纳米多孔材料的绝热性能及催化性能研究
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摘要
进入21世纪，人们对于科学技术有了全新的认识，科学技术的发展方向趋向于多学科交叉，材料科学在现代科学中占有重要地位，新型的多功能材料的开发利用，不仅有利于解决工业上的实际问题，提高工业生产力，不断地创造新产品，也为其他学科的基础研究和创新提供了动力源泉。我们不得不承认，科学技术不断改变着我们的生活，我们既享受着科技为我们带来的福音，同时又被由此引发的各种问题所困扰，能源和环境是目前全人类的两大重要议题。尽管人类从未停止过探索和开发新能源的脚步，并已经取得了一系列令人兴奋的成果，但是事实上，这些新能源依然不能完全替代传统的化石燃料，并且作为化石燃料中最重要的石油，不仅是能量和动力的来源，它的各种精炼后得到的产品也具有巨大的价值，但是化石能源是不可再生资源，如何有效的充分的利用它，是我们一直努力的方向。同时，面对化石燃料给环境和人类健康带来的伤害，我们不断地呼吁要节能减排。
本文中我们主要对多孔材料领域内一类重要的材料，无机纳米多孔材料进行了研究，研究了微孔、介孔材料在超级绝热性能方面的性质和应用；以及有序介孔材料SBA-15作为催化剂载体，制备多相催化剂，并研究它在交叉偶联反应中的催化性能、选择性和催化剂的可再生性；
另外，我们利用反式微乳液法合成了凝胶态的TS-1，与传统TS-1不同，我们所得到G-TS-1具有微孔-介孔的多级孔结构，并且在以H2O2为氧化剂的氧化还原反应中，表现出高转化率，高催化活性的特点。我们从微孔分子筛的晶化机理着手分析，并通过多种表征测试手段，解释了这种TS-1结构和物理化学性质产生的原因。
In the21st century, people have a new understanding of science and technology,science and technology developing direction tends to be interdisciplinary materialswhich plays an important role in modern science, development and utilization ofnew multifunctional materials, not only conducive to resolving industrial practicalproblems and improve industrial productivity, constantly creating new products, butalso provide a source of inspiration for other disciplines of basic research andinnovation. We have to admit that science and technology will change our lives.Although we both enjoyed the technology brought us fortune, it also arises variousserious problems through out the world, energy and the environment are currentlytwo major mankind issues.
Although mankind has never stopped the pace of exploring and developing newenergy, and has made a series of exciting results, but in fact, these new energy stillcan not completely replace traditional fossil fuels and fossil fuels as the mostimportant energy source is not only a source of energy and power, and its variousrefinement products also has great value, but fossil fuels are non-renewableresources, how to effectively make full use of it, is the issue we have been workingon. Meanwhile, in the face of the harm that fossil fuels place on the environmentand human health, we continue to call for energy conservation, so the development of environmentally friendly energy-saving materials is also research hotspotnowadays.
In this paper, we focus on an important field of porous materials, inorganicnanoporous materials. Herein, we studied microporous, mesoporous materialsproperties and applications in terms of super-insulation properties; and orderedmesoporous materials SBA-15as a catalyst carrier, the preparation of heterogeneouscatalysts and catalytic properties it displays, catalytic selectivity and reproducibilityin cross-coupling reactions.
In addition, we synthesized gel state TS-1using reverse micro emulsion, TS-1typewith traditional method, G-TS-1we get has micropores-mesoporous multistagepore structure, and with H2O2as the oxidant in a redox reaction, exhibits a highconversion rate, high catalytic activity characteristics. We characterized Gel stateTS-1through a variety of testing methods and proceed from the microporous zeolitecrystallization mechanism analysis, explains the reasons why this TS-1structure andphysico-chemical properties can be generated.
本文中我们主要对多孔材料领域内一类重要的材料，无机纳米多孔材料进行了研究，研究了微孔、介孔材料在超级绝热性能方面的性质和应用；以及有序介孔材料SBA-15作为催化剂载体，制备多相催化剂，并研究它在交叉偶联反应中的催化性能、选择性和催化剂的可再生性；
另外，我们利用反式微乳液法合成了凝胶态的TS-1，与传统TS-1不同，我们所得到G-TS-1具有微孔-介孔的多级孔结构，并且在以H2O2为氧化剂的氧化还原反应中，表现出高转化率，高催化活性的特点。我们从微孔分子筛的晶化机理着手分析，并通过多种表征测试手段，解释了这种TS-1结构和物理化学性质产生的原因。
In the21st century, people have a new understanding of science and technology,science and technology developing direction tends to be interdisciplinary materialswhich plays an important role in modern science, development and utilization ofnew multifunctional materials, not only conducive to resolving industrial practicalproblems and improve industrial productivity, constantly creating new products, butalso provide a source of inspiration for other disciplines of basic research andinnovation. We have to admit that science and technology will change our lives.Although we both enjoyed the technology brought us fortune, it also arises variousserious problems through out the world, energy and the environment are currentlytwo major mankind issues.
Although mankind has never stopped the pace of exploring and developing newenergy, and has made a series of exciting results, but in fact, these new energy stillcan not completely replace traditional fossil fuels and fossil fuels as the mostimportant energy source is not only a source of energy and power, and its variousrefinement products also has great value, but fossil fuels are non-renewableresources, how to effectively make full use of it, is the issue we have been workingon. Meanwhile, in the face of the harm that fossil fuels place on the environmentand human health, we continue to call for energy conservation, so the development of environmentally friendly energy-saving materials is also research hotspotnowadays.
In this paper, we focus on an important field of porous materials, inorganicnanoporous materials. Herein, we studied microporous, mesoporous materialsproperties and applications in terms of super-insulation properties; and orderedmesoporous materials SBA-15as a catalyst carrier, the preparation of heterogeneouscatalysts and catalytic properties it displays, catalytic selectivity and reproducibilityin cross-coupling reactions.
In addition, we synthesized gel state TS-1using reverse micro emulsion, TS-1typewith traditional method, G-TS-1we get has micropores-mesoporous multistagepore structure, and with H2O2as the oxidant in a redox reaction, exhibits a highconversion rate, high catalytic activity characteristics. We characterized Gel stateTS-1through a variety of testing methods and proceed from the microporous zeolitecrystallization mechanism analysis, explains the reasons why this TS-1structure andphysico-chemical properties can be generated.
引文
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