南淝河表层沉积物中多氯联苯的分布、来源及生态风险评价
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- 英文论文题名：The Distribution, Source and Ecological Risk Assessment of PCBs in surface sediments of Nanfei River
- 论文作者：解宇峰 ; 何斐 ; 徐银慧 ; 张亚
- 英文论文作者：XIE Yu-feng ; HEI Fei ; XU Yin-hui ; ZHANG Ya ; Nanjing Institute of Environmental Sciences ; MEP
- 年：2016
- 作者机构：环境保护部南京环境科学研究所;
- 论文关键词：南淝河 ; 沉积物 ; 多氯联苯 ; 分布 ; 来源 ; 生态风险评价
- 英文论文关键词：Nanfei River ; sediments ; PCBs ; distribution ; source ; ecological risk assessment
- 会议召开时间：2016-12-14
- 会议录名称：2016全国水环境污染控制与生态修复技术高级研讨会论文集
- 语种：中文
- 分类号：X52;X824
- 学会代码：HJKP
- 会议名称：2016全国水环境污染控制与生态修复技术高级研讨会
- 会议地点：中国云南腾冲
- 主办单位：中国环境科学学会、中国环境科学研究院
- 学会名称：中国环境科学学会
- 页数：6
- 文件大小：996k
- 原文格式：D
- 会议级别：全国
摘要
本文以巢湖最大的入湖河流南淝河沉积物为研究对象,利用GC-MS测定南淝河表层沉积物中多氯联苯(PCBs)的含量,主要阐述了南淝河表层沉积物中多氯联苯的残留情况,并运用美国国家环保署法(EPA法)和加拿大沉积物环境质量标准(SQG)对沉积物进行了风险性评价。结果表明,PCBs在南淝河表层沉积物中普遍存在,有22种同系物被检出,属于9类多氯联苯,尤其以二氯联苯、五氯联苯和六氯联苯类为主,主要来源是其流域周围与油漆、绝缘材料的有关工业产业以及大气沉降。南淝河表层沉积物中多氯联苯污染情况具有很高的风险性,对流域内生物生长具有很大威胁。
In this study, the surface sediments of Nanfei River, known as the largest inflowing river of Chaohu Lake, was examined to detect the concentration of Polychlorinated Biphenyls(PCBs) using gas chromatography-mass spectrometry(GC-MS). Then the residual PCBs in surface sediments and following risk assessment according to U.S. Environmental Protection Agency(EPA) methods and Sediment quality guideline(SQG) were descried. As a result, PCBs were common in surface sediments of Nanfei River with 22 kinds of homologuesdetected classified as 9 categories. Among the homologues, the most were dichloro-diphenyl, pentachlorobiphenyl and hexachlorobenzene and mainly result from industries concerning paint and insulation materials, and atmospheric deposition around the water body. What's more, the PCBs pollution in surface sediments of Nanfei River was of high risk, threatening the growth of living things within the water body.
In this study, the surface sediments of Nanfei River, known as the largest inflowing river of Chaohu Lake, was examined to detect the concentration of Polychlorinated Biphenyls(PCBs) using gas chromatography-mass spectrometry(GC-MS). Then the residual PCBs in surface sediments and following risk assessment according to U.S. Environmental Protection Agency(EPA) methods and Sediment quality guideline(SQG) were descried. As a result, PCBs were common in surface sediments of Nanfei River with 22 kinds of homologuesdetected classified as 9 categories. Among the homologues, the most were dichloro-diphenyl, pentachlorobiphenyl and hexachlorobenzene and mainly result from industries concerning paint and insulation materials, and atmospheric deposition around the water body. What's more, the PCBs pollution in surface sediments of Nanfei River was of high risk, threatening the growth of living things within the water body.
引文
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[32]CCME,Canadian Council of Ministers of Environment.Canadian Sediment Quality Guidelines for the Protection of Aquatic Life[S].Ottawa,Ontario,Canada,2002.
[2]秦延文,张雷,郑丙辉,等.渤海湾主要入海河流入海口沉积物有机氯农药污染特征及其来源分析[J].农业环境科学学报,2010,29(10):1900-1906.
[3]邢颖,吕永龙,刘文彬,等.中国部分水域沉积物中多氯联苯污染物的空间分布、污染评价及影响因素分析[J].环境科学,2006(02)
[4]郭军辉,殷月芬,郑立,等.胶州湾东岸表层沉积物中多氯联苯的分布特征及风险评价[J].农业环境科学学报,2011(05).
[5]王桂浩,马嵩,虞坚.钱塘江富阳-杭州段表层沉积物中7种指示性多氯联苯的污染状况调查[J].科技通报,2011,27(3):441-446.
[6]邓安平.酶联免疫吸附分析法测定苯并(a)芘和多氯联苯[J].环境化学,2006,25(3):40-343.
[7]Magdalena Surma-Zadora,Adam Grochowalski.Using a membrane technique(SPM)for high fat food sample preparation in the determination of chlorinated persistent organic pollutants by a GC/ECD method[J].Food Chemistry,2008,111(1):230-235.
[8]陈寒玉,庄惠生,杨光昕.环境样品中多氯联苯的生物检测方法研究进展[J].环境化学,2011,30(5):953-957.
[9]林田,秦延文,张雷,等.辽宁大伙房水库沉积物中有机氯农药和多氯联苯的分布、来源及风险评价[J].环境科学,2011,32(11):3294-3299.
[10]Zhou J L,Hong H,Zhang Z,et al.Mutil-phase distribution oforganic micropollutants in Xianmen Harbour,China[J].Water Research,2000,34(7):2132~2150.
[11]Qiong Lu,Andrew C.Johnson,Monika D.Jürgens,et al.The distribution of Polychlorinated Biphenyls(PCBs)in the River Thames Catchment under the scenarios of climate change[J].Science of the Total Environment,2015,533:187~195.
[12]康跃惠,麦碧娴,黄秀娥,等.珠江三角洲地区水体表层沉积物中有机污染状况初步研究[J].环境科学学报,2000,20(增刊):164-170.
[13]李洪,傅宇众,周传光,等.大连湾和锦州湾表层沉积物中有机氯农药和多氯联苯的分布特征[J].海洋环境科学,1998,17(2):73-76.
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[15]窦薇,赵忠宪.白洋淀几种不同食性鱼类对六六六、DDT的富集[J].环境科学进展,1996,4(6):51-55.
[16]李红莉,李国刚,高虹,等.南四湖表层沉积物中多氯联苯的空间分布特征[J].中国环境监测,2007,23(6):61-64.
[17]王炳一,骆坚平,马梅,等.天津永定新河沉积物中多卤联苯的污染水平和生物有效性[J].环境科学学报,2009,29(11):2427-2432.
[18]张祖麟,洪华生,余刚.闽江口持久性有机污染物——多氯联苯的研究[J].环境科学学报,2002,22(6):788-791.
[19]陈燕燕,尹颖,王晓蓉,等.太湖表层沉积物中PAHs和PCBs的分布及风险评价[J].中国环境科学,2009,29(2):118-124.
[20]Shen M,Yu Y J,Zheng G J,et al.Polychlorinated biphenyls and polybrominated diphenyl ethers in surface sediments from the Yangtze River Delta[J].Marine Pollution Bulletin,2006,52(10):1299-1399.
[21]Wu Y,Zhang J,Zhou Q.Persistent organochlorine residues in sediments from Chinese river/estuary systems[J].Environmental Pollution,1999,105(1):143-150.
[22]孙艳,何孟常,杨志峰,等.黄河中下游表层沉积物中多氯联苯的污染特征[J].环境化学,2005,24(5):590-594.
[23]聂海峰,赵传冬,刘应汉,等.松花江流域河流沉积物中多氯联苯的分布、来源及风险评价[J].环境科学,2012,33(10):3434-3442.
[24]Ma M,Feng Z,Guan C,et al.DDT,PAH and PCB in sediments from the interidal zone of the Bohai Sea and the Yellow Sea[J].Marine Pollution Bulletin,2001,42(2):132-136.
[25]联合国环境规划署,世界卫生组织.多氯联苯和多氯三联苯的环境卫生基准[M].北京:中国环境科学出版社,1987.
[26]Loganathan B C,Kannan K.Global organochlorine contamination trends:an overview[J].Journal of the Human Environment,1994,23(3):187-191.
[27]Di Toro D M,Zarba C S,Hansen D J.Technical basis for establishing sediment quality criteria for nonionic organicchemicals using equilibrium partitioning[J].Environmental Toxicology and Chemistry,1991,10(12):1541-1583.
[28]Chapman P M.Presentation and interpretation of sediment qualitytriaddata[J].Ecotoxicology,1996,5(5):327-339.
[29]Long E R,Field L J,Mac Donald D D.Predicting toxicity inmarine sediments with numerical sediment quality guidelines[J].Environmental Toxicology and Chemistry,1998,17(4):714-727.
[30]Swartz R C.Consensus sediment quality guidelines for polycyclicaromatic hydrocarbon mixtures[J].Environmental Toxicologyand Chemistry,1999,18(4):780-787.
[31]MACDONALD D D,DIPINTO L M,FIELD J,et al.Development andevaluation of consensus-based sediment effect concentrations forpolychlorinatedbiphenyls[J].Environmental Toxicology and Chemis-try,2000,19(5):1403-1413.
[32]CCME,Canadian Council of Ministers of Environment.Canadian Sediment Quality Guidelines for the Protection of Aquatic Life[S].Ottawa,Ontario,Canada,2002.
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