摘要
通过扫描电子显微镜(SEM)、色散X射线能量谱仪(EDS)、X射线衍射分析(XRD),研究了玄武岩纤维在NaOH、KOH、Ca(OH)_2溶液以及混合模拟水泥孔隙液的腐蚀行为以及失效机制。同时,比较了玄武岩纤维与耐碱玻璃纤维在混合模拟孔隙液中的耐碱性能,测试了纤维腐蚀后的拉伸强度以及质量损失。此外,研究了玄武岩和耐碱玻璃纤维增强砂浆的力学性能以及辅助性胶凝材料(硅灰和粉煤灰)对纤维增强砂浆的力学性能的影响和纤维的保护作用。结果表明,玄武岩纤维对砂浆具有较好的增强作用,但是耐碱性能不如耐碱玻璃纤维;辅助胶凝材料可以提高砂浆的力学性能,并且延缓水泥基体碱性环境对纤维的腐蚀。
The corrosion behavior and failure mechanism of basalt fiber immersed in NaOH,KOH,saturated Ca(OH)_2 solution and mixed simulative cement porewater was studied with Scanning electron microscopy(SEM),Energy disperse spectroscopy(EDS),X-ray diffraction(XRD) and infrared spectroscopy(IR).Meanwhile,the alkali resistance of basalt fiber was investigated by comparison with AR-glass fiber treated by the simulative cement porewater.Weight loss ratio and tensile strength loss of fibers after etching in alkali solution were determined.In addition,the mechanical property of basalt and AR-glass fiber reinforced mortar and the fibers corrosion in mortar were investigated.The effect of supplementary cementitious materials,fly ash and silica fume,on the mechanical property of basalt fiber reinforced mortar and the fiber protection were investigated.The obtained results indicated that basalt fiber had better mechanical improvement efficiency for the mortar,but weaker corrosion resistance than AR-glass fiber.The supplementary cementitious could improve the mechanical property and retard the fiber corrosion.
引文