅲ) complexes with nicotinic and isonicotinic acid N-oxides. Polyhedron. 1998,17: 3999-4009.
[185] Hong-Sheng Wang, Wei Shi, Bin Zhai, Jian-Gong Ma, Jun Xia, Peng Cheng. Two 2D cadmium coordination polymers with 3,4-pyridinedicarboxylic acid. J. Mol. Stru. 2007, 833: 102-107.
[186] Yen-Hsiang Liu, Yi-Long Lu, Hui-Lien Tsai, Ju-Chun Wang, Kuang-Lieh Lu. Hydrothermal Synthesis, Crystal Structure, and Magnetic Property of Copper(Ⅱ) Coordination Networks with Chessboard Tunnels. Journal of Solid State Chemistry. 2001, 158:315-319.
[187] Zheng He, En-Qing Gao, Zhe-Ming Wang, Chun-Hua Yan, Mohamedally Kurmoo. Coordination Polymers Based on Inorganic Lanthanide(Ⅲ) Sulfate Skeletons and an Organic Isonicotinate N-oxide Connector: Segregation into Three Structural Types by the Lanthanide Contraction Effect. Inorg. Chem. 2005, 44: 862-874.
[188] Mary E. Chapman, Ponnaiyan Ayyappan, Bruce M. Foxman, Gordon T. Yee, Wenbin Lin. Synthesis, X-ray Structures, and Magnetic Properties of Copper(Ⅱ) Pyridinecarboxylate Coordination Networks. Crystal Growth & Design. 2001,1: 159-163.
[189] Ryo Sekiya, Shin-ichi Nishikiori, Katsuyuki Ogura. Crystalline Inclusion Compounds Constructed through Self-Assembly of Isonicotinic Acid and Thiocyanato Coordination Bridges. J. Am. Chem. Soc. 2004, 126: 16587-16600.
[190]杨华明,张科,史蓉蓉,李云龙,张向超.CdO纳米晶的固相合成及晶化动力学研 究.材料科学与工程,2005,23(4):503-506.
[191] V. V. Sobolev, D. O. Mordas. Electron transitions of cadmium oxide. J. Appl. Spectrosc. 2003, 70: 965-968.
[192] R. S. Mane, H. M. Pathan, C. D. Lokhande, Sung-Hwan Han. An effective use of nanocrystalline CdO thin films in dye-sensitized solar cells. Solar Energy, 2006, 80: 185-190.
[193] X. S. Peng, X. F. Wang, Y. W. Wang, C. Z. Wang, G. W. Meng, L. D. Zhang. Novel method synthesis of CdO nanowires. J. Phys. D: Appl. Phys. 2002, 35: L101-104.
[194] Y. Jiang, Y. J. Zhu, G. F. Cheng. Synthesis of Bi2Se3 Nanosheets by Microwave Heating Using an Ionic Liquid. Crystal Growth & Design. 2006, 6: 2174-2176.
[195] Moumita, Ghosh, C.N.R. Rao. Chem. Phys. Lett. 2004, 393: 493-497.
[196] X. C. Wu, R. Y. Wang, B. S. Zou, L. Wang, S. M. Liu, J. R. Xu. J. Mater. Res. 1998,13: 604-607.
[197]中本一雄.无机和配位化合物的红外和拉曼光谱[M].第一版,北京:化学工业出版社.1991:237-238.
[2] S. R. Batten, B. F. Hosins, B. Moubaraki, K. S. Murray, R. Robson. Crystal structures and magnetic properties of the interpenetrating rutile-related compounds M(tcm)(2) [M= octahedral, divalent metal; tcm(-) = tricyanomethanide, C(CN)(3)(-)] and the sheet structures of [M(tcm)(2)(EtOH)(2)] (M = Co or Ni). J. Chem. Soc. Dalton Trans., 1999: 2977-2986.
[3] M. J. Plater, M. R. St, J. Foreman, T. Gelbrich, M. B. Hursthouse. Synthesis and characterisation of infinite di- and tri-nuclear zinc co-ordination networks with flexible dipyridyl ligands. J. Chem. Soc. Dalton Trans., 2000,1995.
[4] J. L. C. Rowsell, O. M. Yaghi. Metal-organic frameworks: a new class of porous materials. Micro. Meso. Mater. 2004, 73: 3-14.
[5] Jun Tao, Jian-Xin Shi, Ming-Liang Tong, Xiao-Xia Zhang, Xiao-Ming Chen. A New Inorganic-Organic Photoluminescent Material Constructed with Helical [Zn3(μ_3-OH)(μ_3-OH)] Chains. Inorg. Chem. 2001,40: 6328-6330.
[6] Jun Tao, Ming-Liang Tong, Jian-Xin Shi, Xiao-Ming Chen. Blue photoluminescent zinc coordination polymers with supertetranuclear cores. Chem. Commun. 2000: 2043-2044.
[7] Hong-Ling Gao, Long Yi, Bin Zhao, Xiao-Qing Zhao, Peng Cheng, Dai-Zheng Liao, Shi-Ping Yan. Synthesis and Characterization of Metal-Organic Frameworks Based on 4-Hydroxypyridine-2,6-dicarboxylic Acid and Pyridine-2,6-dicarboxylic Acid Ligands. Inorg. Chem. 2006,45: 5980-5988.
[8] Jing-Cao Dai, Xin-Tao Wu, Zhi-Yong Fu, Chuan-Peng Cui, Sheng-Min Hu, Wen-Xin Du, Li-Ming Wu, Han-Hui Zhang, Rui-Qing Sun. Synthesis, Structure, and Fluorescence of the Novel Cadmium(Ⅱ)-Trimesate Coordination Polymers with Different Coordination Architectures. Inorg. Chem. 2002,41: 1391-1396.
[9] Shu-Mei Yue, Hong-Bin Xu, Jian-Fang Ma, Zhong-Min Su, Yu-He Kan, Heng-Jun Zhang. Design and syntheses of blue luminescent zinc(Ⅱ) and cadmium(Ⅱ) complexes with bidentate or tridentate pyridyl-imidazole ligands. Polyhedron. 2006, 25: 635-644.
[10] Ge Tian, Guangshan Zhu, Qianrong Fang, Xiaodan Guo, Ming Xue, Jinyu Sun, Shilun Qiu. Design, synthesis and fluorescence of two-dimensional pillared layers by connecting infinite one-dimensional chains via 4,40-bipyridine. J. Mol. Stru. 2006, 787: 45-49.
[11]Arpi Majumder, Matthias Westerhausen, Alexander N.Kneifel, Jean-Pascal Sutter, Nathalie Daro, Samiran Mitra.A manganese(Ⅱ) dichloro-bridged one-dimensional polymer: Structural, fluorescence and low-temperature magnetic study.Inorg.Chi.Acta.2006, 359:3841-3846.
[12]Firas F.Awwadi a, Christopher P.Landee, Mark M.Turnbull, Brendan Twamley, Brian M.Wells.Low-dimensional quantum magnetic systems: Synthesis, structure and magnetic behavior of (2,5-dimethylpyrazine)copper(Ⅱ) chloride and synthesis and magnetic behavior of bis(2,6-dirnethylpyrazine)copper(Ⅱ) chloride.Polyhedron.2005,24:2153-2159.
[13]P.Bhuina, U.S.Ray, G.Mostafa, J.Ribas, C.Sinha.One-dimensional azido bridge [1-ethyl-2-(phenylazo)imidazole]-manganese(Ⅱ): Structure of low bridge angle system and magnetism.Inorg.Chi.Acta.2006, 359: 4660-4666.
[14]Tapas Kumar Maji, Inamur Rahaman Laskar, Golam Mostafa, Alan J.Welch, Partha Sarathi Mukherjee, Nirmalendu Ray Chaudhuri.AID thiocyanato bridge nickel(Ⅱ) system: crystal structure and magnetic property.Polyhedron.2001, 20: 651-655.
[15]Hitoshi Kumagai, Yoshimi Oka, Katsuya Inoue, Mohamedally Kurmoo.Hydrothermal synthesis, structure and magnetism of square-grid cobalt(Ⅱ)-carboxylate layered compounds with and without pillars.J.Chem.Soc.Dalton Trans.2002: 3442-3446.
[16]Hee K.Chae, Diana Y.Siberio-Pe'rez, Jaheon Kim, YongBok Go, Mohamed Eddaoudi, Adam J.Matzger, Michael O'Keeffe, Omar M.Yaghi.A route to high surface area, porosity and inclusion of large molecules in crystals.Nature.2004, 427: 523-527.
[17]Tina Duren, Lev Sarkisov, Omar M.Yaghi, Randall Q.Snurr.Design of New Materials for Methane Storage.Langmuir.2004,20: 2683-2689.
[18]Danil N.Dybtsev, Hyungphil Chun, Sun Hong Yoon, Dongwoo Kim, Kimoon Kim.Microporous Manganese Formate: A Simple Metal-Organic Porous Material with High Framework Stability and Highly Selective Gas Sorption Properties.J.Am.Chem.Soc.2004,126: 32-33.
[19]K.Seki, W.Mori.Syntheses and Characterization of Microporous Coordination Polymers with Open Frameworks.J.Phys.Chem.B 2002,106: 1380-1385.
[20]Wenbin Lin, Ling Ma, Owen R.Evans.NLO-active zinc(Ⅱ) and cadmium(Ⅱ) coordination networks with 8-fold diamondoid structures.Chem.Commun.2000: 2263-2264.
[21]Hongwei Hou, Yinglin Song, Yaoting Fan, Linping Zhang, Chenxia Du, Yu Zhu.A novel coordination polymer [Co(NCS)2(bpms)2]? (bpms=l,2-bis(4-pyridylmethyl)disulfenyl): synthesis, crystal structure and third-order nonlinear optical properties.Inorg.Chi.Acta.2001, 316: 140-144.
[22]Yu-Biao Chen, Jian Zhang, Jian-Kai Cheng, Yao Kang, Zhao-Ji Li, Yuan-Gen Yao.1D chain structure, NLO and luminescence properties of [Zn_2(bpp)(pht)_2]_n.Inorg.Chem.Commun.2004, 7: 1139-1141.
[23]Xiangru Meng, Yinglin Song, Hongwei Hou, Yaoting Fan, Gang Li, Yu Zhu.Novel Pb and Zn Coordination Polymers: Synthesis, Molecular Structures, and Third-Order Nonlinear Optical Properties.Inorg.Chem.2003,42: 1306-1315.
[24]Hongwei Hou, Yongli Wei, Yinglin Song, Yu Zhu, Linke Li, Yaoting Fan.Two novel two-dimensional double-sheet layered manganese(Ⅱ) coordination polymers: synthesis,crystal structures and third-order nonlinear optical properties.J.Mater.Chem.2002,12:838-843.
[25]Jung Soo Seo, Dongmok Whang, Hyoyoung Lee, Sung Im Jun, Jinho Oh, Young Jin Jeon, Kimoon Kim.A homochiral metal-organic porous material for enantioselective separation and catalysis.Nature.2000,404: 982-986.
[26]Marta Abrantes, Anabela A.Valente, Isabel S.Goncalves, Martyn Pillinger, Carlos C.Romao.Organotin-oxomolybdate coordination polymers as catalysts for the epoxidation of cyclooctene.J.Mol.Catal.A2005,238: 51-55.
[27]Sang-Kun Yoo, Ji Young Ryu, Jun Yong Lee, Cheal Kim, Sung-Jin Kim, Youngmee Kim.Synthesis, structure and heterogeneous catalytic activity of a coordination polymer containing tetranuclear Cu(Ⅱ)-btp units connected by nitrates.Dalton Trans.2003: 1454-1456.
[28]Wells A.F.Three Dimensional Nets and Polyhedra [M]New York, 1977
[29]Wells A.F.Structrual Inorganic Chemistry, 5thed[M].Oxford Univ.Press, 1983
[30]Hoskins B F, Robson R.Infinite polymeric framework consisting of three-dimensinal linked rod-like segments.J Am Chem Soc,1989,l 11:5962-5964.
[31]L.Carlucci, G.Ciani, P.Macchi, DM Proserpio, S.Rizzato.Complex interwoven polymeric frames from the self-assembly of silver(I) cations and sebaconitrile.Chem.Eur.J.1999, 5: 237-243..
[32]E.Y.Lee, M.P.Suh.A robust porous material constructed of linear coordination polymer chains: Reversible single-crystal to single-crystal transformations upon dehydration and rehydration.Angew.Chem.Int.Ed.2004,43: 2798-2801.
[33]H.R.Moon, J.H.Kim, M.P.Suh.Redox-active porous metal-organic framework producing silver nanoparticles from Ag-I ions at room temperature.Angew.Chem.Int.Ed.2005,44: 1261-1265.
[34]K.T.Holman, H.H.Hammud, S.Isber, M.Tabbal.One-dimensional coordination polymer [Co(H20)4(pyz)](N03)(2)center dot 2H(2)0 (pyz = pyrazine) with intra- and inter-chain H-bonds: structure, electronic spectral studies and magnetic properties Polyhedron.2005, 24: 221-228.
[35]L.Carlucci, G.Ciani, A.Gramaccioli, S.Maggini, D.M.Proserpio.Metal-organic coordination frameworks assembled with the long flexible ligand 4,4 '-bis(imidazol-l-ylmethyl)biphenyl.CrystEngComm.2008,10: 1191-1203.
[36]Y.H.Li, C.Y.Cu, A.M.Goforth, K.D.Shimizu, et al.The first 'two-over/two-under'(20/2U) 2D weave structure assembled from Hg-containing 1D coordination polymer chains.Chem.Commun.2003: 1630-1631.
[37]H.Zhu, C.Huang, W.Huang, S.H.Gou.Anovel coordination polymer constructed from ID neutral chains via inter-chain pi-pi stacking and hydrogen bonding.Inorg.Chem.Commun.2004, 7: 1095-1099.
[38]B.O.Patrick, C.L.Stevens, A.Storr, R.C.Thompson.Structural and magnetic properties of three copper(Ⅱ) pyridine-2,3-dicarboxylate coordination polymers incorporating the same chain motif.Polyhedron.2003,22: 3025-3035.
[39]R.Horikoshi, M.Mikuriya.Self-assembly of repeated rhomboidal coordination polymers from 4,4 "-dipyridyl disulfide and ZnX2 salts (X = SCN, N03, C104) Cryst.Growth Des.2005, 5: 223-230.
[40]Ruiz-Perez, P.Lorenzo-Luis, M.Hernandez-Molina, M.M.Laz, F.S.Delgado.1,2,4,5-benzenetetracarboxylic acid and 4,4 '-bipyridine as ligands in designing low-dimensional coordination polymers.Eur.J.Inorg.Chem.2004: 3873-3879.
[41]J.W.Lee, E.A.Kim, Y.J.Kim, Y.A.Lee, Y.Park, O.S.Jung.Relationship between the ratio of ligand to metal and the coordinating ability of anions.Synthesis and structural properties of AgX-bearing bis(4-pyridyl)dimethylsilane (X- = N02-, N03-, CF3S03-, and PF6(-)).Inorg.Chem.2005,44: 3151-3155.
[42]A.Erxleben.Synthesis and structure of {[Ag(SalGly)]center dot 0.33H(2)O}(n): An infinite double helical coordination polymer.Inorg.Chem.2001, 40: 2928-2931.
[43]X.M.Chen, G F.Liu.Chem.Eur.J.Double-Stranded Helices and Molecular Zippers Assembled from Single-Stranded Coordination Polymers Directed by Supramolecular Interactions.Chem.Eur.J.2002, 8, 4811-4817.
[44]P.Grosshans, A.Jouaiti, V.Bulach, J.M.Planeix, M.W.Hosseini, J.F.Nicoud.Molecular tectonics: from enantiomerically pure sugars to enantiomerically pure triple stranded helical coordination network.Chem.Commun.2003: 1336-1337.
[45] Y. Cui, H. L. Ngo, W. B. Lin. A homochiral triple helix constructed from an axially chiral bipyridine. Chem. Commun. 2003: 1388-1389.
[46] X. J. Luan, Y. Y. Wang, D. S. Li, P. Liu, H. M. Hu, Q. Z. Shi, S. M. Peng. Self-assembly of an interlaced triple-stranded molecular braid with an unprecedented topology through hydrogen-bonding interactions. Angew. Chem. Int. Ed. 2005,44: 3864-3867.
[47] X. J. Luan, X. H. Cai, Y. Y. Wang, D. S. Li, C. J. Wang, P. Liu, H. M. Hu. An investigation of the self-assembly of neutral, interlaced, triple-stranded molecular braids. Chem. Eur. J. 2006,12: 6281-6289.
[48] Y. Cui, S. J. Lee, W. Lin. Interlocked chiral nanotubes assembled from quintuple helices J. Am. Chem. Soc. 2003,125: 6014-6015.
[49] A. J. Blake, M. T. Brett, N. R. Champness, A. Khlobystov, D. L. Long, C. Wilson, et al. Inorganic-organic interpenetrating frameworks: 4,4 '-bipyridine N,N '-dioxide as a bridging hydrogen-bond acceptor. Chem. Commun. 2001: 2258-2259.
[50] M. Maekawa, H. Kanoka, Y. Suenage, T. Kuroda-Sowa, M. Munakata. A variety of one-, two- and three-dimensional copper(Ⅰ) and silver(Ⅰ) co-ordination polymers assembled by l,4-bis(4-pyridyl)butadiyne and 1,4-bis(2-pyridyl)butadiyne. J. Chem. Soc. Dalton. Trans. 2000: 4160-4166.
[51] M. B. Zaman, M. D. Smith, D. M. Ciurtin, H. Loye. Zur. New Cd(Ⅱ)-, Co(Ⅱ)-, and Cu(Ⅱ)-containing coordination polymers synthesized by using the rigid ligand 1,2-bis(3-pyridyl)ethyne (3,3'-DPA). Inorg. Chem. 2002: 41: 4895-4903.
[52] Y. B. Dong, R. C. Layland, M. D. Smith, N. G. Pschirer, H. Loye. Zur. Syntheses and characterizations of one-dimensional coordination polymers generated from cadmium nitrate and bipyridine ligands. Inorg. Chem. 1999, 38: 3056-3060.
[53] E. Q. Gao, Y. X. Xu, C. H. Yan. Two square grid coordination polymers with manganese(Ⅱ) and l,4-bis(imidazole-l-ylmethyl) benzene. CrystEngCommun. 2004, 6: 298-302.
[54] Y. R. Xie, H. Zhao, X. S. Wang, Z. R. Qu, R. G Xiong, X. A. Xue, et al. 2D chiral uranyl(Ⅵ) coordination polymers with second-harmonic generation response and ferroelectric properties. Eur. J. Inorg. Chem. 2003: 3712-3715.
[55] K. Uemura, S. Kitagawa, K. Fukui, K. Fukui, K. Saito. A contrivance for a dynamic porous framework: Cooperative guest adsorption based on square grids connected by amide-amide hydrogen bonds. J. Am. Chem. Soc. 2004,126: 3817-3828.
[56] Z. Spichal, M. Necas, J. Pinkas, J. Novosad. The synthesis and crystal structures of two-dimensional coordination polymers of Ph2P(O)-CH2CH2-P(O)Ph-2 and Ph2P(0)-C5H3N-P(0)Ph-2 with praseodymium.Inorg.Chem.2004,43: 2776-2778.
[57]X.M.Ouyang, B.L.Fei, T.A.Okamura, H.W.Bu, W.Y.Sun, W.X.Tang, et al.Syntheses, crystal structures, and properties of four two-dimensional network complexes with multidentate bis(Schiff base) ligands.Eur.J.Inorg.Chem.2003: 618-627.
[58]G.B.Gardener, D.Venkataraman, J.S.Moore, S.Lee.Spontaneous assembly of a hinged coordination network.Nature.1995, 374,792-795.
[59]D.M.Whang, K.M.Park, J.Heo, P.Ashton, K.Kim.Molecular necklace: Quantitative self-assembly of a cyclic oligorotaxane from nine molecules.J.Am.Chem.Soc.1998,120:4899-4900.
[60]J.F.Ma, J.F.Liu, Y.Xing, H.Q.Jia, Y.H.Lin.Networks with hexagonal circuits in co-ordination polymers of metal ions (Zn-Ⅱ, Cd-Ⅱ) with 1,1 '-(l,4-butanediyl)bis(imidazole).J.Chem.Soc.Dalton.Trans.2000: 2403-2407.
[61]J.H.Luo, M.C.Hong, R.H.Wang, R.Cao, L.Han, Z.Z.Lin.Eur.J.Inorg.Chem.2003: 2705-2710.
[62]A.M.Madalan, V.C.Kravtsov, Y.A.Simonov, V.Voronkovo, L.Korobchenko, N.Avarari, et al.A unique diamondoid network resulting from the convolution of pi-pi stacking and lipophilic interactions.Crystal Growth & Design.2005, 5: 45-47.
[63]X.J.Li, R.Cao, D.F.W, H.Bi, Y.Q.Wang, X, Li, et al.Syntheses and characterizations of zinc(Ⅱ) compounds containing three-dimensional interpenetrating diamondoid networks constructed by mixed ligands.Crystal Growth & Design.2004,4: 775-780.
[64]K.A.Hirsch, S.R.Wilson, J.S.Moore.A Packing Model for Interpenetrated Diamondoid Structures - an Interpretation Based on the Constructive Interference of Supramolecular Networks.Chemistry - A European Journal.2006, 3: 765-771.
[65]S.Subramanian, M.J.Zaworotko.Porous Solids by Design: [Zn(4,4 -bpy)2(SiF6)]_n·xDMF, a Single Framework Octahedral Coordination Polymer with Large Square Channels.Angew.Chem.Int.Ed.2003, 34: 2127-2129.
[66]L.Carlucci, G Ciani, D.M.Proserpio, A.Sironi.Polymeric networks of silver(I) and copper(I) ions linked by an anionic acetonyl derivative of tetracyanoethylene.Angew.Chem.Int.Ed.1996,35:1088-1090.
[67]A.Rujiwatra, C.J.Kepert, M.J.Rosseinsky.The organo-pillared porous magnetic framework Co-4(SO4)(OH)(6)(H2NC2H4NH2)(0.5)center dot 3H(2)0.Chem.Commun.1999: 2307-2308.
[68]R.Kitaura, K.Seki, G Akiyama, S.Kitagawa.Porous coordination-polymer crystals with gated channels specific for supercritical gases.Angew.Chem.Int.Ed.2003, 42: 428-431.
[69] J. C. Dai, X. T. Wu, S. M. Hu, Z. Y. Fu, J. J. Zhang, W. X. Du, H. H. Zhang, et al. Crystal engineering of the coordination architecture of metal polycarboxylate complexes by hydrothermal synthesis: Assembly and characterization of four novel cadmium polycarboxylate coordination polymers based on mixed ligands. Eur. J. Inorg. Chem. 2004: 2096-2106.
[70] X. C. Huang, Y. Y. Lin, J. P. Zhang, X. M. Chen. Ligand-directed strategy for zeolite-type metal-organic frameworks: Zinc(II) imidazolates with unusual zeolitic topologies. Angew. Chem. Int. Ed. 2006,45: 1557-1559.
[71] Y. Q. Tian, C. X. Cai, Y. Ji, X. Z. You, S. M. Peng, G. H. Lee. [Co_5(im)_(10)·2MB]_∞: A Metal-Organic Open-Framework with Zeolite-Like Topology. Angew. Chem. Int. Ed. 2002, 41: 1384-1386.
[72] Y. G. Li, N. Hao, Y. Lu, E. B. Wang, Z. H. Kang, C. W. Hu. New Two-Dimensional Metal-Organic Networks Constructed from 1,2,4,5-Benzenetetracarboxylate and Chelate Ligands. Inorg. Chem. 2003,42, 3119-3124.
[73] S Noro, R Kitaura, M Kondo. Framework engineering by anions and porous functionalities of Cu(Ⅱ)/4,4'-bpy coordination polymers. J. Am. Chem. Soc. 2002,124: 2568-2571.
[74] O. M. Yaghi, H. L. Lian, T. L. Groy. A Molecular Railroad with Large Pores: Synthesis and Structure of Ni(4,4'-bpy)_(2.5)(H_2O)_2(ClO_4)_2·1.5(4,4'-bpy)·2H_2O. Inorg. Chem. 1997, 36: 4292-4293.
[75] K Biradha, M Fujita. A springlike 3D-coordination network that shrinks or swells in a crystal-to-crystal manner upon guest removal or readsorption. Angew. Chem. Int. Ed. 2002, 41:3392-3396.
[76] Y.H.Liu, Y.L.Lu, H. C.Wu, J.C.Wang, K. L. Lu. [Cd(Ⅱ)(bpdc)H_2O]_n: a robust, thermally stable porous framework through a combination of a 2-D grid and a cadmium dicarboxylate cluster chain (H_2bpdc = 2,2'-Bipyridyl-4,4'-dicarboxylic acid). Inorg. Chem. 2002,41:2592-2597.
[77] M. Nakash, Z. Clyde-Waston, N. Feeder, S. J. Teat, J. K. M. Sanders. Hydrogen-bonding clusters leading to formation of a supramolecular dimmers of metalloporphyrin receptors: modulation of Lewis acidity by π-π interactions. Chem. Eur. J. 2000, 6: 2112-2119.
[78]陈晓明,童明良。羧基配位结构——共面与非共面。大学化学,1997,12:24-27.
[79] Xin-Yi Wang, Hai-Yan Wei, Zhe-Ming Wang, Zhi-Da Chen, Song Gao. Formate-The Analogue of Azide: Structural and Magnetic Properties of M(HCOO)_2(4,4'-bpy)·H_2O (M = Mn, Co, Ni; n = 0, 5). Inorg. Chem. 2005, 44: 572-583.
[80]D.Czakis-Sulikowska, J.Radwa_ska-Doczekalska* A.Czylkowska, M.Markiewicz A.Broniarczyk.New Complexes of Mn(Ⅱ), Co(Ⅱ), Ni(Ⅱ) and Cu(Ⅱ) with 2,2' or 2,4'-Bipyridine and Formats: Synthesis, thermal and other properties.J.Therm.Anal.Cal.2006, 86: 327-335.
[81]Wei Huang, Dahua Hua, Shaohua Gou, Suchada Chantrapromma, Hoong-Kun Fun, Yan Xu, Qinjing Meng.Two formate-bridging coordination polymers containing dinuclear zinc(Ⅱ) macrocyclic components.Inorg.Chi.Acta.2003, 342: 9-15.
[82]Zheming Wang, Bin Zhang, Katsuya Inoue, Hideki Fujiwara, Takeo Otsuka,Hayao Kobayashi, Mohamedally Kurmoo.Occurrence of a Rare 49-66 Structural Topology,Chirality, and Weak Ferromagnetism in the [NH4][M~Ⅱ(HCOO)_3](M = Mn, Co, Ni) Frameworks.Inorg.Chem.2007,46: 437-445.
[83]Danil N.Dybtsev, Hyungphil Chun, Sun Hong Yoon, Dongwoo Kim, Kimoon Kim.Microporous Manganese Formate: A Simple Metal-Organic Porous Material with High Framework Stability and Highly Selective Gas Sorption Properties.J.Am.Chem.Soc.2004, 126: 32-33.
[84]Yanqin Wang, Rong Cao, Wenhua Bi, Xing Li, Daqiang Yuan, Daofeng Sun.Four novel porous frameworks constructed by formate ligand.Microporous and Mesoporous Materials.2006,91:215-220.
[85]R.Kuhlman, G.L.Schimek, J.W.Kolis.An extended solid from the solvothermal decomposition Co(Acac)3: Stucture and characterization of Co_5(OH)_2(O_2CCH_3)_8·2H_2O.Inorg.Chem.1999,38:194-196.
[86]E.Coronado, J.R.Galan-Maseallros, C.J.Comez-Garcia, J.Ensling, P.Giitlich.Hybrid molecular magnets obtained by insertion of deeamethylmetalloeenium cations into layered,bimetallicoxalate complexes: [ZinCp*2][MnM(ox)3](Z = Co, Fe; M11 = Mn, Fe, Co, Zn; ox =oxalate; Cp* = PentamethyleycloPentadieny).Chem.Eur.J.2000, 6: 552-563.
[87]R.Vaidhyanathan, S.Natarajan, C.N.R.Rao.Aliphatic dicarboxylates with three-dimensional metal-organic frameworks possessing hydrophobic channels.J.Chem.Soc,DaltonTrans.2003, 8: 1459-1464.
[88]R.Vaidhyanathan, S.Natarajan, C.N.R.Rao.Open-framework cadmium succinates of different dimensionalities.Inorg.Chem.2002,41: 5226-5234.
[89]B.Rather, M.J.Zaworotko.A 3-D metal-organic network, [Cu2(glutarate)2(4,4'-bipyridine)], that exhibits single-crystal dehydration and rehydration.Chem.Commun.2003, 7: 830-831.
[90]Hailian Li, Mohamed Eddaoudi, M.O'Keeffe, O.M.Yaghi.Design and synthesis of an exceptionally stable and highly porous metal-organic framework.Nature.1999, 402: 276-279.
[91]Hee K.Chae, Jaheon Kim, Mohamed Eddaoudi, Omar M.Yaghi.A route to high surface area, porosity and inclusion of large molecules in crystals.Nature, 2004,427: 523-527.
[92]Banglin Chen, Mohamed Eddaoudi, Omar M.Yaghi.Interwoven metal-organic framework on aperiodic minimal surface with extra-large pores.Science.2001,291:1021-1023.
[93]T.M.Reineke, M.Eddaoudi, Omar M.Yaghi.From condensed lanthanide coordination solids to microporous frameworks having accessible metal sites.J.Am.Chem.Soc.1999,121:1651-1657.
[94]Mohamed Eddaoudi, Jaheon Kim, Nathaniel Rosi, Omar M.Yaghi.Systematic design of pore size and functionality in isoreticular MOFs and their application in methane storage.Science.2002,295: 469-472.
[95]S S Y Chi, S M F Lo, J P H Charmant.A chemically functionalizable nanoporous material [Cu_3(TMA)_2(H_2O)_3]n.Science.1999, 378: 703-708.
[96]O M Yaghi, G Li, H L Li.Selective binding and removal of guests in a microporous metal-organic framework.Nature.1995, 378: 703-706.
[97]B L Chen, M Eddaoudi, T M Reineke.Cu_2(ATC).6H_2O: Design of open metal sites in porous metal-organic crystals (ATC: 1,3,5,7-adamantane tetracarboxylate).J.Am.Chem.Soc.2000,122:11559-11562.
[98]S.R.J.John.Copper as possible active forms of the antiarthritie agents.J.Med.Chem.1976,19: 135-148.
[99]R.G.Xiong, S.R.Wilson, W.B.Lin.Bis(isonicotinato)iron(Ⅱ): a rare, neutral three-dimensional iron coordination polymer.J.Chem.Soc, Dalton Trans.1998,24:4089-4090.
[100]Jin-Yu.Sun, Lin-hongWeng, Ya-ming Zhou, Jin-xi Chen, Zhen-xia Chen, Zhi-cheng Liu, Dong-yuan Zhao.QMOF-1 and QMOF-2: Three-Dimensional Metal-Organic Open Frameworks with a Quartzlike Topology**.Angew.Chem.Int.Ed.2002,41: 4471-4473.
[101]Mary E.Chapman, Ponnaiyan Ayyappan, Bruce M.Foxman, Gordon T.Yee, Wenbin Lin.Synthesis, X-ray Structures, and Magnetic Properties of Copper(Ⅱ) Pyridinecarboxylate Coordination Networks.Crystal Growth & Design.2001, 1: 159-163.
[102]Liang Y,Cao R,Su W.Syntheses, Structures and Magnetic Properties of Two Gadolinium(Ⅲ)-Copper(Ⅱ) Coordination Polymers by a Hydrothermal Reaction.Angew.Chem.Int.Ed.2000, 39: 3304-3307.
[103]Bin Zhao, Peng Cheng, Yan Dai, Cai Cheng, Dai-Zheng Liao, Shi-Ping Yan, et al.A Nanotubelar 3D Coordination Polymer Based on a 3d-4f Heterometallic Assembly.Angew.Chem.Int.Ed.2003,42: 934-936.
[104]X.M.Zhang, X.M.Chen.A New Porous 3-D Framework Constructed From Fivefold arallel Interpenetration of 2-D (6,3) Nets: A Mixed-Valence Copper(I, Ⅱ) Coordination Polymer [Cu_2~ⅠCu~Ⅱ(4,4'-bpy)_2(pydc)_2]-4H_2O.Eur.J.Inorg.Chem.2003,413-417.
[105]X.Wang, C.Qin, E.B.Wang, Y.Li, N.Hao, C.Hu, L.Xu.Synthesis, structures, andphotoluminescence of a novel class of d10 metal complexes constructed from pyridine-3,4-dicarboxylic acid with different coordination architectures.Inorg.Chem.2004, 43: 1850-1856.
[106]L.Lu, E.Shen, Y.Li, D.Xiao, E.B.Wang, L.Xu.A novel pillar-layered organic-inorganic hybrid based on lanthanide polymer and polyomolybdate clusters: new opportunity toward the design and synthesis of porous framework.Cryst.Growth.Des.2005,5: 65-67.
[107]S.I.Noro, S.Kitagawa, M.Yamashita, T.Wada.New microporous coordination polymer affording guest-coordination sites at channel walls.Chem.Commun.2002, 3:222-223.
[108]S.Kitagawa, R.Kitaura, S.I.Noro.Functional porous coordination polymers.Angew.Chem.Int.Ed.2004,43: 2334-2375.
[109]M.Kondo, T.Okubo, A.Asami, S.Noro, T.Yoshitomi, S.Kitagawa, T.Ishii, H.Matsuzaka, K.Seki.Rational synthesis of stable channel-like cavities with methane gas adsorption properties: [{Cu_2(pzdc)_2(L)}_n](pzdc = pyrazine-2,3-dicarboxylate; L = a pillar ligand).Angew.Chem.Int.Ed.1999, 38: 140-143.
[110]S.Konar, S.C.Manna, E.Zangrando, N.R.Chaudhuri.Crystal structure and magnetic behavior of a copper(Ⅱ)-(pyrazine-2,3-dicarboxylate) coordination polymer: 3D architecture stabilized by H-bonding.Inorg.Chi.Acta.2004, 357: 1593-1597.
[111]O.R.Evans, W.B.Lin.Crystal engineering of nonlinear optical materials based on interpenetrated diamondoid coordination networks.Chem.Mater.2001,13: 2705-2712.
[112]M.Du, X.J.Zhao, Y.Wang.Crystal engineering of a versatile building block toward the design of novel inorganic-organic coordination architectures.J.Chem.Soc, Dalton Trans.2004,14:2065-2072.
[113]M.Du, C.P.Li, X.J.Zhao.Metal-controlled assembly of coordination polymers with the flexible building block 4-pyridylacetic acid (Hypa).Cryst.Growth.Des.2006, 6: 335-341.
[114]Z.H.Zhang, T.Okamura, Y.Hasegawa, H.Kawaguchi, L.Y.Kong, W.Y.Sun, N.Ueyama.Synthesis, structures, and luminescent and magnetic properties of novel three-dimensional lanthanide complexes with 1,3,5-benzenetriacetate.Inorg.Chem.2005,44:6219-6227.
[115]Z.H.Zhang, Z.L.Shen, T.Okamura, H.F.Zhu, W.Y.Sun, N.Ueyama.Synthesis and structures of two series of coordination frameworks based on the assembly of 1,3,5-benzenetriacetic acid with lanthanide metal salts.Crystal Growth & Design.2005, 5:1191-1197.
[116]H.F.Zhu, J.Fan, T.Okamura, Z.H.Zhang, G X.Liu, K.B.Yu, W.Y.Sun, N.Ueyama.Metal-organic architectures of silver(I), cadmium(Ⅱ), and copper(Ⅱ) with a flexible tricarboxylate ligand.Inorg.Chem.2006,45: 3941-3948.
[117]H.F.Zhu, Z.H.Zhang, W.Y.Sun, T.Okamura, N.Ueyama.Synthesis, structures, and properties of two-dimensional alkaline earth metal complexes with flexible tripodal tricarboxylate ligands.Crystal Growth & Design.2005, 5: 177-182.
[118]Klabunde,Kenneth J．纳米材料化学．第一版．北京：化学工业出版社,2004．
[119]J.T.Hu, T.W.Odom, C.M.Lieber.Chemistry and physics in one dimension:Synthesis and properties of nanowires and nanotubes.Ace.Chem.Res.1999, 32 : 435-445.
[120]Y Huang, X.F.Duan, Y.Cui, L.J.Lauhon, K.H.Kim, C.M.Lieber.Logic gates and computation from assembled nanowire building blocks.Science, 2001, 294: 1313-1317.
[121]Bachtold A, Hadley P, Nakanishi T, Dekker C.Logic circuits with carbon nanotube transistors.Science.2001,294: 1317-1320.
[122]Collier CP, Vossmeyer T, JR Heath.Nanocrystal superlattices.Annu.Rev.Phys.Chem.1998,49:371-404.
[123]Y.W.Wang, L.D.Zhang, G.Z.Wang, X.S.Peng, Z.Q.Chu, C.H.Liang.Catalytic growth of semiconducting zinc oxide nanowires and their photoluminescence properties.Journal of Crystal Growth.2002,234: 171-175.
[124]C.C.Tang, S.S.Fan, Marc Lamy de la Chapelle, P.Li.Silica-assisted catalytic growth of oxide and nitride nanowires.Chemical Physics Letters.2001, 333: 12～15.
[125]J.Zhou, S.Z.Deng, J.Chen, J.C.She, NS Xu.Synthesis of crystalline alumina nanowires and nanotrees.Chemical Physics Letters.2002, 365: 505-508.
[126]J.K.Jian, X.L.Chen, W.J.Wang, L.Dai, Y.P.Xu.Growth and morphologies of large-scale SnO_2 nanowires, nanobelts and nanodendrites.Applied Physics.2003, A76: 291-294.
[127]C.K.Xu, G.D.Xu, Y.K.Liu, G.H.Wang.A simple and novel route for the preparation of ZnO nanorods.Solid State Communications.2002,122: 175-179.
[128]C.K.Xu, Y.K.Liu, G.D.Xu, G.H.Wang.Preparation and characterization of CuO nanorods by thermal decomposition of CuC_2O_4 precursor.Mater.Res.Bull.2002, 37: 2365-2372.
[129]C.K.Xu, G.D.Xu, Y.K.Liu, G.H.Wang.Preparation and characterization of SnO_2 nanorods by thermal decomposition of SnC_2O_4 precursor.Scripta Materialia.2002,46 (1):789-794.
[130]Brinda B.Lakshmi, Charles J.Patrissi, Charles R.Martin.Sol-Gel Template Synthesis of Semiconductor Oxide Micro- and Nanostructures.Chemistry of Materials.1997,9:2544-2550.
[131]S.J.Limmer, S.Seraji, Y.Wu, T.P.Chou, C.Nguyen, G.Z.Cao.Template-Based Growth of Various Oxide Nanorods by Sol-Gel Electrophoresis.Advanced Functional Materials.2002,12: 59-64.
[132]B.C.Satishkumar, A.Govindaraj, M.Nath, C.N.R.Rao.Synthesis of metal oxide nanorods using carbon nanotubes as templates.Joural of Materials Chemistry.2000,10:2115-2119.
[133]Y.K.Liu, C.R.Yin, W.Z.Wang, Y.J.Zhan, G.H.Wang.Synthesis of cadmium oxide nanowires by calcining precursors prepared in a novel inverse microemulsion.J.Mater.Sci.Lett.2002, 21: 137-139.
[134]Y.K.Liu, C.L.Zheng, W.Z.Wang, C.R.Yin, G.H.Wang.Synthesis and Characterization of Rutile SnO_2 Nanorods.Advanced Materials.2001,13: 1883-1887.
[135]L.Gu, Z.H Wu, T.Liu, W.D.Wang, H.S.Zhu.Synthesis of novel Sb_2O_3 and Sb_2O_5 nanorods.Chemical Physics Letter.2000, 318:49-52.
[136]X.Wang, Y.D.Li.Selected-Control Hydrothermal Synthesis of a- and P-MnO_2 Single Crystal Nanowires.J.Am.Chem.Soc.2002,124: 2880-2881.
[137]Z.W.Pan, Z.R.Dai, Z.L.Wang.Nanobelts of Semiconducting Oxides.Science.2001,291: 1947-1949.
[138]W.Z.Wang, Y.J.Zhan, G.H.Wang.One-step, solid-state reaction to the synthesis of copper oxide nanorods in the presence of a suitable surfactant.Chem.Commun.2001: 727-728.
[139]Cheng-Yong Su, Andrea M.Goforth, Mark D.Smith, P.J.Pellechia, Hans-Conrad zur Loye.Exceptionally Stable, Hollow Tubular Metal-Organic Architectures: Synthesis,Characterization, and Solid-State Transformation Study.J.Am.Chem.Soc.2004,126:3576-3586.
[140]Haijun Niu, Mingyuan Gao.Diameter-Tunable CdTe Nanotubes Templated by 1D Nanowires of Cadmium Thiolate Polymer.Angew.Chem.Int.Ed.2006, 45: 6462-6466.
[141] Yujie Xiong, Zhengquan Li, Rong Zhang, Yi Xie, Jun Yang, Changzheng Wu. From Complex Chains to 1D Metal Oxides: A Novel Strategy to Cu_2O Nanowires. J. Phys. Chem. B 2003,107: 3697-3702.
[142] Yujie Xiong, Yi Xie, Zhengquan Li, Changzheng Wu. Growth of Well-Aligned γ-MnO_2 Monocrystalline Nanowires through a Coordination-Polymer-Precursor Route. Chem. Eur. J. 2003,9: 1645-1651.
[143] Zhengquan Li, Yujie Xiong Yi Xie. Selective growth of ZnO nanostructures with coordination polymers. Nanotechnology. 2005,16: 2303-2308.
[144] Xuanjun Zhang, Yi Xie, Qingrui Zhao, Yupeng Tian. 1-D coordination polymer template approach to CdS and HgS aligned-nanowire bundles. New J. Chem. 2003,27: 827-830.
[145] J. Y. Wu, C. H. Chang, T. W. Tseng, K. L. Lu. Synthesis of two-dimensional metal-organic networks from 1,10-phenanthroline-chelated cadmium complex and polycarboxylate. J. Mol. Stru. 2006, 796: 69-75.
[146] T. K. Maji, I. R. Lasker, G. Mostafa, A. J. Welch, P. S. Mukherjee, N. R. Chaudhuri. A ID thiocyanato bridge nickel(Ⅱ) system: crystal structure and magnetic property. Polyhedron. 2001,20:651-655.
[147] A. Majumder, M. Westerhausen, A. N. Kneifel, J. P. Sutler, N. Daro, S. Mitra. A manganese(Ⅱ) dichloro-bridged one-dimensional polymer: structural, fluorescence and low-temperature magnetic study. Inorg. Chi. Acta. 2006, 359: 3841-3846.
[148] P. Bhuina, U. S. Ray, G. Mostafa, J. Ribas, C. Sinha. One-dimensional azido bridge [1-ethyl-2-(phenylazo)imidazole]-manganese(Ⅱ): Structure of low bridge angle system and magnetism. Inorg. Chi. Acta. 2006, 359: 4660-4666.
[149] Q. Shi, R. Cao, D. F. Sun, M. C. Hong, Y. C. Liang. Solvothermal synthesis and crystal structures of two metal coordination polymer with double-chain structures. Polyhedron. 2001, 20: 3287-3293.
[150] H. B. Chen, H. Zhang, J. M. Yang, Z. H. Zhou. Transformation of maleato manganese(Ⅱ): temperature effect and coordination modes. Polyhedron. 2004, 23: 987-991.
[151] Yangguang Li, Na Hao, Ying Lu, Enbo Wang, Zhenhui Kang, Changwen Hu. New Two-Dimensional Metal-Organic Networks Constructed from 1,2,4,5-Benzenetetracarboxylate and Chelate Ligands. Inorg. Chem. 2003, 42: 3119-3124.
[152] Xiaojun Gu, Yanhui Chen, Jun Peng, Zhenyu Shi, Enbo Wang, Ninghai Hu. A new 1D metal-organic coordination polymer with blue fluorescent emission: [Cd_2(1,10'-phen)_2(betc)(H_2O)]n. J. Mol. Stru. 2004, 697: 231-235.
[153]Jing-Yun Wu, Che-Hao Chang, Tien-Wen Tseng, Kuang-Lieh Lu.Synthesis oftwo-dimensional metal-organic networks from 1,10-phenanthroline-chelated cadmium complex and polycarboxylate.J.Mol.Stru.2006,796: 69-75.
[154]Yanjuan Qi, Yonghui Wang, Changwen Hu, Minhua Cao, Li Mao, Enbo Wang.A New Type of Single-Helix Coordination Polymer with Mixed Ligands [M_2(phen)_2(e,a-cis-l,4-chdc)_2(H_2O)_2]n (M = Co and Ni; phen = 1,10-phenanthroline; chdc =cyclohexanedicarboxylate).Inorg.Chem.2003,42: 8519-8523.
[155]Xin-Long Wang, Chao Qin, En-Bo Wang, Lin Xu, Zhong-Min Su, Chang-Wen Hu.Interlocked and Interdigitated Architectures from Self-Assembly of Long Flexible Ligands and Cadmium Salts.Angew.Chem.Int.Ed.2004,43: 5036-5040.
[156]YongBok Go, Xiqu Wang, Ekaterina V.Anokhina, Allan J.Jacobson.A Chain of Changes: Influence of Noncovalent Interactions on the One-Dimensional Structures of Nickel(Ⅱ) Dicarboxylate Coordination Polymers with Chelating Aromatic Amine Ligands.Inorg.Chem.2004,43: 5360-5367.
[157]Xiao-Ming Chen, Gao-Feng Liu.Double-stranded helices and molecular zippers assembled from single-stranded coordination polymers directed by supramolecular interactions.Chem.Eur.J.2002, 8:4811-4816.
[158]O.M.Yaghi, M.O'Keeffe, N.W.Ockwig, H.K.Chae, M.eddaoudi, J.Kim.Reticular synthesis and the design of new materials.Nature.2003,423: 705-714.
[159]M.Eddaoudi, J.Kim, J.B.Wachter, H.K.Chae, M.O'Keeffe, O.M.Yaghi.Porous Metal-Organic Polyhedra: 25 A Cuboctahedron Constructed from 12 Cu_2(CO_2)_4 Paddle-Wheel Building Blocks.J.Am.Chem.Soc.2001,123: 4368-4369.
[160]Hailian Li, Mohamed Eddaoudi, Thomas L.Groy, O.M.Yaghi.Establishing icroporosity in Open Metal-Organic Frameworks: Gas Sorption Isotherms for Zn(BDC)(BDC=l,4-Benzenedicarboxylate).J.Am.Chem.Soc.1998,120: 8571-8572
[161]Andrea C.Sudik, Adrien P.Cote, O.M.Yaghi.Metal-Organic Framework Based on Trigonal Prismatic Building Blocks and the New "acs" Topology.Inorg.Chem.2005, 44:2998-3000.
[162]Lili Wen, Yizhi Li, Dongbin Dang, Zhengfang Tian, Zhaoping Ni, Qingjin Meng.Syntheses, crystal structures and luminescent properties of two new 1D d~(10) coordination polymers constructed from 2,20-bibenzimidazole and 1,4-benzenedicarboxylate.J.Solid.State.Chem.2005,178: 3336-3341.
[163]T.R.Whitfield, X.Q.Wang, L.M.Liu, A.J.Jacobson.Metal-organic frameworks based on iron oxide octahedral chains connected by benzenedicarboxylate dianions.Solid State Sciences.2005,7: 1096-1103.
[164]R.L.Sang, L.Xu.Supramolecular architectures of cadmium(Ⅱ) built of 2,2'-biimmidazole and bifunctional carboxylates: Synthesis, crystal structure and properties.Inorg.Chi.Acta.2006, 359: 525-532.
[165]J.Y.Sun, Y.M.Zhou, Q.R.Fang, Z.X.Chen, L.H.Weng, G.S.Zhu, et al.Construction of 3D Layer-pillared homoligand coordination polymers from a 2D layered precursor.Inorg.Chem.2006,45: 8677-8684.
[166]Ge Tian, Guangshan Zhu, Qianrong Fang, Xiaodan Guo, Ming Xue, Jinyu Sun, Shilun Qiu.Design, synthesis and fluorescence of two-dimensional pillared layers by connecting infinite one-dimensional chains via 4,4'-bipyridine.J.Mol.Struc.2006, 787: 45-49.
[167]Brian Moulton, Michael J.Zaworotko.From Molecules to Crystal Engineering: Supramolecular Isomerism and Polymorphism in Network Solids.Chem.Rev.2001,101:1629-1658.
[168]B.F.Abrahams, M.Moylan, S.D.Orchard.Zinc Saccharate: A Robust, 3D Coordination Network with Two Types of Isolated, Parallel Channels, One Hydrophilic and the other Hydrophobic.Angew.Chem.Int.Ed.2003,42:1848-1851.
[169]O.M.Yaghi, Z.Sun, D.A.Richardson.Directed Transformation of Molecules to Solids: Synthesis of a Microporous Sulfide from Molecular Germanium Sulfide Cages.J.Am.Chem.Soc.1994,116: 807-808.
[170]H.K.Fun, S.S.Sundara Raj, R.G.Xiong, J.L.Zuo, Z.Yu, X.Z.You.A three-dimensional network coordination polymer, (terephthalato)(pyridine)cadmium, with blue fluorescent emission.J.Chem.Soc, Dalton Trans.1999,1915-1916.
[171]C.Jiang, Z.P.Yu, C.Jiao, S.J.Wang, J.M.Li, Z.Y.Wang.Luminescent Zn and Cd Coordination Polymers.Eur.J.Inorg.Chem.2004,4669-4674.
[172]Y.H.Li, Y.Z.Tang, X.F.Huang, R.G.Xiong.The Crystal Structure of a Gatifloxacin Complex and its Fluorescent Property.Z.Anorg.Allg.Chem.2005, 631: 639-641.
[173]N.Hao, E.H.Shen, Y.G.Li, E.B.Wang, C.W.Hu, L.Xu.Novel Cadmium(Ⅱ) Adipate Coordination Polymers With Structural Transformation via Oxalate Ligand: Synthesis, Structures and Fluorescence Properties.Eur.J.Inorg.Chem.2004,4102-4107.
[174]J.H.Luo, M.C.Hong, R.H.Wang, R.Cao, L.Han, Z.Z.Lin.Synthesis, Crystal Structure and Fluorescence of Two Novel Mixed-Ligand Cadmium Coordination Polymers with Different Structural Motifs.Eur.J.Inorg.Chem.2003, 2705-2710.
[175]J.Zhang, Y.R.Xie, Q.Ye, R.G.Xiong, Z.L.Xue, X.Z.You.Blue to Red Fluorescent Emission Tuning of a Cadmium Coordination Polymer by Conjugated Ligands.Eur.J.Inorg. Chem. 2003,2572-2577.
[176] X, Z. Sun, Z. L. Huang, H. Z. Wang, B. H. Ye, X. M. Chen. Synthesis and Crystal Structure of Cadmium Complexes with Thiophene-dicarboxylate and Bipyridine-like Ligands. Z. Anorg. Allg. Chem. 2005, 631: 919-923.
[177] B. Valeur, Molecular Fluorescence: Princeples and Applications, Wiley-VCH, Weiheim, 2002.
[178]毛红艳.多吡啶、多羧酸构筑的功能性配合物的结构和性能研究.东北师范大学博士学位论文.2005,28.
[179] S. Noro, S. Kitagawa, M. Kondo, K. Seki, Angew. Chem. Int. Ed., 39 (2000) 2081.
[180] J. Soo, D. Whang, H. Lee, S. I. Jun, J. Oh, Y. J. Jeon, K. Kim, Nature., 402 (2000) 982.
[181] C. B. Aakeroy, A. M. Beatty, D. S. Leinen, Angew. Chem. Int. Ed., 38 (1999) 1815.
[182] C. B. Aakeroy, A. M. Beatty, D. S. Leinen, K. R. Lorimer, Chem. Commun., (2000) 935.
[183] R. Sekiya, S. Nishikiori, Chem. Commun., (2002) 2612.
[184] J. G. Mao, H. J. Zhang, J. Z. Ni, S. B. Wang, TCW Mak. Structural characterization and luminescence studies of new lanthanide(Ⅲ) complexes with nicotinic and isonicotinic acid N-oxides. Polyhedron. 1998,17: 3999-4009.
[185] Hong-Sheng Wang, Wei Shi, Bin Zhai, Jian-Gong Ma, Jun Xia, Peng Cheng. Two 2D cadmium coordination polymers with 3,4-pyridinedicarboxylic acid. J. Mol. Stru. 2007, 833: 102-107.
[186] Yen-Hsiang Liu, Yi-Long Lu, Hui-Lien Tsai, Ju-Chun Wang, Kuang-Lieh Lu. Hydrothermal Synthesis, Crystal Structure, and Magnetic Property of Copper(Ⅱ) Coordination Networks with Chessboard Tunnels. Journal of Solid State Chemistry. 2001, 158:315-319.
[187] Zheng He, En-Qing Gao, Zhe-Ming Wang, Chun-Hua Yan, Mohamedally Kurmoo. Coordination Polymers Based on Inorganic Lanthanide(Ⅲ) Sulfate Skeletons and an Organic Isonicotinate N-oxide Connector: Segregation into Three Structural Types by the Lanthanide Contraction Effect. Inorg. Chem. 2005, 44: 862-874.
[188] Mary E. Chapman, Ponnaiyan Ayyappan, Bruce M. Foxman, Gordon T. Yee, Wenbin Lin. Synthesis, X-ray Structures, and Magnetic Properties of Copper(Ⅱ) Pyridinecarboxylate Coordination Networks. Crystal Growth & Design. 2001,1: 159-163.
[189] Ryo Sekiya, Shin-ichi Nishikiori, Katsuyuki Ogura. Crystalline Inclusion Compounds Constructed through Self-Assembly of Isonicotinic Acid and Thiocyanato Coordination Bridges. J. Am. Chem. Soc. 2004, 126: 16587-16600.
[190]杨华明,张科,史蓉蓉,李云龙,张向超.CdO纳米晶的固相合成及晶化动力学研 究.材料科学与工程,2005,23(4):503-506.
[191] V. V. Sobolev, D. O. Mordas. Electron transitions of cadmium oxide. J. Appl. Spectrosc. 2003, 70: 965-968.
[192] R. S. Mane, H. M. Pathan, C. D. Lokhande, Sung-Hwan Han. An effective use of nanocrystalline CdO thin films in dye-sensitized solar cells. Solar Energy, 2006, 80: 185-190.
[193] X. S. Peng, X. F. Wang, Y. W. Wang, C. Z. Wang, G. W. Meng, L. D. Zhang. Novel method synthesis of CdO nanowires. J. Phys. D: Appl. Phys. 2002, 35: L101-104.
[194] Y. Jiang, Y. J. Zhu, G. F. Cheng. Synthesis of Bi2Se3 Nanosheets by Microwave Heating Using an Ionic Liquid. Crystal Growth & Design. 2006, 6: 2174-2176.
[195] Moumita, Ghosh, C.N.R. Rao. Chem. Phys. Lett. 2004, 393: 493-497.
[196] X. C. Wu, R. Y. Wang, B. S. Zou, L. Wang, S. M. Liu, J. R. Xu. J. Mater. Res. 1998,13: 604-607.
[197]中本一雄.无机和配位化合物的红外和拉曼光谱[M].第一版,北京:化学工业出版社.1991:237-238.