文冠果种仁油制备生物柴油技术的研究
|
摘要
本文充分利用地区资源优势，以赤峰市阿鲁科尔沁旗的文冠果和内蒙古杭锦旗境内杭锦2#土为原料，对文冠果种仁油制备生物柴油的技术进行了研究，其主要的研究内容如下：
1、以文冠果种仁为原料，研究了不同的提取溶剂和不同的提取方法对文冠果种仁油的提取效率，确定了适宜的提取溶剂和提取方法，并对文冠果种仁油的主要理化性质进行了测定，得到了以下结论。
(1)适宜的提取溶剂为石油醚(沸程60℃-90℃)；
(2)以石油醚(沸程60℃-90℃)为提取剂，确定了较为适宜的提取方法为超声波辅助提取法，并采用中心复合(CCD)试验设计法进行优化试验，应用Design expert软件对试验结果进行回归分析，获得了数学模型；在所选试验区域内，最佳提取工艺条件为：提取温度为65℃，提取时间为50min，液料比为9:1，在该条件下文冠果种仁的出油率为62.56%。
(3)测定文冠果种仁油的相对密度为0.8459g/cm3，酸值为0.626gKOH/g，皂化值为162.0gKOH/g，平均分子量为1042.92g/mol。
2、以精制的文冠果种仁油为原料，以氢氧化钠为催化剂采用均相碱催化法催化制备生物柴油，并采用中心复合(CCD)试验设计安排优化试验，应用Design expert软件对试验结果进行回归分析，同时对其产物进行了定性和定量的分析，得到了以下结论。
(1)通过对试验结果的拟合分析，获得了数学模型；在所选试验区域内，最佳制备工艺条件为：醇油摩尔比为7:1，反应温度为62℃，催化剂用量油重的0.9%，在该条件下生物柴油得率为89.05%。
(2)通过气相色谱检测，确定文冠果油基生物柴油的主要成分为软脂酸甲酯、油酸甲酯、亚油酸甲酯、亚麻酸甲酯和芥酸甲酯。
(3)建立了以硬脂酸甲酯为内标物测定文冠果油基生物柴油中脂肪酸甲酯含量的内标法，测得最佳工艺条件下文冠果油基生物柴油中脂肪酸甲酯的总含量为99.33%。
3、以杭锦2#土为原料，采用硫酸活化的方式制备活性白土，并采用溶胶-凝胶法制备SO2-4/SnO2—杭锦2#土固体酸催化剂，通过BET、FT-IR、XRD、TG、SEM对催化剂进行表征，得到了以下结论。
(1)适宜的活化条件为：H2SO4的浓度为3.0mol/L，活化温度为90℃，液固比为5:1，经对胡麻油进行脱色试验，可以确定其具有较强的吸附性，可以用于SO2-4/SnO2—杭锦2#土固体酸催化剂的制备。
(2) SO2-#4/SnO2—杭锦2土固体酸催化剂的制备条件为：SnCl4溶液的浓度为0.4mol/L，H2SO4溶液的浸渍浓度为3.0mol/L，焙烧温度为350℃。
4、以文冠果种仁为原料、石油醚(沸程60℃-90℃)为提取剂、甲醇为合成剂，分别以NaOH和自制的SO2-4/SnO2—杭锦2#土固体酸为催化剂，重点研究了文冠果种仁一步法制取生物柴油的工艺，采用中心复合(CCD)试验设计安排优化试验，应用Design expert软件对试验结果进行回归分析，得到了以下结论。
(1)通过对试验结果的拟合分析，获得了以NaOH为催化剂时的数学模型；在所选试验区域内，最佳制取工艺为：提取/反应温度为77℃，石油醚用量为6:1(mL/g)，甲醇用量为文冠果种仁质量的12%(mL/g)，NaOH用量为文冠果种仁质量的0.3%(质量比)，在该条件下生物柴油得率为65.58%。
(2)通过对试验结果的拟合分析，获得了自制的SO2-4/SnO2—杭锦2#土固体酸为催化剂时的数学模型；在所选试验区域内，最佳制取工艺为：提取/反应温度为81℃，石油醚用量为4:1(mL/g)，甲醇用量为文冠果种仁质量的12%(mL/g)，催化剂用量为文冠果种仁质量的0.7%(质量比)，在该条件下生物柴油得率为90.67%。
(3)由试验结果分析可知，采用自制的SO2-4/SnO2—杭锦2#土固体酸催化剂一步法更适宜催化文冠果种仁制取生物柴油，因此，该方法具有很大的研究潜力的。
5、采用气相色谱法和红外光谱法对一步法制取的产物进行了定性和定量的分析，并采用相应的国标方法对一步法制取的文冠果油基生物柴油的基本理化性能进行了测定，得到了以下结论。
(1)通过气相色谱和红外光谱分析，确定一步法制取的产物为多种脂肪酸甲酯的混合物，且主要由软脂酸甲酯、油酸甲酯、亚油酸甲酯、亚麻酸甲酯和芥酸甲酯组成。
(2)通过对一步法制取的文冠果油基生物柴油的基本理化性能测定结果分析可知，其主要性能指标完全符合我国0#柴油标准，与德国生物柴油标准非常接近，认为其可以替代石化柴油，可以为将来的能源供应提供一条有效途径。
In order to make full use of local resources, Xanthoceras sorbiflia bunge inAlukerqinqi and Hangjin2#caly were ulilized to synthetize biodiesel in this fhesis,themain contents are as follows:
1、It has been studied that Xanthoceras Sorbifolia Bunge seed oil was extracted fromfour kinds of solvents and by three methods, i.e. Soxhlet extraction, microwave assistedextraction, ultrasonic-assisted extraction. The results showed that the optimal extractionsolvent was petroleum ether (60℃-90℃). Tthe effects of factors such as extractiontemperature, extraction times and liquid-solid ratio on the extraction ratio of XanthocerasSorbifolia Bunge seed oil were fully investigated. According to single factor and CentralComposite Design experiment. the predictive model of polynomial quadratic equationwas established by Design Expert software. In the model, extraction temperature,extraction times and liquid-solid were independent variables and oil yield was responsevalue. The model could predict the oil extraction ratio. The results demonstrated that theoptimal extraction temperature was65℃, extraction time was50min and liquid-solidratio were7:1. The oil yield was62.56%under the optimal condition. Physical andchemical test results indicated that specific gravity was0.8459g/cm3and acid value was0.626gKOH/g and saponification value was162.0gKOH/g and the average molecularweight was1042.92g/mol.
2、The two step technique was investigated to accomplish biodiesel synthesis withXanthoceras sorbifolia bunge seed oil. Through single factors experiments, theinfluences of ratio between methyl hydrate and Xanthoceras Sorbifolia Bunge seed oil,reaction temperature and dosage of catalyst were discussed. For process optimization ofbiodiesel production from Xanthoceras sorbifolia Bunge seed oil, The Experiment ofbiodiesel synthesis was designed using Central Composite Design. The predictive modelof polynomial quadratic equation was established with Design Expert software. In themodel, ratio between methyl hydrate and Xanthoceras Sorbifolia Bunge seed oil, reactiontemperature and dosage of catalyst were independent variables and biodiesel yield wasresponse value. The model could predict the biodiesel synthesis ratio. The results showedthat the optimal ratio between methyl hydrate and Xanthoceras Sorbifolia Bunge seedoilwas7:1, reaction temperature was62℃and dosage of catalyst was0.9%ofXanthoceras sorbifolia bunge seed oil amount. The biodiesel yield was89.05%under theoptimal condition. Agas chromatography method has been developed for the quantitative determination of fatty acid methyl esters by internal standard method with stearic acidmethyl. The results showed that the main components of biodiesel was methyl palmitate,methyl oleate, methyl linoleate, methyl linolenate and methyl erueate. the fatty acidmethyl esters amount of biodiesel was99.32%by the method
3、The Hangjin2#clay was activated by sulfuric acid and the SnO2-Hangjin2#claywas prepared.Then the solid acid catalyst of SO2-4/SnO2-Hangjin2#clay was prepared byimpregnation method with sulfuric acid. The results showed that the concentrations ofSnCl4solution and H2SO4were0.4mol/L,3.0mol/L, respectively. The calcinationtemperature was350℃. The products of the catalyst were characterized and analyzedthrough BET、FT-IR、XRD、TG-DTAand SEM
4、The single-step technique was studied on the synthesis of biodiesel fromXanthoceras Sorbifolia bunge seeds in this thesis. The oil extraction and ester exchangereaction was conducted under water bath heating and magnetic stirring with petroleumether as extraction agent, methanol synthesis agent, sodium hydroxide and solid acid asthe catalyst. Through single factor experiments, the influences of temperature ofextraction and reaction, Petroleum ether amount, methanol amount and dosage of catalystwas discussed. In order to optimize of biodiesel synthesis, the single-step technique wasinvestigated to accomplish oil extraction and biodiesel synthesis from Xanthocerassorbifolia bunge seeds using central composite design. The predictive model ofpolynomial quadratic equation was established with Design Expert software. In themodel, temperature of extraction and reaction, Petroleum ether amount, methanol amountand dosage of catalyst were independent variables and biodiesel yield was response value.The model could not only predict the biodiesel synthesis ratio but also calculate oilrecovery. When the catalyst was sodium hydroxid, the results showed that the optimaltemperature of extraction and reaction was77℃, petroleum ether amount was6:1(mL/g),methanol and sodium hydroxide were12%(mL/g) and0.3%(g/g)of Xanthocerassorbifolia bunge seed amount respectively. The biodiesel yield was65.58%under theoptimal condition. When the catalyst was solid acid of SO2-4/SnO2-Hangjin2#clay, theresults showed that the optimal temperature of extraction and reaction was81℃,petroleum ether amount was4:1(mL/g), methanol and sodium hydroxide were12%(mL/g) and0.7%(g/g)of Xanthoceras sorbifolia bunge seed amount respectively. Thebiodiesel yield was90.67%under the optimal condition. The experimental resultsindicated that the single-step technique was more suitable for the use solid acid catalystof SO2-4/SnO2-Hangjin2#clay. Therefore, the single-step technique of biodiesel synthesisfrom Xanthoceras Sorbifolia bunge seeds will has great research potential with SO2-4/SnO2-Hangjin2#clay as catalysts.
5、 Chemical constituents and character of production were synthesized bysingle-step through FT-IR and GC, The results showed that the main components ofproduction was methyl palmitate, methyl oleate, methyl linoleate, methyl linolenate andmethyl erueate. The quality criteria of the biodiesel produced from XanthocerasSorbifolia bunge seeds meet the same standards to0#of China and DINV51606ofGermany, The experimental results indicated that biodiesel of Xanthoceras Sorbifoliabunge seeds could substitute for diesel fuel, It could be an efficient approach to resolvethe recent energy crisis.
1、以文冠果种仁为原料，研究了不同的提取溶剂和不同的提取方法对文冠果种仁油的提取效率，确定了适宜的提取溶剂和提取方法，并对文冠果种仁油的主要理化性质进行了测定，得到了以下结论。
(1)适宜的提取溶剂为石油醚(沸程60℃-90℃)；
(2)以石油醚(沸程60℃-90℃)为提取剂，确定了较为适宜的提取方法为超声波辅助提取法，并采用中心复合(CCD)试验设计法进行优化试验，应用Design expert软件对试验结果进行回归分析，获得了数学模型；在所选试验区域内，最佳提取工艺条件为：提取温度为65℃，提取时间为50min，液料比为9:1，在该条件下文冠果种仁的出油率为62.56%。
(3)测定文冠果种仁油的相对密度为0.8459g/cm3，酸值为0.626gKOH/g，皂化值为162.0gKOH/g，平均分子量为1042.92g/mol。
2、以精制的文冠果种仁油为原料，以氢氧化钠为催化剂采用均相碱催化法催化制备生物柴油，并采用中心复合(CCD)试验设计安排优化试验，应用Design expert软件对试验结果进行回归分析，同时对其产物进行了定性和定量的分析，得到了以下结论。
(1)通过对试验结果的拟合分析，获得了数学模型；在所选试验区域内，最佳制备工艺条件为：醇油摩尔比为7:1，反应温度为62℃，催化剂用量油重的0.9%，在该条件下生物柴油得率为89.05%。
(2)通过气相色谱检测，确定文冠果油基生物柴油的主要成分为软脂酸甲酯、油酸甲酯、亚油酸甲酯、亚麻酸甲酯和芥酸甲酯。
(3)建立了以硬脂酸甲酯为内标物测定文冠果油基生物柴油中脂肪酸甲酯含量的内标法，测得最佳工艺条件下文冠果油基生物柴油中脂肪酸甲酯的总含量为99.33%。
3、以杭锦2#土为原料，采用硫酸活化的方式制备活性白土，并采用溶胶-凝胶法制备SO2-4/SnO2—杭锦2#土固体酸催化剂，通过BET、FT-IR、XRD、TG、SEM对催化剂进行表征，得到了以下结论。
(1)适宜的活化条件为：H2SO4的浓度为3.0mol/L，活化温度为90℃，液固比为5:1，经对胡麻油进行脱色试验，可以确定其具有较强的吸附性，可以用于SO2-4/SnO2—杭锦2#土固体酸催化剂的制备。
(2) SO2-#4/SnO2—杭锦2土固体酸催化剂的制备条件为：SnCl4溶液的浓度为0.4mol/L，H2SO4溶液的浸渍浓度为3.0mol/L，焙烧温度为350℃。
4、以文冠果种仁为原料、石油醚(沸程60℃-90℃)为提取剂、甲醇为合成剂，分别以NaOH和自制的SO2-4/SnO2—杭锦2#土固体酸为催化剂，重点研究了文冠果种仁一步法制取生物柴油的工艺，采用中心复合(CCD)试验设计安排优化试验，应用Design expert软件对试验结果进行回归分析，得到了以下结论。
(1)通过对试验结果的拟合分析，获得了以NaOH为催化剂时的数学模型；在所选试验区域内，最佳制取工艺为：提取/反应温度为77℃，石油醚用量为6:1(mL/g)，甲醇用量为文冠果种仁质量的12%(mL/g)，NaOH用量为文冠果种仁质量的0.3%(质量比)，在该条件下生物柴油得率为65.58%。
(2)通过对试验结果的拟合分析，获得了自制的SO2-4/SnO2—杭锦2#土固体酸为催化剂时的数学模型；在所选试验区域内，最佳制取工艺为：提取/反应温度为81℃，石油醚用量为4:1(mL/g)，甲醇用量为文冠果种仁质量的12%(mL/g)，催化剂用量为文冠果种仁质量的0.7%(质量比)，在该条件下生物柴油得率为90.67%。
(3)由试验结果分析可知，采用自制的SO2-4/SnO2—杭锦2#土固体酸催化剂一步法更适宜催化文冠果种仁制取生物柴油，因此，该方法具有很大的研究潜力的。
5、采用气相色谱法和红外光谱法对一步法制取的产物进行了定性和定量的分析，并采用相应的国标方法对一步法制取的文冠果油基生物柴油的基本理化性能进行了测定，得到了以下结论。
(1)通过气相色谱和红外光谱分析，确定一步法制取的产物为多种脂肪酸甲酯的混合物，且主要由软脂酸甲酯、油酸甲酯、亚油酸甲酯、亚麻酸甲酯和芥酸甲酯组成。
(2)通过对一步法制取的文冠果油基生物柴油的基本理化性能测定结果分析可知，其主要性能指标完全符合我国0#柴油标准，与德国生物柴油标准非常接近，认为其可以替代石化柴油，可以为将来的能源供应提供一条有效途径。
In order to make full use of local resources, Xanthoceras sorbiflia bunge inAlukerqinqi and Hangjin2#caly were ulilized to synthetize biodiesel in this fhesis,themain contents are as follows:
1、It has been studied that Xanthoceras Sorbifolia Bunge seed oil was extracted fromfour kinds of solvents and by three methods, i.e. Soxhlet extraction, microwave assistedextraction, ultrasonic-assisted extraction. The results showed that the optimal extractionsolvent was petroleum ether (60℃-90℃). Tthe effects of factors such as extractiontemperature, extraction times and liquid-solid ratio on the extraction ratio of XanthocerasSorbifolia Bunge seed oil were fully investigated. According to single factor and CentralComposite Design experiment. the predictive model of polynomial quadratic equationwas established by Design Expert software. In the model, extraction temperature,extraction times and liquid-solid were independent variables and oil yield was responsevalue. The model could predict the oil extraction ratio. The results demonstrated that theoptimal extraction temperature was65℃, extraction time was50min and liquid-solidratio were7:1. The oil yield was62.56%under the optimal condition. Physical andchemical test results indicated that specific gravity was0.8459g/cm3and acid value was0.626gKOH/g and saponification value was162.0gKOH/g and the average molecularweight was1042.92g/mol.
2、The two step technique was investigated to accomplish biodiesel synthesis withXanthoceras sorbifolia bunge seed oil. Through single factors experiments, theinfluences of ratio between methyl hydrate and Xanthoceras Sorbifolia Bunge seed oil,reaction temperature and dosage of catalyst were discussed. For process optimization ofbiodiesel production from Xanthoceras sorbifolia Bunge seed oil, The Experiment ofbiodiesel synthesis was designed using Central Composite Design. The predictive modelof polynomial quadratic equation was established with Design Expert software. In themodel, ratio between methyl hydrate and Xanthoceras Sorbifolia Bunge seed oil, reactiontemperature and dosage of catalyst were independent variables and biodiesel yield wasresponse value. The model could predict the biodiesel synthesis ratio. The results showedthat the optimal ratio between methyl hydrate and Xanthoceras Sorbifolia Bunge seedoilwas7:1, reaction temperature was62℃and dosage of catalyst was0.9%ofXanthoceras sorbifolia bunge seed oil amount. The biodiesel yield was89.05%under theoptimal condition. Agas chromatography method has been developed for the quantitative determination of fatty acid methyl esters by internal standard method with stearic acidmethyl. The results showed that the main components of biodiesel was methyl palmitate,methyl oleate, methyl linoleate, methyl linolenate and methyl erueate. the fatty acidmethyl esters amount of biodiesel was99.32%by the method
3、The Hangjin2#clay was activated by sulfuric acid and the SnO2-Hangjin2#claywas prepared.Then the solid acid catalyst of SO2-4/SnO2-Hangjin2#clay was prepared byimpregnation method with sulfuric acid. The results showed that the concentrations ofSnCl4solution and H2SO4were0.4mol/L,3.0mol/L, respectively. The calcinationtemperature was350℃. The products of the catalyst were characterized and analyzedthrough BET、FT-IR、XRD、TG-DTAand SEM
4、The single-step technique was studied on the synthesis of biodiesel fromXanthoceras Sorbifolia bunge seeds in this thesis. The oil extraction and ester exchangereaction was conducted under water bath heating and magnetic stirring with petroleumether as extraction agent, methanol synthesis agent, sodium hydroxide and solid acid asthe catalyst. Through single factor experiments, the influences of temperature ofextraction and reaction, Petroleum ether amount, methanol amount and dosage of catalystwas discussed. In order to optimize of biodiesel synthesis, the single-step technique wasinvestigated to accomplish oil extraction and biodiesel synthesis from Xanthocerassorbifolia bunge seeds using central composite design. The predictive model ofpolynomial quadratic equation was established with Design Expert software. In themodel, temperature of extraction and reaction, Petroleum ether amount, methanol amountand dosage of catalyst were independent variables and biodiesel yield was response value.The model could not only predict the biodiesel synthesis ratio but also calculate oilrecovery. When the catalyst was sodium hydroxid, the results showed that the optimaltemperature of extraction and reaction was77℃, petroleum ether amount was6:1(mL/g),methanol and sodium hydroxide were12%(mL/g) and0.3%(g/g)of Xanthocerassorbifolia bunge seed amount respectively. The biodiesel yield was65.58%under theoptimal condition. When the catalyst was solid acid of SO2-4/SnO2-Hangjin2#clay, theresults showed that the optimal temperature of extraction and reaction was81℃,petroleum ether amount was4:1(mL/g), methanol and sodium hydroxide were12%(mL/g) and0.7%(g/g)of Xanthoceras sorbifolia bunge seed amount respectively. Thebiodiesel yield was90.67%under the optimal condition. The experimental resultsindicated that the single-step technique was more suitable for the use solid acid catalystof SO2-4/SnO2-Hangjin2#clay. Therefore, the single-step technique of biodiesel synthesisfrom Xanthoceras Sorbifolia bunge seeds will has great research potential with SO2-4/SnO2-Hangjin2#clay as catalysts.
5、 Chemical constituents and character of production were synthesized bysingle-step through FT-IR and GC, The results showed that the main components ofproduction was methyl palmitate, methyl oleate, methyl linoleate, methyl linolenate andmethyl erueate. The quality criteria of the biodiesel produced from XanthocerasSorbifolia bunge seeds meet the same standards to0#of China and DINV51606ofGermany, The experimental results indicated that biodiesel of Xanthoceras Sorbifoliabunge seeds could substitute for diesel fuel, It could be an efficient approach to resolvethe recent energy crisis.
引文
1胡思,窦涛,巩雁军等.生物柴油:引领新能源时代的潮流[J].发明与创新(综合版),2008,(12):38-39
2廖李,甲醇/乙醇混合体系酯交换制备生物柴油的研究[D].硕士论文,华中农业大学,2008.
3石油对外依存度2015年将超60%[EB/OL]. http://oil.in-en.com/html/oil082408244-71206401.html,2011
4孙俊.文冠果油的提取及其生物柴油制备工艺研究[D].硕士论文,陕西师范大学,2008
5王涛.中国主要生物质燃料油木本能源植物资源概况与展望[J].科技导报,2005,23(5):12-14
6陈程.绿色植物—能源的希望[J/OL]. http://www.doc88.com/p-917992087713.html,2013
7林业生物质能源：我国蕴藏巨大潜力[EB/OL]. http://www.forestry.gov.cn/portal/swzny/s/740/content-102859.html,2006
8国家发改委提出生物质能源发展规划[J].资源节约与环保,2006,22(5):21
9蔡钰莹,商平,赵瑞华等.超声波处理废油脂制取生物柴油的研究[J].石油炼制与化工,2008,39(1):62-65
10Diego Lomonaco, Francisco Jonas N. Maia, Claudenilson S. Clemente, et al.Thermalstudies of new biodiesel antioxidants synthesized from a natural occurringphenolic lipid[J]. Fuel,2012,(97):552-559
11Dussadee Rattanaphra, Adam P. Harvey, Anusith Thanapimmetha, et al. Simultaneoustransesterification and esterification for biodiesel production with and without asulphated zirconia catalyst[J]. Fuel,2012,(97):467-475
12Chen Yi-Hung, Chen Jhih-Hong, Luo Yu-Min. complementary biodiesel combination fromtung and medium-chain fatty acid oils[J]. Renewable Energy,2012,(44):305-310
13姜绍通,徐涟漪,周勤丽等.固体碱催化棉籽油制备生物柴油[J].农业工程学报,2011,27(3):254-259
14Abraham Casas, Maria Jesus Ramos, Angel Perez. New trends in biodieselproduction:Chemical interesterification of sunflower oil with methyl acetate s[J].biomass and bioenergy,2011,(35):1702-1709
15郝一男,王喜明,丁立军.文冠果籽油制备生物柴油的工艺研究[J].内蒙古农业大学学报,2011,32(2):224-229
16Liu Yingying, Lu Houfang, Jiang Wei, et al. Biodiesel Production from Crude Jatrophacurcas L. Oil with TraceAcid Catalyst[J]. Chinese Journal of Chemical Engineering,2012,20(4):740-746
17Grisel Corro, Nallely Tellez,Fortino Banuelos, et al. Biodiesel from Jatropha curcasoil using Zn for esterification step and solarradiation as energy source [J]. Fuel,2012,(97):72-79
18Jitputti, Kitiyanan, Rangsuvigit, et al. Transesterification of crudepalm kerneloil andcrude coconut oil by different solid catalysts[J].Chemical EngineeringJournal,2006,116(1):61-66
19蒲志鹏,王卫刚,蒋建新,等.黄连木生物柴油及其低温流动性能研究[J].北京林业大学学报,2009,31(Supp.1)：56-61
20刘玉环,王允圃,王应宽,等.微波裂解光皮树油皂化物脱羧制备烃类燃料研究[J].农业机械学报,2012,43(2):111-117
21侯坚,张培栋,袁宪正等.基于开放式培养的微藻生物柴油生命周期环境影响评价[J].农业工程学报,2011,27(7):251-257
22高伟星,那晓婷,刘克武.生物质能源植物———文冠果[J].中国林副特产,2007,(1):93-94
23牟洪香,侯新村.文冠果的研究进展[J].安徽农业科学,2007,35(3):703-705
24马启慧.能源树种文冠果的研究现状与发展前景[J].北方园艺,2007,(8):77-78
25高述明,马凯,杜希华,等.文冠果(Xanthoceras sorbifoliaBunge)研究进展[J].植物学通报,2002,19(3):296-301
26滕虎,牟英,杨天奎,等.生物柴油研究进展[J].生物工程学报,2010,(7):50-60
27中国经济时报电子刊[EB/OL]. http://lib.cet.com.cn/paper/szb_con/152767.html,2013
28杨颖.生物柴油产业国内外现状及我国发展对策[J].粮油加工.2007,(10):75-78
29汤颖,陈刚,穆淑珍.国内外生物柴油发展现状及中国的应对策略[J].世界农业,2010,(8):10-12
30李超民.美国生物柴油产业政策变化的经济后果[J].农业展望,2008,(11):40-43
31Subramanian KA, Singal SK, Saxena M, et al. Utilizationof liquid biofuels inautomotive diesel engines: an Indianperspective. Biomass Bioenerg,2005,(29):65-72
32Azam M M,Waris A,Nahar N M. Prospects and potential of fattyacid methyl esters ofsome non-traditional seed oils for use asbiodiesel in india[J]. Biomass andBioenergy,2005,(29):293-302
33Zhong C,Cao Y-X,Li B-Z,et al. Biofuels in China: Past,presentand,future[J]. BiofuelsBioproducts and Biorefining,2010,4(3):326-342
34Shao H,Chu L. Resource evaluation of typical energy plants and possible functionalzone planning in China[J]. Biomass and Bioenergy,2008,32:283-288
35Kalam MA, Masjuki HH. Recent development on biodieselin Malaysia. J Sci Ind Res,2005,64(11):920-927
36徐薇.我国生物柴油产业发展研究[D].硕士论文,北京林业大学,2008
37张良波,李昌珠,欧日明等.生物柴油产业现状与展望[J],湖南农林科技,2008,(2):70-73
38Lifka,J,Ondruschka,B.Influence of mass transfer on the Production of Biodiesel[J].Chemie ingenieur Technik,2004,(79):168
39Ma F,Hanna MA. Biodiesel production: a review[J]. Bioresource Technol,1999,(70):1-15
40Zhang Y,Duke M A,Mclean D D,et al.Biodiesel Production from waste cookingoil:1.Process design and technological assessment[J].Bioresource Tchnology,2003,(9):1-6
41S.Siler-Marinkovic,A.Tomasevic.Transesterification of sunflower oil in situ[J].Fuel,1998,(79):1389-1391
42符太军,纪威,姚亚光等.地沟油制取生物柴油的试验研究[J].能源技术,2005,26(3):106-108
43谢国剑.潲水油制取生物柴油燃料的研究[J].化工科技,2005,13(4):20-22,29
44李胜清,刘俊超,刘汉兰等. B酸离子液体催化剂在生物柴油制备中的应用[J].湖北农业科学,2009,48(2):438-441
45谷学军,赵飞,王宝鑫等.离子液体SMIA催化大豆油制备生物柴油组分的研究[J].辽宁大学学报,2010,37(2):136-140
46邬国英,林西平,巫淼鑫等.棉籽油甲酯化联产生物柴油和甘油[J].中国油脂,2003,28(4):70-73
47Tomasevic A V,Siler Marinkovi S S C.Methanolysis of used frying oil[J].FuelProcessing Technology,2003,81(1):1-6
48Sanjib KumarKarmeA,nju Chadha.Preparation of Biodiesel from crude oil of Pinnata[J].BioresourceTeehnology,2005,(96):1425-1429
49张无敌,尹芳,李建昌等.大豆油酯交换制备生物柴油的实验研究[J].农机化研究,2009,(9):189-192,199
50Gemma V, MercedesM J A. Integrated Biodiesel Production: a comparison of differenthomogeneous catalysts systems[J].Bioresource Technology,2004,(92):297-305
51林璟,方利国.麻疯果油制备生物柴油及其经济效益[J].化工进展,2008,27(12):1977-1981
52Abraham Casas, María Jesús Ramos, ángel Pérez. New trends in biodieselproduction:Chemical interesterification of sunflower oil with methylacetate[J].Biomass and Bioenergy,2011,(35):1702-1709
53Abraham Casas, Mar í a Jes ú s Ramos, á ngel P é rez. Kinetics of chemicalinteresterification of sunflower oil with methyl acetate forbiodiesel and triacetinproduction[J].Chemical Engineering Journal,2011(171):1324–1332
54David M. Fernandes, Dalyelli S. Serqueira, Flaysner M. Portela, et al. Preparationand characterization of methylic and ethylic biodiesel fromcottonseed oil and effectoftert-butylhydroquinone on its oxidative stability [J].Fuel,2012,(97):658–661
55熊道陵,舒庆,李英,等.生物柴油催化合成研究进展[J].江西理工大学学报,2012,33(1):10-16
56chen G, Fang B.Preparation of solid acid catalyst from glucose-strarch mixture forbiodiesel production[J]．Bioreource Technology,2011,102,(3):2635-2640
57Lopez D E, Suwannakarn K, Bruce D A. Esterification andtransesterification ontungstated zirconia: Effect of calcinationsftemperature[J]. Journal of Catalysis,2007,247(1):43-50
58Corro G,Tellez N, Ayala E, et al. Two-step biodiesel production from Jatrophacurcascrude oil using SiO2·HF solid catalyst for FFA esterification step[J],Fule,2010,89(10):2815-2821
59石彩静,李志成,余济伟,等.二氧化硅－硫酸氢钾固体酸催化制备生物柴油[J].中国油脂,2012,37(7):55-58
60翟绍伟,牛梅菊*,龚树文,等.负载固体酸催化豆油制备生物柴油的研究[J].天然气化工,2012,37(1):21-25
61李娜,李会鹏.负载型固体酸催化合成生物柴油[J].化学工业与工程,2012,29(2):74-78
62徐玲,陈建军,张立明,等.负载型磷钨酸催化剂的制备、表征及酯交换制备生物柴油[J].吉林大学学报(理学版),2012,50(2):346-350
63Serio M D, Cozzolino M, Tesser R, et al. Vanadyl phosphatecatalysts in biodieselproduction [J]. Applied Catalysis A:General,2007,(320):1-7
64Chai F, Cao F H, Zhai F Y, et al. Transesterification of veg-etable oil to biodieselusing a heteropolyacid solid catalyst[J]. Adv Synth Catal,2007,349(7):1057-1065
65Morin P, Hamad B, Sapaly G, et al． Transesterification ofrape-seed oil with ethanolCatalysis with homogeneousKeggin heteropolyacids t[J]. Applied Catalysis A:General,2007,(330):69-76
66夏亚穆,焦斌.非均相催化法生产生物柴油的研究进展[J].化学与生物工程,2012,29(3):6-8
67Deng X, Fang Z,Liu Y H, et al. Production of biodiesel from Jat-ropha oil catalyzedbynanosized solid basic catalyst[J].Energy,2011,36(2)777-784
68Boro J, Thakur A J, Deka D. Solid oxide derived from waste shells of TurLonillustriutulu as a renewable catalyst for biodie-sel production[J]. Fuel ProcessingTechnology,2011,92(10):2061-2067
69Kouzu M, Kasuno T, Tajika M, et al. Calcium oxide as a solidbase catalyst fortransesterification of soybean oil and its application to biodiesel production [J].Fue1,2008,87(12):2798-2806
70Bancquart S,Vanhove C, Pouilloux Y, et al. Glycerol transes-terification with methylstearate over solid basic catalysts:I.Relationship between activity and basicity[J].Applied catalysis A:General,2001,218(1-2):1-11
71刘守庆,李雪梅,赵雷修,等.固体碱CaO催化橡胶籽油制备生物柴油的研究[J].中国油脂,2012,37(7):59-6272周长行,张晓丽,高文艺,等.鸡蛋壳催化大豆油酷制备生物柴油[J].辽宁石油化工大学学报,2012,32(1):25-28
73曲旭坡.镁铝氧化物负载型催化剂催化制备生物柴油的研究[D].硕士论文,长春工业大学,2012
74赵策,曾虹燕,黄炎,等.镁铁水滑石的制备及其对小球藻油脂合成生物柴油的催化性能[J].燃料化学学报,2012,40(3):337-344
75杨玲梅,吕鹏梅,袁振宏,等. KOH负载的不同催化剂催化合成生物柴油[J].化工进展,2012,31(增刊):91-94
76李敏,丛兴顺,孙兰强.负载型NaOH/蒙脱石固体碱催化剂的制备及在生物柴油中的应用[J].工业催化,2011,19(12):97-100
77Kazuhiro Ban, Masaru Kaieda, Takeshi Matsumoto, et al．Whole Cell Biocatalyst forBiodiesel Fuel Production UtilizingRhizopus Oryzaecells Immobilize Within BiomassSupport Parti-cles[J]. Biochem Eng J,2001,8(1):39-43
78Li S F,Fan Y H, Hu R F,et al. Pseudomonas cepacia lipase im-mobilized onto theelectrospun PAN nanofibrous membranes for biodiesel production from soybean oi1[J].Journal of Molecular Catalysis B:Enzymatic,2011,72(1-2):40-45
79Noureddini H. Immobilized Pseudomonas Cepacia Lipase for Biodiesel Fuel Productionfrom Soybean Oil[J]. Bioresour Technol,2005,96(7):769-777
80Li Q, Yan Y. Production oI biodiesel catalyzed by immobilized Pseudomonascepacia-lipase from Sapium sebiferum oil in micro-aqueous phase [J]. Applied Energy,2010,87(10):3148-3154
81Yagiz F, Kazan D, Akin A N. Biodiesel Production fromWaste Oils Using LipaseImmobilized on Hydrotalcite and Zeo-lites [J]. Chem Eng J,2007,143(3):262-267
82Lee M, Lee J, Lee D, et al. Improvement of enzymatic biodiesel production by controlledsubstrate feeding using silica gel in solvent free system [J]. Enzyme and MicrobialTechnology,2011,49(4):402-406
83Li X, He X Y, Li Z I, et al. Enzymatic production of biodiesel from Pistacia chinensisbge seed oil using immobilized lipase [J]. Fue1,2012,92(1):89-93
84梁静娟,杨立鹏,韩钧,等.固定化脂肪酶在离子液体中催化合成生物柴油[J].可再生能源,2012,30(1):77-82
85徐桂转,岳建芝,张百良,等.脂肪酶连续催化桐油酯交换反应制取生物柴油[J].农业工程学报,2010,26(7):245-249
86李俊奎,王芳,谭天伟,等.固定化脂肪酶催化小桐子毛油合成生物柴油[J].北京化工大学学报(自然科学版),2010,37(2):102-105
87李青云,庾乐,覃益民,等.固定化酶催化山茶油制备生物柴油研究[J].可再生能源,2012,30(9):60-64
88申渝,张海东,郑旭煦,等.硅基MCF材料固载脂肪酶转化餐饮废油产生物柴油[J].化工学报,2012,63(6):1888-1892
89Hino M, Arata K. J. Chem. Soc. Chem. Commun.,1980,(18):851--852
90孟丽娜. SO42-/SnO2负载型固体酸的制备表征及催化性能研究[D].硕士论文,齐齐哈尔大学,2012
91刘艳林. SO42-/杭锦2#土的制备、表征及其催化性能研究[D].硕士论文,内蒙古师范大学,2008
92黄永茂,樊玉梅,程艳坤,等.固体酸催化麻疯树籽油制备生物柴油[J].粮油加工,2009,(3):50-53
93张六一,韩彩芸,杜东泉,等.硫酸化氧化锆固体超强酸[J].化学进展,2011,23(5):860-873
94孙晋峰.固体酸催化植物油酯交换制备生物柴油[D].硕士论文,上海师范大学,2009
95刘剑,孔琼宇.固体酸催化小桐子油制备生物柴油[J].长沙理工大学学报(自然科学版),2009,6(2):92-96
96卢怡,苏有勇． SO42-/Fe2O3固体酸的制备及其催化合成生物柴油的研究[J].化学与生物工程,2011,28(1):23-25
97呼晓姝,郝俊,王建中.超声波辅助提取元宝枫油的研究[J].中国粮油学报,2007,22(5):98-100
98高振鹏,岳田利,袁亚宏,等.超声波强化有机溶剂提取石榴籽油的工艺优化[J].农业机械学报,2008,39(5):77-80
99高霞,仇农学,庞福科,等.超声波辅助提取苹果籽油工艺研究[J].中国油料作物学报,2007,29(1):78-82100邓红,孙俊,何玲,等.不同方法提取的文官果籽油的GC-MS分析[J].食品科学,2007,28(8):354-357101GB5526-85,植物油比重的测定[S]102GB/T5530-2005,动植物油脂酸值和酸度测定[S]103GB/T5534-2008,动植物油脂皂化值的测定[S]104黄彩霞,刘荣厚.菜籽油碱催化法制备生物柴油的工艺参数[J].农业工程学报,2009,25(12):234－239105郝一男,文冠果种仁油的提取及其生物柴油合成的研究[D].博士论文,内蒙古农业大学学报,2011
106洪瑶,陈文伟,朱悦,等.芝麻粕蛋白的提取研究[J].中国食品添加剂,2010,(4):169-172
107陈伟文,乌桕籽油制备生物柴油的研究[D].博士论文,南昌大学,2006
108陈曾,吴玉龙,陶玲,等.响应曲面法优化文冠果油提取工艺的研究[J].农产品加工学刊,2010,(7):8-12
109唐志红,吕家森.贾晓晨,等.羊栖菜多糖微波提取工艺的研究[J].时珍国医国药,2011,22(10):2440-2441
110马养民,张航涛,郭俊荣,等.文冠果种子油制备生物柴油工艺的研究[J].技术油脂工程,2010,(1):30-32
111Daniele F, Valerio B, Marcello N, et al. Properties of apotential biofuel obtainedfrom soybean oil by transmethylation with dimethyl carbonate[J]. Fuel,2007,(86):690-697
112Kevin J.Harrington.Chemieal and Physical Properties of Vegetbale oi1Esters and theireffect on Diesel Fuel Performance[J].Biomass,1986,(9):1-17
113范航,张大年,赵一先,等.生物柴油的研究与应用[J].上海环境科学,2000,1911):516-518
114乌云,照日格图,嘎日迪,等.活化条件对活性白土脱色率的影响研究[J].内蒙古师范大学学报,2004,33(4):411-413
115照日格图,乌云,宝迪巴特尔,等.杭锦2#土脱色剂的制备及其对植物油脱色性能的研究[J].中国油脂,2004,29(8):19-21
116白丽梅,郝向英,郭海福,等.固体酸SO42-/SnO2—杭锦2#土催化合成乙酸松油酯[J].内蒙古师范大学学报(自然科学汉文版),2011,40(3):278-282
117魏景芳,郝向英,郭海福,等. SO42-/杭锦2#土固体超强酸催化合成乙酸正丁酯[J].肇庆学院学报,2010,31(2):40-43
118照日格图,乌云,宝迪巴特尔,等.杭锦2#土脱色剂的制备及其对植物油脱色性能的研究[J].中国油脂,2004,29(8):19-21
119赵斌,谷克仁.活性白土的制备及性能研究[J].中国油脂,2002,27(2):56-58
120魏景芳,郝向英,闫鹏,等.不同酸处理对SO42-/杭锦2#土催化性能的影响[J].内蒙古师范大学学报(自然科学汉文版),2010,39(4):401-404
121盛梅,李为民,邬国英.生物柴油研究进展[J].中国油脂,2003,28(4):66-70
122Ayhan Demirbas. Biodiesel fuels from vegetable oils via catalytic and non-catalyticsupercritical alcohol transesterifi-cations and other methods A Survey[J]. EnergyConversion and Management,2003,44(13):2093-2109
123Kusdiana D, Saka S. Kinetics of transesterification in rapeseed oil to biodiesel fuelas treated in supercritical methanol[J]. Fuel,2001,(80):693-698
124Diasakou M, Louloudi A, Papayannakos N. Kinetics of the non-catalytictransesterification of soybean oil[J]. Fuel,1998,(77):1297-1302
125马志豪,张小玉,马凡华,等.生物柴油混合比对柴油机排放颗粒特性的影响[J].农业工程学报,2012,28(18):64-68
126王利兵.三种山杏种子生物柴油特征评价[J].农业工程学报,2011,27(增刊1):138-142
127张豪,乙引,洪鲲,等.响应面法优化酶促脂肪酸甲酯化工艺条件[J].农业工程学报,2011,27(增刊2):125-130
128易军鹏,朱文学,马海乐,等.牡丹籽油超声波辅助提取工艺的响应面法优化[J].农业机械学报,2009,40(6):103-110
129杨颖.生物柴油制备方法研究进展[J].粮油食品科技,2007,15(5):35-37
130鲁厚芳,史国强,刘颖颖,等.生物柴油生产及性质研究进展[J].化工进展,2011,30(1):126-135
131于海燕,周绍箕.文冠果油制备生物柴油的研究[J].中国油脂,2009,34(3):43-45
132中国石油化工股份有限公司科技开发部编.石油和石油产品试验方法国家标准汇编[M].北京:中国标准出版社,2005
133贾金波.固体酸催化合成生物柴油的研究[D].硕士论文,河北师范大学,2010
134柴油的质量要求及性能指标[J/OL]. http://wenku.baidu.com/view/2f66eb1ffc4ffe473368ab08.html,2013
135柳杨,衣怀峰,陈宇,等.酯交换生物柴油的柱层析分离纯化与分析[J].光谱学与光谱分析,2012,32(2):505-509
2廖李,甲醇/乙醇混合体系酯交换制备生物柴油的研究[D].硕士论文,华中农业大学,2008.
3石油对外依存度2015年将超60%[EB/OL]. http://oil.in-en.com/html/oil082408244-71206401.html,2011
4孙俊.文冠果油的提取及其生物柴油制备工艺研究[D].硕士论文,陕西师范大学,2008
5王涛.中国主要生物质燃料油木本能源植物资源概况与展望[J].科技导报,2005,23(5):12-14
6陈程.绿色植物—能源的希望[J/OL]. http://www.doc88.com/p-917992087713.html,2013
7林业生物质能源：我国蕴藏巨大潜力[EB/OL]. http://www.forestry.gov.cn/portal/swzny/s/740/content-102859.html,2006
8国家发改委提出生物质能源发展规划[J].资源节约与环保,2006,22(5):21
9蔡钰莹,商平,赵瑞华等.超声波处理废油脂制取生物柴油的研究[J].石油炼制与化工,2008,39(1):62-65
10Diego Lomonaco, Francisco Jonas N. Maia, Claudenilson S. Clemente, et al.Thermalstudies of new biodiesel antioxidants synthesized from a natural occurringphenolic lipid[J]. Fuel,2012,(97):552-559
11Dussadee Rattanaphra, Adam P. Harvey, Anusith Thanapimmetha, et al. Simultaneoustransesterification and esterification for biodiesel production with and without asulphated zirconia catalyst[J]. Fuel,2012,(97):467-475
12Chen Yi-Hung, Chen Jhih-Hong, Luo Yu-Min. complementary biodiesel combination fromtung and medium-chain fatty acid oils[J]. Renewable Energy,2012,(44):305-310
13姜绍通,徐涟漪,周勤丽等.固体碱催化棉籽油制备生物柴油[J].农业工程学报,2011,27(3):254-259
14Abraham Casas, Maria Jesus Ramos, Angel Perez. New trends in biodieselproduction:Chemical interesterification of sunflower oil with methyl acetate s[J].biomass and bioenergy,2011,(35):1702-1709
15郝一男,王喜明,丁立军.文冠果籽油制备生物柴油的工艺研究[J].内蒙古农业大学学报,2011,32(2):224-229
16Liu Yingying, Lu Houfang, Jiang Wei, et al. Biodiesel Production from Crude Jatrophacurcas L. Oil with TraceAcid Catalyst[J]. Chinese Journal of Chemical Engineering,2012,20(4):740-746
17Grisel Corro, Nallely Tellez,Fortino Banuelos, et al. Biodiesel from Jatropha curcasoil using Zn for esterification step and solarradiation as energy source [J]. Fuel,2012,(97):72-79
18Jitputti, Kitiyanan, Rangsuvigit, et al. Transesterification of crudepalm kerneloil andcrude coconut oil by different solid catalysts[J].Chemical EngineeringJournal,2006,116(1):61-66
19蒲志鹏,王卫刚,蒋建新,等.黄连木生物柴油及其低温流动性能研究[J].北京林业大学学报,2009,31(Supp.1)：56-61
20刘玉环,王允圃,王应宽,等.微波裂解光皮树油皂化物脱羧制备烃类燃料研究[J].农业机械学报,2012,43(2):111-117
21侯坚,张培栋,袁宪正等.基于开放式培养的微藻生物柴油生命周期环境影响评价[J].农业工程学报,2011,27(7):251-257
22高伟星,那晓婷,刘克武.生物质能源植物———文冠果[J].中国林副特产,2007,(1):93-94
23牟洪香,侯新村.文冠果的研究进展[J].安徽农业科学,2007,35(3):703-705
24马启慧.能源树种文冠果的研究现状与发展前景[J].北方园艺,2007,(8):77-78
25高述明,马凯,杜希华,等.文冠果(Xanthoceras sorbifoliaBunge)研究进展[J].植物学通报,2002,19(3):296-301
26滕虎,牟英,杨天奎,等.生物柴油研究进展[J].生物工程学报,2010,(7):50-60
27中国经济时报电子刊[EB/OL]. http://lib.cet.com.cn/paper/szb_con/152767.html,2013
28杨颖.生物柴油产业国内外现状及我国发展对策[J].粮油加工.2007,(10):75-78
29汤颖,陈刚,穆淑珍.国内外生物柴油发展现状及中国的应对策略[J].世界农业,2010,(8):10-12
30李超民.美国生物柴油产业政策变化的经济后果[J].农业展望,2008,(11):40-43
31Subramanian KA, Singal SK, Saxena M, et al. Utilizationof liquid biofuels inautomotive diesel engines: an Indianperspective. Biomass Bioenerg,2005,(29):65-72
32Azam M M,Waris A,Nahar N M. Prospects and potential of fattyacid methyl esters ofsome non-traditional seed oils for use asbiodiesel in india[J]. Biomass andBioenergy,2005,(29):293-302
33Zhong C,Cao Y-X,Li B-Z,et al. Biofuels in China: Past,presentand,future[J]. BiofuelsBioproducts and Biorefining,2010,4(3):326-342
34Shao H,Chu L. Resource evaluation of typical energy plants and possible functionalzone planning in China[J]. Biomass and Bioenergy,2008,32:283-288
35Kalam MA, Masjuki HH. Recent development on biodieselin Malaysia. J Sci Ind Res,2005,64(11):920-927
36徐薇.我国生物柴油产业发展研究[D].硕士论文,北京林业大学,2008
37张良波,李昌珠,欧日明等.生物柴油产业现状与展望[J],湖南农林科技,2008,(2):70-73
38Lifka,J,Ondruschka,B.Influence of mass transfer on the Production of Biodiesel[J].Chemie ingenieur Technik,2004,(79):168
39Ma F,Hanna MA. Biodiesel production: a review[J]. Bioresource Technol,1999,(70):1-15
40Zhang Y,Duke M A,Mclean D D,et al.Biodiesel Production from waste cookingoil:1.Process design and technological assessment[J].Bioresource Tchnology,2003,(9):1-6
41S.Siler-Marinkovic,A.Tomasevic.Transesterification of sunflower oil in situ[J].Fuel,1998,(79):1389-1391
42符太军,纪威,姚亚光等.地沟油制取生物柴油的试验研究[J].能源技术,2005,26(3):106-108
43谢国剑.潲水油制取生物柴油燃料的研究[J].化工科技,2005,13(4):20-22,29
44李胜清,刘俊超,刘汉兰等. B酸离子液体催化剂在生物柴油制备中的应用[J].湖北农业科学,2009,48(2):438-441
45谷学军,赵飞,王宝鑫等.离子液体SMIA催化大豆油制备生物柴油组分的研究[J].辽宁大学学报,2010,37(2):136-140
46邬国英,林西平,巫淼鑫等.棉籽油甲酯化联产生物柴油和甘油[J].中国油脂,2003,28(4):70-73
47Tomasevic A V,Siler Marinkovi S S C.Methanolysis of used frying oil[J].FuelProcessing Technology,2003,81(1):1-6
48Sanjib KumarKarmeA,nju Chadha.Preparation of Biodiesel from crude oil of Pinnata[J].BioresourceTeehnology,2005,(96):1425-1429
49张无敌,尹芳,李建昌等.大豆油酯交换制备生物柴油的实验研究[J].农机化研究,2009,(9):189-192,199
50Gemma V, MercedesM J A. Integrated Biodiesel Production: a comparison of differenthomogeneous catalysts systems[J].Bioresource Technology,2004,(92):297-305
51林璟,方利国.麻疯果油制备生物柴油及其经济效益[J].化工进展,2008,27(12):1977-1981
52Abraham Casas, María Jesús Ramos, ángel Pérez. New trends in biodieselproduction:Chemical interesterification of sunflower oil with methylacetate[J].Biomass and Bioenergy,2011,(35):1702-1709
53Abraham Casas, Mar í a Jes ú s Ramos, á ngel P é rez. Kinetics of chemicalinteresterification of sunflower oil with methyl acetate forbiodiesel and triacetinproduction[J].Chemical Engineering Journal,2011(171):1324–1332
54David M. Fernandes, Dalyelli S. Serqueira, Flaysner M. Portela, et al. Preparationand characterization of methylic and ethylic biodiesel fromcottonseed oil and effectoftert-butylhydroquinone on its oxidative stability [J].Fuel,2012,(97):658–661
55熊道陵,舒庆,李英,等.生物柴油催化合成研究进展[J].江西理工大学学报,2012,33(1):10-16
56chen G, Fang B.Preparation of solid acid catalyst from glucose-strarch mixture forbiodiesel production[J]．Bioreource Technology,2011,102,(3):2635-2640
57Lopez D E, Suwannakarn K, Bruce D A. Esterification andtransesterification ontungstated zirconia: Effect of calcinationsftemperature[J]. Journal of Catalysis,2007,247(1):43-50
58Corro G,Tellez N, Ayala E, et al. Two-step biodiesel production from Jatrophacurcascrude oil using SiO2·HF solid catalyst for FFA esterification step[J],Fule,2010,89(10):2815-2821
59石彩静,李志成,余济伟,等.二氧化硅－硫酸氢钾固体酸催化制备生物柴油[J].中国油脂,2012,37(7):55-58
60翟绍伟,牛梅菊*,龚树文,等.负载固体酸催化豆油制备生物柴油的研究[J].天然气化工,2012,37(1):21-25
61李娜,李会鹏.负载型固体酸催化合成生物柴油[J].化学工业与工程,2012,29(2):74-78
62徐玲,陈建军,张立明,等.负载型磷钨酸催化剂的制备、表征及酯交换制备生物柴油[J].吉林大学学报(理学版),2012,50(2):346-350
63Serio M D, Cozzolino M, Tesser R, et al. Vanadyl phosphatecatalysts in biodieselproduction [J]. Applied Catalysis A:General,2007,(320):1-7
64Chai F, Cao F H, Zhai F Y, et al. Transesterification of veg-etable oil to biodieselusing a heteropolyacid solid catalyst[J]. Adv Synth Catal,2007,349(7):1057-1065
65Morin P, Hamad B, Sapaly G, et al． Transesterification ofrape-seed oil with ethanolCatalysis with homogeneousKeggin heteropolyacids t[J]. Applied Catalysis A:General,2007,(330):69-76
66夏亚穆,焦斌.非均相催化法生产生物柴油的研究进展[J].化学与生物工程,2012,29(3):6-8
67Deng X, Fang Z,Liu Y H, et al. Production of biodiesel from Jat-ropha oil catalyzedbynanosized solid basic catalyst[J].Energy,2011,36(2)777-784
68Boro J, Thakur A J, Deka D. Solid oxide derived from waste shells of TurLonillustriutulu as a renewable catalyst for biodie-sel production[J]. Fuel ProcessingTechnology,2011,92(10):2061-2067
69Kouzu M, Kasuno T, Tajika M, et al. Calcium oxide as a solidbase catalyst fortransesterification of soybean oil and its application to biodiesel production [J].Fue1,2008,87(12):2798-2806
70Bancquart S,Vanhove C, Pouilloux Y, et al. Glycerol transes-terification with methylstearate over solid basic catalysts:I.Relationship between activity and basicity[J].Applied catalysis A:General,2001,218(1-2):1-11
71刘守庆,李雪梅,赵雷修,等.固体碱CaO催化橡胶籽油制备生物柴油的研究[J].中国油脂,2012,37(7):59-6272周长行,张晓丽,高文艺,等.鸡蛋壳催化大豆油酷制备生物柴油[J].辽宁石油化工大学学报,2012,32(1):25-28
73曲旭坡.镁铝氧化物负载型催化剂催化制备生物柴油的研究[D].硕士论文,长春工业大学,2012
74赵策,曾虹燕,黄炎,等.镁铁水滑石的制备及其对小球藻油脂合成生物柴油的催化性能[J].燃料化学学报,2012,40(3):337-344
75杨玲梅,吕鹏梅,袁振宏,等. KOH负载的不同催化剂催化合成生物柴油[J].化工进展,2012,31(增刊):91-94
76李敏,丛兴顺,孙兰强.负载型NaOH/蒙脱石固体碱催化剂的制备及在生物柴油中的应用[J].工业催化,2011,19(12):97-100
77Kazuhiro Ban, Masaru Kaieda, Takeshi Matsumoto, et al．Whole Cell Biocatalyst forBiodiesel Fuel Production UtilizingRhizopus Oryzaecells Immobilize Within BiomassSupport Parti-cles[J]. Biochem Eng J,2001,8(1):39-43
78Li S F,Fan Y H, Hu R F,et al. Pseudomonas cepacia lipase im-mobilized onto theelectrospun PAN nanofibrous membranes for biodiesel production from soybean oi1[J].Journal of Molecular Catalysis B:Enzymatic,2011,72(1-2):40-45
79Noureddini H. Immobilized Pseudomonas Cepacia Lipase for Biodiesel Fuel Productionfrom Soybean Oil[J]. Bioresour Technol,2005,96(7):769-777
80Li Q, Yan Y. Production oI biodiesel catalyzed by immobilized Pseudomonascepacia-lipase from Sapium sebiferum oil in micro-aqueous phase [J]. Applied Energy,2010,87(10):3148-3154
81Yagiz F, Kazan D, Akin A N. Biodiesel Production fromWaste Oils Using LipaseImmobilized on Hydrotalcite and Zeo-lites [J]. Chem Eng J,2007,143(3):262-267
82Lee M, Lee J, Lee D, et al. Improvement of enzymatic biodiesel production by controlledsubstrate feeding using silica gel in solvent free system [J]. Enzyme and MicrobialTechnology,2011,49(4):402-406
83Li X, He X Y, Li Z I, et al. Enzymatic production of biodiesel from Pistacia chinensisbge seed oil using immobilized lipase [J]. Fue1,2012,92(1):89-93
84梁静娟,杨立鹏,韩钧,等.固定化脂肪酶在离子液体中催化合成生物柴油[J].可再生能源,2012,30(1):77-82
85徐桂转,岳建芝,张百良,等.脂肪酶连续催化桐油酯交换反应制取生物柴油[J].农业工程学报,2010,26(7):245-249
86李俊奎,王芳,谭天伟,等.固定化脂肪酶催化小桐子毛油合成生物柴油[J].北京化工大学学报(自然科学版),2010,37(2):102-105
87李青云,庾乐,覃益民,等.固定化酶催化山茶油制备生物柴油研究[J].可再生能源,2012,30(9):60-64
88申渝,张海东,郑旭煦,等.硅基MCF材料固载脂肪酶转化餐饮废油产生物柴油[J].化工学报,2012,63(6):1888-1892
89Hino M, Arata K. J. Chem. Soc. Chem. Commun.,1980,(18):851--852
90孟丽娜. SO42-/SnO2负载型固体酸的制备表征及催化性能研究[D].硕士论文,齐齐哈尔大学,2012
91刘艳林. SO42-/杭锦2#土的制备、表征及其催化性能研究[D].硕士论文,内蒙古师范大学,2008
92黄永茂,樊玉梅,程艳坤,等.固体酸催化麻疯树籽油制备生物柴油[J].粮油加工,2009,(3):50-53
93张六一,韩彩芸,杜东泉,等.硫酸化氧化锆固体超强酸[J].化学进展,2011,23(5):860-873
94孙晋峰.固体酸催化植物油酯交换制备生物柴油[D].硕士论文,上海师范大学,2009
95刘剑,孔琼宇.固体酸催化小桐子油制备生物柴油[J].长沙理工大学学报(自然科学版),2009,6(2):92-96
96卢怡,苏有勇． SO42-/Fe2O3固体酸的制备及其催化合成生物柴油的研究[J].化学与生物工程,2011,28(1):23-25
97呼晓姝,郝俊,王建中.超声波辅助提取元宝枫油的研究[J].中国粮油学报,2007,22(5):98-100
98高振鹏,岳田利,袁亚宏,等.超声波强化有机溶剂提取石榴籽油的工艺优化[J].农业机械学报,2008,39(5):77-80
99高霞,仇农学,庞福科,等.超声波辅助提取苹果籽油工艺研究[J].中国油料作物学报,2007,29(1):78-82100邓红,孙俊,何玲,等.不同方法提取的文官果籽油的GC-MS分析[J].食品科学,2007,28(8):354-357101GB5526-85,植物油比重的测定[S]102GB/T5530-2005,动植物油脂酸值和酸度测定[S]103GB/T5534-2008,动植物油脂皂化值的测定[S]104黄彩霞,刘荣厚.菜籽油碱催化法制备生物柴油的工艺参数[J].农业工程学报,2009,25(12):234－239105郝一男,文冠果种仁油的提取及其生物柴油合成的研究[D].博士论文,内蒙古农业大学学报,2011
106洪瑶,陈文伟,朱悦,等.芝麻粕蛋白的提取研究[J].中国食品添加剂,2010,(4):169-172
107陈伟文,乌桕籽油制备生物柴油的研究[D].博士论文,南昌大学,2006
108陈曾,吴玉龙,陶玲,等.响应曲面法优化文冠果油提取工艺的研究[J].农产品加工学刊,2010,(7):8-12
109唐志红,吕家森.贾晓晨,等.羊栖菜多糖微波提取工艺的研究[J].时珍国医国药,2011,22(10):2440-2441
110马养民,张航涛,郭俊荣,等.文冠果种子油制备生物柴油工艺的研究[J].技术油脂工程,2010,(1):30-32
111Daniele F, Valerio B, Marcello N, et al. Properties of apotential biofuel obtainedfrom soybean oil by transmethylation with dimethyl carbonate[J]. Fuel,2007,(86):690-697
112Kevin J.Harrington.Chemieal and Physical Properties of Vegetbale oi1Esters and theireffect on Diesel Fuel Performance[J].Biomass,1986,(9):1-17
113范航,张大年,赵一先,等.生物柴油的研究与应用[J].上海环境科学,2000,1911):516-518
114乌云,照日格图,嘎日迪,等.活化条件对活性白土脱色率的影响研究[J].内蒙古师范大学学报,2004,33(4):411-413
115照日格图,乌云,宝迪巴特尔,等.杭锦2#土脱色剂的制备及其对植物油脱色性能的研究[J].中国油脂,2004,29(8):19-21
116白丽梅,郝向英,郭海福,等.固体酸SO42-/SnO2—杭锦2#土催化合成乙酸松油酯[J].内蒙古师范大学学报(自然科学汉文版),2011,40(3):278-282
117魏景芳,郝向英,郭海福,等. SO42-/杭锦2#土固体超强酸催化合成乙酸正丁酯[J].肇庆学院学报,2010,31(2):40-43
118照日格图,乌云,宝迪巴特尔,等.杭锦2#土脱色剂的制备及其对植物油脱色性能的研究[J].中国油脂,2004,29(8):19-21
119赵斌,谷克仁.活性白土的制备及性能研究[J].中国油脂,2002,27(2):56-58
120魏景芳,郝向英,闫鹏,等.不同酸处理对SO42-/杭锦2#土催化性能的影响[J].内蒙古师范大学学报(自然科学汉文版),2010,39(4):401-404
121盛梅,李为民,邬国英.生物柴油研究进展[J].中国油脂,2003,28(4):66-70
122Ayhan Demirbas. Biodiesel fuels from vegetable oils via catalytic and non-catalyticsupercritical alcohol transesterifi-cations and other methods A Survey[J]. EnergyConversion and Management,2003,44(13):2093-2109
123Kusdiana D, Saka S. Kinetics of transesterification in rapeseed oil to biodiesel fuelas treated in supercritical methanol[J]. Fuel,2001,(80):693-698
124Diasakou M, Louloudi A, Papayannakos N. Kinetics of the non-catalytictransesterification of soybean oil[J]. Fuel,1998,(77):1297-1302
125马志豪,张小玉,马凡华,等.生物柴油混合比对柴油机排放颗粒特性的影响[J].农业工程学报,2012,28(18):64-68
126王利兵.三种山杏种子生物柴油特征评价[J].农业工程学报,2011,27(增刊1):138-142
127张豪,乙引,洪鲲,等.响应面法优化酶促脂肪酸甲酯化工艺条件[J].农业工程学报,2011,27(增刊2):125-130
128易军鹏,朱文学,马海乐,等.牡丹籽油超声波辅助提取工艺的响应面法优化[J].农业机械学报,2009,40(6):103-110
129杨颖.生物柴油制备方法研究进展[J].粮油食品科技,2007,15(5):35-37
130鲁厚芳,史国强,刘颖颖,等.生物柴油生产及性质研究进展[J].化工进展,2011,30(1):126-135
131于海燕,周绍箕.文冠果油制备生物柴油的研究[J].中国油脂,2009,34(3):43-45
132中国石油化工股份有限公司科技开发部编.石油和石油产品试验方法国家标准汇编[M].北京:中国标准出版社,2005
133贾金波.固体酸催化合成生物柴油的研究[D].硕士论文,河北师范大学,2010
134柴油的质量要求及性能指标[J/OL]. http://wenku.baidu.com/view/2f66eb1ffc4ffe473368ab08.html,2013
135柳杨,衣怀峰,陈宇,等.酯交换生物柴油的柱层析分离纯化与分析[J].光谱学与光谱分析,2012,32(2):505-509
© 2004-2018 中国地质图书馆版权所有 京ICP备05064691号 京公网安备11010802017129号 地址：北京市海淀区学院路29号 邮编：100083 电话：办公室：(+86 10)66554848；文献借阅、咨询服务、科技查新：66554700 |