纳米级TiO_2/沸石/UV催化臭氧化处理水中硝基苯的研究
摘要
目前利用沸石负载TiO_2处理硝基苯的方法主要是半导体光催化法。本文主要采用负载型催化剂TiO_2/沸石,结合紫外光和O_3,将硝基苯完全氧化降解。纳米TiO_2/沸石催化剂采用溶胶-凝胶法制备,制出的催化剂晶型易控制,适合实际工程使用。
单独氧气的吹脱或催化剂吸附对去除硝基苯基本没有效果。通过系统分析O_3/TiO_2/沸石/UV体系降解硝基苯的影响因素,得出在一定范围内,随着进气流量的增加、温度的升高硝基苯的降解速率都会加快。O_3/TiO_2/沸石/UV降解硝基苯的反应属于一级反应,催化臭氧化反应速率与硝基苯的初始浓度无关。PH是影响臭氧氧化过程的一个重要因素,在弱碱性条件下降解硝基苯的效果最好。叔丁醇对硝基苯的降解有很强的抑制作用。TiO_2/沸石催化剂在使用10次时基本失活,对于失活的催化剂采用高温焙烧法可以再生。
另外通过对各种体系降解硝基苯的TOC的研究发现单独臭氧对TOC的去除并没有效果,反应体系中有大量的中间产物产生。而光催化和臭氧联用时臭氧捕获了光催化过程中产生的光致电子e-,生成了更多的强氧化剂·OH,所以O_3/TiO_2/沸石/UV体系对TOC的去除效果最好。通过对O_3/TiO_2/沸石/UV体系降解TOC的影响因素分析,得出氧气进气流量、溶液pH值、催化剂投加量及温度的影响较大。
Nowadays the mostly used alternative of nitrobeneze treatment that based on TiO_2/zeolite catalyst is photocatalytic. This paper is employing ozone together with UV and in particular with a supported catalyst TiO_2/zeolite that can degradate nitrobeneze completely.The oxidation capacity and the photodegradation rate is far better than photocatalytic only. The nanoparticle TiO_2/zeolite catalyst which was suitable for pratical project use was prepared by the sol-gel process.TiO_2/zeolite catalyst was easy to control the crystal.
From the experimental results obtained it is observed that there had no effect to removed nitrobeneze by only use oxygen or catalyst adsorption.Different experimental conditions in degradating nitrobeneze by O_3/TiO_2/zeolite/UV system have been examined,it was showed that with the increase in air flow and temperture,the degradation rate of nitrobeneze will accelerate.Catalytic ozoation reaction was first order with no respect to the initial concentration of nitrobeneze.PH is an important influencing factor which effected the ozone oxidation process,the best effect was received uder alkalescent condition.Tert-butyl alcohol on the degradation of nitrobeneze have a strong inhibitory effct. TiO_2/zeolite catalyst was deactivation after ten times using,and it can be renewable by high temperature roasting.
From investigating various systems degradation of TOC,it is abtained that individual ozone on removing TOC had no effect , there had large number of intermediate products in the reaction system.The photocatalytic combined with ozone can capture the photo-induced electron-e- in the photocatalytic process,generating more strong oxidizer·OH, so O_3/TiO_2/zeolite/UV system on the effect of removing TOC was best.By analyzing the affcting factors on the degradation system of nitrobeneze,it was conculed that some experimental parameters, such as pH value, catalyst dosage and temperature effect strongly the reaction.
单独氧气的吹脱或催化剂吸附对去除硝基苯基本没有效果。通过系统分析O_3/TiO_2/沸石/UV体系降解硝基苯的影响因素,得出在一定范围内,随着进气流量的增加、温度的升高硝基苯的降解速率都会加快。O_3/TiO_2/沸石/UV降解硝基苯的反应属于一级反应,催化臭氧化反应速率与硝基苯的初始浓度无关。PH是影响臭氧氧化过程的一个重要因素,在弱碱性条件下降解硝基苯的效果最好。叔丁醇对硝基苯的降解有很强的抑制作用。TiO_2/沸石催化剂在使用10次时基本失活,对于失活的催化剂采用高温焙烧法可以再生。
另外通过对各种体系降解硝基苯的TOC的研究发现单独臭氧对TOC的去除并没有效果,反应体系中有大量的中间产物产生。而光催化和臭氧联用时臭氧捕获了光催化过程中产生的光致电子e-,生成了更多的强氧化剂·OH,所以O_3/TiO_2/沸石/UV体系对TOC的去除效果最好。通过对O_3/TiO_2/沸石/UV体系降解TOC的影响因素分析,得出氧气进气流量、溶液pH值、催化剂投加量及温度的影响较大。
Nowadays the mostly used alternative of nitrobeneze treatment that based on TiO_2/zeolite catalyst is photocatalytic. This paper is employing ozone together with UV and in particular with a supported catalyst TiO_2/zeolite that can degradate nitrobeneze completely.The oxidation capacity and the photodegradation rate is far better than photocatalytic only. The nanoparticle TiO_2/zeolite catalyst which was suitable for pratical project use was prepared by the sol-gel process.TiO_2/zeolite catalyst was easy to control the crystal.
From the experimental results obtained it is observed that there had no effect to removed nitrobeneze by only use oxygen or catalyst adsorption.Different experimental conditions in degradating nitrobeneze by O_3/TiO_2/zeolite/UV system have been examined,it was showed that with the increase in air flow and temperture,the degradation rate of nitrobeneze will accelerate.Catalytic ozoation reaction was first order with no respect to the initial concentration of nitrobeneze.PH is an important influencing factor which effected the ozone oxidation process,the best effect was received uder alkalescent condition.Tert-butyl alcohol on the degradation of nitrobeneze have a strong inhibitory effct. TiO_2/zeolite catalyst was deactivation after ten times using,and it can be renewable by high temperature roasting.
From investigating various systems degradation of TOC,it is abtained that individual ozone on removing TOC had no effect , there had large number of intermediate products in the reaction system.The photocatalytic combined with ozone can capture the photo-induced electron-e- in the photocatalytic process,generating more strong oxidizer·OH, so O_3/TiO_2/zeolite/UV system on the effect of removing TOC was best.By analyzing the affcting factors on the degradation system of nitrobeneze,it was conculed that some experimental parameters, such as pH value, catalyst dosage and temperature effect strongly the reaction.
引文
[1] Yixin Yang, Jun Ma, Qingdong Qin, etal. Degradation of nitrobenzene by nano-TiO2 catalyzed ozonation[J]. Journal of Molecular Catalysis A: Chemical, 2007, 267: 41-48
[2] Aysegul Latifoglu, Mirat D. Gurol.The effect of humic acids on nitrobenzene oxidation by ozonation and O3/UV processes[J]. Water Research, 2003, 37: 1879-1889
[3] 卢毅明,吴德礼,马鲁铭.硝基苯废水治理的最新研究进展[J].环境科学与管理,2006,6(31):78-81
[4] 毛连山,赵泉珍,林忠祥.硝基苯废水的治理[J].环境污染与防治,2000,22(6):22-24
[5] Aysegul Latifoglu, Mirat D. Gurol. The effect of humic acids on nitrobenzene oxidation by ozonation and O3/UV processes[J]. Water Research, 2003, 37: 1879-1889
[6] 国家环境保护局科技标准司.环境质量与污染物排放国家标准汇编[S].北京:中国标准出版社, 1992:265
[7] Yamagishi T, Miyazaki T, Horii S,etal. Identification of musk xylene and musk ketone infresh water fish collected from the Tama Rever Tokyo. Bull[J].Environ.Contem.Toxic, 1981, 26: 656-662
[8] Gatermann R, Huhnerfuss H, Rimkus G, etal. The distribution of nitrobenzene and other nitroaromatic compounds in the North Sea[J]. Marine Pollution Bulletin, 1994, 30(3): 221-227
[9] 郎佩珍,龙风山,袁星.松花江中游(哨口-松花江村段)水中有毒有机物污染研究[J].环境科学进展,1993,1(6):47-5
[10] 陈国树,刘钦伟.Fe-C联合处理硝基苯废水工艺的研究[J].江西教育学院学报(自然科学),2001,3(22):30-34
[11] 孙明,石彤,袁晓东,刘佳.UV/Fenton法处理硝基苯废水的试验研究[J].辽宁化工,2006,1(35):23-26
[12] 隋铭皓,马军,盛力.MnOx/颗粒活性炭催化臭氧氧化技术降解硝基苯效能研究[J].现代化工,2005,8(25):31-35
[13] 陈萍,邱瑾.国内硝基苯废水治理研究进展[J].贵州化工,2004,2(29):30-34
[14] 李海燕,黄延,安立超.含硝基苯类化合物废水处理技术研究[J].工业水处理,2006,7(26):40-43
[15] 索娜.电催化氧化法处理硝基苯类废水的研究[D].南京理工大学,2006:2-3
[16] Rao, KC Lakshmi Narayan, etal. Color removal from a dyestuff industry effluent using activated carbon[J]. Chem.Technol, 1994, 1(1): 13-19
[17] A.L.Pruden, etal. Degradation on chloroform by photoacssisted heterogerous catalysis in dilute aqueous suspensions of titanium dioxide[J]. Environ.Sci.Technol. 1983, 17 (10): 628-631
[18] 张全兴,王勇,李秀娟,等.树脂吸附法处理硝基苯和硝基氯苯生产废水的研究[J].化工环保,1997,17(6):323-326
[19] 林中祥,程康华.萃取法去除硝基苯生产废水中的硝基酚[J].环境导报,2000,(2):18-20
[20] 于桂珍,靳凛,陈辽玲.利用共沸吸附法处理硝基苯废水的研究[J].辽宁城乡环境科技, 2000, 18(4):23-27
[21] 王丽敏,刘振鸿,王建刚,等.硝基苯废水治理技术研究进展[J].江苏环境科技,2005,2(18):40-42
[22] 宗红鹰,许宜彬.硝基苯水洗废水套用流程的设计与实践[J].化学工程师,2002,93(6):27-29
[23] 林忠祥.萃取法预处理间二硝基苯生产废水[J].环境污染与防治,2002,24(5):279-281
[24] 韦朝海,焦向东,陈焕钦.有毒难降解有机污染物治理方法的研究进展[J].重庆环境科学, 1998,20(4):22-27
[25] 宗红鹰,谢强.硝基苯生产废水处理技术进展[J].化工环保,2003,5(23):265-269
[26] 朱秀华,张诚,丁珂,沙宇.Fenton氧化技术处理硝基苯类废水的实验研究[J].工业安全与环保,2007,1(33):30-33
[27] 沈吉敏,陈忠林,李学艳,等.O3/H2O2去除水中硝基苯效果与机理[J].环境科学,2006,(27):1791-1797
[28] 付冬梅,陈吉平,梁鑫淼.湿式氧化法处理苯酚、苯胺和硝基苯废水的研究[J].精细化工,2004,10(21):772-775
[29] 胡军,周集体,张爱丽,等.光催化-臭氧联用技术协同处理硝基苯废水[J].化工环保,2004,10(24):192-195
[30] 谢娟,屈撑囤,超声波降解水中硝基苯研究[J].化工时刊,2005,11(19):3-5
[31] 赵朝成,赵东风.超临界水氧化技术处理硝基苯废水研究[J].重庆环境科学,2001,(23):45-48
[32] 隋铭皓,马军.臭氧/活性炭对硝基苯的去除效果研究[J].中国给水排水,2001,10(17):71-74
[33] 樊金红,徐文英,高延耀.零价铁体系预处理硝基苯废水机理的研究[J].工业用水与废水,2004,6(35):53-56
[34] 邵春雷,顾丁红,陆晶,等.新型二氧化铅电极处理硝基苯废水[J].环境科学研究,2006,4(19):65-69
[35] Orshansky Frieda, NarkisNava. Evaluation of toxic organics removal by simultaneous adsorption and biodegradation[J]. Proceedings of the industrial Waste Conference, 1997:159-171
[36] 朱小燕,杨英利,李亚岚,等.4 种淡水藻对硝基苯的抗性机制[J].华中师范大学学报(自然科学版),2006,4(40):570-574
[37] 王庆生,李捍东,席北斗,等.利用白腐菌处理含硝基苯类化工废水的研究[J].环境科学研究,2002,2(15):19-21
[38] 叶苗苗,陈忠林,沈吉敏,等.TiO2/UV/O2和TiO2/UV/N2体系降解水中对氯硝基苯[J].感光科学与光化学,2007,4(25):296-305
[39] Rabindra Raj Giri, Hiroaki Ozaki, Takehiro Ishida, etal. Synergy of ozonation and photocatalysis to mineralize low concentration 2,4-dichlorophenoxyacetic acid in aqueous solution[J]. Chemosphere, 2007, 66: 1610-1617
[40] Idil Arslan Alaton, Isil Akmehmet Balcioglu, Detlef W. Bahnemann. Advanced oxidation of a reactive dyebath effluent:comparison of O3, H2O2/UV-C and TiO2/UV-A processes[J]. Water Research, 2002, 36: 1143-1154
[41] Cristina Canton, Santiago Esplugas, Juan Casado. Mineralization of phenol in aqueous solution by ozonation using iron or copper salts and light[J]. Applied Catalysis B: Environmental, 2003, 43: 139-149
[42] B.Legube, N.Karpel, Vel Leitner.Catalytic ozonation: a promising advanced oxidation technology for water treatment[J]. Catalysis Today, 1999, 53: 61-72
[43] 王丽波,孙志忠.Al2O3 催化臭氧化去除水中有机物的研发进展[J].化工进展,2007,4(26):460-466
[44] Ramesh Thiruvenkatachari, Tae Ouk Kwon, Jung Chul Jun, etal,. Application of several advanced oxidation processes for the destruction of terephthalic acid (TPA) [J]. Journal of Hazardous Materials, 2007, 142:308-314
[45] 余宗学.利用Fenton试剂预处理间二硝基苯生产废水[J].环境污染与防治,2002,24(5):282-284
[46] Haag W.R., Yao.C.C. Rate constants for reaction of hydroxyl radicals with several drinking water contaminants[J]. Environ.Sci.Technol., 1992, 26: 1005-1013
[47] Santiago Esplugas, Jaime Gimenez, Sandra Contreras, etal. Comparison of different advanced oxidation processes for phenol degradation[J]. Water Research, 2002, 36: 1034-1042
[48] Barbara Kasprzyk-Hordern, Maria Zió?ek , Jacek Nawrocki. Catalytic ozonation and methods of enhancing molecular ozone reactions in water treatment[J]. Applied Catalysis B: Environmental, 2003, 46: 639-669
[49] 王莉莉,杨孙楷.H2O2/O3组合法处理染料中间体废水的研究[J].环境污染与防治,1994,16(5):11-13
[50] 杨志华,祝万鹏,王利.H2O2/O3组合法处理染料中间体H酸和1-氨基蒽醌生产废液的研究[J].环境科学,1994,15(6):4-6
[51] Prengle H.W. Experimental rate constant and reactor consideration for the destruction of micropollutants and trihalomethane precursors by ozone with UV radiations. Envion.Sci.Techol.,1983,17: 743-749
[52] 童少平,褚有群,马淳安,等.O3/UV降解水中的乙酸和硝基苯[J].中国环境科学,2005,25(3):366-369
[53] 崔龙哲,朴熙定,杨友清,等.UV/O3催化氧化法处理发酵废水中难降解有机物的研究[J].电力环境保护,2004,3(20):54-56
[54] 毛传峰,童少平,刘维屏.臭氧与TiO2/UV 协同降解对氯苯酚[J].环境污染与防治,2003,5(25):259-261
[55] 冯涛,刘洪波,孙月峰.一种新型的水处理高级氧化技术-金属催化臭氧化[J].能源环境保护,2006,4(20):23-26
[56] Fernando J. Beltrán., Francisco J.Rivas, Ramón Montero-de-Espinosa. A TiO2/Al2O3 catalyst to improve the ozonation of oxalic acid in water[J]. Applied Catalysis B: Environmental, 2003, 47: 101-109
[57] Colin Cooper, Robbie Burch.An investigation of catalytic ozonation for the oxidation of halocarbons in drinking water prepapration[J]. Catalysis Research, 1999, 18(33): 3695-3699.
[58] Patrik Kopf, Ernst Gilbert, Siegfried H. Eberle. TiO2 photocatalytic oxidation of monochloroacetic acid and pyridine: influence of ozone[J]. Journal of Photochemistry and Photobiology A: Chemistry, 2000, 136: 163-168
[59] 徐纯芳,黄妙良,程应汉. 沸石负载TiO2催化剂降解有机物的研究[J].化工新型材料,2004,5(32):29-32
[60] 谭砂砾,张玉军,郑华德,张燕等.蜂窝陶瓷负载TiO2光催化降解邻一氯苯酚水溶液[J].环境科学与技术,2004,6(27):95-98
[61] 贾瑞平,陈烨璞.臭氧联合氧化技术在污水处理方面的新进展[J].工业水处理,2007,5(27):4-9
[62] 李绍峰.臭氧-生物活性炭-膜法处理自来水[J].中国给水排水,2002,18(3):69-72.
[63] 陆少鸣,黄海真,方平,等.臭氧-生物活性炭在给水深度处理中的应用[J].水处理技术,2006,32(10):57-59,62
[64] 赵朝成,赵东风.超声-臭氧氧化处理硝基苯废水实验研究[J].上海环境科学,2001,9(20):446-448
[65] Barredo-Damas S, Iborra-Cla M I, Bes-Pia A, et a1. Study of preozonation influence on the physical-chemical treatment of textile waste'water[J]. Desalination, 2005, 182(1-3): 267-274
[66] 李来胜,祝万鹏,张彭义,等.TiO2薄膜光催化臭氧化邻苯二酚[J].催化学报,2003,3(24):163-168
[67] Wei Qiu, Ying Zheng. A comprehensive assessment of supported titania photocatalysts in a fluidized bed photoreactor: Photocatalytic activity and adherence stability[J]. Applied Catalysis B:Environmental, 2007, 71: 151-162
[68] G. Li, X.S. Zhao, Madhumita B. Ray. Advanced oxidation of orange II using TiO2 supported on porous adsorbents: The role of pH, H2O2 and O3[J]. Separation and Purification Technology, 2006, 11: 3-9
[69] 蒋引珊,金为群,张军,等.TiO2沸石复合物结构与光催化性能[J].无机材料学报,2002,6(17):1301-1305
[70] Aysegul Latifoglu, Mirat D. Gurol. The effect of humic acids on nitrobenzene oxidation by ozonation and O3/UV processes[J]. Water Research, 2003, 37: 1879-1889
[71] 国家环保局,《水和废水监测分析方法》编委会.水和废水监测分析方法[M].北京:中国环境科学出版社,2002,467-470
[72] Andreozzi R. The use of manganese dioxide as a heterogeneous catalyst for oxalic acid ozonation in aqueous solution[J]. Applied Catalysis A: General, 1996, 138: 75-81
[73] 刘鑫,刘福田,张宁,等.沸石负载纳米TiO2光催化剂水处理研究进展[J].硅酸盐通报,2006,6(25):135-140
[74] 郑红,汤鸿霄,王怡中.有机污染物半导体多相光催化氧化机理及动力学研究进展[J].环境科学进展,1996,3:1-18
[75] 方送生,蒋引珊,王玉洁,等.天然斜发沸石负载TiO2的光催化性能[J].环境科学,2003,4(24):113-116
[76] Mozgawa W. The influence of some heavy metals cations on the FTIR spectra of zeolites[J]. Journal of Molecular Structure, 2000, 555 (1-3): 299-304.
[77] Christidis G E, Moraetis D, Keheyan E, etal. Chemical and thermal modification of natural HEU-type zeolitic materials from Armenia, Georgia and Greece[J]. Appled Clay Science, 2003, 24(12): 79-91
[78] Keshavaraja A, Ramaswamy V, Soni H S, etal. Synthesis Characyerization and Catalytic properties of Micro-Mesoporous Amorphous Titanosilicate Catalysts[J]. Journal of Catalysis, 1995, 11(157): 501-511
[79] Dutoit D C, Schneider M, Baiker A. Titania-Silica Mixed Oxides: I. Influence of Sol-Gel and Drying Conditions on Strucural Properties[J]. Journal of Catalysis, 1995, 12(153):165-176
[80] Langlais B, Reckhow D A, Deborah R Brink. Ozone in Water Treatment: Application and Engineering. Michigan, USA: Lewis Publishers, 1991: 18-19
[81] Hoffmann M R, Martin S T, Choi W, etal[J]. Chem Rev, 1995, 95(1) : 69
[82] 井立强,徐自力,等.ZnO和TiO2粒子的光催化活性及其失活与再生[J].催化学报,2003,24(3):175-180
[2] Aysegul Latifoglu, Mirat D. Gurol.The effect of humic acids on nitrobenzene oxidation by ozonation and O3/UV processes[J]. Water Research, 2003, 37: 1879-1889
[3] 卢毅明,吴德礼,马鲁铭.硝基苯废水治理的最新研究进展[J].环境科学与管理,2006,6(31):78-81
[4] 毛连山,赵泉珍,林忠祥.硝基苯废水的治理[J].环境污染与防治,2000,22(6):22-24
[5] Aysegul Latifoglu, Mirat D. Gurol. The effect of humic acids on nitrobenzene oxidation by ozonation and O3/UV processes[J]. Water Research, 2003, 37: 1879-1889
[6] 国家环境保护局科技标准司.环境质量与污染物排放国家标准汇编[S].北京:中国标准出版社, 1992:265
[7] Yamagishi T, Miyazaki T, Horii S,etal. Identification of musk xylene and musk ketone infresh water fish collected from the Tama Rever Tokyo. Bull[J].Environ.Contem.Toxic, 1981, 26: 656-662
[8] Gatermann R, Huhnerfuss H, Rimkus G, etal. The distribution of nitrobenzene and other nitroaromatic compounds in the North Sea[J]. Marine Pollution Bulletin, 1994, 30(3): 221-227
[9] 郎佩珍,龙风山,袁星.松花江中游(哨口-松花江村段)水中有毒有机物污染研究[J].环境科学进展,1993,1(6):47-5
[10] 陈国树,刘钦伟.Fe-C联合处理硝基苯废水工艺的研究[J].江西教育学院学报(自然科学),2001,3(22):30-34
[11] 孙明,石彤,袁晓东,刘佳.UV/Fenton法处理硝基苯废水的试验研究[J].辽宁化工,2006,1(35):23-26
[12] 隋铭皓,马军,盛力.MnOx/颗粒活性炭催化臭氧氧化技术降解硝基苯效能研究[J].现代化工,2005,8(25):31-35
[13] 陈萍,邱瑾.国内硝基苯废水治理研究进展[J].贵州化工,2004,2(29):30-34
[14] 李海燕,黄延,安立超.含硝基苯类化合物废水处理技术研究[J].工业水处理,2006,7(26):40-43
[15] 索娜.电催化氧化法处理硝基苯类废水的研究[D].南京理工大学,2006:2-3
[16] Rao, KC Lakshmi Narayan, etal. Color removal from a dyestuff industry effluent using activated carbon[J]. Chem.Technol, 1994, 1(1): 13-19
[17] A.L.Pruden, etal. Degradation on chloroform by photoacssisted heterogerous catalysis in dilute aqueous suspensions of titanium dioxide[J]. Environ.Sci.Technol. 1983, 17 (10): 628-631
[18] 张全兴,王勇,李秀娟,等.树脂吸附法处理硝基苯和硝基氯苯生产废水的研究[J].化工环保,1997,17(6):323-326
[19] 林中祥,程康华.萃取法去除硝基苯生产废水中的硝基酚[J].环境导报,2000,(2):18-20
[20] 于桂珍,靳凛,陈辽玲.利用共沸吸附法处理硝基苯废水的研究[J].辽宁城乡环境科技, 2000, 18(4):23-27
[21] 王丽敏,刘振鸿,王建刚,等.硝基苯废水治理技术研究进展[J].江苏环境科技,2005,2(18):40-42
[22] 宗红鹰,许宜彬.硝基苯水洗废水套用流程的设计与实践[J].化学工程师,2002,93(6):27-29
[23] 林忠祥.萃取法预处理间二硝基苯生产废水[J].环境污染与防治,2002,24(5):279-281
[24] 韦朝海,焦向东,陈焕钦.有毒难降解有机污染物治理方法的研究进展[J].重庆环境科学, 1998,20(4):22-27
[25] 宗红鹰,谢强.硝基苯生产废水处理技术进展[J].化工环保,2003,5(23):265-269
[26] 朱秀华,张诚,丁珂,沙宇.Fenton氧化技术处理硝基苯类废水的实验研究[J].工业安全与环保,2007,1(33):30-33
[27] 沈吉敏,陈忠林,李学艳,等.O3/H2O2去除水中硝基苯效果与机理[J].环境科学,2006,(27):1791-1797
[28] 付冬梅,陈吉平,梁鑫淼.湿式氧化法处理苯酚、苯胺和硝基苯废水的研究[J].精细化工,2004,10(21):772-775
[29] 胡军,周集体,张爱丽,等.光催化-臭氧联用技术协同处理硝基苯废水[J].化工环保,2004,10(24):192-195
[30] 谢娟,屈撑囤,超声波降解水中硝基苯研究[J].化工时刊,2005,11(19):3-5
[31] 赵朝成,赵东风.超临界水氧化技术处理硝基苯废水研究[J].重庆环境科学,2001,(23):45-48
[32] 隋铭皓,马军.臭氧/活性炭对硝基苯的去除效果研究[J].中国给水排水,2001,10(17):71-74
[33] 樊金红,徐文英,高延耀.零价铁体系预处理硝基苯废水机理的研究[J].工业用水与废水,2004,6(35):53-56
[34] 邵春雷,顾丁红,陆晶,等.新型二氧化铅电极处理硝基苯废水[J].环境科学研究,2006,4(19):65-69
[35] Orshansky Frieda, NarkisNava. Evaluation of toxic organics removal by simultaneous adsorption and biodegradation[J]. Proceedings of the industrial Waste Conference, 1997:159-171
[36] 朱小燕,杨英利,李亚岚,等.4 种淡水藻对硝基苯的抗性机制[J].华中师范大学学报(自然科学版),2006,4(40):570-574
[37] 王庆生,李捍东,席北斗,等.利用白腐菌处理含硝基苯类化工废水的研究[J].环境科学研究,2002,2(15):19-21
[38] 叶苗苗,陈忠林,沈吉敏,等.TiO2/UV/O2和TiO2/UV/N2体系降解水中对氯硝基苯[J].感光科学与光化学,2007,4(25):296-305
[39] Rabindra Raj Giri, Hiroaki Ozaki, Takehiro Ishida, etal. Synergy of ozonation and photocatalysis to mineralize low concentration 2,4-dichlorophenoxyacetic acid in aqueous solution[J]. Chemosphere, 2007, 66: 1610-1617
[40] Idil Arslan Alaton, Isil Akmehmet Balcioglu, Detlef W. Bahnemann. Advanced oxidation of a reactive dyebath effluent:comparison of O3, H2O2/UV-C and TiO2/UV-A processes[J]. Water Research, 2002, 36: 1143-1154
[41] Cristina Canton, Santiago Esplugas, Juan Casado. Mineralization of phenol in aqueous solution by ozonation using iron or copper salts and light[J]. Applied Catalysis B: Environmental, 2003, 43: 139-149
[42] B.Legube, N.Karpel, Vel Leitner.Catalytic ozonation: a promising advanced oxidation technology for water treatment[J]. Catalysis Today, 1999, 53: 61-72
[43] 王丽波,孙志忠.Al2O3 催化臭氧化去除水中有机物的研发进展[J].化工进展,2007,4(26):460-466
[44] Ramesh Thiruvenkatachari, Tae Ouk Kwon, Jung Chul Jun, etal,. Application of several advanced oxidation processes for the destruction of terephthalic acid (TPA) [J]. Journal of Hazardous Materials, 2007, 142:308-314
[45] 余宗学.利用Fenton试剂预处理间二硝基苯生产废水[J].环境污染与防治,2002,24(5):282-284
[46] Haag W.R., Yao.C.C. Rate constants for reaction of hydroxyl radicals with several drinking water contaminants[J]. Environ.Sci.Technol., 1992, 26: 1005-1013
[47] Santiago Esplugas, Jaime Gimenez, Sandra Contreras, etal. Comparison of different advanced oxidation processes for phenol degradation[J]. Water Research, 2002, 36: 1034-1042
[48] Barbara Kasprzyk-Hordern, Maria Zió?ek , Jacek Nawrocki. Catalytic ozonation and methods of enhancing molecular ozone reactions in water treatment[J]. Applied Catalysis B: Environmental, 2003, 46: 639-669
[49] 王莉莉,杨孙楷.H2O2/O3组合法处理染料中间体废水的研究[J].环境污染与防治,1994,16(5):11-13
[50] 杨志华,祝万鹏,王利.H2O2/O3组合法处理染料中间体H酸和1-氨基蒽醌生产废液的研究[J].环境科学,1994,15(6):4-6
[51] Prengle H.W. Experimental rate constant and reactor consideration for the destruction of micropollutants and trihalomethane precursors by ozone with UV radiations. Envion.Sci.Techol.,1983,17: 743-749
[52] 童少平,褚有群,马淳安,等.O3/UV降解水中的乙酸和硝基苯[J].中国环境科学,2005,25(3):366-369
[53] 崔龙哲,朴熙定,杨友清,等.UV/O3催化氧化法处理发酵废水中难降解有机物的研究[J].电力环境保护,2004,3(20):54-56
[54] 毛传峰,童少平,刘维屏.臭氧与TiO2/UV 协同降解对氯苯酚[J].环境污染与防治,2003,5(25):259-261
[55] 冯涛,刘洪波,孙月峰.一种新型的水处理高级氧化技术-金属催化臭氧化[J].能源环境保护,2006,4(20):23-26
[56] Fernando J. Beltrán., Francisco J.Rivas, Ramón Montero-de-Espinosa. A TiO2/Al2O3 catalyst to improve the ozonation of oxalic acid in water[J]. Applied Catalysis B: Environmental, 2003, 47: 101-109
[57] Colin Cooper, Robbie Burch.An investigation of catalytic ozonation for the oxidation of halocarbons in drinking water prepapration[J]. Catalysis Research, 1999, 18(33): 3695-3699.
[58] Patrik Kopf, Ernst Gilbert, Siegfried H. Eberle. TiO2 photocatalytic oxidation of monochloroacetic acid and pyridine: influence of ozone[J]. Journal of Photochemistry and Photobiology A: Chemistry, 2000, 136: 163-168
[59] 徐纯芳,黄妙良,程应汉. 沸石负载TiO2催化剂降解有机物的研究[J].化工新型材料,2004,5(32):29-32
[60] 谭砂砾,张玉军,郑华德,张燕等.蜂窝陶瓷负载TiO2光催化降解邻一氯苯酚水溶液[J].环境科学与技术,2004,6(27):95-98
[61] 贾瑞平,陈烨璞.臭氧联合氧化技术在污水处理方面的新进展[J].工业水处理,2007,5(27):4-9
[62] 李绍峰.臭氧-生物活性炭-膜法处理自来水[J].中国给水排水,2002,18(3):69-72.
[63] 陆少鸣,黄海真,方平,等.臭氧-生物活性炭在给水深度处理中的应用[J].水处理技术,2006,32(10):57-59,62
[64] 赵朝成,赵东风.超声-臭氧氧化处理硝基苯废水实验研究[J].上海环境科学,2001,9(20):446-448
[65] Barredo-Damas S, Iborra-Cla M I, Bes-Pia A, et a1. Study of preozonation influence on the physical-chemical treatment of textile waste'water[J]. Desalination, 2005, 182(1-3): 267-274
[66] 李来胜,祝万鹏,张彭义,等.TiO2薄膜光催化臭氧化邻苯二酚[J].催化学报,2003,3(24):163-168
[67] Wei Qiu, Ying Zheng. A comprehensive assessment of supported titania photocatalysts in a fluidized bed photoreactor: Photocatalytic activity and adherence stability[J]. Applied Catalysis B:Environmental, 2007, 71: 151-162
[68] G. Li, X.S. Zhao, Madhumita B. Ray. Advanced oxidation of orange II using TiO2 supported on porous adsorbents: The role of pH, H2O2 and O3[J]. Separation and Purification Technology, 2006, 11: 3-9
[69] 蒋引珊,金为群,张军,等.TiO2沸石复合物结构与光催化性能[J].无机材料学报,2002,6(17):1301-1305
[70] Aysegul Latifoglu, Mirat D. Gurol. The effect of humic acids on nitrobenzene oxidation by ozonation and O3/UV processes[J]. Water Research, 2003, 37: 1879-1889
[71] 国家环保局,《水和废水监测分析方法》编委会.水和废水监测分析方法[M].北京:中国环境科学出版社,2002,467-470
[72] Andreozzi R. The use of manganese dioxide as a heterogeneous catalyst for oxalic acid ozonation in aqueous solution[J]. Applied Catalysis A: General, 1996, 138: 75-81
[73] 刘鑫,刘福田,张宁,等.沸石负载纳米TiO2光催化剂水处理研究进展[J].硅酸盐通报,2006,6(25):135-140
[74] 郑红,汤鸿霄,王怡中.有机污染物半导体多相光催化氧化机理及动力学研究进展[J].环境科学进展,1996,3:1-18
[75] 方送生,蒋引珊,王玉洁,等.天然斜发沸石负载TiO2的光催化性能[J].环境科学,2003,4(24):113-116
[76] Mozgawa W. The influence of some heavy metals cations on the FTIR spectra of zeolites[J]. Journal of Molecular Structure, 2000, 555 (1-3): 299-304.
[77] Christidis G E, Moraetis D, Keheyan E, etal. Chemical and thermal modification of natural HEU-type zeolitic materials from Armenia, Georgia and Greece[J]. Appled Clay Science, 2003, 24(12): 79-91
[78] Keshavaraja A, Ramaswamy V, Soni H S, etal. Synthesis Characyerization and Catalytic properties of Micro-Mesoporous Amorphous Titanosilicate Catalysts[J]. Journal of Catalysis, 1995, 11(157): 501-511
[79] Dutoit D C, Schneider M, Baiker A. Titania-Silica Mixed Oxides: I. Influence of Sol-Gel and Drying Conditions on Strucural Properties[J]. Journal of Catalysis, 1995, 12(153):165-176
[80] Langlais B, Reckhow D A, Deborah R Brink. Ozone in Water Treatment: Application and Engineering. Michigan, USA: Lewis Publishers, 1991: 18-19
[81] Hoffmann M R, Martin S T, Choi W, etal[J]. Chem Rev, 1995, 95(1) : 69
[82] 井立强,徐自力,等.ZnO和TiO2粒子的光催化活性及其失活与再生[J].催化学报,2003,24(3):175-180
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