含氟MnO碳材料的合成以及在超级电容器中的应用
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- 英文论文题名：Synthesis of MnO nano-particle@Flourine doped carbon and its application in Hybrid Supercapacitor
- 论文作者：冯晓珂 ; 周丽娜 ; 朱欣欣 ; 屈德宇 ; 刘丹 ; 唐浩林
- 英文论文作者：Xiaoke Feng ; Lina Zhou ; Xinxin Zhu ; Deyu Qu ; Dan Liu ; Haolin Tang ; Department of Chemistry ; School of Chemistry ; Chemical Engineering and Life Science ; Wuhan University of Technology ; State Key Laboratory of Advanced Technology for Materials Synthesis and Processing ; Wuhan University of Technology
- 年：2016
- 作者机构：武汉理工大学化生学院化学系;武汉理工大学材料复合新技术国家重点实验室;
- 论文关键词：氧化锰 ; 炭包覆 ; 氟掺杂
- 会议召开时间：2016-07-01
- 会议录名称：中国化学会第30届学术年会摘要集-第三十分会：化学电源
- 语种：中文
- 分类号：TQ127.11;TM53
- 学会代码：ZGHY
- 会议名称：中国化学会第30届学术年会-第三十分会 ; 化学电源
- 会议地点：中国辽宁大连
- 主办单位：中国化学会
- 学会名称：中国化学会
- 页数：1
- 文件大小：294k
- 原文格式：D
- 会议级别：全国
摘要
本文介绍了氟掺杂炭包覆MnO的合成方法,在这个体系中以Mn(Ac)_2作为锰源,Nafion作为碳源和氟源,在常温下通过调控pH的方法使得反应液中由于静电作用形成Nafion包覆MnO的结构,经过高温煅烧后形成氟掺杂碳包MnO的结构。XRD谱图的峰与PDF卡片对比基本可得出MnO的晶型结构。XPS谱图计算出锰元素的价态。在锂电池中比容量可达270mAh/g,经过200圈循环后仍保持接近100%的效率。在不对称电容器中,以活性炭作为正极时,比容量可达40mAh/g,在不同电流密度下具有良好的倍率性能。
A flourine doped carbon materials encapsulated MnO nano-particle was synthesized through a self-assembly method and characterized by SEM,TEM and XPS.Then this composited carbon materials were employed as negative electrode in a new lithium ion hybrid supercapacitor with a electrochemical double-layer porous carbon positive electrode.The electrochemical performances of this hybrid device was investigated and exhibited a relative high capacity up to 40 mAh g~(-1) and a good cycling stability.
A flourine doped carbon materials encapsulated MnO nano-particle was synthesized through a self-assembly method and characterized by SEM,TEM and XPS.Then this composited carbon materials were employed as negative electrode in a new lithium ion hybrid supercapacitor with a electrochemical double-layer porous carbon positive electrode.The electrochemical performances of this hybrid device was investigated and exhibited a relative high capacity up to 40 mAh g~(-1) and a good cycling stability.
引文
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3.Xie,Q,Ma,Y,Zeng,D,Zhang,X,Wang,L,Yue,G.&Peng,D.-L.ACS applied materials&interfaces 2014,6,19895-19904.
4.Ren,Z,Wang,Z,Chen,C,Wang,J,Fu,X,Fan,C.&Qian,G Electrochimica Acta 2014,146,52-59.
2.Nakajima,T,Gupta,V,Ohzawa,Y,Koh,M,Singh,R.N,Tressaud,A.&Durand,E.Journal of power sources 2002,104,108-114.
3.Xie,Q,Ma,Y,Zeng,D,Zhang,X,Wang,L,Yue,G.&Peng,D.-L.ACS applied materials&interfaces 2014,6,19895-19904.
4.Ren,Z,Wang,Z,Chen,C,Wang,J,Fu,X,Fan,C.&Qian,G Electrochimica Acta 2014,146,52-59.