新型耐高温换热器涂料的制备及其性能的研究
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摘要
本文详细叙述了有机硅-环氧树脂的合成工艺，通过耐温、及其物理机械性能试验确定环氧-有机硅树脂的比例，通过红外光谱和热失重试验分别确定缩聚反应的反应情况和环氧-有机硅的耐温性，同时测定环氧-有机硅树脂的基本物理机械性能。
以环氧-有机硅-酚醛三元树脂为基料研制的QHF型换热器涂料，与环氧聚酯、无机磷酸盐富锌涂料进行耐温性、热冲击性能及防腐蚀性能的比较，并讨论了耐热颜料及涂装工艺对涂层性能的影响。将QHF型涂料与换热器专用涂料进行耐腐蚀、耐热、耐250℃高温蒸汽及机械力学性能比较。
分别将环氧-有机硅-酚醛涂层与换热器专用涂料涂层浸泡在80℃、3％NaCl溶液中一周，根据在不同浸泡时间下测得的两种涂层的电化学阻抗谱，讨论了阻抗谱图特征变化与涂层结构及性能变化的关系，并根据阻抗谱图的解析结果评价了两种涂层的防护性能。
根据浸泡试验结果及阻抗谱图解析结果，QHF型涂料能够对换热器进行保护，以延长换热器的使用年限。
The aritical narrate the synthesis technics of epoxy-polyslioxane,the proporation of epoxy-polyslioxane the ability of endurable high temperature studied by experimentation of endurable high temperature、 physics mechanistic property、 IS and DSC.
The epoxy-polyslioxane-phenolic three-component resin as the main base of coating for heat exchanger, compared with epoxy- polyester、 powdered zinc inorganic phosphate coating in aspect of endurable high temperature、 heat strike、endurable corrosion. The effect of endurable pigments and painting technology to coating property has been discussed.
Coatings of epoxy-polyslioxane-phenolic and the heat exchanger paint immersed in 80℃ 3%NaCl solutions for one week,Based on the EIS(Electrochemical Impedance Spectroscopy)displays of two coatings at various immersion time , the relation between impedance characteristics and structure or properties of coatings was discussed respectively. The protective properties of two heat exchanger coatings were evaluated in terms of calculated resulted of impedance data in the case.
以环氧-有机硅-酚醛三元树脂为基料研制的QHF型换热器涂料，与环氧聚酯、无机磷酸盐富锌涂料进行耐温性、热冲击性能及防腐蚀性能的比较，并讨论了耐热颜料及涂装工艺对涂层性能的影响。将QHF型涂料与换热器专用涂料进行耐腐蚀、耐热、耐250℃高温蒸汽及机械力学性能比较。
分别将环氧-有机硅-酚醛涂层与换热器专用涂料涂层浸泡在80℃、3％NaCl溶液中一周，根据在不同浸泡时间下测得的两种涂层的电化学阻抗谱，讨论了阻抗谱图特征变化与涂层结构及性能变化的关系，并根据阻抗谱图的解析结果评价了两种涂层的防护性能。
根据浸泡试验结果及阻抗谱图解析结果，QHF型涂料能够对换热器进行保护，以延长换热器的使用年限。
The aritical narrate the synthesis technics of epoxy-polyslioxane,the proporation of epoxy-polyslioxane the ability of endurable high temperature studied by experimentation of endurable high temperature、 physics mechanistic property、 IS and DSC.
The epoxy-polyslioxane-phenolic three-component resin as the main base of coating for heat exchanger, compared with epoxy- polyester、 powdered zinc inorganic phosphate coating in aspect of endurable high temperature、 heat strike、endurable corrosion. The effect of endurable pigments and painting technology to coating property has been discussed.
Coatings of epoxy-polyslioxane-phenolic and the heat exchanger paint immersed in 80℃ 3%NaCl solutions for one week,Based on the EIS(Electrochemical Impedance Spectroscopy)displays of two coatings at various immersion time , the relation between impedance characteristics and structure or properties of coatings was discussed respectively. The protective properties of two heat exchanger coatings were evaluated in terms of calculated resulted of impedance data in the case.
引文
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[02]Q. Zhao, Y. Liu, H, Müller-Steinhagen, G.Liu, Surface and Coatings Technology, 155(2002)279～284.
[03]J. P. Celis, J. R. Rocs, C. Buelem, J. Fransaer, Trans. Inst. Metal Finishing 69(4)(1991) 133-139.
[04]K. Hells, T. walsh, Metal Finishing 75(2)(1997)53, Mar.
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[08]西德1071105
[09]英国107883
[10]西德1264462
[11]JP 05305691,6187878,02227246
[12]JP 5901948
[13]孔荣贵，戴英华，刘胜峰等，硅聚合物耐热耐水涂料，涂料工业1995 Vol．10No．1
[14]US 3853824,4835051,5189121
[15]JP 04-202364,01-096261,337365
[16]邬润德，童筱莉，聚苯硫醚涂料改性及耐蚀性应用研究，浙江工业大学学报
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[18]张爱波，雷渭媛，方海洪，聚苯硫醚复合涂层性能的研究，化工新型材料，Vol27．No9．29-34．
[19]李继红，侯灿淑，余自力，谢美菊，严永刚，陈永荣，陈红，聚苯硫醚涂层／金属基体的界面研究，高分子材料科学与工程，1998,Vol14．No．3
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[25]S.Ananda Kumar,Ph.D.Thesis,Anna University,Chennai,India,2001
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[29]A.Ashok Kumar, M.Alagar, R.M.V.G.K.Rao,Polymer43(2002)693-702.
[30]us 6441106,6355740,4474930,5177157,4371665,4960817,4624998
[31]陈春伟等 合成树脂与塑料，1991，(4)：8
[32]陈丽等 应用化学，1995，12(5)：67
[33]程斌等 热固性树脂，1990，(3)：7
[34]方征平等 热固性树脂，1989(4)：1
[35]陈雷等 功能高分子学报，1991，4(2)：124
[36]鲁照玲等 涂料工业，1999，(4)：1
[37]邓明山等 安徽化工，2000，103(2)：27
[38]胡丽天等 中国胶粘剂，1998，7(2)：7
[39]吕铃 化工新型材料，2000，28(2)：31
[40]陈慧宗CHINA ADHESIVES 1995，4(2)：14
[41]Rammelt U,. Reinhard G.[J].Prog.Org.Coat,. 1992,21:205.
[42]Le Pen C. et al, [J].Prog.Org.Coat,. 2000,39:167.
[43]Gonzalez S., et al.[J].Prog.Org.Coat,. 2001,41: 167.
[44]Oliveira C. G. ,Ferreira M.G.S.[J].Corr Sci,. 2003,45:123.
[45]Oliveira C. G. ,Ferreira M.G.S.[J].Corr.Set,. 2003,45:139.
[46]De Rosa L, et al. [J].Prog.Org.Coat,. 2002,44:153.
[47]Mcintre J.M.,Pham H.Q.[J].Prog.Org. Coat., 1996,27:201.
[48]Yin K.M.,Wu H.Z[J].Surface and Coatins Technology, 1998,106:167.
[49]Deflorian F.,et al. [J].Electrochim.Acta, 1993,38(12):1609.
[50]Mansfeld F.[J].Electrchim.Acta, 1993,38(14): 1891.
[51]Mansfeld F. [J].J.Appl.Electrochem., 1995,25:187.
[52]Walter G.W.[J].Corr.Sci., 1986,26(9):681.
[53]张鉴清，曹楚南．[J]．腐蚀与防护，1998，19(3)：99．
[54]Kacarevic2Popovic J.B.B.,et al. [J].Prog.Org Coat,. 2000,39:127.
[55]胡艳玲，等．[J]．中国腐蚀与防护学报，2002，22(1)：8．
[56]Otero E, et al.[J].Prog.Org.Coat.,2002,45:441.
[57]Xiao H,et al.[J].Corrosion, 1997,53(5):412.
[58]Murray J. N. [J].Prog.Org.Coat, 1997,30:225.
[59]Dehri I. Erbil M.[J].Corr.Sci.,2000,42:969.
[60]Stmnz W. [J].Prog. Org. Coat ,2000,39:49.
[61]Scantlebury J.D.[J].Galic K,. Prog.Org.Coat.,1997,31:201.
[62]温国谋，等．[J]．中国腐蚀与防护学报，1992，12(1)：63．
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[64]Catala R, etal. [J]. Surface Coatings International, 1998,1:37.
[65]Guillaumin V,. Landolt D.[J]. Corr. Sci. ,2002,44:179.
[66]Zou F.,Thierry D.[J]. Electrochim. Acta, 1997, 42 (20～22):3293.
[67]Dehri I, et al,.[J]. Corr. Sci. 1999,41:141.
[68]Taylor S. R.[J]. Prog. Org. Coat,.2001,43:141.
[69]Leng A, et al.[J]. Corr. Sci, 1999,41:547.
[70]Furbeth W. [J]. Stramann M. ,Corr. Sci, 2001 ,43:207.
[71]Schiller C. A., Strunz W. [J]. Electrochim. Acta, 2001,46:3619.
[72]GellingV.J, et al. [J].Prog.org.coat, 2001,43:149.
[73]GreisigerH.[J].Schauer T., Prog.org.coat,. 2000, 39:31.
[74]BierwagenG.P, et al.[J].Prog.org.coat,. 1997,32:25.
[75]khobaibM, et al.[J].Prog.org.coat,. 2001.41:266
[76]SchaureT, et al.[J].Electrochim. Acta1998, 43(16～17):2423.
[77]OshomeJ.H, et al.[J].Prog.Org.Coat,. 2001, 41:217.
[78]Reynoldsl.B, et al.[J].Prog.Org.Coat,. 1997, 32:31.
[79]DeRosaR.L, et al.[J].Corr.Sci,. 2002, 44:1607.
[80]Horvath A.Schiller R.[J].Corr.Sci,. 2003, 45:597.
[81]张鉴清等．[J]．中国腐蚀与防护学报，2002，22(4)：241．
[82]朱自莹等．[M]．拉曼光谱在化学中的应用，东北大学出版社，1998．
[83]Bernard M.C, et al.[J].Prog.Org.Coat, 2002,45:399.
[84]Corfias C, et al.[J].Corr.Sci, 2000, 42:1337.
[02]Q. Zhao, Y. Liu, H, Müller-Steinhagen, G.Liu, Surface and Coatings Technology, 155(2002)279～284.
[03]J. P. Celis, J. R. Rocs, C. Buelem, J. Fransaer, Trans. Inst. Metal Finishing 69(4)(1991) 133-139.
[04]K. Hells, T. walsh, Metal Finishing 75(2)(1997)53, Mar.
[05]C.Kerr,J.Archer, Trans.Inst.Metal Finishing 78(5)(2000) 171, Sep.
[06]侯晓晖，洪祥乐，化学复合镀Ni-P-PTFE的研究，佛山科学技术学院学报(自然科学版)2000，18Vol．No．2
[07]吴吴，化学镀Ni-P-PTFE层的硫化气氛耐蚀性的研究，Electroplating&Finishing，1999，Vol．18，No．3
[08]西德1071105
[09]英国107883
[10]西德1264462
[11]JP 05305691,6187878,02227246
[12]JP 5901948
[13]孔荣贵，戴英华，刘胜峰等，硅聚合物耐热耐水涂料，涂料工业1995 Vol．10No．1
[14]US 3853824,4835051,5189121
[15]JP 04-202364,01-096261,337365
[16]邬润德，童筱莉，聚苯硫醚涂料改性及耐蚀性应用研究，浙江工业大学学报
[17]童筱莉，邬润德，周宇，聚苯硫醚涂料和涂装工艺的改进，腐蚀与防护 1997，Vol 18．N06．265-267．
[18]张爱波，雷渭媛，方海洪，聚苯硫醚复合涂层性能的研究，化工新型材料，Vol27．No9．29-34．
[19]李继红，侯灿淑，余自力，谢美菊，严永刚，陈永荣，陈红，聚苯硫醚涂层／金属基体的界面研究，高分子材料科学与工程，1998,Vol14．No．3
[20]Y.Huang,A.J.Kinloch,Polymer,33 (1992)5338-5340.
[21]Mitsukaxu Ochi, Keixo Tskemiya, Osamu Kiyohara, Takayuki Nakanishi, Polymer, 39(1998): 725～731.
[22]M. Ochi,K, Takemiya,O.Kiyhara,T.Nakanishi,Polymer,41 (2000) 195-201
[23]Mitsukazu Ochi,Shinzi Shimaoka ,Polymer,40(1999) 1305-1312.
[24]S.Ananda Kumar,T.S.N.Sankara Narayanan, Progress in organic Coating 1199(2002)1-8.
[25]S.Ananda Kumar,Ph.D.Thesis,Anna University,Chennai,India,2001
[26]T.V.Thanikai,Velan,Ph.D.Thesis,Anna University,Chennai,India, 1997.
[27]S.AnandaKumar, M.Alagar,V.Mohan, Surf.Coat.Int.B84(1-90)(2001)43-47.
[28]S.Ananda Kumar,M.Alagar ,K.P.O.Mahesh, T.S.N.Sankara Narayanana, V.Mohan, Eur.Coat.J.4(2000)64-77.
[29]A.Ashok Kumar, M.Alagar, R.M.V.G.K.Rao,Polymer43(2002)693-702.
[30]us 6441106,6355740,4474930,5177157,4371665,4960817,4624998
[31]陈春伟等 合成树脂与塑料，1991，(4)：8
[32]陈丽等 应用化学，1995，12(5)：67
[33]程斌等 热固性树脂，1990，(3)：7
[34]方征平等 热固性树脂，1989(4)：1
[35]陈雷等 功能高分子学报，1991，4(2)：124
[36]鲁照玲等 涂料工业，1999，(4)：1
[37]邓明山等 安徽化工，2000，103(2)：27
[38]胡丽天等 中国胶粘剂，1998，7(2)：7
[39]吕铃 化工新型材料，2000，28(2)：31
[40]陈慧宗CHINA ADHESIVES 1995，4(2)：14
[41]Rammelt U,. Reinhard G.[J].Prog.Org.Coat,. 1992,21:205.
[42]Le Pen C. et al, [J].Prog.Org.Coat,. 2000,39:167.
[43]Gonzalez S., et al.[J].Prog.Org.Coat,. 2001,41: 167.
[44]Oliveira C. G. ,Ferreira M.G.S.[J].Corr Sci,. 2003,45:123.
[45]Oliveira C. G. ,Ferreira M.G.S.[J].Corr.Set,. 2003,45:139.
[46]De Rosa L, et al. [J].Prog.Org.Coat,. 2002,44:153.
[47]Mcintre J.M.,Pham H.Q.[J].Prog.Org. Coat., 1996,27:201.
[48]Yin K.M.,Wu H.Z[J].Surface and Coatins Technology, 1998,106:167.
[49]Deflorian F.,et al. [J].Electrochim.Acta, 1993,38(12):1609.
[50]Mansfeld F.[J].Electrchim.Acta, 1993,38(14): 1891.
[51]Mansfeld F. [J].J.Appl.Electrochem., 1995,25:187.
[52]Walter G.W.[J].Corr.Sci., 1986,26(9):681.
[53]张鉴清，曹楚南．[J]．腐蚀与防护，1998，19(3)：99．
[54]Kacarevic2Popovic J.B.B.,et al. [J].Prog.Org Coat,. 2000,39:127.
[55]胡艳玲，等．[J]．中国腐蚀与防护学报，2002，22(1)：8．
[56]Otero E, et al.[J].Prog.Org.Coat.,2002,45:441.
[57]Xiao H,et al.[J].Corrosion, 1997,53(5):412.
[58]Murray J. N. [J].Prog.Org.Coat, 1997,30:225.
[59]Dehri I. Erbil M.[J].Corr.Sci.,2000,42:969.
[60]Stmnz W. [J].Prog. Org. Coat ,2000,39:49.
[61]Scantlebury J.D.[J].Galic K,. Prog.Org.Coat.,1997,31:201.
[62]温国谋，等．[J]．中国腐蚀与防护学报，1992，12(1)：63．
[63]Xie D.M,et al. [J].Acta Metallurgica Sinica, 2002,15(3): 299.
[64]Catala R, etal. [J]. Surface Coatings International, 1998,1:37.
[65]Guillaumin V,. Landolt D.[J]. Corr. Sci. ,2002,44:179.
[66]Zou F.,Thierry D.[J]. Electrochim. Acta, 1997, 42 (20～22):3293.
[67]Dehri I, et al,.[J]. Corr. Sci. 1999,41:141.
[68]Taylor S. R.[J]. Prog. Org. Coat,.2001,43:141.
[69]Leng A, et al.[J]. Corr. Sci, 1999,41:547.
[70]Furbeth W. [J]. Stramann M. ,Corr. Sci, 2001 ,43:207.
[71]Schiller C. A., Strunz W. [J]. Electrochim. Acta, 2001,46:3619.
[72]GellingV.J, et al. [J].Prog.org.coat, 2001,43:149.
[73]GreisigerH.[J].Schauer T., Prog.org.coat,. 2000, 39:31.
[74]BierwagenG.P, et al.[J].Prog.org.coat,. 1997,32:25.
[75]khobaibM, et al.[J].Prog.org.coat,. 2001.41:266
[76]SchaureT, et al.[J].Electrochim. Acta1998, 43(16～17):2423.
[77]OshomeJ.H, et al.[J].Prog.Org.Coat,. 2001, 41:217.
[78]Reynoldsl.B, et al.[J].Prog.Org.Coat,. 1997, 32:31.
[79]DeRosaR.L, et al.[J].Corr.Sci,. 2002, 44:1607.
[80]Horvath A.Schiller R.[J].Corr.Sci,. 2003, 45:597.
[81]张鉴清等．[J]．中国腐蚀与防护学报，2002，22(4)：241．
[82]朱自莹等．[M]．拉曼光谱在化学中的应用，东北大学出版社，1998．
[83]Bernard M.C, et al.[J].Prog.Org.Coat, 2002,45:399.
[84]Corfias C, et al.[J].Corr.Sci, 2000, 42:1337.
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