丙烯酸酯/硅溶胶改性人工林木材与表面纹理强化的研究
|
摘要
对人工林木材进行改性处理，是扩大其使用范围的重要手段之一。有机树脂复合木材耐热性不好，冲击强度小，无机质复合木材耐水性较差，脆性较大，韧性较低。为此，本研究以人工林木材为研究对象，在分析国内外研究成果的基础上，采用试验研究与理论分析相结合的方法，研究硅溶胶/丙烯酸酯复合增强处理液，改性人工林木材的工艺和性能，并通过拉丝显纹处理，加工出具有凹凸纹理的木材表面，提高人工林木材的表面肌理特征。最后将处理材制成人工林杉木实木地板，既拓宽了人工林木材的利用途径，也为优质硬阔叶材的节约代用提供支持。
主要研究结论如下：
1实验室制备硅溶胶丙烯酸酯乳液最佳的制备方式是通过乳液聚合的方式合成；傅里叶红外光谱分析表明有机高分子和无机粒子之间通过化学键作用结合；工业化合成最优的温度为70℃，时间为1.5h；SDS与OP比例为1:2合成乳液处理材的处理效果最好。
2从处理材的综合性能考虑，硅溶胶/丙烯酸酯复合乳液浸渍处理人工林杉木优化的处理工艺为，前真空时间10min，处理压力1.0MPa，处理时间90min，后真空时间10min。处理人工林马尾松优化的处理工艺为，前真空时间10min，处理压力0.8MPa，处理时间30min，后真空时间10min。
3处理材、未处理材和复合乳液三者的傅里叶红外光谱分析显示，处理材的-OH的吸收峰强度减弱，复合乳液的-C=O吸收峰在处理后变得不明显，-O-吸收峰相对与未处理材增强，且-Si-O-Si吸收峰变得不明显，说明复合乳液与木材细胞壁上的-OH和C=O分别形成了Si-O-C和-C(=O)-O-酯键；通过热特性分析，处理材的热稳定性得到了改善，失重率降低，燃烧后固体残余物的重量约为未处理材的两倍；通过X射线衍射分析得出，处理材的衍射峰强度降低，结晶度略有减小，衍射峰的位置没有发生变化，处理材的结晶结构在处理过程中没有发生变化。
4处理后人工林杉木的抗弯强度、抗弯弹性模量和硬度都有不同程度的提高，三者分别增加了10.27%、17.26%和17.75%；经过复合乳液处理，人工林杉木的干缩率降低，尺寸稳定性有所提高；复合乳液处理材和未处理材的胶层剪切强度和木破率无显著差异，说明复合乳液浸渍处理不会影响木材的胶合性能；复合木材被点燃时间略长，平均有效燃烧热略低于未处理材，综合分析质量损失率、热释放速率和热释放总量，复合木材阻燃性能好于未处理材，复合木材和未处理材的比消光面积在燃烧的不同时间变化不一致，复合木材总发烟量高于未处理材，未处理材的CO和CO2产率较低。复合乳液改性处理并未对人工林杉木板材的导热性能产生明显的负面效应，反而还使板材的导热系数有所提高。复合木材的漆膜附着力和漆膜硬度略高于未处理材，说明复合乳液改性处理并未对人工林杉木板材的涂饰性能产生明显的负面效应。
5通过对人工林木材表面纹理显化分析和复合乳液处理木材的应用研究，得出：对于杉木来说，选择0.4mm-0.5mm的拉丝深度比较合适。同一拉丝深度下，密度越小，越容易起毛刺，从而影响拉丝效果。拉丝深度表征图谱信息与表面纹理的表征信息一致，拉丝深度在0.4-0.5mm时美观度最好，因此可以通过数码显微镜来评价拉丝处理对表面特征的影响。
6人工林杉木经过硅溶胶/丙烯酸酯乳液增强处理后，加工成拉丝实木地板和平面实木地板，板材各项性能指标均达到GB/T15036.1~2-2009《实木地板》各项性能指标要求。
Modification is an important method for improving the performance and extendingapplication field of wood. Wood organic functional composite has low heat resistance and badimpact strength, while wood inorganic functional composite has bad water resistance andtoughness. Selecting plantation as experiment material, in the base of analyzing home andabroad research results, with the combination of experiment and theoretical analysis, theresearch focused on the technology and performance of Chinese fir treated with siciliasol/acrylate emulsion. For improving aesthetic in appearance, the lumbers were brushed. Then,the treated wood was made into solid wood floor. The research will widen the application fieldof plantations, also will open up new avenues for the efficient use of plantations and providesupports for saving and substitution of hard wood.
The main research results are as follows:
1Under the test, the best preparation of sicilia sol/acrylate emulsion was synthesized byemulsion polymerization. The results of FTIR indicated that organic polymer and inorganicparticles were united by chemical bond. When preparation in quantity, the optimal temperaturewas70℃, reacting time was1.5h, and the ratio SDS to OP was1:2.
2Considering the compositive performance, in the experimental range, the optimalimpregnating process parameters of Chinese fir were as follows: the vacuum time beforeimpregnating was10minutes, impregnating pressure was1.0MPa, impregnating time was90minutes, and the vacuum time after impregnating was10minutes. The optimal impregnatingprocess parameters of Masson pine were as follows: the vacuum time before impregnating was10minutes, impregnating pressure was0.8MPa, impregnating time was30minutes, and thevacuum time after impregnating was10minutes.
3FTIR spectrum analysis showed that composite emulsion interacted with-OH and C=Oon the cell wall and formed Si-O-C and-C(=O)-O-ester bond. According to composite spectrum and untreated wood spectrum, it was found that–OH absorption peak becameweaken,-O-absorption peak had strengthened,-C=O and-Si-O-Si absorption peak were notobvious. TG and DSC analysis indicated that the mass lose rate was decreased and thermalstability of wood composite had improved. Unchanged XRD diffraction peak positionindicated that the lattice parameters of treated wood were not changed. The diffraction peakstrength of treated wood decreased. The crystallinity of treated wood diminished.
4MOE, MOR, and flat surface hardness of Chinese fir increased by10.27%,17.26%, and17.75%respectively after impregnated with sicilia sol/acrylate emulsion. The shrinkageefficiency of Chinese fir impregnated with emulsion declined, and the dimension stability hadimproved. Bonding properties will not be affected after wood impregnated with emulsion. Thebonding strength and wood failure were similar to that of untreated wood. The synthesis ofMLR, HRR, and THR results indicated that the fire-retardant property of wood impregnatedwith emulsion was also improved. The TTI of composite was longer slightly than that ofuntreated wood, and EHC declined somewhat. The SEA varied with burning time. The TSR,CO yield, CO2yield of composite were higher than that of untreated wood. Wood impregnatedwith emulsion was no negative effect on thermal conductivity. On the contrary, the thermalconductivity was improved. The film adhesion and hardness of paint membrane of woodimpregnated with emulsion had improved. The results showed that wood impregnated withemulsion was also no negative effect on finishing.
5studying on the grain manifestation and application of composite, the results were asfollows: the optimal brushed depth of Chinese fir was0.4mm to0.5mm. In the condition ofsame brushed depth, the effect was related to density of wood. The density was lower, theeffect was better. The spectrum of brushed depth was in accord with the surface grain by eyes.It is viable to access the brushed effect by digital microscope.
6The brushed solid wood floor and flat solid wood floor were made from Chinese firimpregnated with sicilia sol/acrylate emulsion. All kinds of performance index were up to thestandards of GB/T15036.1~2-2009.
主要研究结论如下：
1实验室制备硅溶胶丙烯酸酯乳液最佳的制备方式是通过乳液聚合的方式合成；傅里叶红外光谱分析表明有机高分子和无机粒子之间通过化学键作用结合；工业化合成最优的温度为70℃，时间为1.5h；SDS与OP比例为1:2合成乳液处理材的处理效果最好。
2从处理材的综合性能考虑，硅溶胶/丙烯酸酯复合乳液浸渍处理人工林杉木优化的处理工艺为，前真空时间10min，处理压力1.0MPa，处理时间90min，后真空时间10min。处理人工林马尾松优化的处理工艺为，前真空时间10min，处理压力0.8MPa，处理时间30min，后真空时间10min。
3处理材、未处理材和复合乳液三者的傅里叶红外光谱分析显示，处理材的-OH的吸收峰强度减弱，复合乳液的-C=O吸收峰在处理后变得不明显，-O-吸收峰相对与未处理材增强，且-Si-O-Si吸收峰变得不明显，说明复合乳液与木材细胞壁上的-OH和C=O分别形成了Si-O-C和-C(=O)-O-酯键；通过热特性分析，处理材的热稳定性得到了改善，失重率降低，燃烧后固体残余物的重量约为未处理材的两倍；通过X射线衍射分析得出，处理材的衍射峰强度降低，结晶度略有减小，衍射峰的位置没有发生变化，处理材的结晶结构在处理过程中没有发生变化。
4处理后人工林杉木的抗弯强度、抗弯弹性模量和硬度都有不同程度的提高，三者分别增加了10.27%、17.26%和17.75%；经过复合乳液处理，人工林杉木的干缩率降低，尺寸稳定性有所提高；复合乳液处理材和未处理材的胶层剪切强度和木破率无显著差异，说明复合乳液浸渍处理不会影响木材的胶合性能；复合木材被点燃时间略长，平均有效燃烧热略低于未处理材，综合分析质量损失率、热释放速率和热释放总量，复合木材阻燃性能好于未处理材，复合木材和未处理材的比消光面积在燃烧的不同时间变化不一致，复合木材总发烟量高于未处理材，未处理材的CO和CO2产率较低。复合乳液改性处理并未对人工林杉木板材的导热性能产生明显的负面效应，反而还使板材的导热系数有所提高。复合木材的漆膜附着力和漆膜硬度略高于未处理材，说明复合乳液改性处理并未对人工林杉木板材的涂饰性能产生明显的负面效应。
5通过对人工林木材表面纹理显化分析和复合乳液处理木材的应用研究，得出：对于杉木来说，选择0.4mm-0.5mm的拉丝深度比较合适。同一拉丝深度下，密度越小，越容易起毛刺，从而影响拉丝效果。拉丝深度表征图谱信息与表面纹理的表征信息一致，拉丝深度在0.4-0.5mm时美观度最好，因此可以通过数码显微镜来评价拉丝处理对表面特征的影响。
6人工林杉木经过硅溶胶/丙烯酸酯乳液增强处理后，加工成拉丝实木地板和平面实木地板，板材各项性能指标均达到GB/T15036.1~2-2009《实木地板》各项性能指标要求。
Modification is an important method for improving the performance and extendingapplication field of wood. Wood organic functional composite has low heat resistance and badimpact strength, while wood inorganic functional composite has bad water resistance andtoughness. Selecting plantation as experiment material, in the base of analyzing home andabroad research results, with the combination of experiment and theoretical analysis, theresearch focused on the technology and performance of Chinese fir treated with siciliasol/acrylate emulsion. For improving aesthetic in appearance, the lumbers were brushed. Then,the treated wood was made into solid wood floor. The research will widen the application fieldof plantations, also will open up new avenues for the efficient use of plantations and providesupports for saving and substitution of hard wood.
The main research results are as follows:
1Under the test, the best preparation of sicilia sol/acrylate emulsion was synthesized byemulsion polymerization. The results of FTIR indicated that organic polymer and inorganicparticles were united by chemical bond. When preparation in quantity, the optimal temperaturewas70℃, reacting time was1.5h, and the ratio SDS to OP was1:2.
2Considering the compositive performance, in the experimental range, the optimalimpregnating process parameters of Chinese fir were as follows: the vacuum time beforeimpregnating was10minutes, impregnating pressure was1.0MPa, impregnating time was90minutes, and the vacuum time after impregnating was10minutes. The optimal impregnatingprocess parameters of Masson pine were as follows: the vacuum time before impregnating was10minutes, impregnating pressure was0.8MPa, impregnating time was30minutes, and thevacuum time after impregnating was10minutes.
3FTIR spectrum analysis showed that composite emulsion interacted with-OH and C=Oon the cell wall and formed Si-O-C and-C(=O)-O-ester bond. According to composite spectrum and untreated wood spectrum, it was found that–OH absorption peak becameweaken,-O-absorption peak had strengthened,-C=O and-Si-O-Si absorption peak were notobvious. TG and DSC analysis indicated that the mass lose rate was decreased and thermalstability of wood composite had improved. Unchanged XRD diffraction peak positionindicated that the lattice parameters of treated wood were not changed. The diffraction peakstrength of treated wood decreased. The crystallinity of treated wood diminished.
4MOE, MOR, and flat surface hardness of Chinese fir increased by10.27%,17.26%, and17.75%respectively after impregnated with sicilia sol/acrylate emulsion. The shrinkageefficiency of Chinese fir impregnated with emulsion declined, and the dimension stability hadimproved. Bonding properties will not be affected after wood impregnated with emulsion. Thebonding strength and wood failure were similar to that of untreated wood. The synthesis ofMLR, HRR, and THR results indicated that the fire-retardant property of wood impregnatedwith emulsion was also improved. The TTI of composite was longer slightly than that ofuntreated wood, and EHC declined somewhat. The SEA varied with burning time. The TSR,CO yield, CO2yield of composite were higher than that of untreated wood. Wood impregnatedwith emulsion was no negative effect on thermal conductivity. On the contrary, the thermalconductivity was improved. The film adhesion and hardness of paint membrane of woodimpregnated with emulsion had improved. The results showed that wood impregnated withemulsion was also no negative effect on finishing.
5studying on the grain manifestation and application of composite, the results were asfollows: the optimal brushed depth of Chinese fir was0.4mm to0.5mm. In the condition ofsame brushed depth, the effect was related to density of wood. The density was lower, theeffect was better. The spectrum of brushed depth was in accord with the surface grain by eyes.It is viable to access the brushed effect by digital microscope.
6The brushed solid wood floor and flat solid wood floor were made from Chinese firimpregnated with sicilia sol/acrylate emulsion. All kinds of performance index were up to thestandards of GB/T15036.1~2-2009.
引文
[1]2013年全国林业产业总产值达4.46万亿元，http://news.xinhuanet.com/fortune/2014-01/09/c_118903863.htm
[2]2013年我国木地板销量，http://cnfloor.org/show.php?contentid=397
[3]孙长忠，沈国舫.中国主要树种人工林生产现状及潜力的调查研究：1.杉木、马尾松人工林生产力研究[J].林业科学研究，2000,13（6）：613-621.
[4]彭万喜，吴义强，张仲凤，等.中国的杉木研究现状与发展途径[J].世界林业研究，2006,19（5）：54-58.
[5]吴玉章，松井宏昭，片冈厚.酚醛树脂对人工林杉木木材的浸注性及其改善的研究[J].林业科学，2003,39（6）：136-140.
[6]马宏儒，刘文金.木材肌理在家具造型设计中的表现[J].家具与室内装饰，2008，（3）：66-67.
[7]K J Schmalzl, P D Evans. Wood surface protection with some titanium, zirconium and manganesecompounds［J］. Polymer Degradation and Stability,2003,（82）：409-419.
[8]G Sèbe, M A Brook. Hydrophobization of wood surfaces: covalent grafting of silicone polymer［sJ］.WoodScience and Technology,2001,（35）：269-282.
[9]方桂珍，李淑君，刘健威.低分子量酚醛树脂改性大青杨木材的研究［J］.木材工业，1999，13（5）：17-19.
[10]杨霞.异氰酸酯树脂固定人工林杨木压缩变形的研究［J］.吉林林业科技，2006，35（3）：39-40.
[11]钱俊，王国杜.速生杉木的改性研究——UF树脂浸渍后热压法改性［J］.木材工业，2001，15（2）：14-16.
[12]刘君良，王玉秋.酚醛树脂处理杨木、杉木尺寸稳定性分析.木材工业，2004,18（6）：5-8.
[13]陈瑞英，邓超平，唐兴平，等.福建杉木间伐材改性做地板木[J].东北林业大学学报.2000,28（4）：44-46.
[14]龙传文，龙博，韦文榜.PF树脂对杉木浸渍与压缩工艺的研究[J].2008,17（4）：27-29.
[15]周虹，伍玲，聂阳，等.辐射法制备木塑复合材地板[J].辐射研究与辐射工艺学报.2001，19(2)：111-117.
[16]岳翠银.木塑复合材的研究[J].林业科技.1999，24(4)：40-42.
[17]蔡绍祥.速生杨木木塑复合材料处理工艺实验研究[J].辽宁林业科技.2005，(2)：5-6.
[18]S Saka, T Ueno. Several SiO2wood-inorganic composites and their fire-resisting properties ［J］. WoodScience and Technology,1997,31:457-466.
[19]廖秋霞，卢灿辉，许晨.原位溶胶-凝胶制备木材-PMMA-SiO2复合材料及其显微结构［J］.福建化工，2001，（1）：21-23.
[20]SAKA S,SASAKI M.Wood-inorganic composites prepared by the sol-gel process (Ⅰ): Wood-inorganiccomposites with porous structure[J].Mokuzai Gakkaishi,1992,38(11):1043-1049.
[21]OGISO K,SAKA S.Wood-inorganic composites prepared by the sol-gel process(Ⅱ):Effects of ultrasonictreatments on preparation of wood-inorganic composites[J].Mokuzai Gakkaishi,1993,39(3):301-307.
[22]SAKA S,YAKAKE Y.Wood-inorganic composites prepared by thesol-gelprocess(Ⅲ):Chemical-modified wood-inorganic composites[J].Mokuzai Gakkaishi,1993,39(3):308-314.
[23]OGISO K,SAKA S.Wood-inorganic composites prepared by the sol-gel process (Ⅳ): Effects ofchemical bends between wood and inorganic substances on property enhancement [J].MokuzaiGakkaishi,1994,40(10):1100-1106.
[24]MIYAFUJI H,SAKA S.Wood-inorganic composites prepared by the sol-gel process(Ⅵ):Fire-resistingproperties of the SiO2-P2O5-B2O3wood-inorganic composites[J].MokuzaiGakkaishi,1996,42(1):74-80.
[25]SAKA S,TANNO F.Wood-inorganic composites prepared by the sol-gel process(Ⅶ):Effects of aproperty-enhance on fire-resistance in SiO2-P2O5and SiO2-B2O3wood-inorganic composites[J].MokuzaiGakkaishi,1996,42(1):81-86.
[26]TAKESHI F,TOHRU U, SUSUMU J. Combination of wood and silicate (Ⅰ): Impregnation by waterglass and application of aluminum sulfate and calcium chloride as reactants[J].Mokuzai Gakkaishi,1991,37(5):462-472.
[27]TAKESHI F, KWNTA S, TOHRU U. Combination of wood and silicate (Ⅱ): Wood-mineral compositesusing water glass and reactants of barirum chloride, boric acid, and borax, and theirproperties[J].Mokuzai Gakkaishi,1992,38(5):448-457.
[28]TAKESHI F,TOHRU U.Combination of wood and silicate(Ⅲ):Some properties of wood-mineralcomposites using the water glass-boron compound system[J].Mokuzai Gakkaishi,1993,39(5):561-570.
[29]Bond G M, Richman R H, Mc Naughton W P. Mimicry of natural material design and process[J].Jmepeg.,1995,4(3):334-345.
[30]李坚，邱坚.生物矿化原理与木材纳米结构复合材料[J].林业科学，2005,41（1）：189-192.
[31]Hill, C.A.S., Hale, M. and Forster, S.C. Investigations of the role of cell wall moisture content andmicropore blocking in the decay protection mechanism of anhydride modified wood. Presentation givenat the Final Conference of COST Action E22,2004, Estoril, Portugal.
[32]Waldemar J. Homan, Andre J.M. Jorissen. Wood modification developments[J]. Heron,2004,49(4):361-385.
[33]Waldemir Rodrigues, Mariano Martínez Espinosa, Wagner Luis Polito. Comparison of the compressivestrength of impregnated and nonimpregnated eucalyptus subjected to two different pressures andimpregnation times[J]. Materials research,2004,7(2):241-245.
[34]Abdullah Togay. Effect of impregnation with timber aqua on the properties of some woods[J]. Journal ofapplied science,2009,9(5):956-961.
[35]A. Togay, Y. Kilic, M.H. Colakoglu. Effect of impregnation with timber aqua to surface roughness ofsome varnishes[J]. Journal of applied science,2009,9(9):1719-1725.
[36]José de S. Nogueira, Francisco A. R. Lahr, Nicolau Priante Filho, and et al.Impregnation with naturalresin in the ‘Figueira Branca’ as alternative form of impermeabilization[J].Revista Brasileira deEngenharia Agrícola e Ambiental,2002,6(2):321-324.
[37]M. T. Paridah, L. L. Ong, A. Zaidonl, etc. Improving the dimensional stability of multi-layered strandboard through resin impregnation[J].2006, Journal of Tropical Forest Science18(3):166-172.
[38]彭海源，崔永志，孙铁华，等.速生杨木増硬处理初报[J].东北林学院学报，1985,13（1）：144-148.
[39]陈瑞英，邓邵平，唐兴平，等.福建杉木间伐材改性做地板木[J].东北林业大学学报，2000,28（4）：44-46.
[40]徐红星，王宏棣，胡世明，等.药剂种类和浓度对杨木强化改性效果的影响[J].2009,34（3）：49-52.
[41]唐伟，黄晓山，闫超.杨木表面密实化技术[J].林业科技，2006,31（4）：52＆70.
[42]刘君良，江泽慧，许忠允，等.人工林软质木材表面密实化新技术[J].木材工业，2002,16（1）：20-22.
[43]贺宏奎，常建民.软质木材的表面密实化[J].木材工业，2007,21（2）：16-18.
[44]沈晓玲，陆旭，孙瑾，等.天然有机物对速生杉木的改性研究[J].福建林业科技，2005，32（2）：10-12.
[45]史建君，方崇荣，傅俊杰，等.木材辐射接枝MMA改性研究[J].辐射研究与辐射工艺学报，2000,18（1）：30-34.
[46]涂道伍，邵卓平.KY-FW阻燃剂对木材力学性能的影响[J].林业机械与木工设备，2007,35（10）：19-20.
[47]王强，曹爱丽，黄积涛，等.苯乙烯（St）/甲基丙烯酸甲酯（MMA）/丙烯腈（AN）三元接枝共聚塑合木研制[J].林业科学，1999,35（2）：82-85.
[48]高洪林，吴国元，张艮林，等. Fe3O4/木材复合材料的制备及磁性[J].功能材料，2010,41（11）：1900-1902.
[49]袁光明，刘元，吴义强，等.杉木-纳米SiO2复合材料结构表征及复合机理[J].湖南大学学报，2009,36（9）：59-62.
[50]陈桂丹，符韵林，郑伟杰，等.二氧化硅处理杉木木材增重率与物性之间的关系[J].广西科技，2008,15（4）：441-444,448.
[51]李琳，田海江，何林，等.超微粉新型木质复合材料强度性能分析[J].林业科技，2006,31（6）：40-42.
[52]陈泽君，胡伟，范友华.杉木/二氧化硅复合材料的制备及其尺寸稳定性[J].林业科技开发，2008,22（5）：42-44.
[53]刘干.杉木/纳米Al2O3复合改性研究[J].广西轻工业，2009,124（3）：30-31.
[54]范友华，胡伟，陈泽君.无机物填充改性复合木材的制备及性能研究[J].林业机械与木工设备[J].2008,36（11）：18-21.
[55]John F Kadla,Fadi H Asfour,Batia Bar-Nir. Micropatterned Thin Film Honeycomb Materials fromRegiospecifically Modified Cellulose,2007,8(1),161-165.
[56]PerSt, Martin A, Bjorn St T. Chemical surface modifications of micro-fibrillated ellulose[J].Cellulose,2008,15:35-45.
[57] Xk Yang, Gb Du, Tc Qian. Analysis of the Surface Modification of Wood by X-ray PhotoelectronSpectroscopy[J].J.Instru.Analy.,2003,22(4),5-8.
[58]Musa ATAR, K van BAKIR. Foreign Trade of Impregnated Wood in Turkey[J].2010,12(17):1-9.
[59]童昕.乳液法制备有机/无机纳米复合材料的研究[D].沈阳：东北大学，2001.
[60]应建波.核壳结构ACR及其纳米复合材料[D].杭州：浙江工业大学，2004.
[61]姜英涛.硅溶胶改性的丙烯酸乳液[J].上海涂料，2010，48（6）:18.
[62]徐进.有机/无机（硅溶胶）复合涂料的制备[J].上海涂料，2003,41（6）：7-9.
[63]孙小星、郭红霞，梁英华，等.有机硅化合物应用进展[J].化工生产技术，2007,14（2）：51-54.
[64]Katharina Landfester，Christine Boeffel，Morand Lambla.Charac-terization of interfaces in core-shellpolymers by advanced solid-state NMR method[J]. Macrimolecules，1996，29：5972-5980.
[65]P Li，Jm Zhu，Panya Sunintaboon，et al.New route to am-phiphilic core-shell polymer nanospheres:graftcopolymerization of methyl methacrylate from water-soluble polymer chains con-taining aminogroup[J]. Langmuir，2002，18：8641-8646.
[66]Jan-Erik Jonsson，Ola J.Karlsson Helen Hassander，et al.Shell-layer stability in core-shell particlesprepared with different ini-tiators[J].Macromolecules，2001，34:1512-1514.
[67]Cyril Landier，Maria J Barandiaran，Xaver Drujon，et al.Synthesis of core/Shell latexs in a continuousstirred tank reactor[J].Ind. Eng.Chem.Res，2004，43:700-707.
[68]邬润德，童莜莉，王锐兰.聚丙烯酸酯原位乳液聚合包覆纳米硅溶胶的研究[J].有机硅材料，2002，16（5）：5-8.
[69]童莜莉，邬润德，王锐兰.聚丙烯酸酯原位乳液聚合包覆SiO2的研究[J].有机硅材料，2002，16（4）：1-4.
[70]谈定生，严年喜，施亚钧.无机粉体的聚合物胶囊化过程研究[J].高分子材料科学与工程，1999，15（6）：101-104.
[71]龙复，李同年.有机-无机复合乳液研究（I）[J].现代涂料与涂装，1996，2：1-6.
[72]李瑞.苯乙烯丙烯酸酯／硅溶胶复合乳液的合成及性能研究[D].长安大学硕士学位论文，2009.
[73]K.Yoshinage， ENakashima,T.Nishi.Poiymer modification ofcolloidal particles by spontaneouspolymerization of sueface active monomer[J].Colloid Polymer Science，1999，277：136-144.
[74]Kohji Yoshinage，Junji Shimada，Hiroyasu Nishida,Michio Komatsu.Effects of Secondary PolymerCovalently Attached to Monodisperse，Poly(maleicanhydride—styrene)—Modified Colloidal Silica onDispersibility in Organic Solvent[J].Journal ofColloid andInterface science，1996，109(1)：69-76.
[75]E.Bourgeat-Lami, Ph. Espiard and A. Guyot, Ploy(ethyl acrylate)latexes encapsulating nanoparticles ofsilia:1. Functionalization and dispersion of silica[J].Polymer,1995,36(23):4385-4389.
[76]Ph. Espiard, A. Guyot. Poly(ethyl acrylate)latexes encapsulating nanoparticles of silica:2.Graftingprocess onto silica[J].Polymer,1995,36(23):4391-4395.
[77]Ph. Espiard and A. Guyot. Poly(ethyl acrylate)latexes encapsulating nanoparticles ofsilica:3.Morphology and mechanical properties of reinforced films[J].Polymer,1995,36(23):4397-4403.
[78]Elodie Bourgeat-Lami and Jacques Lang. Encapsulation of Inorganic Particles by DispersionPolymerization in Polar Media1.Silica Nanoparticles Encapsulated by Polystyrene[J].Journal ofColloid and Interface Science,1998,197:293-308.
[79]Elodie Bourgeat-Lami and Jacques Lang. Encapsulation of Inorganic Particles by DispersionPolymerization in Polar Media2.Effect of Silica Size and Concentration on the Morphology ofSilica-Polystyrene Composite Particles[J].Journal of Colloid and Interface Science,1999,210:281-289.
[80]F.Corcos, E. Bourgeat-Lami, C. Novat and J. Lang. Poly(styrene-b-ethylene oxide) copolymers asstabilizer for the sybthesis of silica-polystyrene core-shell particles[J]. Colloid PolymScience,1999,277:1142-1151.
[81]Jose-Luiz Luna-Xavier, E.Bourgeat-Lami and A.Guyot.The role of initiation in the synthesis ofsilica/poly(methyl methacrylate)nanocomposite latex particles through emulsionpolymerization[J].Colloid Poly Sci，2001，279：947-951.
[82]Jose-Luiz Luna-Xavicr, Alain Guyot， Elodie Bourgeat-Lami.Symthesis and Characterization ofsilica/poly(methyl methacrylate)nanoeomposite latex particles emulsion polymerization Using aCationic Azo Initiator[J].Journal of Colloid and Interface Science，2002，250：82-92.
[83]Kohji Yoshimage, Takafumi Yokoyama, Yutaka Sugawa, Hiroyukl Karakawa, Naoyukltoto, HiroyasuNirshida andd Michio Komatsu. Preparation of monodispersed polymer-modified silica particles radicalpolymerization using silica colloid and instroduction of functional groups on the composite surface[J].Polymer bulletin,1992,28:663-668.
[84]董松.硅溶胶-丙烯酸酯乳液外墙涂料的配置[J].建筑材料与涂装，2001，（6）：15-16.
[85]Helmut Schmidt. Inorganic-organic composites by sol-gel techniques[J]. Journal of sol-gel science andtechnology,1994,1:217-231.
[86]M. J. Percy, C. Barthet, J. C. Lobb, M. A. Khan, S. F. Lascelles, M. Vamvakaki, S. P. Armes. Sythesisand Characterization of Vinyl Polymer-Silica Colloid Nanocomposites[J].Langmuir,2000,16,16:6913-6920.
[87]M. J. Percy, J.I.Amalvy, D.P.Randall, and S.P.Armes, synthesis of Vinyl Polymer-Silica ColloidalNanocomposites Prepared Using Commercial Alcoholic Silica Sols[J]. Langmuir,2004,20:2184-2190.
[88]沈宁祥，成国祥，袁振崑，等.硅溶胶/聚丙烯酸酯反应性复合乳液[J].材料科学进展，1989,3（5）：471-475.
[89]李庆余，黄芬芬，王红强，等.硅溶胶对丙烯酸酯乳液改性的影响[J].涂料工业，2009,39（6）：37-41.
[90]王国建，王凤芳.硅溶胶-苯丙乳液复合涂料的稳定性研究[J].化学建材，1992,1:9-13.
[91]陈师，吉静.高SiO2含量硅溶胶/聚丙烯酸酯复合乳液的制备[J].北京化工大学学报，2005,32（3）：57-60.
[92]李岗，吉静.高硅溶胶含量复合乳液的研究[J].新型建筑材料，2007,4:6-8.
[93] Jens Gotze, Robert Mockel, Nico Langh, etc. Silicification of wood in thelaboratory[J].Ceramics-Silikaty,2008,52(4):268-278.
[94]谭惠芬，郭红霞，杜万里，等.有机/无机复合浸渍液对杨木的改性处理[J].木材工业，2009,23（7）：40-42.
[95]陈志林，王群，左铁镛，等.无机质复合木材的复合工艺与性能[J].复合材料学报，2003，20(4)：130-132.
[96]王群，郭红霞，李永卿，等.硅溶胶／苯丙乳液杂化复合木材的制备与性能[J].北京工业大学学报，2006，32(7)：638-641.
[97]王群，郭红霞，李永卿，等.有机/无机杂化复合木材的制备与性能[J].化学研究与应用，2006，18(8)：939-942.
[98]郭红霞，王群，李永卿，等.SiO2／醋丙核壳复合物的合成及其对木材的改性[J].北京工业大学学报，2007，33(10):1091-1095.
[99]徐春利，郭红霞，林兰英，等.聚合物改性水玻璃均相杂化液对速生杨木的改性[J].化学研究与应用，2010，22（2）：240-243.
[100]沈德君，周丛礼.纳米复合材料改性杨木木材的物理力学性能[J].东北林业大学学报，2009,37，（3）：53-54.
[101]时尽书，李建章，周文瑞，等.脲醛树脂与纳米二氧化硅复合改善木材性能的研究[J].北京林业大学学报，2006,28（2）：123-128.
[102]尹思慈.木材学[M].北京：中国林业出版社，2002.
[103]崔会旺，杜官本.我国木材功能性改良研究进展[J].林产工业，2007,06：3-7.
[104]段新芳，孙芳利，官恬.世界木材颜色调控技术研究现状及其展望[J].国际木业，2002,12：9-11.
[105]陈玉和，胡伟华，常德龙.泡桐木材漂白过程中双氧水分解率的研究[J].木材工业，2011,15（6）：6-8.
[106]William George Campbell, Geoffrey Swann. The bleaching action of alkaline hydrogen peroxide onwood[J].Pubmed Central,1938,45(2):702-707.
[107]Mustafa USTA, Ahmet TUTUS.The effect of bleaching conditions on the physical and opticalproperties during the bleaching of CTMP with peroxide[J]. J. of Agriculture and Forestry,1999,23(2):423-429.
[108]Ayhan Z IF I, Musa ATAR, Burhanettin UYSAL. The effects of wood bleaching chemicals on thesurface gloss and the adhesion strength of varnishes. J. of Agriculture and Forestry,1999,23(3):763-770.
[109]Burhanettin UYSAL, Musa ATAR, Ayhan Z IF I. The effects of chemicals for using the bleachingof the wood surfaces on the layer hardness of varnish[J]. J. of Agriculture and Forestry,1999,23:443-450.
[110]Mehmet BUDAK.I, Musa ATAR. Effects of bleaching process on hardness and glossiness of pine wood(Masson pine Sylvestris L.) exposed to outdoor conditions[J]. Turk J Agric For,2001,25:201-207.
[111]熊伟，刘涛，胡书银，等.西藏桦木地板的漂白工艺[J].林业科技开发，1999，1:19-20.
[112]李军、吴智慧.出口工艺木扇扇页的漂白技术[J].林产工业，2002,29（2）：43-44.
[113]陈玉和，黄文豪，常德龙，等.氢氧化钠预处理对木材漂白促进作用的研究[J].林产化学与工业，2000，20(1)：52-56.
[114]范智才，朱同林，彭万喜，等.抽提对尾巨桉木材漂白性影响研究[J].浙江林业科技，2007,29（1）：16-19.
[115]程书娜，徐明，傅深渊.黄芸香仿黑胡桃的染色技术研究[J].林产工业，2007,34（3）：14-17.
[116]张仲凤，彭万喜，张明龙，等.毛白杨仿黑胡桃的染色工艺试验[J].人造板通讯，2005，（2）：29-31.
[117]彭万喜，李凯夫，何嘉凤，等.巨尾桉仿黑胡桃的染色工艺研究[J].木材加工机械，2005，（2）：15-18.
[118]陈玉和.人造板仿黑胡桃木贴面技术[J].人造板通讯，2003，（6）：10-11.
[119]陈玉和，陆仁书，杨洪义.泡桐木材仿红木染色工艺的研究[J].林产工业，2001,28（4）：17-19.
[120]金菊婉，封维忠，华毓坤.彩色定向结构刨花板的研制[J].木材工业，1999,13（5）：14-16.
[121]武林，于志明.计算机配色技术在木材连缸染色中的应用研究[J].北京林业大学学报，2007，29（1）：146-150.
[122]Funaoka M., T. Kako, et al. Condensation of ligin during heating of wood [J]. Wood sci Technol,1990,24:277-288.
[123]Andersson Seppo, Rita Sermaa, et al. X-ray scattering studies of tyermally modified scots pine [J].Holzfoeschung,2005,59:422-427.
[124]Jun Li Shi, D. Kocaefe, J. Zhang. Mechanical behaviour of Qu′ebecwood species heat-treated usingThermo Wood process[J]. Holz als Roh und Werkstoff,(2007)65:255–259.
[125]Hakkou Mohammed, Mathieu Pétrissans, et al. Wettaability changes and mass loss during heattreatment of wood [J]. Holzforschung,2005,59:35-37.
[126]关鑫，郭明辉.木材纹理强化技术[J].家具，2009,174（5）：42-45.
[127]冼迪妍，曹新民，李建堂，等.水曲柳木皮热改色工艺的研究[J].广东林业科技，2010，26（1）：29-32.
[128]涂覆涂料前钢材表面处理_表面处理方法_磨料喷射清理[S].中华人民共和国国家标准：GB／T_18839.2—2002.
[129]李宝权.木材表面的喷砂处理[J].林业科技，1997,22（5）：56-57.
[130]汪世平.附着力[J].上海涂料，1997,2:115（51）-118（54）.
[131]王宏斌，朱典想，王厚立.木材表面立体自然纹理加工设备的初步设计[J].木材加工机械，2008，（4）：33-34.
[132]王宏斌，朱典想，王厚立，等.水杉板材表面凹凸纹理加工前处理方法研究[J].西北林学院学报，2007,22（5）：159-160.
[133]成俊卿，杨家驹，刘鹏.中国木材志[M].北京：中国林业出版社，1992.
[134]成俊卿.木材学[M].北京：中国林业出版社，1985.
[135]邱坚，李坚，刘一星. SiO2溶胶空细胞法浸渍处理木材工艺[J].林业科学.2008，44（3）：124-128.
[136]林兰英.硅溶胶强化杨木复合材的制备与性能研究[D].中国林业科学研究院博士学位论文.2008.
[137]李坚.木材波谱学[M].北京：科学出版社，2003.
[138]符韵林，赵广杰.木材／二氧化硅复合材料的微细构造[J].北京林业大学学报，2006,28（5）:119-124.
[139]武国峰，姜亦飞，宋舒苹，等.木材／改性UF预聚体复合材料制备及性能表征[J].光谱学与光谱分析，2011,31（4）：1083-1086.
[140]刘一星，刘海鹏，赵荣军.木质环境学[M].北京：科学出版社，2007.
[141]杨世铭，陶文铨.传热学[M].北京：高等教育出版社，2006.
[142]田晓瑞，舒立福.锥形量热仪（CONE）在林火研究中的应用[J].森林防火，2000，2：25～26.
[143]李坚，王清文.用CONE法研究木材阻燃剂FRW的阻燃性能，林产化学与工业，2004，24(2):29-34.
[2]2013年我国木地板销量，http://cnfloor.org/show.php?contentid=397
[3]孙长忠，沈国舫.中国主要树种人工林生产现状及潜力的调查研究：1.杉木、马尾松人工林生产力研究[J].林业科学研究，2000,13（6）：613-621.
[4]彭万喜，吴义强，张仲凤，等.中国的杉木研究现状与发展途径[J].世界林业研究，2006,19（5）：54-58.
[5]吴玉章，松井宏昭，片冈厚.酚醛树脂对人工林杉木木材的浸注性及其改善的研究[J].林业科学，2003,39（6）：136-140.
[6]马宏儒，刘文金.木材肌理在家具造型设计中的表现[J].家具与室内装饰，2008，（3）：66-67.
[7]K J Schmalzl, P D Evans. Wood surface protection with some titanium, zirconium and manganesecompounds［J］. Polymer Degradation and Stability,2003,（82）：409-419.
[8]G Sèbe, M A Brook. Hydrophobization of wood surfaces: covalent grafting of silicone polymer［sJ］.WoodScience and Technology,2001,（35）：269-282.
[9]方桂珍，李淑君，刘健威.低分子量酚醛树脂改性大青杨木材的研究［J］.木材工业，1999，13（5）：17-19.
[10]杨霞.异氰酸酯树脂固定人工林杨木压缩变形的研究［J］.吉林林业科技，2006，35（3）：39-40.
[11]钱俊，王国杜.速生杉木的改性研究——UF树脂浸渍后热压法改性［J］.木材工业，2001，15（2）：14-16.
[12]刘君良，王玉秋.酚醛树脂处理杨木、杉木尺寸稳定性分析.木材工业，2004,18（6）：5-8.
[13]陈瑞英，邓超平，唐兴平，等.福建杉木间伐材改性做地板木[J].东北林业大学学报.2000,28（4）：44-46.
[14]龙传文，龙博，韦文榜.PF树脂对杉木浸渍与压缩工艺的研究[J].2008,17（4）：27-29.
[15]周虹，伍玲，聂阳，等.辐射法制备木塑复合材地板[J].辐射研究与辐射工艺学报.2001，19(2)：111-117.
[16]岳翠银.木塑复合材的研究[J].林业科技.1999，24(4)：40-42.
[17]蔡绍祥.速生杨木木塑复合材料处理工艺实验研究[J].辽宁林业科技.2005，(2)：5-6.
[18]S Saka, T Ueno. Several SiO2wood-inorganic composites and their fire-resisting properties ［J］. WoodScience and Technology,1997,31:457-466.
[19]廖秋霞，卢灿辉，许晨.原位溶胶-凝胶制备木材-PMMA-SiO2复合材料及其显微结构［J］.福建化工，2001，（1）：21-23.
[20]SAKA S,SASAKI M.Wood-inorganic composites prepared by the sol-gel process (Ⅰ): Wood-inorganiccomposites with porous structure[J].Mokuzai Gakkaishi,1992,38(11):1043-1049.
[21]OGISO K,SAKA S.Wood-inorganic composites prepared by the sol-gel process(Ⅱ):Effects of ultrasonictreatments on preparation of wood-inorganic composites[J].Mokuzai Gakkaishi,1993,39(3):301-307.
[22]SAKA S,YAKAKE Y.Wood-inorganic composites prepared by thesol-gelprocess(Ⅲ):Chemical-modified wood-inorganic composites[J].Mokuzai Gakkaishi,1993,39(3):308-314.
[23]OGISO K,SAKA S.Wood-inorganic composites prepared by the sol-gel process (Ⅳ): Effects ofchemical bends between wood and inorganic substances on property enhancement [J].MokuzaiGakkaishi,1994,40(10):1100-1106.
[24]MIYAFUJI H,SAKA S.Wood-inorganic composites prepared by the sol-gel process(Ⅵ):Fire-resistingproperties of the SiO2-P2O5-B2O3wood-inorganic composites[J].MokuzaiGakkaishi,1996,42(1):74-80.
[25]SAKA S,TANNO F.Wood-inorganic composites prepared by the sol-gel process(Ⅶ):Effects of aproperty-enhance on fire-resistance in SiO2-P2O5and SiO2-B2O3wood-inorganic composites[J].MokuzaiGakkaishi,1996,42(1):81-86.
[26]TAKESHI F,TOHRU U, SUSUMU J. Combination of wood and silicate (Ⅰ): Impregnation by waterglass and application of aluminum sulfate and calcium chloride as reactants[J].Mokuzai Gakkaishi,1991,37(5):462-472.
[27]TAKESHI F, KWNTA S, TOHRU U. Combination of wood and silicate (Ⅱ): Wood-mineral compositesusing water glass and reactants of barirum chloride, boric acid, and borax, and theirproperties[J].Mokuzai Gakkaishi,1992,38(5):448-457.
[28]TAKESHI F,TOHRU U.Combination of wood and silicate(Ⅲ):Some properties of wood-mineralcomposites using the water glass-boron compound system[J].Mokuzai Gakkaishi,1993,39(5):561-570.
[29]Bond G M, Richman R H, Mc Naughton W P. Mimicry of natural material design and process[J].Jmepeg.,1995,4(3):334-345.
[30]李坚，邱坚.生物矿化原理与木材纳米结构复合材料[J].林业科学，2005,41（1）：189-192.
[31]Hill, C.A.S., Hale, M. and Forster, S.C. Investigations of the role of cell wall moisture content andmicropore blocking in the decay protection mechanism of anhydride modified wood. Presentation givenat the Final Conference of COST Action E22,2004, Estoril, Portugal.
[32]Waldemar J. Homan, Andre J.M. Jorissen. Wood modification developments[J]. Heron,2004,49(4):361-385.
[33]Waldemir Rodrigues, Mariano Martínez Espinosa, Wagner Luis Polito. Comparison of the compressivestrength of impregnated and nonimpregnated eucalyptus subjected to two different pressures andimpregnation times[J]. Materials research,2004,7(2):241-245.
[34]Abdullah Togay. Effect of impregnation with timber aqua on the properties of some woods[J]. Journal ofapplied science,2009,9(5):956-961.
[35]A. Togay, Y. Kilic, M.H. Colakoglu. Effect of impregnation with timber aqua to surface roughness ofsome varnishes[J]. Journal of applied science,2009,9(9):1719-1725.
[36]José de S. Nogueira, Francisco A. R. Lahr, Nicolau Priante Filho, and et al.Impregnation with naturalresin in the ‘Figueira Branca’ as alternative form of impermeabilization[J].Revista Brasileira deEngenharia Agrícola e Ambiental,2002,6(2):321-324.
[37]M. T. Paridah, L. L. Ong, A. Zaidonl, etc. Improving the dimensional stability of multi-layered strandboard through resin impregnation[J].2006, Journal of Tropical Forest Science18(3):166-172.
[38]彭海源，崔永志，孙铁华，等.速生杨木増硬处理初报[J].东北林学院学报，1985,13（1）：144-148.
[39]陈瑞英，邓邵平，唐兴平，等.福建杉木间伐材改性做地板木[J].东北林业大学学报，2000,28（4）：44-46.
[40]徐红星，王宏棣，胡世明，等.药剂种类和浓度对杨木强化改性效果的影响[J].2009,34（3）：49-52.
[41]唐伟，黄晓山，闫超.杨木表面密实化技术[J].林业科技，2006,31（4）：52＆70.
[42]刘君良，江泽慧，许忠允，等.人工林软质木材表面密实化新技术[J].木材工业，2002,16（1）：20-22.
[43]贺宏奎，常建民.软质木材的表面密实化[J].木材工业，2007,21（2）：16-18.
[44]沈晓玲，陆旭，孙瑾，等.天然有机物对速生杉木的改性研究[J].福建林业科技，2005，32（2）：10-12.
[45]史建君，方崇荣，傅俊杰，等.木材辐射接枝MMA改性研究[J].辐射研究与辐射工艺学报，2000,18（1）：30-34.
[46]涂道伍，邵卓平.KY-FW阻燃剂对木材力学性能的影响[J].林业机械与木工设备，2007,35（10）：19-20.
[47]王强，曹爱丽，黄积涛，等.苯乙烯（St）/甲基丙烯酸甲酯（MMA）/丙烯腈（AN）三元接枝共聚塑合木研制[J].林业科学，1999,35（2）：82-85.
[48]高洪林，吴国元，张艮林，等. Fe3O4/木材复合材料的制备及磁性[J].功能材料，2010,41（11）：1900-1902.
[49]袁光明，刘元，吴义强，等.杉木-纳米SiO2复合材料结构表征及复合机理[J].湖南大学学报，2009,36（9）：59-62.
[50]陈桂丹，符韵林，郑伟杰，等.二氧化硅处理杉木木材增重率与物性之间的关系[J].广西科技，2008,15（4）：441-444,448.
[51]李琳，田海江，何林，等.超微粉新型木质复合材料强度性能分析[J].林业科技，2006,31（6）：40-42.
[52]陈泽君，胡伟，范友华.杉木/二氧化硅复合材料的制备及其尺寸稳定性[J].林业科技开发，2008,22（5）：42-44.
[53]刘干.杉木/纳米Al2O3复合改性研究[J].广西轻工业，2009,124（3）：30-31.
[54]范友华，胡伟，陈泽君.无机物填充改性复合木材的制备及性能研究[J].林业机械与木工设备[J].2008,36（11）：18-21.
[55]John F Kadla,Fadi H Asfour,Batia Bar-Nir. Micropatterned Thin Film Honeycomb Materials fromRegiospecifically Modified Cellulose,2007,8(1),161-165.
[56]PerSt, Martin A, Bjorn St T. Chemical surface modifications of micro-fibrillated ellulose[J].Cellulose,2008,15:35-45.
[57] Xk Yang, Gb Du, Tc Qian. Analysis of the Surface Modification of Wood by X-ray PhotoelectronSpectroscopy[J].J.Instru.Analy.,2003,22(4),5-8.
[58]Musa ATAR, K van BAKIR. Foreign Trade of Impregnated Wood in Turkey[J].2010,12(17):1-9.
[59]童昕.乳液法制备有机/无机纳米复合材料的研究[D].沈阳：东北大学，2001.
[60]应建波.核壳结构ACR及其纳米复合材料[D].杭州：浙江工业大学，2004.
[61]姜英涛.硅溶胶改性的丙烯酸乳液[J].上海涂料，2010，48（6）:18.
[62]徐进.有机/无机（硅溶胶）复合涂料的制备[J].上海涂料，2003,41（6）：7-9.
[63]孙小星、郭红霞，梁英华，等.有机硅化合物应用进展[J].化工生产技术，2007,14（2）：51-54.
[64]Katharina Landfester，Christine Boeffel，Morand Lambla.Charac-terization of interfaces in core-shellpolymers by advanced solid-state NMR method[J]. Macrimolecules，1996，29：5972-5980.
[65]P Li，Jm Zhu，Panya Sunintaboon，et al.New route to am-phiphilic core-shell polymer nanospheres:graftcopolymerization of methyl methacrylate from water-soluble polymer chains con-taining aminogroup[J]. Langmuir，2002，18：8641-8646.
[66]Jan-Erik Jonsson，Ola J.Karlsson Helen Hassander，et al.Shell-layer stability in core-shell particlesprepared with different ini-tiators[J].Macromolecules，2001，34:1512-1514.
[67]Cyril Landier，Maria J Barandiaran，Xaver Drujon，et al.Synthesis of core/Shell latexs in a continuousstirred tank reactor[J].Ind. Eng.Chem.Res，2004，43:700-707.
[68]邬润德，童莜莉，王锐兰.聚丙烯酸酯原位乳液聚合包覆纳米硅溶胶的研究[J].有机硅材料，2002，16（5）：5-8.
[69]童莜莉，邬润德，王锐兰.聚丙烯酸酯原位乳液聚合包覆SiO2的研究[J].有机硅材料，2002，16（4）：1-4.
[70]谈定生，严年喜，施亚钧.无机粉体的聚合物胶囊化过程研究[J].高分子材料科学与工程，1999，15（6）：101-104.
[71]龙复，李同年.有机-无机复合乳液研究（I）[J].现代涂料与涂装，1996，2：1-6.
[72]李瑞.苯乙烯丙烯酸酯／硅溶胶复合乳液的合成及性能研究[D].长安大学硕士学位论文，2009.
[73]K.Yoshinage， ENakashima,T.Nishi.Poiymer modification ofcolloidal particles by spontaneouspolymerization of sueface active monomer[J].Colloid Polymer Science，1999，277：136-144.
[74]Kohji Yoshinage，Junji Shimada，Hiroyasu Nishida,Michio Komatsu.Effects of Secondary PolymerCovalently Attached to Monodisperse，Poly(maleicanhydride—styrene)—Modified Colloidal Silica onDispersibility in Organic Solvent[J].Journal ofColloid andInterface science，1996，109(1)：69-76.
[75]E.Bourgeat-Lami, Ph. Espiard and A. Guyot, Ploy(ethyl acrylate)latexes encapsulating nanoparticles ofsilia:1. Functionalization and dispersion of silica[J].Polymer,1995,36(23):4385-4389.
[76]Ph. Espiard, A. Guyot. Poly(ethyl acrylate)latexes encapsulating nanoparticles of silica:2.Graftingprocess onto silica[J].Polymer,1995,36(23):4391-4395.
[77]Ph. Espiard and A. Guyot. Poly(ethyl acrylate)latexes encapsulating nanoparticles ofsilica:3.Morphology and mechanical properties of reinforced films[J].Polymer,1995,36(23):4397-4403.
[78]Elodie Bourgeat-Lami and Jacques Lang. Encapsulation of Inorganic Particles by DispersionPolymerization in Polar Media1.Silica Nanoparticles Encapsulated by Polystyrene[J].Journal ofColloid and Interface Science,1998,197:293-308.
[79]Elodie Bourgeat-Lami and Jacques Lang. Encapsulation of Inorganic Particles by DispersionPolymerization in Polar Media2.Effect of Silica Size and Concentration on the Morphology ofSilica-Polystyrene Composite Particles[J].Journal of Colloid and Interface Science,1999,210:281-289.
[80]F.Corcos, E. Bourgeat-Lami, C. Novat and J. Lang. Poly(styrene-b-ethylene oxide) copolymers asstabilizer for the sybthesis of silica-polystyrene core-shell particles[J]. Colloid PolymScience,1999,277:1142-1151.
[81]Jose-Luiz Luna-Xavier, E.Bourgeat-Lami and A.Guyot.The role of initiation in the synthesis ofsilica/poly(methyl methacrylate)nanocomposite latex particles through emulsionpolymerization[J].Colloid Poly Sci，2001，279：947-951.
[82]Jose-Luiz Luna-Xavicr, Alain Guyot， Elodie Bourgeat-Lami.Symthesis and Characterization ofsilica/poly(methyl methacrylate)nanoeomposite latex particles emulsion polymerization Using aCationic Azo Initiator[J].Journal of Colloid and Interface Science，2002，250：82-92.
[83]Kohji Yoshimage, Takafumi Yokoyama, Yutaka Sugawa, Hiroyukl Karakawa, Naoyukltoto, HiroyasuNirshida andd Michio Komatsu. Preparation of monodispersed polymer-modified silica particles radicalpolymerization using silica colloid and instroduction of functional groups on the composite surface[J].Polymer bulletin,1992,28:663-668.
[84]董松.硅溶胶-丙烯酸酯乳液外墙涂料的配置[J].建筑材料与涂装，2001，（6）：15-16.
[85]Helmut Schmidt. Inorganic-organic composites by sol-gel techniques[J]. Journal of sol-gel science andtechnology,1994,1:217-231.
[86]M. J. Percy, C. Barthet, J. C. Lobb, M. A. Khan, S. F. Lascelles, M. Vamvakaki, S. P. Armes. Sythesisand Characterization of Vinyl Polymer-Silica Colloid Nanocomposites[J].Langmuir,2000,16,16:6913-6920.
[87]M. J. Percy, J.I.Amalvy, D.P.Randall, and S.P.Armes, synthesis of Vinyl Polymer-Silica ColloidalNanocomposites Prepared Using Commercial Alcoholic Silica Sols[J]. Langmuir,2004,20:2184-2190.
[88]沈宁祥，成国祥，袁振崑，等.硅溶胶/聚丙烯酸酯反应性复合乳液[J].材料科学进展，1989,3（5）：471-475.
[89]李庆余，黄芬芬，王红强，等.硅溶胶对丙烯酸酯乳液改性的影响[J].涂料工业，2009,39（6）：37-41.
[90]王国建，王凤芳.硅溶胶-苯丙乳液复合涂料的稳定性研究[J].化学建材，1992,1:9-13.
[91]陈师，吉静.高SiO2含量硅溶胶/聚丙烯酸酯复合乳液的制备[J].北京化工大学学报，2005,32（3）：57-60.
[92]李岗，吉静.高硅溶胶含量复合乳液的研究[J].新型建筑材料，2007,4:6-8.
[93] Jens Gotze, Robert Mockel, Nico Langh, etc. Silicification of wood in thelaboratory[J].Ceramics-Silikaty,2008,52(4):268-278.
[94]谭惠芬，郭红霞，杜万里，等.有机/无机复合浸渍液对杨木的改性处理[J].木材工业，2009,23（7）：40-42.
[95]陈志林，王群，左铁镛，等.无机质复合木材的复合工艺与性能[J].复合材料学报，2003，20(4)：130-132.
[96]王群，郭红霞，李永卿，等.硅溶胶／苯丙乳液杂化复合木材的制备与性能[J].北京工业大学学报，2006，32(7)：638-641.
[97]王群，郭红霞，李永卿，等.有机/无机杂化复合木材的制备与性能[J].化学研究与应用，2006，18(8)：939-942.
[98]郭红霞，王群，李永卿，等.SiO2／醋丙核壳复合物的合成及其对木材的改性[J].北京工业大学学报，2007，33(10):1091-1095.
[99]徐春利，郭红霞，林兰英，等.聚合物改性水玻璃均相杂化液对速生杨木的改性[J].化学研究与应用，2010，22（2）：240-243.
[100]沈德君，周丛礼.纳米复合材料改性杨木木材的物理力学性能[J].东北林业大学学报，2009,37，（3）：53-54.
[101]时尽书，李建章，周文瑞，等.脲醛树脂与纳米二氧化硅复合改善木材性能的研究[J].北京林业大学学报，2006,28（2）：123-128.
[102]尹思慈.木材学[M].北京：中国林业出版社，2002.
[103]崔会旺，杜官本.我国木材功能性改良研究进展[J].林产工业，2007,06：3-7.
[104]段新芳，孙芳利，官恬.世界木材颜色调控技术研究现状及其展望[J].国际木业，2002,12：9-11.
[105]陈玉和，胡伟华，常德龙.泡桐木材漂白过程中双氧水分解率的研究[J].木材工业，2011,15（6）：6-8.
[106]William George Campbell, Geoffrey Swann. The bleaching action of alkaline hydrogen peroxide onwood[J].Pubmed Central,1938,45(2):702-707.
[107]Mustafa USTA, Ahmet TUTUS.The effect of bleaching conditions on the physical and opticalproperties during the bleaching of CTMP with peroxide[J]. J. of Agriculture and Forestry,1999,23(2):423-429.
[108]Ayhan Z IF I, Musa ATAR, Burhanettin UYSAL. The effects of wood bleaching chemicals on thesurface gloss and the adhesion strength of varnishes. J. of Agriculture and Forestry,1999,23(3):763-770.
[109]Burhanettin UYSAL, Musa ATAR, Ayhan Z IF I. The effects of chemicals for using the bleachingof the wood surfaces on the layer hardness of varnish[J]. J. of Agriculture and Forestry,1999,23:443-450.
[110]Mehmet BUDAK.I, Musa ATAR. Effects of bleaching process on hardness and glossiness of pine wood(Masson pine Sylvestris L.) exposed to outdoor conditions[J]. Turk J Agric For,2001,25:201-207.
[111]熊伟，刘涛，胡书银，等.西藏桦木地板的漂白工艺[J].林业科技开发，1999，1:19-20.
[112]李军、吴智慧.出口工艺木扇扇页的漂白技术[J].林产工业，2002,29（2）：43-44.
[113]陈玉和，黄文豪，常德龙，等.氢氧化钠预处理对木材漂白促进作用的研究[J].林产化学与工业，2000，20(1)：52-56.
[114]范智才，朱同林，彭万喜，等.抽提对尾巨桉木材漂白性影响研究[J].浙江林业科技，2007,29（1）：16-19.
[115]程书娜，徐明，傅深渊.黄芸香仿黑胡桃的染色技术研究[J].林产工业，2007,34（3）：14-17.
[116]张仲凤，彭万喜，张明龙，等.毛白杨仿黑胡桃的染色工艺试验[J].人造板通讯，2005，（2）：29-31.
[117]彭万喜，李凯夫，何嘉凤，等.巨尾桉仿黑胡桃的染色工艺研究[J].木材加工机械，2005，（2）：15-18.
[118]陈玉和.人造板仿黑胡桃木贴面技术[J].人造板通讯，2003，（6）：10-11.
[119]陈玉和，陆仁书，杨洪义.泡桐木材仿红木染色工艺的研究[J].林产工业，2001,28（4）：17-19.
[120]金菊婉，封维忠，华毓坤.彩色定向结构刨花板的研制[J].木材工业，1999,13（5）：14-16.
[121]武林，于志明.计算机配色技术在木材连缸染色中的应用研究[J].北京林业大学学报，2007，29（1）：146-150.
[122]Funaoka M., T. Kako, et al. Condensation of ligin during heating of wood [J]. Wood sci Technol,1990,24:277-288.
[123]Andersson Seppo, Rita Sermaa, et al. X-ray scattering studies of tyermally modified scots pine [J].Holzfoeschung,2005,59:422-427.
[124]Jun Li Shi, D. Kocaefe, J. Zhang. Mechanical behaviour of Qu′ebecwood species heat-treated usingThermo Wood process[J]. Holz als Roh und Werkstoff,(2007)65:255–259.
[125]Hakkou Mohammed, Mathieu Pétrissans, et al. Wettaability changes and mass loss during heattreatment of wood [J]. Holzforschung,2005,59:35-37.
[126]关鑫，郭明辉.木材纹理强化技术[J].家具，2009,174（5）：42-45.
[127]冼迪妍，曹新民，李建堂，等.水曲柳木皮热改色工艺的研究[J].广东林业科技，2010，26（1）：29-32.
[128]涂覆涂料前钢材表面处理_表面处理方法_磨料喷射清理[S].中华人民共和国国家标准：GB／T_18839.2—2002.
[129]李宝权.木材表面的喷砂处理[J].林业科技，1997,22（5）：56-57.
[130]汪世平.附着力[J].上海涂料，1997,2:115（51）-118（54）.
[131]王宏斌，朱典想，王厚立.木材表面立体自然纹理加工设备的初步设计[J].木材加工机械，2008，（4）：33-34.
[132]王宏斌，朱典想，王厚立，等.水杉板材表面凹凸纹理加工前处理方法研究[J].西北林学院学报，2007,22（5）：159-160.
[133]成俊卿，杨家驹，刘鹏.中国木材志[M].北京：中国林业出版社，1992.
[134]成俊卿.木材学[M].北京：中国林业出版社，1985.
[135]邱坚，李坚，刘一星. SiO2溶胶空细胞法浸渍处理木材工艺[J].林业科学.2008，44（3）：124-128.
[136]林兰英.硅溶胶强化杨木复合材的制备与性能研究[D].中国林业科学研究院博士学位论文.2008.
[137]李坚.木材波谱学[M].北京：科学出版社，2003.
[138]符韵林，赵广杰.木材／二氧化硅复合材料的微细构造[J].北京林业大学学报，2006,28（5）:119-124.
[139]武国峰，姜亦飞，宋舒苹，等.木材／改性UF预聚体复合材料制备及性能表征[J].光谱学与光谱分析，2011,31（4）：1083-1086.
[140]刘一星，刘海鹏，赵荣军.木质环境学[M].北京：科学出版社，2007.
[141]杨世铭，陶文铨.传热学[M].北京：高等教育出版社，2006.
[142]田晓瑞，舒立福.锥形量热仪（CONE）在林火研究中的应用[J].森林防火，2000，2：25～26.
[143]李坚，王清文.用CONE法研究木材阻燃剂FRW的阻燃性能，林产化学与工业，2004，24(2):29-34.
© 2004-2018 中国地质图书馆版权所有 京ICP备05064691号 京公网安备11010802017129号 地址：北京市海淀区学院路29号 邮编：100083 电话：办公室：(+86 10)66554848；文献借阅、咨询服务、科技查新：66554700 |