化学共混型淀粉基新材料的研制与应用
|
摘要
为了充分利用我国丰富的淀粉资源,满足企业对新型造纸助剂的迫切需求,研究了芭蕉芋变性淀粉与聚二甲基二烯丙基氯化铵(PDADMAC)的复合行为及其对纸浆料的助留助滤作用。通过对淀粉催化氧化反应的考察,解明了反应条件与氧化淀粉(OS)的羧基和羰基含量的关系,采用先进的凝胶渗透色谱-激光光散射联用技术(GPC-MALLS)分析了催化氧化芭蕉芋淀粉(OS)的组分和分子结构,考察了催化氧化对芭蕉芋淀粉的分子量分布的影响;研究了OS/PDADMAC复合物的形成与聚电解质粘性行为,分析了OS/PDADMAC的水溶液性质,探讨了OS/PDADMAC的助留助滤性能;考察了制备条件对芭蕉芋交联淀粉(JS)和芭蕉芋交联氧化淀粉(JOS)性质的影响,采用GPC-MALLS测定了JS、JOS及JOS/PDADMAC的均方根旋转半径、分子量及分子量分布的变化,解析了复合物的电荷密度、分子量与其助留助滤性能的关系,为开发新型造纸助剂开辟了一条新途径。
To utilize plentiful starch resources in our country and meet the urgent requirement on new paper additive to enterprise, such reaserch has been done on the combination of modified canna starch and PDADMAC and the performance of complexes on retention and drainage of the pulps. The relationship between reaction conditions and the carboxyl and carbonyl content of oxidized starches(OS) was investigated by the study of catalytic oxidation. The advanced method GPC-MALLS was used to analyze the component and structure of catalytic oxidized canna starch and to study the effect of catalytic oxidation on the molecular distribution of canna srarch. The formation and polyelectrolyte viscosity behavior of OS/PDADMAC were studied, and its aqueous solution properties and retention filter performace were also studied. The effect of preparation conditions on the performance of cross-linked canna starch(JS) and crosslinking-oxidized canna starch(JOS) were studied. The rms radius, molecular weight and the molecular weight distribution of JS, JOS and JOS/PDADMAC were studied by GPC-MALLS. Finally, the thesis determined the relationship between the charge density and molecular weight of complexes and the retention filter performace. It was established a new way to develop the new paper additive.
To utilize plentiful starch resources in our country and meet the urgent requirement on new paper additive to enterprise, such reaserch has been done on the combination of modified canna starch and PDADMAC and the performance of complexes on retention and drainage of the pulps. The relationship between reaction conditions and the carboxyl and carbonyl content of oxidized starches(OS) was investigated by the study of catalytic oxidation. The advanced method GPC-MALLS was used to analyze the component and structure of catalytic oxidized canna starch and to study the effect of catalytic oxidation on the molecular distribution of canna srarch. The formation and polyelectrolyte viscosity behavior of OS/PDADMAC were studied, and its aqueous solution properties and retention filter performace were also studied. The effect of preparation conditions on the performance of cross-linked canna starch(JS) and crosslinking-oxidized canna starch(JOS) were studied. The rms radius, molecular weight and the molecular weight distribution of JS, JOS and JOS/PDADMAC were studied by GPC-MALLS. Finally, the thesis determined the relationship between the charge density and molecular weight of complexes and the retention filter performace. It was established a new way to develop the new paper additive.
引文
[1]唐泽燕,陈港,唐爱民等.造纸湿部化学微粒子助留助滤技术的研究进展[J].2004.23(4):23-27.
[2]Cosey J P.制浆造纸化学工艺学(中文版第三卷)[M].北京:轻工业出版社,1998.
[3]Scott W E.Fines management and control in wet end chemistry[J].Tappi Journal,1986,69(11):31-34.
[4]Scott W E,Koethe J.Polyeiectrolyte interactions with paper making fibers[J].Tappi Journal,1993,76(12):123-133.
[5]陈夫山,何秋实,隆言泉.两性聚丙烯酰胺的助滤作用[J].纸和造纸,1998(4):43-45.
[6]Scott W E.Principles of Wet End Chemistry[J].TAPPIPRESS,Atlanta,GA.1996.
[7]山田博.造纸过程中的界面动电现象[M].北京:轻工业出版社,1984.
[8]张开.高分子界面科学[M],北京:中国石化出版社,1997.
[9]朱勇强.造纸助剂与湿部化学讲座(二)造纸湿部化学的基本原理[J].上海造纸,2003,34(2):31-34.
[10]凌永龙.造纸湿部化学的进展[J].中国造纸,1996,第4期:52-58.
[11]朱勇强.造纸助剂与湿部化学讲座造纸湿部化学概述[J].上海造纸,2003,34(1):41-44.
[12]Britt.Mechanism of retention during paper formation[J].Tappi Journal,1973(10):46-49.
[13]Klungness J H.,Exner M P.Tappi Journal,1980(6):73.
[14]胡志斌.造纸助剂在非木材植物纤维浆抄纸时的应用[J].天津造纸,2000(Ⅰ):27-30.
[15]付献彩等编.物理化学[M].北京:高等教育出版社,1998:898.
[16]吴玉英.中国造纸助剂的应用现状及发展趋势[J].北京林业大学学报,1999,21(6):89.
[17]宋海农,杨崎峰,黄显南等.多元微粒子助留助滤技术[J].西南造纸,2001(3):8.
[18]谢来苏,胡惠仁,陈夫山等.造纸用两性助剂[J].天津造纸,1999(3):2.
[19]刘松坡,陈港,陶劲松等.两性聚丙烯酰胺在废纸浆中的应用试验[J].造纸科学与技术,2001,21(2):13.
[20]陈夫山,胡惠仁,谢来苏.两性聚丙烯酰胺对麦草浆助留作用的研究[J].纸和造纸,1998(3):52
[21]Oguni,et al.Additive for papermaking[J].United States Patent,1997,12:698,627.
[22]姚献平,郑丽萍.再生纸专用化学品的开发与应用[J].造纸化学品,2001(1):3.
[23]马云静.助留剂在再生新闻纸中的应用[J].西南造纸,2001(6):19.
[24]徐青林,胡惠仁,谢来苏等.造纸工业中几种常见的复式助留体系[J].黑龙江造纸,2000(4):8.
[25]Donald A,Pietsschker.The 100%closed water system what to expect.Tappi proceedings.Papermaking conferences.Tappi Press.Atalanta,1996:521.
[26]Alexander S D,et al.The physical and optical of paper made at high salt concentration[J].Tappi Journal,1997,60(12):121.
[27]刘全校.PEO辅助助剂对胶体悬浮液絮凝作用的影响[J].中华纸业,2002,23(12):29.
[28]刘全校.PEO/PFR双元絮凝系统对造纸白水的絮凝作用[J].纸和造纸,2002,(4):34.
[29]Tom L,et al.Network flocculation and fractionation of latex particales by means of a PEO-PFR complex[J].Journal of colbid and surface science,1984,97(1):62.
[30]刘全校,张风山,李建华等.新型PEO助留助滤体系在新闻纸和双胶纸中的应用研究[J].西南造纸,2002(2):12.
[31]T G M Van de Ven,et al.Association-induced polymer bridging new insights into the retention of fillers with PEO[J].Journal of pulp and paper science,1996,22(7):257.
[32]H.Xiao,et al.Retention mechanisms for two-component system based an phenolic resins and PEO or new PEO-copolymer retention aids[J].Journal of pulp and paper science,1996,22(12):475.
[33]Penniman J G.Unique Dryness Aid:cationic Guar Gum.Paper Trade J,1979,163(5):62.
[34]Dugal H S,Swason J W.Effect of polymer Mannan Content On The Effectiveness of Modified Guar Gum As a beater adhesive[J].Tappi Journal,1972,55(9):1362.
[35]王军利,陈夫山,刘忠.天然的造纸助剂--瓜尔胶[J].造纸化学品,2002(2):19.
[36]张力田.淀粉的化学结构[J].淀粉与淀粉糖,1975(2):25.
[37]Chuenkamol B,Puttanlek C,et al.Characterization of low-substituted hydroxypropylated canna starch[J].Food Hydrocolloids,2007,21(7):1123-1132.
[38]陈颖,吴宗华.几种福建产植物淀粉理化性质的比较[J].淀粉与淀粉糖,2005,(2):17-19.
[39]Thitipraphunkul K,Uttapap D,Piyachomkwan K,et al.A comparative study of edible canna(Canna edulis)starch from different cultivars.Part Ⅰ.Chemical composition and physicochemical properties[J].Carbohydrate Polymers,2003,53:317-324.
[40] Perez E, breene W,Bahnassey Y A. Variations in the gelatinization profiles of cassava and arrowroot native starches as measured with different thermal and mechanical methods[J]. Starch/Staerke, 1998,50, 70-72.
[41] Soni, P L , Sharma, H , Srivastava, H C , & Gharia, M M . Physicochemical properties of Canna edulis starch-comparison with maize starch[J]. Starch/Staerke, 1990,42,460 - 464.
[42] Santacruz S, Koch K, Svensson E, et al. Three underutilised sources of starch from the Adean region . in Ecuador. Part I. Physico-chemical characterisation.Carbohydrate Polymer, 2002, 49, 63 - 70.
[43] Thitipraphunkul K, Uttapap D, Piyachomkwan K, Takeda Y. A comparative study of edible canna (canna edulis) starch from different cultivars, Part 1:Chemical composition and physiochemical properties[J].carbohydrates Polymers, 2003, 53:317-324.
[44] Pham Van Hung, Naofumi Morita. Physicochemical properties and enzymatic digestibility of starch from edible canna (Canna edulis) grown in Vietnam Carbohydrate Polymers, 61 (2005) 314 - 321.
[45] Hung P V, Morita N. Physicochemical properties of hydroxypropylated and cross-linked starches from A-type and B-type wheat starch granules [J]. Carbohydrate Polymers, 2005,59: 239-246.
[46] Puncha-arnon S, Puttanlek C, Rungsardthong V, et al.Changes in physicochemical properties and morphology of canna starches during rhizomal development[J]. Carbohydrate Polymers , 2007,3 (20): 10-16.
[47] Thitipraphunkul K, Uttapap D, Piyachomkwan K, et al.A comparative study of edible canna (Canna edulis) starch from different cultivars. Part II. Molecular structure of amylase and amylopectin[J]. Carbohydrate Polymers, 2003, 54:489-498.
[48] Sirirat Saartrat, Chureerat Puttanlek, Vilai Rungsardthong, Dudsadee Uttapap, Paste and gel properties of low-substituted acetylated canna starches[J]. Carbohydrate Polymers , 2005, 61:211-221.
[49] Bongkot Chuenkamola, Chureerat Puttanlekb, Vilai Rungsardthongc, Dudsadee Uttapap.Characterization of low-substituted hydroxypropylated canna starch[J]. Food Hydrocolloids, 2007, 21: 1123 - 1132.
[50]Puncha-arnon S,Puttanlek C,Rungsardthong V,et al.Changes in physicochemical properties and morphology of canna starches during rhizomal development[J].Carbohydrate Polymers,2007,3(20):10-16.
[51]田培善,林源杰,李蕊.芭蕉芋淀粉衍生物的性能分析及应用[J].棉纺织技术,2004,32(9):521-525.
[52]吴春华,安鑫南,刘应隆.可生物降解的耐水性塑料薄膜的研制[J].南京林业大学学报,2002,26(2):49-51.
[53]郑丽萍,姚献平.纸用变性淀粉的新发展[J].国际造纸,18(4):5-8.
[54]胡本源,张学俊.变性淀粉的特性及应用[J].甘肃科技,2004,20(2):81-82.
[55]张继武,林兴盛.一种有发展前途的变性淀粉-双醛淀粉[J].化学与粘合,2002(2):67-69.
[56]郑昌戈,姚笑红,何艳辉等.双醛淀粉的合成及其氧化度的测定[J].湘潭大学自然科学学报,1996,18(1):70-73.
[57]张继武,朱友益,张强等.玉米淀粉制备双醛淀粉的试验[J].农业工程学报,2002,18(3):135-138.
[58]吴洁.氧化淀粉粘合剂的研制进展[J].化学与粘合,1998(3):167-170.
[59]林险峰.不同情况下氧化剂对玉米淀粉粘合剂质量的影响[J].松辽学刊(自然科学版),1999(2):37-40.
[60]童晓梅.浅谈洗涤助剂的性能及作用机理[J].日用化学品科学,2004,27(10):22-25.
[61]Qin Zhu,Rainer Sjoholm,Kari Nurmi,et al.Structural characterization of oxidized potato starch [J].Carbohy-drate Research,1998,(309):213-218.
[62]Kweon D K,Choi J K,Kim E K,et al.Adsorption of divalentmetal ions by succinylated and oxidized corn starches[J].Carbohydrate Polymers,2001(46):171-177.
[63]葛杰,张功超,白立丰等.变性淀粉在我国的应用及发展趋势[J].黑龙江八一农垦大学学报,2005,17(1):69-73.
[64]Tamaki S,Hisamatsu M,Teranishi K.Strutural changes of maize starch granules by ball-mill treatment[J].Starch,1998,50(8):342-348.
[65]张本山,高大维,林勤保等.高交联马铃薯淀粉的非晶化特征研究[J].中国粮油学报,1999,14(1):19-22.
[66]蔡宗源.交联淀粉醋酸酯的制备及特性[J].暨南大学学报(自然科学版),1994,15(1):100-103.
[67]叶斯奕.淀粉粒度影响可生物降解膜性能的探讨[J].降解塑料通讯,2002,3:17-19.
[68]刘亚伟.淀粉生产及其深加工技术[M].北京:中国轻工业出版社,2001.
[69]Shogren R L,Viswanathan A,Feiker F,et al.Distribution of Octenyl Succinate Groups in Octenyl Succinic Anhydride Modified Waxy MaizeStarch[J].Starch,2000,52:196-204.
[70]Jeon Y S,Viswanathan A,Gross R A.Studies of Starch Esterification:Reactions with Alkenyl Succinates in Qqueous Slurry Systems[J].Starch1999,51:90-93.
[71]易智彪,刘亚伟,袁超等.三重变性小麦淀粉中酯化反应对淀粉糊粘度特性影响的研究[J].粮食与饲料工业,2004,2:15-16.
[72]庄伟洲,梁亮,殷榕灿等.乙二醛交联氧化淀粉粘合剂的研制及其性能研究[J].2006,15(12):14-17.
[73]余少英.交联淀粉对Cr~(3+)离子的吸附研究[J].云南化工,2006,33(6):11-12.
[74]金婵,尤宏,杨玉霞等.以Ce~(4+)为引发剂接枝共聚物羧基淀粉的制备及其去除金属离子效果的研究[J].环境化学,1985,4(1):24-29.
[75]Fanta G F,Swanson C L,DoaneW M.Composites of Starch Poly(ethylene-co-acrylic acid)Complexing between Polymeric-Compoents[J].J Appl Polym Sci,1990,(40):811-821.
[76]刘明华,张新申,邓云.羧甲基淀粉吸附剂对水溶液中铬和铝离子的吸附研究[J].水处理技术,2000,26(4):222-227.
[77]陈静生,周家义.中国水环境重金属研究[M].北京:中国环境科学出版社,1998.
[78]周俊霞.流度及其应用[J].淀粉与淀粉糖,1998,(4):31-33.
[79]卢玉栋,吴宗华.聚胺分子量对其与淀粉的复合物在再生浆上作用效果的影响[J].造纸科学与技术,2003(1):34.
[80]卢玉栋,吴宗华.抄纸条件对淀粉/聚胺复合物作用效果的影响[J].造纸化学品,2002(2):12.
[81]陈少平,吴宗华,凌永泰等.氧化淀粉/PVAm复合物对漂白芦苇化学浆的助留助滤作用[J].中国造纸学报,2005,20(11):142-144.
[82]董朝霞,林梅钦等.光散射技术在研究高分子溶液何凝胶方面的应用[J].高分子通报,2001,(10):5.
[83]何曼君,陈维孝,董西侠.高分子物理[M].上海:复旦大学出版社,1990.
[84]张俐娜,薛其,莫志深等.高分子物理近代研究方法[M].武汉大学出版社,2003.
[85]虞志光.高聚物分子量及其分子量分布的测定[M].上海科学技术出版社,1984.
[86]Pecora R.Dynamic Light Scattering[M].New York Plenum Press,1976.
[87]赵择娜,陆大年,杨定超著.光散射技术[M].北京:纺织工业出版社,1986.
[88]陈重酉.高分子材料科学与工程[M].1990,3(5):55.
[89]张岩飞,崔跃飞.高分子材料科学与工程[M],1990,1:89.
[90]左榘.激光散射与原理在高分子科学中的应用[J].郑州,河南科学技术出版社,1994.
[91]拉贝克.高分子科学实验方法物理原理与应用(吴世康译)[M].北京:科学出版社,1987.
[92]CHIEN JEN-YUAN,YING CHI-TSUNG.Parameters of the Mark-Houwink equation for monodisperse polymer solutions[J].Sciertia Sinica,1962,11(1):66-75.
[93]Ong M H,Jumel J,Tokarczuk P F,Blanshard J M V,Harding S E.Simultaneous determinations of the molecular weight distributions of amyloses and the fine structures of amylopectins of native starches[J].Carbohydrate Research,1994,260:99-117.
[94]Mua J P,Jackson D S.Fine structure of corn amylase and amylopectin fractions with various molecular weights[J].Journal of Agricultural and Food Chemistry,1997,45:3840-3847.
[95]Willett J L,Millard M M,Jasberg B K.Extrusion of waxy maize starch:meltrheology and molecular weight degradation of amylopectin[J].Polymer,1997,38(24):5938-5989.
[96]Yoo S H,Jane J.Structure and physical characteristics of waxy and other wheat starches[J].Carbohydrate Polymers,2002,49:297-305.
[97]Mazeau K,Rinaud M.The prediction of the characteristics of some polysaccharides from molecular modeling Comparison with effective behavior[J].Food Hydrocolloids,2004,18:885-898.
[98]Willett J L,Millard M M,Jasberg B K.Extrusion of waxy maize starch:melt rheology and molecular weight degradation of amylopecti[J].Polymer,1997,38(24):5983-5989.
[99]Van Soest J J G,Benes K,Wit D,et al.The influence of starch molecular mass on the properties of extruded thermoplastic starch[J].Polymer,1996,37(16):3543-3552.
[100]Lee.P O,Nilsson G S,Nilsson K,Wahlund G.Development of asymmeteical flow field-flow fractionation-multi angle laser light scattering analysis for molecular mass characterization of cationic potato amylopecti[J].Journal of Chromatography,2003,A 1101:111-123.
[101]Roger P,Baud B,Colonna P.Characterization of starch polysaccharides by flow field-flow fractionation-multi-angle laser light scattering-differential refractometer index[J].Journal of Chromatography A,2001,917:179-185.
[102]王庭慰,何小兵等.生物合成聚γ-谷氨酸的相对分子质量表征[J].南京工业大学学报,2003,25(6):6-10.
[103]Phan Van Hung,Naofumi Morita.Physicochemical properties and enzymatic digestibility of starch from edible canna(Canna edulis)grown in Vietnam[J].Carbohydrate Polymers,2005,61:314-321.
[104]朱作华,吴天祥.芭蕉芋的性质及其淀粉的工业应用研究[J].生物加工过程,2005,3(4):66-70.
[105]汤庆莉,丘树毅.芭蕉芋淀粉改性研究[J].贵州工业大学学报,1999,28(2):79-85.
[106]Sirirat S,Chureerat P,Vilai R,Dudsadee U.Paste and gel Properties of low-substituted acetylated canna starches[J].Carbohydrate Polymers,2005,61:211-221.
[107]刑剑波等.氧化淀粉变性基团的分析方法[J].山西化工,2002,8:26-27.
[108]张力田.变性淀粉[M].广州:华南理工大学出版社,1999:1-10.
[109]余贻骥.废纸能促进造纸工业发展的重要纤维原料资源[J].国际造纸,2000,19(2):1.
[110]陈嘉翔.扩大二次纤维利用加速造纸工业发展[J].中华纸业,2000,21(9):14.
[111]庞学欣译.提高二次纤维的强度和脱水性能[J].天津造纸,1997,(4):37.
[112]lalegM.UnconventionalStrength Additives[J].NoudicPalpPaperResJ,1993,8(1):41.
[113]巴宾科夫.论水的混凝[M].北京:中国建筑工业出版社,1986.
[114]Billmeyer F W.Textbook of Polymer Science,New York,1984:218.
[115]郭拥军,李健,,冯玉平等.PVP/SDBS“复合物”的物理化学性能研究[J].日用化学工业,1999(5):1-4.
[116]Goddard E D,Ananthapadamanabham Eds K P.Interaction of surfactants with polymers and proteins[M].Boca Raton,CRC Press,1993.
[117]Budd PM..Comprehensive Polymer Science,Pergamon Press,Oxford,1989,Vol(1):226.
[118]沈一丁编.造纸化学品的制备和作用机理[M].北京:中国轻工业出版社,1999.
[119]胡莜敏著.化学助滤剂[M].北京:冶金工业出版社,1999.
[120]陈丽珠.DAMAC-AM共聚物的Hofmann反应及其在造纸中的应用.福建师范大学硕士学位论文,2007:61.
[121]杨秀芳.造纸工业中的氧化淀粉[J].造纸化学品与应用,2004(2):28-29.
[122]付庚昌,和世宝,禹负.造纸化学助剂--改性淀粉[J].造纸化学品,1998(20):10-13.
[123]陆赵情,张美云.助留助滤系统的基本理论和最新研究进展[J].西南造纸,2003(1):15-18.
[124]Kweon M R,Hanover E,Sosulski F W.Efect of cross-linking on functional properties of cationie corn starch[J].Stareh/ Starre.1997,(49):461-462.
[125]冯庆梅,张玉军,阎向阳.醚化交联淀扮的制备及性能测定[J].粮油食品科技,2006,14(1):40-42.
[126]李长彪,刘长江,刘春萍等.玉米交联-氧化复合变性淀粉的制备及性能研究[J].食品科学,2005,26(4):111-114.
[127]李忠阳.OS/PDADMAC复合物的形成、水溶液性质、絮凝性能及机理的研究.福建师范大学硕士学位论文,2006:2 8.
[128]武汉大学等编.分析化学[M].北京:高等教育出版社,1996:443-446.
[129]张光华编译.造纸湿部化学原理及其应用[M].中国轻工业出版社,北京,1998,9-22.
[130]Joanna L K,Willian E S.Polyelectrolyte interactions with papermaking fiber:the mechanism of surface-charge decay[J].Tappi Journal,1993(12):123-133.
[131]刘温霞,隆言泉等.阳离子聚电解质在纸浆纤维上吸附的动态变化[J].造纸化学品,2000(1):2-5.
[2]Cosey J P.制浆造纸化学工艺学(中文版第三卷)[M].北京:轻工业出版社,1998.
[3]Scott W E.Fines management and control in wet end chemistry[J].Tappi Journal,1986,69(11):31-34.
[4]Scott W E,Koethe J.Polyeiectrolyte interactions with paper making fibers[J].Tappi Journal,1993,76(12):123-133.
[5]陈夫山,何秋实,隆言泉.两性聚丙烯酰胺的助滤作用[J].纸和造纸,1998(4):43-45.
[6]Scott W E.Principles of Wet End Chemistry[J].TAPPIPRESS,Atlanta,GA.1996.
[7]山田博.造纸过程中的界面动电现象[M].北京:轻工业出版社,1984.
[8]张开.高分子界面科学[M],北京:中国石化出版社,1997.
[9]朱勇强.造纸助剂与湿部化学讲座(二)造纸湿部化学的基本原理[J].上海造纸,2003,34(2):31-34.
[10]凌永龙.造纸湿部化学的进展[J].中国造纸,1996,第4期:52-58.
[11]朱勇强.造纸助剂与湿部化学讲座造纸湿部化学概述[J].上海造纸,2003,34(1):41-44.
[12]Britt.Mechanism of retention during paper formation[J].Tappi Journal,1973(10):46-49.
[13]Klungness J H.,Exner M P.Tappi Journal,1980(6):73.
[14]胡志斌.造纸助剂在非木材植物纤维浆抄纸时的应用[J].天津造纸,2000(Ⅰ):27-30.
[15]付献彩等编.物理化学[M].北京:高等教育出版社,1998:898.
[16]吴玉英.中国造纸助剂的应用现状及发展趋势[J].北京林业大学学报,1999,21(6):89.
[17]宋海农,杨崎峰,黄显南等.多元微粒子助留助滤技术[J].西南造纸,2001(3):8.
[18]谢来苏,胡惠仁,陈夫山等.造纸用两性助剂[J].天津造纸,1999(3):2.
[19]刘松坡,陈港,陶劲松等.两性聚丙烯酰胺在废纸浆中的应用试验[J].造纸科学与技术,2001,21(2):13.
[20]陈夫山,胡惠仁,谢来苏.两性聚丙烯酰胺对麦草浆助留作用的研究[J].纸和造纸,1998(3):52
[21]Oguni,et al.Additive for papermaking[J].United States Patent,1997,12:698,627.
[22]姚献平,郑丽萍.再生纸专用化学品的开发与应用[J].造纸化学品,2001(1):3.
[23]马云静.助留剂在再生新闻纸中的应用[J].西南造纸,2001(6):19.
[24]徐青林,胡惠仁,谢来苏等.造纸工业中几种常见的复式助留体系[J].黑龙江造纸,2000(4):8.
[25]Donald A,Pietsschker.The 100%closed water system what to expect.Tappi proceedings.Papermaking conferences.Tappi Press.Atalanta,1996:521.
[26]Alexander S D,et al.The physical and optical of paper made at high salt concentration[J].Tappi Journal,1997,60(12):121.
[27]刘全校.PEO辅助助剂对胶体悬浮液絮凝作用的影响[J].中华纸业,2002,23(12):29.
[28]刘全校.PEO/PFR双元絮凝系统对造纸白水的絮凝作用[J].纸和造纸,2002,(4):34.
[29]Tom L,et al.Network flocculation and fractionation of latex particales by means of a PEO-PFR complex[J].Journal of colbid and surface science,1984,97(1):62.
[30]刘全校,张风山,李建华等.新型PEO助留助滤体系在新闻纸和双胶纸中的应用研究[J].西南造纸,2002(2):12.
[31]T G M Van de Ven,et al.Association-induced polymer bridging new insights into the retention of fillers with PEO[J].Journal of pulp and paper science,1996,22(7):257.
[32]H.Xiao,et al.Retention mechanisms for two-component system based an phenolic resins and PEO or new PEO-copolymer retention aids[J].Journal of pulp and paper science,1996,22(12):475.
[33]Penniman J G.Unique Dryness Aid:cationic Guar Gum.Paper Trade J,1979,163(5):62.
[34]Dugal H S,Swason J W.Effect of polymer Mannan Content On The Effectiveness of Modified Guar Gum As a beater adhesive[J].Tappi Journal,1972,55(9):1362.
[35]王军利,陈夫山,刘忠.天然的造纸助剂--瓜尔胶[J].造纸化学品,2002(2):19.
[36]张力田.淀粉的化学结构[J].淀粉与淀粉糖,1975(2):25.
[37]Chuenkamol B,Puttanlek C,et al.Characterization of low-substituted hydroxypropylated canna starch[J].Food Hydrocolloids,2007,21(7):1123-1132.
[38]陈颖,吴宗华.几种福建产植物淀粉理化性质的比较[J].淀粉与淀粉糖,2005,(2):17-19.
[39]Thitipraphunkul K,Uttapap D,Piyachomkwan K,et al.A comparative study of edible canna(Canna edulis)starch from different cultivars.Part Ⅰ.Chemical composition and physicochemical properties[J].Carbohydrate Polymers,2003,53:317-324.
[40] Perez E, breene W,Bahnassey Y A. Variations in the gelatinization profiles of cassava and arrowroot native starches as measured with different thermal and mechanical methods[J]. Starch/Staerke, 1998,50, 70-72.
[41] Soni, P L , Sharma, H , Srivastava, H C , & Gharia, M M . Physicochemical properties of Canna edulis starch-comparison with maize starch[J]. Starch/Staerke, 1990,42,460 - 464.
[42] Santacruz S, Koch K, Svensson E, et al. Three underutilised sources of starch from the Adean region . in Ecuador. Part I. Physico-chemical characterisation.Carbohydrate Polymer, 2002, 49, 63 - 70.
[43] Thitipraphunkul K, Uttapap D, Piyachomkwan K, Takeda Y. A comparative study of edible canna (canna edulis) starch from different cultivars, Part 1:Chemical composition and physiochemical properties[J].carbohydrates Polymers, 2003, 53:317-324.
[44] Pham Van Hung, Naofumi Morita. Physicochemical properties and enzymatic digestibility of starch from edible canna (Canna edulis) grown in Vietnam Carbohydrate Polymers, 61 (2005) 314 - 321.
[45] Hung P V, Morita N. Physicochemical properties of hydroxypropylated and cross-linked starches from A-type and B-type wheat starch granules [J]. Carbohydrate Polymers, 2005,59: 239-246.
[46] Puncha-arnon S, Puttanlek C, Rungsardthong V, et al.Changes in physicochemical properties and morphology of canna starches during rhizomal development[J]. Carbohydrate Polymers , 2007,3 (20): 10-16.
[47] Thitipraphunkul K, Uttapap D, Piyachomkwan K, et al.A comparative study of edible canna (Canna edulis) starch from different cultivars. Part II. Molecular structure of amylase and amylopectin[J]. Carbohydrate Polymers, 2003, 54:489-498.
[48] Sirirat Saartrat, Chureerat Puttanlek, Vilai Rungsardthong, Dudsadee Uttapap, Paste and gel properties of low-substituted acetylated canna starches[J]. Carbohydrate Polymers , 2005, 61:211-221.
[49] Bongkot Chuenkamola, Chureerat Puttanlekb, Vilai Rungsardthongc, Dudsadee Uttapap.Characterization of low-substituted hydroxypropylated canna starch[J]. Food Hydrocolloids, 2007, 21: 1123 - 1132.
[50]Puncha-arnon S,Puttanlek C,Rungsardthong V,et al.Changes in physicochemical properties and morphology of canna starches during rhizomal development[J].Carbohydrate Polymers,2007,3(20):10-16.
[51]田培善,林源杰,李蕊.芭蕉芋淀粉衍生物的性能分析及应用[J].棉纺织技术,2004,32(9):521-525.
[52]吴春华,安鑫南,刘应隆.可生物降解的耐水性塑料薄膜的研制[J].南京林业大学学报,2002,26(2):49-51.
[53]郑丽萍,姚献平.纸用变性淀粉的新发展[J].国际造纸,18(4):5-8.
[54]胡本源,张学俊.变性淀粉的特性及应用[J].甘肃科技,2004,20(2):81-82.
[55]张继武,林兴盛.一种有发展前途的变性淀粉-双醛淀粉[J].化学与粘合,2002(2):67-69.
[56]郑昌戈,姚笑红,何艳辉等.双醛淀粉的合成及其氧化度的测定[J].湘潭大学自然科学学报,1996,18(1):70-73.
[57]张继武,朱友益,张强等.玉米淀粉制备双醛淀粉的试验[J].农业工程学报,2002,18(3):135-138.
[58]吴洁.氧化淀粉粘合剂的研制进展[J].化学与粘合,1998(3):167-170.
[59]林险峰.不同情况下氧化剂对玉米淀粉粘合剂质量的影响[J].松辽学刊(自然科学版),1999(2):37-40.
[60]童晓梅.浅谈洗涤助剂的性能及作用机理[J].日用化学品科学,2004,27(10):22-25.
[61]Qin Zhu,Rainer Sjoholm,Kari Nurmi,et al.Structural characterization of oxidized potato starch [J].Carbohy-drate Research,1998,(309):213-218.
[62]Kweon D K,Choi J K,Kim E K,et al.Adsorption of divalentmetal ions by succinylated and oxidized corn starches[J].Carbohydrate Polymers,2001(46):171-177.
[63]葛杰,张功超,白立丰等.变性淀粉在我国的应用及发展趋势[J].黑龙江八一农垦大学学报,2005,17(1):69-73.
[64]Tamaki S,Hisamatsu M,Teranishi K.Strutural changes of maize starch granules by ball-mill treatment[J].Starch,1998,50(8):342-348.
[65]张本山,高大维,林勤保等.高交联马铃薯淀粉的非晶化特征研究[J].中国粮油学报,1999,14(1):19-22.
[66]蔡宗源.交联淀粉醋酸酯的制备及特性[J].暨南大学学报(自然科学版),1994,15(1):100-103.
[67]叶斯奕.淀粉粒度影响可生物降解膜性能的探讨[J].降解塑料通讯,2002,3:17-19.
[68]刘亚伟.淀粉生产及其深加工技术[M].北京:中国轻工业出版社,2001.
[69]Shogren R L,Viswanathan A,Feiker F,et al.Distribution of Octenyl Succinate Groups in Octenyl Succinic Anhydride Modified Waxy MaizeStarch[J].Starch,2000,52:196-204.
[70]Jeon Y S,Viswanathan A,Gross R A.Studies of Starch Esterification:Reactions with Alkenyl Succinates in Qqueous Slurry Systems[J].Starch1999,51:90-93.
[71]易智彪,刘亚伟,袁超等.三重变性小麦淀粉中酯化反应对淀粉糊粘度特性影响的研究[J].粮食与饲料工业,2004,2:15-16.
[72]庄伟洲,梁亮,殷榕灿等.乙二醛交联氧化淀粉粘合剂的研制及其性能研究[J].2006,15(12):14-17.
[73]余少英.交联淀粉对Cr~(3+)离子的吸附研究[J].云南化工,2006,33(6):11-12.
[74]金婵,尤宏,杨玉霞等.以Ce~(4+)为引发剂接枝共聚物羧基淀粉的制备及其去除金属离子效果的研究[J].环境化学,1985,4(1):24-29.
[75]Fanta G F,Swanson C L,DoaneW M.Composites of Starch Poly(ethylene-co-acrylic acid)Complexing between Polymeric-Compoents[J].J Appl Polym Sci,1990,(40):811-821.
[76]刘明华,张新申,邓云.羧甲基淀粉吸附剂对水溶液中铬和铝离子的吸附研究[J].水处理技术,2000,26(4):222-227.
[77]陈静生,周家义.中国水环境重金属研究[M].北京:中国环境科学出版社,1998.
[78]周俊霞.流度及其应用[J].淀粉与淀粉糖,1998,(4):31-33.
[79]卢玉栋,吴宗华.聚胺分子量对其与淀粉的复合物在再生浆上作用效果的影响[J].造纸科学与技术,2003(1):34.
[80]卢玉栋,吴宗华.抄纸条件对淀粉/聚胺复合物作用效果的影响[J].造纸化学品,2002(2):12.
[81]陈少平,吴宗华,凌永泰等.氧化淀粉/PVAm复合物对漂白芦苇化学浆的助留助滤作用[J].中国造纸学报,2005,20(11):142-144.
[82]董朝霞,林梅钦等.光散射技术在研究高分子溶液何凝胶方面的应用[J].高分子通报,2001,(10):5.
[83]何曼君,陈维孝,董西侠.高分子物理[M].上海:复旦大学出版社,1990.
[84]张俐娜,薛其,莫志深等.高分子物理近代研究方法[M].武汉大学出版社,2003.
[85]虞志光.高聚物分子量及其分子量分布的测定[M].上海科学技术出版社,1984.
[86]Pecora R.Dynamic Light Scattering[M].New York Plenum Press,1976.
[87]赵择娜,陆大年,杨定超著.光散射技术[M].北京:纺织工业出版社,1986.
[88]陈重酉.高分子材料科学与工程[M].1990,3(5):55.
[89]张岩飞,崔跃飞.高分子材料科学与工程[M],1990,1:89.
[90]左榘.激光散射与原理在高分子科学中的应用[J].郑州,河南科学技术出版社,1994.
[91]拉贝克.高分子科学实验方法物理原理与应用(吴世康译)[M].北京:科学出版社,1987.
[92]CHIEN JEN-YUAN,YING CHI-TSUNG.Parameters of the Mark-Houwink equation for monodisperse polymer solutions[J].Sciertia Sinica,1962,11(1):66-75.
[93]Ong M H,Jumel J,Tokarczuk P F,Blanshard J M V,Harding S E.Simultaneous determinations of the molecular weight distributions of amyloses and the fine structures of amylopectins of native starches[J].Carbohydrate Research,1994,260:99-117.
[94]Mua J P,Jackson D S.Fine structure of corn amylase and amylopectin fractions with various molecular weights[J].Journal of Agricultural and Food Chemistry,1997,45:3840-3847.
[95]Willett J L,Millard M M,Jasberg B K.Extrusion of waxy maize starch:meltrheology and molecular weight degradation of amylopectin[J].Polymer,1997,38(24):5938-5989.
[96]Yoo S H,Jane J.Structure and physical characteristics of waxy and other wheat starches[J].Carbohydrate Polymers,2002,49:297-305.
[97]Mazeau K,Rinaud M.The prediction of the characteristics of some polysaccharides from molecular modeling Comparison with effective behavior[J].Food Hydrocolloids,2004,18:885-898.
[98]Willett J L,Millard M M,Jasberg B K.Extrusion of waxy maize starch:melt rheology and molecular weight degradation of amylopecti[J].Polymer,1997,38(24):5983-5989.
[99]Van Soest J J G,Benes K,Wit D,et al.The influence of starch molecular mass on the properties of extruded thermoplastic starch[J].Polymer,1996,37(16):3543-3552.
[100]Lee.P O,Nilsson G S,Nilsson K,Wahlund G.Development of asymmeteical flow field-flow fractionation-multi angle laser light scattering analysis for molecular mass characterization of cationic potato amylopecti[J].Journal of Chromatography,2003,A 1101:111-123.
[101]Roger P,Baud B,Colonna P.Characterization of starch polysaccharides by flow field-flow fractionation-multi-angle laser light scattering-differential refractometer index[J].Journal of Chromatography A,2001,917:179-185.
[102]王庭慰,何小兵等.生物合成聚γ-谷氨酸的相对分子质量表征[J].南京工业大学学报,2003,25(6):6-10.
[103]Phan Van Hung,Naofumi Morita.Physicochemical properties and enzymatic digestibility of starch from edible canna(Canna edulis)grown in Vietnam[J].Carbohydrate Polymers,2005,61:314-321.
[104]朱作华,吴天祥.芭蕉芋的性质及其淀粉的工业应用研究[J].生物加工过程,2005,3(4):66-70.
[105]汤庆莉,丘树毅.芭蕉芋淀粉改性研究[J].贵州工业大学学报,1999,28(2):79-85.
[106]Sirirat S,Chureerat P,Vilai R,Dudsadee U.Paste and gel Properties of low-substituted acetylated canna starches[J].Carbohydrate Polymers,2005,61:211-221.
[107]刑剑波等.氧化淀粉变性基团的分析方法[J].山西化工,2002,8:26-27.
[108]张力田.变性淀粉[M].广州:华南理工大学出版社,1999:1-10.
[109]余贻骥.废纸能促进造纸工业发展的重要纤维原料资源[J].国际造纸,2000,19(2):1.
[110]陈嘉翔.扩大二次纤维利用加速造纸工业发展[J].中华纸业,2000,21(9):14.
[111]庞学欣译.提高二次纤维的强度和脱水性能[J].天津造纸,1997,(4):37.
[112]lalegM.UnconventionalStrength Additives[J].NoudicPalpPaperResJ,1993,8(1):41.
[113]巴宾科夫.论水的混凝[M].北京:中国建筑工业出版社,1986.
[114]Billmeyer F W.Textbook of Polymer Science,New York,1984:218.
[115]郭拥军,李健,,冯玉平等.PVP/SDBS“复合物”的物理化学性能研究[J].日用化学工业,1999(5):1-4.
[116]Goddard E D,Ananthapadamanabham Eds K P.Interaction of surfactants with polymers and proteins[M].Boca Raton,CRC Press,1993.
[117]Budd PM..Comprehensive Polymer Science,Pergamon Press,Oxford,1989,Vol(1):226.
[118]沈一丁编.造纸化学品的制备和作用机理[M].北京:中国轻工业出版社,1999.
[119]胡莜敏著.化学助滤剂[M].北京:冶金工业出版社,1999.
[120]陈丽珠.DAMAC-AM共聚物的Hofmann反应及其在造纸中的应用.福建师范大学硕士学位论文,2007:61.
[121]杨秀芳.造纸工业中的氧化淀粉[J].造纸化学品与应用,2004(2):28-29.
[122]付庚昌,和世宝,禹负.造纸化学助剂--改性淀粉[J].造纸化学品,1998(20):10-13.
[123]陆赵情,张美云.助留助滤系统的基本理论和最新研究进展[J].西南造纸,2003(1):15-18.
[124]Kweon M R,Hanover E,Sosulski F W.Efect of cross-linking on functional properties of cationie corn starch[J].Stareh/ Starre.1997,(49):461-462.
[125]冯庆梅,张玉军,阎向阳.醚化交联淀扮的制备及性能测定[J].粮油食品科技,2006,14(1):40-42.
[126]李长彪,刘长江,刘春萍等.玉米交联-氧化复合变性淀粉的制备及性能研究[J].食品科学,2005,26(4):111-114.
[127]李忠阳.OS/PDADMAC复合物的形成、水溶液性质、絮凝性能及机理的研究.福建师范大学硕士学位论文,2006:2 8.
[128]武汉大学等编.分析化学[M].北京:高等教育出版社,1996:443-446.
[129]张光华编译.造纸湿部化学原理及其应用[M].中国轻工业出版社,北京,1998,9-22.
[130]Joanna L K,Willian E S.Polyelectrolyte interactions with papermaking fiber:the mechanism of surface-charge decay[J].Tappi Journal,1993(12):123-133.
[131]刘温霞,隆言泉等.阳离子聚电解质在纸浆纤维上吸附的动态变化[J].造纸化学品,2000(1):2-5.